Specified Developer (i.e., Electron Acceptor) Patents (Class 106/31.17)
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Patent number: 9876941Abstract: In one embodiment, an image forming apparatus forms an image on a recording medium using a plurality of decolorable coloring materials having different decoloring conditions. Further, the image forming apparatus forms a mark relating to authority information indicating authority capable of decoloring one of the plurality of decolorable coloring materials for each of the decolorable coloring materials on the recording medium. Further, in another embodiment, a decoloring apparatus grasps the authority information, and decolors the image of the decolorable coloring material, in accordance with the grasped authority information.Type: GrantFiled: September 14, 2015Date of Patent: January 23, 2018Assignees: KABUSHIKI KAISHA TOSHIBA, TOSHIBA TEC KABUSHIKI KAISHAInventor: Masanaka Mizuno
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Patent number: 9709539Abstract: Color change compositions that transition from a first to second color state upon application of an applied stimulus are provided. Also provided are substrates having the compositions on a surface thereof, as well as methods of making and using the compositions.Type: GrantFiled: December 17, 2015Date of Patent: July 18, 2017Assignee: Segan Industries, Inc.Inventor: Hans O. Ribi
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Patent number: 9658595Abstract: The present invention relates to a security document and/or document of value with a hologram in a visually changeable window as a novel security element, and also to a method for producing the same.Type: GrantFiled: August 15, 2013Date of Patent: May 23, 2017Assignee: Covestro Deutschland AGInventors: Georgios Tziovaras, Heinz Pudleiner, Kira Planken, Stefan Janke, Marc-Stephan Weiser, Thomas Fäcke
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Patent number: 9505254Abstract: A substrate coated with a markable ink formulation, comprising a thermo activated acid generator (TAG) and a halochromic leuco dye. The thermo activated acid generator is selected form the group consisting of: an amine salt of an organic metal compound comprising boron or silicone and amine neutralized polyalkylnaphthalene polysulphonic acid derivatives. Further, the substrate is covered by a thermoplastic polymer layer, such that the ink formulation is situated between the substrate and the thermoplastic polymer layer and/or in the thermoplastic polymer layer.Type: GrantFiled: December 12, 2012Date of Patent: November 29, 2016Assignee: Tetra Laval Holdings & Finance S.A.Inventors: Anthony Jarvis, Chris Wyres, Ladislav Hurdalek, Marcus Rehberger
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Patent number: 9452629Abstract: According to an embodiment, an image forming apparatus includes a fusing device, a cooling device, and a processor. The fusing device includes a fusing member and a pressure member, the fusing member being heated by a heat source. The fusing device conveys a sheet, the sheet being heated and pressed between the fusing member and the pressure member. The processor causes the cooling device to perform the cooling process to cool the fusing member every predetermined timing when the image erasing process is performed.Type: GrantFiled: January 29, 2016Date of Patent: September 27, 2016Assignees: KABUSHIKI KAISHA TOSHIBA, TOSHIBA TEC KABUSHIKI KAISHAInventor: Hiroshi Ishii
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Patent number: 8865620Abstract: The present invention provides heat-sensitive coating compositions, which comprise a color developer of formula (1) or mixtures thereof wherein R1 can be hydrogen, C1-20-alkyl, C3-8-cycloalkyl, C2-10-alkenyl, aryl or SO3H, and R2 and R3 can be the same or different and can be hydrogen, halogen, C1-20-alkyl, C3-8-cyclo-alkyl, C2-10-alkenyl, aryl, OR6, NR7R8, SR9, SO3H or COOR10 and R4 and R5 can be the same or different, and can be hydrogen, halogen, C1-20-alkyl, C3-8-cyclo-alkyl, C2-10-alkenyl, aryl, OR6, NR7R8 or SR9, R6, R7, R8, R9 and R10 can be the same or different and can be hydrogen, C1-30-alkyl, C3-8-cycloalkyl, C2-10-alkenyl or aryl, wherein C1-20-alkyl can be unsubstituted or substituted with one or more C3-8-cycloalkyl, C2-10-alkenyl, phenyl, halogen, OR11, NR12R13, SR14, SO3H or COOR15, and aryl can be unsubstituted or substituted with one or more halogen, C1-10-alkyl, halogenated C1-10-alkyl, C3-8-cycloalkyl C2-10-alkenyl, phenyl, OR11, NR12R13, SR14, SO3H or COOR15, wherein R11, R12, R13, R14 anType: GrantFiled: March 5, 2008Date of Patent: October 21, 2014Assignee: Datalase, Ltd.Inventors: Allan Francis Cunningham, Thomas Ehlis, Jean-Luc Birbaum, Pascal Hayoz, Kamalesh Pai Fondekar
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Patent number: 8569208Abstract: Color change compositions that transition from a first to second color state upon application of an applied stimulus are provided. Also provided are substrates having the compositions on a surface thereof, as well as methods of making and using the compositions.Type: GrantFiled: December 21, 2009Date of Patent: October 29, 2013Assignee: Segan Industries, Inc.Inventor: Hans O. Ribi
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Publication number: 20130116644Abstract: The invention describes a color-developing composition that contains at least three major components: (1) a leuco dye or a combination of leuco dyes, (2) an color-developer or a combination of color-developers that can form colored complexes with the leuco dyes, and (3) a desensitizer to temporarily remove the effect of the developer so the leuco dye appears in its colorless form. An optional binder may be included so that the composition may be applied to a substrate as an ink. The ink composition may be applied to synthetic polymeric substrates and other substrates that are incorporated into absorbent articles or personal care products.Type: ApplicationFiled: November 9, 2011Publication date: May 9, 2013Inventors: Ning Wei, Xuedong Song, JinHo Ryu, JunMo Gil
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Patent number: 8303857Abstract: The invention relates to a composite with inverse thermochromic properties, the composite changing from a colorless into a colored state with increasing temperature. The composite thereby contains a colorant, a developer and a fluxing agent and also an inorganic filler. The invention likewise relates to a composite material which contains a polymer-based matrix into which at least one composite with inverse thermochromic properties is doped. These composite materials are used in the field of sensor technology, solar technology, transport and communications technology and medical technology.Type: GrantFiled: April 16, 2008Date of Patent: November 6, 2012Assignee: Fraunhofer-Gesellschaft zur Forderung der angewandten Forschung e.V.Inventors: Arno Seeboth, Olaf Mühling, Ralf Ruhmann, Renate Vetter
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Patent number: 8110615Abstract: The application discloses stable correction fluids and/or correction fluids that change from colored to substantially white (or to a color substantially matching the color of a substrate to which the correction fluid is to be applied) after application to a substrate.Type: GrantFiled: August 4, 2006Date of Patent: February 7, 2012Assignee: Sanford, L.P.Inventors: Jiandong Zhu, John Thompson, Richard J. Kaiser, George Korper
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Patent number: 8101544Abstract: The present invention provides coating compositions for marking substrates, which comprise a colour former in an amount of from 0.01 to 50%, a metal salt of a carboxylic acid in an amount of from 0.01 to 50%, a binder in an amount of from 1 to 80% and an organic solvent in an amount of from 1 to 99%, wherein each amount is by weight based on the weight of the composition. The present invention also provides a process for the preparation of the composition of the present invention, substrates coated with these compositions and a process for preparing a marked substrate using these compositions.Type: GrantFiled: December 14, 2005Date of Patent: January 24, 2012Assignee: Datalase Ltd.Inventors: Karen O'Donoghue, Jonathan Campbell
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Patent number: 8101545Abstract: The present invention provides coating compositions for marking substrates, which comprises a color former, an amine salt of an organic metal compound, a binder, a solvent, and optionally additional components, wherein the amine salt of the organic metal compound is of formula (I) in which X is silicon or boron, and E and F are the same or different and are selected from the group consisting of a, b, c, d, e, f, g, h in which R6 and R7 are the same or different are hydrogen, C1-4-alkyl, C1-4-alkoxy, halogen, amino or carboxy, and for X=silicon o=1 and p=0, and R1 is aryl, aralkyl or C1-4-alkyl, or o=1 and p=1, and R1 and R2 together form a one residue selected from the group consisting of a, b, c, d, e, f, g and h, and for X=boron o=0 and p=0, and R3, R4 and R5 are the same or different and are hydrogen, C1-12-alkyl, C1-6-hydroxyalkyl, allyl, aralkyl or arylsulfonyl, in which aralkyl or arylsulfonyl can be substituted with C1-4-alkyl, or R3 and R4 together with the nitrogen to which they are attached form a mType: GrantFiled: March 13, 2006Date of Patent: January 24, 2012Assignee: Datalase Ltd.Inventors: Jonathan Campbell, John Whitworth, Alan Platt, Ian Street
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Patent number: 8093179Abstract: Storage-stable compositions comprising a color developer, an anionic dispersant and a thickening agent as well as heat-sensitive recording materials comprising such compositions, a process for its manufacture and its use.Type: GrantFiled: July 19, 2006Date of Patent: January 10, 2012Assignee: BASF SEInventor: Robert Montgomery O'Neil
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Patent number: 7846984Abstract: If an ultraviolet curing resin is colored by contamination by another substance, there have been issues regarding increased cost and the environmental burden of treating the waste solution due to an inability to recycle the resin as it is. The ultraviolet curing resin that is in a colored, uncured state is decolored in the present invention by irradiation of light having a wavelength in the vicinity of the maximum absorption wavelength of the coloring material, and then recycled. As a result, it is possible to reduce costs and contribute to the protection of the environment.Type: GrantFiled: April 11, 2005Date of Patent: December 7, 2010Assignee: Panasonic CorporationInventors: Yukako Doi, Toshiyuki Aoyama
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Patent number: 7815723Abstract: A no-mess water-based ink including a composition including water, an organic solvent, a coloring agent dissolved in the organic solvent, an emulsifier and a thickening agent for use in conjunction with a specially treated substrate containing a color developer.Type: GrantFiled: August 3, 2006Date of Patent: October 19, 2010Assignee: Crayola LLCInventors: Jie Li, Leena Vadaketh, Jacqueline Aseng
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Patent number: 7727319Abstract: A no-mess water-based ink including a composition including water, an organic solvent, a coloring agent dissolved in the organic solvent and an emulsifier for use in conjunction with a specially treated substrate containing a color developer.Type: GrantFiled: April 19, 2006Date of Patent: June 1, 2010Assignee: Crayola LLCInventors: Jie Li, Leena Vadaketh, Jacqueline Aseng
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Patent number: 7632781Abstract: A color developer for heat sensitive recording which comprises 0.5 to 5 parts by mass of 3-allyl-4-allyloxy-4?-hydroxydiphenylsulfone, 4-allyloxy-3?-allyl-4?-hydroxydiphenylsulfone or a mixture of these compounds per 100 parts by mass of 4-allyloxy-4?-hydroxydiphenylsulfone, a process for producing the color developer and a heat sensitive recording material comprising the color developer in the heat sensitive color forming layer. The color developer and the recording material suppress fog on the background and exhibit excellent color forming property and storage property of image portions.Type: GrantFiled: April 18, 2005Date of Patent: December 15, 2009Assignee: Nicca Chemical Co., Ltd.Inventors: Mikihiko Kurose, Takeo Hasegawa
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Patent number: 7442725Abstract: An improved color changing correction fluid is provided which includes either a volatile base or a volatile acid in combination with a color changing pH indicator, all in a water based fluid or system. As the fluid dries, the volatile base or acid evaporates along with the water and the pH color changing indicator changes from a colored state to a clear state. For white paper, a white pigment is utilized and therefore the fluid changes from a colored state to a white finished state as the solvent water and acid or base evaporates. Different color pigments can be utilized to match the color of the particular paper or substrate.Type: GrantFiled: February 11, 2004Date of Patent: October 28, 2008Assignee: Sanford, L.P.Inventors: Wing Sum Vincent Kwan, Jiandong Zhu
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Publication number: 20070270310Abstract: In one aspect, a method includes directing electromagnetic radiation to a structure, the structure including a substrate, a first layer, and a marking composition between the substrate and the first layer. At least a portion of the electromagnetic radiation is transmitted through the first layer, and the structure is marked.Type: ApplicationFiled: May 22, 2006Publication date: November 22, 2007Inventors: David H. Blank, Benjamin J. Brown, Michael P. Secord, James W. Foley
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Publication number: 20070245925Abstract: A no-mess water-based ink including a composition including water, an organic solvent, a coloring agent dissolved in the organic solvent, an emulsifier and a thickening agent for use in conjunction with a specially treated substrate containing a color developer.Type: ApplicationFiled: August 3, 2006Publication date: October 25, 2007Inventors: Jie Li, Leena Vadaketh, Jacqueline Aseng
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Patent number: 7208449Abstract: A decolorable image forming material contains a color former and a developer, that develop a colored state through interaction therebetween and can be decolored by heating or contact with a solvent, in which the developer contains two or more compounds whose deference in molecular weight is 15 or more.Type: GrantFiled: January 19, 2005Date of Patent: April 24, 2007Assignee: Kabushiki Kaisha ToshibaInventors: Kenji Sano, Satoshi Takayama, Masanori Ogiue
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Patent number: 7060654Abstract: A coating includes an antenna uniformly distributed in both a matrix and a leuco-dye phase of the coating. A method for preparing an imaging material includes providing a powder having an activator and an antenna, dissolving the activator/antenna powder to form an activator/matrix pre-polymer solution, providing a leuco-dye alloy, and dispersing the leuco-dye alloy into the activator/matrix pre-polymer solution to form a radiation-curable paste. An image-recording medium includes a matrix having an antenna and an activator, and an alloy dispersed in the matrix as an independent phase. The alloy includes an antenna, a leuco-dye, and an accelerator.Type: GrantFiled: October 28, 2003Date of Patent: June 13, 2006Assignee: Hewlett-Packard Development CompanyInventors: Vladek P Kasperchik, Makarand P. Gore, Marshall Field, Jayprakash Bhatt
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Publication number: 20040116213Abstract: There are described articles bearing indicia applied with an ink composition which comprises two or more color-changing or color-forming components which combine, or become diluted, upon exposure to water for a sufficient period of time to cause a change in the appearance of the indicia. Also described are printing ink compositions for forming such indicia and methods for forming such articles.Type: ApplicationFiled: December 5, 2003Publication date: June 17, 2004Inventors: Michael P. Filosa, Fariza B. Hasan, Stephen J. Telfer
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Patent number: 6652959Abstract: Disclosed are marking particles comprising a resin, a chelating agent, and a spiropyran material which is of the formula The marking particles are prepared by an emulsion aggregation process.Type: GrantFiled: January 11, 2002Date of Patent: November 25, 2003Assignee: Xerox CorporationInventors: Daniel A. Foucher, Raj D. Patel, Naveen Chopra, Peter M. Kazmaier
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Patent number: 6500245Abstract: A thermoresponsive coloring formulation for use on a reimageable image carrier is provided. An image may be created by exposing the thermoresponsive coloring formulation to heat and erased by exposing it to white light. A screen coated with an uncured stencil coating is placed in registration with the image carrier. The screen and image carrier are exposed to a curing agent which is prevented from passing beyond the image carrier in those areas covered by the image, while the areas of the coated screen that are exposed to the curing agent are hardened by the curing agent. After the stencil coating has been hardened in the desired areas, the screen is removed, and the uncured stencil coating is rinsed away from the screen, leaving a portion of the screen with open pores through which ink can flow.Type: GrantFiled: February 9, 2000Date of Patent: December 31, 2002Inventors: Geoffrey A. McCue, Sebastian V. Kanakkanatt
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Patent number: 6395680Abstract: A composition includes at least two aromatic carboxylic acid compounds selected from the group consisting of aromatic carboxylic acid compounds of formulas (I), (II) and (III) as specified in the specification. A thermosensitive recording material has a support, and a thermosensitive coloring layer formed thereon which contains a leuco dye and a color developer capable of inducing color formation in the leuco dye upon application of heat thereto, with the color developer comprising the aforementioned composition of the aromatic carboxylic acid compounds.Type: GrantFiled: April 12, 2000Date of Patent: May 28, 2002Assignees: Ricoh Company, Ltd., Nicca Chemical Co., Ltd.Inventors: Mitsunobu Morita, Kunio Hayakawa, Ikuo Kameoka, Xiaonan Yang
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Patent number: 6383982Abstract: A color developer composition comprising (A) a color developer containing a polyvalent metal salt of a salicylic acid derivative, and (B) a polyester polyol having in the molecule skeleton at least one carbonate bond or ester bond, and a derivative thereof, an aqueous dispersion and a color developing ink using this color developer composition, and a recording sheet having a layer containing this color developer composition on a base material.Type: GrantFiled: May 2, 2000Date of Patent: May 7, 2002Assignee: Mitsui Chemicals, Inc.Inventors: Jotaro Kida, Yoshimitsu Tanabe, Nobuhiro Takizawa, Masakatsu Nakatsuka
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Patent number: 6365312Abstract: Disclosed are marking particles comprising a first polymer, a second polymer, a chelating agent, and a spiropyran material of the formula wherein n is an integer representing the number of repeat —CH2— units and R is —H or —CH═CH2. The marking particles comprise a core containing the first polymer in which is dispersed the chelating agent and the spiropyran and encapsulated within a shell of the second polymer formulated by an interfacial polymerization.Type: GrantFiled: May 24, 2001Date of Patent: April 2, 2002Assignee: Xerox CorporationInventors: Daniel A. Foucher, Raj D. Patel, Naveen Chopra, Peter M. Kazmaier, James Wojtyk, Erwin Buncel
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Patent number: 6358655Abstract: Disclosed are marking particles comprising a resin, a chelating agent, and a spiropyran material which is of the formula The marking particles are prepared by an emulsion aggregation process.Type: GrantFiled: May 24, 2001Date of Patent: March 19, 2002Assignee: Xerox CorporationInventors: Daniel A. Foucher, Raj D. Patel, Naveen Chopra, Peter M. Kazmaier
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Patent number: 6326332Abstract: A decolorable material contains a color former, a developer, a matrix material, and a decolorant capable of physically or chemically adsorbing the developer, the developer having a molecular weight of 120 to 210. The material is capable of forming a clear image, and the image formed from the material can be decolored well, even when the amount of the decolorant used is small.Type: GrantFiled: March 24, 2000Date of Patent: December 4, 2001Assignee: Kabushiki Kaisha ToshibaInventor: Satoshi Takayama
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Patent number: 6299674Abstract: A fingerprint detecting agent and a fingerprint detecting method using the agent, which can be used to detect latent fingerprints being in a wet condition, the fingerprint detecting agent includes a fixer containing silicone series compound, fluoride series compound, hydrocarbon series compound, animal or vegetable oil, higher fatty acid, or higher alcohol, and an arbitrary mixture thereof; a diluent containing polar soluent; a developer containing achromatic colored powder or chromatic colored powder. Latent fingerprints can be easily detected by spraying the fingerprint detecting agent; particularly, even if the latent fingerprints to be detected are in a wet condition, it is possible to detect them speedily and certainly.Type: GrantFiled: November 12, 1999Date of Patent: October 9, 2001Assignee: Taiho Industries Co., Ltd.Inventors: Yasuo Takamura, Masaharu Shimizu, Takashi Fukuchi, Fujio Ishizawa, Akira Miyagi, Nobuyasu Ochiai, Atsushi Ikeda, Kiyoshi Okamura
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Publication number: 20010025587Abstract: A reversible thermosensitive coloring composition including an electron donating coloring agent and an electron accepting color developer, wherein the composition achieves a colored state when heated at a temperature not lower than a coloring temperature and then cooled at a cooling speed (a), and the composition in the colored state achieves a non-colored state when heated at a temperature lower than the coloring temperature and not lower than an erasing temperature, or when heated at a temperature not lower than the coloring temperature and then cooled relatively slowly compared to the cooling speed (a), and wherein the electron accepting color developer includes a phenolic compound having the following formula (1): 1Type: ApplicationFiled: January 24, 2001Publication date: October 4, 2001Inventors: Masafumi Torii, Hiroaki Matsui, Masaru Shimada
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Patent number: 6203603Abstract: An erasable image forming material includes a color former, a developer, a binder resin, and a polymer decolorizer having an electron donating group capable of physically or chemically adsorbing the developer. This polymer decolorizer is, e.g., a polymer compound having a sugar skeleton, representatively starch. This image forming material can form sharp images and erase images by heat or a solvent to achieve a good erased state.Type: GrantFiled: August 3, 1999Date of Patent: March 20, 2001Assignee: Kabushiki Kaisha ToshibaInventors: Satoshi Takayama, Shigeru Machida, Kenji Sano, Koichi Tsunemi, Shuitsu Sato