Iron Or Bismuth Compound Containing (fe Or Bi) Patents (Class 106/418)
  • Patent number: 5618343
    Abstract: The present invention relates to pigment and coating compositions that are used to prepare pigmented coatings that exhibit geometric metamerism or metallic flop. The pigment compositions comprise a small particle size pigment and a flop-enhancing agent, which flop-enhancing agent is a copper phthalocyanine, an indanthrone or a carbazole dioxazine compound. A method of enhancing the flop of a pigmented polymeric coating by incorporating one or more flop-enhancing agents into the composition is also disclosed.
    Type: Grant
    Filed: December 27, 1994
    Date of Patent: April 8, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Shivakumar B. Hendi, Edward E. Jaffe
  • Patent number: 5618342
    Abstract: The invention relates to a non-dusting, homogeneous pigment preparation containingat least 70% by weight of one or more flaky pigments,1-30% by weight of water,0.1-20% by weight of a humectant, andless than 1.00% by weight of one or more preservatives.
    Type: Grant
    Filed: June 2, 1994
    Date of Patent: April 8, 1997
    Assignee: Merck Patent Gesellschaft MIT Beschrankter Haftung
    Inventors: Gerhard Herget, Otto Stahlecker, Manfred Kieser
  • Patent number: 5603757
    Abstract: A photochromic brightening pigment comprises a brightening pigment and a photochromic material which is encapsulated so as to adhere it to the surface of the brightening pigment.
    Type: Grant
    Filed: March 14, 1995
    Date of Patent: February 18, 1997
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Katsumi Mizuguchi, Naoya Yabuuchi, Keizou Ishii
  • Patent number: 5554217
    Abstract: Disclosed is a process for coloring high-molecular-weight coatings and ink systems which comprises uniformly dispersing an effective pigmenting amount of a stir-in pigment in the coating or ink system; wherein the stir-in pigment is an organic pigment crude consisting essentially of non-platelet-shaped particles having an average particle size of from 0.5 to 25 .mu.m and/or a pigment composition consisting essentially of an organic pigment having an average particle size of from 0.01 to 25 .mu.m and inorganic filler pigment.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: September 10, 1996
    Assignee: Ciba-Geigy Corporation
    Inventor: Fridolin B abler
  • Patent number: 5540770
    Abstract: Luster pigments based on coated plateletlike substrates comprising nitrogen-containing metal layers and if desired additionally one or more layers consisting essentially of colorless or selectively absorbing metal oxide, are prepared and used for coloring paints, inks, including printing inks, plastics, glasses, ceramic products and decorative cosmetic preparations.
    Type: Grant
    Filed: June 16, 1995
    Date of Patent: July 30, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Raimund Schmid, Norbert Mronga, Harald Ochmann, J org Adel
  • Patent number: 5522923
    Abstract: A red pigment comprising: an iron oxide plate type particle, an aluminum compound layer which contains at least aluminum oxide and which is formed on the iron oxide particle, and the optical thickness of the aluminum compound layer being 150-500 nm. The red pigment according to the present invention has excellent color tone with high chroma from the orange to the blue red and moreover, and excellent stability.
    Type: Grant
    Filed: September 22, 1993
    Date of Patent: June 4, 1996
    Assignee: Shiseido Co., Ltd.
    Inventors: Asa Kimura, Fukuji Suzuki, Akiko Sato
  • Patent number: 5472491
    Abstract: A pearlescent pigment based on a metal oxide-coated, platelet-shaped substrate and a top layer on the metal oxide layer, where the top layer comprises silicon dioxide, at least one further metal hydroxide or metal oxide hydrate and at least one organic coupling reagent. The further metal hydroxides or metal oxide hydrates are hydroxides or oxide hydrates of cerium, aluminum or zirconium, or mixtures thereof. The coupling reagents employed are organofunctional silanes, zirconium aluminates or metal acid esters.
    Type: Grant
    Filed: June 24, 1994
    Date of Patent: December 5, 1995
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Joachim Duschek, Ralf Glausch
  • Patent number: 5472640
    Abstract: The application relates to conductive lamellar pigments in which lamellar substrate is coated with an electrically conductive layer, characterized in that a lamellar metal oxide or a lamellar material coated with one or more metal oxides is present as the lamellar substrate and that an optionally hydrated silicon dioxide layer or a layer of another insoluble silicate is arranged between the metal oxide layer and the conductive layer.
    Type: Grant
    Filed: April 22, 1994
    Date of Patent: December 5, 1995
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Hans D. Bruckner, Reiner Esselborn
  • Patent number: 5468289
    Abstract: The present invention relates to surface-modified pigments based on platelet-like substrates which, for improving the settling and redispersion behavior, have been recoated with a mixture comprising two metal oxides selected from the group consisting of silica, alumina and zirconium dioxide.
    Type: Grant
    Filed: September 30, 1994
    Date of Patent: November 21, 1995
    Assignee: Merck Patent Gesellschaft Mit Beschrankter Haftung
    Inventors: Gerhard Herget, Margarete Herbski, Karl Osterried
  • Patent number: 5445671
    Abstract: The present invention relates to a low-viscosity offset printing ink which essentially comprises a binder, additives and 5-40% by weight of pearlescent pigments and has an improved transfer behavior for pearlescent pigments.
    Type: Grant
    Filed: May 24, 1994
    Date of Patent: August 29, 1995
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Gerhard Herget, Wolfgang Hechler, Brigitte Husseini, Heinz Mohr, Rudiger Smolka
  • Patent number: 5441564
    Abstract: The invention relates to a pigment mixture containing a component A composed of at least one platelet-shaped interference pigment and a pigment B composed of at least one platelet-shaped color pigment.
    Type: Grant
    Filed: December 2, 1993
    Date of Patent: August 15, 1995
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventor: Reiner Vogt
  • Patent number: 5433779
    Abstract: A pearlescent pigment comprising micaceous particles having an adherent layer of rutile titanium dioxide thereon is prepared by effecting the deposition of hydrous titanium dioxide on the micaceous particles in the presence of iron and calcium, magnesium and/or zinc ions without the use of tin.
    Type: Grant
    Filed: November 7, 1994
    Date of Patent: July 18, 1995
    Assignee: The Mearl Corporation
    Inventor: Carmine V. DeLuca, Jr.
  • Patent number: 5423912
    Abstract: A titanium dioxide- or iron oxide-coated mica pearlescent pigment having a coating which contains a combination of hydrated cerium and aluminum oxides has enhanced weatherstability.
    Type: Grant
    Filed: October 21, 1993
    Date of Patent: June 13, 1995
    Assignee: The Mearl Corporation
    Inventors: William J. Sullivan, Deborah Cacace
  • Patent number: 5407746
    Abstract: The application relates to deagglomerated and readily dispersible platelet-like substrates with a high degree of softness, which are characterized by a content of 0.5-20% by weight of spherical particles having a small diameter in comparison with the platelet-like substrate, and to a process for their preparation and their use.
    Type: Grant
    Filed: September 28, 1993
    Date of Patent: April 18, 1995
    Assignee: Merck Patent Gesellschaft Mit Beshrankter Haftung
    Inventors: Constanze Prengel, Johann Dietz, Angelika Thurn-Muller
  • Patent number: 5380360
    Abstract: Disclosed are a flaky pigment in which the surfaces of fine flaky grains, as a pigment base, have been coated with ultra-fine barium sulfate grains having a mean grain size of 0.1 .mu.m or less. The pigment is produced by a process comprising reacting:(a) an aqueous solution containing a complexing agent capable of forming a complex compound with barium ion, as dissolved therein;(b) an aqueous solution containing a water-soluble barium compound as dissolved therein; and(c) an aqueous solution containing sulfate ion. The invention involves this method of preparing the flaky pigment, and use of the pigment in pigment coloration of cosmetics, top coats for cars, plastics, printing inks, domestic electrical appliances, coating materials and coating paints for building materials.
    Type: Grant
    Filed: April 12, 1993
    Date of Patent: January 10, 1995
    Assignee: Merck Patent Gesellschaft Mit Beschrankter Haftung
    Inventors: Tamio Noguchi, Yumiko Waragai
  • Patent number: 5344488
    Abstract: The application relates to pigments based on plate-like substrates which, if desired, are covered with one or more layers comprising metal oxides or metal oxide mixtures, zinc oxide being deposited on the surface of the substrates with the formation of a not entirely continuous layer.
    Type: Grant
    Filed: February 24, 1993
    Date of Patent: September 6, 1994
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Peter Reynders, Hans D. Bruckner
  • Patent number: 5326392
    Abstract: Platy pigments with good tactile characteristics are obtained by treating such pigments with a compound of the general formula: ##STR1## where m is an even number from 8 to 18 and n is 3 or 4 under defined conditions. N.epsilon.-lauroyl lysine is preferred. The pigments are especially useful in cosmetic compositions such as eye shadow.
    Type: Grant
    Filed: July 20, 1993
    Date of Patent: July 5, 1994
    Assignee: The Mearl Corporation
    Inventors: Harold A. Miller, Philip Greenberg, Adolph Blum, Wasi Ahmed
  • Patent number: 5320674
    Abstract: A composite synthetic mica powder having an excellent ultraviolet ray screening effect, the composite synthetic mica powder comprising a fine particle layer (B) containing one or more types of elements selected from the group of Te, Bi, Pb, Ce, Fe, Mo, Nb, W, Sb, Sn, V, Mn, Ni, Co, Zn and Ti is formed on the surface of scale-like mica particles (A). The covering ratio of particles (A) by particles (B) is in the range of 0.5 to 1; the ratio of particle size of the particles (B) to plane direction diameter of the particles (A) is 0.1 or less; and particle size of the particles (A) is 1 to 100 .mu.m. Also, a red synthetic mica which develops light-resistant red color closer to the color of human skin and ultraviolet rays, a method for manufacturing the same, and an ultraviolet ray screening agent which contains the synthetic mica. The synthetic mica is expressed by the following formula (I):X.sub.1/3.about.1 Y.sub.2.about.3 (Z.sub.4 O.sub.10)F.sub.2.times.0.75.about.2.times.0.
    Type: Grant
    Filed: September 2, 1992
    Date of Patent: June 14, 1994
    Assignees: Topy Industries, Limited, Shiseido Company, Ltd.
    Inventors: Yuji Takao, Akitsugu Ando, Tetsusi Kosugi, Fukuji Suzuki, Kazuhisa Ohno, Katsuki Ogawa
  • Patent number: 5286291
    Abstract: The invention relates to a pigment containing carbon black having improved abrasion resistance comprising a platelet-shaped substrate coated with a metal oxide layer containing carbon black, wherein the carbon black is fixed on the substrate by means of an anionic or cationic and a nonionic surfactant and an organosilane compound.
    Type: Grant
    Filed: July 7, 1993
    Date of Patent: February 15, 1994
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Klaus Bernhardt, Gerhard Pfaff
  • Patent number: 5277711
    Abstract: Mixtures useful as luster pigments for coloring paints, printing inks, plastics, decorative cosmetic preparations and ceramic products and usable in dry form in printing and coating processes consist ofA) iron oxide-coated aluminum particles andB) iron oxide-coated mica particles with or without a prior coating of a colorless, highly refractive metal oxide as essential components.
    Type: Grant
    Filed: March 9, 1993
    Date of Patent: January 11, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Helmut Schmidt, Werner Ostertag, Norbert Mronga, Raimund Schmid
  • Patent number: 5273576
    Abstract: Iron oxide-coated micaceous pigments having a chroma enhancing amount of a coating of a colorless metal oxide which has a refractive index of at least about 2.0 exhibit intensely colored effects.
    Type: Grant
    Filed: October 19, 1992
    Date of Patent: December 28, 1993
    Assignee: Mearl Corporation
    Inventors: William J. Sullivan, Thomas J. Birch
  • Patent number: 5271770
    Abstract: A pigment comprising leaf-like substrates particles having a particle size of 0.5 to 100 .mu.m, whereby the surface of said particles is covered with a metal oxide comprising titanium oxide and zirconium oxide in a molar ratio of 10:1 to 10:15 within a range of from 20 wt. % to 60 wt. % based on the total weight of the pigment possesses good adhesion and spreadability and has an effect of preventing ultraviolet rays and infrared rays.
    Type: Grant
    Filed: September 29, 1992
    Date of Patent: December 21, 1993
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Tamio Noguchi, Tamio Aikawa
  • Patent number: 5266107
    Abstract: A pearlescent pigment comprising a platelet-shaped substrate coated with titanium dioxide, an oxide of copper, and optionally oxides of aluminum, and/or zinc, whereby the pigment is silver-gray.
    Type: Grant
    Filed: December 21, 1992
    Date of Patent: November 30, 1993
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventor: Paul R. Hoffman
  • Patent number: 5246492
    Abstract: The present invention provides a paint composition which contains a non-glorious color pigment and a scaly glorious color pigment, wherein both the contained non-glorious color pigment and scaly glorious color pigment are selected so as not to be similar colors.
    Type: Grant
    Filed: June 14, 1990
    Date of Patent: September 21, 1993
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Masamichi Arima, Yoshiyuki Yoneda, Tetsuo Masuno
  • Patent number: 5242614
    Abstract: A soap bar having the appearance of a polished wood grain is prepared by mixing the soap formulation with an iron oxide coated micaceous pearlescent pigment and extruding the combination such that the iron oxide coated micaceous pearlescent pigment is oriented generally unidirectionally.
    Type: Grant
    Filed: August 17, 1992
    Date of Patent: September 7, 1993
    Assignee: The Mearl Corporation
    Inventors: Erika M. Baumgartner, Philip Greenberg, Harold A. Miller
  • Patent number: 5196131
    Abstract: A soap bar having the appearance of a polished wood grain is prepared by mixing the soap formulation with an iron oxide coated micaceous pearlescent pigment and extruding the combination such that the iron oxide coated micaceous pearlescent pigment is oriented generally unidirectionally.
    Type: Grant
    Filed: November 26, 1990
    Date of Patent: March 23, 1993
    Assignee: The Mearl Corporation
    Inventors: Erika M. Baumgartner, Philip Greenberg, Harold A. Miller
  • Patent number: 5156678
    Abstract: Effect pigments based on interference pigments coated with phthalocyanine or metal phthalocyanine dyes, characterized in that the dyes are applied to the pigments as a strongly adhering film without the aid of binders or other auxiliary materials, are outstandingly suitable for use in formulations such as paints, dyes, plastics and cosmetics.
    Type: Grant
    Filed: March 25, 1991
    Date of Patent: October 20, 1992
    Assignee: Merck Patent Gesellschaft mit beschraenkter Haftung
    Inventor: Ralf Glausch
  • Patent number: 5154765
    Abstract: An article exhibiting a multicolor effect is obtained by combining a transparent substrate, an interference pigment and an absorption colorant, the pigment and colorant preferably united in the form of a combination pigment, in which the absorption colorant is of a color which is different from the transmission color of the interference pigment or the complement thereof.
    Type: Grant
    Filed: December 11, 1990
    Date of Patent: October 13, 1992
    Assignee: The Mearl Corporation
    Inventor: Louis Armanini
  • Patent number: 5149369
    Abstract: Bismuth oxychloride nacreous pigment coated with a rare earth metal compound is described. The coated pigment is prepared by adding a rare earth metal salt solution to a suspension of bismuth oxychloride pigment crystals to form a further suspension containing the pigment crystals and cerium hydroxide. The cerium hydroxide is then precipitated out of the further suspension to coat the pigment crystals. The coated pigment is endowed with improved weather fastness.
    Type: Grant
    Filed: January 6, 1992
    Date of Patent: September 22, 1992
    Assignee: Mearl Corporation
    Inventors: Robert E. Eberts, Robert M. Juby, II, Michael T. Venturini, II
  • Patent number: 5143548
    Abstract: Disclosed herein is a coating composition comprising plate-like iron oxide particles having an average particle diameter of 4 to 25 .mu.m, a lamellar thickness of 0.16 to 5 .mu.m and a plate ratio (average particle diameter:lamellar thickness) of 5:1 to 25:1, at least one pigment selected from the group consisting of a coloring pigment,a mica pigment and a metal powder pigment, a film-forming polymer, and an organic solvent.
    Type: Grant
    Filed: December 3, 1991
    Date of Patent: September 1, 1992
    Assignees: Toda Kogyo Corp., Dainichiseika Color & Chemicals Mfg. Co. Ltd.
    Inventors: Ken Okura, Satoru Matsuzaki, Tsutomu Katamoto, Nanao Horiishi
  • Patent number: 5112403
    Abstract: Disclosed herein is a coating composition comprising plate-like iron oxide particles having an average particle diameter of 0.5 to 5.0 .mu.m, a lamellar thickness of 50 to 500.ANG. and a plate ratio (the ratio of the average particle diameter to the lamellar thickness) of 50:1 to 500:1, at least one pigment selected from the group consisting of a coloring pigment, a mica pigment and a metal powder pigment, a film-forming polymer, and an organic solvent.
    Type: Grant
    Filed: September 11, 1991
    Date of Patent: May 12, 1992
    Assignees: Toda Kogyo Corp., Dainic Iseika Color & Chemicals Mfg. Co. Ltd
    Inventors: Ken Okura, Satoru Matsuzaki, Tsutomu Katamoto, Nanao Horiishi
  • Patent number: 5106419
    Abstract: Colored pigments having an improved stability in decorative colors, engobes, glazes, and enamels, based on platelet-type substrates coated with metal oxides, in which the coating is free from alkaline earth metal oxides and contains a colored metal oxide or metal hydroxide and at least 10% by weight of aluminum oxide, are outstandingly suitable for pigmenting glazes and enamels.
    Type: Grant
    Filed: March 7, 1991
    Date of Patent: April 21, 1992
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventors: Wolfgang Hechler, Karl Osterried, Manfred Weigand
  • Patent number: 5091011
    Abstract: Metal oxide coated mica pigments are provided with enhanced light and moisture stability by providing on the particle surfaces a coating of hydrous aluminum oxide.
    Type: Grant
    Filed: March 12, 1990
    Date of Patent: February 25, 1992
    Assignee: The Mearl Corporation
    Inventor: Carmine V. DeLuca, Jr.
  • Patent number: 4956019
    Abstract: Flaky colored pigment comprising fine flaky powder as base material, and zinc oxide and an inorganic color pigment attached to the surface thereof.
    Type: Grant
    Filed: August 13, 1987
    Date of Patent: September 11, 1990
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Tamio Noguchi, Takaji Watanabe
  • Patent number: 4946641
    Abstract: A metallic, gold colored composition comprising an olefin polymer, a mica-based gold pigment, a mica-based bronze pigment, carbon black, and optionally, a yellow pigment is provided. Additionally, a process to produce a glossy, metallic, gold colored polyolefin product in a grit blasted mold is provided.
    Type: Grant
    Filed: December 9, 1988
    Date of Patent: August 7, 1990
    Assignee: Phillips Petroleum Company
    Inventor: Majorie B. Skinner
  • Patent number: 4921542
    Abstract: Iron oxide black pigments useful as coloring pigments for lacquers and plastics are prepared by an improved process wherein finely divided iron oxide black suspensions obtained from the precipitation processor the aniline process are filtered, washed, dried and ground with the improvement in the process comprising grinding the dried iron oxide pigment in a jet mill with air as the grinding medium and with a water content of from about 1 to 6% by weight based on the iron oxide black pigment input to the process.
    Type: Grant
    Filed: September 28, 1988
    Date of Patent: May 1, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jakob Rademachers, Karl-Werner Ganter, Wolfgang Rambold, Gunter Linde
  • Patent number: 4915742
    Abstract: Iron blue characterized by an ammonium content of .+-.5.5 weight %, a potassium content of <0.1 weight %, a sodium content of <0.1 weight %, a color strength in a toluene intaglio printing ink up to 15% greater than the standard Vossen blue 705/80 (calculated in accordance with DIN 53 234) and the color spacings (determined in accordance with DIN 6174 relative to Vossen blue 705/80 as standard) of.DELTA.a*:6.5.+-.0.5.DELTA.b*:1.3.+-.0.3.DELTA.c*:-1.5.+-.0.5It is prepared by placing an aqueous solution of sodium hexacyanoferrate (II) in a reaction vessel at a pH of 7.0 and a concentration of 45.+-.5 g/l, calculated as Fe(CN).sub.6 together with ammonium sulfate having a concentration of 14.+-.1 g/l at a temperature of 22.degree.-23.degree. C., adding an aqueous iron-II sulfate solution at a pH of 2.0, a concentration of 100.+-.10 g/l, and a temperature of 22.degree.-23.degree. C., and precipitating the white dough until an excess of iron up to 1.4-1.
    Type: Grant
    Filed: December 9, 1988
    Date of Patent: April 10, 1990
    Assignee: Degussa Aktiengesellschaft
    Inventors: Everhard Gratzfeld, Eva Clausen, Heinrich Winkeler
  • Patent number: 4913063
    Abstract: Improved iron oxide pigments useful in the manufacture of magnetic recording carriers or for coloring inorganic or organic materials are iron oxide pigments having an iron (II) content of at least 5% by weight calculated as FeO after-treated with a phenolic compounds of the formula ##STR1## wherein X is O or NH, andR is straight chained or branched alkyl with 1 to 30 carbon atoms, alkenyl with 2 to 30 carbon atoms, cycloalkyl with 5 to 12 carbon atoms, or hydrogen.
    Type: Grant
    Filed: July 25, 1988
    Date of Patent: April 3, 1990
    Assignee: Bayer Aktiensegellschaft
    Inventors: Friedrich Jonas, Peter R. Schick, Jurgen Wiese
  • Patent number: 4828826
    Abstract: A cosmetic formulation comprising a cosmetically compatible adjuvant and particles of at least one colored pigment is improved by using as the colored pigment a synthetic platelet-shaped iron oxide pigment. The resulting pigment enables improved skin feel in cosmetic preparations.
    Type: Grant
    Filed: October 22, 1987
    Date of Patent: May 9, 1989
    Assignee: Merck Patent Gesellschaft Mit Beschrankter Haftung
    Inventors: Klaus D. Franz, Andrea Griessmann, Gisela Lenz, Gernot Moschl
  • Patent number: 4798766
    Abstract: A method is described in which a layered lattice silicate is surface modified with an organic material by reacting said layered lattice silicate in particulate form with a reactant system comprising gaseous NH.sub.3 at temperatures below about 1000.degree. C. and contacting the aminated silicate in particulate form with an organic compound selected from the group of monomers, co-monomers, prepolymers and compounds condensable with the amine group, such as a nylon precursor, in the presence of gaseous hydrogen. The surface modified silicates are useful as fillers in a filled polymer system comprising a matrix polymer and a filler.
    Type: Grant
    Filed: August 26, 1987
    Date of Patent: January 17, 1989
    Assignee: E.C.C. America Inc.
    Inventor: Camilla A. Rice
  • Patent number: 4780140
    Abstract: The invention relates to platelet-shaped pigments of the formula Al.sub.x Fe.sub.2-x O.sub.3-y, wherein x has a value from 0.02 to 0.5 and y has a value from 0.3 to 1.0, which are optionally coated with further oxides.
    Type: Grant
    Filed: October 22, 1987
    Date of Patent: October 25, 1988
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Klaus D. Franz, Reiner Esselborn, Ralf Emmert, Hans D. Bruckner
  • Patent number: 4773938
    Abstract: Finely divided magnetic particles of hexaferrite pigments with a W-structure having the compositionE.sub.x M.sub.m (I) M.sub.n (II) Fe.sub.18 -(m+n)O.sub.27-y D.sub.ywhereinE is at least one element from the group comprising alkaline earth metals, alkali metals, lanthanides or lead,M(I) and M(II) are independently at least element from the group comprising metals or semi-metals andD is at least one element from the group of halogens and chalcogens and0.8.ltoreq.x.ltoreq.1.2,1.0.ltoreq.m.ltoreq.3.0,0.ltoreq.n.ltoreq.8.0,0.ltoreq.y.ltoreq.5.
    Type: Grant
    Filed: October 14, 1986
    Date of Patent: September 27, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gunter Buxbaum, Ulrich Meisen, Florian Haberey
  • Patent number: 4755229
    Abstract: Dispersed insoluble colored pigments are coated on the surface of mica and oxide-coated mica pigments by deposition in a precipitate of a polyvalent cation and an anionic polymeric substance. The resulting combination pigments have more than one color, depending on the angle of viewing.
    Type: Grant
    Filed: February 9, 1987
    Date of Patent: July 5, 1988
    Assignee: The Mearl Corporation
    Inventor: Louis Armanini