Five-ring Members In The Heterocyclic Ring Patents (Class 106/31.49)
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Patent number: 6726755Abstract: Disclosed is a phase change ink composition comprising a phase change ink carrier and a colorant compound of the formula wherein M is an atom or group of atoms capable of bonding to the central cavity of a phthalocyanine molecule, wherein axial ligands optionally can be attached to M. Also disclosed are printing processes using the phase change inks.Type: GrantFiled: February 8, 2002Date of Patent: April 27, 2004Assignee: Xerox CorporationInventors: Donald R. Titterington, Michael B. Meinhardt, Jeffrey H. Banning, James D. Mayo, James M. Duff, Roger E. Gaynor, Harold R. Frame
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Patent number: 6716277Abstract: An ink for an ink jet, the ink being formed by dispersing in a water-based medium an oil-soluble dye that is dissolved in a high boiling point organic solvent, with the ink containing a compound having in a molecule at least one carbon-carbon unsaturated bond that is different from a phenyl group. Further, an ink jet recording method, the method comprising recording on an image receiving material having an image receiving layer including white inorganic pigment particles on a support, the method using an ink for an ink jet, with the ink being formed by dispersing in a water-based medium an oil-soluble dye that is dissolved in a high boiling point organic solvent, and the ink containing a compound having in a molecule at least one carbon-carbon unsaturated bond that is different from a phenyl group.Type: GrantFiled: May 22, 2001Date of Patent: April 6, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Hideaki Naruse, Tadashi Omatsu
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Patent number: 6712890Abstract: A water soluble compound of Formula (1) or a salt thereof: wherein: Y is an electron withdrawing group; Y1 is H, alkyl or aryl, OR or NR2 in which each R independently is H, optionally substituted alkyl or optionally substituted aryl; or Y and Y1 together form a 5- or 6- membered ring; X1 is a group or atom with co-ordinates with M; M is hexa co-ordinate metal; G is a group of Formula (2), (3) or (4); and L1, L2 and L3, each independently represent ligands required to complete hexa-coordinate geometry around metal M; wherein: S is a water solubilizing group; Ar is a benzene or naphthalene group in which X is located ortho to the azo group; X is a group or atom which co-ordinates with M; Z provides atoms or groups which complete an optionally substituted 5- or 6-membered aromatic heterocyclic ring; Ring A is an optionally substituted aromatic ring; Ring B is an optionally substituted 5- or 6-membered aromatic heterocyclic ring; n is 0, 1, 2 or 3; and the * signify the points of attachment of tType: GrantFiled: January 18, 2002Date of Patent: March 30, 2004Assignee: Avecia LimitedInventors: Maria Soteri Hadjisoteriou, Rachel Anne James
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Patent number: 6712892Abstract: An ink jet printing process having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with ink jet recording elements having a support having thereon an image-receiving layer; C) loading the printer with an ink jet ink composition including water, humectant and a metallized, phthalocyanine colorant, the metallized, phthalocyanine colorant having the formula: MPc(SO3X)a(SO2NRR′)b wherein: M represents a metal; Pc represents a phthalocyanine nucleus; each X independently represents hyrdrogen, alkali metal or an organic cation; a is from 0 to 3; b is from 1 to 4; each R independently represents a substituted or unsubstituted alkyl group having from 1 to about 15 carbon atoms, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclic group; and each R′ independently represents R or hydrogen; with the proviso that a+b is an average of from 2 to 4; and with the further proviso that at least about 50 wt.Type: GrantFiled: August 30, 2002Date of Patent: March 30, 2004Assignee: Eastman Kodak CompanyInventors: Andrei Andrievsky, David T. Southby, Samuel Chen, Dale E. Decann
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Patent number: 6713432Abstract: A thermal transfer recording material comprising a support having thereon an image transferring layer containing a coloring material represented by Formula (I), Formula (I): wherein each R11 and R12 is independently a substituted or unsubstituted aliphatic group; R13 is a substituent and n is an integer of 0 to 4, provided that when n is 2 or more, a plurality of R13s are the same or different; R14 is an alkyl group; and each R15 and R16 is independently an alkyl group having 3 to 8 carbon atoms.Type: GrantFiled: January 28, 2002Date of Patent: March 30, 2004Assignee: Konica CorporationInventors: Dai Ikemizu, Mitsuhiro Fukuda, Motoaki Sugino, Norio Miura
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Patent number: 6712891Abstract: An ink jet ink composition including water, humectant and a metallized, phthalocyanine colorant, the metallized, phthalocyanine colorant having the formula: MPc(SO3X)a(SO2NRR′)b wherein: M represents a metal; Pc represents a phthalocyanine nucleus; each X independently represents hydrogen, alkali metal or an organic cation; a is from 0 to 3; b is from 1 to 4; each R independently represents a substituted or unsubstituted alkyl group having from 1 to about 15 carbon atoms, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclic group; and each R′ independently represents R or hydrogen; with the proviso that a+b is an average of from 2 to 4; and with the further proviso that at least about 50 wt. % of the metallized, phthalocyanine colorant is present in the composition as particles.Type: GrantFiled: August 30, 2002Date of Patent: March 30, 2004Assignee: Eastman Kodak CompanyInventors: Andrei Andrievsky, David T. Southby, Samuel Chen, Dale E. Decann
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Publication number: 20040050291Abstract: The ink set of the present invention provides a high ejection stability, gives an image having an excellent hue, light-resistance and waterproofness and improves the image preservability under severe conditions in ink jet recording, in which the ink set comprising a plurality of inks different in hues, wherein the plurality of inks includes a yellow ink containing a coloring agent that is a dye having: a &lgr;max of from 390 nm to 470 nm; an I(&lgr;max+70 nm)/I(&lgr;max) ratio of not greater than 0.4, in which I(&lgr;max) is the absorbance at &lgr;max and I(&lgr;max+70 nm) is the absorbance at (&lgr;max+70 nm); and a forced fading rate constant of not greater than 5.0×10−2 [hour−1], an ink cartridge having the ink set received therein, an ink jet printer comprising the ink cartridge mounted therein and an image recording method.Type: ApplicationFiled: August 22, 2003Publication date: March 18, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Toshiki Taguchi, Yoshiharu Yabuki, Toru Harada, Naotaka Wachi
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Publication number: 20040050290Abstract: An ink jet ink composition of water, humectant and a self-assembling colorant that is capable of spontaneously forming a nanoparticulate dispersion without any prior physical attrition or surface modification, the colorant having the formula: (A)m-Q-(Z)n wherein: Q represents a chromophore; each A independently represents an organic or inorganic group capable of hydrogen bonding or other non-covalent bonding; each Z independently represents an organic or inorganic group capable of electrostatic bonding; and m and n each independently represents an integer from 0 to 10; with the proviso that n+m is at least 1; and with the further proviso that at least about 50 wt. % of the colorant is present in the composition as particles.Type: ApplicationFiled: August 30, 2002Publication date: March 18, 2004Applicant: Eastman Kodak CompanyInventors: Andrei Andrievsky, David T. Southby, Steven Evans, Dale E. Decann
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Publication number: 20040045477Abstract: An ink jet printing process having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with ink jet recording elements having a support having thereon an image-receiving layer; C) loading the printer with an ink jet ink composition of water, humectant and a self-assembling colorant that is capable of spontaneously forming a nanoparticulate dispersion without any prior physical attrition or surface modification, the colorant having the formula: (A)m-Q-(Z)n wherein: Q represents a chromophore; each A independently represents an organic or inorganic group capable of hydrogen bonding or other non-covalent bonding; each Z independently represents an organic or inorganic group capable of electrostatic bonding; and m and n each independently represents an integer from 0 to 10; with the proviso that n+m is at least 1; and with the further proviso that at least about 50 wt.Type: ApplicationFiled: August 30, 2002Publication date: March 11, 2004Applicant: Eastman Kodak CompanyInventors: Andrei Andrievsky, David T. Southby, Steven Evans, Dale E. Decann
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Publication number: 20040045478Abstract: According to the present invention, a novel phthalocyanine compound having a specific structure is provided, and an ink, an inkjet recording ink, an inkjet recording method and a method for improving preservability of a formed image, each using the compound, are also provided.Type: ApplicationFiled: July 31, 2003Publication date: March 11, 2004Inventors: Keiichi Tateishi, Masaki Noro, Yoshiharu Yabuki, Hideaki Naruse, Tadashi Omatsu
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Publication number: 20040040464Abstract: An ink jet ink composition including water, humectant and a metallized, phthalocyanine colorant, the metallized, phthalocyanine colorant having the formula: MPc(SO3X)a(SO2NRR′)b wherein: M represents a metal; Pc represents a phthalocyanine nucleus; each X independently represents hydrogen, alkali metal or an organic cation; a is from 0 to 3; b is from 1 to 4; each R independently represents a substituted or unsubstituted alkyl group having from 1 to about 15 carbon atoms, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclic group; and each R′ independently represents R or hydrogen; with the proviso that a +b is an average of from 2 to 4; and with the further proviso that at least about 50 wt. % of the metallized, phthalocyanine colorant is present in the composition as particles.Type: ApplicationFiled: August 30, 2002Publication date: March 4, 2004Applicant: Eastman Kodak CompanyInventors: Andrei Andrievsky, David T. Southby, Samuel Chen, Dale E. Decann
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Publication number: 20040040465Abstract: An ink jet printing process having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with ink jet recording elements having a support having thereon an image-receiving layer; C) loading the printer with an ink jet ink composition including water, humectant and a metallized, phthalocyanine colorant, the metallized, phthalocyanine colorant having the formula: MPc(SO3X)a(SO2NRR′)b wherein: M represents a metal; Pc represents a phthalocyanine nucleus; each X independently represents hydrogen, alkali metal or an organic cation; a is from 0 to 3; b is from 1 to 4; each R independently represents a substituted or unsubstituted alkyl group having from 1 to about 15 carbon atoms, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclic group; and each R′ independently represents R or hydrogen; with the proviso that a+b is an average of from 2 to 4; and with the further proviso that at least about 50 wt.Type: ApplicationFiled: August 30, 2002Publication date: March 4, 2004Applicant: Eastman Kodak CompanyInventors: Andrei Andrievsky, David T. Southby, Samuel Chen, Dale E. Decann
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Publication number: 20040035322Abstract: The present invention provides an aqueous ink composition comprising a color microparticle dispersion including an oil-soluble dye, a hydrophilic organic solvent and a perfluoroalkylenesulfonic acid or a fluorine type surfactant other than derivatives thereof, and an ink jet method for recording an image by using this aqueous ink composition.Type: ApplicationFiled: August 7, 2003Publication date: February 26, 2004Inventors: Takahiro Ishizuka, Kenji Ikeda
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Publication number: 20040024037Abstract: An antibiotic additive and an ink composition including the antibiotic additive include a compound produced by binding of an antibiotic substance having the following formula (I) to a predetermined additive via a chemical reaction. The ink composition includes a colorant, a solvent and an antibiotic additive produced by binding of an antibiotic substance having the following formula (I) to a predetermined additive via a chemical reaction. The antibiotic additive prevents surface dry, improves storage stability and inhibits propagation and growth of bacteria in an ink and has excellent compatibility with a general dye or pigment.Type: ApplicationFiled: July 2, 2003Publication date: February 5, 2004Applicant: SAMSUNG Electronics Co., Ltd.Inventors: Seung-Min Ryu, Jae-Hwan Kim, Jong In Lee, Dae Hee Lee
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Publication number: 20040020408Abstract: An ink set having a yellow ink containing at least one yellow dye, a magenta ink containing at least one magenta dye, and a cyan ink containing at least one cyan dye, wherein an oxidation potential of the magenta dye and an oxidation potential of the cyan dye are each higher than 0.8 V (vs SCE), and an inkjet recording method using the ink set.Type: ApplicationFiled: February 20, 2003Publication date: February 5, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventor: Yoshiharu Yabuki
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Patent number: 6685768Abstract: A color inkjet ink set for color printing having: (a) a yellow ink having a carrier and a yellow dye; (b) a magenta ink having a carrier and a mixture of a water-soluble, magenta anthrapyridone dye and Reactive Red 23, Reactive Red 24, Reactive Red 31, Reactive Red 120, Reactive Red 180, Reactive Red 241, Acid Red 35, Acid Red 52, Acid Red 249, Acid Red 289, Acid Red 388, Direct Red 227 or CAS No. 153204-88-7; and (c) a cyan ink having a carrier and a cyan dye.Type: GrantFiled: August 1, 2001Date of Patent: February 3, 2004Assignee: Eastman Kodak CompanyInventors: James W. Blease, Elizabeth A. Gallo
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Patent number: 6685770Abstract: An ink for ink-jet comprising: a water-soluble dye; a compound represented by the following formula (1): wherein, R1 and R2 each independently represents a saturated hydrocarbon having from 4 to 10 carbon atoms with the proviso that the total number of carbon atoms contained in the saturated hydrocarbons represented by R1 and R2 is from 8 to 18, and m represents an integer of from 3 to 20; and triethylene glycol monobutyl ether.Type: GrantFiled: January 17, 2002Date of Patent: February 3, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Keiichi Adachi, Junichi Yamanouchi
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Patent number: 6685767Abstract: A recording liquid for ink jet containing a solid fine particle dispersion obtained by dispersing in a medium a compound represented by the following general formula (I) or (II), and an ink jet recording method of recording using the recording liquid for ink jet containing the solid fine particle dispersion obtained by dispersing in a medium a compound represented by the following general formula (I) or (II):Type: GrantFiled: April 3, 2001Date of Patent: February 3, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Masaki Noro, Yoshiharu Yabuki, Makoto Yamada
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Patent number: 6682591Abstract: Disclosed is an ink composition comprising water, a colorant, and a borate ester, said ink containing water in an amount of at least about 5 percent by weight and containing water in an amount of no more than about 50 percent by weight, wherein either (a) the ink also contains an amine compound, or (b) the borate ester is hydrolytically stable.Type: GrantFiled: November 9, 2001Date of Patent: January 27, 2004Assignee: Xerox CorporationInventors: Thomas W. Smith, Jin Wu
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Publication number: 20040011249Abstract: An ink composition and/or a recording medium are made to contain a compound expressed by general formula (1) and a hydrazide compound. An ink composition thereby obtained does not clog and the ink composition and recording medium thus obtained can offer high quality images that hardly cause yellowing of the resulting recording with superior light resistance. Recording and an inkjet recording method pertaining thereto are also provided.Type: ApplicationFiled: June 24, 2003Publication date: January 22, 2004Applicant: SEIKO EPSON CORPORATIONInventors: Yasuhiro Oki, Kazuhiko Kitamura, Tetsuya Aoyama, Kyoichi Oka, Nobuo Uotani, Hiroshi Takahashi, Yuji Ito
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Publication number: 20040011247Abstract: Ink for inkjet recording comprises a dye, water, a water-miscible organic solvent and a precursor of acids, and thereby is rendered resistant to image blur even under a high humidity condition, an ink set including such ink, and an inkjet recording method, in which such ink or such an ink set is used.Type: ApplicationFiled: July 14, 2003Publication date: January 22, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventor: Toshiki Taguchi
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Patent number: 6676735Abstract: An aqueous ink comprising at least a colorant, a water-soluble organic solvent and a compound represented by general formula (I) shown below, wherein said water-soluble organic solvent stays liquid at a temperature of not higher than 40° C., exhibits a water solubility of not lower than 1% by weight at a temperature of 20° C. and a saturated vapor pressure of not higher than 1.7 Pa at a temperature of 20° C. and is contained in an amount of from 5 to 35% by weight: wherein Y represents a nonmetallic atom group required to form a 5- to 7-membered ring with C and N; X represents a hydrogen atom, oxyradical group, hydroxyl group, alkyl group, alkenyl group, alkinyl group, aryl group, acyl group, sulfonyl group, sulfinyl group, alkoxy group, aryloxy group or acyloxy group; and R1 to R4 may be the same or different and each represent a hydrogen atom or alkyl group, with the proviso that any two of R1 to R4 and Y may be connected to each other to form a 5- to 7-membered ring.Type: GrantFiled: June 21, 2001Date of Patent: January 13, 2004Assignee: Seiko Epson CorporationInventors: Yasuhiro Oki, Kazuhiko Kitamura, Tetsuya Aoyama, Nobuo Uotani, Hiroshi Takahashi, Yuji Ito
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Publication number: 20040003755Abstract: The present invention provides an ink composition comprising at least: water; a cyan dye; and an aromatic compound having a carboxyl group and/or a salt thereof. Also disclosed are an inkjet recording method using the ink composition, and recorded matter recorded using the ink composition or by the inkjet recording method.Type: ApplicationFiled: April 21, 2003Publication date: January 8, 2004Applicant: SEIKO EPSON CORPORATIONInventors: Hiroshi Fukumoto, Yasuhiro Oki, Kazuhiko Kitamura, Hiroko Hayashi
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Patent number: 6669767Abstract: An ink jet printing method comprising the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading said printer with an ink jet recording element comprising a support having thereon an image-receiving layer; C) loading said printer with an ink jet ink comprising water, a colorant and a water-soluble ester or amide of a pyrrolidin-2-one carboxylic acid; and D) printing on said image-receiving layer using said ink jet ink composition in response to said digital data signals.Type: GrantFiled: March 8, 2002Date of Patent: December 30, 2003Assignee: Eastman Kodak CompanyInventors: James W. Blease, Steven Evans, Ellen J. Pyszczek
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Patent number: 6669768Abstract: An ink jet ink comprising a colorant, a water-soluble ester or amide of a pyrrolidin-2-one carboxylic acid and water.Type: GrantFiled: March 8, 2002Date of Patent: December 30, 2003Assignee: Eastman Kodak CompanyInventors: James W. Blease, Steven Evans, Ellen J. Pyszczek
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Publication number: 20030226474Abstract: In general, a smear-resistant ink composition according to the present invention comprises: (1) water; (2) at least one glycol selected from the group consisting of diethylene glycol, ethylene glycol, glycerol, and propylene glycol; (3) a pyrrolidone selected from the group consisting of 2-pyrrolidone and 3-pyrrolidone; and (4) at least one colorant that produces a detectable fluorescent color when the ink composition is applied to paper. Preferably, the pyrrolidone is 2-pyrrolidone. In one preferred embodiment, the at least one glycol comprises diethylene glycol and ethylene glycol. In another preferred embodiment, the at least one glycol comprises diethylene glycol, ethylene glycol, and propylene glycol. The composition can comprise other ingredients, such as a basic color stabilizer, a resin, a resin modifier that is a carbonate salt, a biocide, and a nonionic surfactant. The colorants can be formulated to produce a pink, yellow, blue, green, purple, or orange color; other colors are possible.Type: ApplicationFiled: June 6, 2002Publication date: December 11, 2003Applicant: Avery Dennison CorporationInventors: Thomas Mammen, Robert Valadez
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Publication number: 20030221586Abstract: An aggregation stabilizer is further added to an ink composition for inkjet recording which contains a colorant, a humectant, water, and a water-soluble substance that is condensation-polymerized in the absence of the water. With this aggregation stabilizer, a hardly-soluble or insoluble component formed by the colorant and the water-soluble substance is modified so as to be readily dissolved in water, whereby generation of an aggregate in the ink is prevented.Type: ApplicationFiled: May 19, 2003Publication date: December 4, 2003Inventors: Hidekazu Arase, Mamoru Soga
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Publication number: 20030217671Abstract: An ink comprising an aqueous medium and at least one dye represented by the formula (I) as defined herein, which is dissolved or dispersed in the aqueous medium, wherein the ink permeates into a recording medium having an image-receiving layer to a depth of 5 to 30 &mgr;m.Type: ApplicationFiled: April 1, 2003Publication date: November 27, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventor: Takashi Ozawa
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Patent number: 6652636Abstract: The novel phthalocyanine cyan dye of the formula (I) in which M represents an ion of a metal selected from the group consisting of Cu, Fe, Co, Mg, Mn, Sn and Ni, X represents a linear compound having 6-10 atoms in length containing C, O, and/or N, R1 represents pyridine, imidazole, sulfide, thiol, phenol, benzene, benzaldehyde, pyrimidine, pyrizine, triazine, thiazole, oxazole, pyridone, pyrone, pyrole, thiophene, furan, pyran, dioxane, and morpholine, and derivatives thereof, R2 represents an atom or chemical group that imparts water solubility to the phthalocyanine cyan dye, and y and z each independently represent an integer of 1 to 3 satisfying the relation of 2≦y+z≦4. Ink formulations containing at least one dye of the formula (I) and methods for ink jet printing with inks containing the phthalocyanine cyan dyes of formula (I).Type: GrantFiled: June 29, 2001Date of Patent: November 25, 2003Assignee: Hewlett-Packard Development Company, L.P.Inventors: Larrie A Deardurff, Hiang P Lauw
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Patent number: 6648951Abstract: A waterfast, environmentally friendly ink-jet ink, is disclosed comprising from 1% to 90% by weight of a first humectant selected from the group consisting of glycerol, propanediol, and combinations thereof; from 1% to 25% by weight of a second humectant selected from the group consisting of ethylene glycol, diethylene glycol, propylene glycol, and combinations thereof; from 1% to 20% by weight of a drying agent selected from the group consisting of 1,2-hexanediol, 1,2-pentanediol, and combinations thereof; from 0% to 20% by weight of 2-pyrrolidone; from 0.05% to 10.0% by weight of a waterfastness control dye selected from the group consisting of azo-containing dyes and phthalocyanine-containing dyes; and at least one additional dye present at from about 1.0% to 10.0% by weight. If the waterfastness control dye is an azo-containing dye, such dyes can include Direct Red 227, Direct Red 254, Direct Yellow 86, and Acid Orange 7.Type: GrantFiled: September 4, 2001Date of Patent: November 18, 2003Assignee: Hewlett-Packard Development Company, L.P.Inventors: Xiaohe Chen, David Tyvoll, George M. Sarkisian
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Patent number: 6645280Abstract: The present invention provides a jet ink composition suitable for printing watermarks on paper substrates. The jet ink composition comprises a solvent and a translucentizing agent. An example of a translucentizing agent is sucrose acetate isobutyrate. The present invention further provides a method of ink jet printing watermark on an object comprising projecting a stream of droplets of the ink composition and controlling the direction of the stream so that the droplets form the watermark on the object. The method of the present invention has the advantage that it provides high speed watermarking capability. The method provides a further advantage that it is economical in changing the design of watermarks. The method is versatile and allows changes in the design of watermarks to be incorporated readily.Type: GrantFiled: May 26, 2000Date of Patent: November 11, 2003Assignee: Videojet Technologies Inc.Inventors: Linfang Zhu, Christopher D. Peterson
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Patent number: 6645281Abstract: An ink-jet ink which includes a coloring composition containing oil-soluble dye aggregates is provided. The oil-soluble dye which forms aggregates is preferred a compound represented in the following general formula (1): D-(Y)n General Formula (1) wherein, D represents a dye portion having a chromophore; Y represents a polar group which is connected to D directly or via a bivalent connecting group and which generates interaction between the compounds represented in said general formula (1); and n represents any integer of 2 to 10.Type: GrantFiled: March 30, 2001Date of Patent: November 11, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshiharu Yabuki, Masaki Noro, Keiichi Tateishi
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Patent number: 6638624Abstract: A filter for a display device, which comprises a dipyrazolylsquarylium dye represented by formula: wherein A and B each independently represent a substituted or unsubstituted pyrazolyl group. The filter is excellent in resistance to heat and light and gives no adverse influences on luminescence of the three primary colors, red, green and blue.Type: GrantFiled: May 22, 2001Date of Patent: October 28, 2003Assignee: Mitsubishi Chemical CorporationInventor: Tetsuo Ozawa
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Patent number: 6638350Abstract: The invention provides an ink composition having improved printing performance. The ink composition includes an ink vehicle, from about 0.1 to about 10% by weight self-dispersed ink pigment, from about 0.1 to about 10% by weight dye, a humectant, and a penetrant, wherein the weight ratio of ink pigment to dye ranges from greater than about 0.75:1 to less than about 2.5:1. Such ink compositions exhibit substantially improved permanence, decreased drying time, and high optical density compared to ink compositions containing only ink pigment or dye.Type: GrantFiled: April 11, 2002Date of Patent: October 28, 2003Assignee: Lexmark International, Inc.Inventors: Susan Hardin Butler, Jing X. Sun
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Publication number: 20030183122Abstract: A thermal transfer ink is provided, which includes:Type: ApplicationFiled: November 5, 2002Publication date: October 2, 2003Applicant: MITSUBISHI CHEMICAL CORPORATIONInventors: Mio Ishida, Yukichi Murata
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Publication number: 20030172843Abstract: An ink jet ink comprising a colorant, a water-soluble ester or amide of a pyrrolidin-2-one carboxylic acid and water.Type: ApplicationFiled: March 8, 2002Publication date: September 18, 2003Applicant: Eastman Kodak CompanyInventors: James W. Blease, Steven Evans, Ellen J. Pyszczek
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Publication number: 20030172841Abstract: Disclosed is a phase change ink composition comprising a phase change ink carrier and a colorant compound of the formula 1Type: ApplicationFiled: February 8, 2002Publication date: September 18, 2003Applicant: Xerox CorporationInventors: Donald R. Titterington, Michael B. Meinhardt, Jeffrey H. Banning, James D. Mayo, James M. Duff, Roger E. Gaynor, Harold R. Frame
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Publication number: 20030172842Abstract: An ink jet printing method comprising the steps of:Type: ApplicationFiled: March 8, 2002Publication date: September 18, 2003Applicant: Eastman Kodak CompanyInventors: James W. Blease, Steven Evans, Ellen J. Pyszczek
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Publication number: 20030167966Abstract: Magenta chromophore dyes which are stabilized by adding steric hindering groups to protect the imino carbons; nonlimiting examples of the steric hindering groups being phenyl, methyl, ethyl, isopropyl, fluoride, chloride, bromide and iodide groups.Type: ApplicationFiled: January 25, 2002Publication date: September 11, 2003Inventor: Larrie A. Deardurff
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Patent number: 6607589Abstract: An aqueous inkjet ink and an ink set using such ink, the ink comprising as colorant, a Copper Phthalocyanine (CuPc) dye compound having formula II: wherein (x,y,z)=4.Type: GrantFiled: April 17, 2001Date of Patent: August 19, 2003Assignee: Hewlett-Packard Development Company, L.P.Inventors: Raymond J Adamic, Richard A Sader, Gary W Byers, Paul J. Bruinsma, Howard A. Doumaux, Kai Kong Iu, Richard Anderson, Hiang P Lauw
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Publication number: 20030131756Abstract: Disclosed is a process which comprises (a) preparing a first solution comprising water and an anionic dye; (b) preparing a second solution comprising water and a polyquaternary amine compound; (c) admixing the first solution and the second solution, thereby causing formation of a complex of the anionic dye and the polyquaternary amine compound and precipitation of the complex from the solution; and (d) isolating the complex thus formed.Type: ApplicationFiled: November 7, 2001Publication date: July 17, 2003Applicant: Xerox CorporationInventors: Thomas W. Smith, Richard L. Colt, Kathleen M. McGrane
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Publication number: 20030127020Abstract: Disclosed is an ink composition comprising water, a colorant, and a borate ester, said ink containing water in an amount of at least about 5 percent by weight and containing water in an amount of no more than about 50 percent by weight, wherein either (a) the ink also contains an amine compound, or (b) the borate ester is hydrolytically stable.Type: ApplicationFiled: November 9, 2001Publication date: July 10, 2003Applicant: Xerox CorporationInventors: Thomas W. Smith, Jin Wu
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Publication number: 20030127018Abstract: A cyan dye set and ink-jet ink composition with high water-fastness. The cyan dye set is suitable for use in ink-jet printing and includes Acid Blue 90 dye and at least one copper phthalocyanine type blue dye. The cyan dye set has good water-fastness and exhibits improved printing quality when applied in ink-jet printing.Type: ApplicationFiled: December 17, 2002Publication date: July 10, 2003Applicant: BENO CORPORATIONInventors: Yu-Chang Shen, In-Shan Sir, Chia-Hsin Chien
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Publication number: 20030127019Abstract: An aqueous inkjet ink and an inkset using such ink, the ink comprising as colorant, a Copper Phthalocyanine (CuPc) dye compound having formula II: 1Type: ApplicationFiled: April 17, 2001Publication date: July 10, 2003Inventors: Raymond J. Adamic, Richard A. Sader, Gary W. Byers, Paul J. Bruinsma, Howard A. Doumaux, Kai Kong Iu, Richard Anderson, Hiang P. Lauw
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Publication number: 20030127017Abstract: A dye for ink-jet printing on both hydrophilic and hydrophobic papers. The dye includes a chromophore ionically coupled to a counterion. One of the chromophore and the counterion includes a hydrophilic moiety. The other includes a hydrophobic moiety.Type: ApplicationFiled: October 31, 2001Publication date: July 10, 2003Inventors: David M. Schut, Christian Schmid
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Patent number: 6589325Abstract: An object of the present invention is to provide a novel phthalocyanine compound or the salt thereof as a black colorant that has a hue suitable for ink-jet recording and can provide a recorded material with strong light fastness and water fastness, an ink composition containing the compound, an ink-jet recording method using the ink composition, a tank containing the ink composition, an ink-jet printer set with the tank, and a colored product colored by the colorant. The novel phthalocyanine compound or the salt thereof can be easily obtained by reacting an aminophthalocyanine with (meth)acrylic acid.Type: GrantFiled: October 9, 2001Date of Patent: July 8, 2003Assignee: Nippon Kayaku Kabushiki KaishaInventors: Yoshinori Katoh, Hirokazu Kitayama, Yasuo Shirasaki
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Patent number: 6583234Abstract: Disclosed is a process which comprises (a) reacting allyl bromide with diethyl amine in a molar ratio of at least about 1 mole of allyl bromide per about 1.15 moles of diethyl amine and in a molar ratio of no more than about 1 mole of allyl bromide per about 2 moles of diethyl amine, thereby generating allyl diethyl amine in a monomer reaction mixture; (b) subsequently filtering the monomer reaction mixture to remove impurities; (c) subsequently reacting the allyl diethyl amine with allyl bromide, thereby generating solid diallyl diethyl ammonium bromide; (d) subsequently isolating the solid diallyl diethyl ammonium bromide; (e) subsequently dissolving the diallyl diethyl ammonium bromide in a solvent and adding thereto a polymerization initiator to form a polymerization reaction mixture; (f) subsequently heating the polymerization reaction mixture in a vessel equipped with a reflux condenser to a temperature of from about 90 to about 100° C.Type: GrantFiled: July 26, 2001Date of Patent: June 24, 2003Assignee: Xerox CorporationInventors: Sheau V. Kao, Daniel A. Foucher, Mohammad J. Hossain, Christine E. Bedford, George Liebermann
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Patent number: 6582501Abstract: An ink composition for ink-jet printers is provided which includes a chromophore, a solvent, a co-solvent, a humectant, a surfactant, a viscosity adjuster and an additive. The additive is a nitrogen-containing heterocyclic compound. This nitrogen-containing heterocyclic compound has the hydroxy groups which improve miscibility with water, thereby preventing clogging of nozzles during use. The present invention increases the affinity for dye used as a chromophore and for the hydroxy groups of paper after discharging of ink, which allows the chromophore to easily fix on the paper, thus enhancing smearfastness of the ink composition after printing.Type: GrantFiled: February 26, 2001Date of Patent: June 24, 2003Assignee: Samsung Electronics Co., Ltd.Inventors: Seung-min Ryu, Seung-soon Jang, Jun-hoe Cha
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Publication number: 20030110980Abstract: An ink set for ink-jet printing, having at least one ink of the ink set comprising a light dye load and a dark dye load with both the light dye load and the dark dye load being one color. The one color is selected from magenta, cyan, yellow and black; and the light dye load being at least one of air fade resistant, light fade resistant and humid color migration resistant. The invention also relates to a method of inkjet printing with such a method.Type: ApplicationFiled: December 3, 2002Publication date: June 19, 2003Inventors: Matthew Thornberry, Eric L. Burch, John L. Stoffel
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Publication number: 20030097959Abstract: An ink composition for inkjet recording comprising: an azo dye having an aromatic nitrogen-containing 6-membered heterocycle as a coupling component; a compound represented by the following formula (I); and an aqueous medium wherein the azo dye is dissolved or dispersed in the aqueous medium: 1Type: ApplicationFiled: April 11, 2002Publication date: May 29, 2003Inventors: Tadashi Omatsu, Masaki Noro, Toshiki Fujiwara