Mica, Shell, Scale, Platelet, Or Lamellate Patents (Class 106/415)
  • Patent number: 8900660
    Abstract: Disclosed is a method for producing a silver (Ag) coating pigment. The method for producing a silver coating pigment according to the present invention comprises: a step of forming a tin compound pretreatment layer on the matrix surface; and a step of forming a silver coating layer on the lower portion of the tin compound pretreatment layer through a reflux and electroless plating process using a diluted solution of silver nitrate, ammonia water, a citric acid solution, and a diluted solution of potassium hydroxide.
    Type: Grant
    Filed: April 12, 2012
    Date of Patent: December 2, 2014
    Assignee: CQV Co., Ltd.
    Inventors: Dong-Min Heo, Jae-Il Jeong, Kwang-Choong Kang, Byung-Ki Choi, Kwang-Soo Lim, Kil-Wan Chang, Man-Su Lee, Gun-Eik Jang
  • Publication number: 20140349009
    Abstract: A bright pigment of the present invention is a bright pigment including flaky particles and a metal oxide layer covering each surface of the flaky particles. The metal oxide layer has a thickness variation coefficient (standard deviation of thickness of the metal oxide layer/average thickness of the metal oxide layer) of 20% or less. The bright pigment preferably contains a sodium component, and the sodium component is Na2O. The content of Na2O in the flaky particles is 3% by mass or more and less than 9.5% by mass. The bright pigment preferably has a specific surface area of 5.0 m2/g or less.
    Type: Application
    Filed: December 7, 2012
    Publication date: November 27, 2014
    Applicant: Nippon Sheet Glass Company, Limited
    Inventor: Takeaki Kitamura
  • Publication number: 20140335348
    Abstract: A bright pigment of the present invention is a bright pigment including flaky particles and a metal oxide layer covering each surface of the flaky particles. The bright pigment has a particle diameter corresponding to a 90% volume-cumulative particle diameter from a small particle diameter side, in a particle size distribution, of 55 ?m or less. The flaky particles are formed of a material having a refractive index of 1.4 to 1.8. The flaky particles have an average thickness of 0.35 to 0.55 ?m and substantially do not contain flaky particles having a thickness of 0.15 ?m or less.
    Type: Application
    Filed: December 7, 2012
    Publication date: November 13, 2014
    Inventor: Takeaki Kitamura
  • Patent number: 8882902
    Abstract: The present invention relates to a composite pigment comprising a substrate, said substrate being at least in part covered by at least one layer comprising at least one solid organic UV filter. The composite pigment can be prepared by a method comprising a step of subjecting a substrate, at least one solid organic UV filter, and optionally at least one solid inorganic UV filter, at least one additional UV filter and/or at least one coloring pigment, to a mechanochemical fusion process such as a hybridizer process. The composite pigment can be advantageously used as a component for a cosmetic composition.
    Type: Grant
    Filed: August 4, 2009
    Date of Patent: November 11, 2014
    Assignee: L'Oreal
    Inventors: Takahiro Suzuki, Takehiko Kasai
  • Publication number: 20140322534
    Abstract: The present invention relates to alumina flakes having a defined thickness and particle size distribution and to their use in varnishes, paints, automotive coatings printing inks, masterbatches, plastics and cosmetic formulations and as substrate for effect pigments. and organic dyes.
    Type: Application
    Filed: April 25, 2014
    Publication date: October 30, 2014
    Applicant: Merck Patent GmbH
    Inventors: Ryuta SUZUKI, Gerhard PFAFF, Sabine SCHOEN, Fumiko SASAKI, Satoru KOBAYASHI, Koshiro KUNII, Yuji TAKENAKA, Katsuhisa NITTA
  • Publication number: 20140322536
    Abstract: The present invention relates to alumina flakes having a defined thickness and particle size distribution and to their use in varnishes, paints, automotive coatings, printing inks, masterbatches, plastics and cosmetic formulations and as substrate for effect pigments.
    Type: Application
    Filed: April 29, 2014
    Publication date: October 30, 2014
    Applicant: MERCK PATENT GMBH
    Inventors: Ryuta SUZUKI, Gerhard PFAFF, Sabine SCHOEN, Noriyuki MATSUDA, Katsuhisa NITTA
  • Publication number: 20140275323
    Abstract: Oligomer-grafted nanofiller compositions and composites including oligomer-grafted nanofillers are disclosed. An oligomer-grafted nanofiller composition for disposition in a polymer matrix, the polymeric matrix comprising polymers derived from a plurality of polymerizable units, can include a nanoparticle, one or more coupling groups bonded to the nanoparticle; and one or more oligomers bonded to the one or more coupling groups. In an embodiment the oligomer is derived from two or more polymerizable units, at least one polymerizable unit being at least substantially similar to at least one of the polymerizable units of the polymer matrix. In another embodiment the oligomer comprises two or more polymerizable units and improves dispersion, interfacial strength, or both dispersion and interfacial strength between the nanoparticle and the polymer matrix. Composites and methods are also disclosed.
    Type: Application
    Filed: March 14, 2014
    Publication date: September 18, 2014
    Inventors: Francis R. Thibodeau, Yuqiang Qian, Andreas Stein, Christopher W. Macosko
  • Patent number: 8821627
    Abstract: The present invention relates to effect pigments based on substrates having an outer coating comprising metal oxide, hydroxide and/or oxide hydrate and at least one organic coupling agent.
    Type: Grant
    Filed: October 12, 2011
    Date of Patent: September 2, 2014
    Assignee: Merck Patent GmbH
    Inventor: Koshiro Kunii
  • Patent number: 8808447
    Abstract: The present invention relates to a pigment paint for an exterior material and to a method for manufacturing the same. The pigment paint comprises: a flake matrix, a first metal oxide layer coated on the upper portion of the transparent matrix, an oxide layer containing MgO—SiO2 coated on the upper portion of the first metal oxide layer, and a second metal oxide layer coated on the upper portion of the oxide layer. In order to ensure humidity resistance and weather resistance required for a lustrous pigment paint for exterior materials, a cerium layer and an aluminum oxide layer are further coated. Properties such as high luminance, high chromaticity, and high gloss, which could not be achieved using conventional techniques, can be achieved and a pigment paint having a multi-colored pearl luster can be provided.
    Type: Grant
    Filed: March 8, 2012
    Date of Patent: August 19, 2014
    Assignee: CQV Co., Ltd.
    Inventors: Jae-Il Jeong, Nam-Il Lee, Sang-Keun Park, Jin-Hyung Lee, Kwang-Choong Kang, Byung-Ki Choi, Kwang-Soo Lim, Kil-Wan Chang
  • Publication number: 20140165878
    Abstract: The interference pigment with high color intensity includes: a platelet-shaped substrate including at least one of natural mica, synthetic mica, alumina flakes, glass flakes, and iron oxide flakes; a lower first metal oxide layer formed of Fe2O3 on the platelet-shaped substrate; a second metal oxide layer formed of MgO.SiO2 on the lower first metal oxide layer; and an upper first metal oxide layer formed of Fe2O3 on the second metal oxide layer.
    Type: Application
    Filed: July 15, 2013
    Publication date: June 19, 2014
    Applicant: CQV CO., LTD.
    Inventors: Kil-Wan Chang, Kwang-Soo Lim, Byung-Ki Choi, Jin-Hyoung Lee
  • Patent number: 8728226
    Abstract: Multilayer pearlescent pigments comprising platelet-shaped transparent substrates provided with an optically active coating, where the optically active coating includes at least a) an absorbing high-index layer A having a refractive index n?1.8 b) a low-index layer B having a refractive index n<1.8 c) a high-index layer C having a refractive index n?1.8 and also d) optionally at least one outer protective layer D and where the multilayer pearlescent pigments have a cumulative frequency distribution of a volume-averaged size distribution function, with the indices D10, D50, D90 and a span ?D in a range from 0.7-1.4, the span ?D being calculated in accordance with formula (I) ?D=(D90?D10)/D50??(I). The disclosure further relates to a method for producing these multilayer pearlescent pigments, and also to their use.
    Type: Grant
    Filed: August 9, 2010
    Date of Patent: May 20, 2014
    Assignee: Eckart GmbH
    Inventors: Dirk Schumacher, Michael Grüner, Günter Kaupp
  • Patent number: 8728228
    Abstract: Multilayer pearlescent pigments based on platelet-shaped transparent substrates with an optically active coating, where the optically active coating includes at least a) a nonabsorbing high-index layer A having a refractive index n?1.8, b) a low-index layer B having a refractive index n<1.8 having an optical layer thickness >150 nm, c) an absorbing high-index layer C having a refractive index n?1.8 and also, d) optionally an outer protective layer D, wherein the multilayer pearlescent pigments have a cumulative frequency distribution of the volume-averaged size distribution function, with the indices D10, D50, D90 and a span ?D of 0.7-1.4, the span ?D being calculated in accordance with the formula ?D=(D90?D10)/D50. The disclosure further relates to a method for producing these multilayer pigments, and to their use.
    Type: Grant
    Filed: August 9, 2010
    Date of Patent: May 20, 2014
    Assignee: Eckart GmbH
    Inventors: Dirk Schumacher, Michael Grüner, Günter Kaupp
  • Patent number: 8715407
    Abstract: Multilayer pearlescent pigments comprising platelet-shaped transparent substrates provided with an optically active coating, where the coating includes at least (a) a nonabsorbing high-index layer A having a refractive index n?1.8, (b) a low-index layer B having a refractive index n<1.8, (c) a nonabsorbing high-index layer C having a refractive index n?1.8 and also (d) optionally at least one outer protective layer D where the pigments have a cumulative frequency distribution of a volume-averaged size distribution function, with the indices D10, D50, D90 and a span ?D in a range from 0.7-1.4, the span ?D being calculated in accordance with formula (I) ?D=(D90?D10)/D50??(I). The disclosure further relates to a method for producing these multilayer pearlescent pigments, and also to their use.
    Type: Grant
    Filed: August 9, 2010
    Date of Patent: May 6, 2014
    Assignee: Eckart GmbH
    Inventors: Dirk Schumacher, Michael Grüner, Günter Kaupp
  • Patent number: 8702861
    Abstract: An ink composition includes a water resistant aluminum pigment and water. The water resistant aluminum pigment is formed of an aluminum pigment and a covering film that contains Si and is formed on the surface of the aluminum pigment. A 50% average particle diameter of a corresponding circle obtained by calculation from areas of X-Y plain surfaces of the aluminum pigment is in a range from 0.5 pm to 3 pm. The coverage ratio of the covering film on the surface of the aluminum pigment, calculated from presence ratios of C, O, Al, and Si detected by XPS measurement at an incident angle of 30°, is in a range from 30% to 90%.
    Type: Grant
    Filed: November 13, 2012
    Date of Patent: April 22, 2014
    Assignee: Seiko Epson Corporation
    Inventors: Takayoshi Kagata, Tsuyoshi Sano, Toshimi Fukui, Saori Yamaki, Junko Nakamoto, Hideki Kawasaki
  • Patent number: 8697776
    Abstract: The invention relates to metallic effect pigments having a plateletlike metal core and, surrounding the plateletlike metal core, a homogeneous synthetic resin coating, the synthetic resin coating comprising polyacrylate and/or polymethacrylate and also organofunctional silane. The invention further relates to a process for preparing such metallic effect pigments, and to their use.
    Type: Grant
    Filed: February 7, 2008
    Date of Patent: April 15, 2014
    Assignee: Eckart GmbH
    Inventors: Dirk Schumacher, Thomas Schuster
  • Publication number: 20140090579
    Abstract: A colorant including a mixture of pigments is disclosed. The pigments have a similar coloration but different resistance to corrosion. The mixing ratio is selected to optimize the corrosion resistance against color brightness, and/or acidic corrosion resistance against alkali corrosion resistance of the colorant.
    Type: Application
    Filed: October 1, 2013
    Publication date: April 3, 2014
    Inventors: Cornelis Jan DELST, VLADIMIR P. RAKSHA, DAVID DE LA FUENTE
  • Publication number: 20140080952
    Abstract: A thermally conductive filler composition and a resin composition comprising such filler compositions. The filler composition comprises a blend of a boron nitride, a metal oxide, and a silane. The filler composition can further comprise other filler components including, for example, glass fiber or glass flake. The filler compositions can be added to a resin composition to provide a thermally conductive resin such as, for example, a thermally conductive plastic.
    Type: Application
    Filed: March 14, 2013
    Publication date: March 20, 2014
    Inventors: Chandrashekar Raman, Bei Xiang, Anand Murugaiah
  • Patent number: 8647429
    Abstract: The present invention relates to effect pigments based on uncoated or coated flake-form substrates having an outer coating comprising a) TiO2 and b) Al2O3, MgO and/or CaO and c) SiO2 and d) ZnO and/or e) at least one mixed oxide of the elements mentioned under a) to d), and to the use thereof, inter alia in paints, coatings, printing inks, plastics and cosmetic formulations.
    Type: Grant
    Filed: February 2, 2011
    Date of Patent: February 11, 2014
    Assignee: Merck Patent GmbH
    Inventors: Sabine Melson, Volker Wilhelm, Ulrich Schoenefeld
  • Publication number: 20140018439
    Abstract: The present invention relates to a weather-resistant pearlescent pigment which consists of a platelet-shaped substrate coated with one or more highly refractive metal oxides, the platelet-shaped substrate being selected from the group consisting of synthetic mica flakes, glass flakes, SiO2 flakes, Al2O3 flakes, synthetic boehmite flakes, BiOCl flakes and mixtures thereof, and a top layer, wherein the top layer consists of the following layers: a) a cerium-containing layer, selected from the group consisting of cerium oxide, cerium hydroxide, hydrated cerium oxide, and mixtures thereof, the cerium-containing layer being applied directly to the highly refractive metal oxide layer, and b) an organic-chemical compatibilizing layer, which comprises the reaction products of oligomeric silanes, wherein the oligomeric silanes have one or more amino groups, the organic-chemical compatibilizing layer being applied directly to the cerium-containing layer a).
    Type: Application
    Filed: March 28, 2012
    Publication date: January 16, 2014
    Applicant: ECKART GMBH
    Inventors: Michael Gruner, Thomas Schneider, Gunter Kaupp
  • Patent number: 8613800
    Abstract: The present invention relates to pigment preparations comprising one or more effect pigments in platelet form, at least one antioxidant and a wax or wax mixture, and to the use thereof for pigmentation of application media, especially paints, coating materials, powder coating materials, polymers, and for production of masterbatches.
    Type: Grant
    Filed: April 9, 2009
    Date of Patent: December 24, 2013
    Assignee: Merck Patent GmbH
    Inventors: Volker Wilhelm, Hans Jurgen Brehm
  • Patent number: 8585818
    Abstract: The present disclosure relates to a method of making coated perlite flakes comprises: (i) providing perlite flakes; (ii) applying a layer of tin oxide on the perlite flakes to obtain tin oxide coated perlite flakes; (iii) applying a layer titanium dioxide on the tin oxide coated perlite flakes obtained in step (ii) to obtain titanium dioxide and tin oxide coated perlite flakes; and (iv) applying a layer of iron oxide to the titanium dioxide and tin oxide coated perlite flakes to obtain the coated perlite flakes. The present disclosure also relates to coated perlite flakes comprising: perlite flakes with layer of tin oxide, then a layer of titanium dioxide, and then a layer of iron oxide.
    Type: Grant
    Filed: March 14, 2013
    Date of Patent: November 19, 2013
    Assignee: BASF SE
    Inventor: Steven Alan Jones
  • Patent number: 8574357
    Abstract: A water resistant aluminum pigment dispersion includes a water resistant aluminum pigment which is an aluminum pigment covered with a silica film, wherein the water resistant aluminum pigment is formed of an aluminum pigment having an average thickness from 5 nm to 30 nm and a covering film which contains Si and is formed on the surface of the aluminum pigment; and wherein the coverage ratio of the surface of the aluminum pigment by the covering film, calculated from the composition ratio of C, O, Al, and Si detected by XPS measurement at an incident angle of 30°, is in a range from 30% to 90%.
    Type: Grant
    Filed: April 6, 2010
    Date of Patent: November 5, 2013
    Assignee: Seiko Epson Corporation
    Inventors: Takayoshi Kagata, Tsuyoshi Sano, Toshimi Fukui, Saori Yamaki, Junko Nakamoto, Hideki Kawasaki
  • Patent number: 8568808
    Abstract: An intercalated layered silicate comprises a layered silicate and an intercalating agent sorbed between the silicate layers of the layered silicate. The amount of intercalating agent is effective to provide an average interlayer spacing between the silicate layers of at least about 20 ?. The intercalating agent has a formula selected from formulas I through VII described herein. The intercalated layered silicate may be exfoliated by mixing it with a matrix medium and adding sufficient energy to form a dispersed-particle composition. A packaging film, such as a food packaging film, may comprise the dispersed-particle composition.
    Type: Grant
    Filed: December 2, 2005
    Date of Patent: October 29, 2013
    Assignee: Cryovac, Inc.
    Inventors: Michael D. Grah, Michael L. Becraft, Drew V. Speer, Gary W. Beall, Jeremy Bartels
  • Patent number: 8500901
    Abstract: The present invention relates to interference pigments based on coated flake-form substrates which are distinguished by the fact in that they comprise (A) a layer of SiO2 having a layer thickness of 5-350 nm, (B) a high-refractive-index coating having a refractive index n of >1.8 and/or (C) an interference system consisting of alternating high- and low-refractive-index layers and optionally (D) an outer protective layer, and to the use thereof in paints, coatings, automotive paints, powder coatings, printing inks, security printing inks, plastics, ceramic materials, glasses, paper, in toners for electrophotographic printing processes, in seed, in greenhouse sheeting and tent awnings, as absorbers in the laser marking of paper and plastics, in cosmetic formulations, for the preparation of pigment pastes with water, organic and/or aqueous solvents, and for the preparation of pigment preparations and dry preparations.
    Type: Grant
    Filed: March 22, 2010
    Date of Patent: August 6, 2013
    Assignee: Merck Patent GmbH
    Inventors: Reinhold Rueger, Klaus Ambrosius, Marcus Mathias, Helge Bettina Kniess
  • Patent number: 8440014
    Abstract: The bright pigment of the present invention includes flaky particles and a metal oxide layer coating at least a part of the surface of each flaky particle. The bright pigment or the flaky particles of the present invention have a particle size distribution in which the particle size at 99% of the cumulative volume from the smaller particle size is 48 ?m or less, and the maximum particle size is 62 ?m or less. The flaky particles are made of a material having a refractive index in the range of 1.4 to 1.8. The flaky particles have a thickness distribution in which the frequency of the particles having a thickness in the range of 0.8 ?m to 1.9 ?m is 90% or more by volume, or the frequency of the particles having a thickness in the range of 0.01 ?m to 0.35 ?m is 90% or more by volume.
    Type: Grant
    Filed: April 28, 2008
    Date of Patent: May 14, 2013
    Assignee: Nippon Sheet Glass Company, Limited
    Inventors: Takeaki Kitamura, Takashi Wakamiya, Tomohiro Yagyu
  • Patent number: 8349067
    Abstract: A pearlescent pigment, wherein the pigment is an inorganic material and the color of a homogeneous coating of the pigment, measured over a white background, is selected from the group consisting of: a CIELAB L* value of about 30 or less and a chroma value of about 3 or less; a CIELAB hue angle, hab, from about 50 to about 80 degrees, wherein L* is not more than about 85, and the chroma value is greater than 22; a CIELAB hue angle, hab, from about 80 to about 275 degrees, wherein L* is not more than about 80, and the chroma value is greater than about 10; and a CIELAB hue angle, hab, from not less than about 275 to not more than about 50 degrees, wherein L* is not more than about 85, and the chroma value is greater than about 9. The pigments may be used in a variety of applications including cosmetics, plastics, automotive, or architectural coatings.
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: January 8, 2013
    Assignee: Sun Chemical Corp.
    Inventors: Aaron M. Hollman, Stephane Nicolas, Philippe Schottland, Marguerite Debacker, Aurelie Antonowicz, Hai Hui Lin
  • Patent number: 8337609
    Abstract: A pearlescent effect pigment having an opaque, dark or black color is disclosed. The black pearlescent pigment includes a platelet-shaped non-metal substrate, optionally an oxide layer, a template layer, and a metal layer. The pearlescent luster of the disclosed effect pigment is comparable to those of pure pearlescent effects. The disclosed method provides a cost-effective approach for the manufacturing of the disclosed effect pigment.
    Type: Grant
    Filed: December 1, 2009
    Date of Patent: December 25, 2012
    Assignee: Silberline Manufacturing Co., Inc.
    Inventors: Shufang Yu, Peter Llyod Redmond, Hai Hui Lin, Chang Xu, Parfait Jean Marie Likibi
  • Patent number: 8337611
    Abstract: Disclosed are yellowing-stable, silver-white effect pigments having high whiteness based on synthetic mica flakes and to the use thereof in paints, lacquers, printing inks, plastics, button pastes, ceramic materials, glasses, for coloring seed, as dopant in laser markings of plastics and papers, as additive for laser welding of plastics, as additive for coloring in the foods and pharmaceuticals sectors and in cosmetic formulations, and for the preparation of pigment compositions and dry preparations.
    Type: Grant
    Filed: February 17, 2010
    Date of Patent: December 25, 2012
    Assignee: Merck Patent GmbH
    Inventors: Gerhard Pfaff, Johann Dietz, Sabine Schoen, Doreen Warthe
  • Patent number: 8287636
    Abstract: The present invention relates to a pearlescent pigment with large aspect ratio and a method of their preparation, and particularly to pearlescent pigments prepared by coating a metal or metal precursor on the flaky alpha-alumina crystals obtained by using an aluminum precursor aqueous solution and a zinc precursor aqueous solution as main ingredients. The crystals herein has an average particle thickness of 0.5 ?m or less, an average particle diameter of 15 ?m or higher and a large aspect ratio of 50 or higher, thereby being superior in gloss. The crystals show metal colors and interference colors of silver, gold, red, purple, blue and green.
    Type: Grant
    Filed: July 24, 2007
    Date of Patent: October 16, 2012
    Assignees: Korea Research Institute of Chemical Technology, CQV Co., Ltd.
    Inventors: Jung Min Lee, Jeong Kwon Suh, Byung Ki Park, Dong Uk Choe, Gil Wan Chang, Kwang Su Lim, Sung Yun Jo, Kwang Choong Kang
  • Patent number: 8282729
    Abstract: A multilayer effect pigment includes a transparent substrate, a layer of high refractive index material on the substrate, and alternating layers of low refractive index and high refractive index materials on the first layer, the total number of layers being an odd number of at least three, all adjacent layers differing in refractive index by at least about 0.2 and at least one of the layers having an optical thickness which is different from all of the other layers. The resulting multilayer effect pigment is not a quarter-wave stack. The present effect pigments may be used in cosmetic and industrial applications.
    Type: Grant
    Filed: July 26, 2011
    Date of Patent: October 9, 2012
    Assignee: BASF Corporation
    Inventors: Daniel S. Fuller, Curtis J. Zimmermann
  • Patent number: 8268069
    Abstract: The present invention relates to pearlescent pigments based on glass flakes which are distinguished by the fact that they have the following layer structure: A) optionally a layer of SiO2, B) a high-refractive-index coating have a refractive-index n>1.8 which essentially consists of TiO2, C) a low-refractive-index layer comprising SiO2 and/or Al2O3 and optionally D) an outer protective layer, and to the use thereof in paints, coatings, automobile paints, powder coatings, printing inks, security printing inks, plastics, ceramic materials, glasses, paper, in toners for electrophotographic printing processes, in seed, in greenhouse sheeting and tarpaulins, as absorbers in the laser marking of paper and plastics, as absorbers for the laser welding of plastics, in cosmetic formulations, for the preparation of pigment pastes with water, organic and/or aqueous solvents, for the preparation of pigment compositions and dry preparations.
    Type: Grant
    Filed: August 10, 2005
    Date of Patent: September 18, 2012
    Assignee: Merck Patent GmbH
    Inventors: Sabine Melson, Marc Entenmann, Marita Jekel, Marcus Mathias
  • Patent number: 8221536
    Abstract: A cosmetic containing a pearlescent pigment comprising a substrate and a first layer, wherein the first layer comprises iron oxide, wherein the iron has from about 1% to about 30% Fe(II) and from about 70% to about 99% Fe(III).
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: July 17, 2012
    Assignee: Sun Chemical Corp.
    Inventors: Aaron M. Hollman, Stephane Nicolas, Philippe Schottland, Marguerite Debacker, Aurelie Antonowicz, Hai Hui Lin
  • Publication number: 20120174824
    Abstract: Provided is a scale-shaped filmy fines dispersion. More specifically, scale-shaped filmy fines are subjected to a treatment for keeping the scale-shaped filmy fines from easily settling out. In the case of a metallic pigment using the scale-shaped filmy fines, the scale-shaped filmy fines are dispersed in the ink. As a result, nozzle clogging can be prevented, and the obtained print can achieve abundant metallic luster. The scale-shaped filmy fines dispersion contains, in a solvent, scale-shaped filmy fines obtained by finely grinding a simple metal, an alloy, or a metal compound. The scale-shaped filmy fines have a mean length of 0.5 ?m or more and 5.0 ?m or less, a maximum length of 10 ?m or less, a mean thickness of 5 nm or more and 100 nm or less, and an aspect ratio of 20 or more.
    Type: Application
    Filed: August 18, 2010
    Publication date: July 12, 2012
    Applicant: Oike & Co., Ltd.
    Inventors: Toshio Takenaka, Masato Hirota
  • Patent number: 8211224
    Abstract: A pearlescent pigment comprising a substrate and a first layer, wherein the first layer comprises iron oxide, wherein the iron has from about 1% to about 30% Fe(II) and from about 70% to about 99% Fe(III). A process for making these pearlescent pigment, comprise reducing a metal oxide substrate with a hydrogen source in the presence of a noble metal catalyst in a liquid medium. The pigments may be used in a variety of applications including cosmetics, plastics, automotive, or architectural coatings.
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: July 3, 2012
    Assignee: Sun Chemical Corp.
    Inventors: Aaron M. Hollman, Stephane Nicolas, Philippe Schottland, Marguerite Debacker, Aurelie Antonowicz, Hai Hui Lin
  • Patent number: 8197591
    Abstract: The invention relates to a pearlescent pigment comprising a metal oxide-containing, platelet-shaped substrate and having a first and a second protective layer, wherein the metal oxide has a refractive index greater than 1.
    Type: Grant
    Filed: February 23, 2007
    Date of Patent: June 12, 2012
    Assignee: Eckart GmbH
    Inventors: Günter Kaupp, Ulrich Schmidt
  • Patent number: 8192540
    Abstract: A method for producing a bonded color powder concentrate, the method comprising dry mixing a base powder, a pigment powder and a bonding agent; and during the dry mixing, applying heat so as to bring the bonding agent to an adhesive state while the base powder and the pigment powder remain in a stable state, thereby forming agglomerates essentially each comprising a component of the base powder and a component of the pigment powder, bonded together using a component of the bonding agent.
    Type: Grant
    Filed: July 30, 2009
    Date of Patent: June 5, 2012
    Inventor: Giora Topaz
  • Patent number: 8153163
    Abstract: The present invention relates to a pearl pigment obtained by coating the surface of a flaky powder with a colored metal or a colored metal oxide and further coating the surface of the above colored metal- or colored metal oxide-coated flaky powder with a colorless metal or a colorless metal oxide, wherein when the pearl pigment is applied onto the surface of black artificial leather in an average amount of 0.05 mg/cm2 and the intensity of light reflected from the pearl pigment is measured using illuminant C at a 2° viewing angle with a spectrophotometric colorimeter which is provided with a sheet polarizer S on the light incident side and a sheet polarizer P on the light receiving side, the powder reflection light which is incident to the pearl pigment as a measurement sample at an angle of 45° to the direction normal to the surface of the sample and is received in the direction normal to the surface of the sample has absolute values a* and b* of 10 or less, and make-up cosmetics containing the pearl pigment.
    Type: Grant
    Filed: June 28, 2011
    Date of Patent: April 10, 2012
    Assignees: Kao Corporation, Nihon Koken Kogyo KK
    Inventors: Eiichiro Misaki, Hiroyuki Shiomi, Maoya Adachi, Takahiro Kaida
  • Patent number: 8143182
    Abstract: The present invention provides a fused ceramic particle, having the following chemical composition, in percentages by weight based on the oxides and for a total of 100%: 50%<ZrO2+HfO2<70%; 10%<SiO2<30%; 6.5%<MgO<9.5%; Al2O3 in a quantity such that the MgO/Al2O3 weight ratio is in the range 2.4 to 6.6; 0.1%<Y2O3; CeO2<10%; and less than 0.6% of other oxides. Use in particular as milling agents, wet medium dispersion agents, propping agents, heat exchange agents, or for the treatment of surfaces.
    Type: Grant
    Filed: April 7, 2009
    Date of Patent: March 27, 2012
    Assignee: Saint-Gobain Centre de Recherches Et d'Etudes Europeen
    Inventors: Yves Boussant-Roux, Emmanuel Nonnet
  • Patent number: 8129021
    Abstract: Effect pigments with a platelet-shaped substrate provided on at least one side with at least one coating of semitransparent metal and/or at least one high-index coating having a refractive index ?2.0. The platelet-shaped substrate includes at least one mixed inorganic/organic phase. Also, a method of producing effect pigments including the following steps: a) combining at least one organic network former, at least one reactive organic component, at least one inorganic network former and/or nanoscale inorganic particles and a liquid phase to form a reaction composition, b) applying the reaction composition to a sheetlike base, c) forming a solidified mixed inorganic/organic phase, d) converting the mixed inorganic/organic phase into platelet-shaped substrates, and e) coating the platelet-shaped substrates with at least one coating of semitransparent metal and/or at least one high-index coating having a refractive index ?2.0.
    Type: Grant
    Filed: June 16, 2008
    Date of Patent: March 6, 2012
    Assignee: Eckart GmbH
    Inventors: Günter Kaupp, Ulrich Schmidt, Dirk Schumacher
  • Patent number: 8114211
    Abstract: The present invention relates to pearlescent pigments based on flake-form substrates which have at least one FeOOH layer and at least one TiO2 layer or at least one TiO2/SiO2/TiO2 layer package, and to the use thereof, inter alia, in paints, coatings, printing inks, powder coatings, plastics and in particular in care and decorative cosmetics.
    Type: Grant
    Filed: December 12, 2007
    Date of Patent: February 14, 2012
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Carsten Handrosch, Marcus Mathias, Nicole Schupp, Meike Willius
  • Patent number: 8088214
    Abstract: A multilayer effect pigment includes a transparent substrate, a layer of high refractive index material on the substrate, and alternating layers of low refractive index and high refractive index materials on the first layer, the total number of layers being an odd number of at least three, all adjacent layers differing in refractive index by at least about 0.2 and at least one of the layers having an optical thickness which is different from all of the other layers. The resulting multilayer effect pigment is not a quarter-wave stack. The present effect pigments may be used in cosmetic and industrial applications.
    Type: Grant
    Filed: February 10, 2006
    Date of Patent: January 3, 2012
    Assignee: BASF Corporation
    Inventors: Daniel S. Fuller, Curtis J. Zimmermann
  • Patent number: 8088211
    Abstract: An aluminum pigment having aluminum particles, a molybdenum coat comprising a molybdenum oxide and/or a molybdenum hydrate covering the surface of each aluminum particle and a silica coat comprising amorphous silica and/or a coat prepared from a silane coupling agent further covering this molybdenum coat is provided as an aluminum pigment having excellent dispersibility and stability, neither generating hydrogen gas nor agglomerating during storage and providing excellent designability for the appearance of a film. With respect to 100 parts by mass of aluminum, the content of molybdenum is preferably in the range of 0.01 to 5 parts by mass, and the content of silicon is preferably in the range of 1 to 20 parts by mass.
    Type: Grant
    Filed: April 28, 2003
    Date of Patent: January 3, 2012
    Assignee: Toyo Aluminium Kabushiki Kaisha
    Inventors: Yoshiki Hashizume, Taro Morimitsu
  • Patent number: 8088212
    Abstract: An effect pigment formed from a synthetic platelet substrate such as glass flake has improved sparkle by reducing the amount of substrate particles having a size of less than 9 microns and greater than 85 microns. The present effect pigment is useful in cosmetics, personal care products, and industrial applications such as automotive paints.
    Type: Grant
    Filed: March 29, 2006
    Date of Patent: January 3, 2012
    Assignee: BASF Corporation
    Inventor: Frank Bagala, Sr.
  • Patent number: 8083846
    Abstract: A color effect material is described as composed of a plurality of encapsulated substrate platelets in which each platelet is encapsulated with a highly reflective layer which acts as a reflector to light directed thereon and a spacer pigment layer which is selectively transparent to light directed thereon.
    Type: Grant
    Filed: August 18, 2004
    Date of Patent: December 27, 2011
    Assignee: BASF Corporation
    Inventors: Curtis J. Zimmermann, James D. Christie, Vivian K. Doxey, Daniel Stevenson Fuller
  • Patent number: 8066811
    Abstract: The invention disclosed a pigment having angle dependence of the interference colors and its production process, in which mica is used as the substrate and the first metal oxide coating with high refractive index has the optical thickness of silver to golden interference color. And the second metal oxide coating with low refractive index has the optical thickness of the second circle green to the fourth circle interference color. The third coating is a highly refractive metal oxide. The lowly refractive metal oxide is SiO2 and the highly refractive metal oxide is TiO2, SnO2, Fe2O3, Fe3O4, CoO, Co2O3, ZrO2, Cr2O3 or their mixtures as well as complexes. The mica substrate is wet-milled mica powders with a thickness of 0.1-0.9 micrometers and a diameter of 5-250 micrometers.
    Type: Grant
    Filed: April 18, 2005
    Date of Patent: November 29, 2011
    Inventors: Jiansheng Fu, Yiting Peng, Xiaohui Tian
  • Publication number: 20110265689
    Abstract: Multilayer pearlescent pigments comprising platelet-shaped transparent substrates provided with an optically active coating, where the optically active coating includes at least a) an absorbing high-index layer A having a refractive index n?1.8 b) a low-index layer B having a refractive index n<1.8 c) a high-index layer C having a refractive index n?1.8 and also d) optionally at least one outer protective layer D and where the multilayer pearlescent pigments have a cumulative frequency distribution of a volume-averaged size distribution function, with the indices D10, D50, D90 and a span ?D in a range from 0.7-1.4, the span ?D being calculated in accordance with formula (I) ?D=(D90?D10)/D50??(I). The disclosure further relates to a method for producing these multilayer pearlescent pigments, and also to their use.
    Type: Application
    Filed: August 9, 2010
    Publication date: November 3, 2011
    Inventors: Dirk Schumacher, Michael Grüner, Günter Kaupp
  • Publication number: 20110265690
    Abstract: Multilayer pearlescent pigments based on platelet-shaped transparent substrates with an optically active coating, where the optically active coating includes at least a) a nonabsorbing high-index layer A having a refractive index n?1.8, b) a low-index layer B having a refractive index n<1.8 having an optical layer thickness >150 nm, c) an absorbing high-index layer C having a refractive index n?1.8 and also, d) optionally an outer protective layer D, wherein the multilayer pearlescent pigments have a cumulative frequency distribution of the volume-averaged size distribution function, with the indices D10, D50, D90 and a span ?D of 0.7-1.4, the span ?D being calculated in accordance with the formula ?D=(D90?D10)/D50. The disclosure further relates to a method for producing these multilayer pigments, and to their use.
    Type: Application
    Filed: August 9, 2010
    Publication date: November 3, 2011
    Inventors: Dirk Schumacher, Michael Grüner, Günter Kaupp
  • Publication number: 20110259243
    Abstract: Multilayer pearlescent pigments comprising platelet-shaped transparent substrates provided with an optically active coating, where the coating includes at least (a) a nonabsorbing high-index layer A having a refractive index n?1.8, (b) a low-index layer B having a refractive index n<1.8, (c) a nonabsorbing high-index layer C having a refractive index n?1.8 and also (d) optionally at least one outer protective layer D where the pigments have a cumulative frequency distribution of a volume-averaged size distribution function, with the indices D10, D50, D90 and a span ?D in a range from 0.7-1.4, the span ?D being calculated in accordance with formula (I) ?D=(D90?D10)/D50??(I). The disclosure further relates to a method for producing these multilayer pearlescent pigments, and also to their use.
    Type: Application
    Filed: August 9, 2010
    Publication date: October 27, 2011
    Inventors: Dirk Schumacher, Michael Grüner, Günter Kaupp
  • Patent number: 8034864
    Abstract: The present invention relates to opaque plastics comprising effect pigments which are distinguished by the fact that they have high gloss and virtually no visible or no visible flow lines.
    Type: Grant
    Filed: September 21, 2005
    Date of Patent: October 11, 2011
    Assignee: Merck Patent GmbH
    Inventors: Manfred Kieser, Markus Schum
  • Patent number: 8029615
    Abstract: A pearlescent pigment includes a ceramic flake coated with a metal oxide. The metal oxide is, preferably, an oxide of titanium, iron, tin, chromium1, zirconium or a combination thereof, and the refractive index of the metal oxide coating is preferably at least 0.5 higher than that of the ceramic flake. The pearlescent pigment may be included in a coating applied to a metallic or plastic surface to give the surface a lustrous or pearlescent optical effect.
    Type: Grant
    Filed: October 30, 2007
    Date of Patent: October 4, 2011
    Inventor: Charles Watkinson