Specified Developer (i.e., Electron Acceptor) Patents (Class 106/31.17)
  • Patent number: 9876941
    Abstract: In one embodiment, an image forming apparatus forms an image on a recording medium using a plurality of decolorable coloring materials having different decoloring conditions. Further, the image forming apparatus forms a mark relating to authority information indicating authority capable of decoloring one of the plurality of decolorable coloring materials for each of the decolorable coloring materials on the recording medium. Further, in another embodiment, a decoloring apparatus grasps the authority information, and decolors the image of the decolorable coloring material, in accordance with the grasped authority information.
    Type: Grant
    Filed: September 14, 2015
    Date of Patent: January 23, 2018
    Assignees: KABUSHIKI KAISHA TOSHIBA, TOSHIBA TEC KABUSHIKI KAISHA
    Inventor: Masanaka Mizuno
  • Patent number: 9709539
    Abstract: Color change compositions that transition from a first to second color state upon application of an applied stimulus are provided. Also provided are substrates having the compositions on a surface thereof, as well as methods of making and using the compositions.
    Type: Grant
    Filed: December 17, 2015
    Date of Patent: July 18, 2017
    Assignee: Segan Industries, Inc.
    Inventor: Hans O. Ribi
  • Patent number: 9658595
    Abstract: The present invention relates to a security document and/or document of value with a hologram in a visually changeable window as a novel security element, and also to a method for producing the same.
    Type: Grant
    Filed: August 15, 2013
    Date of Patent: May 23, 2017
    Assignee: Covestro Deutschland AG
    Inventors: Georgios Tziovaras, Heinz Pudleiner, Kira Planken, Stefan Janke, Marc-Stephan Weiser, Thomas Fäcke
  • Patent number: 9505254
    Abstract: A substrate coated with a markable ink formulation, comprising a thermo activated acid generator (TAG) and a halochromic leuco dye. The thermo activated acid generator is selected form the group consisting of: an amine salt of an organic metal compound comprising boron or silicone and amine neutralized polyalkylnaphthalene polysulphonic acid derivatives. Further, the substrate is covered by a thermoplastic polymer layer, such that the ink formulation is situated between the substrate and the thermoplastic polymer layer and/or in the thermoplastic polymer layer.
    Type: Grant
    Filed: December 12, 2012
    Date of Patent: November 29, 2016
    Assignee: Tetra Laval Holdings & Finance S.A.
    Inventors: Anthony Jarvis, Chris Wyres, Ladislav Hurdalek, Marcus Rehberger
  • Patent number: 9452629
    Abstract: According to an embodiment, an image forming apparatus includes a fusing device, a cooling device, and a processor. The fusing device includes a fusing member and a pressure member, the fusing member being heated by a heat source. The fusing device conveys a sheet, the sheet being heated and pressed between the fusing member and the pressure member. The processor causes the cooling device to perform the cooling process to cool the fusing member every predetermined timing when the image erasing process is performed.
    Type: Grant
    Filed: January 29, 2016
    Date of Patent: September 27, 2016
    Assignees: KABUSHIKI KAISHA TOSHIBA, TOSHIBA TEC KABUSHIKI KAISHA
    Inventor: Hiroshi Ishii
  • Patent number: 8865620
    Abstract: The present invention provides heat-sensitive coating compositions, which comprise a color developer of formula (1) or mixtures thereof wherein R1 can be hydrogen, C1-20-alkyl, C3-8-cycloalkyl, C2-10-alkenyl, aryl or SO3H, and R2 and R3 can be the same or different and can be hydrogen, halogen, C1-20-alkyl, C3-8-cyclo-alkyl, C2-10-alkenyl, aryl, OR6, NR7R8, SR9, SO3H or COOR10 and R4 and R5 can be the same or different, and can be hydrogen, halogen, C1-20-alkyl, C3-8-cyclo-alkyl, C2-10-alkenyl, aryl, OR6, NR7R8 or SR9, R6, R7, R8, R9 and R10 can be the same or different and can be hydrogen, C1-30-alkyl, C3-8-cycloalkyl, C2-10-alkenyl or aryl, wherein C1-20-alkyl can be unsubstituted or substituted with one or more C3-8-cycloalkyl, C2-10-alkenyl, phenyl, halogen, OR11, NR12R13, SR14, SO3H or COOR15, and aryl can be unsubstituted or substituted with one or more halogen, C1-10-alkyl, halogenated C1-10-alkyl, C3-8-cycloalkyl C2-10-alkenyl, phenyl, OR11, NR12R13, SR14, SO3H or COOR15, wherein R11, R12, R13, R14 an
    Type: Grant
    Filed: March 5, 2008
    Date of Patent: October 21, 2014
    Assignee: Datalase, Ltd.
    Inventors: Allan Francis Cunningham, Thomas Ehlis, Jean-Luc Birbaum, Pascal Hayoz, Kamalesh Pai Fondekar
  • Patent number: 8569208
    Abstract: Color change compositions that transition from a first to second color state upon application of an applied stimulus are provided. Also provided are substrates having the compositions on a surface thereof, as well as methods of making and using the compositions.
    Type: Grant
    Filed: December 21, 2009
    Date of Patent: October 29, 2013
    Assignee: Segan Industries, Inc.
    Inventor: Hans O. Ribi
  • Publication number: 20130116644
    Abstract: The invention describes a color-developing composition that contains at least three major components: (1) a leuco dye or a combination of leuco dyes, (2) an color-developer or a combination of color-developers that can form colored complexes with the leuco dyes, and (3) a desensitizer to temporarily remove the effect of the developer so the leuco dye appears in its colorless form. An optional binder may be included so that the composition may be applied to a substrate as an ink. The ink composition may be applied to synthetic polymeric substrates and other substrates that are incorporated into absorbent articles or personal care products.
    Type: Application
    Filed: November 9, 2011
    Publication date: May 9, 2013
    Inventors: Ning Wei, Xuedong Song, JinHo Ryu, JunMo Gil
  • Patent number: 8303857
    Abstract: The invention relates to a composite with inverse thermochromic properties, the composite changing from a colorless into a colored state with increasing temperature. The composite thereby contains a colorant, a developer and a fluxing agent and also an inorganic filler. The invention likewise relates to a composite material which contains a polymer-based matrix into which at least one composite with inverse thermochromic properties is doped. These composite materials are used in the field of sensor technology, solar technology, transport and communications technology and medical technology.
    Type: Grant
    Filed: April 16, 2008
    Date of Patent: November 6, 2012
    Assignee: Fraunhofer-Gesellschaft zur Forderung der angewandten Forschung e.V.
    Inventors: Arno Seeboth, Olaf Mühling, Ralf Ruhmann, Renate Vetter
  • Patent number: 8110615
    Abstract: The application discloses stable correction fluids and/or correction fluids that change from colored to substantially white (or to a color substantially matching the color of a substrate to which the correction fluid is to be applied) after application to a substrate.
    Type: Grant
    Filed: August 4, 2006
    Date of Patent: February 7, 2012
    Assignee: Sanford, L.P.
    Inventors: Jiandong Zhu, John Thompson, Richard J. Kaiser, George Korper
  • Patent number: 8101544
    Abstract: The present invention provides coating compositions for marking substrates, which comprise a colour former in an amount of from 0.01 to 50%, a metal salt of a carboxylic acid in an amount of from 0.01 to 50%, a binder in an amount of from 1 to 80% and an organic solvent in an amount of from 1 to 99%, wherein each amount is by weight based on the weight of the composition. The present invention also provides a process for the preparation of the composition of the present invention, substrates coated with these compositions and a process for preparing a marked substrate using these compositions.
    Type: Grant
    Filed: December 14, 2005
    Date of Patent: January 24, 2012
    Assignee: Datalase Ltd.
    Inventors: Karen O'Donoghue, Jonathan Campbell
  • Patent number: 8101545
    Abstract: The present invention provides coating compositions for marking substrates, which comprises a color former, an amine salt of an organic metal compound, a binder, a solvent, and optionally additional components, wherein the amine salt of the organic metal compound is of formula (I) in which X is silicon or boron, and E and F are the same or different and are selected from the group consisting of a, b, c, d, e, f, g, h in which R6 and R7 are the same or different are hydrogen, C1-4-alkyl, C1-4-alkoxy, halogen, amino or carboxy, and for X=silicon o=1 and p=0, and R1 is aryl, aralkyl or C1-4-alkyl, or o=1 and p=1, and R1 and R2 together form a one residue selected from the group consisting of a, b, c, d, e, f, g and h, and for X=boron o=0 and p=0, and R3, R4 and R5 are the same or different and are hydrogen, C1-12-alkyl, C1-6-hydroxyalkyl, allyl, aralkyl or arylsulfonyl, in which aralkyl or arylsulfonyl can be substituted with C1-4-alkyl, or R3 and R4 together with the nitrogen to which they are attached form a m
    Type: Grant
    Filed: March 13, 2006
    Date of Patent: January 24, 2012
    Assignee: Datalase Ltd.
    Inventors: Jonathan Campbell, John Whitworth, Alan Platt, Ian Street
  • Patent number: 8093179
    Abstract: Storage-stable compositions comprising a color developer, an anionic dispersant and a thickening agent as well as heat-sensitive recording materials comprising such compositions, a process for its manufacture and its use.
    Type: Grant
    Filed: July 19, 2006
    Date of Patent: January 10, 2012
    Assignee: BASF SE
    Inventor: Robert Montgomery O'Neil
  • Patent number: 7846984
    Abstract: If an ultraviolet curing resin is colored by contamination by another substance, there have been issues regarding increased cost and the environmental burden of treating the waste solution due to an inability to recycle the resin as it is. The ultraviolet curing resin that is in a colored, uncured state is decolored in the present invention by irradiation of light having a wavelength in the vicinity of the maximum absorption wavelength of the coloring material, and then recycled. As a result, it is possible to reduce costs and contribute to the protection of the environment.
    Type: Grant
    Filed: April 11, 2005
    Date of Patent: December 7, 2010
    Assignee: Panasonic Corporation
    Inventors: Yukako Doi, Toshiyuki Aoyama
  • Patent number: 7815723
    Abstract: A no-mess water-based ink including a composition including water, an organic solvent, a coloring agent dissolved in the organic solvent, an emulsifier and a thickening agent for use in conjunction with a specially treated substrate containing a color developer.
    Type: Grant
    Filed: August 3, 2006
    Date of Patent: October 19, 2010
    Assignee: Crayola LLC
    Inventors: Jie Li, Leena Vadaketh, Jacqueline Aseng
  • Patent number: 7727319
    Abstract: A no-mess water-based ink including a composition including water, an organic solvent, a coloring agent dissolved in the organic solvent and an emulsifier for use in conjunction with a specially treated substrate containing a color developer.
    Type: Grant
    Filed: April 19, 2006
    Date of Patent: June 1, 2010
    Assignee: Crayola LLC
    Inventors: Jie Li, Leena Vadaketh, Jacqueline Aseng
  • Patent number: 7632781
    Abstract: A color developer for heat sensitive recording which comprises 0.5 to 5 parts by mass of 3-allyl-4-allyloxy-4?-hydroxydiphenylsulfone, 4-allyloxy-3?-allyl-4?-hydroxydiphenylsulfone or a mixture of these compounds per 100 parts by mass of 4-allyloxy-4?-hydroxydiphenylsulfone, a process for producing the color developer and a heat sensitive recording material comprising the color developer in the heat sensitive color forming layer. The color developer and the recording material suppress fog on the background and exhibit excellent color forming property and storage property of image portions.
    Type: Grant
    Filed: April 18, 2005
    Date of Patent: December 15, 2009
    Assignee: Nicca Chemical Co., Ltd.
    Inventors: Mikihiko Kurose, Takeo Hasegawa
  • Patent number: 7442725
    Abstract: An improved color changing correction fluid is provided which includes either a volatile base or a volatile acid in combination with a color changing pH indicator, all in a water based fluid or system. As the fluid dries, the volatile base or acid evaporates along with the water and the pH color changing indicator changes from a colored state to a clear state. For white paper, a white pigment is utilized and therefore the fluid changes from a colored state to a white finished state as the solvent water and acid or base evaporates. Different color pigments can be utilized to match the color of the particular paper or substrate.
    Type: Grant
    Filed: February 11, 2004
    Date of Patent: October 28, 2008
    Assignee: Sanford, L.P.
    Inventors: Wing Sum Vincent Kwan, Jiandong Zhu
  • Publication number: 20070270310
    Abstract: In one aspect, a method includes directing electromagnetic radiation to a structure, the structure including a substrate, a first layer, and a marking composition between the substrate and the first layer. At least a portion of the electromagnetic radiation is transmitted through the first layer, and the structure is marked.
    Type: Application
    Filed: May 22, 2006
    Publication date: November 22, 2007
    Inventors: David H. Blank, Benjamin J. Brown, Michael P. Secord, James W. Foley
  • Publication number: 20070245925
    Abstract: A no-mess water-based ink including a composition including water, an organic solvent, a coloring agent dissolved in the organic solvent, an emulsifier and a thickening agent for use in conjunction with a specially treated substrate containing a color developer.
    Type: Application
    Filed: August 3, 2006
    Publication date: October 25, 2007
    Inventors: Jie Li, Leena Vadaketh, Jacqueline Aseng
  • Patent number: 7208449
    Abstract: A decolorable image forming material contains a color former and a developer, that develop a colored state through interaction therebetween and can be decolored by heating or contact with a solvent, in which the developer contains two or more compounds whose deference in molecular weight is 15 or more.
    Type: Grant
    Filed: January 19, 2005
    Date of Patent: April 24, 2007
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Kenji Sano, Satoshi Takayama, Masanori Ogiue
  • Patent number: 7060654
    Abstract: A coating includes an antenna uniformly distributed in both a matrix and a leuco-dye phase of the coating. A method for preparing an imaging material includes providing a powder having an activator and an antenna, dissolving the activator/antenna powder to form an activator/matrix pre-polymer solution, providing a leuco-dye alloy, and dispersing the leuco-dye alloy into the activator/matrix pre-polymer solution to form a radiation-curable paste. An image-recording medium includes a matrix having an antenna and an activator, and an alloy dispersed in the matrix as an independent phase. The alloy includes an antenna, a leuco-dye, and an accelerator.
    Type: Grant
    Filed: October 28, 2003
    Date of Patent: June 13, 2006
    Assignee: Hewlett-Packard Development Company
    Inventors: Vladek P Kasperchik, Makarand P. Gore, Marshall Field, Jayprakash Bhatt
  • Publication number: 20040116213
    Abstract: There are described articles bearing indicia applied with an ink composition which comprises two or more color-changing or color-forming components which combine, or become diluted, upon exposure to water for a sufficient period of time to cause a change in the appearance of the indicia. Also described are printing ink compositions for forming such indicia and methods for forming such articles.
    Type: Application
    Filed: December 5, 2003
    Publication date: June 17, 2004
    Inventors: Michael P. Filosa, Fariza B. Hasan, Stephen J. Telfer
  • Patent number: 6652959
    Abstract: Disclosed are marking particles comprising a resin, a chelating agent, and a spiropyran material which is of the formula The marking particles are prepared by an emulsion aggregation process.
    Type: Grant
    Filed: January 11, 2002
    Date of Patent: November 25, 2003
    Assignee: Xerox Corporation
    Inventors: Daniel A. Foucher, Raj D. Patel, Naveen Chopra, Peter M. Kazmaier
  • Patent number: 6500245
    Abstract: A thermoresponsive coloring formulation for use on a reimageable image carrier is provided. An image may be created by exposing the thermoresponsive coloring formulation to heat and erased by exposing it to white light. A screen coated with an uncured stencil coating is placed in registration with the image carrier. The screen and image carrier are exposed to a curing agent which is prevented from passing beyond the image carrier in those areas covered by the image, while the areas of the coated screen that are exposed to the curing agent are hardened by the curing agent. After the stencil coating has been hardened in the desired areas, the screen is removed, and the uncured stencil coating is rinsed away from the screen, leaving a portion of the screen with open pores through which ink can flow.
    Type: Grant
    Filed: February 9, 2000
    Date of Patent: December 31, 2002
    Inventors: Geoffrey A. McCue, Sebastian V. Kanakkanatt
  • Patent number: 6395680
    Abstract: A composition includes at least two aromatic carboxylic acid compounds selected from the group consisting of aromatic carboxylic acid compounds of formulas (I), (II) and (III) as specified in the specification. A thermosensitive recording material has a support, and a thermosensitive coloring layer formed thereon which contains a leuco dye and a color developer capable of inducing color formation in the leuco dye upon application of heat thereto, with the color developer comprising the aforementioned composition of the aromatic carboxylic acid compounds.
    Type: Grant
    Filed: April 12, 2000
    Date of Patent: May 28, 2002
    Assignees: Ricoh Company, Ltd., Nicca Chemical Co., Ltd.
    Inventors: Mitsunobu Morita, Kunio Hayakawa, Ikuo Kameoka, Xiaonan Yang
  • Patent number: 6383982
    Abstract: A color developer composition comprising (A) a color developer containing a polyvalent metal salt of a salicylic acid derivative, and (B) a polyester polyol having in the molecule skeleton at least one carbonate bond or ester bond, and a derivative thereof, an aqueous dispersion and a color developing ink using this color developer composition, and a recording sheet having a layer containing this color developer composition on a base material.
    Type: Grant
    Filed: May 2, 2000
    Date of Patent: May 7, 2002
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Jotaro Kida, Yoshimitsu Tanabe, Nobuhiro Takizawa, Masakatsu Nakatsuka
  • Patent number: 6365312
    Abstract: Disclosed are marking particles comprising a first polymer, a second polymer, a chelating agent, and a spiropyran material of the formula wherein n is an integer representing the number of repeat —CH2— units and R is —H or —CH═CH2. The marking particles comprise a core containing the first polymer in which is dispersed the chelating agent and the spiropyran and encapsulated within a shell of the second polymer formulated by an interfacial polymerization.
    Type: Grant
    Filed: May 24, 2001
    Date of Patent: April 2, 2002
    Assignee: Xerox Corporation
    Inventors: Daniel A. Foucher, Raj D. Patel, Naveen Chopra, Peter M. Kazmaier, James Wojtyk, Erwin Buncel
  • Patent number: 6358655
    Abstract: Disclosed are marking particles comprising a resin, a chelating agent, and a spiropyran material which is of the formula The marking particles are prepared by an emulsion aggregation process.
    Type: Grant
    Filed: May 24, 2001
    Date of Patent: March 19, 2002
    Assignee: Xerox Corporation
    Inventors: Daniel A. Foucher, Raj D. Patel, Naveen Chopra, Peter M. Kazmaier
  • Patent number: 6326332
    Abstract: A decolorable material contains a color former, a developer, a matrix material, and a decolorant capable of physically or chemically adsorbing the developer, the developer having a molecular weight of 120 to 210. The material is capable of forming a clear image, and the image formed from the material can be decolored well, even when the amount of the decolorant used is small.
    Type: Grant
    Filed: March 24, 2000
    Date of Patent: December 4, 2001
    Assignee: Kabushiki Kaisha Toshiba
    Inventor: Satoshi Takayama
  • Patent number: 6299674
    Abstract: A fingerprint detecting agent and a fingerprint detecting method using the agent, which can be used to detect latent fingerprints being in a wet condition, the fingerprint detecting agent includes a fixer containing silicone series compound, fluoride series compound, hydrocarbon series compound, animal or vegetable oil, higher fatty acid, or higher alcohol, and an arbitrary mixture thereof; a diluent containing polar soluent; a developer containing achromatic colored powder or chromatic colored powder. Latent fingerprints can be easily detected by spraying the fingerprint detecting agent; particularly, even if the latent fingerprints to be detected are in a wet condition, it is possible to detect them speedily and certainly.
    Type: Grant
    Filed: November 12, 1999
    Date of Patent: October 9, 2001
    Assignee: Taiho Industries Co., Ltd.
    Inventors: Yasuo Takamura, Masaharu Shimizu, Takashi Fukuchi, Fujio Ishizawa, Akira Miyagi, Nobuyasu Ochiai, Atsushi Ikeda, Kiyoshi Okamura
  • Publication number: 20010025587
    Abstract: A reversible thermosensitive coloring composition including an electron donating coloring agent and an electron accepting color developer, wherein the composition achieves a colored state when heated at a temperature not lower than a coloring temperature and then cooled at a cooling speed (a), and the composition in the colored state achieves a non-colored state when heated at a temperature lower than the coloring temperature and not lower than an erasing temperature, or when heated at a temperature not lower than the coloring temperature and then cooled relatively slowly compared to the cooling speed (a), and wherein the electron accepting color developer includes a phenolic compound having the following formula (1): 1
    Type: Application
    Filed: January 24, 2001
    Publication date: October 4, 2001
    Inventors: Masafumi Torii, Hiroaki Matsui, Masaru Shimada
  • Patent number: 6203603
    Abstract: An erasable image forming material includes a color former, a developer, a binder resin, and a polymer decolorizer having an electron donating group capable of physically or chemically adsorbing the developer. This polymer decolorizer is, e.g., a polymer compound having a sugar skeleton, representatively starch. This image forming material can form sharp images and erase images by heat or a solvent to achieve a good erased state.
    Type: Grant
    Filed: August 3, 1999
    Date of Patent: March 20, 2001
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Satoshi Takayama, Shigeru Machida, Kenji Sano, Koichi Tsunemi, Shuitsu Sato