Special Process Of Milling, Grinding, Comminuting, Plural Stage Or Zone Mixing Or Product Patents (Class 106/412)
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Patent number: 10800162Abstract: A non-aqueous ink jet composition includes a pigment component containing a diketopyrrolopyrrole pigment and an organic solvent. The organic solvent contains a glycol ether. The amount of water in the non-aqueous ink jet composition is 10 mass % or less based on the total amount of the non-aqueous ink jet composition.Type: GrantFiled: January 25, 2017Date of Patent: October 13, 2020Assignee: Seiko Epson CorporationInventors: Shugo Hattori, Naoki Koike, Jun Ito, Kenichiro Kubota
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Patent number: 10300001Abstract: Techniques for implementing organic materials in sunscreen applications are provided herein. A method includes selecting a combination of multiple organic materials to incorporate into a sunscreen composition, wherein said selecting is based on (i) a desired absorption spectrum of the sunscreen composition, (ii) the absorption spectrum of each of the multiple organic materials, and (iii) a particle size limitation for each of the multiple organic materials, and incorporating the selected combination of organic materials into the sunscreen composition to generate the desired absorption spectrum. A composition includes a combination of multiple organic materials incorporated into a sunscreen composition, wherein the combination of organic materials is selected based on (i) a desired absorption spectrum of the sunscreen composition, (ii) the absorption spectrum of each of the multiple organic materials, and (iii) a particle size limitation for each of the multiple organic materials.Type: GrantFiled: January 19, 2017Date of Patent: May 28, 2019Assignee: International Business Machines CorporationInventors: Talia S. Gershon, Ning Li, Devendra K. Sadana, Teodor K. Todorov
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Patent number: 9978517Abstract: An electro-polarizable compound has the following general formula: Core1 is an aromatic polycyclic conjugated molecule having two-dimensional flat form and self-assembling by pi-pi stacking in a column-like supramolecule, R1 is a dopant group connected to Core1; a number m of R1 groups is 1, 2, 3 or 4. R2 is a substituent comprising one or more ionic groups connected to Core1; a number p of ionic groups R2 is 0, 1, 2, 3 or 4. The fragment marked NLE has a nonlinear polarization effect. Core2 is an electro-conductive oligomer self-assembling by pi-pi stacking in a column-like supramolecule, a number n of such oligomers is 0, 2, or 4. R3 is a substituent comprising one or more ionic groups connected to Core2; a number s of the ionic groups R3 is 0, 1, 2, 3 or 4. R4 is a resistive substituent providing solubility of the compound in a solvent and electrically insulating the column-like supramolecules from each other. A number k of substituents R4 is 0, 1, 2, 3, 4, 5, 6, 7 or 8.Type: GrantFiled: April 4, 2016Date of Patent: May 22, 2018Assignee: CAPACITOR SCIENCES INCORPORATEDInventors: Pavel Ivan Lazarev, Paul T. Furuta, Barry K. Sharp, Yan Li
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Patent number: 9944850Abstract: Provided is a carbon nanostructure including a plurality of organic molecules that are decomposition products of an organic solvent. The carbon nanostructure includes a carbon nanostructure core and a plurality of organic molecules bound to and grown on the carbon nanostructure core, wherein the carbon nanostructure core is a combination of the organic molecules.Type: GrantFiled: May 26, 2016Date of Patent: April 17, 2018Assignee: Korea Institute of Science and TechnologyInventors: Han Ik Jo, Gil Seong Kang, Cheol-Ho Lee, Sung Ho Lee, Dong Su Lee, Tae-Wook Kim, Younki Lee
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Patent number: 9765440Abstract: There is disclosed a method for producing corrosion and erosion-resistant mixed oxide coatings on a metal substrate, as well as a mixed oxide coating itself. A surface of the substrate metal is oxidized and converted into a first coating compound comprising a primary oxide of that metal by a plasma electrolytic oxidation (PEO) process. One or more secondary oxide compounds comprising oxides of secondary elements not present in conventional alloys of the substrate metals at significant (>2 wt %) levels are added to the first oxide coating. The source of the secondary element(s) is at least one of: i) a soluble salt of the secondary element(s) in the electrolyte; ii) an enrichment of the surface of the substrate metal with secondary element(s) prior to PEO processing; and iii) a suspension of the secondary element(s) or oxide(s) of the secondary element(s) applied to the oxide of the metal after this has been formed by the PEO process.Type: GrantFiled: April 29, 2014Date of Patent: September 19, 2017Assignee: Keronite International LimitedInventors: James Curran, Stephen Hutchins, Oleg Dunkin
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Patent number: 8754148Abstract: The present invention provides a method for producing a pigment composition for a printing ink, which involves the step of dry-milling crude copper phthalocyanine using calcium carbonate having a specific property; a pigment composition for a printing ink; and a method for producing a printing ink using the pigment composition. Specifically, the present invention provides a method for producing a pigment composition for a printing ink, which involves the step of dry-milling crude copper phthalocyanine and calcium carbonate having a primary particle diameter of 20 to 1500 nm in the absence of a resin for a printing ink; a pigment composition produced by the method; and a method for producing a printing ink, which includes the steps of heating a mixture of a pigment composition, a resin for a printing ink and a solvent for the printing ink, and wet-milling the heated mixture.Type: GrantFiled: December 19, 2008Date of Patent: June 17, 2014Assignee: DIC CorporationInventors: Yoshiharu Ootoshi, Masayoshi Takahashi, Yuuichi Ayuta
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Patent number: 8409343Abstract: An organic-inorganic hybrid pigment composition is provided comprising an organic pigment, an inorganic pigment, and a fibrous clay. The fibrous clay can be selected from palygorskite, sepiolite, or a combination thereof. The inorganic pigment is selected from rutile pigments, spinel pigments, bismuth vanadate pigments, cerium sulfide pigments, and combinations thereof. The organic pigment is selected from anthraquinone pigments, anthrathrone pigments, anthrapyrimidine pigments, azo pigments, azomethine pigments, quinacridone pigments, quinophthalone pigments, diketopyrrolopyrrol pigments, inanthrone pigments, isoindoline pigments, metal complex pigments, perinone pigments, perylene pigments, phthalocyanine pigments, pyranthrone pigments, pyrazolo-quinazolone pigments, thioindigo pigments, and combinations thereof.Type: GrantFiled: January 21, 2009Date of Patent: April 2, 2013Assignee: Mayan Pigments, Inc.Inventors: Lori A. Niewold, Robyn Torres, Gary E. Williams
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Patent number: 8337610Abstract: A pigment dispersion containing milled particles of near infrared (NIR) absorbing pigment and an anionic surfactant of asymmetric structure as dispersant for the pigment, and a milling method for making the same are disclosed.Type: GrantFiled: September 30, 2009Date of Patent: December 25, 2012Assignee: Hewlett-Packard Development Company, L.P.Inventors: Jayprakash Bhatt, Hichang Yoon, Vladek Kasperchik
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Patent number: 8226761Abstract: A method of modifying a pigment that includes reacting a reactive compound having an X—[Y]n reactive group with a secondary compound N—S—ZM to form a substituted reactive intermediate [Y]a—X—(N—S—ZM)b. A pigment is reacted with the substituted reactive intermediate [Y]a—X—(N—S—ZM)b to attach the substituted reactive intermediate to the surface of the pigment to form a surface modified pigment. X may be a sulfonyl, phosphoryl, or 1,3,5-triazinyl group, Y may be a halogen leaving group, N may be a basic nucleophilic group, S may be an organic group, and ZM may be an ionizable end group. Also, n is an integer between 1 and 3, b is an integer between 1 and 3, and a=n?b. When n is equal to or greater than b, and if b is 2 or 3, each N—S—ZM can be the same or different.Type: GrantFiled: January 20, 2012Date of Patent: July 24, 2012Assignee: Sensient Colors LLCInventors: Puthalath K. Sujeeth, John P. Kane, Daniel A. Ouellette, Mark Ulrich, Vincent Shing, Michael Bogomolny
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Patent number: 8152915Abstract: The invention pertains to a novel, simpler dry-milling method for comminuting crude pigments (especially crude phthalocyanines) for use in publication gravure and packaging inks, wherein the crude pigment is dry-milled at relatively low temperature in combination with a resin and a pigment derivative, preferably further together with an extender and optionally an antioxidant. The invention also pertains to the thus obtained, new compositions, which are extraordinarily easily dispersible in aromatic solvents, and their use for the preparation of publication gravure or packaging inks or ink concentrates. Pigment dispersions obtained from the preferred compositions are also claimed.Type: GrantFiled: August 25, 2006Date of Patent: April 10, 2012Assignee: BASF SEInventors: Thomas Healy, Ian Andrew Lambie
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Patent number: 8147608Abstract: A method of producing a modified pigment by sulfonating a pigment and subsequently oxidizing the pigment. The modified pigment may have sulfonic acid and carboxyl surface modifying groups attached to the surface of the pigment. Charge balancing counterions such as alkali metals, alkaline earth metals and NR1R2R3H+, where R1, R2 and R3 are independently H or C1-C5 alkyl groups, may be associated with the surface modifying groups. The modified pigment is combined with water to produce a dispersion that can be used in such applications as coatings, paints, papers, adhesives, latexes, toners, textiles, fibers, plastics and inks.Type: GrantFiled: March 8, 2011Date of Patent: April 3, 2012Assignee: Sensient Colors LLCInventors: Puthalath K. Sujeeth, Mark Ulrich, Gabe Srouji, John P. Kane, Daniel A. Ouellette
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Patent number: 8123851Abstract: A method of finishing an organic pigment by dry-comminuting said pigment in the presence of a sulfonato-functional condensation product of an arylsulfonic acid and at least one aliphatic aldehyde having 1 to 6 C atoms as crystallization modifier, dispersing the resulting mixture of pigment and crystallization modifier in mineral acid, and swelling the pigment in the presence of the crystallization modifier in mineral acid.Type: GrantFiled: July 30, 2008Date of Patent: February 28, 2012Assignee: BASF SEInventors: Joachim Jesse, Matthias Klueglein, Richard Van Gelder, Wolfgang Best
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Patent number: 8118924Abstract: A method of modifying a pigment that includes reacting a reactive compound having an X—[Y]n reactive group with a secondary compound N—S—ZM to form a substituted reactive intermediate [Y]a—X—(N—S—ZM)b. A pigment is reacted with the substituted reactive intermediate [Y]a—X—(N—S—ZM)b to attach the substituted reactive intermediate to the surface of the pigment to form a surface modified pigment. X may be a sulfonyl, phosphoryl, or 1,3,5-triazinyl group, Y may be a halogen leaving group, N may be a basic nucleophilic group, S may be an organic group, and ZM may be an ionizable end group. Also, n is an integer between 1 and 3, b is an integer between 1 and 3, and a=n?b. When n is equal to or greater than b, and if b is 2 or 3, each. N—S—ZM can be the same or different.Type: GrantFiled: May 17, 2011Date of Patent: February 21, 2012Assignee: Sensient Colors LLCInventors: Puthalath K. Sujeeth, John P. Kane, Daniel A. Ouellette, Mark Ulrich, Vincent Shing, Michael Bogomolny
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Publication number: 20110226160Abstract: A method of finishing an organic pigment by dry-comminuting said pigment in the presence of a sulfonato-functional condensation product of an arylsulfonic acid and at least one aliphatic aldehyde having 1 to 6 C atoms as crystallization modifier, dispersing the resulting mixture of pigment and crystallization modifier in mineral acid, and swelling the pigment in the presence of the crystallization modifier in mineral acid.Type: ApplicationFiled: July 30, 2008Publication date: September 22, 2011Applicant: Basf SEInventors: Joachim Jesse, Matthias Klueglein, Richard Van Gelder, Wolfgang Best
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Patent number: 7999017Abstract: A cationic dispersion which includes at least one pigment, water, and at least one quaternary salt of a styrene maleimide imide resin in an amount effective to disperse the organic pigment. A method for preparing the cationic dispersion includes (i) mixing, at 500 to 10,000 rpm, at least one pigment; water; and either (a) at least one a quaternary salt of a styrene maleimide imide resin or (b) at least one styrene maleimide imide resin in combination with at least one weak acid, thereby forming a dispersion premix; (ii) milling the dispersion premix in a mixer filled with ceramic, metal or glass beads for a period of time sufficient to reduce pigment agglomerates to primary particles, thereby forming a non-standardized dispersion; and (iii) standardizing the dispersion against a color standard by adding water. The resulting cationic dispersion exhibits good alkali resistance and lightfastness, and can be used to integrally color concrete and other building materials.Type: GrantFiled: May 12, 2010Date of Patent: August 16, 2011Assignee: Sun Chemical CorporationInventors: Hans Rasmusen, Jorn R. Thorsson, James E. Moore, Charles W. Perry, Joseph LaBazzo, Sr.
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Patent number: 7993447Abstract: A pigment dispersed liquid prepared by heat-treating an aqueous pigment dispersion containing a self-dispersing pigment, but not a dispersing resin.Type: GrantFiled: March 1, 2006Date of Patent: August 9, 2011Assignee: Seiko Epson CorporationInventors: Masaaki Itano, Miharu Kanaya, Chie Saito
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Patent number: 7964033Abstract: A method of modifying a pigment that includes reacting a reactive compound having an X-[Y]n reactive group with a secondary compound N-S-ZM to form a substituted reactive intermediate [Y]a-X-(N-S-ZM)b. A pigment is reacted with the substituted reactive intermediate [Y]a-X-(N-S-ZM)b to attach the substituted reactive intermediate to the surface of the pigment to form a surface modified pigment. X may be a sulfonyl, phosphoryl, or 1,3,5-triazinyl group, Y may be a halogen leaving group, N may be a basic nucleophilic group, S may be an organic group, and ZM may be an ionizable end group. Also, n is an integer between 1 and 3, b is an integer between 1 and 3, and a=n?b. When n is equal to or greater than b, and if b is 2 or 3, each N-S-ZM can be the same or different.Type: GrantFiled: August 22, 2008Date of Patent: June 21, 2011Assignee: Sensient Colors LLCInventors: Puthalath K. Sujeeth, John P. Kane, Daniel A. Ouellette, Mark Ulrich, Vincent Shing, Michael Bogomolny
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Patent number: 7927416Abstract: A method of producing a modified pigment by sulfonating a pigment and subsequently oxidizing the pigment. The modified pigment may have sulfonic acid and carboxyl surface modifying groups attached to the surface of the pigment. Charge balancing counterions such as alkali metals, alkaline earth metals and NR1R2R3H+, where R1, R2 and R3 are independently H or C1-C5 alkyl groups, may be associated with the surface modifying groups. The modified pigment is combined with water to produce a dispersion that can be used in such applications as coatings, paints, papers, adhesives, latexes, toners, textiles, fibers, plastics and inks.Type: GrantFiled: October 31, 2007Date of Patent: April 19, 2011Assignee: Sensient Colors Inc.Inventors: Puthalath K. Sujeeth, Mark Ulrich, Gabe Srouji, John P. Kane, Daniel A. Ouellette
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Patent number: 7914615Abstract: A process for continuous flush of a pigment press cake involves applying a dispersant to the press cake to produce a fluidized press cake, continuously feeding the fluidized press cake into a twin screw extruder and mixing it with a neutralizing agent in the extruder, mixing the neutralized press cake with a liquid organic medium in the extruder to produce an organic flush phase and a water phase, and removing at least part of the water phase from the extruder through one or more parts of the extruder.Type: GrantFiled: May 1, 2006Date of Patent: March 29, 2011Assignee: Sun Chemical CorporationInventor: George H. Robertson
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Patent number: 7905952Abstract: The invention pertains to pigment compositions comprising from 70 to 93%, preferably from 81 to 93%, of e copper phthalocyanine, from to 18% of an aminomethyl-substituted phthalocyanine, from 2 to 15% of an ammonium sulfonato phthalocyanine and less than 2% of other phthalocyanine compounds, preferably 5 made by wet-milling a mixture of a copper phthalocyanine and e copper phthalocyanine together with the aminomethyl-substituted phthalocyanine and a milling aid in an organic liquid and adding the ammonium sulfonato phthalocyanine before the milling aid and the organic liquid are separated from the wet-milled mixture.Type: GrantFiled: January 28, 2008Date of Patent: March 15, 2011Assignee: BASF SEInventors: HyeonKook Lee, JangWon Jung, Takashi Deno, Masaki Ohwa
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Publication number: 20110011307Abstract: The present invention relates to a method of preparing a modified colored pigment comprising a pigment having attached at least one organic group. The method comprises the step of combining, in any order, a) a solution of an organic colorant in a solvent, b) at least one aromatic amine comprising the organic group, c) at least one diazotizing agent, d) an aqueous medium, e) optionally at least one acid, and f), optionally at least one second solvent, to form the modified colored pigment.Type: ApplicationFiled: July 21, 2010Publication date: January 20, 2011Inventors: Alexander I. Shakhnovich, Yuan Yu, Friedrich K. von Gottberg
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Publication number: 20100331460Abstract: The present invention provides a method for producing a pigment composition for a printing ink, which involves the step of dry-milling crude copper phthalocyanine using calcium carbonate having a specific property; a pigment composition for a printing ink; and a method for producing a printing ink using the pigment composition. Specifically, the present invention provides a method for producing a pigment composition for a printing ink, which involves the step of dry-milling crude copper phthalocyanine and calcium carbonate having a primary particle diameter of 20 to 1500 nm in the absence of a resin for a printing ink; a pigment composition produced by the method; and a method for producing a printing ink, which includes the steps of heating a mixture of a pigment composition, a resin for a printing ink and a solvent for the printing ink, and wet-milling the heated mixture.Type: ApplicationFiled: December 19, 2008Publication date: December 30, 2010Applicant: DIC CORPORATIONInventors: Yoshiharu Ootoshi, Masayoshi Takahashi, Yuuichi Ayuta
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Patent number: 7819967Abstract: A method of producing a dispersion of organic fine particles having a volume average particle diameter (Mv) of 10 nm to 100 nm, which has the step of: subjecting an organic fine particle dispersion liquid containing a high molecular compound to heating treatment under flowing through a channel.Type: GrantFiled: November 5, 2008Date of Patent: October 26, 2010Assignee: Fujifilm CorporationInventors: Hirokazu Kyota, Hideki Maeta
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Patent number: 7794536Abstract: A method is provided for pigment dispersion. The method includes preparing a solution in which the pigment is dissolved in an organic acid, preparing a reaction liquid capable of decreasing the solubility of the pigment in the solution, and mixing the solution and the reaction liquid in the presence of an additive represented by a General Formula (1) below, CmH2m+1(OCH2CH2)nOH??(1) wherein m is an integer higher than 14 and lower than 18, and n is an integer equal to or higher than 15 and equal to or lower than 25.Type: GrantFiled: October 20, 2008Date of Patent: September 14, 2010Assignee: Canon Kabushiki KaishaInventors: Takayuki Teshima, Tetsuo Hino
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Patent number: 7780780Abstract: According to the method of producing organic pigment fine particles of the present invention, when producing organic pigment fine particles by allowing two or more solutions at least one of which is an organic pigment solution in which an organic pigment is dissolved to flow through a microchannel, the organic pigment solution flows through the microchannel in a non-laminar state. Accordingly, the contact area of solutions per unit time can be increased and the length of diffusion mixing can be shortened, and thus instantaneous mixing of solutions becomes possible. As a result, nanometer-scale monodisperse organic pigment fine particles can be produced in a stable manner.Type: GrantFiled: June 9, 2006Date of Patent: August 24, 2010Assignee: FUJIFILM CorporationInventors: Hideharu Nagasawa, Yuki Shimizu
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Patent number: 7722715Abstract: A process for the preparation of pigment compositions which give improved ink flow is provided which comprises treating the pigment, during the pigment synthesis, with a small amount of a long chain aliphatic amine. The pigment compositions obtained can be used for preparing millbase inks which due to their improved flow viscosity (rheology) at high pigmentation can be easily handled as well as flexibly formulated, e.g. a number of final printing inks for different ink applications can be manufactured from a single millbase in a very economical manner. The final inks are preferably used in packaging gravure printing processes.Type: GrantFiled: March 30, 2005Date of Patent: May 25, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Stephen Haggata, Iain Frank Fraser, Stephen John Coughlin
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Patent number: 7682443Abstract: An organic-pigment aqueous dispersion, containing a pigment at a concentration of 6 to 30 mass %, and having a haze of 0.3 to 10%, as determined by enclosing the dispersion in a transparent glass cell of optical distance 0.2 mm and analyzing with integrating-sphere photoelectric photometry; and a colored coating composition using the same.Type: GrantFiled: April 11, 2008Date of Patent: March 23, 2010Assignee: Fujifilm CorporationInventors: Tadahisa Sato, Hideki Maeta, Jun Tanabe, Hirokazu Kyota
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Patent number: 7658793Abstract: The invention relates to a pigment preparation based on at least one inorganic pigment and at least one organic pigment, and to a method for producing one such pigment preparation. Said pigment preparation contains particles wherein fine organic pigment particles are combined with inorganic pigment particles, said particles also being provided with an organic macromolecular coating. The inventive pigment preparation is produced by wet-grinding the inorganic and organic pigments, optionally adding other constituents, in the presence of a surface-active substance in the form of a macromolecular organic compound.Type: GrantFiled: March 5, 2004Date of Patent: February 9, 2010Assignee: Heubach GmbHInventors: Rainer Heubach, Yvonne Brussaard, Hugo Brussaard
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Patent number: 7628849Abstract: Fluorinated bis-(phthalocyanylaluminoxy)silyl bridged cyan or blue-green pigments according to formula (I): wherein R1 and R2 are independently substituted or unsubstituted alkyl, alkenyl, alkynyl, or cycloalkyl groups with eight or less carbon atoms or aryl groups with ten or less carbon atoms; R3 is a divalent linking group comprising oxygen, R1R2Si, substituted or unsubstituted alkyl, alkenyl, alkynyl cycloalkyl or aryl groups; R1, R2, and R3 may comprise the elements of a cyclic ring; n is 1-4; and z is 1-4.Type: GrantFiled: October 29, 2008Date of Patent: December 8, 2009Assignee: Eastman Kodak CompanyInventors: Donald R. Diehl, Tommie L. Royster, Jr., Andrew J. Hoteling, Steven G. Link
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Patent number: 7611572Abstract: A pixel-forming colorant composition contains at least one green colorant selected from the group consisting of the following pigments (A) and (B) and pigment derivative (C): (A) a copper phthalocyanine green pigment obtained by reacting at least one of a phthalic acid substituted on average with from 3.5 to 4.Type: GrantFiled: March 15, 2006Date of Patent: November 3, 2009Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.Inventors: Atsushi Nogami, Takami Minami, Shigeru Sakamoto, Hisao Okamoto, Yoshimasa Tsuchiya, Masanori Takakamo, Nakaji Komiyama, Michiei Nakamura
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Patent number: 7585363Abstract: A method for preparing a nanodispersion comprising the steps of: (i) introducing into a milling apparatus a solid fluorinated phthalocycanine pigment according to Formula (I): Wherein M is a metal cation chosen from Groups 1b, 2b, 2a or 3a of the Periodic Table of the Elements; R is fluorine, a perfluoroalkyl or a perfluoroaryl group; z is 1 to 4; L is an anionic ligand; and n is 0 or 1 such that the overall charge on the molecular unit is neutral; followed by milling with agitation the solid fluorinated phthalocyanine in an organic solvent into a suspension of particles so that at least 80 volume % of the particles have a particle size of less than 100 nm.Type: GrantFiled: October 29, 2008Date of Patent: September 8, 2009Assignee: Eastman Kodak CompanyInventors: Tommie L. Royster, Jr., Marina E. Kondakova, Peter G. Bessey
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Patent number: 7578880Abstract: A method of producing fine particles of metal complex pigment, containing the step of reacting a solution of an alkali metal salt of a ligand that constitutes the metal complex with a solution of salts of a metal that constitutes the metal complex, in the course of a laminar flow in a channel; and a method of producing fine particles of metal complex pigment, containing the step of bringing a solution of an alkali metal salt of a ligand that constitutes the metal complex and a solution of salts of a metal that constitutes the metal complex into contact with each other in a channel having an equivalent diameter of 1 mm or less to form a liquid flow.Type: GrantFiled: September 5, 2006Date of Patent: August 25, 2009Assignee: FUJIFILM CORPORATIONInventors: Tadahisa Sato, Jun Tanabe, Hideki Maeta
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Patent number: 7569106Abstract: The invention relates to a method for producing an aqueous suspension of pure-phase ?-copper phtalocyanine blue pigment using an agitator ball mill. According to said method: a) in a preparatory step, a phthalocyanine crude blue is suspended by means of a dissolver in an aqueous medium, said aqueous medium containing in particular lipophilic substances, which are similar to binding agents and are compatible with the final application medium and crystalline-phase controlling and/or pigment-surface conditioning compounds; b) said aqueous suspension of the phthalocyanine crude blue is ground in an agitator ball mill to form a suspension of a ?-phtalocyanine blue pigment. The aqueous suspension thus obtained is characterized in that it contains a high-grade ?-phtalocyanine blue pigment for producing a conditioned ?-phtalocyanine blue pigment. The advantage is that said suspension can also be directly converted into a colour concentrate, in particular by means of a flushing and kneading method.Type: GrantFiled: June 16, 2005Date of Patent: August 4, 2009Assignee: Colour Ltd.Inventors: Rainer Heubach, Dieter Lieske
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Patent number: 7550041Abstract: The invention pertains to a highly concentrated pigment comprising from 75 to 95% by weight, preferably from 78 to 95% by weight, most preferred from 80 to 95% by weight, based on the weight of the composition, of a pigment; from 0 to 20% by weight, preferably from 5 to 18% by weight, based on the weight of the composition, of a resin; the total of pigment and resin being from 85 to 98% by weight of the composition; and from 1 to 15% by weight, preferably from 2 to 15% by weight, most preferably from 5 to 15% by weight, based on the weight of the composition, of a C10-C18 alcohol, a liquid hydrocarbon having a boiling point higher than 80° C. at 105 Pa, or both a C10-C18 alcohol and a liquid hydrocarbon having a boiling point higher than 80° C. at 105 Pa. Also claimed are a process for its manufacture, comprising dry-milling, blending and kneading the components, and the use of the pigment concentrates for the preparation of a masterbatch, ink, coating, plastic material, toner or colour filter.Type: GrantFiled: October 24, 2005Date of Patent: June 23, 2009Assignee: Ciba Specialty Chemicals CorporationInventors: Thomas Healy, Lynda Cannon, Tracy Murray
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Patent number: 7503972Abstract: Two or more solutions comprising an organic pigment solution in which an organic pigment is dissolved in a good solvent, and a poor solvent compatible with the good solvent, or a solution of the poor solvent are allowed to flow through a microchannel in a non-laminar state; and organic pigment fine particles are deposited from the organic pigment solution in a course of flowing through the microchannel by changing the solubility of the organic pigment solution with the poor solvent or the solution of the poor solvent. As a result, nanometer-scale monodisperse organic pigment fine particles can be produced in a stable manner.Type: GrantFiled: October 1, 2007Date of Patent: March 17, 2009Assignee: FUJIFILM CorporationInventors: Hideharu Nagasawa, Masato Nakao
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Patent number: 7459016Abstract: A method for the production of a phthalocyanine pigment preparation includes finely distributing a crude phthalocyanine pigment by dry milling, wet milling, salt kneading, acid pasting or acid swelling to give a pre-pigment, the pre-pigment is subjected to a finishing treatment in a mixture of water and an organic solvent at alkaline pH, increased temperature and in the presence of at least one pigment dispersant from the group of phthalocyanine sulphonic acids, phthalocyanine carboxylic acids, phthalocyanine sulphonate salts, phthalocyanine carboxylate salts and phthalocyanine suiphonamides.Type: GrantFiled: November 27, 2003Date of Patent: December 2, 2008Assignee: Clariant Produkte (Deutschland) GmbHInventors: Klaus Brychcy, Joachim Weber, Heidrun Mehler
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Patent number: 7459017Abstract: Disclosed is a composition and process of manufacture of a stir-in form of pigment with increased dispersing and color properties. Pigment is slurried with acetylenic dispersing agents, wet-milled to a particular particle size, and then dried to powder or granulate form. Also disclosed is a process for producing a pigmented paint composition from the stir-in pigment.Type: GrantFiled: November 15, 2006Date of Patent: December 2, 2008Assignee: Sun Chemical CorporationInventors: Mark Ortalano, Darleen Wright, William Burgess, Brian Thompson
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Patent number: 7427322Abstract: A method of producing a dispersion of a pigment, comprising: bringing a solution in which an organic pigment is dissolved, and an aqueous medium, into contact with each other in a channel having an equivalent diameter of 1 mm or less, thereby making the pigment into a fine particle thereof, wherein at least one of the solution and the aqueous medium comprises at least one anionic dispersing agent.Type: GrantFiled: August 13, 2007Date of Patent: September 23, 2008Assignee: FUJIFILM CorporationInventors: Hideki Maeta, Yuki Shimizu, Tadahisa Sato
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Method for pigmenting semi-crystalline plastics with phthalocyanine pigments in a non-warping manner
Patent number: 7404854Abstract: A process for warpage-free pigmentation of a plastic pigmented by a phthalocyanine pigment which was heated to not less than 80° C. as a suspension in a organic solvent in the presence of a carboxylic acid containing 2, 3 or 4 carboxyl groups or a salt of such a carboxylic acid.Type: GrantFiled: August 7, 2004Date of Patent: July 29, 2008Assignee: Clariant Produkte (Deutschland) GmbHInventors: Matthias Ganschow, Carsten Plueg, Hans Joachim Metz -
Patent number: 7399354Abstract: Dispersible pigment granules are produced by mixing an aqueous suspension of an organic pigment with an aqueous emulsion of a wax-like additive. The aqueous emulsion is then allowed to coagulate and the resulting aqueous dispersion is spray dried.Type: GrantFiled: April 27, 2002Date of Patent: July 15, 2008Assignee: Clariant Produkte (Deutschland) GmbHInventors: Hans Joachim Metz, Andreas Stohr, Heinfred Ohleier
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Patent number: 7387670Abstract: A pigment preparation comprising at least one copper phthalocyanine pigment from the group of C.I. Pigment Blue 15, 15:0, 15:1,15:2, 15:3, 15:4, and 15:6, and at least one pigment dispersant of the formula (I), in which n is a number 1, 2, 3 or 4.Type: GrantFiled: February 22, 2005Date of Patent: June 17, 2008Assignee: Clariant Produkte (Deutschland) GmbHInventors: Joachim Weber, Manfred Opravil, Magali Meder, Hans-Tobias Macholdt
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Publication number: 20080035026Abstract: Phthalocyanine pigments having 0-4 chlorine atoms have a narrow particle-size range with 90% of particles between about 0.01-0.10 ?m, the average particle size of no more than about 0.5 ?m, a D99 of no more than about 0.3 ?m, and a polydispersity of about 2.0 or less. Pigment compositions contain the phthalocyanine pigment and water-based dispersing resin. The pigments and the compositions are compatible with waterborne coating systems, exhibit an excellent metallic down travel, and are especially useful for the automotive painting applications.Type: ApplicationFiled: August 9, 2006Publication date: February 14, 2008Applicant: Sun Chemical CorporationInventors: Bethany J. Wolf, Brian Thompson, Wengan Wu, Richard K. Faubion
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Patent number: 7329315Abstract: Phthalocyanine blue pigments and pigment dispersions for water-borne inks and coatings are described. The pigments are produced by dry milling phthalocyanine blue and a polymeric dispersant, optionally with inorganic fillers and other additives, to obtain a material with improved coloristic, rheological, and stability properties. The resulting activated crude is then processed directly into water-based pigment dispersion with additives and/or surfactants to facilitate conversion to pigmentary form while maintaining the desirable green and clean shade.Type: GrantFiled: December 11, 2006Date of Patent: February 12, 2008Assignee: Sun Chemical CorporationInventors: Stanislav Vilner, Tatiana N. Romanova, Mark Ortalano, George H. Robertson, Russell J. Schwartz
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Patent number: 7323046Abstract: Phthalocyanine pigments having 0-4 chlorine atoms have a narrow particle-size range with 90% of particles between about 0.01-0.10 ?m, the average particle size of no more than about 0.5 ?m, a D99 of no more than about 0.3 ?m, and a polydispersity of about 2.0 or less. Pigment compositions contain the phthalocyanine pigment and water-based dispersing resin. The pigments and the compositions are compatible with waterborne coating systems, exhibit an excellent metallic down travel, and are especially useful for the automotive painting applications.Type: GrantFiled: August 9, 2006Date of Patent: January 29, 2008Assignee: Sun Chemical CorporationInventors: Bethany J. Wolf, Brian Thompson, Wengan Wu, Richard K. Faubion
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Patent number: 7309391Abstract: An aluminum flake pigment containing aluminum flakes as basic particles, said aluminum flakes having an average particle diameter in the range of 3 to 20 ?m and an average value of minimum diameter/maximum diameter of at least 0.6.Type: GrantFiled: February 16, 2004Date of Patent: December 18, 2007Assignee: Toyo Aluminium Kabushiki KaishaInventor: Keita Nagano
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Patent number: 7282263Abstract: A method of coloring a cellulosic material which includes a) dispersing pulped cellulosic material into water; and b) coloring the pulped cellulosic material by adding a cationic dispersion to the water, where the dispersion includes: (i) at least one pigment; (ii) water; and (iii) at least one acid salt of a styrene maleimide resin in an amount effective to disperse the pigment. The cationic dispersion may be prepared by (i) mixing, at 500 to 10,000 rpm, at least one pigment; water; and either (a) at least one acid salt of a styrene maleimide imide resin or (b) at least one styrene maleimide imide resin in combination with at least one weak acid, thereby forming a dispersion premix; (ii) milling the dispersion premix in a mixer filled with ceramic, metal or glass beads for a period of time sufficient to reduce pigment agglomerates to primary particles, thereby forming a nonstandarized dispersion; and (iii) standardizing the dispersion against a color standard by adding water.Type: GrantFiled: May 17, 2002Date of Patent: October 16, 2007Assignee: Sun Chemical CorporationInventors: Hans Rasmusen, Jorn R. Thorsson, James E. Moore, Charles W. Perry, Joseph P. LaBazzo
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Patent number: 7255733Abstract: A process for the production of a ? type copper phthalocyanine pigment, comprising dry-milling a crude copper phthalocyanine having a purity of 97 to 100% and a primary crystal diameter of 0.5 to 100 ?m at a temperature of 180 to 50° C., to prepare an ?/? mixed crystal type copper phthalocyanine having an ? ratio of 5 to 35%, and treating the dry-milled product with a water-miscible organic solvent, wherein 0.1 to 20% by weight of at least one compound selected from the group consisting of a compound of the formula (1), a compound of the formula (2) and a compound of the formula (3) is added to the dry-milled product before, during or after the step (B) MePc—{X—(CH2)kNR1R2}n??(1) MePc—(SO3?N+R5R6R7R8)p.Type: GrantFiled: June 18, 2004Date of Patent: August 14, 2007Assignee: Toyo Ink Mfg. Co., Ltd.Inventors: Osamu Shiromaru, Yusaku Ide, Toshio Oshiba, Takuya Kotani
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Patent number: 7255734Abstract: A copper phthalocyanine pigment preparation contains a copper phthalocyanine pigment and at least one pigment dispersant from the group of copper phthalocyanine sulfonic acids and copper phthalocyanine sulfonic acid salts. The inventive pigment preparation is characterized by a) a maximum dynamic viscosity of 180 mPas and/or a maximum thixotropy of 800 Pa/s, the dynamic viscosity and the thixotropy being determined by a rotary viscometer at a temperature of 23° C. in a pigment dispersion comprising 28 percent by weight of dry copper phthalocyanine pigment preparation, 9 percent by weight of nitrocellulose, 62.3 percent by weight of ethanol, and 0.7 percent by weight of ethyl acetate; and b) a color intensity such that a printing ink consisting of an ethanol/nitrocellulose gravure varnish, containing 75 to 65 percent by weight of ethanol and 9 to 11 percent by weight of nitrocellulose at a ratio of 2 to 7.5, and a maximum amount of dry copper phthalocyanine pigment preparation of 6.Type: GrantFiled: December 4, 2003Date of Patent: August 14, 2007Assignee: Clariant Produkte (Deutschland) GmbHInventors: Klaus Brychcy, Joachim Weber
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Patent number: 7198667Abstract: Solid pigment preparations containing the following ingredients as substantial components: (A) 60–85 wt. % of at least one organic pigment, (B) 0.1–15 wt.Type: GrantFiled: November 28, 2003Date of Patent: April 3, 2007Assignee: BASF AktiengesellschaftInventors: Ingo Klopp, Juan Antonio Gonzalez Gomez, Uwe Mauthe, Hansulrich Reisacher, Andreas Stohr
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Patent number: 7192477Abstract: The process for producing highly concentrated nanometer-size fine particles of an organic pigment, which comprises dissolving the organic pigment in an amide solvent, especially an organic solvent comprising at least 50 vol % 1-methyl-2-pyrrodinone, and pouring the resultant organic pigment solution with stirring into a poor solvent which is not compatible with the organic pigment. The pigment may be a quinacridone pigment, phthalocyanine pigment etc. Any atmospheric pressure to a sub-critical and/or supercritical state can be employed as the production conditions.Type: GrantFiled: April 2, 2003Date of Patent: March 20, 2007Assignee: Japan Science and Technology AgencyInventors: Hachiro Nakanishi, Koich Baba, Hitoshi Kasai, Hidetoshi Oikawa, Shuji Oikawa