Organic Material Containing Patents (Class 106/603)
  • Patent number: 10668524
    Abstract: To provide a binder composition for molding, by which a mold made of aggregate has an excellent resistance to moisture. The binder composition for molding contains a water-soluble binder and at least one kind of lithium salt that is selected from a group of lithium silicate, lithium oxide, lithium hydroxide, lithium carbonate, lithium bromide, lithium chloride, lithium nitrate, and lithium nitrite.
    Type: Grant
    Filed: February 14, 2017
    Date of Patent: June 2, 2020
    Assignee: Sintokogio, Ltd.
    Inventors: Tomohiro Aoki, Yusuke Kato
  • Patent number: 10457814
    Abstract: An aqueous inorganic or hybrid binder composition includes (as % by weight of the solid matter): from 55 to 100% of at least one alkali metal silicate exhibiting an Si/alkali metal weight ratio which varies from 0.3 to 2, from 0 to 35% of at least one plasticizing agent, and from 0 to 10% of one or more additives. Fibrous products can obtained from this composition, in particular based on mineral fibers, such as mats, screens, woven fabrics, in particular painter's canvases, and knitted fabrics.
    Type: Grant
    Filed: December 22, 2015
    Date of Patent: October 29, 2019
    Assignee: SAINT-GOBAIN ADFORS
    Inventors: Alexandre Garcia, Louis Garnier
  • Patent number: 10252942
    Abstract: Foamed fiber compositions and processes of making said compositions. Compositions include a hydraulic mixture including (i) a polymer and (ii) one or more of gypsum, fly ash, and cement; and a foam including a foaming agent, a foam stabilizer, and 0.5-35% fibers by weight. The process for forming the foamed fiber composition includes providing a stable foam including a foaming agent and a foam stabilizer; mixing fibers into the stable foam until the fibers are uniformly distributed in the foam to form a fiber-containing foam, wherein the fiber-containing aqueous foam contains 0.5-35% fibers by weight; and mixing the fiber-containing foam into a hydraulic slurry including (i) a polymer and (ii) one or more of gypsum, fly ash, and cement. The composition is suitable for use in roof tiles, underlayments, backerboards, cement composites, foam fills, bricks, cement sidings, etc.
    Type: Grant
    Filed: June 29, 2016
    Date of Patent: April 9, 2019
    Assignee: ALLIED FOAM TECH CORP.
    Inventor: Yen-Yau Harrison Chao
  • Patent number: 9452406
    Abstract: Disclosed are methods of preparing stable gas-in-water dispersions by silicic acid complexation of micron-sized gas bubbles, and stable dispersions prepared by silicic acid complexation. Compositions and products comprising the dispersions are also disclosed. Dispersions may be stable over an extended period of time at room temperature.
    Type: Grant
    Filed: May 17, 2013
    Date of Patent: September 27, 2016
    Assignee: L'OREAL
    Inventors: Vance Bergeron, Jean-Thierry Simonnet, Florence Levy, Aurelie Lafuma, Stephane Santucci
  • Patent number: 8911549
    Abstract: The invention provides a process for the production of a cementious material. The process comprises mixing cement starting materials and a particulate healing agent to provide the cementious material. The healing agent comprises coated particles, wherein the coated particles comprise bacterial material and additive. The bacterial material is selected from the group consisting of a bacterium, a lyophilized bacterium and a bacterial spore of a bacterium. The present invention solves these problems, as (substantially leakage-proof) tablets containing the actual healing agent may neither interfere with either the workability of the liquid mixture (“cementious material”) nor negatively affect properties of either mixture or final material (hardened concrete), even when applied in large quantities. During crack formation in cementious based constructions, the particles also crack, and healing agent is released.
    Type: Grant
    Filed: April 6, 2011
    Date of Patent: December 16, 2014
    Assignee: Technische Universiteit Delft
    Inventor: Hendrik Marius Jonkers
  • Patent number: 8715408
    Abstract: A method for forming a composite structure, using a mandrel that is later removed from the composite structure, involves production of a mandrel by depositing a particulate mixture, including an aggregate and a binder, into a mold and removing the mandrel from the mold. The mandrel may be treated while still in the mold by heating, curing with an agent, microwave energy, or by some combination thereof. Once finished, the mandrel can be used in manufacturing polymer and/or composite components. The mandrel can also be include materials that can be easily removed from the finished composite structure by water, shakeout, chemically dissolving, or by some combination thereof.
    Type: Grant
    Filed: June 4, 2010
    Date of Patent: May 6, 2014
    Assignee: Advanced Ceramics Manufacturing, LLC
    Inventors: Matt Wallen, Jens Rossfeldt
  • Patent number: 8425794
    Abstract: A method for producing a finely subdivided insulating material includes the steps of: preparing a fluid composition by mixing together an alkaline silicate, a metal hydroxide and an impermeabilizing agent, heat-treating the composition so as to produce a plurality of small cavities in the composition, and finely subdividing the composition.
    Type: Grant
    Filed: October 6, 2008
    Date of Patent: April 23, 2013
    Assignee: Basic & Co. S.r.l.
    Inventor: Stafano Tabarelli de Fatis
  • Patent number: 8182603
    Abstract: Disclosed are cement compositions for applying to honeycomb bodies. The cement compositions can be applied as a plugging cement composition, segment cement, or even as after applied artificial skins or coatings. The cement compositions generally include an inorganic powder batch mixture consisting essentially of inorganic particles having a particle size greater than 100 nm. The cement compositions can further include an organic binder, a liquid vehicle, and one or more optional processing aids. Also disclosed are honeycomb bodies having the disclosed cement compositions applied thereto and methods for making same.
    Type: Grant
    Filed: November 20, 2008
    Date of Patent: May 22, 2012
    Assignee: Corning Incorporated
    Inventors: Anthony Joseph Cecce, Thomas James Deneka, Kintu Odinga X Early, Jeffrey Donald Roche, Patrick David Tepesch
  • Patent number: 7896962
    Abstract: A slurry coating composition is described, which is very useful for enriching the surface region of a metal-based substrate with aluminum. The composition includes colloidal silica and particles of an aluminum-based powder, and is substantially free of hexavalent chromium. The slurry may include colloidal silica and an alloy of aluminum and silicon. Alternatively, the slurry includes colloidal silica, aluminum or aluminum-silicon, and an organic stabilizer such as glycerol. The slurry exhibits good thermal and chemical stability for extended periods of time, making it very useful for industrial applications. Related methods and articles are also described.
    Type: Grant
    Filed: August 17, 2007
    Date of Patent: March 1, 2011
    Assignee: General Electric Company
    Inventors: Lawrence Bernard Kool, Michael Francis Gigliotti, Jr., Stephen Francis Rutkowski, Paul Steven Svec, Anatoli Kogan, Richard DiDomizio, Brian Stephen Noel, David Carr, William Randall Thompson
  • Patent number: 7789959
    Abstract: A description is given of coating compositions comprising at least one strongly basic agent to set a pH of at least 10, at least one selected vinyl ester copolymer, if desired, pigment and/or filler, and, if desired, further additives customary per se. The coating compositions can be stored without use of additional preservatives and can be used to coat substrates of all kinds.
    Type: Grant
    Filed: May 4, 2005
    Date of Patent: September 7, 2010
    Assignee: Celanese Emulsions GmbH
    Inventors: Thomas Fichtner, Ivan Cabrera, Bernhard Momper
  • Patent number: 7744692
    Abstract: A lightweight cementitious composition containing from 10 to 90 volume percent of a cement composition, from 10 to 90 volume percent of particles having an average particle diameter of from 0.2 mm to 8 mm, a bulk density of from 0.03 g/cc to 0.64 g/cc, an aspect ratio of from 1 to 3, and from 10 to 50 volume percent of sand and/or other fine aggregate, where at least a portion of the sand and/or fine aggregate has a fineness modulus of less than 2; where the sum of components used does not exceed 100 volume percent, and where after the lightweight cementitious composition is set it has a compressive strength of at least 1700 psi as tested according to ASTM C39 after seven days. The cementitious composition can be used to make concrete masonry units, construction panels, road beds and other articles.
    Type: Grant
    Filed: March 22, 2006
    Date of Patent: June 29, 2010
    Assignees: Nova Chemicals, Inc., Metromont Corporation
    Inventors: Tricia Guevara, Michael T. Williams, David A. Cowan, John K. Madish, Kolapo Adewale, Roger Moore, Mary M. Moore, legal representative, Blain Hileman, Richard H. Pennell, Jr.
  • Patent number: 7709091
    Abstract: A core material for a composite light weight building panel formed from a settable mixture, said mixture including an acrylic, polymer-based resin comprising: 85% by volume water based copolymer emulsion of polyvinyl acetate with versatate and/or acrylic copolymers in a water emulsion; 10% water soluble colloid protector; 5% additives; such that the resin obtains a specific gravity in the range of 1000±50 g/l and an 8 Ford viscosity at 20° C. of 7±1: and the mixture having the following ratios: from 1 to 3 liters of cement; more than 2 liters of resin; from 10 to 100 liters of light weight filler material; less than 6 kilograms of water, and such that the volume of cement is more than half the volume of resin.
    Type: Grant
    Filed: August 3, 2001
    Date of Patent: May 4, 2010
    Assignee: E.I.F.S. Holdings
    Inventors: Giancarlo Antonio Villani, Vincent Michael Martin
  • Patent number: 7429295
    Abstract: A water-based mixture of multi compounds was invented for the purposes of treating and providing an ultimate protection for large areas of concrete pavements against moisture and moisture-associated problems. The mixture preferably works from within the concrete as well as at the surface. A water-repelling function prevents water from penetrating the concrete matrix. A hygroscopic and hydrophilic behavior of its crystallization system within a concrete matrix minimizes moisture transmission through capillaries and connected voids. As a result, the mixture promises to provide a permanent treatment for moisture related problems, such as damage caused by repeated freeze and thaw cycles and chloride ion penetration as from deicing salts, as well as a permanent treatment for the so-called alkali-silica reactions.
    Type: Grant
    Filed: June 6, 2002
    Date of Patent: September 30, 2008
    Inventor: Radi Al-Rashed
  • Patent number: 7255738
    Abstract: A lightweight cementitious composite material includes expanded synthetic polymer particulate having a particle size of between 0.0625 and 0.5 inches. A dispersant coating on said particulate suppresses electrostatic attraction between particulate particles. A matrix surrounds the particulate and is present from 0.25 to 1 pound per gallon of dispersant coated particulate.
    Type: Grant
    Filed: October 29, 2004
    Date of Patent: August 14, 2007
    Assignee: Conservation Roofing Systems, Inc.
    Inventor: Blaine K. Semmens
  • Patent number: 7022178
    Abstract: A binding agent system based on water glass is disclosed, comprising an aqueous alkali silicate solution having the general composition: xSiO2·yM2O ·zH2O, with M standing for the alkali ions Li+, K+, or Na+, and a hygroscopic base, which is added in the ratio 1:4 to 1:6, with the modulus Na2O/SiO2 being equal to 2.5 to 3.5 at a proportion of solids of 20 to 40% and with 30% sodium hydroxide in an aqueous solution being used as the hygroscopic base. According to the present invention, the aqueous alkali silicate solution contains an emulsion solution having 8 to 10% silicone oil in relation to the quantity of binder, with the silicone oil having a boiling point?250°. The quantity of binder for a core sand mixture is 1.0 to 2.5%, in relation to the total quantity of granular solid, with the production method being performed in a core shooter comprising a vertically positioned housing having a horizontal air intake. The core sand mixture is introduced via a funnel into a slotted sand cylinder.
    Type: Grant
    Filed: October 21, 2000
    Date of Patent: April 4, 2006
    Assignee: Hydro Aluminium Deutschland GmbH
    Inventor: Thomas Steinhäuser
  • Patent number: 6916366
    Abstract: A substrate treatment composition of an aqueous solution for imparting hydrophobicity to a substrate or for rendering the substrate hydrophobic. This solution preferably includes sodium and/or potassium methylsiliconate and sodium and/or potassium silicate. Also, the use of this composition for the treatment of a substrate to impart hydrophobicity or to render the substrate hydrophobic.
    Type: Grant
    Filed: July 10, 2001
    Date of Patent: July 12, 2005
    Inventors: Pierre Hirsbrunner, Ian Horman
  • Patent number: 6641657
    Abstract: Porous inorganic silica foam compositions are derived from water soluble silicate precursors and swollen non-ionic polymer templates are described. The compositions are useful as catalyst supports and as catalysts in hydrocarbon cracking and organic reactions, among other applications.
    Type: Grant
    Filed: April 25, 2002
    Date of Patent: November 4, 2003
    Assignee: Board of Trustees of Michigan State University
    Inventors: Thomas J. Pinnavaia, Thomas R. Pauly, Seong-Su Kim
  • Patent number: 6506246
    Abstract: A substantially water-free hardener composition suitable for admixture with a cement to give a product capable of reaction with a silicate to form a hardened mass, comprises: (a) from 5 to 99.9%, preferably 75 to 99.8%, of an organic carbonate hardener for the silicate; (b) from 0.01 to 20%, preferably 0.02 to 10% of an organic retarder, preferably an organic acid retarder such as citric acid for the cement, the % being by weight based on the total weight of (a) and (b). The organic carbonate hardener is preferably a mixture of ethylene and propylene carbonates in proportions of from 3:1 to 1:3 by weight. The hardener may include a cement such as Portland cement. Suitable amounts are (a) organic carbonate hardener from 10 to 60%, (b) organic retarder is from 0.05 to 10% and (c) cement from 20 to 85%.
    Type: Grant
    Filed: June 8, 2001
    Date of Patent: January 14, 2003
    Assignee: Fosroc International Limited
    Inventors: Leslie W. Cheriton, Anthony C. Plaisted, Anthony M. James, Judith A. Simcox
  • Patent number: 6488761
    Abstract: A method of making a composite product such as a building board, includes the steps of mixing together finely divided lignocellulosic fibres, a hydraulic binder, and water optionally containing a polyvinyl alcohol, to form a paste; introducing a foam generated from a polyvinyl alcohol into the paste and mixing to form a foamed product; forming the foamed product into a desired shape; and allowing the hydraulic binder to set to form the composite product.
    Type: Grant
    Filed: May 26, 2000
    Date of Patent: December 3, 2002
    Assignee: Windsor Technologies Limited
    Inventor: Michael Windsor Symons
  • Patent number: 6409818
    Abstract: The present invention is directed to a composition and method for forming an inexpensive, semi-permanent cured foamed cementitious cover layer over deicing salt which is stored outdoors in large bulk mounds or piles and a salt pile or mound covered with such a layer.
    Type: Grant
    Filed: February 16, 2000
    Date of Patent: June 25, 2002
    Assignee: Cargill, Incorporated
    Inventor: Philip S. Johnson
  • Patent number: 6409817
    Abstract: Disclosed is a rigid fine-celled light-weight foam composition and a method of producing it which has improved retention of liquids by absorption/adsorption which improves the thermal insulation and fire retardant properties of the fine-celled foam particularly suited for use in double walled tanks and hollow canopies, building panels, profiles, and the like.
    Type: Grant
    Filed: May 8, 2000
    Date of Patent: June 25, 2002
    Assignee: Agritec, Inc.
    Inventor: Douglas K. Stephens
  • Patent number: 6355098
    Abstract: The present light-weight material contains expanded perlite, alkali silicates and optionally added hardeners for aqueous alkali silicates, wherein said expanded perlite has a grain of from 0.8 to 6 mm, a hydrophobizing agent is present, the bulk densities are in the range of from 60 to 500 kg/m3.
    Type: Grant
    Filed: September 13, 1999
    Date of Patent: March 12, 2002
    Assignee: Marmorit GmbH
    Inventor: Alfred Pfemeter
  • Publication number: 20020005147
    Abstract: In a coating material for the inner surface of a cathode-ray tube comprising an aqueous dispersion medium containing silicates of lithium and potassium and a dispersing agent, and a graphite particles and, if necessary, particles of the other specific metal compounds suspended therein, the invention is characterized in that the molar ratio of potassium to lithium is in the range of 1 to 9, and the molar ratio of silicon dioxide to the total quantity of oxides of lithium and potassium is in the range of 2.5 to 3.5, and the obtained coating material is most suitable for suppressing the quantities of gases released from the inner coating, for making good use of gas-adsorbing ability of graphite, and for increasing the degree of vacuum in the cathode-ray tube.
    Type: Application
    Filed: April 26, 2001
    Publication date: January 17, 2002
    Inventor: Hiroshi Shimbori
  • Patent number: 6299677
    Abstract: No-bake inorganic binder compositions for binding particulate material and methods for curing such inorganic binders. The inorganic binder compositions are composed of silicate and phosphate components. The no-bake compositions further contain curing catalyst such as a catalyst selected from the group consisting of aliphatic carbonates, cyclic alkylene carbonates, aliphatic carboxylic acid esters, cyclic carboxylic acid esters, phosphate esters and mixtures thereof. The composition produces a binder having the advantageous strength properties of a silicate binder system with the water breakdown properties of a phosphate binder system. Thus, relative to an all-silicate binder system, the present invention has improved mechanical shakeout and improved water collapsibility. Also, relative to conventional all-phosphate binder system, the present invention has superior hot strength, i.e., the foundry cores and molds do not soften at elevated temperatures.
    Type: Grant
    Filed: June 25, 1999
    Date of Patent: October 9, 2001
    Assignee: Borden Chemical, Inc.
    Inventors: Calvin K. Johnson, Kwok-tuen Tse, Leonid S. Zaretskiy, Brian E. Algar
  • Patent number: 6284819
    Abstract: The present invention provides a recording medium comprising a substrate having a glossy coating thereon, wherein the glossy coating comprises a binder and first and second groups of particles, wherein: (a) the first group comprises metal oxide particles, wherein the metal oxide particles are aggregates of smaller, primary particles, (b) the mean diameter of the primary particles is less than about 100 nm, (c) the mean diameter of the aggregates is from about 100 nm to about 500 nm, (d) the mean diameter of the particles in the second group is less than about 50% of the mean diameter of the aggregates in the first group, and (e) the ratio of particles in the first group to particles in the second group is from about 0.1:1 to about 10:1 by weight. The glossy coating of the inventive recording medium has an excellent rate of liquid absorption, a relatively high liquid absorption capacity, excellent adhesiveness, and a non-brittle, crack-resistant, glossy surface.
    Type: Grant
    Filed: July 1, 1999
    Date of Patent: September 4, 2001
    Assignee: Cabot Corporation
    Inventors: Michael S. Darsillo, David J. Fluck, Rudiger Laufhutte
  • Patent number: 6063738
    Abstract: The present invention provides improved foamed well cement slurries, additives and methods. The additives, which foam and stabilize a cement slurry containing fresh water or salt water, are basically comprised of a mixture of an ethoxylated alcohol ether sulfate surfactant, an alkyl or alkene amidopropyl betaine surfactant and an alkyl or alkene amidopropyl dimethyl amine oxide surfactant.
    Type: Grant
    Filed: April 19, 1999
    Date of Patent: May 16, 2000
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Jiten Chatterji, Roger S. Cromwell, Frank Zamora, Bobby J. King
  • Patent number: 5837047
    Abstract: This invention relates to heat cured binder systems comprising as separate Parts: Part I comprising (a) a soluble source of silica, (b) an alcohol, and preferably (c) a surfactant; and Part II comprising an alkali aluminate. The binder systems are mixed with a refractory to form a refractory mix. The resulting refractory mix is shaped and heated at an elevated temperature to form a cured refractory shape, particularly a preform. Heat is applied by warm air, baking in an oven, microwave, or preferably by hot-box equipment.
    Type: Grant
    Filed: December 11, 1996
    Date of Patent: November 17, 1998
    Assignee: Ashland Inc.
    Inventors: Helena Twardowska, John J. Cooper
  • Patent number: 5714000
    Abstract: Disclosed is a rigid fine-celled foam composition and a method of producing it. The foam composition is nontoxic, environmentally friendly, has improved absorption/adsorption and retention of liquids, is not as hard as prior art foams, does not include polymerization by-products detrimental to flower and plant life, and is a foamed mixture of a caustic silicate solution derived from the caustic digestion of rice hull ash having diffused activated carbon particles from thermal pyrolysis of rice hulls rather than from commercial sodium silicate solutions. Valuable by-products of commodity grade are obtained including activated carbon and sodium fluoride.
    Type: Grant
    Filed: July 10, 1996
    Date of Patent: February 3, 1998
    Assignee: Agritec, Inc.
    Inventors: Clyde W. Wellen, Douglas K. Stephens, Greg R. Wellen
  • Patent number: 5681383
    Abstract: A surface-treating agent for a high-temperature refractory material, essentially consisting of 35.0 to 50.0 wt % of sodium silicate, 1.0 to 10.0 wt % of lithium compound, 1.0 to 10.0 wt % of alkali borate, 1 to 10.0 wt % of an organic silicone compound represented by the formula, R--Si(OH).sub.2 Na, wherein R stands for an alkyl group of 1 to 12 carbon atoms, and water and having a viscosity of not more than 100 cps at 20.degree. C., and a method for the surface treatment of a high-temperature refractory material, essentially consisting of rapidly spraying the treating agent mentioned above onto the surface of the refractory material when it is at a temperature in the range of 500.degree. to 1200.degree. C., thereby forming a layer of the treating agent in a molten state, and retaining the layer at a temperature of at least 1100.degree. C.
    Type: Grant
    Filed: October 5, 1995
    Date of Patent: October 28, 1997
    Inventors: Takeshi Andoh, Yasuyuki Yamaguchi, Tadakatu Kisi, Hiroaki Motoyama, Yoshimi Imoto, Matsumi Hirao
  • Patent number: 5532196
    Abstract: The invention relates to new curable inorganic resins based on alkali metal boroaluminosilicates, which, before curing, include inorganic elements in the reactive state, in the following proportions, expressed as their molar ratio of oxides:2.ltoreq.SiO.sub.2 /Al.sub.2 O.sub.3 .ltoreq.41.3.ltoreq.X.sub.2 O/Al.sub.2 O.sub.3 .ltoreq.3.810.ltoreq.H.sub.2 O/Al.sub.2 O.sub.3 .ltoreq.280.5<B.sub.2 O.sub.3 /Al.sub.2 O.sub.3 .ltoreq.2.0X.sub.2 O denoting one or more alkali metal oxides chosen from Na.sub.2 O, K.sub.2 O, Li.sub.2 O, and optionally fillers.The invention also relates to the process for the preparation of these new inorganic resins.The cured resins obtained are very useful for manufacturing heat protection materials.
    Type: Grant
    Filed: July 1, 1994
    Date of Patent: July 2, 1996
    Assignee: Societe National Des Poudres et Explosifs
    Inventors: Claude L'Hernault, Ludovic Neel
  • Patent number: 5362318
    Abstract: A sand consolidating method is provided for use in a borehole within an unconsolidated or loosely consolidated oil or gas reservoir which is likely to introduce substantial amounts of sand into the borehole and cause caving. After perforating the borehole's casing at an interval of the formation where sand will be produced, an aqueous silicate solution is injected into said interval. Next, a spacer volume of a water-immiscible hydrocarbonaceous liquid is introduced into the interval. Thereafter, a water-miscible organic solvent containing an alkylpolysilicate and inorganic salt or chelated calcium is injected into the interval. A permeability retentive silicate cement is formed in the interval. Injection of the aqueous silicate and organic solvent is continued until the interval has been consolidated by the silicate cement to an extent sufficient to prevent sand migration and thereby prevent caving.
    Type: Grant
    Filed: May 18, 1993
    Date of Patent: November 8, 1994
    Assignee: Mobil Oil Corporation
    Inventor: Paul Shu
  • Patent number: 5358565
    Abstract: A method and composition for controlling the profile of a formation where temperatures higher than 400.degree. F. are encountered. An aqueous solution of an organoammonium silicate, alkali metal or ammonium silicate is injected into a zone of higher permeability in a formation. Subsequently, a spacer volume of a water-immiscible organic solvent is directed into said zone. Afterwards, a water-miscible organic solvent containing an alkylpolysilicate and an inorganic salt or a chelated calcium compound are injected into the higher permeability zone. A silicate cement is formed in-situ thereby substantially closing the higher permeability zone to fluid flow. Thereafter, a steam-flooding, water-flooding, carbon dioxide-flooding, or fire-flooding EOR operation is commenced in a lower permeability zone.
    Type: Grant
    Filed: July 6, 1993
    Date of Patent: October 25, 1994
    Assignee: Mobil Oil Corporation
    Inventor: Paul Shu
  • Patent number: 5260405
    Abstract: A binding agent for molding compositions and molded bodies produced by reacting a low molecular weight lignin from the Organosolv process with phenol in a weight ratio of 1:20 to 3:1 at 100.degree. to 180.degree. C., adjusting the pH to an acidic value and condensing the mixture with 0.2 to 0.9 moles of formaldehyde per mole of phenol at 60.degree. to 120.degree. C. to form the binding agent useful for producing curable molding compositions, high-temperature molding compositions, refractory products, textile fleeces and friction coatings as well as carbon materials.
    Type: Grant
    Filed: October 26, 1992
    Date of Patent: November 9, 1993
    Assignee: Rutgerswerke Aktiengesellschaft AG
    Inventors: Arno Gardziella, Achim Hansen, Stephan Schroter, Josef Suren
  • Patent number: 5254639
    Abstract: A binding agent for molded bodies and molding compositions produced by prereacting a mixture of 5 to 60% by weight of lignin or a lignin fraction produced by the Organosolv process and 40 to 95% by weight of a phenol novolac resin and subjecting the latter to high shear forces in a kneader or extruder and optionally mixing the same with a curing agent useful in molding compositions and high temperature-stable molded products such as refractory products, friction coatings, textile fleeces and carbon or graphite materials.
    Type: Grant
    Filed: October 26, 1992
    Date of Patent: October 19, 1993
    Assignee: Rutgerswerke Aktiengesellschaft AG
    Inventors: Arno Gardziella, Achim Hansen, Stephan Schroter, Josef Suren
  • Patent number: 5246495
    Abstract: A novel and stable solution that can be applied on already existing cementitious structures or mixed with the cementitious matter prior to casting, is described. This solution is a simple, stable and environmentally safe material containing a sodium silicate, a dispersing agent and water containing a polysiloxane. Structures that have this material coated thereon or mixed therewith exhibit significant resistance to water penetration and resulting corrosion of re-bar elements and spalling of the concrete.
    Type: Grant
    Filed: March 5, 1992
    Date of Patent: September 21, 1993
    Assignee: Loc Systems, Ltd. (LP)
    Inventor: Jack G. Helmstetter
  • Patent number: 5242494
    Abstract: This invention relates to a foamable silicate composition comprising (a) one or more alkali metal silicates, (b) a blowing agent, (c) a hardener which can be an acetate or a formate ester of a di-polyhydric alcohol or a polyoxyalkylene glycol and (d) a surfactant having a hydrophilic-lypophilic balance of at least 8. The formulations are readily produced by mixing the components, are pourable, pumpable and sprayable, and give rise to foams of excellent compressive strength and thermal insulation properties under ambient conditions.
    Type: Grant
    Filed: August 5, 1991
    Date of Patent: September 7, 1993
    Assignee: British Technology Group Ltd.
    Inventors: Ian C. Callaghan, Elizabeth C. Cooper, Anne Lepre, Alistair S. Taylor
  • Patent number: 5228913
    Abstract: A composition and method are disclosed whereby the formation of geopolymers from curable, inorganic, stone-forming SiO.sub.2 and Al.sub.2 O.sub.3 containing compositions is accelerated by materials which exhibit exothermic behavior in the presence of water. Such polymerizable compositions are suitable as mortar compositions for fastening anchor rods.
    Type: Grant
    Filed: March 27, 1991
    Date of Patent: July 20, 1993
    Assignee: Hilti Aktiengesellschaft
    Inventors: Rudolf Hinterwaldner, Peter Mauthe, Ulrich Hense
  • Patent number: 5147565
    Abstract: Foamed well cementing compositions and methods of performing cementing operations in salt containing subterranean environments are provided. The compositions are comprised of hydraulic cement, salt water, dispersed gas and a foaming agent selected from the group consisting of surfactants of the formula R--(OR').sub.n --OSO.sub.3.sup.- X.sup.+.
    Type: Grant
    Filed: August 7, 1991
    Date of Patent: September 15, 1992
    Assignee: Halliburton Company
    Inventors: Daniel L. Bour, Jerry D. Childs
  • Patent number: 5147459
    Abstract: Macro defect free cementitious products are obtained by curing or firing a cementitious composition comprising water, a reactive filler and a water soluble alkali metal silicate.The products show good strength and heat and water stability, by contrast with known mdf products where leaching out of the polymers used results in decreased strength.
    Type: Grant
    Filed: September 5, 1990
    Date of Patent: September 15, 1992
    Assignee: Marley Tile AG
    Inventors: Michael E. Lynn, Christine A. Durey
  • Patent number: 5028270
    Abstract: An aqueous silicic acid sol which is freeze-stabilized and which is useful for the production of phosphate-based embedding compositions used in dental technology, the aqueous silicic acid sol including from 25 to 50 weight percent of silicon dioxide; and from 2 to 10 weight % of a compound which is one of urea or a urea derivative and which has the general formula: ##STR1## wherein X and Y are groups selected from the group consisting of an --NH.sub.2 group and an --NHR group, in which R is an alkyl radical having from 1 to 4 carbon atoms.
    Type: Grant
    Filed: March 23, 1989
    Date of Patent: July 2, 1991
    Assignee: Giulini Chemie GmbH
    Inventors: Hans-Joachim Forster, Josef Gotzig, Jorg Brenn, Wolfgang Tucholke
  • Patent number: 4940844
    Abstract: A stable polyol-alkali metal silicate emulsion is produced by mixing and emulsifying an aqueous alkali metal solution, a polyol and an organic compound that will cause the aqueous alkali metal silicate solution to solidify. The polyol-alkali metal silicate emulsion may be used to react with compounds containing at least two isocyanate radicals to produce polyurethane silicate solid or foamed products which may be used for thermal and sound insulation, coating agents, adhesives, caulking agents and molded objects.
    Type: Grant
    Filed: April 4, 1988
    Date of Patent: July 10, 1990
    Inventor: David H. Blunt