Abstract: Pigment formulations in granule form, comprising (A) at least two different pigments, (B) at least one thermoplastic polymer, and if desired (C) a dispersant, obtainable by
Type:
Application
Filed:
May 15, 2003
Publication date:
March 4, 2004
Inventors:
Gunter Etzrodt, Achim Grefenstein, Wieland Jenet, Robert Bayer, Reinhold Rieger
Abstract: The invention relates to pigment preparations containing (a) at least one organic or inorganic pigment; (b) at least one cyclic imide of general formula (1) wherein R1 represents a linear-chain, branched or cyclic aliphatic radical having 10 to 30—preferably 12 to 25—carbon atoms, or an alkenyl radical having 10 to 30—preferably 12 to 25—carbon atoms, the aforementioned radicals being able to be substituted by at least one, e.g. 2, 3, 4 or 5, substituent from the group consisting of C1-C6-alkyl, C1-C6-alkoxy, C6-C10-aryl, hydroxy, carboxy, and sulfo, R2, R3, R4 and R5 are the same or different and represent hydrogen, C1-C10-alkyl, C1-C10-alkoxy, halogen, OR6, NR6R7, —COOR6, —CONR6R7, —NR6—COR7, SO2NR6R7, —SO3M, —NO2, —CN or CF3, R6 and R7 representing H or an alkyl radical having 1 to 10 C atoms and M representing an equivalent of a cation having a valency of 1 to 3; and (c) optionally further standard additives.
Type:
Application
Filed:
April 24, 2003
Publication date:
March 4, 2004
Inventors:
Martin Alexander Winter, Andreas Harz, Hans Joachim Metz
Abstract: The present invention relates to a process for preparing a polymer-modified pigment comprising the step of: combining, in any order, at least one pigment having attached at least one nucleophilic group, at least one polymer comprising at least one carboxylic acid group or salt thereof, and at least one coupling agent. At least one mediator compound may also be used. The modified pigments can be used in applications such as inkjet ink applications.
Abstract: The invention relates to pigment preparations that contain A) at least one organic or inorganic pigment, and B) at least one ethoxylated and propoxylated and/or butoxylated polyethylenimine.
Type:
Application
Filed:
November 25, 2002
Publication date:
February 26, 2004
Inventors:
Oliver Borzyk, Jurgen Huff, Manfred Mielke, Rudiger Sens
Abstract: The present invention employs ester compounds such as butyl acetate, oleyl acetate and the like that are typically employed in solvents and other applications as an agent for improving the fluidity of a pigment dispersion liquid. The pigment composition of the present invention includes a pigment and the aforementioned ester compound as essential components. A pigment dispersion liquid in which the present invention's pigment composition is dispersed in a solvent or the like demonstrates a great improvement in pigment dispersibility and dispersion liquid flow properties. When the present invention's pigment composition and pigment dispersion liquid are employed in a color filter, it is possible to obtain a uniform paint film having high contrast.
Abstract: Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems.
Type:
Application
Filed:
January 13, 2003
Publication date:
January 22, 2004
Inventors:
Jeffrey A. Sturgill, Andrew Wells Phelps
Abstract: Processes for preparing modified pigments are described. In one embodiment, the process comprises the step of combining, in any order, a pigment having attached an electrophilic group and a thiol reagent comprising at least one —SH group and at least two ionic or ionizable groups. In a second embodiment, the process comprises the step of combining, in any order, a pigment having attached an electrophilic group and a thiopolymer comprising at least one —H group. Modified pigments are also described.
Abstract: A method of attaching one or more organic groups onto a particle is described which involves reacting at least one radical with at least one particle wherein the radical is generated from the interaction of at least one transition metal compound with at least one organo-halide compound in the presence of one or more particles capable of radical capture. Variations of this method are also described.
Abstract: An embodiment of the invention relates to an aqueous dispersion containing pigment-containing particles. The dispersion is an aqueous dispersion comprising particles containing a water-insoluble colorant dispersed in a water-containing medium, wherein the light-scattering intensity of the dispersion is at most 30,000 cps when the absorbance peak value of the dispersion in a visible region is regarded as 1.
Abstract: An aqueous ink-jet ink composition for MICR applications is provided comprising a metal oxide pre-dispersion combined with an aqueous ink-jet ink composition, wherein the metal oxide pre-dispersion contains metal oxide pigment or particles of a very small particle size, about 0.5&mgr; or less, and exhibiting high remanence of at least 20 emu/g. The metal oxide particles may be coated with a hydrophilic coating, and the pre-dispersion may contain at least one surfactant to aid in the dispersion of the metal oxide particles.
Type:
Application
Filed:
July 1, 2002
Publication date:
January 8, 2004
Applicant:
Nu-kote International, Inc.
Inventors:
Michael J. McElligott, Donald E. Snyder
Abstract: A coating agent for a base for ink-jet printing comprises an alumina dispersion containing dispersed alumina and aluminium nitrate dissolved in an aqueous dispersing medium, and a binder. This coating agent and the coated base material are free of irritating odor, contain alumina well dispersed therein, and provide printed images on the inkjet-printing materials, which images are excellent in the color density, resistance to water, resistance to light and color definition.
Abstract: A black colorant for ink-jet printing ink, has an average particle diameter of 0.001 to 0.15 &mgr;m, and comprises:
extender pigments as core particles;
a gluing agent-coating layer formed on at least a part or the surface of said core particles; and
a black pigment coat uniformly formed on at least a part of said gluing agent-coating layer.
The black colorant for ink-jet printing ink exhibits not only a high blackness and an excellent tinting strength, but also excellent dispersibility and light resistance in spite of fine particles.
Abstract: Corrosion-inhibiting pigments based on manganese are described that contain a heptavalent (permanganate), hexavalent (manganate), or pentavalent (manganate) compound. An inorganic or organic material is used with the heptavalent, hexavalent, or pentavalent manganese ion to form a compound that is sparingly soluble in water. Specific solubility control cations are chosen to control the release rate of heptavalent, hexavalent, or pentavalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Solubility control agents may also modify the processing and handling characteristics of the formed powders. Many permanganate or manganate compounds are presented that can equal the performance of conventional hexavalent chromium systems. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure.
Type:
Application
Filed:
January 13, 2003
Publication date:
December 4, 2003
Inventors:
Jeffrey A. Sturgill, Andrew Wells Phelps
Abstract: A particulate metal oxide having a mean length of the primary particles in the range from 50 to 90 nm, the mean width of the primary particles in the range from 5 to 20 nm, and the median volume particle diameter of the secondary particles is less than 45 nm. The metal oxide can be used in a sunscreen product that exhibits both effective UV protection and improved transparency.
Type:
Application
Filed:
December 20, 2002
Publication date:
December 4, 2003
Applicant:
Imperial Chemical Industrial PLC
Inventors:
Graham Paul Dransfield, Susan Cutter, Philip Laurence Lyth
Abstract: Processes for preparing modified pigments are described. In one embodiment, the process comprises the step of combining, in any order, a pigment having attached an electrophilic group and a thiol reagent comprising at least one —SH group and at least two ionic or ionizable groups. In a second embodiment, the process comprises the step of combining, in any order, a pigment having attached an electrophilic group and a thiopolymer comprising at least one —SH group. Modified pigments are also described.
Abstract: The present invention relates to a process for preparing a polymer-modified pigment comprising the step of: combining, in any order, at least one pigment having attached at least one nucleophilic group, at least one polymer comprising at least one carboxylic acid group or salt thereof, and at least one coupling agent. At least one mediator compound may also be used. The modified pigments can be used in applications such as inkjet ink applications.
Abstract: The invention relates to a nondusting, solvent-containing homogeneous pigment preparation that includes
≧70% by weight of one or more effect pigments
0.1-30% by weight of an organic solvent or solvent mixture having an evaporation number (EN) of 10 to 100 and a surface tension (ST) of ≦35 mN/m
and optionally
0-5% by weight of a surface-active substance.
Type:
Grant
Filed:
November 20, 2000
Date of Patent:
November 18, 2003
Assignee:
Merck Patent Gesellschaft mit beschraenkter Haftung
Inventors:
Wolfgang Hechler, Gerhard Herget, Brigitte Husseini, Sabine Schoen
Abstract: The present invention relates to a process for preparing a polymer-modified pigment comprising the step of: combining, in any order, at least one pigment having attached at least one nucleophilic group, at least one polymer comprising at least one carboxylic acid group or salt thereof, and at least one coupling agent. At least one mediator compound may also be used. The modified pigments can be used in applications such as inkjet ink applications.
Abstract: The present invention describes an ink composition comprising a liquid vehicle and a modified colored pigment. The modified colored pigment comprises the product of a colored pigment having at least one leaving group and a treating agent. The modified colored pigments are also disclosed, as are processes for producing them.
Abstract: The present invention is directed to a water-based acrylic emulsion dispersant to be used as a grind resin to incorporate inorganic pigment into a pigment dispersion for a coating composition. The acrylic emulsion dispersant is the reaction product of butyl methacrylate, butyl acrylate, styrene, methyl ether polyethylene glycol methacrylate, polyethylene glycol methacrylate, and polyphosphoric acid. The present invention is also directed to a method of preparing the acrylic emulsion dispersant. In this method, the butyl methacrylate, butyl acrylate, and styrene are combined with water to establish a first reaction blend. Similarly, the methyl ether polyethylene glycol methacrylate and the polyethylene glycol methacrylate are combined with water to establish a second reaction blend. Next, the first and second reaction blends are polymerized to form an intermediate emulsion polymer containing a hydroxyl group from the functionality of the polyethylene glycol methacrylate.
Type:
Grant
Filed:
December 22, 2000
Date of Patent:
November 4, 2003
Assignee:
BASF Corporation
Inventors:
Swaminathan Ramesh, JoAnn Lanza, Paul J. Harris
Abstract: A fluidizing agent which is a diamine and/or diquaternary ammonium salt of a coloured acid of the phthalocyanine or disazo series of dyestuffs wherein the diamine or diquaternary ammonium cation is of formula (1) wherein R is optionally substituted C6-30-alkyl or optionally substituted C6-30-alkenyl; R1 is hydrogen, optionally substituted C1-30-alkyl or C2-30-alkenyl, optionally substituted cycloalkyl, optionally substituted aryl or optionally substituted aralkyl; R2, R3 and R5 are each, individually, optionally substituted C1-6-alkyl, optionally substituted cycloalkyl, optionally substituted aryl or optionally substituted aralkyl; R4 is hydrogen, optionally substituted C1-6-alkyl, optionally substituted cycloalkyl, optionally substituted aryl or optionally substituted aralkyl; X is C1-12-alkylene or C2-14-alkenylene; or R1 and R3 together with the two nitrogen atoms to which they are attached and X form a ring; and/or R4 and R5 together with the nitrogen atom to which they are attached form a ring.
Type:
Grant
Filed:
February 26, 2002
Date of Patent:
November 4, 2003
Assignee:
Avecia Limited
Inventors:
John Joseph McElhinney, Kristen Susan Low, Laura Janette Murphy
Abstract: A pigment dispersion including a pigment; a dispersant; and a dispersion medium including water, wherein the pigment is dispersed in the dispersion medium, wherein the average particle diameter D50 of the pigment is not greater than 50 nm and the standard deviation of the pigment particle diameter distribution thereof is less than the average particle diameter D50. An inkjet ink including the pigment dispersion and at least one of water, a water-soluble organic solvent and a surfactant. A method and apparatus for forming an image using the inkjet ink. An image produced by the image forming method and apparatus.
Abstract: By incorporating and dispersing infrared ray shielding ultrafine particles having an average particle size of from 10 to 60 nm and a volume ratio of ultrafine particles having particle sizes of at least 60 nm being at most 15% of all particles, in a plasticizer, it is possible to obtain an ultrafine particle dispersion composition having the ultrafine particles uniformly dispersed. By using this composition, it is possible to obtain a laminated glass or an interlayer of a laminated glass, which has a small haze value and which is excellent in the infrared ray shielding performance.
Type:
Grant
Filed:
June 17, 2002
Date of Patent:
October 14, 2003
Assignees:
Asahi Glass Company, Fuji Titanium Industry Co., Ltd.
Abstract: Disclosed is a process for the preparation of a pigment dispersion starting with a tank flushed pigment that is continuously fed into a twin screw extruder, washed and dried by vacuum to get a desirable product.
Type:
Application
Filed:
April 5, 2002
Publication date:
October 9, 2003
Inventors:
Kalpathy R. Anantharaman, Michael L. Lewis, Pat Galioto
Abstract: A process for producing a pigment dispersion is disclosed. This process comprises the steps of: providing a mixture consisting essentially of a pigment, a dispersant, a polysiloxane surfactant and/or an alkanediol, a polyhydric alcohol, and water; and dispersing the ingredients of the mixture in one another. A process for producing an ink composition is also disclosed wherein the above pigment dispersion is mixed with a member selected from the group consisting of water, a surfactant, a wetting agent, a pH adjustor, and mixtures thereof. This ink composition can realize good image quality.
Abstract: The present invention relates to a process for producing alpha, gamma-I, gamma-II and gamma-III crystal modifications of quinacridone and transparent quinacridone pigments including the solid solutions of various quinacridones, using a variety of tris-aryl-s-triazines, particularly resorcinol triazine derivatives, or aromatic- or heteraromatic-compounds having at least one hydroxyl or keto group bonded to the ring, as an additive, prior to or concurrently with the oxidation of corresponding dihydroquinacridone salts.
Type:
Grant
Filed:
March 18, 2002
Date of Patent:
September 30, 2003
Assignee:
Ciba Specialty Chemicals Corporation
Inventors:
Shivakumar Basalingappa Hendi, Suruliappa Gowder Jeganathan, James Barry Ganci
Abstract: The present invention provides a process for continuous production of pigment flushes and an apparatus for carrying out the process. In the process of the invention, the pigment press cake is first fluidized. The fluidized press cake and a hydrophobic liquid organic medium are fed into a twin screw extruder. The kneading of the organic medium and press cake between the twin screws flushes the pigment into the organic medium. The water phase and flushed pigment phase are separated by removing at least part of the water phase through a vent in the extruder. An impediment to the flow of material downstream of the water vent causes the flush to accumulate in the vented section for a period of time sufficient to remove the desired amount of the water phase. The flush works over the impediment and passes downstream to where vacuum is applied to remove residual water from the flush. The flush may be further combined with other ink ingredients to form an ink product.
Abstract: The present invention relates to pigment mixtures consisting of at least two components, component A being SiO2 flakes coated with one or more metal oxides and/or metals and component B being special-effect pigments, and to their use in varnishes, paints, printing inks, masterbatches, plastics and cosmetic formulations.
Type:
Application
Filed:
March 24, 2003
Publication date:
September 25, 2003
Applicant:
Merck Patent Gesellschaft mit beschrankter Haftung
Inventors:
Sabine Schoen, Reiner Vogt, Norbert Schul, Karl Osterried, Johann Munz
Abstract: A pigment product for use in a coating composition to provide a gloss coating on paper, the pigment product comprising a processed particulate kaolin having a particle size distribution such that at least about 80% by weight of the particles have an equivalent spherical diameter less than about 2 &mgr;m and in the range of from about 15% to about 40% by weight of the particles have an equivalent spherical diameter less than about 0.25 &mgr;m and the particles have a shape factor in the range of from about 30 to about 60 and wherein the pigment product comprises a blend of Component A: a particulate kaolin in which the particles have a shape factor of at least about 45, and Component B: a particulate kaolin in which the particles have a shape factor of less than about 20.
Abstract: A colorant for ink-jet printing ink of the present invention, has an average particle diameter of 0.001 to 0.15 &mgr;m, and comprises: extender pigments as core particles; a gluing agent coating layer formed on at least a part of surface of said core particle; and an organic pigment coat uniformly formed on at least a part of said gluing agent coating layer. The colorant for ink-jet printing ink exhibits not only a high tinting strength and a clear hue, but also excellent dispersibility and light resistance in spite of fine particles.
Abstract: A powder coating material or powder coating dispersion (powder slurry) comprising at least one hydrophilic effect pigment, and the use thereof.
Abstract: An aluminum pigment excellent in water resistance useful in water-based metallic paints, water-based metallic inks and the like, is provided. The pigment is excellent in water resistance and has a coating derived from peroxo-polymolibdate represented by the compositional formula:
MoO3.mH2O2.nH2O or MoO3-m(O2)m.nH2O
where Mo is molybdenum, O is oxygen, 0≦m≦1 and 1≦n≦2 and also includes at least one amine selected from alkylamine, allylamine, arylamine, alkanolamine or alkoxylamine.
Abstract: A pigment yellow 74 obtained by coupling a coupler component containing 2-methoxyacetoacetoanilide and an acetoacetoanilide derivative of the following formula (1) in an amount of 0.
Abstract: The invention relates to a solid pigment composition comprising
a) at least one pigment,
b) at least one compound selected from the group consisting of
b0) a phenol-styrene-polyglycol ether or an ionically modified phenol-styrene-polyglycol ether,
b1) a condensation product prepared from
b1A) sulphonated aromatics
b1B) aldehydes and/or ketones and
b1C) optionally one or more compounds selected from the group of unsulphonated aromatics, urea and urea derivatives, and
b2) phosphoric acid, phosphonic acid and derivatives thereof, and
c) at least one organic thickener.
Abstract: Organic and inorganic composite pigments having an average particle diameter of 0.01 to 10.0 &mgr;m composed of a white inorganic particle, an organosilane compound obtained from alkoxysilanes, or polysiloxanes coating on the white inorganic particle, and an organic pigment coat formed on said coating. An ultraviolet light-absorbing agent is present in any portion from the surface of the white inorganic particle to surface of the organic pigment coat. These composite pigments have reduced amounts of organic pigments desorbed from their surface and exhibit excellent light resistance due to their ultraviolet absorbing property.
Abstract: The present invention provides: an aqueous fast-drying resin composition which is excellent in the fast driability and can exhibit performances with regard to adhesion and resistance on a level with those of solvent type compositions; a production process for the aqueous fast-drying resin composition; and a use of the aqueous fast-drying resin composition as a gravure ink composition. An aqueous fast-drying resin composition comprises an anionic resin, a cationic resin, and a polyvalent metallic compound. In addition, another aqueous fast-drying resin composition comprises an aqueous medium and a resin component wherein the aqueous medium will be removed by drying. In this aqueous fast-drying resin composition, the resin component is combined with a polyvalent metallic compound and includes a combination of an anionic resin and a cationic resin.
Type:
Grant
Filed:
May 22, 2000
Date of Patent:
July 22, 2003
Assignee:
Nippon Shokubai Co., Ltd.
Inventors:
Asutosh Nigam, Chien-Chang David Yao, Ravi S Renduchintala, Koichiro Saeki, Masakazu Morimoto, Takashi Miyai
Abstract: A ceramic slurry composition has a powdered ceramic uniformly dispersed therein without excessive damage thereto. A method for producing a ceramic green sheet using the ceramic slurry composition and a method for producing multilayer ceramic electronic devices are also disclosed. The ceramic slurry composition contains the powdered ceramic, a dispersing agent, a binder and a solvent, in which an anionic dispersing agent is used as the dispersing agent, and the content of the anionic dispersing agent is set to be such that the total acid content thereof corresponds to about 10 to 150% of the total base content of the powdered ceramic. In addition, the powdered ceramic having an average particle diameter of about 0.01 to 1 &mgr;m is used.
Abstract: The present invention provides a gel composition capable of maintaining a high viscosity controlling ability over a wide polarity range from a low to a high polarity and also capable of exhibiting an excellent viscosity stability over a prolonged period as well as such nail enamel.
Abstract: A pigment dispersion including a pigment, a dispersant, and a dispersion medium including water, wherein the dispersant includes a compound having the following formula (1).
Abstract: The invention relates to fiber compositions that can be pumped and metered in the fashion of fluid chemical admixtures into a concrete mix, thereby enabling the fibers to be dispensed by concrete ready-mix plant operators who can provide verification of fiber administration and dosage. The fibers, particularly plastic shrinkage control fibers having large cumulative surface area, are suspended in an aqueous medium such that their surface area is already wetted out, thereby virtually assuring that substantial uniform fiber dispersion can be achieved without clumping and the delay that is usually required by fiber intermixing.
Type:
Application
Filed:
February 6, 2003
Publication date:
June 26, 2003
Applicant:
W.R. GRACE & CO.-CONN.
Inventors:
Michael B. Macklin, Anandakumar Ranganathan, Klaus-Alexander Rieder
Abstract: A pigment dispersion suitable for use in the manufacture of pigmented coating compositions is provided. The pigment dispersion comprises a) pigment, b) carrier, and c) an acrylic/polyether comb-branched copolymer dispersant wherein the polyether portion of the copolymer is free of any acidic groups. A method of making a present dispersion is also provided. The method comprises mixing together, in any combination: a) pigment, b) carrier, and c) an acrylic/polyether comb-branched copolymer dispersant wherein the polyether portion of the copolymer is free of any acidic groups. A pigmented coating composition is also provided comprising a pigment dispersion made in accordance with present invention.
Abstract: Pigment flakes having cores preferably composed of resins, polymers, thermoplastics, and/or thermosets with colorant (pigment and/or dyes) deposited thereon, coating applications thereof, and a method for making pigment flakes which includes providing a core material, compounding the core material, processing the core material into uniform forms such as films, wires, thread with rectangular cross sections and bead strings, providing colorant material, vaporizing the colorant material, exposing a surface of core material to the vaporized colorant material to form a layer of colorant on thereon, and fracturing the resultant colorant layered core material into flakes.
Abstract: The present invention provides sulfated and carboxymethylated surfactants and dispersants produced by reacting a styrenated phenol alkoxylate with sulfamic acid and then neutralizing with a base such as ammonium hydroxide. The instant invention also provides pigment dispersion comprising: (a) a pigment; and (b) a dispersant based on sulfated and carboxymethylated styrenated phenol alkoxylates. Carbon black dispersions are also provided containing carbon black and the dispersants of the invention.
Abstract: The present invention describes a dispersion comprising a vehicle and a modified pigment. The modified pigment has, when measured in an aqueous medium, a zeta potential of 0.0 mV at a pH of between 5.0 and 11.0. Inkjet ink compositions and an inkjet consumable set are also disclosed.
Abstract: The present invention relates to an aqueous formulation containing phenol and/or phenol derivatives having a low freezing point and anti-microbial activity.
Abstract: There is provided a method for regulating the average particle diameter of a pigment for an ink composition possessing excellent anti-clogging properties and ejection stability. The method comprises the steps of: dispersing the pigment in a solvent to prepare a stock pigment dispersion; and subjecting the stock pigment dispersion to crossflow membrane filtration.
Abstract: A finely divided pigment is formed of an aggregate of primary particles. A number of primary particles of not greater than 0.1 &mgr;m in particle size is at least 95% of an entire number of the primary particles, and a number of primary particles of greater than 0.1 &mgr;m in particle size is at most 5% of the entire number of the primary particles. The finely divided pigment can be produced by grinding a parent pigment (pre-division pigment) together with a water-soluble inorganic salt and a water-soluble organic solvent in a grinding machine at a temperature of from 30 to 90° C. for 2 to 6 hours under a load, and then removing the water-soluble inorganic salt and the water-soluble organic solvent. A coloring composition comprises a dispersing medium and the finely divided pigment dispersed in the dispersing medium.
Type:
Application
Filed:
June 27, 2002
Publication date:
May 8, 2003
Applicant:
Dainichiseika Color & Chem. Mfg. Co., Ltd.
Abstract: The invention relates to block-copolymeric polyalkylene oxides containing styrene oxide, obtained by alkoxylation, and their use as low-foam pigment wetting agents in aqueous pigment pastes with or without cosolvent and in aqueous and low-solvent coating materials and printing inks.
Type:
Grant
Filed:
August 24, 2000
Date of Patent:
April 22, 2003
Assignee:
Goldschmidt AG
Inventors:
Tammo Boinowitz, Ellen Reuter, Stefan Silber, Joachim Venzmer