Organic Pigment Containing Patents (Class 106/493)
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Publication number: 20010042492Abstract: This invention relates to a process for preparing conditioned organic pigments byType: ApplicationFiled: November 22, 1999Publication date: November 22, 2001Inventors: MICHAEL J. GREENE, Patrick F. McIntyre, James G. King, Gregory R. Schulz, Karyn B. Visscher
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Patent number: 6312514Abstract: Pigment concentrates comprising a pigment, a liquid carrier medium and a diol alkoxylate of the general formulae (I), (II) and/or (III) are described in conjunction with methods of preparing the same.Type: GrantFiled: August 31, 2000Date of Patent: November 6, 2001Assignee: Cognis Deutschland GmbHInventors: Heinz-Guenther Schulte, Rainer Hoefer, Hans-Christian Raths, Harald Frommelius, Stefan Gollnick
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Patent number: 6312513Abstract: Pigment concentrates comprising a pigment, a liquid carrier medium and a dimerdiolalkoxylate, wherein a dimer portion of the dimerdiolalkoxylate comprises from about 36 to about 44 carbon atoms, and wherein the at least one dimerdiolalkoxylate has from about 1 to about 200 moles of alkylene oxide per mole of dimerdiol, are described in conjunction with methods of preparing the same.Type: GrantFiled: August 7, 2000Date of Patent: November 6, 2001Assignee: Cognis Deutschland GmbHInventors: Rainer Hoefer, Heinz-Guenther Schulte, Hans-Christian Raths, Harald Frommelius, Stefan Gollnick, Ulrich Pegelow
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Patent number: 6306209Abstract: A pigment dispersion comprising pigment, an aqueous carrier selected from water and a mixture of water and at least one organic solvent, and a pigment dispersant is described. The pigment dispersant is prepared by polymerizing (i) at least one prepolymer having a radically polymerizable group, and (ii) at least one second monomer. The prepolymer is prepared by controlled radical polymerization, e.g., atom transfer radical polymerization, of at least one radically polymerizable first monomer. The second monomer forms a polymeric backbone segment of the pigment dispersant, and the prepolymer forms polymeric segments that are pendent to the backbone. The backbone segment of the pigment dispersant is hydrophilic, while at least a portion of each pendent polymeric segment is hydrophobic.Type: GrantFiled: December 16, 1999Date of Patent: October 23, 2001Assignee: PPG Industries Ohio, inc.Inventors: Brian E. Woodworth, Gregory J. McCollum, James B. O'Dwyer, Simion Coca
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Patent number: 6294014Abstract: A pigment dispersion comprising pigment, an aqueous carrier selected from water and a mixture of water and at least one organic solvent, and a pigment dispersant is described. The pigment dispersant is prepared by controlled radical polymerization, e.g., atom transfer radical polymerization, of a radically polymerizable monomer in the presence of a polymeric initiator having at least one radically transferable group. The polymeric initiator forms the polymeric backbone segment of the pigment dispersant, and the monomer forms polymeric segments that are pendent to the polymeric backbone segment. The pigment dispersant has comb-like architecture in which the polymeric backbone segment is hydrophobic, and at least a portion of each pendent polymeric segment is hydrophilic.Type: GrantFiled: December 16, 1999Date of Patent: September 25, 2001Assignee: PPG Industries Ohio, Inc.Inventors: Brian E. Woodworth, Simion Coca, James B. O'Dwyer
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Patent number: 6294012Abstract: Disclosed is a yellow monoazo pigment which is obtained by diazotization of anthranilic acid, coupling of the diazonium compound with 1-(3′-sulfophenyl)-3-methyl-5-pyrazolone and subsequent laking of the coupling product to a strontium salt. The pigment is characterized by the formula: The new pigment has excellent heat stability and bleed fastness and very high color strength. It is suitable for pigmenting of plastics, inks and coatings, and particularly suitable for pigmenting of plastics.Type: GrantFiled: November 15, 1999Date of Patent: September 25, 2001Assignee: Engelhard CorporationInventor: Amrit P. Bindra
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Patent number: 6290768Abstract: Pigment preparations comprising an organic pigment and a phenol-modified natural resin derivative having a weight-average molecular weight (Mw) of from 400 to 10,000 g/mol which is obtainable by reacting a mixture of reactants containing a) from 50 to 95% by weight of natural resin or natural resin acids, b) from 0.5 to 30% by weight of monocyclic or polycyclic phenols, c) from 0.01 to 15% by weight of aldehydes or aldehyde acetals, d) from 0.001 to 2% by weight of metal compounds from groups Ia and IIa of the Periodic Table, and e) from 4.489 to 30% by weight of &agr;,&bgr;-ethylenically unsaturated carboxylic acids or their anhydrides and has an acid number in the range from 160 to 300 mg of KOH per g of resin, preferably from 200 to 260 mg of KOH per g of resin, are used advantageously in offset printing.Type: GrantFiled: August 17, 1999Date of Patent: September 18, 2001Assignee: Clariant GmbHInventors: Hans Joachim Metz, Joachim Weide, Thomas Wallach
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Publication number: 20010020432Abstract: The present Application relates to pigment colorants of formula 1Type: ApplicationFiled: December 27, 2000Publication date: September 13, 2001Inventor: Jean-Marie Adam
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Patent number: 6287377Abstract: A universal tinting concentrate for both solvent- and water-based paints and coatings. The universal tinting concentrate is a composition which includes a colorant component, such as pigment, colorant, tinting agent and/or metal effect agent; a pigment dispersant including an organic acid containing no more an 70 carbon atoms; and a pH-neutralizing agent. In one embodiment of the invention, the pigment dispersant is represented by the following structure: where r and s are integers and r+s is 6 to 16; and x and y are integers and x+y is 0 to 19; and Z is H or COOH and Z′ is H or COOH.Type: GrantFiled: October 13, 1999Date of Patent: September 11, 2001Assignee: The Valspar CorporationInventors: Mark Binns, Dana L. Phillips, Don Diehl, Stephen Korenkiewicz, Larry Brandenburger
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Patent number: 6284036Abstract: The present invention relates to a process for pigmenting a porous sintered material comprising boride, carbide, silicide, nitride or phosphide compounds by applying a solution of a soluble pigment derivative to the non-coloured sintered material and regenerating the organic pigment by heating, whereby the organic pigment is deposited into the sintered material's pores, as well as to the new pigmented sintered materials themselves.Type: GrantFiled: November 8, 1999Date of Patent: September 4, 2001Assignee: Ciba Specialty Chemicals CorporationInventors: Seiji Homma, Hans-Thomas Schacht, Zhimin Hao
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Patent number: 6284035Abstract: Pigment preparations in granule form comprising as essential constituents from 50 to 99.5% by weight of at least one inorganic pigment and from 0.5 to 50% by weight of at least one organic pigment are prepared and used for coloring polymeric materials.Type: GrantFiled: September 7, 1999Date of Patent: September 4, 2001Assignee: BASF AktiengesellschaftInventors: Hansulrich Reisacher, Anton Dotter, Gerhard Berger, Otmar Pelz, Oliver Seeger
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Publication number: 20010016656Abstract: The present invention provides a process for preparing transparent perylimide pigments of the formula (I) 1Type: ApplicationFiled: February 5, 2001Publication date: August 23, 2001Applicant: Clariant GmbHInventors: Joachim Weber, Gerhard Wilker, Manfred Urban, Martin Bohmer, Erwin Dietz
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Patent number: 6274728Abstract: Compounds of formula A(B)x (I), wherein x is an integer from 1 to 8, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, indanthrone, isoindolinone, isoindoline, dioxazine, azo, phthalocyanine or diketopyrrolopyrrole series that is bonded to x groups B via one or more hetero atoms, those hetero atoms being selected from the group consisting of N, O and S and forming part of the radical A, each group B independently of any other(s) is hydrogen or a group of the formula at least one group B being a group of the formula The compounds according to the invention are used in high-molecular-weight organic materials, thermo-, photo- or chemo-sensitive recording materials, light-sensitive negative or positive resist compositions, ink compositions for ink-jet printing and color tapes for thermal transfer printing.Type: GrantFiled: December 16, 1999Date of Patent: August 14, 2001Assignee: Ciba Specialty Chemicals Corp.Inventors: VĂ©ronique Hall-Goulle, Aline Bize
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Patent number: 6261359Abstract: Compounds of formula A(B)x, (I), wherein x is an integer from 1 to 4, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group, B is a group of formula and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R1, R2, R3, R4, X, Y, Z, m and n, are as defined in claim 1.Type: GrantFiled: June 11, 1998Date of Patent: July 17, 2001Assignee: Ciba Specialty Chemicals CorporationInventors: Zhimin Hao, John S. Zambounis, Abul Iqbal
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Publication number: 20010007887Abstract: The invention relates to a pigment preparation comprising an organic pigment and 0.2 to 20% by weight, based on the total weight of the pigment preparation, of an ammonium polyphosphate or of an organophosphorus compound.Type: ApplicationFiled: December 8, 2000Publication date: July 12, 2001Applicant: Clariant GmbHInventors: Rudiger Jung, Klaus Saitmacher, Arpad Acs
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Patent number: 6258158Abstract: The present invention relates to a process for pigmenting a porous metal oxide by applying a solution of a soluble pigment derivative and regenerating the organic pigment by heating, whereby the organic pigment is deposited into the metal oxide's pores. The invention also relates to pigmented porous metal oxides and materials comprising a solid substrate and a surface layer of a pigmented metal oxide.Type: GrantFiled: November 8, 1999Date of Patent: July 10, 2001Assignee: Ciba Specialty Chemicals Corp.Inventors: Philippe Bugnon, Seiji Homma, Patrick Verhoustraeten
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Publication number: 20010006034Abstract: The invention relates to a process for preparing organic pigment granules with a particle size from 0.5 to 4 mm, which consist of at least 90% by weight of at least one organic pigment with a particle size from 0.Type: ApplicationFiled: February 15, 2001Publication date: July 5, 2001Inventors: Paolo Balliello, Horst Olaf Brucker
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Publication number: 20010004871Abstract: Various modified pigment products are described which are preferably capable of being dispersed in a variety of materials such as coatings, inks, toners, films, plastics, polymers, elastomers, and the like. The modified pigments are pigments having attached groups, such as polymeric groups, onto the pigment by means other than adsorption.Type: ApplicationFiled: December 29, 2000Publication date: June 28, 2001Inventors: Joseph E. Johnson, Nanying Bian, Collin P. Galloway
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Publication number: 20010003959Abstract: The invention provides a process for aftertreating organic pigments by causing the ground or unground crude organic pigment and liquid or supercritical carbon dioxide to act on one another.Type: ApplicationFiled: December 8, 2000Publication date: June 21, 2001Inventors: Rudiger Jung, Klaus Kund, Bernd Nestler, Martin U. Schmidt, Leonhard Unverdorben, Rudolf Steiner
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Patent number: 6241813Abstract: The invention relates to a process for preparing organic pigment granules with a particular particle size wherein an organic pigment with a particle size of 0.01 to 10 &mgr;m is mixed with water, a C1-C4alcohol, a C3-C8ketone or a mixture thereof, a binder and ammonia or a C1-C3amine and an emulsifier. This mixture is pressed in a continuously operating apparatus through one or more apertures each having a size of 0.2-5.0 mm2, the apparatus consisting of at least one conveying device and a shaping section comprising the apertures, and being constructed, and operated with a throughput, such that the pressure in its shaping section does not exceed 10 bar. The granulated product is then dried at a temperature of −50 to 200° C. at atmospheric pressure or under reduced pressure. The invention also relates to pigment granules prepared by the process of the invention, with a particle size of 0.5 to 4 mm, wherein the pigment present essentially has a particle size from 0.01 to 10&mgr;m.Type: GrantFiled: March 29, 1999Date of Patent: June 5, 2001Assignee: Ciba Specialty Chemicals CorporationInventors: Paolo Balliello, Horst Olaf BrĂ¼cker
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Patent number: 6235100Abstract: In one embodiment, the present invention relates to a method of preparing a medium shade yellow pigment composition comprising making an azo pigment by coupling (i) two or more diazonium components made from two or more aromatic amines including 2-amino-5-chloro-4-ethylbenzene-1-sulfonic acid and 2-amino-4-chloro-5-methylbenzene-1-sulfonic acid with (ii) at least 1-(3′-sulfophenyl)-3-methyl-5-pyrazolone, and metallizing the azo pigment with a divalent metal to provide the medium shade yellow pigment composition. The medium shade yellow pigment composition is suitable for use in plastics, paints and inks.Type: GrantFiled: June 24, 1999Date of Patent: May 22, 2001Assignee: Engelhard CorporationInventor: Byron G. Hays
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Patent number: 6235099Abstract: A water-dispersed inkjet recording liquid excellent in water resistance and transparency and also excellent in the property of ejection from a nozzle, containing, as a colorant, a water-based dispersion of an organic pigment (A) which is at least one member selected from the group consisting of a quinacridone pigment, a benzimidazolone pigment, an insoluble azo pigment, a fuzed azo pigment, a quinophthalone pigment, a naphthol pigment, a perylene pigment and an isoindolinone pigment and has an average particle diameter of 10 to 150 nm (measured by laser scattering), the water-based dispersion of the organic pigment (A) being obtained by mechanically kneading a mixture containing at least three components of the organic pigment (A), a water-soluble inorganic salt (B) in an amount by weight at least three times as large as the amount of the organic pigment (A) and a water-soluble solvent (C) to finely mill the organic pigment (A), and then removing the water-soluble inorganic salt (B) and the water-soluble solvType: GrantFiled: July 28, 1997Date of Patent: May 22, 2001Assignee: Toyo Ink Manufacturing Co., Ltd.Inventors: Seiji Aida, Tsutomu Fujigamori, Hisashi Uraki, Ichiro Toyoda, Sunao Satake, Seiji Sawada, Yasuharu Iida
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Patent number: 6231662Abstract: An additive for enhancing the performance of industrial pigments. The additive improves dispersibility and is the reaction product of an amine, a fatty amine, and a polybasic acid.Type: GrantFiled: October 25, 1999Date of Patent: May 15, 2001Inventor: George K. Atkinson
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Patent number: 6228162Abstract: C.I. Pigment Red 53:2 is obtained in new crystal modifications (epsilon, zeta, eta, theta, iota, kappa, lambda, nu, xi, omicron, pi and rho phases) by heating any other phase of this pigment in certain organic solvents and reprecipitating the pigment. The new crystal phases differ from one another in rheology and coloristics.Type: GrantFiled: December 17, 1999Date of Patent: May 8, 2001Assignee: Clariant GmbHInventor: Martin U. Schmidt
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Patent number: 6224664Abstract: The invention relates to mixtures containing pigments which comprise oriented three-dimensionally crosslinked substances having a liquid-crystalline structure with a chiral phase, and to the use of such mixtures. Pigment and matrix are matched to one another in such a way that on application of the mixture at different temperatures to a substrate, the lowest application temperature and highest application temperature differing by at least 10° C. and by not more than 150° C., there are no visually perceptible color differences of the pigmented paint on the substrate after drying.Type: GrantFiled: June 18, 1998Date of Patent: May 1, 2001Assignee: Wacker-Chemie GmbHInventors: Christoph MĂ¼ller-Rees, Eckhard Hanelt, Franz-Heinrich Kreuzer, JĂ¼rgen KĂ¼pfer, Horst Leigeber
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Patent number: 6224665Abstract: This invention relates to a process for preparing perylene pigment compositions by reaction of (a) a perylene tetracarboxylic compound; (b) about 0.01 to about 20% by weight, relative to the perylene tetracarboxylic compound, of a non-pigmentary cyclic anhydride or imide of formula (I) wherein W is O or NR1 (where R1 is hydrogen, a metal, or optionally substituted alkyl, cycloalkyl, aralkyl, or aryl), R2, R3, and R4 are various combinations of substituents and/or fused-on rings, and the dotted line is an optional double bond representing R2−C=C—R3; (c) ammonia or a primary alkyl, aralkyl, or aryl amine; optionally in the presence of (d) a solvent and/or (e) one or more dispersants.Type: GrantFiled: January 25, 2000Date of Patent: May 1, 2001Assignee: Bayer CorporationInventors: Gregory R. Schulz, Michael J. Greene
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Patent number: 6221150Abstract: The present invention relates to pigment dispersants of the formula (I) in which Z1 is a radical of the formula (Ia) —[X—Y]q—[X1—Y1]r—[X2—NH]sH (Ia) in which X, X1 and X2 are identical or different and are a branched or unbranched C2-C6-alkylene radical or a C5-C7-cycloalkylene radical which can be substituted by from 1 to 4 C1-C4-alkyl radicals, hydroxyl radicals, and/or by from 1 to 2 further C5-C7-cycloalkyl radicals; Y and Y1 are identical or different and are an NH—, —O— or N(C1-C6-alkyl) group, q is a number from 1 to 6, r and s independently of one another are a number from 0 to 6, but are not simultaneously zero; and Z is defined as Z1, Z2 or Z3, where Z2 is a radical of the formula (Ib) —[X—O]q1—[X1—O]qH (Ib) in which q1 is a number from 0 to 6, and Z3 is hydrogen, hydroxyl, amino or C1-C6-alkyl where the alkyl group canType: GrantFiled: February 22, 1999Date of Patent: April 24, 2001Assignee: Clariant GmbHInventors: Joachim Weber, Manfred Urban, Erwin Dietz
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Patent number: 6207770Abstract: The invention relates to cholesteric polymer flakes obtainable from a chiral polymerizable mesogenic material, to methods of manufacturing such cholesteric flakes, to the use of certain chiral and achiral polymerizable compounds with one or more terminal polymerizable groups for the manufacturing of such flakes and to the use of such cholesteric flakes as effect pigments in spraying or printing inks or paints or colored plastics for different applications, especially for automotive use, cosmetic products and security applications.Type: GrantFiled: August 14, 1998Date of Patent: March 27, 2001Assignee: Merck Patent GmbHInventors: David Coates, Mark Goulding, Alison May
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Patent number: 6203909Abstract: A composite pigment, which consists of a colourant and a substrate, using a substrate (S) and a colourant (C), which are each coated with ions or ionisable compounds having a charge rotating in the same direction, and, if desired, of additional ions or ionisable compounds having a change rotating in the same direction as layer material (L), wherein either (I) the sign of the change of the coating of S, or the sign of the charge of the coating of S and of the charge of L, which is the same, is opposite to that of charge of the coating of C, or (II) the sign of charges of the coatings of S and C is the same and is opposite to that of the charge of L.Type: GrantFiled: January 9, 1998Date of Patent: March 20, 2001Assignee: Ciba Specialty Chemicals CorporationInventor: Laurent Chassot
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Patent number: 6200378Abstract: A compound according to the formula (I) wherein R1 and R2 are independently the atoms necessary to complete the formation of a substituted or unsubstituted aromatic or aliphatic carbocyclic or heterocyclic ring system and R3 and R4 have the meaning indicated in claim 1, a new process for the preparation of such a compound, solid solutions and mixtures comprising such a compound and the use of a compound of formula (I) as a pigment.Type: GrantFiled: July 23, 1999Date of Patent: March 13, 2001Assignee: Clariant Finance (BVIĂ˜) LimitedInventors: Bruno Piastra, Bansi Lal Kaul
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Patent number: 6176907Abstract: Formulation for anti-corrosion coating materials, comprising (i) 3-30% by mass of a monomeric and/or polymeric, metal-free or metal-containing, chelate-forming compound, (ii) 10-80% by mass of a material which binds hydroxide ions, and (iii) 5-65% by mass of a conductive pigment based on carbon.Type: GrantFiled: January 19, 1999Date of Patent: January 23, 2001Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventor: Ralf Glausch
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Patent number: 6156114Abstract: A method for treating the surface of substantially each deagglomerated particle of an array of easily agglomerated particles by contacting deagglomerated particles with a plasma-activated gas species and modifying the surfaces of the deagglomerated particles to aid subsequent incorporation of the particles into a matrix composition; the module for deagglomerating and dispersing the particles into the plasma-activated gas; the apparatus that comprises the deagglomeration module (322) and a reaction chamber (20) in which the particles are treated with the plasma-activated gas; the method for deagglomerating particles that may reagglomerate after plasma treatment; and a color composition containing plasma-treated pigment particles.Type: GrantFiled: August 4, 1998Date of Patent: December 5, 2000Assignee: E. I. du Pont de Nemours and CompanyInventors: Timothy Allan Bell, Wronald Scott Best, Michael Patrick Chouinard, Paul Francis Herman, James Lewis Hohman, Jr., Laurence J. Levase, Tyau-Jeen Lin, An-Gong Yeh, Thomas William Harding
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Patent number: 6156324Abstract: Cosmetic compositions and cosmetics which have good dispersibility, high UV protection effect that lasts for a long period and high stability with suppressed optical activity and catalytic activity. The cosmetic contains 10.5 weight % of a composition comprising fine-grain titanium oxide (mean particle size 0.9 .mu.m) treated with 5% methylhydrogenpolysiloxane, zinc oxide (mean particle size 2.5 .mu.m) treated in the same manner and talc (mean particle size 4 .mu.m) treated in the same manner.Type: GrantFiled: May 20, 1997Date of Patent: December 5, 2000Assignee: Miyoshi Kasei, Inc.Inventors: Masaakira Horino, Yukio Hasegawa
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Patent number: 6153764Abstract: This invention relates to a process for preparing perylene pigment compositions by reaction of(a) a perylene tetracarboxylic compound;(b) about 0.01 to about 20% by weight, relative to the perylene tetracarboxylic compound, of a non-pigmentary cyclic anhydride or imide of formula (I) ##STR1## wherein W is O or NR.sup.1 (where R.sup.1 is hydrogen, a metal, or optionally substituted alkyl, cycloalkyl, aralkyl, or aryl), R.sup.2, R.sup.3, and R.sup.4 are various combinations of substituents and/or fused-on rings, and the dotted line is an optional double bond representing R.sup.2 --C.dbd.C--R.sup.3 ;(c) ammonia or a primary alkyl, aralkyl, or aryl amine; optionally in the presence of(d) a solvent and/or(e) one or more dispersants.Type: GrantFiled: January 25, 2000Date of Patent: November 28, 2000Assignee: Bayer CorporationInventors: Gregory R. Schulz, Michael J. Greene
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Patent number: 6146455Abstract: The invention relates to a novel crystal modification (.delta.-modification) of C.I. Pigment Red 53:2 of the formula (1) ##STR1## having the following characteristic reflections in the X-ray powder diffraction pattern:______________________________________ 2.THETA. d relative intensity (in %) ______________________________________ 3.3 26.6 32 4.7 18.7 100 7.5 11.9 14 9.4 9.3 19 10.5 8.4 13 13.8 6.4 10 14.2 6.2 9 14.9 5.9 10 16.7 5.3 11 17.6 5.0 9 18.1 4.9 16 18.9 4.7 10 20.4 4.3 7 21.1 4.2 9 22.1 4.0 9 22.7 3.9 12 23.1 3.8 9 23.6 3.8 13 24.1 3.7 9 24.9 3.6 10 25.5 3.5 23 26.3 3.4 9 27.7 3.2 9 28.1 3.2 6 28.9 3.1 6 30.4 2.Type: GrantFiled: June 21, 1999Date of Patent: November 14, 2000Assignee: Clariant GmbHInventors: Martin Ulrich Schmidt, Hans Joachim Metz
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Patent number: 6146145Abstract: A method of blending a light-transmittable powder coating which is colored in at least one color and a colorless light-transmittable powder coating which is not colored, and dryblending the powder coatings, to color-match the powder coatings, capable of reproducing colors which could not be reproduced in conventional powder coatings, for example, light colors, transparent colors, or brilliant colors.Type: GrantFiled: April 7, 1999Date of Patent: November 14, 2000Assignee: Kyocera Mita CorporationInventors: Takayuki Itakura, Norio Horikami
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Patent number: 6143402Abstract: Pigment preparations in pellet form wherein the organic pigment particles are coated with a mixture of a resin (A) having an acid number .gtoreq.200 and a resin (B) having an acid number <200 are useful for pigmenting printing inks.Type: GrantFiled: August 13, 1998Date of Patent: November 7, 2000Assignee: BASF AktiengesellschaftInventor: Hansulrich Reisacher
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Patent number: 6143067Abstract: A pigment composition, which comprises70-95% by weight of a pigment of formula ##STR1## 5-15% by weight of at least one C.sub.2 -C.sub.16 alkylenedicarboxylic acid-di-C.sub.1 -C.sub.12 alkyl ester; and0-15% by weight of at least one C.sub.12 -C.sub.24 fatty acid ester of polyhydroxy-C.sub.2 -C.sub.12 alkane;each based on the total weight of the pigment composition.Also claimed is a process for the preparation of this pigment composition and its use for mass-colouring in particular high molecular weight organic materials which can be moulded as plastics or melts.The products obtained are distinguished by an improved low shear dispersibility effect at high tinctorial strength.Type: GrantFiled: January 13, 1999Date of Patent: November 7, 2000Assignee: Ciba Specialty Chemicals CorporationInventors: Philippe Bugnon, Fritz Herren, Michel Fran.cedilla.ois, Alastair McAlpine Marr
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Patent number: 6139613Abstract: The present invention describes a novel method for the formation of optically variant pigments by the coating of layers onto a substrate and the fracturing of the coated material into pigment particles after the coating operation and novel pigments produced thereby. Coating techniques such as slot die coating (especially multiple slot die coating), spin coating, meniscus coating, curtain coating, and the like have proven successful. It is preferred that multiple die slots are used to coat multiple layers in a single pass so that manufacturing costs are minimized. The use of these coating techniques, and especially multiple die slot coating, allows for many layers to be coated, with from three to fifty layers being readily possible. This offers a relatively inexpensive way of coating out a wide variety of layers, and especially the pigment materials needed for optically variable pigments, quickly and with high quality.Type: GrantFiled: August 21, 1998Date of Patent: October 31, 2000Assignee: Aveka, Inc.Inventors: William A. Hendrickson, James J. Marti
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Patent number: 6136087Abstract: A crystal growth inhibitor for azo pigments is disclosed. The crystal growth inhibitor comprises: (1) one or more sulfonated or carboxylated amines, and (2) one or more coupling components selected from the group consisting of acetoacetanilides, naphthanilides, pyrazalones and benzamidazoles; the coupling component being bonded to the sulfonated or carboxylated amines. The crystal growth inhibitor can be produced separately and added to the coupling component prior to the coupling reaction, or it can be formed in situ with the pigment. Preferably, an improved pigment according to the invention includes 2% to 5% by weight of the crystal growth inhibitor. Monoazo pigments including the crystal growth inhibitor have been shown to have greatly improved gloss, transparency and tinctorial strength.Type: GrantFiled: November 4, 1998Date of Patent: October 24, 2000Assignee: Uhlich Color Company, Inc.Inventor: Sain D. Kapoor
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Patent number: 6136081Abstract: An aqueous ink Jet ink composition comprising a humectant in an amount of up to about 70% by weight of the composition, and from about 0.Type: GrantFiled: August 10, 1999Date of Patent: October 24, 2000Assignee: Eastman Kodak CompanyInventors: Raymond P. Scaringe, Steven Evans, Richard C. VanHanehem
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Patent number: 6132501Abstract: An aqueous ink jet ink composition comprising a humectant in an amount of up to about 70% by weight of the composition, and from about 0.Type: GrantFiled: August 10, 1999Date of Patent: October 17, 2000Assignee: Eastman Kodak CompanyInventors: Raymond P. Scaringe, Steven Evans, Richard C. VanHanehem
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Patent number: 6123763Abstract: A colorless or only slightly colored pigment dispersing agent which is feasible as a pigment dispersing agent for pigments having various hues and has the general formula (1), ##STR1## wherein R.sub.1, R.sub.2, X.sub.1, Y.sub.1, Y.sub.2, k and h are as defined in claim 1.Type: GrantFiled: January 20, 1999Date of Patent: September 26, 2000Assignee: Toyo Ink Mfg. Co., Ltd.Inventors: Takashi Kamikubo, Yuuji Hirasawa, Toru Omura
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Patent number: 6123761Abstract: A pigment composition comprising pigment and an amido phthalocyanine compound having the general formula I:MPc--(CONR.sup.1 R.sup.2).sub.n Iwherein which Pc is a phthalocyanine ring which is optionally further substituted by up to an average of one chlorine or bromine atom or of a sulphonic acid; M is hydrogen or a metal such as Mg, Al, Ni, Fe, Zn, Pb, Sn or Cu: n is a number ranging from 0.1 to 4.0; R.sup.1 and R.sup.2 are independently selected from hydrogen, C.sub.1 -C.sub.20 alkyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.7 -C.sub.12 aralkyl, C.sub.6 -C.sub.10 aryl, C.sub.4 -C.sub.6 alkyl amino alkyl, C.sub.2 -C.sub.20 aliphatic amine, C.sub.2 -C.sub.20 aliphatic amine acid salt, C.sub.2 -C.sub.20 alcohol, polyoxyalkylene, polyoxyalkylene amine.Type: GrantFiled: August 18, 1999Date of Patent: September 26, 2000Assignee: Ciba Specialty Chemicals CorporationInventor: Thomas Healy
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Patent number: 6120596Abstract: Surface treated pigment particles made by contacting a dispersion of pigment particles with a halosilane or organohalosilane, elevating the temperature to form a siloxane on the surface of the particles and recovering the surface treated particles as a presscake or as dry particles.Type: GrantFiled: January 23, 1997Date of Patent: September 19, 2000Assignee: Marconi Data Systems Inc.Inventor: Yoshikazu Mizobuchi
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Patent number: 6113683Abstract: Colored pearlescent pigment comprising a pearlescent pigment and a second pigment, characterized in using an adhesion promotor for the mutual adsorbance of the pearlescent pigment and the second pigment, whereby the adhesion promotor is a polymer containing hydroxy groups, a process for its preparation, its use and a colored high molecular weight material.Type: GrantFiled: November 10, 1998Date of Patent: September 5, 2000Assignee: Ciba Specialty Chemicals CorporationInventors: Fritz Herren, Kimiya Takeshita, Michel Fran.cedilla.ois
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Patent number: 6103006Abstract: Thermoplastic, non-water soluble, fluorescent pigments having improved lightfastness are provided which are suitable for coloring a variety of materials including plastics, particularly polyolefins, as well as paints, inks and textiles. The pigments of the present invention referred to herein as the "light fast pigments" demonstrate good color, migration resistance, heat stability, water insolubility, friability and resistance to plateout. The light fast pigments of the present invention have several embodiments, the polyamide embodiment, polyamide ester embodiment and the polyester embodiment. The pigments of the present invention comprises a polymer which comprises polymerized units of fluorescent dye and polymerized monomers such as for example dicarboxylicacids, polycarboxylicacids, diamines, polyamines, alkanolamines, carboxyalcohols, carboxyamines and difunctional alcohols, and/or polyhydric alcohols.Type: GrantFiled: January 28, 1998Date of Patent: August 15, 2000Assignee: Day-Glo Color CorporationInventor: Thomas C. DiPietro
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Patent number: 6102996Abstract: A pigment-based ink composition is provided which employs a pigment precursor that is soluble in a non-aqueous solvent. Preferably, the ink composition is in the form of an aqueous, two-phase system wherein the pigment precursor is solubilized in a high boiling, water-insoluble organic compound. Optionally, a second high boiling compound miscible with both aqueous and organic phases and at least one amphiphile are also present.Type: GrantFiled: December 12, 1997Date of Patent: August 15, 2000Assignee: Hewlett-Packard CompanyInventor: Dennis P Parazak
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N,N'-dimethylperylene-3,4,9,10-tetracarboxylic acid diimide pigments suitable for water-based paints
Patent number: 6099636Abstract: A N,N'-dimethylperylene-3,4,9,10-tetracarboxylic diimide pigment suitable for aqueous basecoats is obtainable by coating the diimide, suspended in an aqueous medium, with a carboxyl-carrying resin in the presence of 3,4-dicarboximidoperylene-9-sulfonic acid or salts thereof and with a C.sub.8 -C.sub.8 -alkyl- or-alkenylamine, isolating and drying the coated dimide and then subjecting it to dry milling.Type: GrantFiled: July 16, 1998Date of Patent: August 8, 2000Assignee: BASF AktiengesellschaftInventors: Georg Henning, Peter Blaschka, Arno Bohm -
Patent number: 6099635Abstract: This invention provides a process for forming an acetoacetarylide-based pigment, comprising: (a) reacting a diketene with an amine to form an acetoacetarylide slurry; (b) separating the acetoacetarylide as a solid from the acetoacetarylide slurry; (c) adding the acetoacetarylide solid to a homogenizer; (d) homogenizing the acetoacetarylide in the presence of water and one or more additives to form an acetoacetarylide slurry; (e) pumping the acetoacetarylide slurry to a reaction tank; (f) adding an alkali or alkaline metal base to the slurry; (g) adding an acid to form a precipitate of the acetoacetarylide; and (h) reacting the precipitate with an azo compound, thereby forming a pigment. This invention also includes the pigments and intermediates thereto formed by the above processes.Type: GrantFiled: April 9, 1999Date of Patent: August 8, 2000Assignee: Lonza AGInventors: Rebecca Lee Rosas, James Michael McCormick