Antimony Containing (sb) Patents (Class 106/455)
  • Patent number: 5672201
    Abstract: A process for preparing a structured composite pigmentary material comprises forming a dispersion of uncoated particles of titanium dioxide at a pH value at which the particles have a surface charge and subjecting the dispersion to cross-flow filtration until the dispersion contains more than 50% by weight titanium dioxide. The concentrated dispersion is mixed with a dispersion of chemically distinct particles having a surface charge of opposite sign under conditions which ensure that the sign of the surface charge on either of the particulate materials is not reversed. In the resultant composite pigmentary material the titanium dioxide particles are held in association with the chemically distinct particles as a result of said surface charges.
    Type: Grant
    Filed: March 5, 1996
    Date of Patent: September 30, 1997
    Assignee: Tioxide Group Services Limited
    Inventors: Leslie Ainsley Simpson, Keith Robson, David Trevor Knight, Ronald Brown
  • Patent number: 5569413
    Abstract: A process for producing crystallites comprising silica and antimony containing tin oxide. The quantity of antimony within the tin oxide can be reduced, thereby permitting production a powder which is absent a blue coloration.
    Type: Grant
    Filed: February 3, 1995
    Date of Patent: October 29, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Howard W. Jacobson
  • Patent number: 5554215
    Abstract: A composite particulate pigmentary material is disclosed which comprises an association of at least two chemically distinct materials in which the particles of one material carry a positive surface charge and the particles of the second material carry a negative surface charge and particles are held in association as a result of these surface charges. Also disclosed is a method for preparing composite particulate pigmentary material comprising forming aqueous dispersions of two particulate materials under conditions in which the surface charges of the particles of the two materials are of different signs and mixing the dispersions. Typical materials useful for preparing the composite include inorganic pigments, fillers and extenders and organic polymeric microspheres. The product is useful as a pigment in, for example, paints, inks, paper and plastics.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: September 10, 1996
    Assignee: Tioxide Specialties Limited
    Inventors: Leslie A. Simpson, John Robb, Jonathan Banford, Paul F. Dietz, John Temperley
  • Patent number: 5534056
    Abstract: Radiation-absorptive materials, suitable for fabrication into packages, sheets, inks, paints, decorative surface treatments, lotions, creams, and gels are disclosed. The materials exploit certain optical properties associated with uniform, spherical, nanosize particles to provide complete radiation absorption, over a selected bandwidth, at low concentration. One type of particle exhibits an "absorption edge" at a chosen wavelength, transmitting radiation whose wavelength exceeds the characteristic bandgap wavelength, while effectively absorbing all radiation with wavelengths smaller than that minimum. Another type of particle exhibits "optical resonance," which causes radiation of a characteristic wavelength to interact with the particles so as to produce self-reinforcing internal reflections that strongly enhance the amplitude of the radiation trapped within the particle.
    Type: Grant
    Filed: October 28, 1993
    Date of Patent: July 9, 1996
    Assignee: Manfred R. Kuehnle
    Inventors: Manfred R. Kuehnle, Hermann Statz
  • Patent number: 5527386
    Abstract: Radiation-absorptive materials, suitable for fabrication into packages, sheets, inks, paints, decorative surface treatments, lotions, creams, and gels are disclosed. The materials exploit certain optical properties associated with uniform, spherical, nanosize particles to provide complete radiation absorption, over a selected bandwidth, at low concentration. One type of particle exhibits an "absorption edge" at a chosen wavelength, transmitting radiation whose wavelength exceeds the characteristic bandgap wavelength, while effectively absorbing all radiation with wavelengths smaller than that minimum. Another type of particle exhibits "optical resonance," which causes radiation of a characteristic wavelength to interact with the particles so as to produce self-reinforcing internal reflections that strongly enhance the amplitude of the radiation trapped within the particle.
    Type: Grant
    Filed: November 18, 1994
    Date of Patent: June 18, 1996
    Assignee: Manfred R. Kuehnle
    Inventor: Hermann Statz
  • Patent number: 5501724
    Abstract: A coating composition for the attenuation of the reflection electromagnetic radiation and particularly electromagnetic radiation have a wavelength of greater than 800 nm including the near infrared is described. The composition comprises a chromophore capable of absorbing up to about 95% of the electromagnetic radiation having a wavelength greater than 800 nm. Optionally, the composition may comprise microbeads that serve the purpose of also scattering the electromagnetic radiation.
    Type: Grant
    Filed: June 16, 1994
    Date of Patent: March 26, 1996
    Inventor: Howard Loff
  • Patent number: 5500043
    Abstract: The object of the present invention is to provide a lustrous pigment free from the defects of conventional platelike or flaky iron oxide pigments that a mechanical strength is poor, adjustable colors are restricted and that a pigment lustrous is weak even if colors can adjusted variously and a method of producing the same. The present invention relates to a flaky iron oxide lustrous pigment having a hematite structure characterized by containing at least one of the elements selected from Zn, Sb and Sn and Al in solid solution and its platelike crystal having an average thickness of 0.8 .mu.m or more, preferably the content of at least one of the elements selected from Zn, Sb and Sn being in the range of 0.05 to 0.5 weight % as oxides and the content of Al being in the range of 0.5 to 3 weight % as Al.sub.2 O.sub.3.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 19, 1996
    Assignee: Titan Kogyo Kabushiki Kaisha
    Inventors: Hidefumi Harada, Takanori Yamasaki, Eizi Sadanaga, Teruyoshi Okazaki
  • Patent number: 5476613
    Abstract: A process for producing crystallites comprising silica and antimony containing tin oxide. The quantity of antimony within the tin oxide can be reduced, thereby permitting production a powder which is absent a blue coloration.
    Type: Grant
    Filed: March 25, 1994
    Date of Patent: December 19, 1995
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Howard W. Jacobson
  • Patent number: 5376307
    Abstract: A coating composition of a perfluorocarbon resin and an electroconductive double shell pigment comprising inner shells of amorphous silica or a silica-containing material and outer shells of antimony-containing tin oxide is useful on a copy roller or belt.
    Type: Grant
    Filed: September 3, 1993
    Date of Patent: December 27, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Minori Hagiwara, Kenji Kiwa, Laurence W. McKeen
  • Patent number: 5366545
    Abstract: A coating composition comprising an organosilicon compound and modified stannic oxide - zirconium oxide composite colloidal particles which are obtained by partially or fully coating the surface of stannic oxide - zirconium oxide composite colloidal particles with tungstic oxide - stannic oxide composite colloidal particles. The formed cured coating film is excellent in hot water resistance, and light-resistance and weathering resistance are not impaired even when the antireflection film made by vepor deposition of inorganic oxides is applied on the cured coating film.
    Type: Grant
    Filed: July 7, 1993
    Date of Patent: November 22, 1994
    Assignees: Hoya Corporation, Nissan Chemical Industries, Ltd.
    Inventors: Eiichi Yajima, Yoshitane Watanabe, Keitaro Suzuki, Tetsunori Matsukura
  • Patent number: 5364566
    Abstract: A method for preparing a substantially white electroconductive powders by applying a surface coating comprising a two-dimensional network of antimony-containing tin oxide to amorphous silica or silica coated particles.
    Type: Grant
    Filed: February 12, 1993
    Date of Patent: November 15, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Howard W. Jacobson
  • Patent number: 5358560
    Abstract: Solid form additive systems which are dispersible in aqueous media are disclosed, as are methods for preparing such additive systems. The additive systems are dry, free-flowing particulate materials that contain at least one additive component, at least one tackifying agent, and at least one surfactant.
    Type: Grant
    Filed: October 4, 1991
    Date of Patent: October 25, 1994
    Assignee: Eastman Chemical Company
    Inventors: Brenda J. Hitch, Mahendra K. Sharma, Leo P. Voetgli
  • Patent number: 5336312
    Abstract: This invention relates to colorants represented by the formulaBi.sub.2 A.sub.x-1 D.sub.x O.sub.ywherein: A is selected from the group consisting of Bi, Ba, Sr, Ca, Y, La, or a mixture of two or more thereof; D is selected from the group consisting of V, Mo, Mn, Ti, Ta, Nb, W, Sb, Fe, Cr, Sn, Ce, or a mixture of two or more thereof; x is a number that is at least 1; and y is the number of oxygens needed to fulfill the valence requirements of Bi, A and D; with the proviso that when A is Bi, D is other than a mixture consisting of V and Mo. These colorants are useful in providing colored compositions including: organic compositions such as plastics, rubbers, and the like; inorganic compositions such as ceramics, porcelain enamels, and the like; and coating compositions such as paints, printing inks, and the like; etc. The invention also provides for processes for making such colorants and for making such colored compositions. The invention also provides for such colorants in the form of particulate solids (e.g.
    Type: Grant
    Filed: May 10, 1993
    Date of Patent: August 9, 1994
    Assignee: Ferro Corporation
    Inventors: Christine J. Byrne, Robert P. Blonski, John J. Welch
  • Patent number: 5320781
    Abstract: There is disclosed an electrically conductive pigment containing 20 to 95% by weight of a component A comprising one or more conductive platelet-like pigments and 5 to 80% by weight of a component B comprising one or more conductive needle-shaped or fibrous pigments.
    Type: Grant
    Filed: April 16, 1993
    Date of Patent: June 14, 1994
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Otto Stahlecker, Manfred Thon, Ralf Glausch, Gerhard Pfaff, Manfred Kieser, Wilhelm Gobel
  • Patent number: 5308394
    Abstract: Disclosed are a pigment including a light-transparent ceramic scaly substrate, a tin compound layer coated on a surface of the substrate in an amount of 0.6 to 0.75% by weight with respect to the substrate, the amount being converted into metallic tin, a rutile type titanium dioxide layer formed on a surface of the substrate coated with the tin compound, a metal compound layer coated on a surface of the titanium dioxide layer in an amount of 0.15 to 0.6% by weight with respect to the substrate, metal of the metal compound being at least one selected from the group consisting of Bi, Sb, As, Cd, Zn, Mn, Pb and Cr, and the amount being converted into metal, and metallic glossy dots formed on the surfaces in a scattering manner, the metallic glossy dots occupying 0.05 to 95% of a total surface area of the surfaces, and a process for producing the same.
    Type: Grant
    Filed: August 20, 1992
    Date of Patent: May 3, 1994
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Taketoshi Minohara, Hiroshi Ito, Junichi Handa, Yuji Tanaka
  • Patent number: 5296168
    Abstract: An electroconductive powder composition of antimony-containing tin oxide with an outer layer of hydrous metal oxide having an isoelectric point in the range from about 5 to 9.
    Type: Grant
    Filed: December 19, 1990
    Date of Patent: March 22, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Howard W. Jacobson
  • Patent number: 5248337
    Abstract: A stable lead chromate pigment composition comprising a lead chromate pigment which has been treated by forming a continuous amorphous silica encapsulation on the surface of each particle of the pigment and subsequently depositing an antimony compound on the silica encapsulation and the process for producing the same.
    Type: Grant
    Filed: April 10, 1991
    Date of Patent: September 28, 1993
    Assignee: Toho Ganryo Kogyo Co., Ltd.
    Inventors: Hiroyuki Matsubara, Takashi Shigematsu, Kazuo Konno, Minoru Yokoyama
  • Patent number: 5190583
    Abstract: An aqueous coating composition is provided which reflects light, especially UV radiation, and can be colored as desired. It is prepared from a synthetic resin dispersion and inorganic pigments having a particle size ranging between 7 and 10 nm, with the exception of carbon black.
    Type: Grant
    Filed: June 24, 1992
    Date of Patent: March 2, 1993
    Assignee: Transfer-Electric Gesellschaft Fur
    Inventors: Tankred Menzel, Hermann Nickel
  • Patent number: 5190586
    Abstract: Disclosed are pigment composite particles which are superior in water resistance, weather resistance, thermal stability and hardness. The pigment composite particles are prepared by suspension-polymerizing an aqueous suspension comprising(a) a pigment paste comprising pigment and a pigment grinding resin having a hydrophilic group of at least 0.2 mmol/g,(b) a polymerizable monomer and(c) a polymerization initiator.
    Type: Grant
    Filed: November 28, 1990
    Date of Patent: March 2, 1993
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Katsumi Mizuguchi, Masanori Ohiwa, Keizou Ishii, Shinichi Ishikura
  • Patent number: 5188667
    Abstract: An aqueous sol of colloidal particles of tungstic oxide (WO.sub.3)-stannic oxide (SnO.sub.2) composite having a particle size of from 2 to 7 millimicrons is prepared by blending an aqueous solution of tungstic acid and an aqueous solution of an stannate in a weight ratio of from 0.5 to 100 as WO.sub.3 /SnO.sub.2. Where the WO.sub.3 -SnO.sub.2 composite sol in an amount of from 2 to 100 parts by weight as the total of WO.sub.3 and SnO.sub.2 is blended with a sol of a 3- to 5 valent metal oxide having a particle size of from 4 to 50 millimicrons in an amount of 100 parts by weight as the metal oxide, a modified metal oxide sol of colloidal particles having a size of 4.5 to 60 millimicrons as surface-coated with the tungstic oxide (WO.sub.3)-stannic oxide (SnO.sub.5) composite colloidal particles is prepared.
    Type: Grant
    Filed: November 21, 1991
    Date of Patent: February 23, 1993
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Yoshitane Watanabe, Keitaro Suzuki
  • Patent number: 5164005
    Abstract: A black manganese/iron oxide pigment having a spinel structure and having the composition Mn.sub.x Fe.sub.3-x O.sub.4 wherein x has a value from 0.1 to 0.9, is prepared by the steps:a) oxidizing iron(II) salts or mixtures of iron(II) salts and manganese(II) salts, in solution or after reaction with alkaline precipitants, with manganese dioxide or other compounds containing manganese in high valency,b) additionally oxidizing the salts of (a) to establish an Fe(III) content therein with another oxidizing agent, andc) filtering, washing, drying and grinding the pigment;and the pigment is useful for pigmenting building materials to a black color.
    Type: Grant
    Filed: March 18, 1992
    Date of Patent: November 17, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Kuske, Gunter Buxbaum
  • Patent number: 5160374
    Abstract: A semi-insulating coating or surface layer is applied over insulating materials such as a circuit board or wiring harness or feedthrough insulator. The paint is electrically fixed to ground and as a result leaks away charge buildup before large pulse discharges occur. For example, pure tin oxide particles in phenoxy resin binder forms a paintable application for the invention.
    Type: Grant
    Filed: July 24, 1990
    Date of Patent: November 3, 1992
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Arthur R. Frederickson, Joseph E. Nanevicz, Jeffrey S. Thayer, Dean B. Parkinson
  • Patent number: 5094691
    Abstract: An aqueous sol of colloidal particles of tungstic oxide (WO.sub.3)-stannic oxide (SnO.sub.2) composite having a particle size of from 2 to 7 millimicrons is prepared by blending an aqueous solution of tungstic acid and an aqueous solution of a stannate in a weight ratio of from 0.5 to 100 as WO.sub.3 /SnO.sub.2. Where the WO.sub.3 --SnO.sub.2 composite sol in an amount of from 2 to 100 parts by weight as the total of WO.sub.3 and SnO.sub.2 is blended with a sol of a 3- to 5 valent metal oxide having a particle size of from 4 to 50 millimicrons in an amount of 100 parts by weight as the metal oxide, a modified metal oxide sol collidal particles having a size of 4.5 to 60 millimicrons as surface-coated with the tungstic oxide (WO.sub.3)-stannic oxide (SnO.sub.5) composite colloidal particles is prepared.
    Type: Grant
    Filed: October 30, 1990
    Date of Patent: March 10, 1992
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Yoshitane Watanabe, Keitaro Suzuki
  • Patent number: 5021091
    Abstract: A hard coating composition comprising an organic silicon compound and inorganic submicron particles such as silica sol and antimony oxide sol is improved in curing properties and shelf stability by blending aluminum perchlorate as the curing catalyst.
    Type: Grant
    Filed: January 16, 1990
    Date of Patent: June 4, 1991
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Mitsuhiko Takarada, Kazuharu Sato, Kenji Yamamoto, Shigeru Mori
  • Patent number: 5007963
    Abstract: A process for the preparation of lead molybdate pigments containing lead chromate, lead sulfate and lead molybdate, which comprises preparing the lead molybdate pigments by reacting an aqueous solution of a lead salt with an aqueous solution containing chromate, molybdate and sulfate salts or with an aqueous solution of each of said salts using 2 to 5 mol % of lead molybdate seed crystals, based on the total molar amount of lead chromate, lead sulfate and lead molybdate. The lead molybdate pigments so obtained are strong and are highly suitable for coloring organic materials of high molecular weight.
    Type: Grant
    Filed: October 17, 1988
    Date of Patent: April 16, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Leonardus J. H. Erkens, Gerben P. Algra, Herman J. J. M. Geurts, Hubertus P. A. Gielkens
  • Patent number: 5008036
    Abstract: A colloidal dispersion of hydrous antimony pentoxide particles is made by a process which comprises introducing a particulate antimony component selected from the group consisting of antimony metal and antimony trioxide into an essentially aqueous medium and contacting said antimony component with hydrogen peroxide at a temperature of from about 0.degree. C. to about the decomposition temperature of the reaction mixture for a length of time sufficient to convert at least a portion of the antimony component to colloidal particles of hydrous antimony pentoxide.
    Type: Grant
    Filed: August 18, 1975
    Date of Patent: April 16, 1991
    Assignee: Laurel Industries, Inc.
    Inventors: Charles E. Crompton, Abdulla M. Z. Kazi, Inderjit S. Soni
  • Patent number: 4990473
    Abstract: Zirconyl phosphate ceramics having high strength and high heat shock resistance, which consist essentially of at least 99% by weight of zirconyl phosphate, zirconium phosphates or both and no other phase material in quantities of more than 1% by weight are useful in ceramic filters and ceramic internal combustion engine parts and are prepared by mixing zirconyl phosphate or substances which form zirconyl phosphate with an antimony compound, moulding the resulting mixture and then sintering the moulded mixture at temperatures of 1200.degree. to 1700.degree. C.
    Type: Grant
    Filed: June 12, 1989
    Date of Patent: February 5, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ernst Gugel, Isfried Petzenhauser
  • Patent number: 4844741
    Abstract: Thermostable rutile mixed phase pigments of the ternary system titanium, antimony and chromium contain from 0.1 to 2.0% by weight of magnesium.
    Type: Grant
    Filed: April 20, 1988
    Date of Patent: July 4, 1989
    Assignee: Lacke & Farben Aktiengesellschaft
    Inventors: Helmut Knittel, Roland Bauer, Egon Liedek, Guenter Etzrodt