Electrically Conductive Or Magnetic Compositions (e.g., Electrically Sensitive, Electrochemical, Electrolytic, Etc.) Patents (Class 106/31.92)
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Patent number: 12119134Abstract: An electrically conductive, flexible, strain resilient product is produced by mixing metal coated carbon nanotube networks with a liquid polymeric resin to produce a liquid mixture, and the mixture is cured to produce the product. The networks may include welded junctions between nanotubes formed by depositing and melting metal nanoparticles on the nanotubes to form the metal coating. After the mixing step the liquid mixture may be deposited on a flexible substrate in the form of an electrical circuit. The mixing step may further include mixing the composite with a volatile solvent to produce a selected viscosity. Then, a three-dimensional printer may be used to print the product, such as an electrical circuit, on a substrate. The product is cured in an atmosphere that absorbs the solvent. The conductivity of the mixture may be adjusted by adjusting the weight percentage of the metal coated carbon nanotube networks from 50% to 90%, but a preferred range is between 75% and 85%.Type: GrantFiled: October 5, 2023Date of Patent: October 15, 2024Assignee: United States of America as represented by Secretary of the Air ForceInventors: Sabyasachi Ganguli, Ajit K Roy, Chenggang Chen
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Patent number: 11905427Abstract: Provided herein is a composition for eutectic metal alloy nanoparticles having an average particle size ranging from about 0.5 nanometers to less than about 5000 nanometers and at least one organoamine stabilizer. Also provided herein is a process for preparing eutectic metal alloy nanoparticles comprising mixing at least one organic polar solvent, at least one organoamine stabilizer, and a eutectic metal alloy to create a mixture; sonicating the mixture at a temperature above the melting point of the eutectic metal alloy; and collecting a composition comprising a plurality of eutectic metal alloy nanoparticles having an average particle size ranging from about 0.5 nanometers to less than about 5000 nanometers. Further disclosed herein are hybrid conductive ink compositions comprising a component comprising a plurality of metal nanoparticles and a component comprising a plurality of eutectic metal alloy nanoparticles.Type: GrantFiled: June 15, 2021Date of Patent: February 20, 2024Assignee: XEROX CORPORATIONInventors: Guiqin Song, Sarah J. Vella, Barkev Keoshkerian
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Patent number: 11750940Abstract: An imaging apparatus includes: an imaging sensor; a lens mount to which a lens is attached; and a processor is configured to read out an imaging signal from the imaging sensor and generate a raw image. The processor is configured to determine a length of a second focal length in a second direction which intersects with an extending direction of an optical axis of the lens and a first direction which intersects with the extending direction, relative to a first focal length in the first direction, and make a resolution ratio, which is a ratio of a resolution of the raw image in the first direction to a resolution of the raw image in the second direction, higher than a resolution ratio of the imaging sensor in a case where the second focal length is longer than the first focal length.Type: GrantFiled: October 26, 2022Date of Patent: September 5, 2023Assignee: FUJIFILM CorporationInventors: Tomoyuki Kawai, Koichi Tanaka, Junya Kitagawa, Yuya Nishio
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Patent number: 11548068Abstract: Provided is a method of producing spherical silver powder, which makes it possible to easily produce spherical silver powder having primary particle diameters with less variation than conventional powder and spherical silver powder obtained by the method. The method of producing spherical silver powder includes a reduction precipitation step of precipitating silver particles by reduction by adding a reductant including hydrazine carbonate to an aqueous reaction system containing silver ions.Type: GrantFiled: July 17, 2019Date of Patent: January 10, 2023Assignee: DOWA Electronics Materials Co., Ltd.Inventors: Kemmei Otsubo, Koji Hirata
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Patent number: 11217659Abstract: An improved silicon carbide wafer using direct application conductive ink interconnects positioned on printing connection pads. The conductive ink interconnected can be routed to form a custom length resistive trace for a device after fabrication and measurement of the device.Type: GrantFiled: January 24, 2020Date of Patent: January 4, 2022Inventors: Matthew W. Barlow, Nicholas J. Chiolino, Anthony M. Francis, James A. Holmes
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Patent number: 10815387Abstract: The aqueous ink jet ink composition contains a pigment dispersion formed of a surface-treated pigment having a phosphorus-containing group on a surface thereof and a resin dispersion, in which a conductivity of the ink composition is 2600 ?s/cm or less.Type: GrantFiled: February 5, 2018Date of Patent: October 27, 2020Assignee: Seiko Epson CorporationInventors: Akiko Matsuzaki, Mitsuaki Kosaka
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Patent number: 10696852Abstract: A problem is to provide a silver paste which can produce, without variation in resistivity value, a conductive silver coating film exhibiting resistivity substantially equivalent to the resistance value of bulk silver in low-temperature sintering. The problem is solved by providing a silver paste including a silver nanoparticle aqueous dispersion prepared by using a compound having a polyethyleneimine skeleton as a protective agent, a compound having a functional group reactable with nitrogen atoms in the polyethyleneimine, and at least one compound selected from the group consisting of a compound having an amine functional group and a compound having an amide functional group.Type: GrantFiled: December 8, 2015Date of Patent: June 30, 2020Assignee: DIC CORPORATIONInventors: Kaori Kawamura, Masayuki Moriwaki, Yoshiyuki Sano
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Patent number: 10597547Abstract: A robust formulation of silver-organo-complex (SOC) ink and method of making same are provided. In an aspect, the complexing molecules act as reducing agents. The silver loaded ink can be printed and sintered on a wide range of substrates with uniform surface morphology and excellent adhesion.Type: GrantFiled: December 13, 2016Date of Patent: March 24, 2020Assignee: KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGYInventors: Mohammad Vaseem, Garret McKerricher, Atif Shamim
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Patent number: 10418498Abstract: Disclosed are a single-source precursor for synthesizing metal chalcogenide nanoparticles for producing a light absorption layer of solar cells comprising a Group VI element linked as a ligand to any one metal selected from the group consisting of copper (Cu), zinc (Zn) and tin (Sn), metal chalcogenide nanoparticles produced by heat-treating at least one type of the single-source precursor, a method of preparing the same, a thin film produced using the same and a method of producing the thin film.Type: GrantFiled: April 29, 2019Date of Patent: September 17, 2019Assignee: LG CHEM, LTD.Inventors: Eun Ju Park, Seokhee Yoon, Seokhyun Yoon, Hosub Lee
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Patent number: 10340402Abstract: Disclosed are a single-source precursor for synthesizing metal chalcogenide nanoparticles for producing a light absorption layer of solar cells comprising a Group VI element linked as a ligand to any one metal selected from the group consisting of copper (Cu), zinc (Zn) and tin (Sn), metal chalcogenide nanoparticles produced by heat-treating at least one type of the single-source precursor, a method of preparing the same, a thin film produced using the same and a method of producing the thin film.Type: GrantFiled: October 27, 2015Date of Patent: July 2, 2019Assignee: LG CHEM, LTD.Inventors: Eun Ju Park, Seokhee Yoon, Seokhyun Yoon, Hosub Lee
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Patent number: 10155877Abstract: Improved materials and compositions for improving materials to enhance their properties; the compositions, in certain aspects, strengthening materials, enhancing bonding between materials, and/or improving properties such as strength, impact resistance, sustainability, protection level, and structural integrity; the material in certain aspects being glass; the compositions including alcohol, glycerol, a silane, acetate adhesive, a surfactant, and carbon nanotubes; and, optionally in certain aspects, no nanotubes and/or no surfactants but with a vinyl acetate monomer. This abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure and is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims, 37 C.F.R. 1.72(b).Type: GrantFiled: October 29, 2014Date of Patent: December 18, 2018Assignee: C-Bond Systems, LLCInventor: Paul H. Brogan
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Patent number: 10134994Abstract: The present invention relates to a novel polycyclic polymer comprising fused thiophene units. The present invention also relates to a method for producing such polymer as well as the use of such polymer, particularly in organoelectronic applications.Type: GrantFiled: October 29, 2014Date of Patent: November 20, 2018Assignee: MERCK PATENT GMBHInventors: William Mitchell, Mansoor D'Lavari, Changsheng Wang, David Sparrowe
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Patent number: 10119932Abstract: A gas detector includes an electrochemical gas sensor. The sensor includes a plurality of electrodes. At least one of the electrodes is formed of a catalyst/binder slurry which is halftone printed onto a substrate. The composite printed element and substrate are sintered to form the electrode.Type: GrantFiled: May 28, 2014Date of Patent: November 6, 2018Assignee: Honeywell International Inc.Inventors: Ling Liu, Yan Zhang, Qian Zheng
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Patent number: 10100218Abstract: Provided is a curable composition for inkjet, which can have improved storage stability. The curable composition for inkjet according to the present invention can be applied in an inkjet mode, and can be cured by the irradiation with light and the application of heat, the curable composition for inkjet according to the present invention comprises a polyfunctional compound having at least two (meth)acryloyl groups, a compound having a cyclic ether group, a heat-curing agent and a color material which cannot be dissolved in the polyfunctional compound and which is dissolved in the curable composition.Type: GrantFiled: September 19, 2013Date of Patent: October 16, 2018Assignee: SEKISUI CHEMICAL CO., LTD.Inventors: Ryosuke Takahashi, Takanori Inoue, Michihisa Ueda, Takashi Watanabe, Shigeru Nakamura
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Patent number: 9980415Abstract: A modular jet impingement assembly includes an inlet tube fluidly coupled to a fluid inlet, an outlet tube fluidly coupled to a fluid outlet, and a modular manifold having a first distribution recess extending into a first side of the modular manifold, a second distribution recess extending into a second side of the modular manifold, a plurality of inlet connection tubes positioned at an inlet end of the modular manifold, and a plurality of outlet connection tubes positioned at an outlet end of the modular manifold. A first manifold insert is removably positioned within the first distribution recess, a second manifold insert is removably positioned within the second distribution recess, and a first and second heat transfer plate each removably coupled to the modular manifold. The first and second heat transfer plates each comprise an impingement surface.Type: GrantFiled: August 20, 2015Date of Patent: May 22, 2018Assignee: Toyota Motor Engineering & Manufacturing North America, Inc.Inventors: Feng Zhou, Ercan Mehmet Dede
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Patent number: 9879145Abstract: An ink composition for screen printing for a glass substrate includes a solvent with a boiling point at least 170° C. at least at 70 mass % of the total solvent and a prepolymer or polymer with a weight-average molecular weight of at least 2000 at least at 2 mass % with respect to total ink composition, and with a viscosity of 5 to 180 Pa·s measured with a BH-type rotating viscosimeter at 25° C. and thixotropic index (TI value) of 2.0 to 8.0, the measured flow radius value being 13.0 to 24.0 mm after 1 minute from start of measurement by a flow property measuring method using a spread meter at 25° C. according to JIS K5701-1:2000, satisfying “F60”?“F45”?1.0 mm, where “F60” and “F45” are measured flow radius values after 1 minute and 45 seconds, respectively, from start of measurement, and containing a coupling agent compound.Type: GrantFiled: January 26, 2016Date of Patent: January 30, 2018Assignee: Teikoku Printing Inks Mfg. Co. Ltd.Inventors: Tomomi Ogata, Takuya Torihata, Naoto Takada
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Patent number: 9741877Abstract: A composition for solar cell electrodes, the composition including silver (Ag) powder; a glass frit; an organic binder; and a solvent, the organic binder including a compound containing a repeat unit represented by Formula 1: wherein R1 is Na+, K+, NH4+, or PH3+; R2 is a hydrogen atom or a C1 to C2 alkyl group; and n is an integer of 1 to 3,500.Type: GrantFiled: September 1, 2015Date of Patent: August 22, 2017Assignee: Samsung SDI Co., Ltd.Inventors: HyungSeok Park, EunKyung Kim, Hee In Nam, SungIl Moon, Young Sil Lee
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Patent number: 9707624Abstract: Provided is a method of synthesizing silver nanoparticles including: a) a nucleation step of reacting a composition containing a silver precursor, a heterogeneous metal precursor, and an amine-based compound at 30 to 120° C. to form a nucleus; and b) a growth step of reacting the composition containing the nucleus formed therein at 155 to 350° C. to grow the nucleus. According to the present invention, significantly uniform and fine silver nanoparticles may be synthesized with high reproducibility on a large scale.Type: GrantFiled: December 8, 2014Date of Patent: July 18, 2017Assignee: KOREA BASIC SCIENCE INSTITUTEInventors: Gaehang Lee, Yeon Suk Choi
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Patent number: 9540734Abstract: A conductive composition that comprises a branched metal carboxylate and one or more solvents. The solvents may be an aromatic hydrocarbon solvent. In embodiments, the branched metal carboxylate is a silver carboxylate. The conductive composition may be used in forming conductive features on a substrate, including by inkjet printing, screen printing or offset printing.Type: GrantFiled: November 13, 2013Date of Patent: January 10, 2017Assignee: XEROX CORPORATIONInventors: Yiliang Wu, Ping Liu
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Patent number: 9145503Abstract: A low-temperature sintered conductive metal ink and a method for preparing the same are provided. To be specific, the preparation method includes the following steps of: preparing the conductive film or pattern by printing a conductive metal ink including metal nanocolloids, metal salts, and polymers reacted with the metal salts and preparing the metal nanocolloids (step 1); preparing a mixture by mixing the metal salts and polymers (step 2); preparing the metal ink by stirring the metal nanocolloids and the metal salt/polymer mixture prepared at steps 1 and 2 (step 3); printing the metal ink prepared at step 3 (step 4); and drying and thermally treating a product printed at step 4 (step 5).Type: GrantFiled: October 20, 2011Date of Patent: September 29, 2015Assignee: Korea Institute of Machinery and MaterialsInventors: Ji-Hun Yu, Sangsun Yang, Yong-Jin Kim
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Patent number: 9028601Abstract: An ink composition of the invention is an ink composition to be ejected by an ink jet system and includes silver particles and water. When a composition A formed of components of the ink composition other than the water is held in an atmosphere at an ambient temperature of 23° C. and a relative humidity (RH) of 50%, the equilibrium moisture content of the component A is in a range of 2 to 7.8 percent by mass.Type: GrantFiled: February 3, 2012Date of Patent: May 12, 2015Assignee: Seiko Epson CorporationInventors: Atsushi Denda, Shiki Hirata, Tsuyoshi Sano
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Publication number: 20150122335Abstract: Disclosed are an ink composition for manufacturing a light absorption layer including metal nano particles and a method of manufacturing a thin film using the same, more particularly, an ink composition for manufacturing a light absorption layer including copper (Cu)-enriched Cu—In bimetallic metal nano particles and Group IIIA metal particles including S or Se dispersed in a solvent and a method of manufacturing a thin film using the same.Type: ApplicationFiled: January 6, 2015Publication date: May 7, 2015Inventors: Seokhee YOON, Seokhyun YOON, Taehun YOON
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Patent number: 8986575Abstract: A conductive paste containing a conductive powder (A), a vinyl chloride-vinyl acetate resin (B), a polyester resin and/or polyurethane resin (C), a blocked isocyanate (D) blocked with an active methylene compound, and an organic solvent (E), wherein the resin (C) has a glass transition temperature of ?50° C. to 20° C., a sum of amounts of the resin (C) is 50 to 400 parts by weight relative to 100 parts by weight of the resin (B), and a sum of amounts of the resin (B), the resin (C) component, and the blocked isocyanate (D) is 10 to 60 parts by weight relative to 100 parts by weight of the conductive powder (A). An electric wiring in which this conductive paste is formed on an insulating substrate.Type: GrantFiled: October 22, 2009Date of Patent: March 24, 2015Assignees: Toyo Boseki Kabushiki Kaisha, Kabushiki Kaisha ToshibaInventors: Yuichiro Akiba, Tomoko Honda, Fujio Takahashi, Shinji Nakata
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Publication number: 20150070818Abstract: An inkjet ink that contains a functional particle having a BET-equivalent particle diameter of 50 to 1000 nm, a rheology-controlling particle having a BET-equivalent particle diameter of 4 to 40 nm, and an organic vehicle. The ink has a viscosity of 1 to 50 mPa·s at a shear rate of 1000 s?1. At a shear rate of 0.1 s?1, the ink has a viscosity equal to or higher than a viscosity ? calculated using the following equation: ?=(D)2×?/104/2+80 [where ? is the viscosity (mPa·s) at a shear rate of 0.1 s?1, D is the BET-equivalent particle diameter (nm) of the functional particle, and ? is the specific gravity of the functional particle].Type: ApplicationFiled: November 18, 2014Publication date: March 12, 2015Inventors: Akihiro Tsuru, Taketsugu Ogura, Naoaki Ogata
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Publication number: 20150056382Abstract: Provided is a transparent conductive ink which contains metal nanowires and/or metal nanotubes as a conductive component and can form a coating film which has good conductivity and a high light transmittance property, and also provided is a transparent conductive pattern forming method wherein this transparent conductive ink is used for forming a transparent conductive pattern by simple production steps, to thereby suppress the production cost and environmental load. At least one of metal nanowires and metal nanotubes are dispersed in a dispersion medium containing a shape-holding material which contains an organic compound having a molecular weight in the range of 150 to 500 and which has a viscosity of 1.0×103 to 2.0×106 mPa·s at 25° C., to prepare a transparent conductive ink.Type: ApplicationFiled: April 26, 2013Publication date: February 26, 2015Applicants: SHOWA DENKO K. K., OSAKA UNIVERSITYInventors: Katsuaki Suganuma, Kuniaki Ohtsuka, Koichiro Murahashi, Yasutaka Takemura, Hiroshi Uchida
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Patent number: 8945429Abstract: The present invention relates conductive nanostructured copolymer materials, such as thin film. In particular, the nanostructured copolymer material comprises plurality of chains substantially parallel to each other, each conductive chain comprising a plurality of conductive polyacetylene polymer blocks positioned along the chain and a plurality of polar poly(vinyl alcohol) polymer blocks in between the polyacetylene polymer blocks to form a pattern of alternatively repeating polyacetylene polymer blocks and poly(vinyl alcohol) polymer blocks and a ratio of polyacetylene polymer to poly(vinyl alcohol) polymer to provide the nanostructured copolymer material with conductivity of at least 1 S/cm. In some aspects, the invention relates to photoelectric devices comprising a nanostructured copolymer material and capable to convert light to electrical current.Type: GrantFiled: April 11, 2012Date of Patent: February 3, 2015Assignee: Energy Materials CorporationInventors: Stephan DeLuca, Sitaraman Krishnan
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Patent number: 8940195Abstract: A conductive paste includes a conductive powder, a metallic glass, and an organic vehicle. The metallic glass includes a first element, a second element having a higher absolute value of Gibbs free energy of oxide formation than the first element, and a third element having an absolute value of Gibbs free energy of oxide formation of about 1000 kJ/mol or less at a baking temperature and a eutectic temperature with the conductive powder of less than about 1000° C. An electronic device and a solar cell may include an electrode formed using the conductive paste.Type: GrantFiled: November 30, 2011Date of Patent: January 27, 2015Assignee: Samsung Electronics Co., Ltd.Inventors: Eun Sung Lee, Se Yun Kim, Sang Soo Jee, Yong Nam Ham
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Patent number: 8894888Abstract: A conductive paste composition contains a source of an electrically conductive metal, a fusible material, a synthetic clay additive, and an optional etchant additive, dispersed in an organic medium. An article such as a photovoltaic cell is formed by a process having the steps of deposition of the paste composition on a semiconductor substrate by a process such as screen printing and firing the paste to remove the organic medium and sinter the metal and fusible material. The synthetic clay additive aids in establishing a low resistance electrical contact between the front side metallization and underlying semiconductor substrate during firing.Type: GrantFiled: December 21, 2011Date of Patent: November 25, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Steven Dale Ittel, John Graeme Pepin
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Patent number: 8871014Abstract: A phase change ink composition includes metal nanoparticles, a dispersing agent allowing the metal nanoparticles to be stably dispersed and arranged within the phase change ink composition, and a solvent in which the metal nanoparticles and the dispersing agent are mixed and which comprises at least two sulfur-containing compounds, wherein the phase change ink composition has a melting temperature ranging from 60° C. to 90° C.Type: GrantFiled: August 14, 2013Date of Patent: October 28, 2014Assignee: LG Chem, Ltd.Inventor: Joon-Hyung Kim
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Patent number: 8834965Abstract: Processes for producing organoamine-stabilized silver nanoparticles are disclosed. The processes comprise: (a) forming a solution comprising an organic solvent and a first amount of organoamine; (b) adding silver salt particles to the solution; (c) adding a second amount of organoamine to the solution; (d) adding an organohydrazine to the solution; and (e) reacting the solution to form organoamine-stabilized silver nanoparticles.Type: GrantFiled: February 12, 2009Date of Patent: September 16, 2014Assignee: Xerox CorporationInventors: Mahya Mokhtari, Marko D. Saban, Roger Earl Gaynor
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Patent number: 8771558Abstract: A method of manufacturing an anti-counterfeit ink is provided. A tungsten oxide nanowire is provided. A hydrophilic treatment is performed to the tungsten oxide nanowire to form a tungsten oxide nanowire with hydrophilicity. The tungsten oxide nanowire with hydrophilicity and an ink are mixed to form an anti-counterfeit ink.Type: GrantFiled: December 9, 2010Date of Patent: July 8, 2014Assignee: National Taiwan University of Science and TechnologyInventors: Borh-Ran Huang, Tzu-Ching Lin, Ying-Kan Yang
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Patent number: 8734678Abstract: The present invention relates to a marking of polymeric liquid crystal material having determined optical characteristics allowing its authentication and reading by a machine and its authentication by the human eye. The marking is applied onto an item, good or article by a variable information printing process. The marking is in the form of indicia representing a unique code which allows for an easy authentication by the human eye and a secure tracking and tracing of the marked item, good or article throughout is life cycle.Type: GrantFiled: June 25, 2012Date of Patent: May 27, 2014Assignee: SICPA Holding SAInventors: Xavier Marguerettaz, Frédéric Gremaud, Aurélien Commeureuc, Vickie Aboutanos, Thomas Tiller, Olivier Rozumek
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Patent number: 8734679Abstract: The present invention relates to a marking of polymeric liquid crystal material having determined optical characteristics allowing its authentication and reading by a machine and its authentication by the human eye. The marking is applied onto an item, good or article by a variable information printing process. The marking is in the form of indicia representing a unique code which allows for an easy authentication by the human eye and a secure tracking and tracing of the marked item, good or article throughout its life cycle.Type: GrantFiled: June 25, 2012Date of Patent: May 27, 2014Assignee: Sicpa Holding SAInventors: Xavier Marguerettaz, Frédéric Gremaud, Aurélien Commeureuc, Vickie Aboutanos, Thomas Tiller, Olivier Rozumek
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Patent number: 8680678Abstract: A conductive electrode paste or ink formulation including a getter removes or reduces the concentration of the unwanted impurities in an electronic device. These reductions may happen during or immediately after the fabrication or sealing of the device, or they may occur after some activation time or event. Water, oxygen, carbon dioxide, hydrogen, and residual solvents are gettered.Type: GrantFiled: June 1, 2010Date of Patent: March 25, 2014Assignee: Sumitomo Chemical Co., Ltd.Inventors: John Devin MacKenzie, Jian Ping Chen
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Patent number: 8673401Abstract: A method for depositing gallium using a gallium ink, comprising, as initial components: a gallium component comprising gallium; a stabilizing component; an additive; and, a liquid carrier; is provided comprising applying the gallium ink on the substrate; heating the applied gallium ink to eliminate the additive and the liquid carrier, depositing gallium on the substrate; and, optionally, annealing the deposited gallium.Type: GrantFiled: January 7, 2013Date of Patent: March 18, 2014Assignee: Rohm and Haas Electronic Materials LLCInventors: David Mosley, David Thorsen
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Patent number: 8623938Abstract: An inkjet ink includes carbon nanotubes, flake graphites, an organic carrier, a binder, a surfactant, a film enhancer and a solvent. A method for making an inkjet ink includes dispersing the plurality of carbon nanotubes in the surfactant solvent to form a first mixture, dispersing the plurality of flake graphites in the organic carrier solvent to form a second mixture, adding the film enhancer into the second mixture to form a third mixture, and mixing the first mixture and the third mixture.Type: GrantFiled: September 2, 2011Date of Patent: January 7, 2014Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.Inventors: Hai-Yan Hao, Bing-Chu Du, Chun-Hai Zhang, Shou-Shan Fan
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Patent number: 8623939Abstract: An ink contains at least a first solid particle, and a second solid particle formed of a base material of a different main component from that of the first solid particle. The first solid particle and the second solid particle have zeta potentials of the same polarity, or zeta potentials of 0±5 mV. The first and second solid particles in the ink have the same surface property, specifically the same interface property in the ink. This makes it possible to use a common dispersant suited for adsorption on the first and second solid particles. In this way, more than one kind of solid particle can be stably dispersed using a sole kind of dispersant.Type: GrantFiled: February 1, 2012Date of Patent: January 7, 2014Assignee: NGK Spark Plug Co., Ltd.Inventors: Daisuke Uematsu, Kentaro Mori, Nobuhiro Hayakawa
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Patent number: 8597420Abstract: Solvent-based ink compositions which can be used for ink jet printing in a variety of applications. In particular, the present embodiments are directed to magnetic inks having desirable ink properties. The ink of the present embodiments comprises magnetic nanoparticles that are coated with various materials to prevent the exposure of the nanoparticles to oxygen, and provides robust prints.Type: GrantFiled: March 17, 2011Date of Patent: December 3, 2013Assignee: Xerox CorporationInventors: Gabriel Iftime, Peter G. Odell, C. Geoffrey Allen, Marcel P. Breton, Richard P. N. Veregin
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Patent number: 8574356Abstract: An ink composition includes an aluminum pigment, a white pigment, and a dispersion solvent, wherein the ink composition has a structure in which the aluminum pigment is dispersed in the dispersion solvent and the content of the white pigment is 0.01% to 10% based on the content of the aluminum pigment, or includes silver particles, a white pigment, and water, wherein the particle diameter d90 in the particle diameter accumulation curve of the silver particles is 50 nm to 1 ?m, the ink composition has a structure in which the silver particles are dispersed in the water, and the content of the white pigment is 1% to 10% based on the content of the silver particles.Type: GrantFiled: May 13, 2011Date of Patent: November 5, 2013Assignee: Seiko Epson CorporationInventors: Takayoshi Kagata, Kiyohiko Takemoto, Tsuyoshi Sano, Shiki Hirata, Naoki Koike
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Patent number: 8563088Abstract: A method for preparing a Group 1a-1b-3a-6a material using a selenium/Group 1b ink comprising, as initial components: a selenium component comprising selenium, an organic chalcogenide component having a formula selected from RZ—Z?R? and R2—SH, a Group 1b component and a liquid carrier; wherein Z and Z? are each independently selected from sulfur, selenium and tellurium; wherein R is selected from H, C1-20 alkyl group, a C6-20 aryl group, a C1-20 alkylhydroxy group, an arylether group and an alkylether group; wherein R? and R2 are selected from a C1-20 alkyl group, a C6-20 aryl group, a C1-20 alkylhydroxy group, an arylether group and an alkylether group; and wherein the selenium/Group 1b ink is a stable dispersion.Type: GrantFiled: October 12, 2012Date of Patent: October 22, 2013Assignee: Rohm and Haas Electronic Materials LLCInventors: Kevin Calzia, David Mosley, David L. Thorsen, Charles R. Szmanda
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Patent number: 8546466Abstract: According to the invention, there is provided an image recording composition comprising a curable material capable of immobilizing a colorant material in a received ink and curable by an external stimulus.Type: GrantFiled: January 21, 2009Date of Patent: October 1, 2013Assignee: Fuji Xerox Co., Ltd.Inventors: Yoshiro Yamashita, Ken Hashimoto
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Patent number: 8518170Abstract: Boron-comprising inks for forming boron-doped regions in semiconductor substrates using non-contact printing processes and methods for fabricating such boron-comprising inks are provided. A boron-comprising ink comprises boron from or of a boron-comprising material and a spread-minimizing additive that results in a spreading factor of the boron-comprising ink in a range of from about 1.5 to about 6. The boron-comprising ink has a viscosity in a range of from about 1.5 to about 50 centipoise and, when deposited on a semiconductor substrate, provides a post-anneal sheet resistance in a range of from about 10 to about 100 ohms/square, a post-anneal doping depth in a range of from about 0.1 to about 1 ?m, and a boron concentration in a range of from about 1×1019 to 1×1020 atoms/cm3.Type: GrantFiled: December 29, 2008Date of Patent: August 27, 2013Assignee: Honeywell International Inc.Inventors: Roger Yu-Kwan Leung, De-Ling Zhou, Wenya Fan
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Patent number: 8460584Abstract: Processes for producing carboxylic acid-stabilized silver nanoparticles are disclosed. The processes comprise (a) forming a suspension of silver salt particles in a carboxylic acid; (b) forming a solution of an organohydrazine and a first organic solvent; (c) heating the suspension; (d) adding the solution to the suspension to form a mixture; and (e) reacting the mixture to form carboxylic acid-stabilized silver nanoparticles.Type: GrantFiled: October 14, 2008Date of Patent: June 11, 2013Assignee: Xerox CorporationInventors: Mahya Mokhtari, Marko Saban, Roger Earl Gaynor
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Patent number: 8435424Abstract: A solvent-free conductive paste composition including (a) a binder, (b) an initiator, (c) a glass powder and (d) a conductive powder; and a solar cell element having an electrode or wire made by coating and sintering the conductive paste composition coated on a silicon semiconductor substrate. The conductive paste composition is solvent-free so that it will not cause environmental problems with respect to the evaporation of solvents and will not be easy to spread out. The conductive paste composition facilitates the development of fine wire and high aspect ratio designs and can efficiently enhance the photoelectric conversion efficiency.Type: GrantFiled: December 22, 2009Date of Patent: May 7, 2013Assignee: Eternal Chemical Co., Ltd.Inventor: Tsai-Fa Hsu
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Publication number: 20130082217Abstract: Disclosed is a method of producing metal particles, including preparing a first solution including a silver (Ag) compound and a solvent, heating and stirring the first solution, adding an organophosphorus compound to the first solution and heating the first solution, and forming metal particles capped with a phosphorus (P) compound from the first solution.Type: ApplicationFiled: November 23, 2011Publication date: April 4, 2013Applicant: SAMSUNG ELECTRO-MECHANICS CO., LTD.Inventors: Sung Koo Kang, Ro Woon Lee, Dong Hoon Kim
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Patent number: 8409341Abstract: Solvent-based ink compositions which can be used for ink jet printing in a variety of applications. In particular, the present embodiments are directed to magnetic inks having desirable ink properties. The ink of the present embodiments comprise magnetic nanoparticles that are coated with various materials to prevent the exposure of the nanoparticles to oxygen, and provides robust prints.Type: GrantFiled: March 17, 2011Date of Patent: April 2, 2013Assignee: Xerox CorporationInventors: Gabriel Iftime, Peter G. Odell, C. Geoffrey Allen, Marcel P. Breton, Richard P. N. Veregin
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Patent number: 8404160Abstract: A metallic ink including a vehicle, a multiplicity of copper nanoparticles, and an alcohol. The conductive metallic ink may be deposited on a substrate by methods including inkjet printing and draw-down printing. The ink may be pre-cured and cured to form a conductor on the substrate.Type: GrantFiled: March 31, 2009Date of Patent: March 26, 2013Assignees: Applied Nanotech Holdings, Inc., Ishihara Chemical Co., Ltd.Inventors: Yunjun Li, David Max Roundhill, Xueping Li, Peter B. Laxton, Hidetoshi Arimura, Zvi Yaniv
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Patent number: 8372485Abstract: A gallium ink is provided, comprising, as initial components: a gallium component comprising gallium; a stabilizing component; an additive; and, a liquid carrier; wherein the gallium ink is a stable dispersion. Also provided are methods of preparing the gallium ink and for using the gallium ink in the preparation of semiconductor films (e.g., in the deposition of a CIGS layer for use in photovoltaic devices).Type: GrantFiled: February 18, 2011Date of Patent: February 12, 2013Assignee: Rohm and Haas Electronic Materials LLCInventors: David Mosley, David Thorsen
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Publication number: 20130025497Abstract: A nanoink composition for forming an absorber layer of a thin film solar cell comprises particles and a volatile chelating agent mixing with the particles. The particles contain one or more elements selected from group IB and/or IIB and/or IVA and/or VIA. In the present invention, the volatile chelating agent is a polyetheramine which can alternatively be monoamine compounds, diamine compounds and triamine compounds and has a molecular weight of from about 100 to about 4,000. Accordingly, the particles can be reacted mutually into a single composition while the existence of the volatile chelating agent.Type: ApplicationFiled: July 29, 2011Publication date: January 31, 2013Inventors: Chi-Jie WANG, Shih-Chang Shei
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Patent number: 8328928Abstract: Metal nanoink (100) for bonding an electrode of a semiconductor die and an electrode of a substrate and/or bonding an electrode of a semiconductor die and an electrode of another semiconductor die by sintering under pressure is produced by injecting oxygen into an organic solvent (105) in the form of oxygen nanobubbles (125) or oxygen bubbles (121) either before or after metal nanoparticles (101) whose surfaces are coated with a dispersant (102) are mixed into the organic solvent (105). Bumps are formed on the electrode of the semiconductor die and the electrode of the substrate by ejecting microdroplets of the metal nanoink (100) onto the electrodes, the semiconductor die is turned upside down and overlapped in alignment over the substrate, and then, the metal nanoparticles of the bumps are sintered under pressure by pressing and heating the bumps between the electrodes. As a result, generation of voids during sintering under pressure is minimized.Type: GrantFiled: July 8, 2009Date of Patent: December 11, 2012Assignees: Shinkawa Ltd., Tohoku University, Ulvac, Inc.Inventors: Toru Maeda, Tetsuro Tanikawa, Akinobu Teramoto, Masaaki Oda