Aluminum Compound Or Silicon Containing, E.g., Clay, Etc. Patents (Class 106/426)
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Patent number: 11471549Abstract: Provided is a stretchable film having excellent stretchability, excellent air permeability, and an excellent deodorizing property. Also provided is an article including such stretchable film. A stretchable film of the present invention is a film having stretchability, and includes a deodorant. The stretchable film of the present invention is a film having stretchability, and has a deodorization efficiency for each of ammonia and hydrogen sulfide 3 hours after the start of a deodorization test, the deodorization efficiency being measured by a detector tube method, of 10% or more.Type: GrantFiled: September 14, 2017Date of Patent: October 18, 2022Assignee: NITTO DENKO CORPORATIONInventors: Muneshige Nakagawa, Kohei Takeda, Shinsuke Ikishima
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Patent number: 11458674Abstract: A device and production method, in which a workpiece is built up gradually in layers. To build up the workpiece, preformed layers, which are individually formed on a layer support using an electrophotographic printing process are transferred one at a time from the layer support to the workpiece. For this purpose, the layer is transferred to the workpiece in a printing operation, the layer being preferably laid on the workpiece by a die. In one embodiment, a plurality of workpieces are built up simultaneously and a plurality of preformed layers are transferred simultaneously to different respective workpieces. In another embodiment, the layer is formed on the layer support, which is preferably a film or paper, prior to being transferred.Type: GrantFiled: October 13, 2016Date of Patent: October 4, 2022Assignee: M & R BETEILIGUNGSGESELLSCHAFT MBHInventor: Michael Zimmer
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Patent number: 10584927Abstract: A thermal coupling assembly for facilitating thermal transfer between a heat source and a heat sink is provided herein. The thermal coupling assembly includes a thermally conductive element, an insulative wrap, and a cover. The thermally conductive element includes a first end wall configured to engage a surface of the heat source, a second end wall configured to engage a surface of the heat sink, and a body including a thermal conductor. The insulative wrap at least partially surrounds the thermally conductive element, the heat source, and the heat sink. The cover at least partially surrounds at least one of said insulative wrap, the thermally conductive element, the heat source, and the heat sink.Type: GrantFiled: December 30, 2015Date of Patent: March 10, 2020Assignee: General Electric CompanyInventors: Caner Karatas, Hasan Yoruk
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Patent number: 10458016Abstract: A method for forming a protective film is provided. In the method, a source gas containing an organic metal gas or an organic semi-metal gas is supplied to a substrate having a plurality of recessed shapes formed in a surface so as to cause the source gas to adsorb on the surface of the substrate including the plurality of recessed shapes. Then, an oxidation gas is supplied to the surface of the substrate including the plurality of recessed shapes to oxidize the source gas adsorbed on the surface of the substrate, thereby depositing an oxidation film of the organic metal or the organic semi-metal on a flat area between the plurality of recessed shapes. Supplying the source gas to the substrate and supplying the oxidation gas to the substrate are repeated at a rate in a range of 90 to 300 cycles per minute.Type: GrantFiled: December 19, 2016Date of Patent: October 29, 2019Assignee: Tokyo Electron LimitedInventors: Takeshi Kumagai, Yutaka Takahashi, Chihhsiang Hsiao, Atsushi Endo
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Patent number: 9505615Abstract: A method for controlling the microstructural arrangement of nominally-aligned arrays of carbon nanotubes (CNTs) and a foam structure of CNTs are disclosed. The method includes a functionalization of CNT surfaces, for example, a non-covalent functionalization. The non-covalent functionalization of CNT surfaces can be obtained by way of a wetting process, for example by the use of a solution of surfactant or silica (SiO2) nanoparticles to wet the CNTs. In particular, the CNT array is first detached from the growth substrate and then a functionalization substance (surfactant or SiO2) is added to the CNT array. The functionalization substance can be dissolved in a volatile solvent, such that CNT arrays densify after the solvent evaporates. A method for synthesizing nominally-aligned arrays of carbon nanotubes (CNTs) is further disclosed, wherein the synthesizing method is combined with the wetting process.Type: GrantFiled: April 23, 2013Date of Patent: November 29, 2016Assignee: CALIFORNIA INSTITUTE OF TECHNOLOGYInventors: Abha Misra, Chiara Daraio, Jordan R. Raney
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Publication number: 20140256866Abstract: This invention relates to megakalsilite platelets, methods of hydrothermally forming said platelets and the megakalsilite platelets obtainable via the disclosed hydrothermal method. More specifically the disclosure describes an improved hydrothermal synthesis of megakalsilite platelets, which are suitable as platelet for interference pigments, and in barrier and flame retardant applications.Type: ApplicationFiled: March 11, 2014Publication date: September 11, 2014Inventors: Meaghan Clark McGuire, Ivor Bull, Geoffrey Mark Johnson
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Patent number: 8821627Abstract: The present invention relates to effect pigments based on substrates having an outer coating comprising metal oxide, hydroxide and/or oxide hydrate and at least one organic coupling agent.Type: GrantFiled: October 12, 2011Date of Patent: September 2, 2014Assignee: Merck Patent GmbHInventor: Koshiro Kunii
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Patent number: 8771717Abstract: The present invention relates to pigments, comprising a plate-like substrate of perlite which does not contain 3D twin structure particles contained in milled expanded perlite in an amount of greater than 5% by weight., and (a) a dielectric material, especially a metal oxide, having a high index of refraction; and/or (a) a metal layer, especially a thin semi-transparent metal layer; a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass.Type: GrantFiled: December 1, 2009Date of Patent: July 8, 2014Assignee: BASF SEInventors: Patrice Bujard, Marc Baysang, Philippe Bugnon
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Publication number: 20140102333Abstract: The disclosure provides a treated inorganic particle, in particular a titanium dioxide particle, having reduced photoactivity, lower acid solubility and improved anti-microbial properties comprising: an inorganic core particle, in particular a titanium dioxide particle; a first treatment of silica, wherein the silica is added in a single step; and a second treatment comprising co-precipitated zinc oxide and alumina. These particles have reduced photoactivity, lower acid solubility and improved anti-microbial properties.Type: ApplicationFiled: June 20, 2012Publication date: April 17, 2014Applicant: E I DU PONT DE NEMOURS AND COMPANYInventor: Charles David Musick
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Publication number: 20140080952Abstract: A thermally conductive filler composition and a resin composition comprising such filler compositions. The filler composition comprises a blend of a boron nitride, a metal oxide, and a silane. The filler composition can further comprise other filler components including, for example, glass fiber or glass flake. The filler compositions can be added to a resin composition to provide a thermally conductive resin such as, for example, a thermally conductive plastic.Type: ApplicationFiled: March 14, 2013Publication date: March 20, 2014Inventors: Chandrashekar Raman, Bei Xiang, Anand Murugaiah
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Patent number: 8647429Abstract: The present invention relates to effect pigments based on uncoated or coated flake-form substrates having an outer coating comprising a) TiO2 and b) Al2O3, MgO and/or CaO and c) SiO2 and d) ZnO and/or e) at least one mixed oxide of the elements mentioned under a) to d), and to the use thereof, inter alia in paints, coatings, printing inks, plastics and cosmetic formulations.Type: GrantFiled: February 2, 2011Date of Patent: February 11, 2014Assignee: Merck Patent GmbHInventors: Sabine Melson, Volker Wilhelm, Ulrich Schoenefeld
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Publication number: 20140031455Abstract: The present invention relates to a method for producing a compound that comprises a pseudolaminar silicate of natural origin, which is at least one clay of the paligorskite-sepiolite group, characterized in that said method comprises the following steps: defibrillating the microfibre bundles of the at least one clay in water; dispersing the defibrillated clay in an organic or inorganic liquid solvent until a stable gel is formed; adding to the dispersion at least one clay-surface-modifying agent; removing the solvent from the dispersion by means of a solid-liquid separation process and/or drying process; and deagglomerating the final compound until a powdered product is obtained. A further object of the present invention is the compound that can be obtained using said method, as well as the use of the compound as an additive or filler in composite polymeric materials in order to enhance the properties thereof, the composite polymeric material likewise being encompassed within the present invention.Type: ApplicationFiled: January 30, 2012Publication date: January 30, 2014Inventors: Julio Santarén Romé, Eduardo Aguilar Diez, Antonio Esteban Cubillo, Antonio Álvarez Berenguer, Esperanza Benito Cano, Nuria García García, Julio Guzmán Perote, Pilar Tiemblo Magro
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Patent number: 8524261Abstract: The present invention relates to inorganic spherical pigments which are based on spherical particles having a particle diameter of 0.1-100 ?m and are coated on the surface with agglomerates selected from the group ZrO2, ZnO, Al2O3, TiO2, Fe2O3, Fe3O4, FeOOH and BaSO4 or mixtures thereof, and are optionally coated with a further layer (2nd layer) comprising a metal oxide, lake or Berlin Blue, and to the use thereof in paints, coatings, printing inks, security printing inks, plastics, ceramic materials, glasses, in cosmetic formulations, as tracer, as filler and for the preparation of pigment preparations and dry preparations.Type: GrantFiled: October 26, 2010Date of Patent: September 3, 2013Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventors: Christoph Schmidt, Sabine Schoen
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Publication number: 20130213260Abstract: The present invention relates to effect pigments based on substrates having an outer coating comprising metal oxide, hydroxide and/or oxide hydrate and at least one organic coupling agent.Type: ApplicationFiled: October 12, 2011Publication date: August 22, 2013Applicant: Merck Patent GmbHInventor: Koshiro Kunii
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Publication number: 20130125789Abstract: Provided is a manufacturing method for a refractory filler, comprising melting a raw material batch and cooling the resultant melt to precipitate willemite as a main crystal phase.Type: ApplicationFiled: April 18, 2011Publication date: May 23, 2013Inventors: Tomoko Enomoto, Hiroyuki Okamura, Nobutoshi Ito
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Publication number: 20120308667Abstract: The present invention relates to effect pigments based on uncoated or coated flake-form substrates having an outer coating comprising a) TiO2 and b) Al2O3, MgO and/or CaO and c) SiO2 and d) ZnO and/or e) at least one mixed oxide of the elements mentioned under a) to d), and to the use thereof, inter alia in paints, coatings, printing inks, plastics and cosmetic formulations.Type: ApplicationFiled: February 2, 2011Publication date: December 6, 2012Applicant: MERCK PATENT GESELLSCHAFT MIT BESCHRANKTER HAFTUNGInventors: Sabine Melson, Volker Wilhelm, Ulrich Schoenefeld
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Publication number: 20120296025Abstract: The invention provides a treated powder having improved loose bulk density comprising a silanized inorganic powder treated with a long chain fatty acid or salts thereof, wherein the amount of the long chain fatty acid is about 0.25% to about 2 wt %, based on the total weight of the treated powder.Type: ApplicationFiled: July 27, 2012Publication date: November 22, 2012Applicant: E I DU PONT DE NEMOURS AND COMPANYInventors: Timothy Allan Bell, Joy Sawyer Bloom
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Patent number: 8287636Abstract: The present invention relates to a pearlescent pigment with large aspect ratio and a method of their preparation, and particularly to pearlescent pigments prepared by coating a metal or metal precursor on the flaky alpha-alumina crystals obtained by using an aluminum precursor aqueous solution and a zinc precursor aqueous solution as main ingredients. The crystals herein has an average particle thickness of 0.5 ?m or less, an average particle diameter of 15 ?m or higher and a large aspect ratio of 50 or higher, thereby being superior in gloss. The crystals show metal colors and interference colors of silver, gold, red, purple, blue and green.Type: GrantFiled: July 24, 2007Date of Patent: October 16, 2012Assignees: Korea Research Institute of Chemical Technology, CQV Co., Ltd.Inventors: Jung Min Lee, Jeong Kwon Suh, Byung Ki Park, Dong Uk Choe, Gil Wan Chang, Kwang Su Lim, Sung Yun Jo, Kwang Choong Kang
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Publication number: 20110269845Abstract: The present invention relates to pigments, comprising a plate-like substrate of perlite which does not contain 3D twin structure particles contained in milled expanded perlite in an amount of greater than 5% by weight, and (a) a dielectric material, especially a metal oxide, having a high index of refraction; and/or (a) a metal layer, especially a thin semi-transparent metal layer; a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass.Type: ApplicationFiled: December 1, 2009Publication date: November 3, 2011Applicant: BASF SEInventors: Patrice Bujard, Marc Baysang, Philippe Bugnon
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Publication number: 20110172327Abstract: A method of treating filler can include the steps of providing the filler, disposing silica within the filler so that a bulk density of the filler is approximately 24 to 26 pounds per cubic feet, forming a silane compound that includes silane and paraffin wax, and combining the silane compound with the filler.Type: ApplicationFiled: January 8, 2010Publication date: July 14, 2011Applicant: General Cable Technology CorporationInventors: David CAMILLO, Mark R. EASTER
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Patent number: 7959727Abstract: The present invention relates to pigments, the particles of which generally have a length of from 2 ?m to 5 mm, a width of from 2 ?m to 2 mm, and a thickness of from 20 nm to 2 ?m, and a ratio of length to thickness of at least 2:1, wherein the particles contain a core of SiO2 or a silicon/silicon oxide obtained by heating SiOy flakes with 1.1?y?1.8 in an oxygen-free atmosphere at a temperature of at least 400° C., which core has a narrow distribution of particle sizes and two substantially parallel faces, the distance between which is the shortest axis of the core, and a material layer having a high index of refraction a metal oxide; a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass.Type: GrantFiled: February 26, 2009Date of Patent: June 14, 2011Assignee: BASF SEInventors: Patrice Bujard, Holger Leybach
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Patent number: 7955430Abstract: A coating material comprising a binding agent and at least one filler including particles having a size and/or surface roughness of about 100 ?m or less, and a photocatalytically active agent. The binding agent may be at least partially decomposed by a photocatalytic action, and a microstructured, self-cleaning surface may be formed.Type: GrantFiled: April 15, 2005Date of Patent: June 7, 2011Assignee: STO AGInventor: Peter Grochal
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Publication number: 20110104220Abstract: The present invention relates to inorganic spherical pigments which are based on spherical particles having a particle diameter of 0.1-100 ?m and are coated on the surface with agglomerates selected from the group ZrO2, ZnO, Al2O3, TiO2, Fe2O3, Fe3O4, FeOOH and BaSO4 or mixtures thereof, and are optionally coated with a further layer (2nd layer) comprising a metal oxide, lake or Berlin Blue, and to the use thereof in paints, coatings, printing inks, security printing inks, plastics, ceramic materials, glasses, in cosmetic formulations, as tracer, as filler and for the preparation of pigment preparations and dry preparations.Type: ApplicationFiled: October 26, 2010Publication date: May 5, 2011Applicant: MERCK PATENT GESELLSCHAFT MIT BESCHRANKTER HAFTUNGInventors: Christoph SCHMIDT, Sabine SCHOEN
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Publication number: 20110011309Abstract: The present disclosure provides an exoergic filler composition which is able to exert superior exoergic property, and a resin composition, a grease, and a coating composition which having superior exoergic property, respectively, by using the above-mentioned exoergic filler composition. The exoergic filler composition contains 1 to 50 volume % of a needle-shaped zinc oxide having an average long diameter of 0.1 to 10 ?m, an average short diameter of 0.025 to 2.5 ?m, aspect ratio defined by (average long diameter)/(average short diameter) of 4 or more and specific surface area according to BET method of 50 m2/g or less, and 50 to 99 volume % of other exoergic filler.Type: ApplicationFiled: July 14, 2009Publication date: January 20, 2011Applicant: Sakai Chemical Industry Co., Ltd.Inventors: Ken-Ichi Nakagawa, Masahiro Suzuki
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Patent number: 7837781Abstract: A pigment of empirical composition (TiO2)a(ZnO)b(SnO)c(SnO2)d(RExOy)e(AEO)f(MuOv)g wherein RE is a metal from transition group 3 or a rare earth metal, AE is an alkaline earth metal, and M is any other metal, where a=0.8-3; b=0.5-1.3; c=0.5-1.3; d=0-0.5; e=0-0.3; f=0-0.3; and g=0-0.1, and e+f?0.01. Preferably RE is selected from the elements Y, La, Ce, and Pr. The pigments are used as colorants for coloring paints, inks, plastics, and rubber.Type: GrantFiled: December 17, 2007Date of Patent: November 23, 2010Assignee: BASF SEInventors: Norbert Mronga, Kirill Bramnik
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Publication number: 20100255047Abstract: The present invention relates to effect pigments based on thin glass flakes and to a method for the production of such pigments. The resulting pigment can be used in any application for which pearlescent pigments have been heretofore used such as, for example, in plastics, paints, inks, cosmetic formulations, coatings including solvent or waterborne automotive paint systems, powder coatings, inks and agriculture foils.Type: ApplicationFiled: June 16, 2010Publication date: October 7, 2010Inventors: Ralf ANSELMANN, Klaus Ambrosius, Marcus Mathias
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Patent number: 7749320Abstract: A process for the production of finely particulate, inorganic solids by precipitation of the finely particulate inorganic solids from solution is described, in which the surface of the inorganic solids particles is covered (coated) with at least one additive, in which the additive(s) contains a dispersing agent or deflocculating agent, in which the proportion of the additives is overall at most 80 wt. %, preferably at most 40 wt. % or 30 wt. % and particularly preferably at most 15 wt. % of the coated solids, and wherein the additive(s) is added to the starting solution or solutions. Uses of the inorganic solids produced according to the invention are also described.Type: GrantFiled: August 20, 2004Date of Patent: July 6, 2010Assignee: Sachtleben Chemie GmbHInventor: Djamschid Amirzadeh-Asl
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Patent number: 7658793Abstract: The invention relates to a pigment preparation based on at least one inorganic pigment and at least one organic pigment, and to a method for producing one such pigment preparation. Said pigment preparation contains particles wherein fine organic pigment particles are combined with inorganic pigment particles, said particles also being provided with an organic macromolecular coating. The inventive pigment preparation is produced by wet-grinding the inorganic and organic pigments, optionally adding other constituents, in the presence of a surface-active substance in the form of a macromolecular organic compound.Type: GrantFiled: March 5, 2004Date of Patent: February 9, 2010Assignee: Heubach GmbHInventors: Rainer Heubach, Yvonne Brussaard, Hugo Brussaard
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Publication number: 20090320719Abstract: The present invention relates to a pearlescent pigment with large aspect ratio and a method of their preparation, and particularly to pearlescent pigments prepared by coating a metal or metal precursor on the flaky alpha-alumina crystals obtained by using an aluminum precursor aqueous solution and a zinc precursor aqueous solution as main ingredients. The crystals herein has an average particle thickness of 0.5 ?m or less, an average particle diameter of 15 ?m or higher and a large aspect ratio of 50 or higher, thereby being superior in gloss. The crystals show metal colors and interference colors of silver, gold, red, purple, blue and green.Type: ApplicationFiled: July 24, 2007Publication date: December 31, 2009Inventors: Jung Min Lee, Jeong Kwon Suh, Byung Ki Park, Dong Uk Choe, Gil Wan Chang, Kwang Su Lim, Sung Yun Jo, Kwang Choong Kang
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Patent number: 7611815Abstract: An external additive for a toner for electrophotography which contains oxide fine particles which contain silicon, in which the oxide fine particles have a primary particle diameter of 30 nm to 300 nm in number average, a standard deviation ? of a particle size distribution of the primary particle diameter satisfies a relation of: R/4???R, in which the R expresses the primary particle diameter, the oxide fine particles are substantially spherical having a circularity SF1 defined as equation (1) of 100 to 130 and a circularity SF2 defined as equation (2) of 100 to 125; SF1=(L2/A)×(?/4)×100??equation (1) SF2=(P2/A)×(1/4?)×100??equation (2), in the equations, “L” expresses the absolute maximum length of the oxide fine particles; “A” expresses a projected area of the oxide fine particles; and “P” expresses a maximum perimeter of the oxide fine particles.Type: GrantFiled: July 15, 2003Date of Patent: November 3, 2009Assignee: Ricoh Company, Ltd.Inventors: Hideki Sugiura, Satoshi Mochizuki, Kazuhiko Umemura, Shinya Nakayama, Yasuo Asahina
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Publication number: 20090169499Abstract: The present invention relates to pigments, the particles of which generally have a length of from 2 ?m to 5 mm, a width of from 2 ?m to 2 mm, and a thickness of from 20 nm to 2 ?m, and a ratio of length to thickness of at least 2:1, wherein the particles contain a core of SiO2 or a silicon/silicon oxide obtained by heating SiOy flakes with 1.1?y?1.8 in an oxygen-free atmosphere at a temperature of at least 400° C., which core has a narrow distribution of particle sizes and two substantially parallel faces, the distance between which is the shortest axis of the core, and a material layer having a high index of refraction a metal oxide; a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass.Type: ApplicationFiled: February 26, 2009Publication date: July 2, 2009Inventors: Patrice Bujard, Holger Leybach
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Patent number: 7540976Abstract: A sputtering target for fluorescent thin-film formation comprising a matrix material and a luminescent center material, wherein said matrix material has a chemical composition represented by the following formula (1), and simultaneously satisfies conditions represented by the following inequalities (2) to (5). MIIvAxByOzSw ??(1) 0.05?v/x?5 ??(2) 1?y/x?6 ??(3) 0.01?z/(z+w)?0.85 ??(4) 0.6?(v+x+3y/2)/(z+w)?1.5 ??(5) wherein MII represents one or more elements selected from the group consisting of Zn, Cd and Hg, A represents one or more elements selected from the group consisting of Mg, Ca, Sr, Ba and rare earth elements, B represents one or more elements selected from the group consisting of Al, Ga and In, and v, x, y, z and w each represent numerical values satisfying the conditions specified in the inequalities (2) to (5).Type: GrantFiled: March 5, 2004Date of Patent: June 2, 2009Assignee: Ifire IP CorporationInventors: Yoshihiko Yano, Tomoyuki Oike, Naruki Kataoka, Masaki Takahashi, Yukio Kawaguchi
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Patent number: 7517404Abstract: The present invention relates to pigments, the particles of which generally have a length of from 2 ?m to 5 mm, a width of from 2 ?m to 2 mm, and a thickness of from 20 nm to 2 ?m, and a ratio of length to thickness of at least 2:1, wherein the particles contain a core of SiOy with 0.70?y?1.8, especially 1.40?y?1.8, having two substantially parallel faces, the distance between which is the shortest axis of the core, comprising (a) a material, especially a metal oxide, having a high index of refraction; or (a) a thin semi-transparent metal layer; a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass.Type: GrantFiled: October 7, 2003Date of Patent: April 14, 2009Assignee: Ciba Specialty Chemicals CorporationInventors: Patrice Bujard, Holger Leybach
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Patent number: 7503970Abstract: A particulate metal oxide having the mean length of the primary particles in the range from 50 to 90 nm, the mean width of the primary particles in the range from 5 to 20 nm, and the median volume particle diameter of the secondary particles is less than 45 nm. The metal oxide can be used in a sunscreen product that exhibits both effective UV protection and improved transparency.Type: GrantFiled: April 13, 2007Date of Patent: March 17, 2009Assignee: Croda International PLCInventors: Graham Paul Dransfield, Susan Cutter, Phillip Laurence Lyth
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Publication number: 20080295736Abstract: The invention relates to a pearl pigment, and the preparing method of the same comprises: coating metal oxides on a sheet-like substrate, and coating metal phosphites (aluminum phosphite or zinc phosphite) on it, and then treating by hydrolysable silane coupling agent. The pearl pigment obtained highly improves its stability and its aging resistance when used for external outsides.Type: ApplicationFiled: September 21, 2005Publication date: December 4, 2008Inventors: Yizhong Lin, Wensong Jin
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Patent number: 7455726Abstract: The present invention relates to photostabilised effect pigments in which one or more calcined and vanadium-containing oxide layers, alone or mixed with sulfates, borates or phosphates, have been applied to a substrate, to a process for the preparation thereof, and to the use thereof in plastics, paints, coatings, printing inks, cosmetics, films, in security printing, for laser marking, in thermal protection or for colouring seed.Type: GrantFiled: April 27, 2004Date of Patent: November 25, 2008Assignee: Merck Patent GmbHInventors: Ulrich Schoenefeld, Padma Kaviratna
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Publication number: 20080181921Abstract: The present invention relates to interference pigments on the basis of multiply coated, platelet-shaped substrates which comprise at least one layer sequence comprising: (A) a metal oxide coating having a refractive index n?2.0, (B) a colorless metal oxide or fluoride coating having a refractive index n?1.8, (C) a nonabsorbing metal oxide coating of high refractive index, and, wherein the pigment further comprises (D) an oxide of calcium, magnesium, or zinc. The present pigment may be used in paints, printing inks, and for producing counterfeit-protected documents of value, such as bank notes, cheques, cheque cards, credit cards, identity cards, etc.Type: ApplicationFiled: October 16, 2007Publication date: July 31, 2008Applicant: BASF CorporationInventor: Carmine DeLuca
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Publication number: 20080168924Abstract: The present invention relates to pearlescent pigments based on glass flakes which are distinguished by the fact that they have the following layer structure: A) optionally a layer of SiO2, B) a high-refractive-index coating have a refractive-index n>1.8 which essentially consists of TiO2, C) a low-refractive-index layer comprising SiO2 and/or Al2O3 and optionally D) an outer protective layer, and to the use thereof in paints, coatings, automobile paints, powder coatings, printing inks, security printing inks, plastics, ceramic materials, glasses, paper, in toners for electrophotographic printing processes, in seed, in greenhouse sheeting and tarpaulins, as absorbers in the laser marking of paper and plastics, as absorbers for the laser welding of plastics, in cosmetic formulations, for the preparation of pigment pastes with water, organic and/or aqueous solvents, for the preparation of pigment compositions and dry preparations.Type: ApplicationFiled: August 10, 2005Publication date: July 17, 2008Inventors: Sabine Melson, Marc Entenmann, Marita Jekel, Marcus Mathias
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Publication number: 20080110372Abstract: A pearlescent pigment comprising a substrate and a first layer, wherein the first layer comprises iron oxide, wherein the iron has from about 1% to about 30% Fe(II) and from about 70% to about 99% Fe(III). A process for making these pearlescent pigment, comprise reducing a metal oxide substrate with a hydrogen source in the presence of a noble metal catalyst in a liquid medium. The pigments may be used in a variety of applications including cosmetics, plastics, automotive, or architectural coatings.Type: ApplicationFiled: October 31, 2007Publication date: May 15, 2008Inventors: Aaron M. Hollman, Stephane Nicolas, Philippe Schottland, Marguerite Debacker, Aurelie Antonowicz, Hai Hui Lin
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Patent number: 7318861Abstract: An effect pigment is constituted by coated laminar platelets in which the platelets are a mixture of different platelet materials, one of which is platy glass or platy aluminum oxide, and in which the pigment exhibits visual homogeneity.Type: GrantFiled: December 17, 2003Date of Patent: January 15, 2008Assignee: BASF Catalysts LLCInventors: Frank Bagala, Sr., Curtis J. Zimmermann
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Patent number: 7220793Abstract: A curable film-forming composition is provided comprising (i) 10 to 90 percent by weight based on the total weight of resin solids in the film-forming composition of a crosslinking agent; (ii) 10 to 90 percent by weight of a polymer containing a plurality of functional groups reactive with the crosslinking agent; and (iii) 5 to 85 percent by volume of particles having a mean particle size less than 100 nm. The particles comprise 1 to 99 percent by weight of at least one metal oxide wherein the metal is selected from zinc, titanium, cerium, manganese, bismuth, copper, zirconium and iron. A multi-component composite coating composition is also provided, comprising a pigmented basecoat and a clear coat. The basecoat and/or clearcoat may be derived from the curable film-forming composition described above. Also provided are coated substrates in which the curable coating compositions or the multi-component composite coating compositions described above are applied to a substrate and cured to form a cured coating.Type: GrantFiled: February 6, 2003Date of Patent: May 22, 2007Assignee: PPG Industries Ohio, Inc.Inventors: Noel R. Vanier, Calum H. Munro
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Patent number: 7186393Abstract: The present invention relates to a complex oxide having a BET specific surface area of about 10 to about 200 m2/g, comprising zinc oxide as a primary component, containing crystalline structures of both zinc oxide and silica, and exhibiting diffraction peaks in lattice planes (100), (002), and (101), which are X-ray crystallographically specific to diffraction peaks of crystalline zinc oxide, and in a lattice plane (101) which is X-ray crystallographically specific to the diffraction peak of crystalline silica.Type: GrantFiled: November 21, 2003Date of Patent: March 6, 2007Assignee: Showa Denko K.K.Inventors: Hisao Kogoi, Jun Tanaka, Hiroyuki Hagihara
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Patent number: 7163999Abstract: A method for preparing a resin particle having a large surface area and a shape factor (SF-1) of 110 to 800, which comprises a step of applying a shear force to an aqueous dispersion having a viscosity of 300 to 100,000 mPa·s formed by adding a thickener to an aqueous dispersion containing resin particles, and a subsequent step of decreasing the viscosity of the aqueous dispersion to 200 mPa·s or less by adding a viscosity decreasing agent as necessary. Resin particles obtained by the method can be used as additives for paint, additives for coating materials, powder coatings, additives for cosmetics, resins for slush molding, spacers for use in manufacturing electronic components or devices, standard particles for electronic measuring instruments, toners for electrophotography, toners for electrostatic recording, toners for electrostatic printing, and hot-melt adhesives.Type: GrantFiled: June 17, 2003Date of Patent: January 16, 2007Assignee: Sanyo Chemical Industries, Ltd.Inventors: Kazuhito Kawakami, Hidetoshi Noda, Toshihiko Kinsho, Masayuki Hatanaka
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Patent number: 7160374Abstract: A flaky pigment excellent in leafing properties and in adhesion between pigment particles and a coating (resin) was obtained by coating the surface of a flaky pigment with a coupling agent and a phosphate having a perfluoroalkly group or a silane compound. Accordingly, the flaky pigment is excellent as a pigment for coating or printing ink of which brightness and durability are required.Type: GrantFiled: February 15, 2001Date of Patent: January 9, 2007Assignee: Merck Patent GmbHInventors: Eiji Umehara, Koushiro Kunii
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Patent number: 7022398Abstract: A waterproofing article in the form of rod-, or rope-shaped clay-containing compositions, and a method of waterproofing using the article, whereby a water-penetrable, degradable, or water-soluble film or coating forms an outer surface of the article for avoiding premature hydration of an underlying clay-containing composition. In the preferred embodiment, an inner core of a water-swellable clay-containing composition includes a coating of a water-removable or degradable material, completely encasing the major outer surfaces of the composition, having controlled, predetermined water-penetration; high pH degradability; or water-solubility so that the core of water-swellable clay-containing composition is quickly hydrated after water-penetration of the coating material, and to prevent clay hydration during installation, prior to water-penetration of the coating material.Type: GrantFiled: September 18, 2003Date of Patent: April 4, 2006Assignee: Amcol International CorporationInventors: Jerald W. Darlington, Jr., Robert J. Trauger, Natalie A. Dotlich
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Patent number: 7014915Abstract: A material has a mass of powder particles. The mass of powder particles includes controlled binary macrosegregated powder particles made of at least two constituent elements. Each controlled binary macrosegregated powder particle has a chemically binary structure wherein the chemical composition varies from one side to the other side of the powder particle. The controlled binary macrosegregated powder particles may be used in applications which conventionally employ homogeneous powder particles, such as paints, solar cells, and the like. A paint uses as its pigment the controlled binary macrosegregated powder particles whose compositions are within the chemical system Zn(Al,Ga)2O4, and an inorganic or organic binder. The controlled binary macrosegregated powder particles are made by chemical synthesis at temperatures below those conventionally used to prepare homogeneous particles.Type: GrantFiled: August 20, 2002Date of Patent: March 21, 2006Assignee: The Boeing CompanyInventor: James F. Cordaro
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Patent number: 6919444Abstract: Preparations of particles having a glass surface, wherein more than 75% by weight of these particles have a particle size between 0.5 ?m and 15 ?m and a glass surface which contains between 2 and 6 mole % zinc oxide, have proven to be particularly advantageous in processes for the purification of nucleic acids. This in particular results in an increased nucleic acid yield.Type: GrantFiled: February 20, 2003Date of Patent: July 19, 2005Assignee: Roche Diagnostics GmbHInventors: Herbert Harttig, Michael Riedling, Martin Mennig, Helmut Schmidt
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Patent number: 6730156Abstract: A filler comprising a substantially amorphous cluster comprising non-heavy metal oxide particles and heavy metal oxide. The filler can be mixed into a hardenable resin to provide radiopaque dental materials having desirable strength and aesthetic character.Type: GrantFiled: October 28, 1999Date of Patent: May 4, 2004Assignee: 3M Innovative Properties CompanyInventors: Mark Steven Windisch, Xiaodong Zhang, Richard Paul Rusin, Sumita Basu Mitra
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Patent number: 6656259Abstract: The invention relates to multilayered interference pigments which comprise a platelet-shaped substrate of silicon dioxide which is coated alternately with layers of light-transparent materials having refractive indices of n>1.8 and layers of light-transparent materials having refractive indices of n≦1.8, where the optical thickness of the platelet-shaped substrate and the optical thickness of the individual layers of light-transparent materials having refractive indices of n≦1.8 are the same.Type: GrantFiled: August 2, 2002Date of Patent: December 2, 2003Assignee: Merck Patent Gesellschaft mit beschraenkter HaftungInventors: Gerhard Pfaff, Helge Kniess, Peter Reynders
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Patent number: 6616746Abstract: The titanium dioxide pigment of this invention has on the titanium dioxide particle surface a coating layer comprising a polyhydric alcohol and a hydrolysis product of an aminosilane compound, has a dispersibility of not more than 20 kg/cm2 as judged in terms of resin pressure increase, and is excellent in hydrophobicity and dispersibility. The pigment is useful as a coloring agent for plastics which requires good lacing resistance and dispersibility.Type: GrantFiled: June 13, 2002Date of Patent: September 9, 2003Assignee: Ishihara Sangyo Kaisha, Ltd.Inventors: Hideo Takahashi, Eiji Yamada, Toshihiko Akamatsu, Takeshi Fujimura