Organic Nitrogen Containing Material Patents (Class 106/448)
  • Patent number: 6409815
    Abstract: Surface-modified conductive pigment obtainable by partial coating of a conductive pigment with an organic modifying agent. The modifying agent is an organometallic compound of the elements silicon, tin, titanium, zirconium or aluminum. The pigment is prepared by dispersing a conductive pigment, subsequently adding the modifying agent, if appropriate as a mixture with a solvent, to the pigment dispersion, and in particular in an amount such that the powder electrical conductance of the partly coated conductive pigment is in the range between 80% of the starting value and 10−7 S, removing the solvent present, if appropriate, with further agitation and heating of the pigment to 100° C. and finally drying the partly coated pigment.
    Type: Grant
    Filed: April 5, 1995
    Date of Patent: June 25, 2002
    Assignee: Merck Patent Gesellschaft mit beschraenkter Haftung
    Inventors: Alfred Hennemann, Manfred Kieser
  • Patent number: 6348092
    Abstract: A composition consisting of the reaction product of a halogenated carboxylic acid, an amine, and optionally a fatty acid. The composition has biocidal properties and enhances pigment dispersibility.
    Type: Grant
    Filed: October 25, 1999
    Date of Patent: February 19, 2002
    Inventor: George K. Atkinson
  • Patent number: 6336966
    Abstract: A pigment dispersion comprising pigment, an aqueous carrier selected from water and a mixture of water and at least one organic solvent, and a pigment dispersant is described. The pigment dispersant has core and arm star-type architecture, and is prepared by controlled radical polymerization, e.g., atom transfer radical polymerization, using (i) arm-core, (ii) arm-core-arm, (iii) core-arm, or (iv) concurrent core and arm methods. The arms of the pigment dispersant each have hydrophobic and hydrophilic polymeric chain segments.
    Type: Grant
    Filed: December 16, 1999
    Date of Patent: January 8, 2002
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Simion Coca, James B. O'Dwyer
  • Publication number: 20010007231
    Abstract: The present invention discloses high solids slurries of anatase titanium dioxide pigment comprising greater than about 75% by weight of anatase TiO2 pigment dispersed in water. A process for producing the slurries of the present invention is disclosed which comprises the steps of a) dry milling the anatase titanium dioxide pigment, preferably by pressure rolling, and b) mixing the dry milled pigment with water in the presence of an acrylic acid dispersant.
    Type: Application
    Filed: February 7, 2001
    Publication date: July 12, 2001
    Inventors: Robert J. Kostelnik, Fu-chu Wen
  • Patent number: 6231662
    Abstract: An additive for enhancing the performance of industrial pigments. The additive improves dispersibility and is the reaction product of an amine, a fatty amine, and a polybasic acid.
    Type: Grant
    Filed: October 25, 1999
    Date of Patent: May 15, 2001
    Inventor: George K. Atkinson
  • Patent number: 6197104
    Abstract: The present invention discloses high solids slurries of anatase titanium dioxide pigment comprising greater than about 75% by weight of anatase TiO2 pigment dispersed in water. A process for producing the slurries of the present invention is disclosed which comprises the steps of a) dry milling the anatase titanium dioxide pigment, preferably by pressure rolling, and b) mixing the dry milled pigment with water in the presence of an acrylic acid dispersant.
    Type: Grant
    Filed: May 4, 1998
    Date of Patent: March 6, 2001
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Robert J. Kostelnik, Fu-chu Wen
  • Patent number: 6176918
    Abstract: Modified pearl luster pigments for waterborn coating systems, based on a platelet-form substrate coated with metal oxides and, located on the topmost metal oxide layer, a top layer consisting of at least two oxides and/or mixed oxides from the group consisting of silicon dioxide, aluminium oxide, cerium oxide, titanium oxide and zirconium oxide, and on a water-based oligomeric silane system. The oligomeric silane system can be described, for example, by the following approximate structure: [HO[Si(A)(OH)z(CH3)1−zO]a[Si(B)(OH)y(CH3)1−yO]b[Si(E)(OH)w(CH3)1−wO]c[Si(D)(OH)v(CH3)1−vO]dH].
    Type: Grant
    Filed: May 22, 1998
    Date of Patent: January 23, 2001
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung and Huels AG
    Inventors: Ralf Glausch, Nicole Fornoff, Joachim Duschek, Burkhard Standke, Roland Edelmann
  • Patent number: 6139617
    Abstract: There are provided titanium dioxide pigments characterized by improved gloss developing and dispersibility properties in surface coating vehicles and reduced dispersant requirements. Said titanium dioxide pigments comprise pigmentary titanium dioxide particles having deposited thereon a treating agent comprising at least one amine salt of a monoprotic.
    Type: Grant
    Filed: September 9, 1997
    Date of Patent: October 31, 2000
    Assignee: Kerr-McGee Chemical LLC
    Inventors: John E. Halko, Frances K. Tyler, David A. Doherty
  • Patent number: 6139610
    Abstract: A corrosion-inhibiting composition for application to a metal substrate, such as steel, silver, copper or aluminum, includes a film-forming organic polymer component and a dispersed pigment phase of a stable unitary hybrid which contains organic and inorganic solid phase constituents interfaced at a micro-crystalline level, which are inseparable by physical separation procedures and which display uniphase behavior. The inorganic phase includes a cation selected from Zn, Al, Mg, Ca, Sr, Ti, Zr, Ce and Fe and an anion selected from phosphates, polyphosphates, phosphites, molybdates, silicates and cyanamides.
    Type: Grant
    Filed: June 3, 1999
    Date of Patent: October 31, 2000
    Assignee: Wayne Pigment Corp.
    Inventor: John Sinko
  • Patent number: 6129786
    Abstract: Composite pigments based on nanoparticulate metal oxides modified by crosslinked or uncrosslinked polyalkylenepolyamine and anionic dyes are useful for coloring paints, inks, plastic, paper, wood, leather and textile materials.
    Type: Grant
    Filed: May 19, 1998
    Date of Patent: October 10, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Boubacar Camara, Manfred Patsch, Ulrich Steuerle, Jurgen Romeis
  • Patent number: 6123763
    Abstract: A colorless or only slightly colored pigment dispersing agent which is feasible as a pigment dispersing agent for pigments having various hues and has the general formula (1), ##STR1## wherein R.sub.1, R.sub.2, X.sub.1, Y.sub.1, Y.sub.2, k and h are as defined in claim 1.
    Type: Grant
    Filed: January 20, 1999
    Date of Patent: September 26, 2000
    Assignee: Toyo Ink Mfg. Co., Ltd.
    Inventors: Takashi Kamikubo, Yuuji Hirasawa, Toru Omura
  • Patent number: 6123762
    Abstract: The invention relates to granulates based on silicate fillers, the surface of which was modified with organosilicon compounds, a process for manufacturing the granulates by spraying a suspension of these fillers together with the organosilicon compounds in a spray granulator and the use of the granulates in vulcanizable rubber mixtures.
    Type: Grant
    Filed: March 12, 1997
    Date of Patent: September 26, 2000
    Assignee: Degussa-Huls AG
    Inventors: Thomas Barthel, Udo Gorl, Alan Parkhouse, Kurt Eichenauer
  • Patent number: 6103360
    Abstract: A ceiling board coating composition includes water, a binder and a filler, said filler having large particles with an average particle size of a minimum of about 50 microns, medium particles with an average particle size in the range of from about 1.2 to about 30 microns, and small particles which have an average particle size in the range of from about 0.1 to about 1.0 microns.
    Type: Grant
    Filed: January 9, 1998
    Date of Patent: August 15, 2000
    Assignee: Armstrong World Industries, Inc.
    Inventors: Kenneth G. Caldwell, Raymond H. Fernando
  • Patent number: 6068688
    Abstract: A modified particle is disclosed wherein a particle has an attached group having the formula: ##STR1## wherein Ar represents an aromatic group; R.sup.1 represents a bond, an arylene group, an alkylene ##STR2## wherein R.sup.4 is an alkyl or alkylene group or an aryl or arylene group; R.sup.2 and R.sup.3, which can be the same or different, represent hydrogen, an alkyl group, an aryl group, --OR.sup.5, --NHR.sup.5, --NR.sup.5 R.sup.5, or --SR.sup.5, wherein R.sup.5, which is the same or different, represents an alkyl group or an aryl group; and SFR represents a stable free radical. Also disclosed is a modified particle or aggregate having attached a group having the formula: ##STR3## wherein CoupA represents a Si-containing group, a Ti-containing group, or a Zr-containing group; R.sup.8 and R.sup.9, which can be the same or different, represent hydrogen, an alkyl group, an aryl group, --OR.sup.10, --NHR.sup.10, --NR.sup.10 R.sup.10, or --SR.sup.10, wherein R.sup.
    Type: Grant
    Filed: November 12, 1997
    Date of Patent: May 30, 2000
    Assignee: Cabot Corporation
    Inventors: Robert S. Whitehouse, Russell L. Warley, Thimma R. Rawalpally, Hairuo Tu
  • Patent number: 6063182
    Abstract: A stir-in pigment composition for coloring high-molecular-weight material, particularly coatings and ink systems, comprises 85 to 99.5 parts by weight of a pigment and 0.5 to 15 parts by weight of an additive comprising a vinylpyrrolidone polymer or copolymer. The stir-in pigment composition is in the form of microgranules and is obtainable by spray drying a high solids content aqueous pigment dispersion containing the pigment and the additive. The new pigment composition powders are easily handled, easily wetted and disperse rapidly to form homogeneous aqueous pigment dispersions which are practically free of larger pigment aggregates and can readily be incorporated into aqueous ink and paint systems as stir-in pigments without a dispersion step in a bead mill.
    Type: Grant
    Filed: December 16, 1998
    Date of Patent: May 16, 2000
    Assignee: Ciba Speciality Chemicals Corporation
    Inventor: Fridolin Babler
  • Patent number: 6022404
    Abstract: Surface-modified, pyrogenically produced mixed oxides which contain two or more components of the series SiO.sub.2, Al.sub.2 O.sub.3, TiO.sub.2, ZrO.sub.2, Fe.sub.2 O.sub.3, Nb.sub.2 O.sub.5, V.sub.2 O.sub.5, WO.sub.3, SnO.sub.2, GeO.sub.2 and have been surface-modified with one to several compounds of the following groups:(a) organosilanes of the type (RO).sub.3 Si(C.sub.n H.sub.2n+1),(b) R'.sub.x (RO).sub.y Si(C.sub.n H.sub.2n+1),(c) X.sub.3 Si(C.sub.n H.sub.2n+1),(d) X.sub.2 (R')Si(C.sub.n H.sub.2n+1),(e) X(R').sub.2 Si(C.sub.n H.sub.2n+1),(f) (RO).sub.3 Si(CH.sub.2).sub.m --R',(g) (R").sub.x (RO).sub.y Si(CH.sub.2).sub.m --R',(h) X.sub.3 Si(CH.sub.2).sub.m --R',(i) (R)X.sub.2 Si(CH.sub.2).sub.m --R',(j) (R).sub.2 X Si(CH.sub.2).sub.m --R',(k) Silazanes of the type ##STR1## (l) Cyclic polysiloxanes, (m) Polysiloxanes or silicone oils.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: February 8, 2000
    Assignee: Degussa Aktiengesellschaft
    Inventors: Manfred Ettlinger, Werner Hartmann, Dieter Kerner, Jurgen Meyer
  • Patent number: 5910213
    Abstract: A pigmentary material comprises particulate titanium dioxide the particles of which have been treated with a polymeric hindered amine stabiliser. The stabiliser is a polymer having a main chain substantially free of acidic groups and having hindered amine stabilising groups. The stabilising groups comprise at least 35 per cent by weight of the polymer. Preferably, the titanium dioxide particles are also treated with an organic compound such as a polyhydric alcohol, an alkanolamine, a polysiloxane or a fatty acid.
    Type: Grant
    Filed: July 31, 1997
    Date of Patent: June 8, 1999
    Assignee: Tioxide Group Services Limited
    Inventors: Steven Hugh Ashdown, Robert McIntyre, Neil Martin Richmond
  • Patent number: 5908498
    Abstract: A process for preparing a low-dusting, free-flowing pigment which has not been subjected to any micronizing treatment comprising the steps of providing an inorganic pigment material; providing a source of water; forming a fine, well dispersed slurry of the pigment and water; milling the slurry; depositing a treating agent having the formula ROOCCHSO.sub.3 MCH.sub.2 COOR' wherein R and R' are monovalent alkyl radicals having from about 2 to about 20 carbon atoms, and M is a metallic monovalent cation on the slurried milled pigment; and drying the pigment material having a treating agent deposited thereon. The invention also provides the free-flowing pigments produced by this process.
    Type: Grant
    Filed: March 31, 1998
    Date of Patent: June 1, 1999
    Assignee: Kerr-McGee Chemical LLC
    Inventors: James W. Kauffman, Phillip M. Story, John E. Halko
  • Patent number: 5855662
    Abstract: Aqueous pigment preparations comprisinga) 10 to 80% by weight, in particular 20 to 60% by weight, of a pigment,b) 0.1 to 20% by weight, in particular 0.1 to 15% by weight, of an oxyalkylation product which is obtained by addition of optionally substituted styrenes onto optionally substituted phenols and reaction with ethylene oxide and/or propylene oxide,c) 2 to 30% by weight of a polyether-polyol having a boiling point under normal pressure of greater than 150.degree. C. andd) if appropriate further additives, and water as the remainder,which are particularly suitable for pigmenting naturally occurring and synthetic materials, such as emulsion paints, emulsion coatings and emulsion printing inks, have been found.
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: January 5, 1999
    Assignee: Bayer Aktiengesellschaft
    Inventors: Achim Brand, Josef Leitermann, Roger Nyssen, Klaus Schubert, Erhard Schuffenhauer, Karlheinz Wieser, Herbert Wigger
  • Patent number: 5837045
    Abstract: A surface-modified colored pigment is disclosed which includes a colored pigment having no primary amines and at least one attached hydrophilic organic group, wherein said organic group comprises a) at least one aromatic group, and b) at least one ionic group or ionizable group, or a mixture of an ionic group or an ionizable group. The colored pigment may be blue, brown, cyan, green, violet, magenta, red, orange, yellow, mixtures thereof and the like. The surface-modified colored pigment, due to the hydrophilic groups on its surface, is readily dispersed in a liquid vehicle without the addition of a surfactant or other dispersing aid or additive. The surface-modified color pigment may be used in a variety of aqueous systems including, but not limited to, coatings, paints, papers, adhesives, latexes, inks, toners, textiles and fibers. In addition, an aqueous composition is disclosed including water-based liquid vehicle and the surface-modified colored pigment described above.
    Type: Grant
    Filed: June 17, 1996
    Date of Patent: November 17, 1998
    Assignee: Cabot Corporation
    Inventors: Joseph E. Johnson, James A. Belmont
  • Patent number: 5705033
    Abstract: Unique titanium dioxide (TiO.sub.2) particulates have an especially high physicochemical affinity for cellulosic fibers and, thus, are well suited as opacifying pigments for paper and paper laminates, and include a zeta potential-adjusting amount of at least one cationic polymer, e.g., a polymer of a quaternary ammonium, sulfonium or phosphonium salt or a copolymer of acrylamide with a cationic comonomer, fixed to the face surfaces thereof.
    Type: Grant
    Filed: December 30, 1992
    Date of Patent: January 6, 1998
    Assignee: Rhone-Poulenc Chimie
    Inventors: Bernard Gerard, Remy Lorang, Anny Mazzacavallo
  • Patent number: 5686085
    Abstract: New lysine derivatives containing a containing an alkylsulphonyl or alkylaminocarbonyl group of formula (I):COOH--CH(NH.sub.2)--(CH.sub.2).sub.4 --NH--Xin which X represents an --SO.sub.2 R or --CONHR group, where R represents a linear or branched, saturated or unsaturated, alkyl radical having from 8 to 22 carbon atoms, salts thereof, and mixtures of the derivatives and the salts. A process for the preparation of these derivatives, salts, and mixtures and use of such derivatives, salts, and mixtures, especially in cosmetics. Compositions, especially cosmetic compositions, comprising the derivatives, salts, and mixtures.
    Type: Grant
    Filed: January 23, 1996
    Date of Patent: November 11, 1997
    Assignee: L'Oreal
    Inventors: Thierry Bordier, Michel Philippe
  • Patent number: 5676748
    Abstract: A method for producing bulking and opacifying kaolin fillers for filling cellulosic products is disclosed. An aqueous slurry of anionically dispersed kaolin particles is formed at 1 to 30% solids. A low-molecular-weight cationic aggregating agent is then added to the dispersed slurry to selectively aggregate fine and ultra-fine particles. The resultant aggregates are of larger mean particle size than the feed material and contain little or no fine and ultra-fine or colloidal particles. The net charge present on the aggregated particles is lower than that of the feed material. The aggregated structure contains within it a labyrinth of internal voids or pores. These mineral aggregates are then of a suitable size and surface charge to be retained well in a fiber web, and provide added bulk and opacity to the cellulosic products.
    Type: Grant
    Filed: December 29, 1995
    Date of Patent: October 14, 1997
    Assignee: Columbia River Carbonates
    Inventor: Alan J. Brown
  • Patent number: 5676747
    Abstract: A method for producing structured calcium carbonate pigments for coating paper is disclosed. An aqueous slurry of anionically dispersed calcium carbonate particles is formed at 1 to 30 percent solids. A low-molecular-weight cationically charged aggregating agent is then added to the slurry to selectively aggregate fine and ultra-fine particles. The resultant aggregates are of larger mean particle size than the mixture of particles in the original slurry and contain little or no fine and colloidal particles. The net charge present on the aggregated particles is lower than that of the original mineral particles. The low solids suspension of the aggregated mineral particles is then dewatered, or increased in solids to form a slurry with a solids content greater than 60 percent by weight.
    Type: Grant
    Filed: December 29, 1995
    Date of Patent: October 14, 1997
    Assignee: Columbia River Carbonates
    Inventor: Alan J. Brown
  • Patent number: 5676746
    Abstract: A process is provided for the selective aggregation of the fine and ultrafine particles present in an anionically or cationically dispersed mineral pigment slurry, such that an aggregated structure is formed which contains within it a labyrinth of internal voids or pores, which collectively function as light scattering centers. The aggregates are formed from an assemblage of fine mineral particles, interconnected or bonded together with small quantities of a cationic or anionic polymer or agent of low molecular weight. The resultant aggregates are of larger mean particle size than the feed material and contain little or no fine and colloidal particles. The net charge present on the aggregated particles is lower than that of the feed material. These mineral aggregates are then of a suitable size and surface charge to be retained well in a fiber web by a combination of filtration retention and adsorption retention, and provide added bulk and opacity to the finished sheet of paper.
    Type: Grant
    Filed: April 11, 1995
    Date of Patent: October 14, 1997
    Assignee: Columbia River Carbonates
    Inventor: Alan J. Brown
  • Patent number: 5653795
    Abstract: A method is disclosed for producing bulking and opacifying pigments for filling paper by the selective aggregation of fine particles in an anionically or cationically dispersed slurry, such that an aggregated structure is formed which contains within it a labyrinth of internal voids or pores. The aqueous slurry is formed at one to thirty percent solids. A low molecular weight agent of opposite ionic charge is then added to the slurry to selectively aggregate the fine particles present. The resultant aggregates are of larger mean particle size than the feed material and contain little or no fine and colloidal particles. The net charge present on the aggregated particles is lower than that of the feed material.
    Type: Grant
    Filed: November 16, 1995
    Date of Patent: August 5, 1997
    Assignee: Columbia River Carbonates
    Inventor: Alan J. Brown
  • Patent number: 5650003
    Abstract: A pigment composition containing titanium dioxide (TiO.sub.2) and calcined clay in a weight ratio of between about 30:70 and 70:30, preferably between about 35:65 and 45:55 that is substantially free of a functional microgel component has advantages over a similar pigment containing a functional microgel. The pigment composition contains an amount of epichlorohydrin dimethylamine condensate that is sufficient to cationize the pigment, and lacks a microgel component. It is liquid when agitated. Preferably the composition has a solids content greater than about 55%, and most preferably between about 59% and about 61%.
    Type: Grant
    Filed: December 18, 1995
    Date of Patent: July 22, 1997
    Assignee: Nord Naolin Company
    Inventors: Jerry Leon Curtis, Lester William House
  • Patent number: 5556641
    Abstract: A composition comprising colorant-containing particles having a coating comprising propylene glycol and a carrier component selected from the group consisting of carriers suitable for food, drug and cosmetic preparations and mixtures thereof.
    Type: Grant
    Filed: June 17, 1994
    Date of Patent: September 17, 1996
    Assignee: Whittaker, Clark & Daniels, Inc.
    Inventors: George C. Lambridis, Nathanial Goodwin
  • Patent number: 5505965
    Abstract: A composition comprising colorant-containing particles having a coating comprising propylene glycol and a carrier component selected from the group consisting of carriers suitable for food, drug and cosmetic preparations and mixtures thereof.
    Type: Grant
    Filed: December 6, 1994
    Date of Patent: April 9, 1996
    Assignee: Whittaker, Clark & Daniels, Inc.
    Inventors: George C. Lambridis, Nathanial Goodwin
  • Patent number: 5482640
    Abstract: Aqueous dispersions of PTFE and TiO.sub.2 stabilized from the effects of freeze/thaw cycles are disclosed, wherein the stabilizing agents are monohydric alcohols and monoamines having less than five carbon atoms.
    Type: Grant
    Filed: October 28, 1994
    Date of Patent: January 9, 1996
    Assignee: Consep, Inc.
    Inventor: Thomas H. Eberlein
  • Patent number: 5449403
    Abstract: A product in the form of colored inorganic particles including one or a number of melanin pigments, a process for its preparation and to its use, especially in the field of cosmetics, for make-up for the exoskeleton and/or for the skin, and in protecting human skin against UV radiation.
    Type: Grant
    Filed: January 3, 1994
    Date of Patent: September 12, 1995
    Assignee: L'Oreal
    Inventors: Herve Andrean, Alex Junino, Jean P. Arraudeau
  • Patent number: 5449774
    Abstract: The present invention provides a process for producing beta-form pigmentary copper phthalocyanine comprising a) producing crude copper phthalocyanine by charging phthalic anhydride or phthalimide, urea, a copper compound and a catalyst, at a substantially continuous and uniform rate, into a reaction chamber containing dry, granular, pre-formed copper phthalocyanine, and removing the reaction product from the reaction chamber; and b) convening the crude copper phthalocyanine produced in step a) into pigmentary form, by milling it either in the dry state or in an aqueous medium; mixing the milled material with an aqueous emulsion comprising i) a liquid C.sub.6 -C.sub.20 amine which is insoluble in water or alkali but is soluble in acid and ii) a surfactant capable of emulsifying the liquid amine; rendering the resulting mixture acidic to thereby dissolve the amine; and finally separating the desired pigmentary copper phthalocyanine from the treatment mixture.
    Type: Grant
    Filed: April 1, 1991
    Date of Patent: September 12, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Ian A. Lambie, Michael D. McFarlane, Robert Langley
  • Patent number: 5401313
    Abstract: This invention relates to modifying the surface of particles for improved dispersion characteristics in aqueous, solvent, resinous, polymeric, cementitious or the like application systems. In particular, this invention relates to a pigment or filler particle whose surface is coated with at least one electric charge modifying agent and at least one dispersion promoting agent, which has improved dispersibility, coloring, handling, and other processing properties in application systems. The electric charge modifying agent may be selected from the group of Mg, Ca, Ba, Sr, Ti, V, Zr, Cr, Mn, Fe, Co, Ni, Cu, Zn, and Al. The dispersion promoting agent may be selected from the group of stearates, acetates, alkylphenols, cellulosics, waxes, lignins, polyacrylics, polyepoxies, polyurethanes, polyethylenes, polystyrenes and polypropylenes, and polymers having functional groups of alcohols, glycols, aldehydes, amides and carboxylic acids. Iron oxide is the preferred pigment particle.
    Type: Grant
    Filed: February 10, 1993
    Date of Patent: March 28, 1995
    Assignee: Harcros Pigments, Inc.
    Inventors: William W. Supplee, James T. Will, Jr.
  • Patent number: 5380359
    Abstract: A melanin-coated pigment obtained by coating a carrier with a readily alkali-soluble natural melanin, and a cosmetic containing the pigment are provided. The melanin-coated pigment is highly safe and has high coloring and high saturation tone, and a cosmetic which contains it is also expected to have ultraviolet-ray-absorbing and anti-oxidizing effects.
    Type: Grant
    Filed: November 24, 1993
    Date of Patent: January 10, 1995
    Assignee: Kyowa Hakko Kogyo Co., Ltd.
    Inventors: Shinkichi Honda, Yoichiro Takekoshi, Yoichiro Arai
  • Patent number: 5376172
    Abstract: A process for preparing silane metal oxides comprising reacting a metal oxide with an amine compound to form an amine metal oxide intermediate, and subsequently reacting said intermediate with a halosilane.
    Type: Grant
    Filed: December 23, 1992
    Date of Patent: December 27, 1994
    Assignee: Xerox Corporation
    Inventors: Carl P. Tripp, Michael L. Hair, Richard P. N. Veregin
  • Patent number: 5336311
    Abstract: This invention relates to structural aggregate pigment products that are cationic, and have improved wet-end retention. A method for converting anionic pigments to cationic pigments is also provided. More particularly, a structural aggregate pigment comprising a clay and/or titanium dioxide or other particulate components, and a functional microgel made from silicon and aluminum or zinc gel formers and a gelling agent such as calcium chloride, can be cationized by adding an effective amount of modified or unmodified epichlorhydrin dimethylamine condensate to a slurry of the structured pigment. The resulting cationic pigments have superior papermaking characteristics and a much improved retention.
    Type: Grant
    Filed: July 7, 1992
    Date of Patent: August 9, 1994
    Assignee: Nord Kaolin Company
    Inventors: Jerry L. Curtis, Kenneth A. Johnson, Lester W. House
  • Patent number: 5279664
    Abstract: A method for dispersing a comminuted solid in an aqueous medium is described. An aqueous dispersing agent is added to an aqueous medium in an amount sufficient to disperse the comminuted solid in the aqueous medium. The aqueous dispersing agent includes from about 10 wt. % to about 55 wt. % of an amine compound selected from the group consisting of alkanolamines, triethylamine and morpholine, from about 15 wt. % to about 35 wt. % of a base selected from the group consisting of sodium hydroxide and potassium hydroxide, and from about 0.1 wt. % to about 15 wt. % chelating agent.
    Type: Grant
    Filed: December 17, 1991
    Date of Patent: January 18, 1994
    Assignee: Angus Chemical Company
    Inventors: Glenn N. Robinson, Gregory E. McWright
  • Patent number: 5169441
    Abstract: Fillers and pigments, such as clay, titanium dioxide, calcium carbonate, silicas, and silicoaluminates, can be rendered cationic by treating the fillers or pigments with the reaction product of a polyamine or polyamide and epichlorohydrin. The resulting water soluble cationic fillers or pigments are useful in the paper industry as fillers for paper and can also be utilized in coating paper.
    Type: Grant
    Filed: December 17, 1990
    Date of Patent: December 8, 1992
    Assignee: Hercules Incorporated
    Inventor: Rodrigue V. Lauzon
  • Patent number: 5076847
    Abstract: A new titanium chelate has been developed which introduces improvements into aqueous emulsion paints. The chelate is a reaction product of a titanium orthoester, a glycol or a glycol ether, an alkanolamine and an alpha-hydroxy carboxy acid.
    Type: Grant
    Filed: May 8, 1990
    Date of Patent: December 31, 1991
    Assignee: Tioxide Group PLC
    Inventors: Peter D. Kay, McDonald Keith
  • Patent number: 4985079
    Abstract: Disclosed is a medium set cationic bituminous emulsion comprising, relative to the emulsion:a. about 40 to 75% by weight asphalt;b. 0.25 to 5% by weight of a cationic emulsifier;c. 0.1 to 0.5% by weight of a nonionic water-soluble thickening agent;d. 0 to 8% of a low-boiling hydrocarbon; ande. water as a continuous phase of said emulsion to make up 100% by weight;wherein said medium set emulsion when combined with open-graded aggregate produces a mix which has a thick coating of emulsion on said aggregate surface and said mix is workable and results in minimum runoff.
    Type: Grant
    Filed: April 5, 1989
    Date of Patent: January 15, 1991
    Assignee: Chevron Research Company
    Inventors: Peter E. Graf, Steven J. Agazzi, Eugene J. Vanderzanden
  • Patent number: 4978747
    Abstract: Colorants are obtained by reacting a dyestuff which is free from ionic groups and has.gtoreq.2 NH.sub.2 groups which are preferably arranged in such a manner that they do not participate in the resonance of the chromophore with such an amount of a (cyclo)aliphatic diisocyante so as to form an adduct that still contains at least two free NCO groups, and subsequently reacting this adduct with a (cyclo)aliphatic diamine, to form an adduct suitable for dyeing and pigmenting macromolecular substances, in particular for coloring PUR-based paints, coatings and laminates.
    Type: Grant
    Filed: April 13, 1989
    Date of Patent: December 18, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl-Arnold Weber, Hermann Henk, Klaus Kunde, Jochen Westphal, Klaus Wunderlich
  • Patent number: 4935063
    Abstract: Stabilizing inorganic fillers or pigments having simultaneous reinforcing effect and stabilizing effect on organic polymers are obtained by a process comprising the following stages:(a) bringing the inorganic filler or pigment into contact with a solution, in an inert organic solvent, of a sterically hindered amine comprising one or more alkoxysilane groups in its molecule;(b) maintaining the obtained mixture at higher than ambient temperature (20.degree.-25.degree. C.) for a period of at least 0.5 hours;(c) removing the solvent, treating at a temperature of 120.degree.-200.degree. C. and recovering the stabilizing filler or pigment obtained.
    Type: Grant
    Filed: September 9, 1988
    Date of Patent: June 19, 1990
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Silvestro Costanzi, Omero Zavattini, deceased, Ugo Bersellini, Damiano Gussoni
  • Patent number: 4935502
    Abstract: When a diamine of the formula ##STR1## in which n is 1 to 4, is bis-diazotized and the resulting bis-diazo compound is coupled with 2 moles of one or more coupling components of the formula ##STR2## in which R.sup.1 is hydrogen, chlorine, bromine, methyl or methoxy and R.sup.2 is hydrogen or, if R.sup.1 is hydrogen, also methyl or ethyl, disazo compounds are obtained which are colorants. Due to their high fastness to light and to migration and their heat stability and dispersibility, these compounds are useful for pigmenting high molecular weight materials, especially polyolefins.
    Type: Grant
    Filed: August 22, 1989
    Date of Patent: June 19, 1990
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Rudolf Kuhne, Heinrich Hamal
  • Patent number: 4909852
    Abstract: This invention is concerned with the treatment of particulate titanium dioxide and other pigments with a surfactant compound which serves to enhance its employment in pigmented and/or filled paints and plastics, paper making compositions and in reinforced plastic composite compositions.
    Type: Grant
    Filed: April 29, 1988
    Date of Patent: March 20, 1990
    Inventor: George K. Atkinson
  • Patent number: 4870164
    Abstract: Symmetrical and asymmetrical disazo compounds of the formula: ##STR1## wherein: the R.sup.1 's are identical or different and are hydrogen, chlorine, bromine, methyl or methoxy;the R.sup.2 's are hydrogen, or, if the R.sup.1 's are hydrogen, the R.sup.2 's are hydrogen, methyl or ethyl, the two R.sup.2 radicals being identical or different; andn is 1 to 4and mixtures of such compounds as colorants, especially for pigmenting high molecular weight organic material.
    Type: Grant
    Filed: January 28, 1985
    Date of Patent: September 26, 1989
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Rudolf Kuhne, Heinrich Hamal
  • Patent number: 4844742
    Abstract: Surface modification of a variety of pigments, particularly quinacridone pigments, and the pigments resulting therefrom whereby the pigment is treated with a solvent-free, basic, nitrogen-containing copolymer of the polyurethane series and with a dispersion-improving derivative of the primary pigment resulting in compositions exhibiting enhanced performance in automative and other finish systems.
    Type: Grant
    Filed: May 15, 1987
    Date of Patent: July 4, 1989
    Assignee: Ciba-Geigy Corporation
    Inventor: Edward E. Jaffe
  • Patent number: 4822427
    Abstract: Disclosed is a cationic bituminous emulsion comprising relative to the emulsion about 40 to 70% by weight asphalt, 0.25 to 5% by weight of a cationic emulsifier, 0.1-0.5% by weight of a water-soluble thickening agent, 0-8% of a low-boiling hydrocarbon, and water as a continuous phase of said emulsion to make up 100% by weight. The emulsion is particularly useful for open-graded roads.
    Type: Grant
    Filed: October 31, 1986
    Date of Patent: April 18, 1989
    Assignee: Chevron Research Company
    Inventors: Peter E. Graf, Steven J. Agazzi, Eugene J. Vanderzanden