Abstract: Pigment composition comprising an organic pigment and a combination of at least two normally water-soluble coloured compounds (dyes) of opposing charge, i.e. of at least one anionic and one cationic dye are provided. The compositions impart improved rheology on non-aqueous pigment based printing inks and paints.
Type:
Grant
Filed:
April 24, 2003
Date of Patent:
July 11, 2006
Assignee:
Ciba Specialty Chemicals Corporation
Inventors:
Stephen John Coughlin, Iain Frank Fraser, Thomas Healy, Stuart Cook Niven
Abstract: A pigment composition obtainable by dry-milling an organic pigment in the presence of a resin for a printing ink, the resin being composed of a synthetic resin for a printing ink in an amount of 10 to 80 parts by weight per 100 parts by weight of the organic pigment and an aliphatic hydrocarbon resin which is extracted from gilsonite and has a softening point of 120 to 125° C. in an amount of 0.1 to 5 parts by weight per 100 parts by weight of the organic pigment.
Abstract: A coloring agent for use in toners which comprises coloring particles modified with a surface modifier having in one molecule a hydrophilic moiety, a hydrophobic moiety, and a reactive moiety between the hydrophilic moiety and the hydrophobic moiety. Also disclosed is a toner comprising toner particles containing at least a binder resin and a coloring agent comprising the above surface-modified coloring particles.
Abstract: Organic solid solution pigments are prepared and conditioned by treating a mixture of their components, after synthesis but preferably without or with only partial drying, in a mixture of from 0 to 30% by weight of an organic liquid having a dipole moment ? of 2.8–6.0·10?18 .esu (2.8 to 6.0 debye units) and from 70 to 100% by weight of water in an agitated media pearl mill having a specific power density of at most 2.0 kj·s?1 per liter of grinding space. Drying the starting components is especially suitable in the case of only slightly agglomerating, easy to wet pigments of specific surface area from 1 to 25 m2/g. The method gives excellent results, and is flexible and also much simpler than known methods.
Abstract: The present invention relates to a method of producing a low-dust pigment composition, which comprises suspending a filter cake obtained from preparation of the pigment, or a solid pigment, in water, adding thereto from 0.1 to 6.0% by weight, based On the weight of the pigment composition, of an amphoteric surfactant and, where appropriate, further adjuvants, and then drying the aqueous suspension to form granules, to the pigment composition obtainable according to that method, and to the use thereof in the production of colored plastics or colored polymeric particles.
Abstract: An initial solids mixture for a later organic coating, such as pigmented coatings, films, priming coats, etc., e.g., for a coil coating method in which an initial solids mixture is applied to a substrate, e.g., broad strip, and this is thereby pre-coated, wherein the initial solids mixture includes, as additive particles, boron carbide and/or silicon carbide and/or compounds of transition elements or lanthanides, the electrical conductivity of which is selected to be in the metallic range (?>102 1/?cm and ?<107 1/?cm), during the later coating, the additive particles have a continuous physical connection in at least one spatial direction.
Abstract: Inorganic pigments, having deposited on the pigment surface at least one alkenyl- or alkyl-substituted succinic anhydride and at least one organic polyol, possess improved processibility and dispersibility in thermoplastic materials, and impart improved properties to thermoplastic compositions containing said surface-treated pigments.
Abstract: The invention relates to aqueous colorant preparations containing A) between 0.1 and 50 wt. % of at least one organic and/or inorganic pigment and/or at least one organic colorant. B) between 0.01 and 80 wt. % of at least one naphthol-oxyalkylate sulfopropyl ether, one alkanol-oxyalkylate sulfopropyl ether or one alkylphenol-oxyalkylate sulfopropyl ether. C) between 0 and 30 wt. % of at least one organic solvent. D) between 0 and 20 wt. % of other standard derivatives and E) between 10 and 90 wt % of water, respectively in relation to the total weight (100%) of the colorant preparation. The colorant preparation is used, for example, in printing inks, especially ink jet printing inks.
Type:
Grant
Filed:
June 21, 2002
Date of Patent:
March 7, 2006
Assignee:
Clariant GmbH
Inventors:
Rudolf Randler, Ulrike Rohr, Josef Geisenberger, Ruediger Baur, Hans-Tobias Macholdt, Heidemarie Menzel
Abstract: The present invention discloses an aqueous phenolates-containing liquid formulation having a solidification point of less than or equal to ?10° C. which is characterized by comprising the following components: a) 50–80% by wt. of one or more phenolates; b) 0.1–10% by wt. of at least one crystallization inhibitor; and water and optionally other components forming the balance.
Abstract: Titanium dioxide-calcium carbonate composite particles capable of realizing characteristic properties inherent in titanium dioxide such as a high opacity, a process for producing the same, and a complex composition or complex incorporated with the same are provided. The composite particles were prepared by adding titanium dioxide particles having an average particle diameter of 0.1 to 0.5 ?m in a carbonation step, typically a step of introducing a gaseous mixture of carbon dioxide and air into a calcium hydroxide slurry with stirring, to conduct a carbonation, and continuing the reaction till pH of the slurry becomes 7 by continuous introduction of the gaseous mixture. Moreover, by incorporating the formed composite particles, complexes such as coatings and paints for paper making or composite materials such as paper, plastic molded materials, and rubber molded materials are produced.
Type:
Grant
Filed:
July 3, 2001
Date of Patent:
January 31, 2006
Assignee:
Nittetsu Mining Co., Ltd.
Inventors:
Katsuyuki Tanabe, Kouhei Mitsuhashi, Takehiko Yoshida
Abstract: A monoazo lake pigment composition containing a monoazo lake pigment obtained from a laked pigment aqueous slurry prepared by conducting coupling of a diazo component obtained by diazotizing an aromatic amine having a soluble group and a coupler component and conducting laking after or simultaneously with the coupling, wherein the laking is carried out in the presence of a water-soluble acrylic polymer in an amount of 0.1 to 40 parts by weight per 100 parts of the above coupler component, and a gravure ink containing the above pigment composition and a gravure ink vehicle.
Abstract: Paper coating slips whose additives comprise addition polymers or copolymers containing N-vinylformamide in (co)polymerized form, and their use.
Type:
Grant
Filed:
November 2, 2001
Date of Patent:
November 29, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Friedrich Linhart, Bernd Dirks, Heinrich Ullrich, Thierry Blum, Norbert Mahr, Stefan Frenzel, Martin Wendker
Abstract: Inorganic pigments treated with at least one amide of a fatty acid and an aliphatic amine possess improved processibility and dispersibility in thermoplastic materials, and impart improved properties to thermoplastic compositions containing said surface-treated pigments.
Abstract: A pigment dispersion liquid comprises pigment particles dispersed in a dispersion medium, the difference (D90?D10) between D90 and D10 being not more than 25 nm, wherein D90 and D10 represent the primary particle size that the pigment particles having a primary particle size up to and including D90 account for 90% by number of the total pigment particles, and the particle size that the pigment particles having a primary particle size up to and including D10 account for 10% by number of the total pigment particles, respectively, in the integral of the primary particle size distribution function dG=f(D)dD of the pigment particles in which G is a particle number (%) and D is a primary particle size (nm).
Abstract: Inorganic pigments treated with one or more of the ?,?-dialkyl substituted linear or branched carboxylic acids and the salts thereof possess improved processibility and dispersibility in thermoplastic materials, and impart improved properties to thermoplastic compositions containing said surface-treated pigments.
Abstract: The present invention relates to methods of preparing modified organic colorant dispersions comprising the step of combining, in any order, i) an organic colorant; ii) an hydroxide reagent; and iii) an aqueous medium, to form a modified organic colorant dispersion. The methods further comprises a particle size reduction step. These steps can occur in either order. The organic colorant comprises at least one organic species having at least one carboxylic acid group. Modified organic colorants and uses of these modified organic colorants, including inkjet ink compositions, are also disclosed.
Abstract: The invention deals with thermoplastic compositions comprising at least one transparent or translucent thermoplastic material and a pigment wherein the thermoplastic composition comprises at least one cholesteric liquid crystal polymeric plate shaped pigment in a quantity of 0.55 or less parts by weight per 100 parts by weight of the transparent or translucent thermoplastic material.
Abstract: The present invention relates to methods of preparing modified organic colorant dispersions comprising the step of combining, in any order, i) an organic colorant; ii) an hydroxide reagent; and iii) an aqueous medium, to form a modified organic colorant dispersion. The methods further comprises a particle size reduction step. These steps can occur in either order. The organic colorant comprises at least one organic species having at least one ester group. Modified organic colorants and inkjet ink compositions are also disclosed.
Abstract: The present invention provides a dye loaded zeolite material comprising: a) at least one zeolite crystal having straight through uniform channels each having a channel axis parallel to, and a channel width transverse to, a c-axis of crystal unit cells; b) closure molecules having an elongated shape and consisting of a head moiety and a tail moiety, the tail moiety having a longitudinal extension of more than a dimension of the crystal unit cells along the c-axis and the head moiety having a lateral extension that is larger than said channel width and will prevent said head moiety from penetrating into a channel; c) a channel being terminated, in generally plug-like manner, at least at one end thereof located at a surface of the zeolite crystal by a closure molecule hose tail moiety penetrates into said chanel and whose head moiety substantially occludes said channel end while projecting over said surface; and d) an essentially linear arrangement of luminescent dye molecules enclosed within a terminated channe
Abstract: A pigment's etheramine sulfonic acid salt is described. Also described is a method for enhancing the performance of a pigment composition containing an organic pigment, comprising enhancing the dispersion of said pigment by adding to 100 parts of said pigment about 1 to 40 parts of a pigment's etheramine sulfonic acid salt.
Type:
Grant
Filed:
April 14, 2003
Date of Patent:
August 9, 2005
Assignee:
Sun Chemical Corporation
Inventors:
Kevin A. Arthur, George H. Robertson, George McLaren, Stanislav G. Vilner, Ronald R. Forbes
Abstract: A process for the preparation of organic pigments with enhanced fluorescence, which process comprises treating said pigments with a surfactant, and to the fluorescent organic pigments obtained by said process. The pigments according to the present invention can be used in marking applications, wherein durable fluorescence is required.
Type:
Grant
Filed:
November 8, 2001
Date of Patent:
August 2, 2005
Assignee:
Ciba Specialty Chemicals Corporation
Inventors:
Iain Frank Fraser, Sharon Kathleen Wilson, Ian Alexander Macpherson
Abstract: A number of stable mixtures are disclosed containing specific combinations and levels of extender pigments and thickeners. These stable mixtures may be employed, inter alia, as a mixture in a method of making paints using prepaints or as a conventional component in a coating, such as a paint, or other end-use where opacifying pigments are employed.
Type:
Grant
Filed:
August 8, 2002
Date of Patent:
July 26, 2005
Assignee:
Rohm & Haas Company
Inventors:
Edwin Hugh Nungesser, Jerry William Washel, John Michael Friel
Abstract: An embodiment of the invention relates to an aqueous dispersion containing pigment-containing particles. The dispersion is an aqueous dispersion comprising particles containing a water-insoluble colorant dispersed in a water-containing medium, wherein the light-scattering intensity of the dispersion is at most 30,000 cps when the absorbance peak value of the dispersion in a visible region is regarded as 1.
Abstract: The invention relates to pigment dispersants of the formula (I), and to pigment preparations including at least one organic pigment and at least one pigment disperant of the formula (I): wherein Q1, R1, R2, E+, G+, s and n are defined in the specification.
Type:
Grant
Filed:
January 31, 2002
Date of Patent:
July 19, 2005
Assignee:
Clariant GmbH
Inventors:
Joachim Weber, Gerhard Wilker, Klaus Brychcy, Erwin Dietz
Abstract: Processes for preparing modified pigments are described. In one embodiment, the process comprises the step of combining, in any order, a pigment having attached an electrophilic group and a thiol reagent comprising at least one —SH group and at least two ionic or ionizable groups. In a second embodiment, the process comprises the step of combining, in any order, a pigment having attached an electrophilic group and a thiopolymer comprising at least one —H group. Modified pigments are also described.
Abstract: The present invention relates to a process for preparing a polymer-modified pigment comprising the step of: combining, in any order, at least one pigment having attached at least one nucleophilic group, at least one polymer comprising at least one carboxylic acid group or salt thereof, and at least one coupling agent. At least one mediator compound may also be used. The modified pigments can be used in applications such as inkjet ink applications.
Abstract: Cationically modified white pigments (W) in particulate form, essentially consisting of a particulate inorganic white pigment (M) of a particle size in the range of 0,1 to 40 ?m and an applied water soluble, cationic, crosslinked polymer (PA) containing quaternary ammonium groups in salt form, obtainable by reaction of epichlorohydrin or of epichlorohydrin derivatives or precursors with amines, under conditions leading to at least partial crosslinking, optionally in combination with an anionic optical brightener (B) and where the molar ratio of (B) to (PA) is such that the number of cationic charges of the total polymer (PA) is higher than the number of anionic charges of the total anionic optical brightener (B), are surprisingly useful as cationic white pigments in various fields of technique, especially in papermaking.
Type:
Grant
Filed:
December 19, 2000
Date of Patent:
June 28, 2005
Assignee:
Clariant Finance (BVI) Limited
Inventors:
John Martin Farrar, Andrew Clive Jackson, Alec Stewart Tindal
Abstract: The invention relates to a process for preparing pigments, which comprises subjecting a crude pigment or mixture of crude pigments and a crystalline inorganic salt or mixture of crystalline inorganic salts together, essentially in the absence of other constituents, to the action of a rotor having a tangential speed of at least 10 m/s, so that a temperature of at least 80° C. is attained by means of friction effects; and subsequently kneading the product of this treatment with an organic liquid, during which it is possible if desired to add additional substances selected from the group consisting of inorganic salts, inert additives and colorant. These pigments and their use in polymers, printing inks and colours filters are also claimed. The invention in particular relates to a novel pigment form of Pigment Violet 23 obtained by above-mentioned process and having higher colour strength and colour saturation as well as excellent other applications properties in particular in printing inks.
Type:
Grant
Filed:
December 4, 2002
Date of Patent:
June 28, 2005
Assignee:
CIBA Specialty Chemicals Corp.
Inventors:
Yves Grandidier, Albert Riegler, Klaus Ruf, Urs Schlatter, Takashi Deno
Abstract: A mixture of an organic nanosize pigment comprising of from 50 to 99% by weight of the nanosize pigment and 1 to 50% by weight based of a low molecular weight naphthalene sulfonic acid formaldehyde polymer and its use as a particle growth and crystal phase director for the preparation of a direct pigmentary organic pigment or in pigment finishing.
Abstract: The present invention relates to surface-treated organic pigments, to a process for their preparation and to their use in colouring a high molecular weight organic material. Compared with untreated pigments, the surface-treated pigments exhibit better rheological properties and/or no warping in the pigmenting of partially crystalline plastics.
Abstract: Organic pigments are conditioned by treating them, after synthesis but preferably without or with only partial drying, in a mixture of from 1 to 30% by weight of a neutral, polar liquid having a dipole moment ? of 2.8-6.0? 10?18 esu (2.8 to 6.0 debye units) and from 70 to 99% by weight of water in an agitated media pearl mill having a specific power density of at most 2.0 kJs??1 per liter of grinding space. Drying is especially suitable in the case of only slightly agglomerating, easy to wet pigments of specific surface area from 1 to 25 m2/g. The method gives excellent results, and is flexible and also much simpler than known methods.
Type:
Grant
Filed:
January 31, 2002
Date of Patent:
May 10, 2005
Assignee:
Ciba Specialty Chemicals Corporation
Inventors:
Gerhard Giger, Jürgen Beyrich, Philippe Bugnon, Marc Maurer
Abstract: Pigment preparations comprising a) at least one pigment, b) at least one polyethyleneimine which is alkoxylated, especially ethoxylated and propoxylated and/or butoxylated, and c) at least one condensation product based on A) sulphonated aromatics, B) aldehydes and/or ketones and optionally C) one or more compounds selected from the group consisting of nonsulphonated aromatics, urea and urea derivatives.
Type:
Grant
Filed:
March 3, 2004
Date of Patent:
April 19, 2005
Assignee:
Bayer Chemicals AG
Inventors:
Udo Herrmann, Dirk Pfützenreuter, Josef Witt, Hans-Jürgen Hartrumpf
Abstract: Rylene derivatives of the general formula I where the variables have the following meanings: R is hydrogen or substituted or unsubstituted C1-C30-alkyl, aryl or hetaryl; R1 is hydrogen or bromine; R2 is hydrogen or C1-C6-alkyl; R3 is hydrogen, C1-C18-alkyl or substituted or unsubstituted aryl or hetaryl; and n is 2 or 3.
Type:
Grant
Filed:
February 14, 2002
Date of Patent:
April 12, 2005
Assignees:
BASF Aktiengesellschaft, Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.
Inventors:
Matthias Krieger, Arno Böhm, Erik Reuther, Klaus Müllen
Abstract: A method of attaching one or more organic groups onto a particle is described which involves reacting at least one radical with at least one particle wherein the radical is generated from the interaction of at least one transition metal compound with at least one organo-halide compound in the presence of one or more particles capable of radical capture. Variations of this method are also described.
Abstract: The invention relates to a pigment dispersion comprising: a condensate of or a salt between a polyallylamine and a polyester having a free carboxylic acid or the salt; a pigment derivative represented by the following general formula (1); a pigment; and an organic solvent,
Abstract: The present invention relates to a method of producing a granular formulation of colorants soluble in plastics, which method comprises suspending in water a filter cake obtained from preparation of the colorant, adding thereto from 0.1 to 5.0% by weight, calculated with respect to the weight of colorant, of a polyvinylpyrrolidone or of a sodium lauryl sulfate and, where appropriate, further adjuvants, and then drying the aqueous suspension to form granules, to the granular formulations obtainable according to that method, and to the use thereof in the production of colored plastics or colored polymeric particles.
Abstract: Processes for preparing modified pigments are described. In one embodiment, the process comprises the step of combining, in any order, a pigment having attached an electrophilic group and a thiol reagent comprising at least one —SH group and at least two ionic or ionizable groups. In a second embodiment, the process comprises the step of combining, in any order, a pigment having attached an electrophilic group and a thiopolymer comprising at least one —SH group. Modified pigments are also described.
Abstract: The invention concerns the use of hydrosoluble homopolymers and/or copolymers of acrylic/or methacrylic acid with one or more acrylic, vinyl or allyl monomers as an aid to the grinding of mineral particles in aqueous suspension, providing them by their use particular optical properties.
Type:
Application
Filed:
June 18, 2003
Publication date:
December 16, 2004
Inventors:
Xueping Qiu, Jacques Mongoin, Christian Jacquemet
Abstract: The invention relates to passivated optically variable pigment, a method of preparing said passivated optically variable pigment, an ink composition comprising said passivated optically variable pigment, the use of said ink composition, and a document carrying a marking made with said ink composition.
Type:
Application
Filed:
March 12, 2004
Publication date:
December 9, 2004
Inventors:
Aline Vuarnoz, Olivier Amrein, Patrick Veya
Abstract: A metal colloid luster color material having an unique appearance without using any organic color material that is deficient in weather resistance as the coloring component is obtained.
Abstract: The invention relates to a compound of the 1-aminoanthraquinone, anthanthrone, anthrapyrimidine, quinacridone, dioxazine, diketopyrrolopyrrole, flavanthrone, indanthrone, isoindolinone, isoviolanthrone, perinone, perylene, phthalocyanine, pyranthrone or thioindigo series, which compound has one or more sulfonate groups of formula (I) wherein R1 is methyl or ethyl, R2 is C6-C24alkyl, C6-C24alkenyl or C7-C24aralkyl, R3 and R4 are each independently of the other a chain consisting 1, 2 or 3 members, each member independently of any other(s) being (CH2))2O—, —(CH2)3O—, CH(CH3)CH2O—, —CH2CH(CH3)—O— or —CH2CH(CH2O—)O—and the chains being terminated by H, CH3, C2H5 ?or C(═O)CH3, m is a number from 0.3 to 1.0 and n is number from 0 to (1.0−m), the compound being suitable for use as a pigment dispersant and rheology improver.
Abstract: The invention relates to a compound of the 1-aminoanthraquinone, anthanthrone, anthrapyrimidine, quinacridone, dioxazine, diketopyrrolopyrrole, flavanthrone, indanthrone, isoindolinone, isoviolanthrone, perinone, perylene, phthalocyanine, pyranthrone or thioindigo series, which compound has one or more sulfonate groups of formula (1) wherein R1 is methyl or ethyl, R2, R3? and R4 are each independently of the others C6-C24alkyl or C6-C24alkenyl, m is a number from 0.3 to 1.0 and n is a number from 0 to (1.0 m), the compound being suitable for use as a pigment dispersant and rheology improver. Also claimed are modified pigments having that compound on their surface, and also pigment compositions and dispersions comprising that compound.
Abstract: An aqueous pigment dispersion for ink jet having a pigment dispersed, characterized by containing a water-soluble resin and a resin having a urethane bond and/or an amide bond.
Abstract: Nonaqueous compositions formulated for spray application to a substrate wherein the composition contains a foam-reducing quantity of at least one base-catalyzed reaction product comprising the following reactants:
Type:
Application
Filed:
January 29, 2004
Publication date:
December 2, 2004
Inventors:
David W. Brown, Kenneth Breindel, Michael S. Wiggins, Ronald W. Broadbent
Abstract: The invention relates to coloring pigment granulates and a method for producing the same. The aim of the invention is to provide a granulate and a method for economically producing the same. The granulate disintegrates very quickly once added to a building material that is to be colored. To this end, the granulates are comprised of granulate cores which do not contain binding agents, which have a granular size ranging from 0.1 to 8 mm and which are enclosed by an enveloping layer made of a material that can be broken down. In addition, the granulates have a moisture content <30% and the granulates that do not contain binding agents are produced in a pregranulator, are compacted immediately after granulation and are subsequently subjected to a screening process. Lastly, the useful granular fraction that has been separated out during the screening process is enclosed with an enveloping material.
Type:
Grant
Filed:
January 4, 2002
Date of Patent:
November 30, 2004
Assignee:
Rhein-Chemotechnik GmbH Gesellschaft für
Chemisch-Technishche Erzeugnisse
Abstract: The present disclosure provides a decorative stain and/or coating composition which can be applied, using conventional, low-cost techniques to concrete, masonry or like material surfaces in order to provide an desired aesthetic appearance to such surfaces. The methods of use taught herein do not require expensive and laborious pre-treatment, such as cleaning and restoration, as well as handling/disposal concerns typically associated with acid-utilizing stains and decorative coatings and sealers.
Abstract: A cementitious composition is provided that is composed of hydraulic cement and a liquid coloring suspension. The liquid coloring suspension which contains polycarboxylate dispersant and pigment provides the cementitious composition with increased dispersion of pigment particles, lowered water content, and improved coloration over that observed in the prior art. Also, a liquid coloring suspension for cementitious compositions is provided which contains polycarboxylate dispersant, pigment, and thixotropic additive. The liquid coloring suspension increases the color of cementitious compositions, reduces the water content and has long term stability in that it does not become increasingly viscous over time.
Type:
Application
Filed:
March 26, 2004
Publication date:
November 25, 2004
Applicants:
Construction Research & Technology GmbH, L. M. Scofield Company
Inventors:
Nancy A. Dulzer, Jeffrey L. Matrician, Martin E. Wild
Abstract: The present invention provides a novel method to produce grade road base material using recycled oilfield waste, called “oil and gas waste,” more specifically, drilling waste and aggregate and a novel road base material. Hydration and mixing of the waste materials along with a binder, will achieve an irreversible pozzolanic chemical reaction necessary for stabilization into a road base. An asphalt emulsifier may be included in the binder to manufacture asphalt stabilized road base. The entire method is a cold batch process.