Treatment Of Alkali Silicate With Mineral Acid Or Product Patents (Class 106/492)
  • Patent number: 11285088
    Abstract: Silica particles having a d50 median particle size of at least 6 ?m, a ratio of (d90?d10)/d50 from 1.1 to 2.4, a RDA at 20 wt. % loading from 40 to 200, and a sphericity factor (S80) of at least 0.9, are disclosed, as well as methods for making these silica particles, and dentifrice compositions containing the silica particles.
    Type: Grant
    Filed: August 28, 2018
    Date of Patent: March 29, 2022
    Assignee: Evonik Operations GmbH
    Inventors: William J. Hagar, Terry W. Nassivera, Karl W. Gallis
  • Patent number: 11241370
    Abstract: The invention relates to a novel method of preparing silicas and to highly-structured silicas having the following characteristics: a specific surface area CTAB (SCTAB) of between 40 and 525 m2/g; a specific surface area BET (SBET) of between 45 and 550 m2/g; an object size distribution width Ld ((d84?D16)/d50), which is measured by XDC particle size analysis after deagglomeration with ultrasound, of at least 0.91; and a pore-size distribution such that ratio V(d5?d50)/V(d5?d100) is at least 0.66. The invention also relates to the use of said silicas as polymer reinforcing fillers.
    Type: Grant
    Filed: June 22, 2011
    Date of Patent: February 8, 2022
    Assignee: RHODIA CHIMIE
    Inventors: Rémi Valero, Julien Hernandez
  • Patent number: 9708770
    Abstract: Paper, paperboard, or label stock coated with a synthetic nano-composite coating. A synthetic nano-composite coating includes a first component including a fibrous structured amorphous silica structure, and a second component including a precipitated calcium carbonate structure developed by pressure carbonation.
    Type: Grant
    Filed: November 14, 2016
    Date of Patent: July 18, 2017
    Assignee: PACIFIC NANO PRODUCTS, INC.
    Inventor: Vijay K Mathur
  • Patent number: 9637864
    Abstract: A nano-composite structure. A synthetic nano-composite is described having a first component including a fibrous structured amorphous silica structure, and a second component including a precipitated calcium carbonate structure developed by pressure carbonation. The nano-composite may be useful for fillers in paints and coatings. Also, the nano-composite may be useful in coatings used in the manufacture of paper products.
    Type: Grant
    Filed: April 26, 2014
    Date of Patent: May 2, 2017
    Assignee: PACIFIC NANO PRODUCTS, INC.
    Inventor: Vijay K. Mathur
  • Patent number: 9617162
    Abstract: Disclosed herein is a continuous process for preparing a silica product, comprising: (a) continuously feeding an acidulating agent and an alkali metal silicate into a loop reaction zone comprising a stream of liquid medium; wherein at least a portion of the acidulating agent and the alkali metal silicate react to form a silica product in the liquid medium of the loop reaction zone; (b) continuously recirculating the liquid medium through the loop reaction zone; and (c) continuously discharging from the loop reaction zone a portion of the liquid medium comprising the silica product. Silica products and dentifrice compositions comprising the silica products are also disclosed. A continuous loop reactor is also disclosed.
    Type: Grant
    Filed: April 4, 2016
    Date of Patent: April 11, 2017
    Assignee: J.M. Huber Corporation
    Inventors: William J. Hagar, Karl W. Gallis
  • Patent number: 9580867
    Abstract: A nano-composite structure. A synthetic nano-composite is described having a first component including a fibrous structured amorphous silica structure, and a second component including a precipitated calcium carbonate structure developed by pressure carbonation. The nano-composite may be useful for fillers in paints and coatings. Also, the nano-composite may be useful in coatings used in the manufacture of paper products.
    Type: Grant
    Filed: April 26, 2014
    Date of Patent: February 28, 2017
    Assignee: PACIFIC NANO PRODUCTS, INC.
    Inventor: Vijay K. Mathur
  • Patent number: 9346031
    Abstract: A sodium-nanoliquid reactivity experiment apparatus includes: a storage tank that stores liquid sodium; a mixing tank that is connected to the storage tank through a first transport line to receive supply of the liquid sodium and that injects nanoparticles to mix the nanoparticles with the liquid sodium; and a reactor that is connected to the mixing tank through a second transport line to receive supply of a sodium-nanoparticle mixture and that injects water to react the water with the sodium-nanoparticle mixture.
    Type: Grant
    Filed: March 20, 2012
    Date of Patent: May 24, 2016
    Assignee: POSTECH ACADEMY-INDUSTRY FOUNDATION
    Inventors: Moo Hwan Kim, Ho Seon Ahn, Gunyeop Park, Soojae Kim
  • Patent number: 9028957
    Abstract: Embodiments of the present disclosure relate to the preparation of colloidal dispersions or suspensions of inorganic materials with nano-sized and nano-structured morphologies, preferably the nanosheet form, compositions produced by this method, and the like.
    Type: Grant
    Filed: September 12, 2013
    Date of Patent: May 12, 2015
    Assignee: University of Georgia Research Foundation, Inc.
    Inventors: Tina T. Salguero, Darrah Johnson-McDaniel, Christopher A. Barrett
  • Patent number: 8268921
    Abstract: The instant invention relates to elastomeric compositions especially useful for manufacturing articles for tires which comprise: (1) at least one butadienic elastomer E, containing a functionalized butadienic elastomer prepared in solution, and modified by a polyfunctional alkoxy silane coupling agent; and (2) a specific precipitated silica having high dispersibility properties and containing aluminum, as at least one reinforcing filler in said butadienic elastomer.
    Type: Grant
    Filed: December 22, 2005
    Date of Patent: September 18, 2012
    Assignees: Rhodia Chimie, JSR Corporation
    Inventors: Philippe Cochet, Dominique Petit, Toshihiro Tadaki, Naokazu Kobayashi
  • Patent number: 7390358
    Abstract: A method for preparing a modified kaolin clay, includes the steps of providing a kaolin clay material having a starting ratio of silica to alumina; mixing the kaolin clay material with acid so as to form a substantially homogenous paste; calcining the paste so as to provide a calcined acid-treated clay material; mixing the calcined acid-treated clay material in water so as to form a suspension; precipitating aluminum from the suspension so as to produce a reduced aluminum suspension; and obtaining a modified clay material from the reduced aluminum suspension, wherein the modified clay material has a final ratio of silica to alumina which is higher than the starting ratio.
    Type: Grant
    Filed: April 29, 2005
    Date of Patent: June 24, 2008
    Assignee: Intevep, S.A.
    Inventors: Andres M. Quesada Perez, Gerardo Vitale-Rojas
  • Patent number: 7335342
    Abstract: In the present invention a process for the preparation of sodium silicate from Kimberlite tailing generated as solid waste during diamond mining is disclosed. The process comprises, reacting Kimberlite tailing with mineral acid to remove acid soluble impurities followed by digesting acid treated Kimberlite tailing with alkali solution in a open or closed system to obtain sodium silicate useful for commercial applications.
    Type: Grant
    Filed: March 14, 2006
    Date of Patent: February 26, 2008
    Assignee: Council of Scientific and Industrial Research
    Inventors: Raksh Vir Jasra, Hari Chand Bajaj, Rajesh Shantilal Somani, Haresh Mahipatlal Mody, Jatin Rameshchandra Chunawala, Devendra Lalijibhai Ghelani, Hemal Narendrakumar Ranpara, Dipti Jivanbhai Barochiya, Suresh Chandra, Maharaj Kishan Dhar, C. Kesava Rao, Kamlesh Kumar
  • Patent number: 7125432
    Abstract: New methods of producing narrower particle size distribution precipitated silica and/or silicate materials are provided. Such a method permits a significant reduction in manufacturing costs through the utilization of more efficient drying/evaporation components, in essence, in one potentially preferred embodiment, production of such silica and/or silicate materials followed directly by a hydraulic chamber press filtering step combined with vacuum dewatering subsequently leading to the needed resultant particle comminution. The resultant precipitated silicas and/or silicates produced thereby exhibit greater density prior to comminution and thus greater propensity for more uniform milling than previously utilized and prevalent spray/flash drying apparatuses.
    Type: Grant
    Filed: July 23, 2004
    Date of Patent: October 24, 2006
    Assignee: J.M. Huber Corporation
    Inventor: Yung-Hui Huang
  • Patent number: 7037476
    Abstract: A new process is described for the preparation of free flowing hydrated amorphous silica from kimberlite tailing—a waste in diamond mining. The process comprises treating of kimberlite with acid, further reacting it with alkali solution to obtain soluble metal silicate solution, which is subsequently neutralized with mineral acid to polymerize silica as insoluble precipitates. The products is useful in rubber, paints as abrasive etc.
    Type: Grant
    Filed: December 27, 2004
    Date of Patent: May 2, 2006
    Assignees: Council of Scientific and Industrial Research, National Mineral Development Corporation Limited
    Inventors: Raksh Vir Jasra, Haresh Mahipatlal Mody, Hari Chand Bajaj, Rajesh Shantilal Somani, Jatin Rameshchandra Chunawala, Hemal Ranpara, Dipti Barochiya, Devendra Ghelani, Suresh Chandra, Maharaj Kishen Dhar, Keshav Rao, Kamlesh Kumar
  • Patent number: 6719881
    Abstract: A microparticle system for use as a retention and drainage aid in the production of alkaline and acid paper products comprises a HMW flocculent polymer (6), an acid colloid (7), and a coagulant or a MMW flooculant (5). The acid colloid (7) comprises an aqueous solution of a water soluble polymer or copolymer of melamine aldehyde, preferably melamine formaldehyde, and is present in an amount ranging between 0.0005% to 0.5% by weight based on the dry weight of the solids in the furnish. The HMW flocculant polymer (6) may be added to stock or furnish after the fan pump; and prior to the pressure screen (2); the acid colloid (7) may be added to the stock after the pressure screen (2), and the coagulant/MMW flocculant (5) may be added prior to the fan pump (1). Alternatively, this sequence of chemical additions can be changed, i.e. the acid colloid (7) can be added prior to or after the fan pump (1) or prior to the pressure screen (2).
    Type: Grant
    Filed: July 5, 2001
    Date of Patent: April 13, 2004
    Inventors: Charles R. Hunter, Craig W. Vaughan
  • Patent number: 6702888
    Abstract: The invention relates to a new process for the preparation of precipitated silica which has an excellent dispersibility and very satisfactory reinforcing properties. It also relates to new precipitated silicas which are in the form of powder, of substantially spherical beads or of granules, these silicas being characterized by the fact that they have a CTAB specific surface of between 140 and 200 m2/g, a BET specific surface of between 140 and 200 m2/g, a DOP oil uptake lower than 300 ml/100 g, a median diameter, after disintegration with ultrasound, smaller than 3 &mgr;m, an ultrasonic disintegration factor higher than 10 ml and an aluminum content of at least 0.35% by weight. The invention also relates to the use of the said silicas as reinforcing fillers for elastomers.
    Type: Grant
    Filed: June 26, 2002
    Date of Patent: March 9, 2004
    Assignee: Rhodia Chimie
    Inventors: Yves Bomal, Yvonick Chevallier, Philippe Cochet
  • Patent number: 6673738
    Abstract: A photocatalytic active carbon capable of demonstrating a stable deodorizing and adsorbing ability for a prolonged period of time is produced by depositing a coating of a photocatalyst on the surface of the active carbon by means of vapor deposition. Colored photocatalytic active carbon coloring active carbon including the photocatalytic active carbon, which while maintaining the adsorbing action and the decomposing and sterilizing action, comes to be rich in color variations and capable of improving visual design and handling are produced by subjecting the surface of the active carbon to coloring treatment and/or treatment with a compound having coloring or discoloring properties upon hydration.
    Type: Grant
    Filed: April 3, 2002
    Date of Patent: January 6, 2004
    Assignee: K.K. Ueda Shikimono Kojyo
    Inventors: Toshiya Ueda, Motoyoshi Nishimura
  • Patent number: 6638354
    Abstract: Disclosed are amorphous precipitated silicas, silica gels, and amorphous carbons derived from biomass and methods of producing them with and without adhered or deposited amorphous carbons produced by acidifying a caustic silicate solution produced by caustic digestion of biomass ash containing silica with and without activated carbon, the ash being obtained from thermal pyrolysis of the biomass, the acidifying effective to produce a slurry of the precipitated silica and silica gels with and without adhered or deposited amorphous carbon, and separated from the slurry the precipitated silicas and silica gels with and without the adhered or deposited amorphous carbons. The properties of the precipitated silica with adhered or deposited carbon being within the range as utilized in rubber compositions thereby avoiding the blending of silica and carbon components for such use.
    Type: Grant
    Filed: January 30, 2002
    Date of Patent: October 28, 2003
    Assignees: Agritec, Inc., Occidental Chemical Corporation
    Inventors: Douglas K. Stephens, Clyde W. Wellen, Jeffrey B. Smith, Kenneth F. Kubiak
  • Publication number: 20030066459
    Abstract: The invention relates to a new process for the preparation of precipitated silica which has an excellent dispersibility and very satisfactory reinforcing properties. It also relates to new precipitated silicas which are in the form of powder, of substantially spherical beads or of granules, these silicas being characterized by the fact that they have a CTAB specific surface of between 140 and 200 m2/g, a BET specific surface of between 140 and 200 m2/g, a DOP oil uptake lower than 300 ml/100 g, a median diameter, after disintegration with ultrasound, smaller than 3 &mgr;m, an ultrasonic disintegration factor higher than 10 ml and an aluminum content of at least 0.35% by weight. The invention also relates to the use of the said silicas as reinforcing fillers for elastomers.
    Type: Application
    Filed: June 26, 2002
    Publication date: April 10, 2003
    Inventors: Yves Bomal, Yvonick Chevallier, Philippe Cochet
  • Patent number: 6534176
    Abstract: Scaly silica particles having a laminated structure, consisting essentially of secondary particles of foliar silica, each formed by a plurality of flaky primary particles of scaly silica which are overlaid one on another and aligned face-to-face in parallel with one another, said secondary particles being present independent of one another.
    Type: Grant
    Filed: December 6, 2000
    Date of Patent: March 18, 2003
    Assignees: Asahi Glass Company, Limited, Dohkai Chemical Industry Co., Ltd.
    Inventors: Kunihiko Terase, Masaki Inoue, Atsunari Fujii, Takayoshi Sasaki, Shikou Minohara, Yoshimi Ohba
  • Patent number: 6375735
    Abstract: Disclosed are amorphous precipitated silicas, silica gels, and amorphous carbons derived from biomass and methods of producing them with and without adhered or deposited amorphous carbons produced by acidifying a caustic silicate solution produced by caustic digestion of biomass ash containing silica with and without activated carbon, the ash being obtained from thermal pyrolysis of the biomass, the acidifying effective to produce a slurry of the precipitated silica and silica gels with and without adhered or deposited amorphous carbon, and separated from the slurry the precipitated silicas and silica gels with and without the adhered or deposited amorphous carbons. The properties of the precipitated silica with adhered or deposited carbon being within the range as utilized in rubber compositions thereby avoiding the blending of silica and carbon components for such use.
    Type: Grant
    Filed: March 31, 2000
    Date of Patent: April 23, 2002
    Assignees: Agritec, Inc., Occidental Chemical Corporation
    Inventors: Douglas K. Stephens, Clyde W. Wellen, Jeffrey B. Smith, Kenneth F. Kubiak
  • Publication number: 20020011186
    Abstract: A flaky fine powder comprising a flaky substance as the base and silica particles covering the surface of the base, aiming at reducing the glossiness of the base caused by the irregular ref lection of light on its surface and improving the slipperiness In particular the powder comprises a flaky base substance such as natural mica and silica particles deposited on the base surface, wherein the silica particles may be optionally further immobilized by the hydrolysate of alkoxysilane or silica gel. The flaky fine powder is produced either by adding alkoxysilane to a dispersion containing a flaky substance and silica particles and hydrolyzing it, by adding a silicic acid solution to the dispersion and gelling it, or by adding a combination of alkoxysilane and silicic acid solution. This powder can be compounded with various ingredients and is particularly useful with cosmetics.
    Type: Application
    Filed: March 28, 2001
    Publication date: January 31, 2002
    Inventors: Hirokazu Tanaka, Naoyuki Enomoto
  • Patent number: 6221149
    Abstract: The invention relates to a new process for the preparation of precipitated silica which has a very good dispersibility and very satisfactory reinforcing properties. It also relates to new precipitated silicas which are in the form of powder, of substantially spherical beads or of granules, these silicas being characterized by the fact that they have a CTAB specific surface of between 100 and 240 m2/g, a DOP oil uptake lower than 300 ml/100 g, a pore distribution such that the pore volume consisting of the pores whose diameter is between 175 and 275 Å represents less than 50% of the pore volume consisting of the pores of diameters which are smaller than or equal to 400 Å, a median diameter, after disintegration with ultrasound, smaller than 5 &mgr;m and an aluminum content of at least 0.35% by weight. The invention also relates to the use of the said silicas as reinforcing fillers for elastomers.
    Type: Grant
    Filed: August 24, 1998
    Date of Patent: April 24, 2001
    Assignee: Rhodia Chimie
    Inventors: Yves Bomal, Yvonick Chevallier, Philippe Cochet
  • Patent number: 6171384
    Abstract: An amorphous silicate pigment having a pore volume of at least about 4.0 ml/g as measured by mercury intrusion, a BET surface area of at least about 300 m2/g, and an Al2O3 content of about 2.0-10.0 wt % is provided. The invention can be successfully used in recording media coatings, particularly coatings for recording media used in ink jet printing systems.
    Type: Grant
    Filed: May 4, 1998
    Date of Patent: January 9, 2001
    Assignee: J. M. Huber Corp.
    Inventors: Donald P. Conley, Gary W. Loock, Barry W. Preston, Michael C. Withiam
  • Patent number: 6146454
    Abstract: The invention relates to a new process for the preparation of precipitated silica which has a good dispersibility and very satisfactory reinforcing properties. It also relates to new precipitated silicas which are in the form of powder, of substantially spherical beads or of granules, these silicas being characterized by the fact that they have a CTAB specific surface of between 90 and 250 m.sup.2 /g, a BET specific surface of between 90 and 250 m.sup.2 /g, a DOP oil uptake lower than 300 ml/100 g, a zinc content of between 1 and 5% by weight, and by the fact that the number N of stearic acid molecules consumed per nm.sup.2 of silica surface, when stearic acid is reacted with this silica in xylene for 2 hours at 120.degree. C., is at least 1. The invention also relates to the use of the said silicas as reinforcing fillers for elastomers, especially for improving their rheological properties.
    Type: Grant
    Filed: February 11, 1999
    Date of Patent: November 14, 2000
    Assignee: Rhodia Chimie
    Inventors: Yves Bomal, Yvonick Chevallier, Evelyne Prat
  • Patent number: 6143066
    Abstract: The invention relates to a new process for the preparation of precipitated silica which has a good dispersibility and very satisfactory reinforcing properties. It also relates to new precipitated silicas which are in the form of powder, of substantially spherical beads or of granules, these silicas being characterized by the fact that they have a CTAB specific surface of between 90 and 250 m.sup.2 /g, a DOP oil uptake lower than 300 ml/100 g, a pore distribution such that the pore volume consisting of the pores whose diameter is between 175 and 275 .ANG. represents less than 50% of the pore volume consisting of the pores of diameters smaller than or equal to 400 .ANG., a zinc content of between 1 and 5% by weight and by the fact that the number N of molecules of stearic acid consumed per nm.sup.2 of silica surface, when stearic acid is reacted with the said silica in xylene for 2 hours at 120.degree. C., is at least 1.
    Type: Grant
    Filed: September 2, 1998
    Date of Patent: November 7, 2000
    Assignee: Rhodia Chimie
    Inventors: Yves Bomal, Yvonick Chevallier, Evelyne Prat
  • Patent number: 6136740
    Abstract: A method of producing a porous inorganic particulate material which comprises treating a particulate aluminosilicate material with a leaching agent which chemically reacts with or solubilizes aluminum and thereby leaches aluminum from the aluminosilicate material, wherein the particulate aluminosilicate material is a particulate hydrous aluminosilicate material which has been flash calcined.
    Type: Grant
    Filed: November 9, 1998
    Date of Patent: October 24, 2000
    Assignee: Imerys Minerals, Ltd.
    Inventors: Thomas Richard Jones, Christopher Derek Paynter
  • Patent number: 6077341
    Abstract: A silica-metal oxide particulate composite comprising silica agglomerates having voids formed by random stacking of scaly silica primary particles, and metal oxide particulates supported on the surfaces, and the inner surfaces in the voids, of the silica agglomerates.
    Type: Grant
    Filed: September 28, 1998
    Date of Patent: June 20, 2000
    Assignees: Asahi Glass Company, Ltd., Dohkai Chemical Industry Co., Ltd.
    Inventors: Kunihiko Terase, Masaharu Tanaka, Masaki Inoue, Eiichi Ono, Takayoshi Sasaki
  • Patent number: 5964937
    Abstract: An amorphous silica having an RDA value of between 30 and 70, an oil absorption capacity of between 100 and 155 cc/100 g and a moisture loss of less than 7% w/w, can be incorporated at a 10% to 25% loading into a transparent toothpaste having a refractive index of above 1.445, this toothpaste having an RDA value of between 30 and 60.
    Type: Grant
    Filed: December 23, 1997
    Date of Patent: October 12, 1999
    Assignee: Crosfield Limited
    Inventor: Peter William Stanier
  • Patent number: 5958127
    Abstract: The invention relates to a new process for the preparation of precipitated silica which has a good dispersibility and very satisfactory reinforcing properties. It also relates to new precipitated silicas which are in the form of powder, of substantially spherical beads or of granules, these silicas being characterized by the fact that they have a CTAB specific surface of between 90 and 250 m.sup.2 /g, a BET specific surface of between 90 and 250 m.sup.2 /g, a DOP oil uptake lower than 300 ml/100 g, a zinc content of between 1 and 5% by weight, and by the fact that the number N of stearic acid molecules consumed per nm.sup.2 of silica surface, when stearic acid is reacted with this silica in xylene for 2 hours at 120.degree. C., is at least 1. The invention also relates to the use of the said silicas as reinforcing fillers for elastomers, especially for improving their rheological properties.
    Type: Grant
    Filed: March 3, 1997
    Date of Patent: September 28, 1999
    Assignee: Rhone-Poulenc Chimie
    Inventors: Yves Bomal, Yvonick Chevallier, Evelyne Prat
  • Patent number: 5935543
    Abstract: Amorphous precipitated silica which may be used to form battery separators of very low specific resistance is characterized by (a) a CTAB surface area in the range of from 140 to 185 m.sup.2 /g; (b) a DBP oil absorption in the range of from 210 to 310 cm.sup.3 /100 g; (c) a mean ultimate particle size in the range of from 10 to 18 nm; (d) a total intruded volume in the range of from 2.6 to 4 cm.sup.3 /g; and (e) an intruded volume in the range of from 0.9 to 2 cm.sup.3 /g for pores having diameters in the range of from 20 to 100 nm.
    Type: Grant
    Filed: August 8, 1997
    Date of Patent: August 10, 1999
    Assignee: PPG Industries Ohio, Inc.
    Inventors: James L. Boyer, Thomas G. Krivak, Robert C. Wang, Laurence E. Jones
  • Patent number: 5891235
    Abstract: An additive for resins, a process for preparing amorphous definite particles used as an inorganic additive, and an olefin resin composition blended with the additive, and an agricultural film blended with the additive and a lithium-aluminum composite hydroxide carbonate. The additive for resins comprises amorphous definite particles having (1) a molar ratio SiO.sub.2 /Al.sub.2 O.sub.3 of from 2.1 to 3.3 on the basis of oxides, (2) an average particle diameter of from 0.3 to 10 .mu.m, (3) a moisture regain at equilibrium (RH90%) of not greater than 10%, (4) a bulk density of from 0.5 to 1.2 g/ml, and (5) a pH in the form of an aqueous suspension of from 6 to 10, said amorphous definite particles being obtained by acid-treating and then heat-treating a Pc zeolite having a spherical particle shape, a notched surface and a molar ratio SiO.sub.2 /Al.sub.2 O.sub.3 of from 2 to 3.
    Type: Grant
    Filed: May 22, 1997
    Date of Patent: April 6, 1999
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Kazuhiko Suzuki, Hiroshi Ogawa, Hideyuki Nakagawa, Hiroo Inoue
  • Patent number: 5876494
    Abstract: The invention relates to a new process for the preparation of precipitated silica which has a very good dispersibility and very satisfactory reinforcing properties. It also relates to new precipitated silicas which are in the form of powder, of substantially spherical beads or of granules, these silicas being characterized by the fact that they have a CTAB specific surface of between 100 and 240 m.sup.2 /g, a DOP oil uptake lower than 300 ml/100 g, a pore distribution such that the pore volume consisting of the pores whose diameter is between 175 and 275 .ANG. represents less than 50% of the pore volume consisting of the pores of diameters which are smaller than or equal to 400 .ANG., a median diameter, after disintegration with ultrasound, smaller than 5 .mu.m and an aluminium content of at least 0.35% by weight. The invention also relates to the use of the said silicas as reinforcing fillers for elastomers.
    Type: Grant
    Filed: March 30, 1997
    Date of Patent: March 2, 1999
    Assignee: Rhone-Poulenc Chimie
    Inventors: Yves Bomal, Yvonick Chevallier, Philippe Cochet
  • Patent number: 5846311
    Abstract: The invention relates to a new process for the preparation of precipitated silica which has a good dispersibility and very satisfactory reinforcing properties. It also relates to new precipitated silicas which are in the form of powder, of substantially spherical beads or of granules, these silicas being characterized by the fact that they have a CTAB specific surface of between 90 and 250 m.sup.2 /g, a DOP oil uptake lower than 300 ml/100 g, a pore distribution such that the pore volume consisting of the pores whose diameter is between 175 and 275 .ANG. represents less than 50% of the pore volume consisting of the pores of diameters smaller than or equal to 400 .ANG., a zinc content of between 1 and 5% by weight and by the fact that the number N of molecules of stearic acid consumed per nm.sup.2 of silica surface, when stearic acid is reacted with the said silica in xylene for 2 hours at 120.degree. C., is at least 1.
    Type: Grant
    Filed: March 3, 1997
    Date of Patent: December 8, 1998
    Assignee: Rhone-Poulenc Chimie
    Inventors: Yves Bomal, Yvonick Chevallier, Evelyne Prat
  • Patent number: 5827363
    Abstract: A method for preparing precipitated silicates and silicas having good high shear rheology in high solids aqueous slurries. Destructuring of aluminum silicate and silica via dry milling results in decreasing DBP oil absorption. The destructured materials are useful for ink jet coating formulations.
    Type: Grant
    Filed: December 17, 1996
    Date of Patent: October 27, 1998
    Assignee: Degussa Corporation
    Inventors: Michael S. Darsillo, Sturgis Gregg Allen
  • Patent number: 5800608
    Abstract: The invention relates to a new process for the preparation of precipitated silica which has an excellent dispersibility and very satisfactory reinforcing properties. It also relates to new precipitated silicas which are in the form of powder, of substantially spherical beads or of granules, these silicas being characterized by the fact that they have a CTAB specific surface of between 140 and 200 m.sup.2 /g, a BET specific surface of between 140 and 200 m.sup.2 /g, a DOP oil uptake lower than 300 ml/100 g, a median diameter, after disintegration with ultrasound, smaller than 3 .mu.m, an ultrasonic disintegration factor higher than 10 ml and an aluminium content of at least 0.35% by weight. The invention also relates to the use of the said silicas as reinforcing fillers for elastomers.
    Type: Grant
    Filed: March 3, 1997
    Date of Patent: September 1, 1998
    Assignee: Rhone-Poulenc Chimie
    Inventors: Yves Bomal, Yvonick Chevallier, Philippe Cochet
  • Patent number: 5747003
    Abstract: A statistically large population of particles of amorphous precipitated silica comprising pigmentary phase particles and glassy phase particles and having a glassy phase fraction in the range of from 0.3 to 30 area percent is useful as an abrasive for dentifrice compositions, especially toothpaste.
    Type: Grant
    Filed: March 22, 1995
    Date of Patent: May 5, 1998
    Assignee: PPG Industries, Inc.
    Inventors: Shantilal M. Mohnot, Harold E. Swift, Thomas G. Krivak, Robert H. Fear, Laura M. Randall, Laurence E. Jones
  • Patent number: 5738718
    Abstract: A process for producing zinc oxide-containing spherical silica, which comprises emulsifying, in an organic solvent containing a surfactant, a dispersion having zinc oxide with a particle size of from 0.005 to 0.5 .mu.m dispersed in an aqueous alkali metal silicate solution in an amount of from 10 to 70 wt % based on the total amount of zinc oxide and SiO.sub.2 in the aqueous alkali metal silicate solution, followed by gelation of the resulting emulsion with carbon dioxide gas.
    Type: Grant
    Filed: April 7, 1997
    Date of Patent: April 14, 1998
    Assignee: Asahi Glass Company Ltd.
    Inventors: Hiroo Mori, Hiroshi Funaki, Kunihiko Terase, Hachirou Hirano
  • Patent number: 5705137
    Abstract: Precipitated silicas, characterized in that they have a CTAB surface area (in accordance with ASTM D 3765-92) of 200 to 400 m.sup.2 /g, a DBP index (in accordance with ASTM D 2414) between 230 and 380 ml/100 g as powder and 180-250 g/100 g as granulate, a silanol group density (V.sub.2 -NaOH consumption) of 20 to 30 ml and the following macropore size distribution which is typical of the surface area range involved, determined by means of Hg porosimetry (DIN 66 133) for specific pore size intervals (incremental mode of application):______________________________________ CTAB surface CTAB surface CTAB surface area range: area range: area range: 200-250 250-300 300-400 Pore size m.sup.2 /g m.sup.2 /g m.sup.2 /g interval ?nm! Hg consumption in ml/g of silica ______________________________________ 10-20 0.27-0.49 0.35-0.50 0.32-0.42 20-30 0.22-0.32 0.15-0.30 0.17-0.22 30-40 0.15-0.21 0.12-0.17 0.12-0.15 40-50 0.11-0.16 0.09-0.12 0.08-0.11 50-60 0.08-0.12 0.06-0.10 0.06-0.
    Type: Grant
    Filed: May 29, 1996
    Date of Patent: January 6, 1998
    Assignee: Degussa Aktiengesellschaft
    Inventors: Udo Goerl, Andrea Hunsche, Robert Kuhlmann, Mustafa Siray, Heinz Esch
  • Patent number: 5660622
    Abstract: A coating composition for ink jet recording sheets, which includes a combination of hydrated amorphous synthetic silica, a synthetic binder, a cationic agent, a leveling-flow modifier, a dispersing agent, an optical brightener, and the remainder being water, is provided. The composition achieves superior brilliance, water fastness, water resistance and improved controlled absorbency of the ink with improved color density.
    Type: Grant
    Filed: August 8, 1996
    Date of Patent: August 26, 1997
    Inventor: Koyu P. Nikoloff
  • Patent number: 5647903
    Abstract: Precipitated silicas having wet cake moisture values in excess of 85%, BET surface areas of 600-700 m.sup.2 /g, oil absorption values of 50 to 60 cc/100 g, total intruded volume of about 1.2 to 0.8 cc/g, and a median pore radius of 50 .ANG. to 20 .ANG. are produced by a low temperature silica precipitation process. The silicas have unique flatting characteristics and are additionally useful as conditioning agents for food and salt and in dentifrice compositions.
    Type: Grant
    Filed: October 3, 1995
    Date of Patent: July 15, 1997
    Inventors: Patrick D. McGill, William Fultz
  • Patent number: 5616316
    Abstract: Novel silica particulates especially adapted for formulation to dentifrice compositions exhibit unique physical and chemical properties. In one embodiment, silica particulates have a unique surface chemistry as to be at least 50% compatible with zinc values, and have a number of OH functions, expressed as OH/nm.sup.2, of at most 15 and a zero charge point (PZC) of from 3 to 6.5. In a second embodiment, particulates have a surface chemistry as to be at least 65%, and preferably at least 90% compatible with guanidine values, notably chlorhexidine, and acidity function thereof, Ho, of at least 3.3. In a third embodiment, silica particulates are compatible with organic amines, and have a pH, in aqueous suspension, which varies according to the equations pH.ltoreq.7.5-0.7 log(C) and pH.gtoreq.5.0-0.5 log(C) and which also varies as a function of the electrical conductivity thereof, according to the equations pH.ltoreq.8.5-0.4 log(D) and pH.gtoreq.7.0-0.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 1, 1997
    Assignee: Rhone-Poulenc Chimie
    Inventor: Jacques Persello
  • Patent number: 5614176
    Abstract: Novel silica particulates especially adapted for formulation to dentifrice compositions exhibit unique physical and chemical properties. In one embodiment, silica particulates have a unique surface chemistry as to be at least 50% compatible with zinc values, and have a number of OH functions, expressed as OH/nm.sup.2, of at most 15 and a zero charge point (PZC) of from 3 to 6.5. In a second embodiment, particulates have a surface chemistry as to be at least 65%, and preferably at least 90% compatible with guanidine values, notably chlorhexidine, and acidity function thereof, Ho, of at least 3.3. In a third embodiment, silica particulates are compatible with organic amines, and have a pH, in aqueous suspension, which varies according to the equations pH.ltoreq.7.5-0.7 log(C) and pH.gtoreq.5.0-0.5 log(C) and which also varies as a function of the electrical conductivity thereof, according to the equations pH.ltoreq.8.5-0.4 log(D) and pH.gtoreq.7.0-0.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 25, 1997
    Assignee: Rhone-Poulenc Chimie
    Inventor: Jacques Persello
  • Patent number: 5614177
    Abstract: Novel silica particulates especially adapted for formulation to dentifrice compositions exhibit unique physical and chemical properties. In one embodiment, silica particulates have a unique surface chemistry as to be at least 50% compatible with zinc values, and have a number of OH functions, expressed as OH/nm.sup.2, of at most 15 and a zero charge point (PZC) of from 3 to 6.5. In a second embodiment, particulates have a surface chemistry as to be at least 65%, and preferably at least 90% compatible with guanidine values, notably chlorhexidine, and acidity function thereof, Ho, of at least 3.3. In a third embodiment, silica particulates are compatible with organic amines, and have a pH, in aqueous suspension, which varies according to the equations pH.ltoreq.7.5-0.7 log(C) and pH.gtoreq.5.0-0.5 log(C) and which also varies as a function of the electrical conductivity thereof, according to the equations pH.ltoreq.8.5-0.4 log(D) and pH.gtoreq.7.0-0.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 25, 1997
    Assignee: Rhone-Poulenc Chimie
    Inventor: Jacques Persello
  • Patent number: 5612020
    Abstract: Novel silica particulates especially adapted for formulation to dentifrice compositions exhibit unique physical and chemical properties. In one embodiment, silica particulates have a unique surface chemistry, as to be at least 50% compatible with zinc values, and have a number of OH functions, expressed as OH/nm.sup.2, of at most 15 and a zero charge point (PZC) of from 3 to 6.5. In a second embodiment, particulates have a surface chemistry as to be at least 65%, and preferably at least 90% compatible with guanidine values, notably chlorhexidine, and acidity function thereof, Ho, of at least 3.3. In a third embodiment, silica particulates are compatible with organic amines, and have a pH, in aqueous suspension, which varies according to the equations pH.ltoreq.7.5-0.7 log(C) and pH.gtoreq.5.0-0.5 log(C) and which also varies as a function of the electrical conductivity thereof, according to the equations pH.ltoreq.8.5-0.4 log(D) and pH.gtoreq.7.0-0.
    Type: Grant
    Filed: October 26, 1993
    Date of Patent: March 18, 1997
    Assignee: Rhone-Poulenc Chimie
    Inventor: Jacques Persello
  • Patent number: 5605569
    Abstract: Particles comprising particulate amorphous precipitated silica in association with from 5 to 10 percent by weight sodium sulfate and less than 10 percent by weight water, wherein the percentages are based on the weight of the silica, the sodium sulfate, and the water, which particles have a BET surface area of from 100 to 300 m.sup.2 /g, a total intruded volume from 1.8 to 3.6 cm.sup.3 /g, and a DBP oil absorption of from 180 to 320 cm.sup.3 /100 g, may be employed in microporous battery separators to introduce all or a portion of the desired sodium sulfate to the battery electrolyte. Moreover the enhanced amount of sodium sulfate enhances silica characteristics and battery separator production.
    Type: Grant
    Filed: November 8, 1995
    Date of Patent: February 25, 1997
    Assignee: PPG Industries, Inc.
    Inventors: James L. Boyer, Thomas G. Krivak, Harold E. Swift, Robert C. Wang
  • Patent number: 5591256
    Abstract: Sodium alumino-silicates are produced by silicate/clay reactions under hydrothermal conditions with increased solids during processing while still producing structural materials characterized by low oil absorption values, high total pore volume and increased differential pore volumes. The products are useful as coating pigments for paper and paperboard, paper fillers, paint pigments and as reinforcing pigments for rubber.
    Type: Grant
    Filed: August 10, 1994
    Date of Patent: January 7, 1997
    Assignee: J. M. Huber Corporation
    Inventors: Gary M. Freeman, Richard D. Carter, Thad T. Broome, Kurt H. Moller
  • Patent number: 5342598
    Abstract: Precipitated silica particulates having a BET specific surface ranging from 20 to 300 m.sup.2 /g, a CTAB specific surface ranging from 10 to 200 m.sup.2 /g, an oil uptake (DBP) ranging from 80 to 400 cm.sup.3 /100 g, a pore volume ranging from 1 to 10 cm.sup.3 /g and a mean pore diameter ranging from 10 to 50 nm, well adapted for such applications as the coating of paper and catalysis, are prepared by (a) simultaneously introducing a silicate and an acid into a dispersion of colloidal silica, thereby providing a silica suspension, (b) next decreasing the pH of such suspension to a value ranging from 3 to 7, and (c) then separating the silica particulates from the final suspension and drying them.
    Type: Grant
    Filed: January 24, 1992
    Date of Patent: August 30, 1994
    Assignee: Rhone-Poulenc Chimie
    Inventor: Jacques Persello
  • Patent number: 5340393
    Abstract: An improved process for preparing non-agglomerated water insoluble inorganic particles having a dense amorphous silica coating by using a dispersion aid.
    Type: Grant
    Filed: October 12, 1993
    Date of Patent: August 23, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Howard W. Jacobson
  • Patent number: 5316576
    Abstract: Sodium Aluminosilicates (SAMS) are produced by silicate/clay reactions under hydrothermal conditions, the SAMS being characterized by low oil absorption values and high total pore volumes. The SAMS products are useful as coating pigments for paper, paper fillers and paint pigments.
    Type: Grant
    Filed: March 13, 1992
    Date of Patent: May 31, 1994
    Assignee: J. M. Huber Corporation
    Inventor: Gary M. Freeman
  • Patent number: 5300147
    Abstract: A method for producing a low-structure magnesium silicate SLR product useful to lower the strike through of low brightness paper products comprises adding a raw mineral source of soluble magnesium ions and sulfuric acid in a proportion and under conditions effective to form a slurry comprising soluble magnesium sulfate and a silica leach residue (SLR), and adding to the slurry a solution of an alkali metal silicate in a molar equivalent proportion of MgO:SiO.sub.2 of 1:2.0-4.0 under conditions effective to precipitate the magnesium ions and form a product comprising a low-structure magnesium silicate and SLR having a proportion of SiO.sub.2 MgO:SLR of 50-75%:5-12%:10-50% by weight of the product.A low-structure magnesium silicate SLR filler comprises 50 to 75 wt % SiO.sub.2, 5 to 12 wt % MgO, 10 to 50 wt % SLR, 0 to 6 wt % Fe.sub.2 O.sub.3, and 0 to 7 wt % Al.sub.2 O.sub.3, wherein the proportion MgO:SiO.sub.2 is 1:2.0-4.0.A paper product comprises at least an amount of the filler of the invention.
    Type: Grant
    Filed: April 12, 1993
    Date of Patent: April 5, 1994
    Assignee: J. M. Huber Corporation
    Inventors: Leif B. Martensson, Kaarina Heikkila