Organic Oxygen Compound Containing Patents (Class 106/31.58)
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Publication number: 20030019395Abstract: An ink jet inkset is provided for image printers, in particular large format printers, for printing on both porous, non-porous, and hybrid glossy media. The inket contains a black ink and one or more color inks, said color ink composition comprises at least one water-soluble dye and a vehicle comprising at least one co-solvent and at least two different surfactants, a non-ionic surfactant and a fluoro-surfactant. The total surfactant concentration ranges from about 0.05 to 6 wt % of the ink composition. The non-ionic surfactant is present in a range of about 0.05 to 3 wt % of the ink composition, while the fluoro-surfactant is present in a range of about 0.001 to 3 wt % of the ink composition. The ink formulation that works well with porous, non-porous, and hybrid glossy media and provides substantially instant ink drying and light fastness of the ink. Further, the ink formulation evidences excellent image quality. The ink can also pass harsh pen material compatibility tests.Type: ApplicationFiled: March 21, 2001Publication date: January 30, 2003Inventors: Zeying Ma, Kai Kong lu, Rodney D. Stramel, Shunqiong Yue
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Patent number: 6511535Abstract: The invention relates to a method for printing fibrous textile materials using the ink-jet printing technique, wherein the fibrous materials are printed with an aqueous ink that comprises at least one acid dye according to claim 1 and that has a viscosity of from 1 to 40 mPa·s.Type: GrantFiled: January 3, 2001Date of Patent: January 28, 2003Assignee: Ciba Specialty Chemicals CorporationInventors: Roger Lacroix, Peter Scheibli, Mickael Mheidle
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Publication number: 20030015119Abstract: Inkjet printer inks wherein kogation reduction is accomplished by the addition of phosphonate additives to the inks. In a preferred embodiment, the following are utilized: sodium salt of amino tri(methylene-phosphonic acid), 1-Hydroxyethylidene-1,1,-diphosphonic acid, diethylene triaminepenta(methylenephosonic acid); and potassium salt form of hexamethylenediamine tetra(methylene phosphonic acid). Although in the examples disclosed herein, the salt form of the phosphonic acids were used, the acid form of the phosphonic acid can also be used provided the pH of the final inks are adjusted to desirable levels. Use of the above listed additives essentially eliminate kogation for the life of the pens, such as those used in Hewlett-Packard Company's thermal inkjet printers.Type: ApplicationFiled: February 12, 2001Publication date: January 23, 2003Inventors: Shirley Lee, Joe R. Pietrzyk, Susan L. Pietrzyk
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Publication number: 20030015120Abstract: Color ink sets for use in printer systems are provided and formulated to provide improved plain paper and special media performance while maintaining good printing characteristics. The inks and ink sets of the present invention exhibit excellent color performance and lightfastness across a range of media, robust K/Y bleed resistance on plain paper at fast print speeds, as well as excellent printability and reliability.Type: ApplicationFiled: May 4, 2001Publication date: January 23, 2003Inventors: Raymond J. Adamic, Mary E. Austin, Hiang P. Lauw, Dennis P. Parazak, Zia Rehman
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Patent number: 6508870Abstract: The ink allows to prevent spout of the ink from the nib, and has a good penetrating and drying ability of writing to a material to be written. And the ink comprises a penetrant and a coloring agent, a humectant and water, wherein viscosity at 20° C. is from 1.2 to 10 mPa·s and surface tension is from 35 to 55 dyne/cm. The penetrant can be glycol ether represented by the following formula R1—(O—R2)x—O—R3 wherein, R1 is an alkyl group having 2 to 4 carbon atoms or a phenyl group, R2 is “—CH2—CH2—” or “—CH2CH(CH3)—”, R3 is H or an alkyl group having 1 to 6 carbon atoms, and X is an integer of 2 or 3.Type: GrantFiled: August 21, 2000Date of Patent: January 21, 2003Assignee: Kabushiki Kaisha PilotInventors: Tadashi Komatsuzawa, Hiroshi Kiyomoto
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Publication number: 20030010253Abstract: The ink composition of the present invention contains a coloring agent, water, a water-soluble organic solvent which is a liquid at least at temperatures of 40° C. or less, and which has a solubility of 1 wt % or greater with respect to water at a temperature of 20° C., and a saturation vapor pressure of 1.7 Pa or less at a temperature of 20° C. (with said organic solvent being contained in the ink composition at the rate of 10 to 35 wt %), and one or more amidine type compounds. As a result, the present invention provides an ink composition, a recording medium, recorded matter and an ink jet recording method that make it possible to obtain images with a high image quality which are superior in terms of the gas resistance of the recorded matter.Type: ApplicationFiled: March 21, 2002Publication date: January 16, 2003Applicant: SEIKO EPSON CORPORATIONInventors: Yasuhiro Oki, Kazuhiko Kitamura, Tetsuya Aoyama, Kyoichi Oka, Nobuo Uotani, Hiroshi Takahashi, Yuji Ito
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Publication number: 20030010251Abstract: An ink composition including a near infrared absorbing dye that converts absorbed near infrared radiation into heat without fluorescing significantly and a substantially non-aqueous, organic solvent system. The dye is a tetrakis (dialkylaminophenyl) aminium dye coupled with one anion, a cyanine or a squarylium. The non-aqueous, organic solvent system includes an alcohol, for example, a diacetone alcohol, 1-methoxy-2-propanol, or combinations thereof The method of treating thermoplastic according to the invention includes (a) providing a near infrared absorbing dye that converts absorbed NIR radiation into heat without fluorescing significantly; (b) dissolving the dye into a substantially non-aqueous, organic solvent to form an ink composition; and (c) contacting a thermoplastic part with the ink composition. The contacting step may include painting, dry-burnishing, dip-coating, spraying, printing, and particularly ink jet printing.Type: ApplicationFiled: June 26, 2001Publication date: January 16, 2003Inventors: Nicole M. Woosman, Susan R. Loehr, Robert A. Sallavanti
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Publication number: 20030010252Abstract: An ink composition including a colorant; and a solvent, wherein a zeta potential 2 between the colorant and a material selected from the group consisting of silicon, glass, silicon oxide, titanium oxide, chromium oxide, titanium nitride, silicon nitride, zirconium and polyimide is from 0 to −50 mV at a pH of from 6.5 to 11.5. A corrosion inhibitor is preferably added to the ink composition to adjust the zeta potential 2. An ink cartridge containing the ink which optionally includes a recording head discharging the ink to form an image on a recording material, wherein the zeta potential 2 between the colorant in the ink and a material of the recording head contacting the ink is from 0 to −50 mV at a pH of from 6.5 to 11.5. An inkjet recording apparatus including the ink cartridge and a carriage carrying the ink cartridge.Type: ApplicationFiled: January 22, 2002Publication date: January 16, 2003Inventors: Hitoshi Arita, Nobutaka Osada, Kiyofumi Nagai, Kakuji Murakami, Tomoko Maeda, Akihiko Gotoh
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Patent number: 6506239Abstract: An ink set capable of reducing the influence of recording media on image quality and stably forming high-quality images is provided. The ink set includes a liquid composition containing at least one salt selected from the group consisting of (M1)2SO4, CH3COO(M1), Ph—COO(M1), (M1)NO3, (M1)Cl, (M1)Br, (M1)I, (M1)2SO3 and (M1)2CO3, wherein M1 denotes an alkali metal, ammonium or organic ammonium, and Ph denotes a phenyl group, and at least one ink selected from the group consisting of yellow, magenta, cyan, black, red, blue and green inks.Type: GrantFiled: September 14, 2000Date of Patent: January 14, 2003Assignee: Canon Kabushiki KaishaInventors: Koichi Osumi, Shinya Mishina
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Publication number: 20030005853Abstract: A fragrant ink-jet ink including: a fragrant agent, a surfactant, wherein a boiling point of the surfactant is above 78° C. and a Hydrophilic Lipophilic Balance (HLB) of the surfactant is in a range of about 5 to 16, a colorant, and a solvent. The fragrant agent can be a natural fragrant agent, a synthetic fragrant agent or a mixture thereof. The amount of the fragrant agent is about 0.01 wt % to 10.0 wt %.Type: ApplicationFiled: May 30, 2002Publication date: January 9, 2003Inventors: Yi-Jing Leu, In-Shan Sir, Yu-Chang Shen, Chia-Hsin Chien
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Publication number: 20030005854Abstract: In a ball pen which is formed to have an ink-consumption value per unit area of 0.64 to 1.6 mg/cm2, the water content is adjusted in the range from 30.0 to 80.0 wt %, the content of a volatilization-inhibiting substance in the range from 0.1 to 10.0 wt % and the content of a hardly-volatile water-soluble liquid medium in the range from 1.0 to 40.0 wt % in the ink for a ball pen in order to achieve both the quick-drying property of the ink transferred onto the paper surface and the non-drying property of the point of the pen-tip and further a good writing feeling.Type: ApplicationFiled: June 14, 2002Publication date: January 9, 2003Inventors: Masaru Miyamoto, Shigeru Miyazaki, Youji Takeuchi
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Patent number: 6503307Abstract: An ink set is provided which produces a printed article having excellent water resistance and excellent abrasion resistance. The ink set comprises a first liquid composition containing a first water-soluble compound having in the molecule an ethylenically unsaturated double bond having an electron-attractive substituent on the &agr;-position, and a second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence, at least one of the first liquid composition and the second liquid composition further containing a coloring material.Type: GrantFiled: April 26, 2000Date of Patent: January 7, 2003Assignee: Canon Kabushiki KaishaInventor: Hiromichi Noguchi
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Patent number: 6500245Abstract: A thermoresponsive coloring formulation for use on a reimageable image carrier is provided. An image may be created by exposing the thermoresponsive coloring formulation to heat and erased by exposing it to white light. A screen coated with an uncured stencil coating is placed in registration with the image carrier. The screen and image carrier are exposed to a curing agent which is prevented from passing beyond the image carrier in those areas covered by the image, while the areas of the coated screen that are exposed to the curing agent are hardened by the curing agent. After the stencil coating has been hardened in the desired areas, the screen is removed, and the uncured stencil coating is rinsed away from the screen, leaving a portion of the screen with open pores through which ink can flow.Type: GrantFiled: February 9, 2000Date of Patent: December 31, 2002Inventors: Geoffrey A. McCue, Sebastian V. Kanakkanatt
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Patent number: 6500248Abstract: An ink composition for ink jet recording is provided which comprises at least a pigment, a 1,2-alkanediol, glycerin, a polyhydric alcohol derivative and/or an acetylene glycol surfactant, a water-soluble organic solvent, and water, the pigment having been surface treated to render the pigment dispersible and/or dissolvable in water without any dispersant, the 1,2-alkanediol being at least one member selected from the group consisting of 1,2-butanediol, 1,2-pentanediol, and 1,2-hexanediol, the ink composition having a surface tension of not more than 40 mNm−1 at 20° C. This ink composition enables ink jet recording which can provide good print quality and can realize continuous printing.Type: GrantFiled: June 14, 2000Date of Patent: December 31, 2002Assignee: Seiko Epson CorporationInventor: Hiroko Hayashi
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Patent number: 6500246Abstract: The present invention provides an ink-jet ink composition which includes (a) at least one water-soluble dye; (b) at least one low vapor-pressure solvent; (c) a nonionic non-amphoteric surfactant; (d) a fluoric surfactant; and (e) balanced water. The ink-jet ink composition of the present invention is suitable for thermal ink-jet printers.Type: GrantFiled: January 5, 2001Date of Patent: December 31, 2002Assignee: Everlight USA, Inc.Inventors: Hong-Chang Huang, Jen-Fang Lin
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Publication number: 20020195586Abstract: Ink compositions described are suitable for ink jet printing (ink jet inks) and are highly effective for simultaneously imparting visible and fluorescent images. In the preferred forms, both a dark, visible image and a complementary fluorescent image will be visually discernable as well as machine readable to enable efficient hand and automated processing or handling of the objects printed. These results are achieved by ink formulations that moderate the typically occurring phenomenon of quenching while possessing the physical properties necessary for an ink jet ink.Type: ApplicationFiled: May 9, 2002Publication date: December 26, 2002Inventors: Judith D. Auslander, John Griffiths, John Mama
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Patent number: 6494942Abstract: An aqueous ink jet ink is disclosed which comprises an effective amount of an azomethine dye having at least one water solubilizing functional group covalently attached thereto. The water solubilizing functional group can either be directly attached to the azomethine dye and/or can be attached to the azomethine dye through an electrophilic coupling moiety. If an organic spacer group is used to separate the water solubilizing functional group from azomethine dye or the electrophilic coupling moiety, then straight and branched chained alkyl groups having from about 1 to 10 carbon atoms is preferred. Preferred azomethine dyes can be pyrazolone azomethines, pyrazolotriazole azomethines, and combinations thereof. Additionally, an aqueous ink jet ink is disclosed comprising an effective amount of a dye-based colorant and an essentially water soluble spiroindane additive for improving light fastness and stability of the dye-based colorant.Type: GrantFiled: September 15, 2000Date of Patent: December 17, 2002Inventors: Larrie A Deardurff, James David White, Christopher Lincoln
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Publication number: 20020185037Abstract: Ink-jet ink compositions are described comprising at least one organo-phosphonic acid. The ink-jet ink compositions reduce adhesive swell, scale formation and corrosion, and as such lead to improved interactions with the structural materials of ink-jet printer pens.Type: ApplicationFiled: May 1, 2001Publication date: December 12, 2002Inventors: Shirley Lee, John Dangelewicz
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Patent number: 6491747Abstract: A water based ink composition for a writing instrument containing at least one selected from the group consisting of alkylene oxide adducts of polyglycerin, alkylene oxide adducts of glycerin and alkylene oxide adducts of trimethylolpropane and further containing a colorant, a perfume and water, which is less liable to cause feathering of the lines and in which a perfume is dispersed and retained in an aqueous medium in a stable state and the fragrance lasts long.Type: GrantFiled: February 28, 2001Date of Patent: December 10, 2002Assignee: Mitsubishi Pencil Kabushiki KaishaInventors: Masaru Miyamoto, Tadashi Kamagata
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Publication number: 20020174801Abstract: The present invention provides an ink for ink-jet printer containing a fluorescent compound which emits fluorescence by ultraviolet irradiation, a surfactant, and water, wherein the ink can satisfy all points of quick-drying property of the ink after printing, print quality, and change in the hue, lightness, and chroma of the print part by irradiation of light source.Type: ApplicationFiled: February 6, 2002Publication date: November 28, 2002Applicant: Seiko Epson CorporationInventors: Yoshifumi Hano, Chiyoshige Nakazawa
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Patent number: 6485551Abstract: A method of printing a polyamide structure using two or more of water-soluble dye with an inorganicity/organicity value of 1 to 7 selected so that the ones with the largest and smallest inorganicity/organicity values show a difference of 2 or below between their two such values, to allow the polyamide structure to be printed with no uneven color, high color reproducibility and excellent ink bleeding prevention.Type: GrantFiled: August 22, 2000Date of Patent: November 26, 2002Assignees: Seiren Co., Ltd., Nippon Kayaku Kabushiki KaishaInventors: Takahiro Kohsaka, Eiichi Ogawa
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Publication number: 20020162481Abstract: Ink-jet ink compositions are described comprising a mixture of succinic acid and at least one second organic acid. The ink-jet ink compositions alleviate color bleed, and lead to reliable pen performance when incorporated in a pen architecture.Type: ApplicationFiled: March 5, 2001Publication date: November 7, 2002Inventors: Zia Rehman, Dennis P. Parazak, Raymond J. Adamic
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Patent number: 6475271Abstract: A multicolor ink jet printing process employs an ink jet ink composition comprising water, a colorant of pigment, dye, or mixtures thereof, and a low boiling point additive to produce high quality multicolor ink jet images with minimal intercolor bleed and lines with sharp edges as characterized by a relatively low mid frequency line edge noise (MFLEN) number. The additive is an alcohol or thiol having a boiling point less than or equal to about 115° C. The aforementioned ink jet ink composition can further include an optional additive of alcohol or thiol with a boiling point less than or equal to about 135° C. if necessary. The desired additive increases the ink's drying rate with fast evaporation and an accelerated penetration into a print substrate (e.g. paper) upon printing. As a result, little or minimum residual ink (e.g. carbon black ink) comprising the aforementioned additive is available on the surface of the print substrate to intermix with a previously or subsequently printed ink (e.g.Type: GrantFiled: December 28, 2000Date of Patent: November 5, 2002Assignee: Xerox CorporationInventor: John Wei-Ping Lin
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Patent number: 6474804Abstract: An ink comprise a dye, a silicon-containing surfactant, an ethylene oxide adduct of acetylene glycol and a liquid medium, wherein a weight ratio of the silicon-containing surfactant to the ethylene oxide adduct of acetylene glycol is not lower than {fraction (1/5000)}, but lower than {fraction (1/20)}. An ink-jet recording process include the step of ejecting the ink by an ink-jet system. An ink set include in combination a first dye having a certain color tone, and a second dye ink having a color tone different from that of the first dye ink, wherein at least one of the first and second dye inks is the above ink. An ink set include dye inks of yellow, magenta and cyan, wherein the dye inks include an ethylene oxide adduct of acetylene glycol respectively, and the dye inks of magenta and cyan further have a silicon-containing surfactant.Type: GrantFiled: June 25, 2001Date of Patent: November 5, 2002Assignee: Canon Kabushiki KaishaInventors: Koichi Osumi, Shinya Mishina, Hisashi Teraoka, Yuko Takada
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Publication number: 20020157567Abstract: An ink jet ink composition comprising water, a humectant, a polyvalent transition metal complex of an 8-heterocyclylazo-5-hydroxy-quinoline and an anti-kogation material comprising an alkali metal salt of a monobasic organic or inorganic acid. Examples of anti-kogation materials useful in the invention include sodium hexanoate, sodium sulfate, sodium propionate, sodium benzoate, sodium p-toluenesulfonate, sodium acetate, sodium bromide, sodium nitrate, potassium nitrate, lithium nitrate, lithium acetate, tetramethylammonium acetate and tetrabutylammonium bromide.Type: ApplicationFiled: February 27, 2001Publication date: October 31, 2002Applicant: Eastman Kodak CompanyInventors: David Erdtmann, Edgardo Lopez, Richard C. Van Hanehem, Steven Evans
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Publication number: 20020157568Abstract: An ink for ink-jet comprising: a water-soluble dye; a compound represented by the following formula (1): 1Type: ApplicationFiled: January 17, 2002Publication date: October 31, 2002Inventors: Keiichi Adachi, Junichi Yamanouchi
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Publication number: 20020157566Abstract: An ink jet printing method, comprising the steps of:Type: ApplicationFiled: February 27, 2001Publication date: October 31, 2002Applicant: Eastman Kodak CompanyInventors: David Erdtmann, Steven Evans, Edgardo Lopez, Richard C. Van Hanehem
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Ink composition for a meltable ink and a method of printing a substrate with such an ink composition
Patent number: 6471758Abstract: An ink composition for a meltable ink usable in a printing device in which ink drops are ejected from ink ducts, which comprises agents which reversibly cross-link the ink, the said agents containing a gelling agent. When an ink drop which has been transferred to a substrate passes over into a gel during the cooling process, the consequence is that the viscosity of the melted ink drop increases greatly so that the drops become relatively immobile. In this way the ink drops are prevented from uncontrollably flowing into the paper. As a result, inks of this kind are suitable for use on both porous and smooth substrates. In addition, these inks have been found suitable for use in a printing device in which printed substrates are subjected to thermal after-treatment.Type: GrantFiled: July 7, 2000Date of Patent: October 29, 2002Assignee: Oce Technologies B.V.Inventors: Erik Kelderman, Marcus Petrus Leonardus Huinck, Nicolina Margriet Kortenhoeven, Frederik Leonardus Everardus Marie Suilen, Guido Gerardus Willems, Albin Bernhard Werner Haas -
Publication number: 20020155224Abstract: A dye-based, thermal ink jet printer ink is formulated by combining a water miscible organic solvent, water, and a dye, and blending the water miscible organic solvent, the water, and the dye together. The ink has the ability to form printed images on a variety of textile media and can be used to achieve acceptable results on both coated silk and coated cotton substrates. Also included is a method of making the ink jet ink and a method of applying the ink to a recording medium.Type: ApplicationFiled: January 25, 2002Publication date: October 24, 2002Applicant: MacDermid Colorspan, IncorporatedInventors: Peter D. Schmidt, Uyen Q. Thai
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Patent number: 6468338Abstract: An ink jet ink composition comprising water, a humectant and a water-soluble pyrazoleazoindole dye.Type: GrantFiled: October 12, 2000Date of Patent: October 22, 2002Assignee: Eastman Kodak CompanyInventors: Steven Evans, Helmut Weber, Ellen M. Pyszczek, Ann L. Carroll-Lee
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Patent number: 6468337Abstract: Disclosed is a set of inks for printing multicolor images in an ink jet printer, said ink set comprising (1) a first ink having a first color and comprising water and an anionic dye; and (2) a second ink having a second color different from the first color and comprising (a) water, and (b) pigment particles having chemically bonded to the surfaces thereof moieties containing amine or quaternary amine functional groups, wherein the anionic dye in the first ink is capable of being immobilized on a printing substrate by interaction with the pigment particles in the second ink, thereby enabling reduced intercolor bleed.Type: GrantFiled: July 19, 2000Date of Patent: October 22, 2002Assignee: Xerox CorporationInventors: Kurt B. Gundlach, Richard L. Colt, Maura A. Sweeney, Luis A. Sanchez
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Publication number: 20020148386Abstract: An ink composition including a near infrared absorbing dye that converts absorbed near infrared radiation into heat without fluorescing significantly and a substantially non-aqueous, organic solvent system. The dye is a tris (dialkylaminophenyl) aminium dye coupled with one anion, a nickel dithiolate or a nickel dithiolene. The non-aqueous, organic solvent system includes an alcohol, for example, a diacetone alcohol, 1-methoxy-2-propanol, or combinations thereof. The method of treating thermoplastic according to the invention includes (a) providing a near infrared absorbing dye that converts absorbed NIR radiation into heat without fluorescing significantly; (b) dissolving the dye into a substantially non-aqueous, organic solvent to form an ink composition; and (c) contacting a thermoplastic part with the ink composition. The contacting step may include painting, dry-burnishing, dip-coating, spraying, printing, and particularly ink jet printing.Type: ApplicationFiled: April 17, 2001Publication date: October 17, 2002Inventors: Nicole M. Woosman, Susan R. Loehr, Robert A. Sallavanti
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Patent number: 6464767Abstract: An ink jet printing method, comprising the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading said printer with an ink jet recording element comprising a support having thereon an image-receptive layer capable of accepting an ink jet image; C) loading said printer with an ink jet ink composition comprising water, a humectant and a water-soluble pyrazoleazoindole dye; and D) printing on said ink jet recording element using said ink jet ink in response to said digital data signals.Type: GrantFiled: October 12, 2000Date of Patent: October 15, 2002Assignee: Eastman Kodak CompanyInventors: Steven Evans, Helmut Weber, Ellen M. Pyszczek, Ann L. Carroll-Lee
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Patent number: 6464766Abstract: The invention includes colorless compounds having a central core and at least two arms extending from the core. The core can comprise one or more atoms. The at least two arms have the formula In such formula, Z is a segment of one or more atoms; j is an integer from 1 to about 300 and can be different at one of the at least two arms than at another of the at least two arms; Q is an alkyl or aryl group and can vary amongst different alkyl and aryl groups within the colorless compound; and n is an integer greater than 1 and can be different at one of the at least two arms than at another of the at least two arms. In other aspects, the invention encompasses phase change inks incorporating the above-described colorless compound as toughening agent, and methods of printing with such phase change inks.Type: GrantFiled: February 15, 2002Date of Patent: October 15, 2002Assignee: Xerox CorporationInventors: Jeffrey H. Banning, Donald R. Titterington, Wolfgang G. Wedler
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Publication number: 20020144626Abstract: An inkjet ink is provided that employs one or more water-soluble colorants or water-insoluble colorants, such as solvent dyes, disperse dyes, or pigments. The colorant, whether water-soluble or water-insoluble, is derivatized with one or more crown ethers to render the water-insoluble colorants soluble in water and in water-miscible organic solvents commonly employed in inkjet printing, particularly thermal inkjet printing, and to impart improved properties to the colorants, such as lightfastness, smearfastness, and waterfastness. The inkjet ink comprises a vehicle and at least one crown ether derivatized colorant. The resulting inkjet ink evidences improved print quality properties, compared to inkjet inks containing colorants that are not so derivatized.Type: ApplicationFiled: February 27, 2001Publication date: October 10, 2002Inventor: David M. Schut
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Patent number: 6460988Abstract: An ink set which comprises a magenta ink and a cyan ink, where the magenta ink comprises a coloring material of general formula (I) and a compound of general formula (II), and the cyan ink comprises a coloring material having a copper phthalocyanine structure and a compound of general formula (II): which can provide color images excellent in light fastness at a mixed color region of the magenta and the cyan inks.Type: GrantFiled: June 11, 2001Date of Patent: October 8, 2002Assignee: Canon Kabushiki KaishaInventors: Kumiko Mafune, Tsuyoshi Kanke
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Patent number: 6461418Abstract: The present invention is directed to aqueous based ink compositions for ink jet printing on offset media and offset ink comprising various combinations of nonionic surfactants. Such formulations include effective amounts of an ink colorant and a nonionic surfactant having an HLB value from about 4 to 14. Optionally, additional nonionic surfactants, solvents, and binders can be added. In another formulation, an effective amount of an ink colorant, at least two nonionic surfactants, each being present at from about 0.01% to 10% by weight (preferably 0.01% to 2% by weight) and an effective amount of at least one binder (such as an acrylate binder) is disclosed.Type: GrantFiled: September 28, 2000Date of Patent: October 8, 2002Assignee: Hewlett-Packard CompanyInventors: Shunqiong Yue, George M. Sarkisian, Mark L. Choy, Yi-Hua Tsao, Howard A Doumaux
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Patent number: 6461417Abstract: An ink composition comprised of (1) an ink vehicle of (a) alkyl alkyl ketones of the formula CH3(CH2)m CO (CH2)n CH3 where m and n represent the number of segments and wherein alkyl contains from about 1 to about 25 carbons, (b) alkyl aryl ketones where each alkyl contains from about 1 to about 20 carbons, and the aryl is anthracene, naphthalene or phenyl, (c) arylaryl ketones where each aryl is benzyl, phenyl or naphthyl, (2) an ink viscosity component, (3) a conductive compound, (4) an antioxidant compound, (5) a lightfastness component, and (6) a colorant.Type: GrantFiled: August 24, 2000Date of Patent: October 8, 2002Assignee: Xerox CorporationInventors: Shadi L. Malhotra, Raymond W. Wong, Marcel P. Breton
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Publication number: 20020139280Abstract: A ballpoint pen oil-based ink composition, comprising an ink having therein a mixture of at least one phosphoric acid ester having an acid number of 90 to 600 and at least one weakly cationic component selected from the group consisting of:Type: ApplicationFiled: December 27, 2001Publication date: October 3, 2002Applicant: MITSUBISHI PENCIL CO., LTD.Inventor: Shuji Ichikawa
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Patent number: 6458192Abstract: An object of this invention is to provide an ink composition with particularly excellent erasability and fixability, the erasability not declining with the lapse of time. This invention provides an erasable ink composition comprising a colorant, a film-forming resin and a release agent.Type: GrantFiled: January 3, 2000Date of Patent: October 1, 2002Assignee: Sakura Color Products CorporationInventor: Shinji Tsujio
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Patent number: 6458193Abstract: Washable coloring compositions comprising mixtures of specific low-molecular weight carboxylic acids and carboxylates are provided. Such mixtures are produced through the partial neutralization of a carboxylic acid by a base to provide a relatively neutral pH mixture comprising some acid and some carboxylate species. Such mixtures provide excellent washability enhancing performance in association with colorants and inks. Also, these specific mixtures exhibit low viscosities which allow for greater amounts of washability enhancing additive and colorant to be added within colorant and ink formulations while simultaneously permitting the mention of sufficiently low overall viscosities of the target compositions. Such mixtures provide highly effective prevention of permanent colorations to certain substrates, such as skin, clothing, and the like, by the inks, dyes, and the like, within the target compositions.Type: GrantFiled: May 16, 2000Date of Patent: October 1, 2002Assignee: Milliken & CompanyInventor: Richard A. VanDahm
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Publication number: 20020134280Abstract: An ink composition includes: an aqueous medium; a coloring compound dissolved or dispersed in the aqueous medium; and at least one clathrate compound, so as to exhibit excellent fastness and weather resistance.Type: ApplicationFiled: January 25, 2002Publication date: September 26, 2002Inventor: Hideaki Naruse
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Patent number: 6454846Abstract: An ink composition is provided which can yield prints having high color density and, even when printed on recycled papers, causes no significant feathering or bleeding and, at the same time, has excellent ejection stability and storage stability, The ink composition comprises a colorant, water, and a compound represented by formula (I): R-(EO)n-(PO)m-M wherein R represents an alkoxy group having in its molecular chain an acetylene bond; EO represents an ethyleneoxy group; and PO represents a propyleneoxy group; n and m each represent a repeating unit in terms of an average value in the whole system. EO and PO may be present in any order in the molecule. M represents a terminal group attached to the terminal oxygen atom of EO or PO.Type: GrantFiled: February 21, 2001Date of Patent: September 24, 2002Assignee: Seiko Epson CorporationInventor: Masahiro Yatake
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Patent number: 6451098Abstract: A water-based ink jet ink includes water, N-methylmorpholine-N-oxide co-solvent of the following structure, and at least 0.5 % by ink weight of a dye selected from the reactive, acid, basic or direct dye classes.Type: GrantFiled: October 3, 2001Date of Patent: September 17, 2002Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Jason Lye, Diane Vernice Graff, Mary Elizabeth Kister
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Patent number: 6451099Abstract: Provided is a water based ink composition for a ball point pen comprising at least one selected from the group consisting of an alkylene oxide adduct of polyglycerin, an alkylene oxide adduct of glycerin and an alkylene oxide adduct of trimethylolpropane and further comprising a colorant, a white plastic pigment, a viscosity-controlling agent and water. The ink composition is excellent in a writing property as well as a coloring property of the drawn lines regardless of the kind of writing paper and is stable with the passage of time. In addition thereto, it provides the drawn lines with a color having the same color tone as that of the visual color when it is charged into an ink reservoir.Type: GrantFiled: May 23, 2000Date of Patent: September 17, 2002Assignee: Mitsubishi Pencil Kabushiki KaishaInventors: Masaru Miyamoto, Tadashi Kamagata, Miki Shinozuka
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Publication number: 20020124771Abstract: A meltable ink composition used in a printing apparatus in which ink drops are ejected from ink ducts wherein the ink composition contains a compound with the following formula 1Type: ApplicationFiled: January 8, 2002Publication date: September 12, 2002Inventors: Danny Hendrik Maria Hendricks, Marcus Petrus Leonardus Huinck, Frederik Leonardus Everardus Suilen
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Patent number: 6447592Abstract: Disclosed are ink compositions, which can satisfy, on a high level, various properties required of ink compositions for ink jet textile printing and can realize good printed images, and an ink jet textile printing method using the same. An ink composition comprising at least an acid dye, a surfactant, water, and at least one compound represented by formula (I), the ink composition having a viscosity of not more than 8.0 m.Pa.s (20° C.), is printed on a woven fabric by means of a piezoelectric vibrator type ink jet recording head: wherein EP1, EP2, and EP3 each independently represent an ethyleneoxy or propyleneoxy group; and ;, m, and n each are independently 0 of a natural number of 1 or more, provided that at least one of l, m, and n is 1 or more with the average of l+m+n in the whole compound represented by formula (I) contained in the ink composition being 1 to 30.Type: GrantFiled: March 9, 2000Date of Patent: September 10, 2002Assignee: Seiko Epson CorporationInventor: Makoto Taniguchi
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Publication number: 20020121220Abstract: A multicolor ink jet printing process employs an ink jet ink composition comprising water, a colorant of pigment, dye, or mixtures thereof, and a low boiling point additive to produce high quality multicolor ink jet images with minimal intercolor bleed and lines with sharp edges as characterized by a relatively low mid frequency line edge noise (MFLEN) number. The additive is an alcohol or thiol having a boiling point less than or equal to about 115° C. The aforementioned ink jet ink composition can further include an optional additive of alcohol or thiol with a boiling point less than or equal to about 135° C. if necessary. The desired additive increases the ink's drying rate with fast evaporation and an accelerated penetration into a print substrate (e.g. paper) upon printing. As a result, little or minimum residual ink (e.g. carbon black ink) comprising the aforementioned additive is available on the surface of the print substrate to intermix with a previously or subsequently printed ink (e.g.Type: ApplicationFiled: December 28, 2000Publication date: September 5, 2002Inventor: John Wei-Ping Lin
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Patent number: 6444018Abstract: A phase change ink carrier composition comprising at least one anhydride/amino alcohol based adduct which is a reaction product of at least one anhydride and at least one amino alcohol, wherein the reaction product is an ester material or an amide material, but not an ester-amide material.Type: GrantFiled: February 12, 1999Date of Patent: September 3, 2002Assignee: Xerox CorporationInventors: Clifford R. King, Jeffery H. Banning, Donald R. Titterington
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Patent number: 6444019Abstract: The present invention provides a jet ink composition comprising a volatile organic solvent, an oil, one or more binder resins which are soluble in the volatile organic solvent, and a colorant. The ink composition is fast drying and provides excellent adhesion to non-porous substrates. Printers, such as drop-on-demand ink jet printers, employing the ink composition can operate without nozzle clogging even after long non-printing intervals. The present invention further provides a method for reducing clogging of a nozzle orifice in an ink jet printer comprising printing with an ink composition that includes an oil that forms a continuous oil phase which acts as the boundary layer between the air outside the nozzle orifice and the ink inside the nozzle during non-printing intervals.Type: GrantFiled: June 10, 1999Date of Patent: September 3, 2002Assignee: Videojet Technologies Inc.Inventors: Wan Kang Zou, Xiaomang Wang, Carrie Woodcock, Qiao Qiao Dong, Fengfei Xiao