Iron Or Bismuth Compound Containing (fe Or Bi) Patents (Class 106/418)
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Patent number: 11459469Abstract: Effect pigments based on Al2O3 flakes with high weather resistance and less photoactivity and to their use thereof in paints, industrial coatings, automotive coatings, printing inks, cosmetic formulations. The effect pigments have a ratio of the amount by weight of Al2O3 of the Al2O3 flake and the amount by weight of the metal oxide(s) of the coating layer(s) in the range of from 27:73 to 83:17 based on the total weight of the effect pigment.Type: GrantFiled: December 19, 2018Date of Patent: October 4, 2022Assignee: Merck Patent GmbHInventors: Sabine Schoen, Michael Jungnitz, Stefan Schlueter, Kirsten Fritsche, Carsten Plueg, Stephanie Andes, Ulrich Schoenefeld
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Patent number: 11214690Abstract: The present invention relates to semitransparent pearlescent pigments, to processes for producing them, and to the use of such pearlescent pigments, where the pearlescent pigments comprise monolithically constructed substrate platelets composed of a metal oxide having an average thickness of 1 to 40 nm and a form factor, expressed by the ratio of the mean size to the average thickness, of at least 80, which are enveloped by at least one substantially transparent coating A composed of at least one low-index metal oxide and/or metal oxide hydrate, having a refractive index of less than 1.8, and at least one interference layer in the form of a coating B composed of at least one high-index metal oxide, having a refractive index of at least 1.8.Type: GrantFiled: April 15, 2016Date of Patent: January 4, 2022Inventors: Adalbert Huber, Fabian Piech, Kaiman Shimizu
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Patent number: 9873773Abstract: Disclosed are a composite material and a method for preparing the same. The composite material is consisted of TiO2 and BaZn1.2Co0.8Fe16O27. The composite material of the invention has the advantages of high absorption frequency band, good compatibility and wide frequency band, and it is applicable for the shell protection material of a mobile phone or a TV set, thereby absorbing the electromagnetic wave band that is the most harmful to human bodies, without influencing the normal communication function of an electronic device, for example, a mobile phone.Type: GrantFiled: April 21, 2016Date of Patent: January 23, 2018Assignee: BOE TECHNOLOGY GROUP CO., LTD.Inventors: Wei Zhang, Xiangchun Kong
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Patent number: 9815970Abstract: A high chroma effect pigment includes a platelet substrate and an optical coating formed on the platelet substrate. The optical coating includes a first high refractive index layer, a second high refractive index layer on the first high refractive index layer, and a diffused third material having a range of diffusion between 100% to partial diffusion in the first high refractive index layer, the second high refractive index layer, or both the first and the second high refractive index layers. The first and second high refractive index layers independently have a refractive index of about >1.65. The diffused third material is SiO2 or a metal oxide is different than the first and second high refractive index layers.Type: GrantFiled: May 21, 2015Date of Patent: November 14, 2017Assignee: BASF SEInventors: Steven Jones, Meaghan Clark McGuire, James Sioss, Christopher Sichmeller, Martin Saltzman
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Patent number: 9637651Abstract: The present invention is directed to a bismuth oxide-based additive for laser marking containing oxygen-deficient bismuth oxide represented by the general formula: Bi2O(3-x) (provided that x is 0.01 or more and 0.3 or less and x represents the amount of oxygen deficiency calculated according to the formula: x=3?O1s/Bi4f×2 from the ratio (O1s/Bi4f) of the peak area attributed to the 1s electrons of oxygen bonded to bismuth to the peak area attributed to the 4f electrons of bismuth obtained by X-ray photoelectron spectrometry), which enables marking with excellent blackness and contrast without causing undesirable coloration of a resin composition regardless of the type or shape of a resin to be used.Type: GrantFiled: April 17, 2014Date of Patent: May 2, 2017Assignee: TOKAN MATERIAL TECHNOLOGY CO., LTD.Inventors: Tatsuo Matoda, Shigeru Suzuki, Taketo Shinchi, Akira Ishiko
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Patent number: 9609934Abstract: The present invention relates to a method of applying makeup to keratinous substances, in particular the skin, the lips, the nails, or hair, the method comprising the following steps: depositing at least one cosmetic composition on the surface to be made up, the cosmetic composition comprising: bodies that present non-zero magnetic susceptibility and that are movable under the effect of a magnetic field; and at least one interferential pigment; and exposing at least part of the composition to a magnetic field, so as to modify the orientation and/or displace at least some of the magnetic bodies.Type: GrantFiled: July 8, 2005Date of Patent: April 4, 2017Assignee: L'OREALInventor: Ludovic Thevenet
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Patent number: 9404259Abstract: The present invention provides shaped articles comprising one or more composite layer of (i) a vulcanizate encapsulated in a colored or uncolored thermoplastic polymer matrix containing one or more passivating agent, and (ii) a reflective material chosen from colored fluidizable particles of a thermoplastic reflective colorant encapsulated vulcanizate, roofing granules, thermoplastic encapsulated roofing granules, the colored thermoplastic polymer matrix, and combinations thereof. The articles can be laminates of colored or reflective layers on uncolored or other layers, or one or more colored layer having colored fluidizable particles are dispersed within the surface of the uppermost composite layer or having either the colored fluidizable particles or the granules are dispersed on the surface of the composite layer or are adhered thereto with a thermoplastic resin. Roofing shingles are provided.Type: GrantFiled: December 21, 2011Date of Patent: August 2, 2016Assignee: Rohm and Haas CompanyInventors: Harry R. Heulings, Willie Lau, Joseph M. Rokowski
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Patent number: 9309411Abstract: The present invention relates to a nacreous pigment and a method of preparing the same. The nacreous pigment includes a flake substrate, a first metal oxide layer coated on the substrate, and an oxide layer coated on the first metal oxide layer and containing MgO.SiO2, and a second metal oxide layer coated on the oxide layer. The pigment exhibits high brightness, high chroma, high gloss, and multi-color effects.Type: GrantFiled: June 22, 2011Date of Patent: April 12, 2016Assignee: CQV CO., LTD.Inventors: Jae-Il Jeong, Kwang-Choong Kang, Byung-Ki Choi, Kwang-Soo Lim, Kil-Wan Chang
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Patent number: 9238739Abstract: The present invention relates to effect pigments based on coated, flake-form substrates, where an organic coating which contains fluoroalkyl groups and hydrophilic groups and is built up from at least one siloxane and/or at least one silane is applied to the substrate as outer layer.Type: GrantFiled: July 5, 2013Date of Patent: January 19, 2016Assignee: Merck Patent GmbHInventors: Ulrich Schoenefeld, Joachim Duschek, Alfred Hennemann
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Patent number: 8940189Abstract: The present invention relates to intensely colored and/or optically variable pigments which have a flake-form transparent or semitransparent electrically conductive core and at least one coloring dielectric layer surrounding the core, to a process for the preparation of such pigments, and to the use thereof.Type: GrantFiled: December 11, 2008Date of Patent: January 27, 2015Assignee: Merck Patent GmbHInventors: Burkhard Krietsch, Matthias Kuntz, Reinhold Rueger
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Patent number: 8906154Abstract: A coating, ink, or article containing a pearlescent pigment comprising a substrate and a first layer, wherein the first layer comprises iron oxide, wherein the iron has from about 1% to about 30% Fe(II) and from about 70% to about 99% Fe(III).Type: GrantFiled: October 31, 2007Date of Patent: December 9, 2014Assignee: Sun Chemical CorporationInventors: Aaron M. Hollman, Stephane Nicolas, Philippe Schottland, Marguerite Debacker, Aurelie Antonowicz, Hai Hui Lin
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Publication number: 20140255459Abstract: The subject matter of the invention is a method of surface modification of a pigment or of a composite pigment comprising at least a metal oxide, a metal complex or a derivative thereof, and the use of these pigments or composite pigments thus obtained for cosmetics, paint or inks.Type: ApplicationFiled: October 5, 2012Publication date: September 11, 2014Inventors: Franck Martin, Johanne Moineau, Aude Mezy, Guillaume Gracy
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Patent number: 8808447Abstract: The present invention relates to a pigment paint for an exterior material and to a method for manufacturing the same. The pigment paint comprises: a flake matrix, a first metal oxide layer coated on the upper portion of the transparent matrix, an oxide layer containing MgO—SiO2 coated on the upper portion of the first metal oxide layer, and a second metal oxide layer coated on the upper portion of the oxide layer. In order to ensure humidity resistance and weather resistance required for a lustrous pigment paint for exterior materials, a cerium layer and an aluminum oxide layer are further coated. Properties such as high luminance, high chromaticity, and high gloss, which could not be achieved using conventional techniques, can be achieved and a pigment paint having a multi-colored pearl luster can be provided.Type: GrantFiled: March 8, 2012Date of Patent: August 19, 2014Assignee: CQV Co., Ltd.Inventors: Jae-Il Jeong, Nam-Il Lee, Sang-Keun Park, Jin-Hyung Lee, Kwang-Choong Kang, Byung-Ki Choi, Kwang-Soo Lim, Kil-Wan Chang
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Publication number: 20140165878Abstract: The interference pigment with high color intensity includes: a platelet-shaped substrate including at least one of natural mica, synthetic mica, alumina flakes, glass flakes, and iron oxide flakes; a lower first metal oxide layer formed of Fe2O3 on the platelet-shaped substrate; a second metal oxide layer formed of MgO.SiO2 on the lower first metal oxide layer; and an upper first metal oxide layer formed of Fe2O3 on the second metal oxide layer.Type: ApplicationFiled: July 15, 2013Publication date: June 19, 2014Applicant: CQV CO., LTD.Inventors: Kil-Wan Chang, Kwang-Soo Lim, Byung-Ki Choi, Jin-Hyoung Lee
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Patent number: 8728502Abstract: This disclosure is directed to a black effect pigment and a method of forming said pigment. The pigment comprises a platy substrate coated with SnO2 and/or SnO2 hydrates and Fe3O4 with an optional coating of metal oxides such as SiO2, TiO2, ZrO2 and ZnO2. The deposition of the SnO2 and/or SnO2 hydrates onto the substrate improves the adhesion and prepares the substrate surface for deposition of the iron oxides onto the platy surface, especially mica surfaces. While the pigment may be used in such applications as coating, powder coating, printing ink, plastic, ceramic material, glass, cosmetic formulation, laser marking pigment, pigment composition or dry preparation, the pigment is especially suitable for cosmetic applications.Type: GrantFiled: March 14, 2012Date of Patent: May 20, 2014Assignee: BASF CorporationInventors: James Sioss, Thomas Chirayil, Betty Aucar
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Publication number: 20140099346Abstract: An iron oxide containing effect pigment, and methods for producing and using the same are discussed. The iron oxide containing effect pigment may include an iron oxide coating in direct contact with a particulate substrate, which may have high levels of hematite, magnetite, or maghemite; and low amounts of toxic metals. A method for producing the pigment may include chemical vapor deposition of iron pentacarbonyl onto a particulate substrate. The iron oxide containing effect pigments may be incorporated into compositions, such as cosmetics.Type: ApplicationFiled: October 2, 2013Publication date: April 10, 2014Applicant: BASF CorporationInventors: Juergen Walker, Gabe Uzunian, Raimund Schmid, Aron Wosylus, Christoph Schwidetzky
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Publication number: 20140018439Abstract: The present invention relates to a weather-resistant pearlescent pigment which consists of a platelet-shaped substrate coated with one or more highly refractive metal oxides, the platelet-shaped substrate being selected from the group consisting of synthetic mica flakes, glass flakes, SiO2 flakes, Al2O3 flakes, synthetic boehmite flakes, BiOCl flakes and mixtures thereof, and a top layer, wherein the top layer consists of the following layers: a) a cerium-containing layer, selected from the group consisting of cerium oxide, cerium hydroxide, hydrated cerium oxide, and mixtures thereof, the cerium-containing layer being applied directly to the highly refractive metal oxide layer, and b) an organic-chemical compatibilizing layer, which comprises the reaction products of oligomeric silanes, wherein the oligomeric silanes have one or more amino groups, the organic-chemical compatibilizing layer being applied directly to the cerium-containing layer a).Type: ApplicationFiled: March 28, 2012Publication date: January 16, 2014Applicant: ECKART GMBHInventors: Michael Gruner, Thomas Schneider, Gunter Kaupp
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Publication number: 20140010772Abstract: A silver-colored pigment is provided having a nonmetallic platelet-shaped substrate and at least one ilmenite-containing coating, wherein the nonmetallic platelet-shaped substrate is a nonmetallic platelet-shaped synthetic substrate and the amount of iron compounds, calculated as elemental iron, in the pigment is less than 5.0% by weight, based on the total weight of the pigment. Processes for preparing the pigment also are provided.Type: ApplicationFiled: March 23, 2012Publication date: January 9, 2014Applicant: ECKART GMBHInventors: Michael Gruner, Thomas Schneider, Gunter Kaupp, Christian Rummer, Dirk Schumacher
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Patent number: 8486189Abstract: A cosmetic containing a pearlescent pigment comprising a substrate and a first layer, wherein the first layer comprises iron oxide, wherein the iron has from about 1% to about 30% Fe(II) and from about 70% to about 99% Fe(III).Type: GrantFiled: June 15, 2012Date of Patent: July 16, 2013Assignee: Sun Chemical CorporationInventors: Aaron M. Hollman, Stephane Nicolas, Philippe Schottland, Marguerite Debacker, Aurelie Antonowicz, Hai Hui Lin
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Publication number: 20130164356Abstract: The present invention relates to effect pigments which are based on flake-form substrates having a circular form factor of 1.2-2 and are coated with at least one high-refractive-index layer, and to the use thereof, inter alia in paints, coatings, printing inks, plastics and in cosmetic formulations.Type: ApplicationFiled: December 20, 2012Publication date: June 27, 2013Applicant: MERCK PATENT GESELLSCHAFT MIT BESCHRANKTER HAFTUNGInventor: Merck Patent Gesellschaft Mit Beschrankter Haftung
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Patent number: 8409342Abstract: A pearlescent pigment and a process for enhancing the magnetic properties of a pearlescent pigment. The pearlescent pigment has a layer with regions of ?-Fe2O3 and regions of ?-Fe2O3. The magnetic properties of a pearlescent pigment may be enhanced by the steps of: providing a platelet pigment with a layer of Fe2O3, with a magnetic susceptibility less than 0.1×10?5 m3/kg; reducing some or all of the Fe2O3 to Fe3O4; and oxidizing some or all of the Fe3O4 to ?-Fe2O3. The color difference (?E*) between the provided pigment and the resultant pigment is not more than about 5.Type: GrantFiled: June 26, 2012Date of Patent: April 2, 2013Assignee: Sun Chemical CorporationInventors: Aaron M. Hollman, Philippe Schottland
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Patent number: 8349067Abstract: A pearlescent pigment, wherein the pigment is an inorganic material and the color of a homogeneous coating of the pigment, measured over a white background, is selected from the group consisting of: a CIELAB L* value of about 30 or less and a chroma value of about 3 or less; a CIELAB hue angle, hab, from about 50 to about 80 degrees, wherein L* is not more than about 85, and the chroma value is greater than 22; a CIELAB hue angle, hab, from about 80 to about 275 degrees, wherein L* is not more than about 80, and the chroma value is greater than about 10; and a CIELAB hue angle, hab, from not less than about 275 to not more than about 50 degrees, wherein L* is not more than about 85, and the chroma value is greater than about 9. The pigments may be used in a variety of applications including cosmetics, plastics, automotive, or architectural coatings.Type: GrantFiled: October 31, 2007Date of Patent: January 8, 2013Assignee: Sun Chemical Corp.Inventors: Aaron M. Hollman, Stephane Nicolas, Philippe Schottland, Marguerite Debacker, Aurelie Antonowicz, Hai Hui Lin
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Patent number: 8323396Abstract: An orange pearlescent pigment comprising a substrate and a first layer containing FeOOH, and a second layer containing Fe2O3 located between the substrate and the first layer. The color of the pigment is such that a homogeneous coating of the pigment, measured over a white background, has a CIELAB hue angle, hab, from about 40 to about 60 degrees, and the chroma value is greater than 50. The pigment may be used in a cosmetic, coating, or ink composition.Type: GrantFiled: February 18, 2008Date of Patent: December 4, 2012Assignee: Sun Chemical Corp.Inventors: Aaron Hollman, Philippe Schottland, Jim Black
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Publication number: 20120282311Abstract: The present invention relates to pigments with improved and adjustable sparkling effect comprising A) a plate-like substrate of perlite coated with (a) dielectric material, and/or metal; and B) a plate-like substrate of mica, coated with (a) dielectric material, and/or a metal; and a process for their production and their use in paints, ink jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass. The pigments show an improved sparkle effect; in particular an attractive high sparkle intensity.Type: ApplicationFiled: October 18, 2010Publication date: November 8, 2012Applicant: BASF SEInventors: Raimund Schmid, Norbert Mronga, Patrice Bujard, Steven Jones, Paul Cao
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Patent number: 8303864Abstract: Flame-retardant plastics mouldings composed of polyphenyl sulphones (PPSUs) or of polycarbonates (PCs) are coloured with Iridoin® pigments in such a way as to have a metallic effect. The effect is resistant to the usual stresses present in an aircraft cabin and complies with the respective fire-protection requirements.Type: GrantFiled: June 16, 2005Date of Patent: November 6, 2012Assignee: Evonik Rohm GmbHInventor: Detlef Bumann
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Patent number: 8273171Abstract: A pearlescent pigment (100) includes: a flaky substrate (10); a titanium dioxide layer (20) that is formed on the flaky substrate (10); and an oxazoline compound layer (40) that is formed on the titanium dioxide layer (20) with the titanium dioxide layer (20) being interposed between the flaky substrate (10) and the oxazoline compound layer (40), and serves as a top surface of the pearlescent pigment (100).Type: GrantFiled: August 29, 2007Date of Patent: September 25, 2012Assignee: Nippon Sheet Glass Company, LimitedInventors: Takeaki Kitamura, Juichi Ino
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Publication number: 20120237577Abstract: This disclosure is directed to a black effect pigment and a method of forming said pigment. The pigment comprises a platy substrate coated with SnO2 and/or SnO2 hydrates and Fe3O4 with an optional coating of metal oxides such as SiO2, TiO2, ZrO2 and ZnO2. The deposition of the SnO2 and/or SnO2 hydrates onto the substrate improves the adhesion and prepares the substrate surface for deposition of the iron oxides onto the platy surface, especially mica surfaces. While the pigment may be used in such applications as coating, powder coating, printing ink, plastic, ceramic material, glass, cosmetic formulation, laser marking pigment, pigment composition or dry preparation, the pigment is especially suitable for cosmetic applications.Type: ApplicationFiled: March 14, 2012Publication date: September 20, 2012Inventors: James Sioss, Thomas Chirayil, Betty Aucar
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Publication number: 20120207802Abstract: Provided is a pigment composition comprising a first and second effect pigments, wherein the composition has a hue comparable to carmine but does not comprise carmine.Type: ApplicationFiled: February 14, 2012Publication date: August 16, 2012Inventor: Sung Yeun CHOI
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Patent number: 8221536Abstract: A cosmetic containing a pearlescent pigment comprising a substrate and a first layer, wherein the first layer comprises iron oxide, wherein the iron has from about 1% to about 30% Fe(II) and from about 70% to about 99% Fe(III).Type: GrantFiled: October 31, 2007Date of Patent: July 17, 2012Assignee: Sun Chemical Corp.Inventors: Aaron M. Hollman, Stephane Nicolas, Philippe Schottland, Marguerite Debacker, Aurelie Antonowicz, Hai Hui Lin
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Patent number: 8211224Abstract: A pearlescent pigment comprising a substrate and a first layer, wherein the first layer comprises iron oxide, wherein the iron has from about 1% to about 30% Fe(II) and from about 70% to about 99% Fe(III). A process for making these pearlescent pigment, comprise reducing a metal oxide substrate with a hydrogen source in the presence of a noble metal catalyst in a liquid medium. The pigments may be used in a variety of applications including cosmetics, plastics, automotive, or architectural coatings.Type: GrantFiled: October 31, 2007Date of Patent: July 3, 2012Assignee: Sun Chemical Corp.Inventors: Aaron M. Hollman, Stephane Nicolas, Philippe Schottland, Marguerite Debacker, Aurelie Antonowicz, Hai Hui Lin
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Patent number: 8211225Abstract: A pearlescent pigment and a process for enhancing the magnetic properties of a pearlescent pigment. The pearlescent pigment has a layer with regions of ?-Fe2O3 and regions of ?-Fe2O3. The magnetic properties of a pearlescent pigment may be enhanced by the steps of: providing a platelet pigment with a layer of Fe2O3, with a magnetic susceptibility less than 0.1×10?5 m3/kg; reducing some or all of the Fe2O3 to Fe3O4; and oxidizing some or all of the Fe3O4 to ?-Fe2O3. The color difference (?E*) between the provided pigment and the resultant pigment is not more than about 5.Type: GrantFiled: April 9, 2008Date of Patent: July 3, 2012Assignee: Sun Chemical Corp.Inventors: Aaron M. Hollman, Philippe Schottland
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Patent number: 8197591Abstract: The invention relates to a pearlescent pigment comprising a metal oxide-containing, platelet-shaped substrate and having a first and a second protective layer, wherein the metal oxide has a refractive index greater than 1.Type: GrantFiled: February 23, 2007Date of Patent: June 12, 2012Assignee: Eckart GmbHInventors: Günter Kaupp, Ulrich Schmidt
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Patent number: 8153163Abstract: The present invention relates to a pearl pigment obtained by coating the surface of a flaky powder with a colored metal or a colored metal oxide and further coating the surface of the above colored metal- or colored metal oxide-coated flaky powder with a colorless metal or a colorless metal oxide, wherein when the pearl pigment is applied onto the surface of black artificial leather in an average amount of 0.05 mg/cm2 and the intensity of light reflected from the pearl pigment is measured using illuminant C at a 2° viewing angle with a spectrophotometric colorimeter which is provided with a sheet polarizer S on the light incident side and a sheet polarizer P on the light receiving side, the powder reflection light which is incident to the pearl pigment as a measurement sample at an angle of 45° to the direction normal to the surface of the sample and is received in the direction normal to the surface of the sample has absolute values a* and b* of 10 or less, and make-up cosmetics containing the pearl pigment.Type: GrantFiled: June 28, 2011Date of Patent: April 10, 2012Assignees: Kao Corporation, Nihon Koken Kogyo KKInventors: Eiichiro Misaki, Hiroyuki Shiomi, Maoya Adachi, Takahiro Kaida
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Patent number: 8114211Abstract: The present invention relates to pearlescent pigments based on flake-form substrates which have at least one FeOOH layer and at least one TiO2 layer or at least one TiO2/SiO2/TiO2 layer package, and to the use thereof, inter alia, in paints, coatings, printing inks, powder coatings, plastics and in particular in care and decorative cosmetics.Type: GrantFiled: December 12, 2007Date of Patent: February 14, 2012Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventors: Carsten Handrosch, Marcus Mathias, Nicole Schupp, Meike Willius
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Publication number: 20120034178Abstract: The present invention relates to novel pigment mixtures comprising at least two different particulate components A and B. The first component A comprises titanium suboxide(s), a titanium oxynitride or a titanium nitride species. Component B particle comprises inorganic, or organic pigments. The titanium suboxide particles display a bluish metallic luster, are new and form a further aspect of the present invention. When combined with particles from component B such as variously coated micas, for example, the bluish or bluish/black metallic color effect from component A leads to special color effects in the various mixtures.Type: ApplicationFiled: October 21, 2011Publication date: February 9, 2012Inventors: Patrice Bujard, Philippe Bugnon, Marc Mamak, Urs Leo Stadler
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Patent number: 8083846Abstract: A color effect material is described as composed of a plurality of encapsulated substrate platelets in which each platelet is encapsulated with a highly reflective layer which acts as a reflector to light directed thereon and a spacer pigment layer which is selectively transparent to light directed thereon.Type: GrantFiled: August 18, 2004Date of Patent: December 27, 2011Assignee: BASF CorporationInventors: Curtis J. Zimmermann, James D. Christie, Vivian K. Doxey, Daniel Stevenson Fuller
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Publication number: 20110301273Abstract: Pigment granules including a support material which is coated with one or more flake-form effect pigments by means of an adhesion promoter. The effect pigments may be, for example, pearlescent pigments, interference pigments, metal-effect pigments, multilayered pigments having one or more transparent, semi-transparent or opaque layers, goniochromatic pigments, holographic pigments, coated BiOCL flakes, uncoated BiOCl flakes, and LCP pigments, and mixtures thereof. A process for the production of pigment granules includes mixing one or more flake-form effect pigments, a support material, at least one adhesion promoter, and optionally one or more additives simultaneously or successively with one another. The pigment granules may be used for the pigmenting of application media, in particular paints, plasters, coatings, powder coatings, plastics, and in particular as scatter and effect granules, for example for the decoration of wallcoverings.Type: ApplicationFiled: December 18, 2009Publication date: December 8, 2011Applicant: Merck Patent GmbHInventors: Thomas Rathschlag, Carsten Griessmann
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Publication number: 20110237683Abstract: The present invention relates to pigment compositions with improved and adjustable sparkling effect comprising A) a platelet-like perlite; and B) an effect pigment; and a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass. The pigment compositions show an improved sparkle effect; in particular an attractive high sparkle intensity.Type: ApplicationFiled: February 1, 2011Publication date: September 29, 2011Applicant: BASF SEInventors: Raimund Schmid, Carolyn Lavallee, Steven A. Jones, James Carroll
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Publication number: 20110223218Abstract: A combination pigment having a mica and/or metal oxide-coated mica substrate, an absorption colorant coating, and a waxy film bonding the absorption colorant coating to the substrate.Type: ApplicationFiled: March 9, 2010Publication date: September 15, 2011Inventors: Steven Alan Jones, Gabriel E. Uzunian, Betty F. Aucar
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Patent number: 8016934Abstract: The present invention relates to a pearl pigment obtained by coating the surface of a flaky powder with a colored metal or a colored metal oxide and further coating the surface of the above colored metal- or colored metal oxide-coated flaky powder with a colorless metal or a colorless metal oxide, wherein when the pearl pigment is applied onto the surface of black artificial leather in an average amount of 0.05 mg/cm2 and the intensity of light reflected from the pearl pigment is measured using illuminant C at a 2° viewing angle with a spectrophotometric colorimeter which is provided with a sheet polarizer S on the light incident side and a sheet polarizer P on the light receiving side, the powder reflection light which is incident to the pearl pigment as a measurement sample at an angle of 45° to the direction normal to the surface of the sample and is received in the direction normal to the surface of the sample has absolute values a* and b* of 10 or less, and make-up cosmetics containing the pearl pigment.Type: GrantFiled: December 15, 2005Date of Patent: September 13, 2011Assignees: Kao Corporation, Nihon Koken Kogyo KKInventors: Eiichiro Misaki, Hiroyuki Shiomi, Maoya Adachi, Takahiro Kaida
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Patent number: 7993444Abstract: A multilayer effect pigment includes a transparent substrate, a layer of high refractive index material on the substrate, and alternating layers of low refractive index and high refractive index materials on the first layer, the total number of layers being an odd number of at least three, all adjacent layers differing in refractive index by at least about 0.2 and at least one of the layers having an optical thickness which is different from all of the other layers. The resulting multilayer effect pigment is not a quarter-wave stack. The present effect pigments may be used in cosmetic and industrial applications.Type: GrantFiled: October 19, 2006Date of Patent: August 9, 2011Assignee: BASF Catalysts LLCInventors: Daniel S. Fuller, Curtis J. Zimmermann
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Patent number: 7993443Abstract: A multilayer effect pigment includes a transparent substrate, a layer of high refractive index material on the substrate, and alternating layers of low refractive index and high refractive index materials on the first layer, the total number of layers being an odd number of at least three, all adjacent layers differing in refractive index by at least about 0.2 and at least one of the layers having an optical thickness which is different from all of the other layers. The resulting multilayer effect pigment is not a quarter-wave stack. The present multilayer effect pigment may be used in cosmetics or personal care products.Type: GrantFiled: February 10, 2006Date of Patent: August 9, 2011Assignee: BASF Catalysts LLCInventors: Daniel S. Fuller, Curtis J. Zimmermann
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Patent number: 7951420Abstract: A method of preparing a pigment exhibiting a color-shifting effect, including at least heating mica powder suspension in water, adjusting the pH value of the mixture to between 2 and 9, adding a first inorganic salt solution, maintaining the pH value of the mixture constant, stirring the mixture at constant temperature, adjusting the pH value of the mixture to between 6 and 14, adding a second inorganic salt solution, maintaining the pH value of the mixture constant, stirring the mixture at constant temperature, adjusting the pH value of the mixture to between 2 and 9, adding a third inorganic salt solution, maintaining the pH value of the mixture constant, and stirring the mixture at constant temperature.Type: GrantFiled: September 26, 2009Date of Patent: May 31, 2011Inventors: Jiansheng Fu, Yiting Peng, Xiaohui Tian
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Patent number: 7850775Abstract: A pearlescent pigment comprising a substrate and a first layer, wherein the first layer comprises iron oxide, wherein the iron has from about 1% to about 30% Fe(II) and from about 70% to about 99% Fe(III). A process for making these pearlescent pigment, comprise reducing a metal oxide substrate with a hydrogen source in the presence of a noble metal catalyst in a liquid medium. The pigments may be used in a variety of applications including cosmetics, plastics, automotive or architectural coatings.Type: GrantFiled: June 20, 2007Date of Patent: December 14, 2010Assignee: Sun Chemical CorporationInventors: Aaron M. Hollman, Stephane Nicolas, Philippe Schottland, Marguerite Debacker, Aurelie Antonowicz, Hai Hui Lin
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Publication number: 20100291014Abstract: Disclosed are pigment mixtures containing at least two components, where component A contains bismuth oxychloride (BiOCl) or boron nitride (BN) and component B contains synthetic flakes treated with at least one metal soap or mineral flakes treated with at least one metal soap and to the use thereof especially in cosmetic formulations.Type: ApplicationFiled: May 13, 2010Publication date: November 18, 2010Applicant: MERCK Patent GesselschaftInventors: Mark Tellefsen, Qinyun Peng
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Patent number: 7745003Abstract: The present invention relates to particles having a functional multilayered structure based on substrates, characterized in that the substrates are coated with one or more layers of one or more polymers and one or more layers of one or more silanes, process for the production thereof, and the use thereof.Type: GrantFiled: January 15, 2005Date of Patent: June 29, 2010Assignee: Merck Patent GmbHInventors: Alfred Hennemann, Marc Entenmann, Margarete Müller, Renate Bonn-Walter, Adalbert Huber, Ulrich Schoenefeld
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Publication number: 20100011991Abstract: A method of preparing a pigment exhibiting a color-shifting effect, including at least heating mica powder suspension in water, adjusting the pH value of the mixture to between 2 and 9, adding a first inorganic salt solution, maintaining the pH value of the mixture constant, stirring the mixture at constant temperature, adjusting the pH value of the mixture to between 6 and 14, adding a second inorganic salt solution, maintaining the pH value of the mixture constant, stirring the mixture at constant temperature, adjusting the pH value of the mixture to between 2 and 9, adding a third inorganic salt solution, maintaining the pH value of the mixture constant, and stirring the mixture at constant temperature.Type: ApplicationFiled: September 26, 2009Publication date: January 21, 2010Inventors: Jiansheng FU, Yiting PENG, Xiaohui TIAN
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Publication number: 20090255442Abstract: A pearlescent pigment and a process for enhancing the magnetic properties of a pearlescent pigment. The pearlescent pigment has a layer with regions of ?-Fe2O3 and regions of ?-Fe2O3. The magnetic properties of a pearlescent pigment may be enhanced by the steps of: providing a platelet pigment with a layer of Fe2O3, with a magnetic susceptibility less than 0.1×10?5 m3/kg; reducing some or all of the Fe2O3 to Fe3O4; and oxidizing some or all of the Fe3O4 to ?-Fe2O3. The color difference (?E*) between the provided pigment and the resultant pigment is not more than about 5.Type: ApplicationFiled: April 9, 2008Publication date: October 15, 2009Inventors: Aaron M. Hollman, Philippe Schottland
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Patent number: 7578879Abstract: The present invention relates to surface-modified effect pigments based on flake-form substrates which are distinguished by the fact that they are sheathed with one or more layers of immobilized LCST and/or UCST polymers. The invention furthermore relates to a process for the production of the surface-modified effect pigments and to the use thereof in surface coatings, water-borne coatings, powder coatings, paints, printing inks, security printing inks, plastics, concrete, in cosmetic formulations, in agricultural sheeting and tarpaulins, for the laser marking of papers and plastics, as light protection, as pigment for corrosion protection and for the preparation of pigment compositions and dry preparations.Type: GrantFiled: September 4, 2003Date of Patent: August 25, 2009Assignee: Merck Patent GmbHInventors: Adalbert Huber, Marc Entenmann, Thadeus Schauer
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Patent number: RE41858Abstract: A pearlescent pigment based on a metal oxide-coated, platelet-shaped substrate and a top layer on the metal oxide layer, where the top layer comprises silicon dioxide, at least one further metal hydroxide or metal oxide hydrate and at least one organic coupling reagent. The further metal hydroxides or metal oxide hydrates are hydroxides or oxide hydrates of cerium, aluminum or zirconium, or mixtures thereof. The coupling reagents employed are organofunctional silanes, zirconium aluminates or metal acid esters.Type: GrantFiled: October 7, 2009Date of Patent: October 26, 2010Assignee: Merck Patent Gesellschaft MIT Beschrankter HaftungInventors: Joachim Duschek, Ralf Glausch