Organic Nitrogen Containing Material Patents (Class 106/448)
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Patent number: 6409815Abstract: Surface-modified conductive pigment obtainable by partial coating of a conductive pigment with an organic modifying agent. The modifying agent is an organometallic compound of the elements silicon, tin, titanium, zirconium or aluminum. The pigment is prepared by dispersing a conductive pigment, subsequently adding the modifying agent, if appropriate as a mixture with a solvent, to the pigment dispersion, and in particular in an amount such that the powder electrical conductance of the partly coated conductive pigment is in the range between 80% of the starting value and 10−7 S, removing the solvent present, if appropriate, with further agitation and heating of the pigment to 100° C. and finally drying the partly coated pigment.Type: GrantFiled: April 5, 1995Date of Patent: June 25, 2002Assignee: Merck Patent Gesellschaft mit beschraenkter HaftungInventors: Alfred Hennemann, Manfred Kieser
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Patent number: 6348092Abstract: A composition consisting of the reaction product of a halogenated carboxylic acid, an amine, and optionally a fatty acid. The composition has biocidal properties and enhances pigment dispersibility.Type: GrantFiled: October 25, 1999Date of Patent: February 19, 2002Inventor: George K. Atkinson
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Patent number: 6336966Abstract: A pigment dispersion comprising pigment, an aqueous carrier selected from water and a mixture of water and at least one organic solvent, and a pigment dispersant is described. The pigment dispersant has core and arm star-type architecture, and is prepared by controlled radical polymerization, e.g., atom transfer radical polymerization, using (i) arm-core, (ii) arm-core-arm, (iii) core-arm, or (iv) concurrent core and arm methods. The arms of the pigment dispersant each have hydrophobic and hydrophilic polymeric chain segments.Type: GrantFiled: December 16, 1999Date of Patent: January 8, 2002Assignee: PPG Industries Ohio, Inc.Inventors: Simion Coca, James B. O'Dwyer
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Publication number: 20010007231Abstract: The present invention discloses high solids slurries of anatase titanium dioxide pigment comprising greater than about 75% by weight of anatase TiO2 pigment dispersed in water. A process for producing the slurries of the present invention is disclosed which comprises the steps of a) dry milling the anatase titanium dioxide pigment, preferably by pressure rolling, and b) mixing the dry milled pigment with water in the presence of an acrylic acid dispersant.Type: ApplicationFiled: February 7, 2001Publication date: July 12, 2001Inventors: Robert J. Kostelnik, Fu-chu Wen
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Patent number: 6231662Abstract: An additive for enhancing the performance of industrial pigments. The additive improves dispersibility and is the reaction product of an amine, a fatty amine, and a polybasic acid.Type: GrantFiled: October 25, 1999Date of Patent: May 15, 2001Inventor: George K. Atkinson
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Patent number: 6197104Abstract: The present invention discloses high solids slurries of anatase titanium dioxide pigment comprising greater than about 75% by weight of anatase TiO2 pigment dispersed in water. A process for producing the slurries of the present invention is disclosed which comprises the steps of a) dry milling the anatase titanium dioxide pigment, preferably by pressure rolling, and b) mixing the dry milled pigment with water in the presence of an acrylic acid dispersant.Type: GrantFiled: May 4, 1998Date of Patent: March 6, 2001Assignee: Millennium Inorganic Chemicals, Inc.Inventors: Robert J. Kostelnik, Fu-chu Wen
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Patent number: 6176918Abstract: Modified pearl luster pigments for waterborn coating systems, based on a platelet-form substrate coated with metal oxides and, located on the topmost metal oxide layer, a top layer consisting of at least two oxides and/or mixed oxides from the group consisting of silicon dioxide, aluminium oxide, cerium oxide, titanium oxide and zirconium oxide, and on a water-based oligomeric silane system. The oligomeric silane system can be described, for example, by the following approximate structure: [HO[Si(A)(OH)z(CH3)1−zO]a[Si(B)(OH)y(CH3)1−yO]b[Si(E)(OH)w(CH3)1−wO]c[Si(D)(OH)v(CH3)1−vO]dH].Type: GrantFiled: May 22, 1998Date of Patent: January 23, 2001Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung and Huels AGInventors: Ralf Glausch, Nicole Fornoff, Joachim Duschek, Burkhard Standke, Roland Edelmann
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Patent number: 6139617Abstract: There are provided titanium dioxide pigments characterized by improved gloss developing and dispersibility properties in surface coating vehicles and reduced dispersant requirements. Said titanium dioxide pigments comprise pigmentary titanium dioxide particles having deposited thereon a treating agent comprising at least one amine salt of a monoprotic.Type: GrantFiled: September 9, 1997Date of Patent: October 31, 2000Assignee: Kerr-McGee Chemical LLCInventors: John E. Halko, Frances K. Tyler, David A. Doherty
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Patent number: 6139610Abstract: A corrosion-inhibiting composition for application to a metal substrate, such as steel, silver, copper or aluminum, includes a film-forming organic polymer component and a dispersed pigment phase of a stable unitary hybrid which contains organic and inorganic solid phase constituents interfaced at a micro-crystalline level, which are inseparable by physical separation procedures and which display uniphase behavior. The inorganic phase includes a cation selected from Zn, Al, Mg, Ca, Sr, Ti, Zr, Ce and Fe and an anion selected from phosphates, polyphosphates, phosphites, molybdates, silicates and cyanamides.Type: GrantFiled: June 3, 1999Date of Patent: October 31, 2000Assignee: Wayne Pigment Corp.Inventor: John Sinko
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Patent number: 6129786Abstract: Composite pigments based on nanoparticulate metal oxides modified by crosslinked or uncrosslinked polyalkylenepolyamine and anionic dyes are useful for coloring paints, inks, plastic, paper, wood, leather and textile materials.Type: GrantFiled: May 19, 1998Date of Patent: October 10, 2000Assignee: BASF AktiengesellschaftInventors: Boubacar Camara, Manfred Patsch, Ulrich Steuerle, Jurgen Romeis
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Patent number: 6123762Abstract: The invention relates to granulates based on silicate fillers, the surface of which was modified with organosilicon compounds, a process for manufacturing the granulates by spraying a suspension of these fillers together with the organosilicon compounds in a spray granulator and the use of the granulates in vulcanizable rubber mixtures.Type: GrantFiled: March 12, 1997Date of Patent: September 26, 2000Assignee: Degussa-Huls AGInventors: Thomas Barthel, Udo Gorl, Alan Parkhouse, Kurt Eichenauer
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Patent number: 6123763Abstract: A colorless or only slightly colored pigment dispersing agent which is feasible as a pigment dispersing agent for pigments having various hues and has the general formula (1), ##STR1## wherein R.sub.1, R.sub.2, X.sub.1, Y.sub.1, Y.sub.2, k and h are as defined in claim 1.Type: GrantFiled: January 20, 1999Date of Patent: September 26, 2000Assignee: Toyo Ink Mfg. Co., Ltd.Inventors: Takashi Kamikubo, Yuuji Hirasawa, Toru Omura
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Patent number: 6103360Abstract: A ceiling board coating composition includes water, a binder and a filler, said filler having large particles with an average particle size of a minimum of about 50 microns, medium particles with an average particle size in the range of from about 1.2 to about 30 microns, and small particles which have an average particle size in the range of from about 0.1 to about 1.0 microns.Type: GrantFiled: January 9, 1998Date of Patent: August 15, 2000Assignee: Armstrong World Industries, Inc.Inventors: Kenneth G. Caldwell, Raymond H. Fernando
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Patent number: 6068688Abstract: A modified particle is disclosed wherein a particle has an attached group having the formula: ##STR1## wherein Ar represents an aromatic group; R.sup.1 represents a bond, an arylene group, an alkylene ##STR2## wherein R.sup.4 is an alkyl or alkylene group or an aryl or arylene group; R.sup.2 and R.sup.3, which can be the same or different, represent hydrogen, an alkyl group, an aryl group, --OR.sup.5, --NHR.sup.5, --NR.sup.5 R.sup.5, or --SR.sup.5, wherein R.sup.5, which is the same or different, represents an alkyl group or an aryl group; and SFR represents a stable free radical. Also disclosed is a modified particle or aggregate having attached a group having the formula: ##STR3## wherein CoupA represents a Si-containing group, a Ti-containing group, or a Zr-containing group; R.sup.8 and R.sup.9, which can be the same or different, represent hydrogen, an alkyl group, an aryl group, --OR.sup.10, --NHR.sup.10, --NR.sup.10 R.sup.10, or --SR.sup.10, wherein R.sup.Type: GrantFiled: November 12, 1997Date of Patent: May 30, 2000Assignee: Cabot CorporationInventors: Robert S. Whitehouse, Russell L. Warley, Thimma R. Rawalpally, Hairuo Tu
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Patent number: 6063182Abstract: A stir-in pigment composition for coloring high-molecular-weight material, particularly coatings and ink systems, comprises 85 to 99.5 parts by weight of a pigment and 0.5 to 15 parts by weight of an additive comprising a vinylpyrrolidone polymer or copolymer. The stir-in pigment composition is in the form of microgranules and is obtainable by spray drying a high solids content aqueous pigment dispersion containing the pigment and the additive. The new pigment composition powders are easily handled, easily wetted and disperse rapidly to form homogeneous aqueous pigment dispersions which are practically free of larger pigment aggregates and can readily be incorporated into aqueous ink and paint systems as stir-in pigments without a dispersion step in a bead mill.Type: GrantFiled: December 16, 1998Date of Patent: May 16, 2000Assignee: Ciba Speciality Chemicals CorporationInventor: Fridolin Babler
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Patent number: 6022404Abstract: Surface-modified, pyrogenically produced mixed oxides which contain two or more components of the series SiO.sub.2, Al.sub.2 O.sub.3, TiO.sub.2, ZrO.sub.2, Fe.sub.2 O.sub.3, Nb.sub.2 O.sub.5, V.sub.2 O.sub.5, WO.sub.3, SnO.sub.2, GeO.sub.2 and have been surface-modified with one to several compounds of the following groups:(a) organosilanes of the type (RO).sub.3 Si(C.sub.n H.sub.2n+1),(b) R'.sub.x (RO).sub.y Si(C.sub.n H.sub.2n+1),(c) X.sub.3 Si(C.sub.n H.sub.2n+1),(d) X.sub.2 (R')Si(C.sub.n H.sub.2n+1),(e) X(R').sub.2 Si(C.sub.n H.sub.2n+1),(f) (RO).sub.3 Si(CH.sub.2).sub.m --R',(g) (R").sub.x (RO).sub.y Si(CH.sub.2).sub.m --R',(h) X.sub.3 Si(CH.sub.2).sub.m --R',(i) (R)X.sub.2 Si(CH.sub.2).sub.m --R',(j) (R).sub.2 X Si(CH.sub.2).sub.m --R',(k) Silazanes of the type ##STR1## (l) Cyclic polysiloxanes, (m) Polysiloxanes or silicone oils.Type: GrantFiled: January 11, 1996Date of Patent: February 8, 2000Assignee: Degussa AktiengesellschaftInventors: Manfred Ettlinger, Werner Hartmann, Dieter Kerner, Jurgen Meyer
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Patent number: 5910213Abstract: A pigmentary material comprises particulate titanium dioxide the particles of which have been treated with a polymeric hindered amine stabiliser. The stabiliser is a polymer having a main chain substantially free of acidic groups and having hindered amine stabilising groups. The stabilising groups comprise at least 35 per cent by weight of the polymer. Preferably, the titanium dioxide particles are also treated with an organic compound such as a polyhydric alcohol, an alkanolamine, a polysiloxane or a fatty acid.Type: GrantFiled: July 31, 1997Date of Patent: June 8, 1999Assignee: Tioxide Group Services LimitedInventors: Steven Hugh Ashdown, Robert McIntyre, Neil Martin Richmond
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Patent number: 5908498Abstract: A process for preparing a low-dusting, free-flowing pigment which has not been subjected to any micronizing treatment comprising the steps of providing an inorganic pigment material; providing a source of water; forming a fine, well dispersed slurry of the pigment and water; milling the slurry; depositing a treating agent having the formula ROOCCHSO.sub.3 MCH.sub.2 COOR' wherein R and R' are monovalent alkyl radicals having from about 2 to about 20 carbon atoms, and M is a metallic monovalent cation on the slurried milled pigment; and drying the pigment material having a treating agent deposited thereon. The invention also provides the free-flowing pigments produced by this process.Type: GrantFiled: March 31, 1998Date of Patent: June 1, 1999Assignee: Kerr-McGee Chemical LLCInventors: James W. Kauffman, Phillip M. Story, John E. Halko
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Patent number: 5855662Abstract: Aqueous pigment preparations comprisinga) 10 to 80% by weight, in particular 20 to 60% by weight, of a pigment,b) 0.1 to 20% by weight, in particular 0.1 to 15% by weight, of an oxyalkylation product which is obtained by addition of optionally substituted styrenes onto optionally substituted phenols and reaction with ethylene oxide and/or propylene oxide,c) 2 to 30% by weight of a polyether-polyol having a boiling point under normal pressure of greater than 150.degree. C. andd) if appropriate further additives, and water as the remainder,which are particularly suitable for pigmenting naturally occurring and synthetic materials, such as emulsion paints, emulsion coatings and emulsion printing inks, have been found.Type: GrantFiled: March 26, 1996Date of Patent: January 5, 1999Assignee: Bayer AktiengesellschaftInventors: Achim Brand, Josef Leitermann, Roger Nyssen, Klaus Schubert, Erhard Schuffenhauer, Karlheinz Wieser, Herbert Wigger
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Patent number: 5837045Abstract: A surface-modified colored pigment is disclosed which includes a colored pigment having no primary amines and at least one attached hydrophilic organic group, wherein said organic group comprises a) at least one aromatic group, and b) at least one ionic group or ionizable group, or a mixture of an ionic group or an ionizable group. The colored pigment may be blue, brown, cyan, green, violet, magenta, red, orange, yellow, mixtures thereof and the like. The surface-modified colored pigment, due to the hydrophilic groups on its surface, is readily dispersed in a liquid vehicle without the addition of a surfactant or other dispersing aid or additive. The surface-modified color pigment may be used in a variety of aqueous systems including, but not limited to, coatings, paints, papers, adhesives, latexes, inks, toners, textiles and fibers. In addition, an aqueous composition is disclosed including water-based liquid vehicle and the surface-modified colored pigment described above.Type: GrantFiled: June 17, 1996Date of Patent: November 17, 1998Assignee: Cabot CorporationInventors: Joseph E. Johnson, James A. Belmont
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Patent number: 5705033Abstract: Unique titanium dioxide (TiO.sub.2) particulates have an especially high physicochemical affinity for cellulosic fibers and, thus, are well suited as opacifying pigments for paper and paper laminates, and include a zeta potential-adjusting amount of at least one cationic polymer, e.g., a polymer of a quaternary ammonium, sulfonium or phosphonium salt or a copolymer of acrylamide with a cationic comonomer, fixed to the face surfaces thereof.Type: GrantFiled: December 30, 1992Date of Patent: January 6, 1998Assignee: Rhone-Poulenc ChimieInventors: Bernard Gerard, Remy Lorang, Anny Mazzacavallo
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Patent number: 5686085Abstract: New lysine derivatives containing a containing an alkylsulphonyl or alkylaminocarbonyl group of formula (I):COOH--CH(NH.sub.2)--(CH.sub.2).sub.4 --NH--Xin which X represents an --SO.sub.2 R or --CONHR group, where R represents a linear or branched, saturated or unsaturated, alkyl radical having from 8 to 22 carbon atoms, salts thereof, and mixtures of the derivatives and the salts. A process for the preparation of these derivatives, salts, and mixtures and use of such derivatives, salts, and mixtures, especially in cosmetics. Compositions, especially cosmetic compositions, comprising the derivatives, salts, and mixtures.Type: GrantFiled: January 23, 1996Date of Patent: November 11, 1997Assignee: L'OrealInventors: Thierry Bordier, Michel Philippe
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Patent number: 5676748Abstract: A method for producing bulking and opacifying kaolin fillers for filling cellulosic products is disclosed. An aqueous slurry of anionically dispersed kaolin particles is formed at 1 to 30% solids. A low-molecular-weight cationic aggregating agent is then added to the dispersed slurry to selectively aggregate fine and ultra-fine particles. The resultant aggregates are of larger mean particle size than the feed material and contain little or no fine and ultra-fine or colloidal particles. The net charge present on the aggregated particles is lower than that of the feed material. The aggregated structure contains within it a labyrinth of internal voids or pores. These mineral aggregates are then of a suitable size and surface charge to be retained well in a fiber web, and provide added bulk and opacity to the cellulosic products.Type: GrantFiled: December 29, 1995Date of Patent: October 14, 1997Assignee: Columbia River CarbonatesInventor: Alan J. Brown
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Patent number: 5676746Abstract: A process is provided for the selective aggregation of the fine and ultrafine particles present in an anionically or cationically dispersed mineral pigment slurry, such that an aggregated structure is formed which contains within it a labyrinth of internal voids or pores, which collectively function as light scattering centers. The aggregates are formed from an assemblage of fine mineral particles, interconnected or bonded together with small quantities of a cationic or anionic polymer or agent of low molecular weight. The resultant aggregates are of larger mean particle size than the feed material and contain little or no fine and colloidal particles. The net charge present on the aggregated particles is lower than that of the feed material. These mineral aggregates are then of a suitable size and surface charge to be retained well in a fiber web by a combination of filtration retention and adsorption retention, and provide added bulk and opacity to the finished sheet of paper.Type: GrantFiled: April 11, 1995Date of Patent: October 14, 1997Assignee: Columbia River CarbonatesInventor: Alan J. Brown
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Patent number: 5676747Abstract: A method for producing structured calcium carbonate pigments for coating paper is disclosed. An aqueous slurry of anionically dispersed calcium carbonate particles is formed at 1 to 30 percent solids. A low-molecular-weight cationically charged aggregating agent is then added to the slurry to selectively aggregate fine and ultra-fine particles. The resultant aggregates are of larger mean particle size than the mixture of particles in the original slurry and contain little or no fine and colloidal particles. The net charge present on the aggregated particles is lower than that of the original mineral particles. The low solids suspension of the aggregated mineral particles is then dewatered, or increased in solids to form a slurry with a solids content greater than 60 percent by weight.Type: GrantFiled: December 29, 1995Date of Patent: October 14, 1997Assignee: Columbia River CarbonatesInventor: Alan J. Brown
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Patent number: 5653795Abstract: A method is disclosed for producing bulking and opacifying pigments for filling paper by the selective aggregation of fine particles in an anionically or cationically dispersed slurry, such that an aggregated structure is formed which contains within it a labyrinth of internal voids or pores. The aqueous slurry is formed at one to thirty percent solids. A low molecular weight agent of opposite ionic charge is then added to the slurry to selectively aggregate the fine particles present. The resultant aggregates are of larger mean particle size than the feed material and contain little or no fine and colloidal particles. The net charge present on the aggregated particles is lower than that of the feed material.Type: GrantFiled: November 16, 1995Date of Patent: August 5, 1997Assignee: Columbia River CarbonatesInventor: Alan J. Brown
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Patent number: 5650003Abstract: A pigment composition containing titanium dioxide (TiO.sub.2) and calcined clay in a weight ratio of between about 30:70 and 70:30, preferably between about 35:65 and 45:55 that is substantially free of a functional microgel component has advantages over a similar pigment containing a functional microgel. The pigment composition contains an amount of epichlorohydrin dimethylamine condensate that is sufficient to cationize the pigment, and lacks a microgel component. It is liquid when agitated. Preferably the composition has a solids content greater than about 55%, and most preferably between about 59% and about 61%.Type: GrantFiled: December 18, 1995Date of Patent: July 22, 1997Assignee: Nord Naolin CompanyInventors: Jerry Leon Curtis, Lester William House
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Patent number: 5556641Abstract: A composition comprising colorant-containing particles having a coating comprising propylene glycol and a carrier component selected from the group consisting of carriers suitable for food, drug and cosmetic preparations and mixtures thereof.Type: GrantFiled: June 17, 1994Date of Patent: September 17, 1996Assignee: Whittaker, Clark & Daniels, Inc.Inventors: George C. Lambridis, Nathanial Goodwin
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Patent number: 5505965Abstract: A composition comprising colorant-containing particles having a coating comprising propylene glycol and a carrier component selected from the group consisting of carriers suitable for food, drug and cosmetic preparations and mixtures thereof.Type: GrantFiled: December 6, 1994Date of Patent: April 9, 1996Assignee: Whittaker, Clark & Daniels, Inc.Inventors: George C. Lambridis, Nathanial Goodwin
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Patent number: 5482640Abstract: Aqueous dispersions of PTFE and TiO.sub.2 stabilized from the effects of freeze/thaw cycles are disclosed, wherein the stabilizing agents are monohydric alcohols and monoamines having less than five carbon atoms.Type: GrantFiled: October 28, 1994Date of Patent: January 9, 1996Assignee: Consep, Inc.Inventor: Thomas H. Eberlein
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Patent number: 5449403Abstract: A product in the form of colored inorganic particles including one or a number of melanin pigments, a process for its preparation and to its use, especially in the field of cosmetics, for make-up for the exoskeleton and/or for the skin, and in protecting human skin against UV radiation.Type: GrantFiled: January 3, 1994Date of Patent: September 12, 1995Assignee: L'OrealInventors: Herve Andrean, Alex Junino, Jean P. Arraudeau
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Patent number: 5449774Abstract: The present invention provides a process for producing beta-form pigmentary copper phthalocyanine comprising a) producing crude copper phthalocyanine by charging phthalic anhydride or phthalimide, urea, a copper compound and a catalyst, at a substantially continuous and uniform rate, into a reaction chamber containing dry, granular, pre-formed copper phthalocyanine, and removing the reaction product from the reaction chamber; and b) convening the crude copper phthalocyanine produced in step a) into pigmentary form, by milling it either in the dry state or in an aqueous medium; mixing the milled material with an aqueous emulsion comprising i) a liquid C.sub.6 -C.sub.20 amine which is insoluble in water or alkali but is soluble in acid and ii) a surfactant capable of emulsifying the liquid amine; rendering the resulting mixture acidic to thereby dissolve the amine; and finally separating the desired pigmentary copper phthalocyanine from the treatment mixture.Type: GrantFiled: April 1, 1991Date of Patent: September 12, 1995Assignee: Ciba-Geigy CorporationInventors: Ian A. Lambie, Michael D. McFarlane, Robert Langley
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Patent number: 5401313Abstract: This invention relates to modifying the surface of particles for improved dispersion characteristics in aqueous, solvent, resinous, polymeric, cementitious or the like application systems. In particular, this invention relates to a pigment or filler particle whose surface is coated with at least one electric charge modifying agent and at least one dispersion promoting agent, which has improved dispersibility, coloring, handling, and other processing properties in application systems. The electric charge modifying agent may be selected from the group of Mg, Ca, Ba, Sr, Ti, V, Zr, Cr, Mn, Fe, Co, Ni, Cu, Zn, and Al. The dispersion promoting agent may be selected from the group of stearates, acetates, alkylphenols, cellulosics, waxes, lignins, polyacrylics, polyepoxies, polyurethanes, polyethylenes, polystyrenes and polypropylenes, and polymers having functional groups of alcohols, glycols, aldehydes, amides and carboxylic acids. Iron oxide is the preferred pigment particle.Type: GrantFiled: February 10, 1993Date of Patent: March 28, 1995Assignee: Harcros Pigments, Inc.Inventors: William W. Supplee, James T. Will, Jr.
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Patent number: 5380359Abstract: A melanin-coated pigment obtained by coating a carrier with a readily alkali-soluble natural melanin, and a cosmetic containing the pigment are provided. The melanin-coated pigment is highly safe and has high coloring and high saturation tone, and a cosmetic which contains it is also expected to have ultraviolet-ray-absorbing and anti-oxidizing effects.Type: GrantFiled: November 24, 1993Date of Patent: January 10, 1995Assignee: Kyowa Hakko Kogyo Co., Ltd.Inventors: Shinkichi Honda, Yoichiro Takekoshi, Yoichiro Arai
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Patent number: 5376172Abstract: A process for preparing silane metal oxides comprising reacting a metal oxide with an amine compound to form an amine metal oxide intermediate, and subsequently reacting said intermediate with a halosilane.Type: GrantFiled: December 23, 1992Date of Patent: December 27, 1994Assignee: Xerox CorporationInventors: Carl P. Tripp, Michael L. Hair, Richard P. N. Veregin
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Patent number: 5336311Abstract: This invention relates to structural aggregate pigment products that are cationic, and have improved wet-end retention. A method for converting anionic pigments to cationic pigments is also provided. More particularly, a structural aggregate pigment comprising a clay and/or titanium dioxide or other particulate components, and a functional microgel made from silicon and aluminum or zinc gel formers and a gelling agent such as calcium chloride, can be cationized by adding an effective amount of modified or unmodified epichlorhydrin dimethylamine condensate to a slurry of the structured pigment. The resulting cationic pigments have superior papermaking characteristics and a much improved retention.Type: GrantFiled: July 7, 1992Date of Patent: August 9, 1994Assignee: Nord Kaolin CompanyInventors: Jerry L. Curtis, Kenneth A. Johnson, Lester W. House
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Patent number: 5279664Abstract: A method for dispersing a comminuted solid in an aqueous medium is described. An aqueous dispersing agent is added to an aqueous medium in an amount sufficient to disperse the comminuted solid in the aqueous medium. The aqueous dispersing agent includes from about 10 wt. % to about 55 wt. % of an amine compound selected from the group consisting of alkanolamines, triethylamine and morpholine, from about 15 wt. % to about 35 wt. % of a base selected from the group consisting of sodium hydroxide and potassium hydroxide, and from about 0.1 wt. % to about 15 wt. % chelating agent.Type: GrantFiled: December 17, 1991Date of Patent: January 18, 1994Assignee: Angus Chemical CompanyInventors: Glenn N. Robinson, Gregory E. McWright
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Patent number: 5169441Abstract: Fillers and pigments, such as clay, titanium dioxide, calcium carbonate, silicas, and silicoaluminates, can be rendered cationic by treating the fillers or pigments with the reaction product of a polyamine or polyamide and epichlorohydrin. The resulting water soluble cationic fillers or pigments are useful in the paper industry as fillers for paper and can also be utilized in coating paper.Type: GrantFiled: December 17, 1990Date of Patent: December 8, 1992Assignee: Hercules IncorporatedInventor: Rodrigue V. Lauzon
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Patent number: 5076847Abstract: A new titanium chelate has been developed which introduces improvements into aqueous emulsion paints. The chelate is a reaction product of a titanium orthoester, a glycol or a glycol ether, an alkanolamine and an alpha-hydroxy carboxy acid.Type: GrantFiled: May 8, 1990Date of Patent: December 31, 1991Assignee: Tioxide Group PLCInventors: Peter D. Kay, McDonald Keith
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Patent number: 4985079Abstract: Disclosed is a medium set cationic bituminous emulsion comprising, relative to the emulsion:a. about 40 to 75% by weight asphalt;b. 0.25 to 5% by weight of a cationic emulsifier;c. 0.1 to 0.5% by weight of a nonionic water-soluble thickening agent;d. 0 to 8% of a low-boiling hydrocarbon; ande. water as a continuous phase of said emulsion to make up 100% by weight;wherein said medium set emulsion when combined with open-graded aggregate produces a mix which has a thick coating of emulsion on said aggregate surface and said mix is workable and results in minimum runoff.Type: GrantFiled: April 5, 1989Date of Patent: January 15, 1991Assignee: Chevron Research CompanyInventors: Peter E. Graf, Steven J. Agazzi, Eugene J. Vanderzanden
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Patent number: 4978747Abstract: Colorants are obtained by reacting a dyestuff which is free from ionic groups and has.gtoreq.2 NH.sub.2 groups which are preferably arranged in such a manner that they do not participate in the resonance of the chromophore with such an amount of a (cyclo)aliphatic diisocyante so as to form an adduct that still contains at least two free NCO groups, and subsequently reacting this adduct with a (cyclo)aliphatic diamine, to form an adduct suitable for dyeing and pigmenting macromolecular substances, in particular for coloring PUR-based paints, coatings and laminates.Type: GrantFiled: April 13, 1989Date of Patent: December 18, 1990Assignee: Bayer AktiengesellschaftInventors: Karl-Arnold Weber, Hermann Henk, Klaus Kunde, Jochen Westphal, Klaus Wunderlich
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Patent number: 4935063Abstract: Stabilizing inorganic fillers or pigments having simultaneous reinforcing effect and stabilizing effect on organic polymers are obtained by a process comprising the following stages:(a) bringing the inorganic filler or pigment into contact with a solution, in an inert organic solvent, of a sterically hindered amine comprising one or more alkoxysilane groups in its molecule;(b) maintaining the obtained mixture at higher than ambient temperature (20.degree.-25.degree. C.) for a period of at least 0.5 hours;(c) removing the solvent, treating at a temperature of 120.degree.-200.degree. C. and recovering the stabilizing filler or pigment obtained.Type: GrantFiled: September 9, 1988Date of Patent: June 19, 1990Assignee: Enichem Synthesis S.p.A.Inventors: Silvestro Costanzi, Omero Zavattini, deceased, Ugo Bersellini, Damiano Gussoni
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Patent number: 4935502Abstract: When a diamine of the formula ##STR1## in which n is 1 to 4, is bis-diazotized and the resulting bis-diazo compound is coupled with 2 moles of one or more coupling components of the formula ##STR2## in which R.sup.1 is hydrogen, chlorine, bromine, methyl or methoxy and R.sup.2 is hydrogen or, if R.sup.1 is hydrogen, also methyl or ethyl, disazo compounds are obtained which are colorants. Due to their high fastness to light and to migration and their heat stability and dispersibility, these compounds are useful for pigmenting high molecular weight materials, especially polyolefins.Type: GrantFiled: August 22, 1989Date of Patent: June 19, 1990Assignee: Hoechst AktiengesellschaftInventors: Rudolf Kuhne, Heinrich Hamal
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Patent number: 4909852Abstract: This invention is concerned with the treatment of particulate titanium dioxide and other pigments with a surfactant compound which serves to enhance its employment in pigmented and/or filled paints and plastics, paper making compositions and in reinforced plastic composite compositions.Type: GrantFiled: April 29, 1988Date of Patent: March 20, 1990Inventor: George K. Atkinson
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Patent number: 4870164Abstract: Symmetrical and asymmetrical disazo compounds of the formula: ##STR1## wherein: the R.sup.1 's are identical or different and are hydrogen, chlorine, bromine, methyl or methoxy;the R.sup.2 's are hydrogen, or, if the R.sup.1 's are hydrogen, the R.sup.2 's are hydrogen, methyl or ethyl, the two R.sup.2 radicals being identical or different; andn is 1 to 4and mixtures of such compounds as colorants, especially for pigmenting high molecular weight organic material.Type: GrantFiled: January 28, 1985Date of Patent: September 26, 1989Assignee: Hoechst AktiengesellschaftInventors: Rudolf Kuhne, Heinrich Hamal
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Patent number: 4844742Abstract: Surface modification of a variety of pigments, particularly quinacridone pigments, and the pigments resulting therefrom whereby the pigment is treated with a solvent-free, basic, nitrogen-containing copolymer of the polyurethane series and with a dispersion-improving derivative of the primary pigment resulting in compositions exhibiting enhanced performance in automative and other finish systems.Type: GrantFiled: May 15, 1987Date of Patent: July 4, 1989Assignee: Ciba-Geigy CorporationInventor: Edward E. Jaffe
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Patent number: 4822427Abstract: Disclosed is a cationic bituminous emulsion comprising relative to the emulsion about 40 to 70% by weight asphalt, 0.25 to 5% by weight of a cationic emulsifier, 0.1-0.5% by weight of a water-soluble thickening agent, 0-8% of a low-boiling hydrocarbon, and water as a continuous phase of said emulsion to make up 100% by weight. The emulsion is particularly useful for open-graded roads.Type: GrantFiled: October 31, 1986Date of Patent: April 18, 1989Assignee: Chevron Research CompanyInventors: Peter E. Graf, Steven J. Agazzi, Eugene J. Vanderzanden