Organic Nitrogen Containing Material Patents (Class 106/448)
  • Patent number: 9920224
    Abstract: The present invention is directed to a unique composition and method for promoting adhesion of substrates to adhesives. The solution comprises a water based primer composition comprising: a) a hydrosylate of one or more alkoxysilyl amine; b) a surfactant; c) an organotitanate, organozirconate, or combinations thereof; d) optionally a fluorescing compound; and e) water. Preferably the organotitanate or organozirconate correspond to formula (I): wherein M is titanium or zirconium and R8 comprises hydrocarbyl ligands, which may optionally contain one or more heteroatoms comprising oxygen, nitrogen, sulfur or phosphorus, optionally two or more of R8 may combine to form a cyclic ring structure. Preferably the composition and method of the invention can be used to bond glass or plastic coated with an abrasion resistant coating, in particular a window for a vehicle, to other substrates such as metal or plastics.
    Type: Grant
    Filed: January 18, 2013
    Date of Patent: March 20, 2018
    Assignee: DOW GLOBAL TECHNOLOGIES LLC
    Inventor: Stefan Schmatloch
  • Patent number: 9662631
    Abstract: A desiccant composition is described. The desiccant composition has a polymeric binder and a dispersion of powders of hygroscopic inorganic oxides as desiccant materials, in which the desiccant powders are finely dispersed in consequence of their surface-modification by fatty acid anions without affecting their moisture sorption performances.
    Type: Grant
    Filed: February 19, 2013
    Date of Patent: May 30, 2017
    Assignee: SAES GETTERS S.P.A.
    Inventors: Jiabril Gigli, Giorgio Macchi, Marco Mudu, Paolo Vacca
  • Patent number: 9528862
    Abstract: A flame resistant fabric with tracing yarns includes a flame resistant fabric with a first non-tracing yarn, and a second tracing yarn. The first non-tracing yarn and/or the second tracing yarn include flame resistant fibers being selected from the group consisting of inherently flame resistant fibers and treated fibers. When the flame resistant fabric is exposed to heat, flames, long-term excessive UV light, or the like, the first non-tracing yarn is adapted to hold its color and the second tracing yarn is adapted to change colors.
    Type: Grant
    Filed: June 16, 2014
    Date of Patent: December 27, 2016
    Assignee: PBI Performance Products, Inc.
    Inventors: William L. Lawson, III, Kimberly M. Henry, Brian P. Shiels
  • Patent number: 9518192
    Abstract: The present invention relates to a process comprising the steps of a) contacting an aqueous dispersion of a TiO2 slurry containing adsorbing dispersant with an adsorbing latex to form a mixture, wherein the pH of the mixture of the TiO2 slurry and adsorbing latex are sufficiently high to inhibit interaction between the TiO2 and the adsorbing latex; then b) lowering the pH of the mixture of step a) sufficiently to promote interaction between the TiO2 and the adsorbing latex, thereby forming a composite. The process of the present invention provides for improved hiding and reduced grit for coatings compositions.
    Type: Grant
    Filed: July 5, 2011
    Date of Patent: December 13, 2016
    Assignee: Rohm and Haas Company
    Inventors: James C. Bohling, Deborah G. Fradkin, Wei Gao, John W. Hook, III, Tao Wang, Tao Wang
  • Patent number: 9259700
    Abstract: The invention concerns a composition comprising as component (A): 10% to 97% by weight, based on the total weight of the composition, of one or more monocarboxylic esters of the general formula R1—CO—OR2, in which R1 is a saturated or unsaturated, branched or straight-chain, aliphatic group having 11 to 23 carbon atoms and R2 is a branched or straight-chain aliphatic group, a cycloaliphatic group or aromatic group having 1 to 13 carbon atoms, and the sum of the carbon atoms of the groups R1 and R2 is not more than 30, the monocarboxylic ester or esters possessing a boiling point of more than 250° C. under a standard pressure of 101.3 kPa, and as component (B): 3% to 90% by weight, based on the total weight of the composition, of one or more dispersants, the composition possessing a viscosity at 25° C. of less than 5000 mPas. The invention further concerns the use of the composition as a dispersion medium, millbases obtained from the composition, and the use of the millbases.
    Type: Grant
    Filed: September 1, 2009
    Date of Patent: February 16, 2016
    Assignee: BYK-Chemie GmbH
    Inventors: Martin Fischer, Wolfgang Pritschins, Frank Vennhoff, Lucia Spikker-Heilen, Andrea Esser
  • Patent number: 9023146
    Abstract: Hydrophilic self-cleaning coating compositions and methods to make and use the compositions are disclosed. The compositions include a pigment material made up of an inorganic pigment attached or linked to at least one oxidizing agent. In some embodiments, the oxidizing agent is an organic molecule covalently or non-covalently attached to the inorganic pigment. In some embodiments, the oxidizing agent is linked to the inorganic pigment by a linker moiety.
    Type: Grant
    Filed: September 25, 2012
    Date of Patent: May 5, 2015
    Assignee: Empire Technology Development LLC
    Inventors: William Brenden Carlson, Feng Wan, Timothy Londergan
  • Patent number: 8968462
    Abstract: The subject matter of the invention relates to aqueous pigment preparations containing (A) 30 to 75% by weight of at least one inorganic white or colored pigment or a mixture of different inorganic white or colored pigments, (B) 0.01 to 15% by weight of at least one fatty acid ethanol amide ethoxylate of the formula (I), in which R1 is a linear or branched alkyl radical or alkenyl radical with 7 to 21 carbon atoms, and n is a whole number from 2 to 40, (C) 0.01 to 5% by weight of at least one amine of the formula (II), in which R2 is a linear or branched alkyl radical or alkenyl radical with 8 to 22 carbon atoms, identical to or different from R1, A represents an iminopropyl group —NH—CH2—CH2—CH2—, an oxyethyl group —O—CH2—CH2— or an oxypropyl group —O—CH2—CH(CH3)—CH2—, and a is a whole number from 0 to 5, wherein the compound of the formula (II); can be present in the form of an ammonium salt, and (E) water.
    Type: Grant
    Filed: December 19, 2012
    Date of Patent: March 3, 2015
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Hendrik Ahrens
  • Patent number: 8961682
    Abstract: Hydrophilic coating compositions and methods to make and use the compositions are disclosed. The compositions include a photocatalytic pigment material made up of an inorganic pigment and a monomeric anti-oxidants and free radical scavenger that is contacted to the surface of the inorganic pigment.
    Type: Grant
    Filed: July 26, 2012
    Date of Patent: February 24, 2015
    Assignee: Empire Technology Development LLC
    Inventors: William Brenden Carlson, Angele Sjong, Feng Wan, Timothy Londergan
  • Publication number: 20150000566
    Abstract: The subject matter of the invention relates to aqueous pigment preparations containing (A) 30 to 75% by weight of at least one inorganic white or colored pigment or a mixture of different inorganic white or colored pigments, (B) 0.01 to 15% by weight of at least one fatty acid ethanol amide ethoxylate of the formula (I), in which R1 is a linear or branched alkyl radical or alkenyl radical with 7 to 21 carbon atoms, and n is a whole number from 2 to 40, (C) 0.01 to 5% by weight of at least one amine of the formula (II), in which R2 is a linear or branched alkyl radical or alkenyl radical with 8 to 22 carbon atoms, identical to or different from R1, A represents an iminopropyl group —NH—CH2—CH2—CH2—, an oxyethyl group —O—CH2—CH2— or an oxypropyl group —O—CH2—CH(CH3)—CH2—, and a is a whole number from 0 to 5, wherein the compound of the formula (II); can be present in the form of an ammonium salt, and (E) water.
    Type: Application
    Filed: December 19, 2012
    Publication date: January 1, 2015
    Applicant: Clariant Finance (BVI) Limited
    Inventor: Hendrik Ahrens
  • Publication number: 20140366776
    Abstract: An aqueous paint composition comprising by weight of the total composition i) from 1 to 6%, preferably from 2 to 5% chelating thickener ii) from 2 to 8%, preferably from 3 to 5% clay thickener and iii) from 0 to 30%, preferably 5 to 20% clay extender whereby said composition is capable of being formed into a self-supporting, dimensionally stable paint body
    Type: Application
    Filed: June 16, 2014
    Publication date: December 18, 2014
    Applicant: AKZO NOVEL COATINGS INTERNATIONAL B.V.
    Inventor: Gary Thomas WREN
  • Publication number: 20140238272
    Abstract: The present invention relates to a new mineral matter particle hydrophobization agent and to its various uses for the surface treatment of mineral matter particles.
    Type: Application
    Filed: February 18, 2014
    Publication date: August 28, 2014
    Applicant: COATEX
    Inventors: Jean-Marc SUAU, Jacques MONGOIN, Christian JACQUEMET
  • Publication number: 20140225021
    Abstract: The present invention relates to a method for producing a dispersion and to the use of a protein hydrolysate as a dispersant or dispersing agent. In particular, the invention relates to a method for producing a suspension as well as the use of a protein hydrolysate as a dispersant in a suspension. According to the invention it is proposed to use in particular hydrolysates of proteins with a consecutive sequence of amino acids with polar and nonpolar side groups as dispersants.
    Type: Application
    Filed: September 17, 2012
    Publication date: August 14, 2014
    Applicant: OTC GMBH
    Inventors: Gerd Dahms, Andreas Jung
  • Publication number: 20140196629
    Abstract: Hydrophilic coating compositions and methods to make and use the compositions are disclosed. The compositions include a photocatalytic pigment material made up of an inorganic pigment and a monomeric anti-oxidants and free radical scavenger that is contacted to the surface of the inorganic pigment.
    Type: Application
    Filed: July 26, 2012
    Publication date: July 17, 2014
    Applicant: EMPIRE TECHNOLOGY DEVELOPMENT LLC
    Inventors: William Brenden Carlson, Angele Sjong, Feng Wan, Timothy Londergan
  • Patent number: 8747617
    Abstract: A method of preparing a stable dispersion of flocculated filler particles for use in papermaking processes comprises sequential addition of a first flocculating agent to an aqueous dispersion of filler particles followed by shearing of the dispersion, followed by addition of a second flocculating agent to the dispersion and further shearing of the resultant filler flocs to the desired particle size resulting in shear resistant filler flocs with a defined and controllable size distribution. In addition, a neutralizing coagulant can be added to the dispersion to partially or completely neutralize the charge of the filler before the first flocculating agent is added.
    Type: Grant
    Filed: April 18, 2012
    Date of Patent: June 10, 2014
    Assignee: Nalco Company
    Inventors: Weiguo Cheng, Ross T. Gray
  • Publication number: 20140083323
    Abstract: Hydrophilic self-cleaning coating compositions and methods to make and use the compositions are disclosed. The compositions include a pigment material made up of an inorganic pigment attached or linked to at least one oxidizing agent. In some embodiments, the oxidizing agent is an organic molecule covalently or non-covalently attached to the inorganic pigment. In some embodiments, the oxidizing agent is linked to the inorganic pigment by a linker moiety.
    Type: Application
    Filed: September 25, 2012
    Publication date: March 27, 2014
    Applicant: EMPIRE TECHNOLOGY DEVELOPMENT LLC
    Inventors: William Brenden Carlson, Feng Wan, Timothy Londergan
  • Publication number: 20140041549
    Abstract: The disclosure provides a treated inorganic pigment, typically a titanium dioxide pigment, comprising an inorganic pigment having a surface area of about 30 to about 75 m2/g; wherein the pigment surface is treated with an organic treating agent comprising a polyalkanol alkane or a polyalkanol amine, present in the amount of at least about 1.5%, based on the total weight of the treated pigment; wherein the treated inorganic pigment has a RHI (rat hole index) of about 7 to about 11. The treated inorganic pigments have better flow characteristics, and generally fewer lumps.
    Type: Application
    Filed: April 24, 2012
    Publication date: February 13, 2014
    Applicant: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: Daniel C. Kraiter, Timothy Allan Bell
  • Patent number: 8647472
    Abstract: The invention provides a method of producing paper with a higher proportion of mineral filler particles than is otherwise be possible without the expected loss in paper strength by preflocculating the filler particles. The method allows for the use of the greater amount of filler particles by coating at least some of the filler particles with a material that prevents the filler materials form adhering to a strength additive. The strength additive holds the paper fibers together tightly and is not wasted on the filler particles.
    Type: Grant
    Filed: March 19, 2010
    Date of Patent: February 11, 2014
    Assignee: Nalco Company
    Inventors: Weiguo Cheng, Ross T. Gray
  • Publication number: 20130074731
    Abstract: The invention relates to a stable, highly concentrated, aqueous suspension of nanoparticles, particularly of titanium dioxide particles, a method for production, and use of the suspension, e.g. for coating or impregnation, or as an additive in organic or inorganic matrices. The suspension contains a first dispersant based on a polymeric alkoxylate and a second dispersant selected from the group of amino alcohols. The suspension is preferably characterized by the fact that its stability is preserved even during and after vigorous dispersion in an attrition mill and no increase in viscosity occurs. In a preferred embodiment, the viscosity declines by up to 10 to 50% as a function of the milling time. In a further embodiment, the suspension can be dried and subsequently redispersed, without the state of dispersion deteriorating.
    Type: Application
    Filed: September 26, 2012
    Publication date: March 28, 2013
    Applicant: Kronos International, Inc.
    Inventors: Ina Metz, Christian Scheidt, Stephan-Peter Blob
  • Publication number: 20130040392
    Abstract: Various agents for improving adhesion of cold end coatings on glass surfaces are described Also described are agents for improving bonding between cold end coatings and organic inks. And, methods and related detection solutions for detecting the presence of cold end coatings on a substrate such as a glass bottle are disclosed. Additionally, particular additives and primers are described that can be applied onto cold end coatings for improving adhesion thereto.
    Type: Application
    Filed: January 21, 2011
    Publication date: February 14, 2013
    Applicant: FERRO CORPORATION
    Inventors: Cindy Pankiewicz, Thirumalai Duraisamy, Bertram Gardner, Ian Dudas, David C. Kapp, Enos A. Axtell, III, George E. Sakoske
  • Publication number: 20130011350
    Abstract: The invention relates to metal oxide particles and/or metal hydroxide particles, aftertreated with an organic phosphorus compound, process for the preparation thereof, and compositions comprising same.
    Type: Application
    Filed: February 28, 2011
    Publication date: January 10, 2013
    Applicants: SACHTLEBEN CHEMIE GMBH, MERCK PATENT GMBH
    Inventors: Joern Beck, Ruediger Graf, Frank Pfluecker, Gabriele Benkner, Bernd Hirthe, Stephan John
  • Publication number: 20130000518
    Abstract: A water-based paint composition may include at least one mineral treated with at least one hydrophobizing agent. The at least one mineral may include at least one of clay, kaolin, mica, titanium dioxide, talc, natural or synthetic silica or silicates, feldspars, nepheline syenite, talc, wollastonite, diatomite, barite, glass, and calcium carbonate. The at least one hydrophobizing agent may include at least one of fatty acids, fatty amines, and silanes. A method of making water-based paint may include treating at least one mineral with a hydrophobizing agent, and combining the at least one treated mineral with a binder.
    Type: Application
    Filed: March 3, 2011
    Publication date: January 3, 2013
    Applicant: Imerys Kaolin, Inc.
    Inventors: Stephen Raper, David Skelhorn
  • Patent number: 8317912
    Abstract: The present invention relates to an antimicrobial composition comprising an isothiazolin-3-one, such as 1,2-benzisothiazolin-3-one, a zinc compound selected from zinc salts, zinc oxide, zinc hydroxide or combinations thereof, a pyrithione salt or pyrithione acid, and a surfactant selected from the group consisting of (i) an anionic surfactant having a sulfate or sulfonate moiety attached to a straight or branched chain containing from about 10 to about 18 atoms at the backbone of the chain, (ii) an anionic surfactant being an alkylaryl sulfonic acid or salt thereof wherein the alkyl portion contains from about 10 to about 18 carbon atoms, and the aryl portion contains a benzyl or substituted benzyl group, and combinations thereof. This composition is particularly effective in preventing the growth of various microorganisms in mineral slurries such as aqueous calcium carbonate slurries.
    Type: Grant
    Filed: March 9, 2012
    Date of Patent: November 27, 2012
    Assignee: Arch Chemicals, Inc.
    Inventors: Helen Margaret Hyde, Fitzgerald Clarke, Helmut Peters, Terri Williams
  • Patent number: 8303851
    Abstract: Mixtures of additives in granular form comprising: one or more stabilizers for organic polymers; one or more organic or inorganic pigments; and/or one or more dyes; obtained by extrusion at a temperature capable of enabling the partial or total melting of the lowest-melting component. The above mixtures can be used in the stabilization and dyeing of organic polymers.
    Type: Grant
    Filed: January 18, 2008
    Date of Patent: November 6, 2012
    Assignee: Great Lakes Chemical (Europe) GmbH
    Inventors: Carlo Neri, Corrado Callierotti
  • Patent number: 8172983
    Abstract: A method of preparing a stable dispersion of flocculated filler particles for use in papermaking processes comprises sequential addition of high and low molecular weight flocculating agents to an aqueous dispersion of filler particles followed by shearing of the resultant filler flocs to the desired particle size resulting in shear resistant filler flocs with a defined and controllable size distribution.
    Type: Grant
    Filed: September 12, 2007
    Date of Patent: May 8, 2012
    Assignee: Nalco Company
    Inventors: Weiguo Cheng, Ross T. Gray
  • Patent number: 8088213
    Abstract: A method of preparing a stable dispersion of flocculated filler particles for use in papermaking processes comprises sequential addition of a first flocculating agent to an aqueous dispersion of filler particles followed by shearing of the dispersion, followed by addition of a second flocculating agent to the dispersion and further shearing of the resultant filler flocs to the desired particle size resulting in shear resistant filler flocs with a defined and controllable size distribution. In addition, a neutralizing coagulant can be added to the dispersion to partially or completely neutralize the charge of the filler before the first flocculating agent is added.
    Type: Grant
    Filed: April 28, 2009
    Date of Patent: January 3, 2012
    Assignee: Nalco Company
    Inventors: Weiguo Cheng, Ross T. Gray
  • Publication number: 20110259244
    Abstract: This invention refers to particles with a crystalline core of titanium dioxide that has an average diameter of ?30 nm measured with the XRD/Scherrer method, a shell made of a metal oxide that has no photocatalytic properties and an outer skin that carries organic radicals.
    Type: Application
    Filed: December 18, 2009
    Publication date: October 27, 2011
    Applicant: Fraunhofer-Gesellschaft zur Foerderung der angewandlen Forschung e.V.
    Inventors: Bettina Herbig, Gerhard Schottner
  • Publication number: 20100311871
    Abstract: There is provided colloidal silica particles comprising at least one polyvalent metal element M selected from a group consisting of iron, aluminum, zinc, zirconium, titanium, tin, and lead in an average content of 0.001 to 0.02 in terms of an M/Si molar ratio, and having an average primary particle diameter of 5 to 40 nm, wherein the content of the polyvalent metal element M present in an outermost layer of the colloidal particles is 0 to 0.003 atom per square nanometer (nm2) of a surface area of the colloidal particles; and a silica sol that the colloidal silica particles are dispersed in an organic solvent, a silica sol that the colloidal silica particles are dispersed in a polymerizable compound, and a silica sol that the colloidal silica particles are dispersed in a dicarboxylic anhydride.
    Type: Application
    Filed: February 12, 2009
    Publication date: December 9, 2010
    Applicant: NISSAN CHEMICAL INDUSTRIES, LTD.
    Inventors: Naohiko Suemura, Keiko Yoshitake, Toshiaki Takeyama
  • Publication number: 20100227181
    Abstract: A bright pigment 100 includes: a flaky substrate 10; a first layer 20 that is formed on the flaky substrate 10 and that contains one selected from the group consisting of titanium dioxide, silver and a silver alloy as its main component; and a second layer 30 that is formed so that the first layer 20 is interposed between the flaky substrate 10 and the second layer 30 and that contains the hydroxide or hydrated oxide of neodymium.
    Type: Application
    Filed: October 17, 2008
    Publication date: September 9, 2010
    Applicant: NIPPON SHEET GLASS COMPANY, LIMITED
    Inventor: Takeaki Kitamura
  • Patent number: 7763111
    Abstract: In various embodiments, a pigment composition is provided comprising a base particle and a dispersing agent, the dispersing agent comprising a salt and/or ester of: (i) an amine, alcohol, and/or alkanol amine and (ii) a polyprotic acid, wherein the mole ratio of the amine, alcohol, and/or alkanol amine to the polyprotic acid is greater than 3:1. In various embodiments, the pigments have improved stability, hiding power, tint strength, and/or gloss.
    Type: Grant
    Filed: July 17, 2007
    Date of Patent: July 27, 2010
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Modasser El-Shoubary, Robert M. Hopkins, Karen L. Bowen, David E. Bell
  • Publication number: 20100126378
    Abstract: A sulfonated derivative of an organic pigment moiety comprising a polyetheramine, and a metal or ammonium salt. The pigment is used for coloration of printing inks and coatings. For ink-jet systems there is excellent filterability, low viscosity, and stability thereof.
    Type: Application
    Filed: April 3, 2008
    Publication date: May 27, 2010
    Inventor: Stanislav Vilner
  • Patent number: 7452416
    Abstract: A composition containing cationic pigment particles includes titanium dioxide particles to which are bound a first water-soluble cationic polymer and cationic polymer latex particles. In some embodiments the cationic latex is made by treating an anionic latex with a second water-soluble cationic polymer, which may be the same as or different from the first water-soluble cationic polymer. The compositions may be used in papermaking applications, both for internal addition and or coatings.
    Type: Grant
    Filed: May 17, 2005
    Date of Patent: November 18, 2008
    Assignee: CPM Industries
    Inventor: Glenn R. Evers
  • Publication number: 20080156224
    Abstract: A method for forming a transparent hydrophobic self-cleaning coating material, comprising: providing particle precursors to form first particles; and reacting first particles with a low-surface-energy compound to form second particles, wherein the first particles are chemically bonded to the low-surface-energy compound and diameters of the second particles are less than 400 nm.
    Type: Application
    Filed: August 3, 2007
    Publication date: July 3, 2008
    Inventors: Yi-Che Su, Yuung-Ching Sheen, Ya-Tin Yu
  • Patent number: 7387672
    Abstract: The present invention relates to oxidation-stable iron oxide pigments which have a coating of at least one organic substance, to their preparation and to their use.
    Type: Grant
    Filed: May 1, 2007
    Date of Patent: June 17, 2008
    Assignee: LANXESS Deutschland GmbH
    Inventor: Holger Friedrich
  • Patent number: 7341626
    Abstract: A pigment composition containing one or more, organic yellow pigments selected from the group C.I. Pigment Yellow (213), Pigment Yellow (214) and disazo pigment of the formula (I) and containing one or more inorganic pigments.
    Type: Grant
    Filed: August 18, 2004
    Date of Patent: March 11, 2008
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Joachim Weber, Gerhard Wilker
  • Patent number: 7261770
    Abstract: In various embodiments, a pigment composition is provided comprising a base particle and a dispersing agent, the dispersing agent comprising a salt and/or ester of: (i) an amine, alcohol, and/or alkanol amine and (ii) a polyprotic acid, wherein the mole ratio of the amine, alcohol, and/or alkanol amine to the polyprotic acid is greater than 3:1. In various embodiments, the pigments have improved stability, hiding power, tint strength, and/or gloss.
    Type: Grant
    Filed: November 24, 2004
    Date of Patent: August 28, 2007
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Modasser El-Shoubary, Robert M. Hopkins, Karen L. Bowen, David E. Bell
  • Patent number: 7138010
    Abstract: The invention is a pigment comprising titanium dioxide and an amino phosphoryl compound. The pigment of the invention imparts improved physical qualities, such as improved lacing resistance and dispersion, when incorporated into polymers.
    Type: Grant
    Filed: December 12, 2005
    Date of Patent: November 21, 2006
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Modasser El-Shoubary, M. Kamal Akhtar
  • Patent number: 6911116
    Abstract: Cationically modified white pigments (W) in particulate form, essentially consisting of a particulate inorganic white pigment (M) of a particle size in the range of 0,1 to 40 ?m and an applied water soluble, cationic, crosslinked polymer (PA) containing quaternary ammonium groups in salt form, obtainable by reaction of epichlorohydrin or of epichlorohydrin derivatives or precursors with amines, under conditions leading to at least partial crosslinking, optionally in combination with an anionic optical brightener (B) and where the molar ratio of (B) to (PA) is such that the number of cationic charges of the total polymer (PA) is higher than the number of anionic charges of the total anionic optical brightener (B), are surprisingly useful as cationic white pigments in various fields of technique, especially in papermaking.
    Type: Grant
    Filed: December 19, 2000
    Date of Patent: June 28, 2005
    Assignee: Clariant Finance (BVI) Limited
    Inventors: John Martin Farrar, Andrew Clive Jackson, Alec Stewart Tindal
  • Patent number: 6811601
    Abstract: Pigment preparations comprising A) at least one organic or inorganic pigment and B) at least one ethoxylated and propoxylated and/or butoxylated polyethyleneimine.
    Type: Grant
    Filed: November 25, 2002
    Date of Patent: November 2, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Oliver Borzyk, Jürgen Huff, Manfred Mielke, Rüdiger Sens
  • Patent number: 6784231
    Abstract: A pigment having weak dispersion force to be readily dispersed in a medium to be colored from which an excellent yellow image having superior transparency can be produced. The pigment includes a compound having the same chemical formula as C.I. Pigment Yellow 180. The BET specific surface area based on the nitrogen absorption process of the pigment is 20-100 m2/g, and the ratio of the absolute strength of X-ray diffraction at Bragg angle 2&thgr;=17.5°±0.2° to the absolute strength of X-ray diffraction at Bragg angle 2&thgr;=18.2°±0.2° of the pigment in a powder X-ray diffraction diagram using a CuK&agr; characteristic X-ray is less than 1.8/1.0. The present invention also provides a dispersion including the pigment and a thermoplastic resin having excellent transparency and color strength.
    Type: Grant
    Filed: March 19, 2002
    Date of Patent: August 31, 2004
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Katsunori Shimada, Junko Sunouchi
  • Patent number: 6736892
    Abstract: The present invention provides sulfated and carboxymethylated surfactants and dispersants produced by reacting a styrenated phenol alkoxylate with sulfamic acid and then neutralizing with a base such as ammonium hydroxide. The instant invention also provides pigment dispersion comprising: (a) a pigment; and (b) a dispersant based on sulfated and carboxymethylated styrenated phenol alkoxylates. Carbon black dispersions are also provided containing carbon black and the dispersants of the invention.
    Type: Grant
    Filed: July 16, 2002
    Date of Patent: May 18, 2004
    Assignee: Ethox Chemicals LLC
    Inventors: Edward R. Godwin, Paul David Weipert
  • Patent number: 6663851
    Abstract: A product obtained by treating surface-modified, pyrogenically produced titanium dioxide with at least one ammonium-functional silane, such as by spraying the pyrogenically produced titanium dioxide with the at least one silane, alone or in ethanol solution, and tempering, and useful in the field of cosmetics in sunblocks, in toner powders, in paints and varnishes, in silicone rubber, as abrasives and polishes, for example, in the field of CMP.
    Type: Grant
    Filed: June 29, 2000
    Date of Patent: December 16, 2003
    Assignee: Degussa AG
    Inventors: Klaus Deller, Dieter Kerner, Juergen Meyer
  • Patent number: 6638349
    Abstract: A composition consisting of the reaction product of a halogenated carboxylic acid, an amine, and optionally a fatty acid. The composition has biocidal properties and enhances pigment dispersibility.
    Type: Grant
    Filed: March 5, 2002
    Date of Patent: October 28, 2003
    Inventor: George K. Atkinson
  • Publication number: 20030181329
    Abstract: A method of producing composite particles of titanium dioxide and a compound inactive as a photocatalyst, comprising the steps of preparing a water based slurry of pH 3 to 5 comprising titanium dioxide, preparing a water based solution comprising a compound inactive as a photocatalyst, and reacting the slurry and the water based solution together at a pH within a range from 4 to 10 is provided, together with highly active photocatalyst particles produced using such a method, and potential uses of such photocatalyst particles.
    Type: Application
    Filed: December 19, 2002
    Publication date: September 25, 2003
    Applicant: SHOWA DENKO K.K.
    Inventors: Jun Tanaka, Masayuki Sanbayashi, Yoshinori Ueyoshi
  • Patent number: 6558464
    Abstract: The present invention discloses high solids slurries of anatase titanium dioxide pigment comprising greater than about 75% by weight of anatase TiO2 pigment dispersed in water. A process for producing the slurries of the present invention is disclosed which comprises the steps of a) dry milling the anatase titanium dioxide pigment, preferably by pressure rolling, and b) mixing the dry milled pigment with water in the presence of an acrylic acid dispersant.
    Type: Grant
    Filed: February 7, 2001
    Date of Patent: May 6, 2003
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Robert J. Kostelnik, Fu-chu Wen
  • Patent number: 6521038
    Abstract: A near-infrared reflecting composite pigment comprises a near-infrared non-absorbing colorant and a white pigment coated with the near-infrared non-absorbing pigment. The near-infrared reflecting composite pigment can be produced by mixing a colorant dispersion, in which the near-infrared non-absorbing colorant is dispersed in a liquid medium, with the white pigment in a form selected from powder or a dispersion and then drying the resultant mixture. A near-infrared reflecting coating agent comprises as a coloring agent the near-infrared reflecting composite pigment. A near-infrared reflecting material comprises a base material coated on a surface thereof with the near-infrared reflecting coating agent.
    Type: Grant
    Filed: November 28, 2001
    Date of Patent: February 18, 2003
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Hiromitsu Yanagimoto, Yoshiyuki Zama, Hisao Okamoto, Tohru Hosoda, Yoshio Abe, Michiei Nakamura
  • Publication number: 20030010459
    Abstract: Cationically modified white pigments (W) in particulate form, essentially consisting of a particulate inorganic white pigment (M) of a particle size in the range of 0, 1 to 40 &mgr;m and an applied water soluble, cationic, crosslinked polymer (PA) containing quaternary ammonium groups in salt form, obtainable by reaction of epichlorohydrin or of epichlorohydrin derivatives or precursors with amines, under conditions leading to at least partial crosslinking, optionally in combination with an anionic optical brightener (B) and where the molar ratio of (B) to (PA) is such that the number of cationic charges of the total polymer (PA) is higher than the number of anionic charges of the total anionic optical brightener (B), are surprisingly useful as cationic white pigments in various fields of technique, especially in papermaking.
    Type: Application
    Filed: June 17, 2002
    Publication date: January 16, 2003
    Inventors: John Martin Farrar, Andrew Clive Jackson, Alec Stewart Tindal
  • Patent number: 6471762
    Abstract: Colored lustrous pigments of superior quality are prepared by dry blending a platy substrate such as a metal oxide-coated mica nacreous pigment and a hydrophobic colorant at low shear. The resulting blend exhibits a well dispersed, stable coloration, increased hydrophobicity and is particularly useful in industrial and automotive applications. The technique can also be employed to prepare pigments for cosmetic application.
    Type: Grant
    Filed: August 23, 2000
    Date of Patent: October 29, 2002
    Assignee: Engelhard Corp.
    Inventors: Carmine Vincent DeLuca, Jr., Jeannine M. Gale
  • Patent number: 6444313
    Abstract: A thermochromic acrylic synthetic fiber comprising an acrylonitrile polymer in which a thermochromic pigment composition with an average particle diameter of from 0.5 &mgr;m to 30 &mgr;m is dispersedly contained in an amount of from 0.5% by weight to 40% by weight based on the weight of the polymer, and being made into fibers; the pigment composition containing (a) an electron-donating color-developing organic compound, (b) an electron-accepting compound and (c) a reaction medium that determines the temperature at which the color-developing reaction of the both compounds takes place. Also disclosed are a processed article of the above thermochromic acrylic synthetic fiber, and a process for producing the thermochromic acrylic synthetic fiber.
    Type: Grant
    Filed: January 5, 2001
    Date of Patent: September 3, 2002
    Assignee: The Pilot Ink Co., Ltd.
    Inventors: Yoshiaki Ono, Naoya Ishimura, Yutaka Shibahashi
  • Patent number: 6420437
    Abstract: A neutral titanium dioxide colloid sol having a high stability in a neutral range and capable of forming a colorless transparent coating even when dried at room temperature is produced by mixing an acid titanium dioxide sol comprising 50 to 100 parts by weight of titanium dioxide colloidal particles and 5 to 50 parts by weight of a chelating agent for titanium ions with 1 to 50 parts by weight of an alkaline substance comprising at least one of alkali metal compounds and amine compounds, and optionally by adjusting the pH value of the liquid mixture to 5 to 10, or adjusting the pH value of the liquid mixture to 6 to 10, and then applying a deionization treatment to the mixture to thereby charge the titanium dioxide colloidal particles with negative electricity.
    Type: Grant
    Filed: July 26, 2000
    Date of Patent: July 16, 2002
    Assignee: Nihon Parkerizing Co., Ltd.
    Inventors: Kazuhiko Mori, Mitsuru Nakamura, Masanobu Tanaka
  • Patent number: RE41858
    Abstract: A pearlescent pigment based on a metal oxide-coated, platelet-shaped substrate and a top layer on the metal oxide layer, where the top layer comprises silicon dioxide, at least one further metal hydroxide or metal oxide hydrate and at least one organic coupling reagent. The further metal hydroxides or metal oxide hydrates are hydroxides or oxide hydrates of cerium, aluminum or zirconium, or mixtures thereof. The coupling reagents employed are organofunctional silanes, zirconium aluminates or metal acid esters.
    Type: Grant
    Filed: October 7, 2009
    Date of Patent: October 26, 2010
    Assignee: Merck Patent Gesellschaft MIT Beschrankter Haftung
    Inventors: Joachim Duschek, Ralf Glausch