Aluminum Compound Or Silicon Containing, E.g., Clay, Etc. Patents (Class 106/426)
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Publication number: 20030158316Abstract: A curable film-forming composition is provided comprising (i) 10 to 90 percent by weight based on the total weight of resin solids in the film-forming composition of a crosslinking agent; (ii) 10 to 90 percent by weight of a polymer containing a plurality of functional groups reactive with the crosslinking agent; and (iii) 5 to 85 percent by volume of particles having a mean particle size less than 100 nm. The particles comprise 1 to 99 percent by weight of at least one metal oxide wherein the metal is selected from zinc, titanium, cerium, manganese, bismuth, copper, zirconium and iron.Type: ApplicationFiled: February 6, 2003Publication date: August 21, 2003Inventors: Noel R. Vanier, Calum H. Munro
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Patent number: 6596061Abstract: Inorganic anti-corrosive pigments consist of surface-coated solids having a grain size of 0.1 to 75 &mgr;m. In order to improve the resistance of the paints and coatings containing such pigments, firstly Mn3(PO4)2 and secondly aluminium oxides and/or aluminium hydroxides are precipitated onto the solids.Type: GrantFiled: May 4, 2001Date of Patent: July 22, 2003Assignee: Metallgesellschaft AktiengesellschaftInventor: Thomas Rentschler
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Patent number: 6596071Abstract: Organic and inorganic composite pigments having an average particle diameter of 0.01 to 10.0 &mgr;m composed of a white inorganic particle, an organosilane compound obtained from alkoxysilanes, or polysiloxanes coating on the white inorganic particle, and an organic pigment coat formed on said coating. An ultraviolet light-absorbing agent is present in any portion from the surface of the white inorganic particle to surface of the organic pigment coat. These composite pigments have reduced amounts of organic pigments desorbed from their surface and exhibit excellent light resistance due to their ultraviolet absorbing property.Type: GrantFiled: June 11, 2002Date of Patent: July 22, 2003Assignee: Toda Kogyo CorporationInventors: Kazuyuki Hayashi, Keisuke Iwasaki, Mineko Ohsugi, Yusuke Shimohata, Hiroko Morii
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Patent number: 6576052Abstract: The titanium dioxide pigment of the present invention comprises titanium dioxide particles, the coating layer containing the aluminum phosphate compound and the coating layer containing the hydrolyzate of the organosilane compound, on the surface of the particles, in which a difference in water content between 100° C. and 300° C., determined by the Karl Fischer method, is not greater than 1500 ppm, and is thus excellent in light fastness, hydrophobicity and dispersibility. In particular, the titanium dioxide pigment of the invention is extremely advantageous as a colorant for plastics, which requires light fastness (resistance to discoloration) lacing resistance and dispersibility, to a high degree.Type: GrantFiled: March 12, 2002Date of Patent: June 10, 2003Assignee: Ishihara Sangyo Kaisha, Ltd.Inventors: Hideo Takahashi, Masaki Shimojo, Toshihiko Akamatsu
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Publication number: 20030101908Abstract: Organic and inorganic composite pigments have an average particle diameter of 0.01 to 10.Type: ApplicationFiled: June 11, 2002Publication date: June 5, 2003Inventors: Kazuyuki Hayashi, Keisuke Iwasaki, Mineko Ohsugi, Yusuke Shimohata, Hiroko Morii
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Patent number: 6545143Abstract: Preparations of particles having a glass surface, wherein more than 75% by weight of these particles have a particle size between 0.5 &mgr;m and 15 &mgr;m and a glass surface which contains between 2 and 6 mole % zinc oxide, have proven to be particularly advantageous in processes for the purification of nucleic acids. This in particular results in an increased nucleic acid yield.Type: GrantFiled: January 9, 2002Date of Patent: April 8, 2003Assignee: Roche Diagnostics, GmbHInventors: Herbert Harttig, Michael Riedling, Martin Mennig, Helmut Schmidt
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Patent number: 6544326Abstract: The pigment dispersion composition having a good dispersibility, a good transparence and an anti-coating properties, which contains 0.5 to 50 parts by weight of an inorganic pigment, at least one type of dispersant selected from the group consisting of a sodium salt, an ammonium salt and an amine salt of an acrylic resin, an acryl copolymer resin, a polycarbonic acid, a condensation product of aromatic formalin sulfonate, and water or a solvent miscible with water.Type: GrantFiled: January 22, 1999Date of Patent: April 8, 2003Assignees: Kabushiki Kaisha Toshiba, Fuji Pigment Co., Ltd.Inventors: Takeo Itou, Hidemi Matsuda, Hisashi Chigusa, Kazuo Sakai, Masaru Fukuda
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Publication number: 20030056693Abstract: A colorant for ink-jet printing ink of the present invention, has an average particle diameter of 0.001 to 0.15 &mgr;m, and comprises: extender pigments as core particles; a gluing agent coating layer formed on at least a part of surface of said core particle; and an organic pigment coat uniformly formed on at least a part of said gluing agent coating layer. The colorant for ink-jet printing ink exhibits not only a high tinting strength and a clear hue, but also excellent dispersibility and light resistance in spite of fine particles.Type: ApplicationFiled: June 4, 2002Publication date: March 27, 2003Inventors: Kazuyuki Hayashi, Hiroko Morii, Keisuke Iwasaki
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Publication number: 20030039836Abstract: The invention relates to multilayered interference pigments which comprise a platelet-shaped substrate of silicon dioxide which is coated alternately with layers of light-transparent materials having refractive indices of n>1.8 and layers of light-transparent materials having refractive indices of n≦1.8, where the optical thickness of the platelet-shaped substrate and the optical thickness of the individual layers of light-transparent materials having refractive indices of n≦1.8 are the same.Type: ApplicationFiled: August 2, 2002Publication date: February 27, 2003Applicant: Merck Patent GmbHInventors: Gerhard Pfaff, Helge Kniess, Peter Reynders
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Patent number: 6485656Abstract: Paint detackifiers and/or sedimentation agents are provided which contain amorphous alumina and/or alumina in pseudoboehmite or boehmite form having an average crystallite size of from 0.1 to 15 nm and/or the hydrates and hydroxyalkylpolysaccharides thereof.Type: GrantFiled: February 11, 2000Date of Patent: November 26, 2002Assignee: SASOL Germany GmbHInventors: Arnold Meyer, Jens Juhl, Klaus Noweck
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Patent number: 6447759Abstract: To provide an ultraviolet absorbent having high UV shieldability, especially UV-A shieldability, high transparency and good dispersibility. An ultraviolet absorbent, which comprises a flaky substrate coated with ultra-fin zinc oxide particles having a mean particle size of not larger than 100 nm, and which is optionally treated with an organic silicone compound; and a method for producing the ultraviolet absorbent, which comprises calcining particles as coated with basic zinc carbonate in the presence of a complex-forming agent.Type: GrantFiled: April 23, 2001Date of Patent: September 10, 2002Assignee: Merck Patent GesellschaftInventors: Tamio Noguchi, Yukitaka Watanabe
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Patent number: 6387498Abstract: A flake-based pigment is provided having improved specular reflectance characteristics in the visible wavelength range. The flake-based pigment has a plurality of core flake sections each formed of a central reflector layer and dielectric support layers on opposing sides of the reflector layer. The resulting core flake section is a very thin three-layered structure that exhibits a uniaxial compressive strength much greater than a corresponding uniaxial tensile strength. This structure provides the benefits of rigidity and brittle fracture during manufacturing and application processes, which ultimately provides favorable planar and specular reflectance characteristics for the pigment in the visible wavelength range. A variety of outer coating layers can be formed around the core flake sections, such as various dielectric and absorber layers having thicknesses dependent upon the desired optical characteristics of the pigment.Type: GrantFiled: April 7, 2000Date of Patent: May 14, 2002Assignee: Flex Products, Inc.Inventors: Kent E. Coulter, Thomas Mayer, Roger W. Phillips, John S. Matteucci
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Patent number: 6383638Abstract: A flake-based pigment is provided having improved specular reflectance characteristics in the visible wavelength range. The flake-based pigment has a plurality of core flake sections each formed of a central reflector layer and dielectric support layers on opposing sides of the reflector layer. The resulting core flake section is a very thin three-layered structure that exhibits a uniaxial compressive strength much greater than a corresponding uniaxial tensile strength. This structure provides the benefits of rigidity and brittle fracture during manufacturing and application processes, which ultimately provides favorable planar and specular reflectance characteristics for the pigment in the visible wavelength range. A variety of outer coating layers can be formed around the core flake sections, such as various dielectric and absorber layers having thicknesses dependent upon the desired optical characteristics of the pigment.Type: GrantFiled: October 13, 2000Date of Patent: May 7, 2002Assignee: Flex Products, Inc.Inventors: Kent E. Coulter, Thomas Mayer, Roger W. Phillips, John S. Matteucci
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Patent number: 6270566Abstract: A process is disclosed for coloring building materials with inorganic pigments in the form of microgranulates. The granulates comprise one or more pigments and one or more compounds selected from boron, aluminum, silicon, titanium, zinc and tin.Type: GrantFiled: June 6, 1995Date of Patent: August 7, 2001Assignee: Bayer AGInventors: Jakob Rademachers, Günther Teichmann
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Patent number: 6267810Abstract: The present invention relates to pigment mixtures containing at least two components, component A being Al2O3 flakes coated with one or more metals, metal oxides and/or metal sulfides and component B being special-effect pigments, and to their use in varnishes, paints, printing inks, masterbatches, plastics and cosmetic formulations.Type: GrantFiled: December 23, 1999Date of Patent: July 31, 2001Assignee: Merck Patent Gesellschaft mit beschraenkter HaftungInventors: Gerhard Pfaff, Sabine Schoen, Nishimagi Atsuko
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Patent number: 6214106Abstract: The present invention provides a process for the production of hydrophobic inorganic oxide products which comprises reacting the inorganic oxide particles with organohalosilanes, preferably organochlorosilanes, to produce hydrophobic organosilane coated inorganic oxides. It is preferred that the organohalosilane compounds be reacted with the inorganic oxide particles in an aqueous slurry and subjected to intense mixing. The inorganic oxide pigments prepared by the processes of this invention have essentially quantitative retention of the organosilanes and contain no adsorbed aldehydes on their surface. The by-products produced in the preferred embodiments of the invention are innocuous salts, which are environmentally safe and readily disposable.Type: GrantFiled: October 28, 1998Date of Patent: April 10, 2001Assignee: Millenium Inorganic Chemicals, Inc.Inventors: Leon Weber, Robert J. Kostelnik, Charles Wheddon
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Patent number: 6193794Abstract: The iron oxide platelets comprise at least one layer packet comprising A) a colorless coating having a refractive index n≦1.8, and B) a colorless coating having a refractive index n≧2.0.Type: GrantFiled: March 2, 1999Date of Patent: February 27, 2001Assignee: BASF AktiengesellschaftInventors: Raimund Schmid, Oliver Seeger, Norbert Mronga
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Patent number: 6139616Abstract: The present invention relates to an anti-corrosive pigment composition, characterized by comprising, as main components, white anti-corrosive pigment and an inorganic anion exchanger represented by the following formula (1):(3-4)[M.sub.1 ]O.Al.sub.2 O.sub.3.[M.sub.2 ]X.sub.2/m .multidot.nH.sub.2 O(1)(wherein, M.sub.1 and M.sub.2 are at least one selected from Ca.sup.2+ or Zn.sup.2+, X represents at least one anion selected from NO.sub.2.sup.-, NO.sub.3.sup.- or MoO.sub.4.sup.2-, m represents a valency of the anion, and n is 20 or less).Type: GrantFiled: March 30, 1999Date of Patent: October 31, 2000Assignees: Nippon Chemical Industrial Co., LTD, Toho Ganryo Kogyo Co., Ltd.Inventors: Takahiro Nagayama, Minoru Yokoyama
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Patent number: 6132743Abstract: A zinc oxide powder having a suppressed photocatalytic activity and prepared by coating a zinc oxide powder with at least one silicone compound in a nongaseous state and firing the coated zinc oxide powder in an oxidizing atmosphere at a temperature of 600 to 950.degree. C. A cosmetic preparation containing this zinc oxide powder is excellent in feel, sebum resistance, and protection against ultraviolet light.Type: GrantFiled: July 6, 1999Date of Patent: October 17, 2000Assignees: Kanebo, Ltd., Daito Kasei Kogyo Co., Ltd.Inventors: Akihiro Kuroda, Yoshinori Waki, Masataka Shimomura
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Patent number: 6099637Abstract: A paint is a liquid or solid mixture of a plurality of particles and an inorganic binder such as a silicate. The particles have a composition A[xAl(1-x)Ga].sub.2 O.sub.4.+-..gamma. (.delta.In), wherein A is zinc, magnesium and/or cadmium, the value of x is from 0 to 1, the value of .delta. is from 0 to about 0.2, and the value of .gamma. is less than about 0.2. In the liquid mixture, a paint vehicle is also typically present to impart the desired fluidity to the mixture. The solid paint made using this material is white, has very low solar absorptance, and may be made electrically conductive by doping the particles with indium or other appropriate dopant.Type: GrantFiled: September 2, 1998Date of Patent: August 8, 2000Assignee: Hughes Electronics CorporationInventor: James F. Cordaro
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Patent number: 6068692Abstract: The invention relates to a process for manufacturing decorated ceramic and glass articles according to which a ceramic dye composition, including fine particles which comprise ceramic pigments and binding medium resin(s) as well as possible further additives, is applied by means of an electrophotographic reproduction process onto a transfer means, for example paper coated with gum arabic, the transfer means coated with the ceramic dye composition is applied onto the ceramic or glass article, and after removal of the transfer means, the ceramic dye composition is combined with the ceramic or glass article by baking. The invention also includes decorative ceramic or glass articles obtainable by means of the above process and a ceramic dye composition of the type mentioned above.Type: GrantFiled: March 22, 1999Date of Patent: May 30, 2000Inventor: Michael Zimmer
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Patent number: 6017982Abstract: For making a cement such as a dental cement by reacting an organic polyacid (such as polyacrylic acid or polyvinylphosphonic acid or a copolymer of these) with an ion-leachable glass as the base, the invention offers a glass containing the cations Al, Si, Ca and Zn wherein Si:Al>1.5 and Zn is 30-70 percent of those cations. The glass is made by heat treating an aqueous paste of Al, Si, and Ca oxides, such as bentonite, with ZnO and a precursor of ZnO such as zinc acetate, whereby the zinc forms a layer on the glass and is also incorporated as a glass network former. The setting of the cement is speeded and sharpened by using around 2% MgCl.sub.2.Type: GrantFiled: July 30, 1998Date of Patent: January 25, 2000Assignee: BTG International LimitedInventor: Ademola Olaseni Akinmade
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Patent number: 6004391Abstract: Purple pigments according to the invention based on a stovable support material, in particular a glass frit, having a coat applied by coprecipitation of an oxide hydrate of one or more elements from the range comprising Al, Si, Sn, Pb, Ti, Nb, Ta, Sc, Y, La, Ce and Zn and a water-insoluble gold compound or colloidal gold are distinguished from prior art pigments of a similar composition by improved color stability in high temperature firing. The pigments are obtainable in the aqueous phase by coprecipitation of an oxide hydrate and a gold compound or colloidal gold in the presence of a support material and in the absence of a reducing agent. Pigments containing gold compounds assume a purple color on heat treatment or by chemical reduction. Preferred pigments containing gold compounds, which may directly be used as decorative colorants, conveniently develop their color during firing of the decoration.Type: GrantFiled: November 28, 1997Date of Patent: December 21, 1999Assignee: Cerdec Aktiengesellschaft Keramische FarbenInventors: Hans-Peter Letschert, Jenny Wilfert
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Patent number: 5948471Abstract: The invention relates to a process for manufacturing decorated ceramic and glass articles according to which a ceramic dye composition, including fine particles which comprise ceramic pigments and binding medium resin(s) as well as possible further additives, is applied by means of an electrophotographic reproduction process onto a transfer means, for example paper coated with gum arabic, the transfer means coated with the ceramic dye composition is applied onto the ceramic or glass article, and after removal of the transfer means, the ceramic dye composition is combined with the ceramic or glass article by baking. The invention also includes decorative ceramic or glass articles obtainable by means of the above process and a ceramic dye composition of the type mentioned above.Type: GrantFiled: February 20, 1997Date of Patent: September 7, 1999Inventor: Michael Zimmer
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Patent number: 5914101Abstract: A stabilised aqueous dispersion of particulate zinc oxide comprises water, a stabilising agent and zinc oxide, the particles of which are coated with dense amorphous silica. Useful stabilising agents include cellulose ethers which contain quaternary ammonium groups and polyalkylene glycols. The dispersions have excellent stability at high concentrations of zinc oxide and are useful for preparing sunscreen formulations, cosmetics and veterinary products.Type: GrantFiled: August 6, 1997Date of Patent: June 22, 1999Assignee: Tioxide Specialties LimitedInventors: Carole Allyson Maria Tapley, Philip Laurence Lyth, Iain Michael Harper
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Patent number: 5904761Abstract: The present invention provides a method for preparing a needle-shaped pigment with a particle size of 0.3.+-.0.1 .mu.m, which has uniform particle distribution, higher thixotropy, an excellent gloss, and good absorption of printing ink, by continuous addition of aluminum sulfate solution and zinc sulfate solution to a milk of lime.Type: GrantFiled: October 14, 1997Date of Patent: May 18, 1999Inventor: Kyu Jae You
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Patent number: 5820669Abstract: A paint is a liquid or solid mixture of a plurality of particles and an inorganic binder such as a silicate. The particles have a composition A?xAl(1-x)Ga!.sub.2 O.sub.4 (.delta.In), wherein A is zinc or cadmium, the value of x is from 0 to 1, and the value of .delta. is from 0 to about 0.2. In the liquid mixture, a paint vehicle is also typically present to impart the desired fluidity to the mixture. The solid paint made using this material is white, has very low solar absorptance, and may be made electrically conductive by doping the particles with indium or other appropriate dopant.Type: GrantFiled: March 18, 1997Date of Patent: October 13, 1998Assignee: Hughes Electronics CorporationInventor: James F. Cordaro
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Patent number: 5798059Abstract: A color display screen having a coating which comprises at least a greend an/or a red phosphor as well as at least a pigment having the following composition:Ga.sub.a In.sub.b Zn.sub.c Al.sub.d O.sub.n S.sub.m Se.sub.o Te.sub.pwherein0.05<a<1.95 0.0.ltoreq.n<0.30.05<b<1.95 2.1<m.ltoreq.30.00.ltoreq.c<0.09 0.0.ltoreq.o<0.30.00.ltoreq.d<0.2 0.0.ltoreq.p<0.3and n+m+o+p=3 and a+b+2/3c+d=2, yields a high-contrast and low-reflection picture, because the pigmentation in accordance with the invention is self-luminescent and its solid-solution properties enable its absorption properties to be accurately adapted to the emission spectrum of the phosphor. The solid solutions having the composition Ga.sub.a In.sub.b Zn.sub.c Al.sub.d O.sub.n S.sub.m Se.sub.o Te.sub.p are characterized by steep absorption edges in the yellow-orange spectral range and by a high absorptivity. This permits thin pigment-containing layers and small quantities of pigment to be used.Type: GrantFiled: December 9, 1996Date of Patent: August 25, 1998Assignee: U.S. Philips CorporationInventors: Michael Bredol, Jacqueline Merikhi, Dieter Wadow
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Patent number: 5776239Abstract: An ultrafine titanium dioxide powder is disclosed that can be produced by hydrothermal treating an amino titanium oxalate composition. Ultrafine titanium dioxide powders are useful in cosmetic and other applications for controlling exposure to ultraviolet (UV) light.Type: GrantFiled: August 22, 1997Date of Patent: July 7, 1998Assignee: E. I. Du Pont de Nemours and CompanyInventor: Salvatore Anthony Bruno
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Patent number: 5766336Abstract: Colored pigments are provided from the green-yellow to red spectrum based on oxide-nitrides with two or three different cations Q, R and S in the crystal lattice, wherein the nitrogen to oxygen atomic ratio is determinative for the color. These pigments crystallise in the pyrochlore, spinel or elpasolite structure. Pigments in the perovskite are as provided with increased color brilliance. The color of the pigments can be adjusted in a wide range of the color spectrum during their preparation within a substance class with the cations Q, R and S and while retaining the crystal structure, by increasing or lowering the atomic ratio N to O in the oxide-nitride and bringing about the required charge balancing by replacing an equivalent quantity of the cation Q with the valency q by a cation R with the valency q+1.Type: GrantFiled: August 21, 1995Date of Patent: June 16, 1998Assignee: Cerdec Aktiengesellschaft Keramische FarbenInventors: Martin Jansen, Hans-Peter Letschert
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Patent number: 5711798Abstract: A pigment containing low-order titanium oxide of this invention is characterized in that both aluminum oxide and silicon oxide exist together with low-order titanium oxide. A method of manufacturing such a pigment comprises the steps of; presenting an aluminum compound and silicon as a reducing agents together with titanium dioxide: and then heating and reducing the mixture in an atmosphere having a low oxygen content. According to this method, the pigment containing low-order titanium oxide can efficiently be manufactured, while preventing sintering generated due to the fusion between the reducing agents or the reducing agents and powders.Type: GrantFiled: October 10, 1995Date of Patent: January 27, 1998Assignee: Shiseido Co., Ltd.Inventors: Shoichiro Shio, Fukuji Suzuki
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Patent number: 5707440Abstract: A finely divided inorganic filler material is a sintered composite which consists of larger macro-filler particles of glass and of smaller micro-filler particles of glass or ceramics partially covering the macro-filler particle and firmly connected to it by sintering. Plastic materials reinforced with the filler are distinguished by improved abrasion resistance.Type: GrantFiled: October 7, 1994Date of Patent: January 13, 1998Assignee: Heraeus Kulzer GmbHInventors: Xu Hengchang, Joachim Nagel
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Patent number: 5700318Abstract: Improved alumina-coated inorganic pigments having a first coating of boehmite alumina, a second coating of amorphous alumina, and a third coating of boehmite alumina which exhibit good durability, dispersibility, and optical properties in plastic compositions are disclosed. Also disclosed is a process whereby an aqueous slurry of an alumina-containing inorganic pigment is milled to achieve a particular particle size distribution, a first coating of boehmite alumina is precipitated onto the pigment material within a first pH range, a second amount of an alumina coating agent is added to the aqueous slurry within a second pH range to obtain a second coating of amorphous alumina over the first boehmite alumina coating, and then the pH of the slurry is adjusted to a third pH range thus forming a third boehmite alumina coating over the second amorphous alumina coating.Type: GrantFiled: April 16, 1996Date of Patent: December 23, 1997Assignee: Kerr-McGee Chemical CorporationInventors: John R. Brand, Kelly A. Green
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Patent number: 5656074Abstract: Anticorrosive compositions for use in paints comprise (i) zinc oxide with (ii) the reaction product of an acidic trivalent metal compound and a silicate or (iii) an aluminium/silicate material eg a clay.Type: GrantFiled: April 17, 1995Date of Patent: August 12, 1997Assignee: Albright & Wilson LimitedInventors: John Richard Collier, Kenneth Urmston Holker
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Patent number: 5653794Abstract: The present invention provides a process for the production of hydrophobic inorganic oxide products which comprises reacting the inorganic oxide particles with organohalosilanes, preferably organochlorosilanes, to produce hydrophobic organosilane coated inorganic oxides. It is preferred that the organohalosilane compounds be reacted with the inorganic oxide particles in an aqueous slurry. The inorganic oxide pigments prepared by the processes of this invention have essentially quantitative retention of the organosilanes and contain no adsorbed aldehydes on their surface. The by-products produced in the preferred embodiments of the invention are innocuous salts, which are environmentally safe and readily disposable.Type: GrantFiled: December 1, 1995Date of Patent: August 5, 1997Assignee: SCM Chemicals, Inc.Inventors: Leon Weber, Robert J. Kostelnik, Charles Wheddon
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Patent number: 5611852Abstract: A stabilized conductive pigment based on aluminum-doped zinc oxide which, for stabilizing the electric conductivity, contains an alkaline earth metal titanate or an oxide of an element from group III or IV.Type: GrantFiled: August 16, 1994Date of Patent: March 18, 1997Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventors: Gerhard Pfaff, Hans-Dieter Bruckner
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Patent number: 5496403Abstract: Inorganic oxide pigments (ceramics) are prepared by mixing the starting materials in the presence of water and in the presence or absence of assistants, drying and subsequent calcining in a rotary furnace by processing the starting materials in the presence of water into a pumpable suspension having particle sizes of 50%<10 .mu.m and 100%<50 .mu.m, dewatering the suspension by spray drying it to leave porous granules, and calcining those granules>97% from 20 to 800 .mu.m in size.Type: GrantFiled: August 23, 1990Date of Patent: March 5, 1996Assignee: BASF Lacke + Farben AktiengesellschaftInventors: Harald Gaedcke, Guenter Etzrodt, Egon Liedek
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Patent number: 5468289Abstract: The present invention relates to surface-modified pigments based on platelet-like substrates which, for improving the settling and redispersion behavior, have been recoated with a mixture comprising two metal oxides selected from the group consisting of silica, alumina and zirconium dioxide.Type: GrantFiled: September 30, 1994Date of Patent: November 21, 1995Assignee: Merck Patent Gesellschaft Mit Beschrankter HaftungInventors: Gerhard Herget, Margarete Herbski, Karl Osterried
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Patent number: 5456749Abstract: Disclosed is an anti-discoloring pearly luster pigment of white titanium dioxide-coated mica grains wherein; (a) the surfaces of the titanium dioxide and/or titanium oxide hydrate coated mica particles are coated with from 1 to 7 parts by weight, to 100 parts by weight of the titanium dioxide and/or titanium oxide hydrate coated mica particles, of a silicon oxide and/or silicon oxide hydrate; (b) the surfaces of the coated grains are further coated with from 0.5 to 5 parts by weight, to 100 parts by weight of the mica titanium dioxide and/or titanium oxide hydrate coated particles, of an aluminium oxide and/or aluminum oxide hydrate; and (c) the surfaces of the coated particles are still further coated with from 0.5 to 3 parts by weight, to 100 parts by weight of the titanium dioxide and/or titanium oxide hydrate coated mica particles, of a zinc oxide and/or zinc oxide hydrate.Type: GrantFiled: March 1, 1994Date of Patent: October 10, 1995Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventors: Kazuhisa Iwasa, Katsuhisa Nitta, Tamio Noguchi
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Patent number: 5389140Abstract: An electrodeposition paint composition which contains a titanium oxide pigment coated with 1 to 10% by weight of an zinc compound in terms of metal zinc based on the titanium oxide. It is possible by use of the composition to form a coating film excellent in corrosion resistance without using an anticorrosive pigment having a problem on measures against environmental pollution.Type: GrantFiled: October 28, 1993Date of Patent: February 14, 1995Assignee: Kansai Paint Co., Ltd.Inventors: Yoshio Yasuoka, Masafumi Kume, Hidehiko Haneishi
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Patent number: 5369331Abstract: The present invention provides a pigment-attached blue-emitting phosphor having attached a blue pigment which has fastness and chemical stability and is excellent in reflection spectrum characteristics, and a color cathode-ray tube having a blue-emitting fluorescent layer containing the blue pigment formed on the inner surface of a face plate.The present invention also provides a pigment-attached blue-emitting phosphor having a CoO.ZnO.SiO.sub.2 type blue pigment attached thereto, and a color cathode-ray tube provided with a blue-emitting fluorescent layer containing the blue pigment particles on the inner surface of a face plate.Type: GrantFiled: February 3, 1993Date of Patent: November 29, 1994Assignee: Kasei Optonix, Ltd.Inventors: Tomohito Mizukami, Chihito Funayama, Yasuo Oguri
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Patent number: 5366660Abstract: An oil dispersion which is substantially transparent to visible light comprises an oil, particles of zinc oxide having an average size of from 0.005 to 0.15 micron and an organic dispersing agent. The solids content of the dispersion is at least 30 weight percent, its extinction coefficients at 308 nm (E(308)) and 360 nm (E(360)) wavelengths are both at least 9 liters per gram per centimeter and the ratio E(360):E(308) is in the range 0.75:1 to 1.5:1.A method of preparing the dispersion is also described in which the ingredients are milled together in the presence of a particulate grinding medium until the required particle size and optical properties are obtained.The dispersions are useful in sun-screening preparations and especially those products designed to provide a balanced protection from UVA and UVB radiation.Type: GrantFiled: September 30, 1992Date of Patent: November 22, 1994Assignee: Tioxide Specialties LimitedInventor: Carole A. M. Tapley
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Patent number: 5363012Abstract: A pigment-attached blue-emitting phosphor comprising a blue-emitting phosphor and a blue pigment attached to the surface of the blue-emitting phosphor, said blue pigment being a CoO.ZnO.SiO.sub.2 type pigment containing Mo.Type: GrantFiled: September 3, 1993Date of Patent: November 8, 1994Assignee: Kasei Optonix, Ltd.Inventors: Tomohito Mizukami, Chihito Funayama
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Patent number: 5340395Abstract: The technical field of the invention is concerned with smoke-generating devices and with powdered materials scattered by dispersion means in order to produce a camouflaging cloud which is effective in the infrared region. The material in accordance with the invention essentially consists of at least one powder having grains provided with a coating which is chemically inert with respect to the grain, which affords resistance to temperatures lower than or equal to the dispersion temperature, and which does not oxidize in free air.Type: GrantFiled: July 1, 1992Date of Patent: August 23, 1994Assignee: Giat IndustriesInventors: Daniel Larmignat, Phillippe C. Morand, Christian H. Prieur, Gilles F. Lacreuse
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Patent number: 5338353Abstract: A method for the production of powder of fine inorganic particles excellent in dispersibility in various solvents from a slurry of said fine inorganic particles containing water, which method comprises preparing a slurry as a raw material by incorporating in said slurry at least one orgaic compound selected from the group consisting of (A) methanol and (B) organic compound capable of dissolving of dissolving water in an amount of not less than 1.0% by weight at 20.degree. C. and forming a two-component azeotropic mixture of water and organic compounds having a water content of not less than 4.0% by weight and converting said prepared slurry into powder by the use of a powderization apparatus comprising an externally heatable pipe one end of which serves as a slurry inlet and the other end of which serves as a device for separating the produced powder and a vapor held in a vacuum state and a powder and a powder collecting chamber connected to said separating device.Type: GrantFiled: October 20, 1992Date of Patent: August 16, 1994Assignee: Nippon Shokubai Kagaku KogyoInventors: Hiroyoshi Uchino, Tadahiro Yoneda
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Patent number: 5312614Abstract: A method is provided for the high yield production of white, electrically conductive zinc oxide which comprises the simultaneous addition to a reactor of (1) an aqueous solution containing a water-soluble zinc compound and at least one water-soluble compound of a metal selected from the group consisting of tin, aluminum, gallium and indium, and (2) an aqueous alkaline solution, while maintaining the resulting neutralization reaction solution at a pH from 6 to 12.5 to obtain coprecipitates, and then calcining the coprecipitates in a reducing atmosphere to obtain said conductive zinc oxide.Type: GrantFiled: June 14, 1990Date of Patent: May 17, 1994Assignee: Metallgesellschaft AktiengesellschaftInventors: Takao Hayashi, Norihiro Sato, Chikara Omotani, Manabu Hosoi, Nobuyoshi Kasahara, Gunther Rudolph, Wolf-Dieter Griebler, Jorg Hocken
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Patent number: 5298065Abstract: Disclosed herein are an ultraviolet-screening scale pigment comprising scale-like inorganic particles and a zinc oxide coating layer of 50 to 250 wt% (calculated as ZnO) based on the scale-like inorganic particles, a water content of said zinc oxide coating layer being not more than 7 wt%; a process for producing the scale pigment; and cosmetics containing the scale pigment.Type: GrantFiled: January 4, 1993Date of Patent: March 29, 1994Assignee: Tayca CorporationInventors: Nobumoto Hiraoka, Norihiro Tanimoto, Mayumi Mandai
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Patent number: 5198026Abstract: Zinc powder, which contains a coloring element, e.g., Ti, Mn, or V, is heated to a temperature of from 350.degree. to 700.degree. C. so as to oxidize the surface of the powder and hence to develop such colors as brown, navy blue, blue, greenish-brown, green, and coffee brown. The colored zinc powder is sprayed onto a steel, aluminum, or ceramic article to produce a colored article. The colored zinc powder is also used as a pigment.Type: GrantFiled: September 25, 1991Date of Patent: March 30, 1993Assignee: Nippon Mining Co., Ltd.Inventors: Eiji Nishimura, Chikara Tominaga, Yusaku Masuda, Hiroshi Tasaki
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Patent number: 5194089Abstract: Coated spinel color pigments with a core of a colored spinel, in particular CoAl.sub.2 O.sub.4, and a coating glassy layer of a silicate are described. The coating layer is essentially silicon dioxide and one or more oxides of the group of alkali metals, alkaline earth metals, and/or earth metals show a high resistance to bleeding in the presence of glass fluxes, as compared to uncoated spinels. The pigments are produced by sintering, for 0.5 to 5 hours, a powder mixture of the spinel, silicon dioxide, and at least one member chosen from the group of alkali metal halides, alkaline earth metal halides, earth metal halides and mixtures thereof as mineralizer at 900.degree. to 1,300.degree. C. The coated spinel color pigments are suitable for the production of ceramic decorations with improved contour sharpness.Type: GrantFiled: May 9, 1991Date of Patent: March 16, 1993Assignee: Degussa AGInventors: Dietrich Speer, Akos Kiss, Peter Kleinschmit, Jenny Horst
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Patent number: 5171364Abstract: A process for preparing a conductive, acicular zinc oxide, comprising the steps of: preparing a zinc oxide slurry comprising an acicular zinc oxide, a salt of at least one metal selected from the group consisting of aluminum, gallium, indium and tin and an aqueous solution of an alkali metal hydroxide and having a pH value maintained at 10 to 13, adjusting the pH value of said zinc oxide slurry to 5 to 9 while stirring, aging the slurry, separating the zinc oxide present in the slurry by filtration, washing and drying the separated zinc oxide, and then firing the dried zinc oxide at 500.degree. to 700.degree. C. in a reducing atmosphere.Type: GrantFiled: November 13, 1991Date of Patent: December 15, 1992Assignees: Mitsui Mining & Smelting Co. Ltd., Metallgesellschaft AktiengesellschaftInventors: Norihiro Sato, Takao Hayashi, Nobuyoshi Kasahara, Wolf-Dieter Griebler, Jorg Hocken, Gunther Rudolph