Magnesium Oxy-chloride (e.g., Sorel Cement, Etc.) Patents (Class 106/685)
  • Patent number: 11590898
    Abstract: A smart license plate vault securely holds small objects, such as a vehicle key, while resembling a license plate mounting platform. The smart license plate vault may be operated by authorized third parties via a keypad located on the smart license plate vault to accept access codes and other information. The smart license plate vault may include a storage compartment with a removable cover for providing access to the storage compartment and an electronic locking mechanism for locking and unlocking the vault, a vault cover plate sensor for detecting when the vault cover plate has been placed into a closed position, a storage compartment sensor for recording information regarding an interior of the storage compartment when the vault cover plate sensor detects that the vault cover plate has been placed into the closed position, and a transmitter for wirelessly transmitting the recorded information to a remote location.
    Type: Grant
    Filed: December 16, 2019
    Date of Patent: February 28, 2023
    Assignee: Biig Technologies Inc.
    Inventors: Charlene Consolacion, Janno Stern, Jaan Viru
  • Patent number: 11148977
    Abstract: A system and method for applying a cement composition, including storing a slurry, adding magnesium oxide to the slurry to give a magnesium-oxychloride cement slurry, pumping the magnesium-oxychloride cement slurry into a wellbore, and sealing a loss circulation zone in the wellbore.
    Type: Grant
    Filed: October 4, 2019
    Date of Patent: October 19, 2021
    Assignee: Saudi Arabian Oil Company
    Inventors: Carl Thaemlitz, Ashok Santra
  • Patent number: 11008252
    Abstract: According to some embodiments, a curable mixture configured to set in the presence of water, wherein the mixture comprises magnesium oxide, a primary cementitious component and at least one accelerant. A proportion by weight of the primary cementitious component is 80% to 120% of a proportion of magnesium oxide by weight.
    Type: Grant
    Filed: August 28, 2020
    Date of Patent: May 18, 2021
    Assignee: MSB Global, Inc.
    Inventors: Mark R. Lukkarila, Kevin A. MacDonald, Sam F. Marshall, Matthew D. Spencer
  • Patent number: 10927041
    Abstract: According to some embodiments, a curable mixture configured to set in the presence of water, wherein the mixture comprises magnesium oxide, a primary cementitious component and at least one accelerant. A proportion by weight of the primary cementitious component is 80% to 120% of a proportion of magnesium oxide by weight.
    Type: Grant
    Filed: August 28, 2020
    Date of Patent: February 23, 2021
    Assignee: MSB Global, Inc.
    Inventors: Mark R. Lukkarila, Kevin A. MacDonald, Sam F. Marshall, Matthew D. Spencer
  • Patent number: 10910988
    Abstract: A method to make an ultra-stable structural laminate of a cementitious material with a nano-molecular veneer and a foam component catalytically reacted into an expanded closed cell foam having a thickness from ?th inch to 8 inches, a density from 1.5 pounds/cubic foot to 3 pounds/cubic foot that inter-engages the cementitious material forming a matrix creating the ultra-stable structural laminate with fire resistance; a lateral nail pull strength from 44 pounds to 300 pounds of force; an insulation R value from 1 to 40; a resistance to seismic impact for earthquakes over 3.1 on the Richter Scale; a break point from 7 lbs/inch to 100 lbs/inch; and a resistance to wind shear equivalent to a 15 mph downburst.
    Type: Grant
    Filed: December 11, 2018
    Date of Patent: February 2, 2021
    Assignee: MiTek Holdings, Inc.
    Inventors: James A. Wambaugh, Brett Rochner, Cole J. Weinberger
  • Patent number: 10897222
    Abstract: A building with ultra-stable cementitious material with nano-molecular veneer has 29 wt % to 40 wt % of a magnesium oxide dry powder containing 80 wt % to 98 wt % of magnesium oxide based on a final total weight of the cementitious material, 14 wt % to 18 wt % of a magnesium chloride dissolved in water and reacting to form a liquid suspension, a phosphorus-containing material, and wherein the mixture forms a liquid suspension that reacts into an amorphous phase cementitious material, wherein a portion of the amorphous phase cementitious material grows a plurality of crystals. The plurality of crystals are encapsulated by the amorphous phase cementitious material forming a nano-molecular veneer and a wall material that is affixed to a frame of a building.
    Type: Grant
    Filed: December 5, 2018
    Date of Patent: January 19, 2021
    Assignee: MiTek Holdings, Inc.
    Inventors: James A. Wambaugh, Brett Rochner
  • Patent number: 10759697
    Abstract: According to some embodiments, a curable mixture configured to set in the presence of water, wherein the mixture comprises magnesium oxide, a primary cementitious component (e.g., slag cement) and at least one accelerant. A proportion by weight of the primary cementitious component is 80% to 120% of a proportion of magnesium oxide by weight.
    Type: Grant
    Filed: March 26, 2020
    Date of Patent: September 1, 2020
    Assignee: MSB Global, Inc.
    Inventors: Mark R. Lukkarila, Kevin A. MacDonald, Sam F. Marshall, Matthew D. Spencer
  • Patent number: 10227259
    Abstract: A ultrastable cementitious material with nano-molecular veneer makes a cementitious material by blending 29 wt % to 40 wt % of a magnesium oxide dry powder containing 80 wt % to 98 wt % of magnesium oxide based on a final total weight of the cementitious material, with 14 wt % to 18 wt % of a magnesium chloride dissolved in water and reacting to form a liquid suspension, mixing from 2 to 10 minutes, adding a phosphorus-containing material, and allowing the liquid suspension to react into an amorphous phase cementitious material, wherein a portion of the amorphous phase cementitious material grows a plurality of crystals. The plurality of crystals are encapsulated by the amorphous phase cementitious material forming a nano-molecular veneer.
    Type: Grant
    Filed: June 12, 2018
    Date of Patent: March 12, 2019
    Inventors: James Allen Wambaugh, Brett Rochner
  • Patent number: 10167232
    Abstract: A process to make a cementitious material includes blending 29 wt % to 40 wt % of a magnesium oxide dry powder containing 80 wt % to 98 wt % of magnesium oxide based on a final total weight of the cementitious material with 14 wt % to 18 wt % of a magnesium chloride dissolved in water and reacting to form a liquid suspension, mixing from 2 to 10 minutes, adding a phosphorus-containing material, and allowing the liquid suspension to react into an amorphous phase cementitious material. A portion of the amorphous phase cementitious material grows a plurality of crystals. The plurality of crystals is encapsulated by the amorphous phase cementitious material forming a nano-molecular veneer.
    Type: Grant
    Filed: June 12, 2018
    Date of Patent: January 1, 2019
    Inventors: James Allen Wambaugh, Brett Rochner
  • Patent number: 10167231
    Abstract: A process to make a tile backer board includes using a stabilizing material with a phosphorus-containing compound, reacting magnesium containing starting materials into an amorphous phase cementitious material, and adding 0.1 wt % to 30 wt % of an aggregate and a reinforcing component by mixing in or pouring over the reinforcing component and allowing the amorphous phase cementitious material to cure into a tile backer board.
    Type: Grant
    Filed: June 12, 2018
    Date of Patent: January 1, 2019
    Inventors: James Allen Wambaugh, Brett Rochner
  • Patent number: 10167230
    Abstract: A tile backer board has 29 wt % to 40 wt % of a magnesium oxide dry powder containing 80 wt % to 98 wt % of magnesium oxide, 14 wt % of 18 wt % of a magnesium chloride dissolved in water; 0.1 wt % to 10 wt % of a stabilizing material with a phosphorus-containing compound, reacting into an amorphous phase cementitious material. The phosphorus-containing compound is a phosphorous acid (A) or a phosphoric acid (B). 0.1 wt % to 30 wt % of an aggregate is added and then a reinforcing component is mixed in or the cement is poured onto the reinforcing component forming a tile backer board.
    Type: Grant
    Filed: June 12, 2018
    Date of Patent: January 1, 2019
    Inventors: James Allen Wambaugh, Brett Rochner
  • Patent number: 9828293
    Abstract: A formulation for use as a lost circulation preventive material is a cement-forming aqueous fluid comprising water, a viscoelastic surfactant (VES), a monovalent or multivalent salt, a magnesium powder, a retarder, a weighting material, and a dispersant. The formulation is used in a method of drilling into a subterranean formation that includes introducing into a wellbore passing at least partially through the subterranean formation the cement-forming aqueous fluid, and further increasing the viscosity of the aqueous fluid with the VES; where the monovalent salt is present in an amount effective to pseudo-crosslink the elongated VES micelles to further increase the viscosity of fluid. The formulation further forms a cement by reacting the magnesium powder and the water which reaction is retarded by the retarder. The water may be saline water. When the fluid density is greater than 14 pounds per gallon, a dispersant is required, such as a sulfonated copolymer.
    Type: Grant
    Filed: March 15, 2017
    Date of Patent: November 28, 2017
    Assignee: Baker Hughes, a GE company, LLC
    Inventors: Prahlad Kumar Yadav, Pranjal Sarmah, Gaurav Agrawal, Tianping Huang
  • Patent number: 9403288
    Abstract: A cast sheet that consists of a non planar net structure with cavities, where the net structure spread across a plane and where the cavities can form holes from one side of the sheet to the other. The cavities on both of the sides of the sheet can be arranged in identical structures where the structure of both sides are displaced or rotated in relation to each-other. Also described is a form template for casting of such a sheet and a method for producing such sheet.
    Type: Grant
    Filed: November 4, 2010
    Date of Patent: August 2, 2016
    Assignee: BUTONG AB
    Inventor: Lars Hoglund
  • Patent number: 9023150
    Abstract: The present invention relates to acid-soluble cement compositions that comprise cement kiln dust (“CKD”) and/or a natural pozzolan and associated methods of use. An embodiment includes a method of cementing comprising: placing an acid-soluble cement composition in a subterranean formation, wherein the acid-soluble cement composition comprises a hydraulic cement, a component selected from the group consisting of CKD, pumicite, and a combination thereof, and water; allowing the acid-soluble cement composition to set; and contacting the set acid-soluble cement composition with an acid to dissolve the set acid-soluble cement composition.
    Type: Grant
    Filed: September 19, 2012
    Date of Patent: May 5, 2015
    Inventors: D. Chad Brenneis, Craig W. Roddy, James R. Benkley, Preston DePlacido, William J. Caveny, Rickey L. Morgan, Ronnie G. Morgan
  • Patent number: 8950486
    Abstract: The present invention relates to acid-soluble cement compositions that comprise cement kiln dust (“CKD”) and associated methods of use. An embodiment provides a method of cementing comprising: providing an acid-soluble cement composition comprising a kiln dust and water; allowing the acid-soluble cement composition to set to form an acid-soluble hardened mass; and contacting the acid-soluble hardened mass with an acid.
    Type: Grant
    Filed: August 27, 2012
    Date of Patent: February 10, 2015
    Assignee: Halliburton Energy Services, Inc.
    Inventors: James Robert Benkley, D. Chad Brenneis, Craig W. Roddy
  • Patent number: 8911547
    Abstract: Novel decorative products including interior home decorative products, garden ornaments, building decorative products and the like are disclosed in which the novel decorative products are characterized in having rigid shells of compacted fiber reinforced magnesium oxychloride composite, seam lines of below two millimeters and cores of which densities can be adjusted according to the preferred weight of the products during the product design stage. The aforesaid compacted fiber reinforced magnesium oxychloride composite is characterized in having compacted structures of F-5 MOC phase magnesium oxychloride. A method for producing the novel decorative products is also provided.
    Type: Grant
    Filed: October 27, 2011
    Date of Patent: December 16, 2014
    Assignee: CompoClay Holdings Limited
    Inventors: Ching Wah Man, Lai Kit Lau, King Lung Lee
  • Patent number: 8747546
    Abstract: The composition applied to the refractory structure has a magnesia-based refractory material, calcia source and a binder. After application of the refractory material to a refractory structure and upon application of heat to the applied refractory material a matrix is formed which protects against penetration of the slag into the refractory material. The resulting refractory material has improved hot strength, slag resistance and durability.
    Type: Grant
    Filed: March 19, 2010
    Date of Patent: June 10, 2014
    Assignee: Specialty Minerals (Michigan) Inc.
    Inventors: William J. Peschler, Dominick M. Colavito, Yves C. Vermeulen
  • Patent number: 8603237
    Abstract: Despite the excellent properties associated with Magnesium OxyChloride (Sorel) based cements and Magnesium OxySulfate based cements, water and corrosion resistance has been limiting factors for achieving greater commercial applications. Such issues can be addressed by incorporating various alkali metal phosphates, such as Magnesium mono- or dihydrogen phosphate (MgHPO4 or MgH2PO4) with alkali metal fatty acids; such as Magnesium Stearate; and metal or alkali metal sulfates such as Aluminum Sulfate or Magnesium Sulfate. Water resistance is further enhanced by either pre-carbonating the mix water or the liquid magnesium chloride phase of the cements, or by adding a carbonate into the powder phase. Accelerated cure of this system has also been obtained by using various inorganic metal oxides. Additionally, improved corrosion resistance is achieved through the use of certain phosphates, zeolites, nitrites and other novel additives.
    Type: Grant
    Filed: April 5, 2012
    Date of Patent: December 10, 2013
    Assignee: Premier Magnesia, LLC
    Inventors: Jerry Elliott Rademan, Ronald Wardle, Mark Shand
  • Publication number: 20130263759
    Abstract: Despite the excellent properties associated with Magnesium OxyChloride (Sorel) based cements and Magnesium OxySulfate based cements, water and corrosion resistance has been limiting factors for achieving greater commercial applications. Such issues can be addressed by incorporating various alkali metal phosphates, such as Magnesium mono- or dihydrogen phosphate (MgHPO4 or MgH2PO4) with alkali metal fatty acids; such as Magnesium Stearate; and metal or alkali metal sulfates such as Aluminum Sulfate or Magnesium Sulfate. Water resistance is further enhanced by either pre-carbonating the mix water or the liquid magnesium chloride phase of the cements, or by adding a carbonate into the powder phase. Accelerated cure of this system has also been obtained by using various inorganic metal oxides. Additionally, improved corrosion resistance is achieved through the use of certain phosphates, zeolites, nitrites and other novel additives.
    Type: Application
    Filed: April 5, 2012
    Publication date: October 10, 2013
    Inventors: Jerry Elliot Rademan, Ronald Wardle, Mark Shand
  • Patent number: 8453733
    Abstract: A method for controlling driving fluid breakthrough caused by zones of pressure communication, i.e., a matrix bypass event (“MBE”) or a wormhole, having a void space and possibly areas of enhanced permeability (a halo region) associated with the void space, within a subterranean formation arising from use of a driving fluid in reservoirs where heavy/viscous oil is being produced. In embodiments, the method includes injection of a slurry of a cementitious material into the zone, which upon setting, provides a cement plug in the void space that reduces the pressure communication and flow of driving fluid within the zone. Another step injects a gel precursor within the zone, which upon setting, produces a gel plug that also reduces pressure communication and driving fluid flow through the halo region of the zone.
    Type: Grant
    Filed: July 29, 2010
    Date of Patent: June 4, 2013
    Inventors: Bradley W. Brice, Giovanna Boccardo, Bernard Tremblay
  • Patent number: 8409346
    Abstract: Waste storage vessels formed from a composition including calcium silicate, magnesium or calcium oxides and an acid phosphate are provided. The composition may also include fly ash or kaolin with or without the calcium silicate.
    Type: Grant
    Filed: October 2, 2009
    Date of Patent: April 2, 2013
    Assignee: Grancrete, Inc.
    Inventors: Jeffrey L. Selph, James W. Paul, Jr.
  • Publication number: 20130043026
    Abstract: Resilient graphitic carbon may be an effective lost-circulation control agent for well-cementing compositions. During primary or remedial cementing, the carbon particles may hinder or prevent the egress of the well-cementing composition from the wellbore into subterranean formations via formation fissures or cracks. The carbon particles may also be added to spacer fluids, chemical washes or both.
    Type: Application
    Filed: August 15, 2011
    Publication date: February 21, 2013
    Applicant: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Salim Taoutaou, Shameed Ashraf, Khalid Abdel Hadi
  • Patent number: 8297357
    Abstract: The present invention relates to acid-soluble cement compositions that comprise cement kiln dust (“CKD”) and/or a natural pozzolan and associated methods of use. An embodiment includes a method of cementing comprising: placing an acid-soluble cement composition in a subterranean formation, wherein the acid-soluble cement composition comprises a hydraulic cement, a component selected from the group consisting of CKD, pumicite, and a combination thereof, and water; allowing the acid-soluble cement composition to set; and contacting the set acid-soluble cement composition with an acid to dissolve the set acid-soluble cement composition.
    Type: Grant
    Filed: June 28, 2010
    Date of Patent: October 30, 2012
    Assignee: Halliburton Energy Services Inc.
    Inventors: D. Chad Brenneis, Craig W. Roddy, James R. Benkley, Preston DePlacido, William J. Caveny, Rickey L. Morgan, Ronnie G. Morgan
  • Patent number: 8257485
    Abstract: The composition applied to the refractory structure has a magnesia-based refractory material, calcium carbonate and a binder. After application of the refractory material to a refractory structure and upon application of heat to the applied refractory material a matrix is formed which protects against penetration of the slag into the refractory material. The resulting refractory material has improved hot strength, slag resistance and durability.
    Type: Grant
    Filed: August 18, 2008
    Date of Patent: September 4, 2012
    Assignee: Specialty Minerals (Michigan) Inc.
    Inventors: Dominick M. Colavito, Yves C. Vermeulen
  • Patent number: 8182605
    Abstract: A cementitious veneer and laminate composition is provided. The cementitious laminate composition includes a substrate, a primer layer applied to the substrate, the primer layer comprising a mixture of polyvinyl alcohol catalyst, Portland cement, and sand; and a cementitious veneer layer applied to the primer layer, the cementitious veneer layer comprising a mixture of magnesium sulfate, filler, magnesium oxide, gypsum cement or bassanite, cellulose ethers, and polyvinyl alcohol catalyst. The polyvinyl alcohol catalyst comprises a mixture of polyvinyl alcohol fibers dissolved in water and mixed with butylene carbonate. The veneer layer is applied to the substrate and primer layer by means including spraying and manual spreading, and can be ornamentally manipulated either before or after curing of the veneer layer. The veneer composition can be formed into laminated tiles or panels for use in building applications.
    Type: Grant
    Filed: May 12, 2010
    Date of Patent: May 22, 2012
    Assignee: Ecomeld Corp.
    Inventor: Christine E. Wallner
  • Patent number: 8066812
    Abstract: A magnesium oxychloride cement (MOC) composition comprising: caustic calcined magnesia magnesium chloride phosphoric acids or corresponding salts exfoliated vermiculite.
    Type: Grant
    Filed: May 19, 2009
    Date of Patent: November 29, 2011
    Assignee: Promat Research and Technology Centre, N.V.
    Inventors: Xiao Wu, Octavian Anton, Ann Opsommer
  • Patent number: 7854262
    Abstract: Methods of cementing comprising introducing a cement composition into a subterranean formation, wherein the cement composition comprises a Sorel cement and an amine phosphono retarder; and allowing the cement composition to set.
    Type: Grant
    Filed: October 14, 2008
    Date of Patent: December 21, 2010
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Ashok K. Santra, Rocky Fitzgerald
  • Patent number: 7833344
    Abstract: A slurry composition comprising an alkaline metal oxide, a chloride or phosphate salt, water, glass beads and a foaming agent. A foamed slurry comprising magnesium oxide, water, a chloride or phosphate salt, and glass beads, wherein the slurry has a density of from about 4 to about 12 pounds per gallon. A foamed slurry comprising magnesium oxide, water, a chloride or phosphate salt, and beads, wherein the slurry has a density of from about 4 to about 12 pounds per gallon and the set slurry is acid soluble.
    Type: Grant
    Filed: November 3, 2006
    Date of Patent: November 16, 2010
    Assignee: Halliburton Energy Services Inc.
    Inventors: Ashok K. Santra, Christopher L. Gordon
  • Patent number: 7794688
    Abstract: Magnesium oxychloride cement is formed by mixing a magnesium chloride (MgCl2) brine solution with a magnesium oxide (MgO) composition in a selected stoichiometric ratio of MgCl2, MgO, and H2O that forms the 5 phase magnesium oxychloride cement composition. Although Sorel cements formed from the mixture of MgCl2, MgO can form a variety of compounds, the inventive systems and methods provide for controlling the cement kinetics to form the five phase magnesium oxychloride cement composition and results in an improved and stable cement composition. Various fillers can be optionally added to form preferred cement materials for uses as diverse such as road stripping, fire-proofing, fire barriers, cement repair, and mortar.
    Type: Grant
    Filed: January 13, 2010
    Date of Patent: September 14, 2010
    Assignee: Maya Magstone, Inc.
    Inventors: George Eccles Caine, Charles W. Ellis
  • Patent number: 7744693
    Abstract: Lightweight composite or “mineral foam” composite materials can be made from reactive materials such as metal oxides. The materials can be prepared from a reaction of metal oxide(s), phosphate(s) and residual materials to which may be added a reactive foaming agent and/or latex polymer to provide enhanced physical properties. The composite materials can have a density of between about 0.35 to 2.25 g/cc, and may be used for many applications including pre-cast structures, in-situ structures, insulating blocks, slabs and composite wall sections, light weight spheres, mixes and coatings.
    Type: Grant
    Filed: March 29, 2005
    Date of Patent: June 29, 2010
    Inventor: Michael John Mabey
  • Patent number: 7740700
    Abstract: A cementitious veneer and laminate composition is provided. The cementitious laminate composition includes a substrate, a primer layer applied to the substrate, the primer layer comprising a mixture of polyvinyl alcohol catalyst, Portland cement, and sand; and a cementitious veneer layer applied to the primer layer, the veneer layer comprising a mixture of magnesium sulfate, filler, magnesium oxide, gypsum cement, and polyvinyl alcohol catalyst. The polyvinyl alcohol catalyst comprises a mixture of polyvinyl alcohol fibers dissolved in water and mixed with butylene carbonate. The veneer layer is applied to the substrate and primer layer by means including spraying and manual spreading. The veneer layer can be ornamentally manipulated either before or after curing of the veneer layer. The veneer composition can be formed into laminated tiles or panels for use in building applications.
    Type: Grant
    Filed: June 25, 2008
    Date of Patent: June 22, 2010
    Assignee: Ecomeld Corp.
    Inventor: Christine E. Wallner
  • Publication number: 20100112229
    Abstract: Magnesium oxychloride cement is formed by mixing a magnesium chloride (MgCl2) brine solution with a magnesium oxide (MgO) composition in a selected stoichiometric ratio of MgCl2, MgO, and H2O that forms the 5 phase magnesium oxychloride cement composition. Although Sorel cements formed from the mixture of MgCl2, MgO can form a variety of compounds, the inventive systems and methods provide for controlling the cement kinetics to form the five phase magnesium oxychloride cement composition and results in an improved and stable cement composition. Various fillers can be optionally added to form preferred cement materials for uses as diverse such as road stripping, fire-proofing, fire barriers, cement repair, and mortar.
    Type: Application
    Filed: January 13, 2010
    Publication date: May 6, 2010
    Applicant: MAYA MAGSTONE, INC.
    Inventors: George Eccles Caine, Charles W. Ellis
  • Publication number: 20100089582
    Abstract: A variety of methods and compositions are disclosed, including, in one embodiment, a method of cementing comprising introducing a cement composition into a subterranean formation, wherein the cement composition comprises a Sorel cement and an amine phosphono retarder; and allowing the cement composition to set.
    Type: Application
    Filed: October 14, 2008
    Publication date: April 15, 2010
    Inventors: Ashok K. Santra, Rocky Fitzgerald
  • Patent number: 7674333
    Abstract: A sealant having a specific gravity in the range of from about 0.7 to about 1.6 for heavy oil and/or coal bed methane fields is disclosed. The sealant has a binder including an oxide or hydroxide of Al or of Fe and a phosphoric acid solution. The binder may have MgO or an oxide of Fe and/or an acid phosphate. The binder is present from about 20 to about 50% by weight of the sealant with a lightweight additive present in the range of from about 1 to about 10% by weight of said sealant, a filler, and water sufficient to provide chemically bound water present in the range of from about 9 to about 36% by weight of the sealant when set. A porous ceramic is also disclosed.
    Type: Grant
    Filed: June 16, 2006
    Date of Patent: March 9, 2010
    Assignee: UChicago Argonne, LLC
    Inventors: Arun S. Wagh, Ramkumar Natarajan, David Kahn
  • Patent number: 7658795
    Abstract: Magnesium oxychloride cement is formed by mixing a magnesium chloride (MgCl2) brine solution with a magnesium oxide (MgO) composition in a selected stoichiometric ratio of MgCl2, MgO, and H2O that forms the 5 phase magnesium oxychloride cement composition. Although Sorel cements formed from the mixture of MgCl2, MgO can form a variety of compounds, the inventive systems and methods provide for controlling the cement kinetics to form the five phase magnesium oxychloride cement composition and results in an improved and stable cement composition. Various fillers can be optionally added to form preferred cement materials for uses as diverse such as road stripping, fire-proofing, fire barriers, cement repair, and mortar.
    Type: Grant
    Filed: November 7, 2007
    Date of Patent: February 9, 2010
    Assignee: Maya Magstone, Inc.
    Inventors: George Eccles Caine, Charles W. Ellis
  • Patent number: 7654326
    Abstract: A method of servicing a wellbore comprising contacting a metal oxide, a soluble chloride or phosphate salt, water, and a liquid retarder to form a cement composition via a continuous process, wherein the liquid retarder is an aqueous solution having a concentration of less than about 25 w/v %, placing the cement composition into the wellbore, and allowing the cement composition to set. A method of servicing a wellbore comprising (a) contacting an aqueous solution with a soluble salt to form a salt solution, (b) contacting an aqueous solution with a solid retarder to form a liquid retarder wherein the liquid retarder has concentration of less than about 25 w/v %, (c) contacting water, the salt solution, and the liquid retarder to form a mixture, (d) contacting the mixture with a metal oxide to form a cement slurry, wherein the cement slurry is produced with an output rate of from about 0.
    Type: Grant
    Filed: July 10, 2008
    Date of Patent: February 2, 2010
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Ashok Santra, Christopher L. Gordon, Daniel L. Bour, Keith D Pewitt, Dwain King
  • Patent number: 7530394
    Abstract: A method of servicing a wellbore comprising placing in the wellbore a cement composition comprising light-burned magnesium oxide, water and an alkaline metal chloride, and allowing the composition to set. A method of cementing comprising preparing a cement composition comprising a light-burned magnesium oxide, water and an alkaline metal chloride, and allowing the composition to set.
    Type: Grant
    Filed: June 30, 2006
    Date of Patent: May 12, 2009
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Ashok K. Santra, Rocky Fitzgerald
  • Patent number: 7527098
    Abstract: A wellbore may be cemented by preparing a cementitious composition comprising water, a metal oxide or hydroxide compound, a phosphate compound, a borate compound, and a sugar, followed by displacing the cementitious composition into the wellbore. The metal oxide or hydroxide compound reacts with the phosphate compound in the wellbore to set into a hard mass. The synergistic effect of the borate compound and the sugar may increase a thickening time of the cementitious composition to in a range of from about 2 hours to about 11 hours at ambient temperatures in the wellbore. As such, the thickening time is sufficient to allow the cementitious composition to be placed in its desired location in the wellbore before setting.
    Type: Grant
    Filed: May 27, 2004
    Date of Patent: May 5, 2009
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Ashok K. Santra, Russell M. Fitzgerald
  • Patent number: 7407545
    Abstract: A cementitious veneer and laminate composition is provided. The cementitious laminate composition includes a substrate, a primer layer applied to the substrate, the primer layer comprising a mixture of polyvinyl alcohol catalyst, Portland cement, and sand; and a cementitious veneer layer applied to the primer layer, the veneer layer comprising a mixture of magnesium sulfate, filler, magnesium oxide, gypsum cement, and polyvinyl alcohol catalyst. The polyvinyl alcohol catalyst comprises a mixture of polyvinyl alcohol fibers dissolved in water and mixed with butylene carbonate. The veneer layer is applied to the substrate and primer layer by means including spraying and manual spreading. The veneer layer can be ornamentally manipulated either before or after curing of the veneer layer. The veneer composition can be formed into laminated tiles or panels for use in building applications.
    Type: Grant
    Filed: March 28, 2005
    Date of Patent: August 5, 2008
    Assignee: Stonelace
    Inventor: Christine E. Wallner
  • Patent number: 7347896
    Abstract: Novel hydraulic cements are disclosed that include reactive magnesium oxide prepared by low temperature calcination. The cements can be formulated to suit a large number of applications with various setting times, strength and levels of sustainability either by adding iron salts such as ferrous sulfate or blending with other compatible faster setting hydraulic cements such as Portland cement or by using both methods. The compositions are able to incorporate relatively large amounts of low cost pozzolans such as fly ash to advantage as well as wastes. Many excellent properties are exhibited and in particular good comprehensive strength and resistance to sulfates is able to be achieved.
    Type: Grant
    Filed: December 21, 2004
    Date of Patent: March 25, 2008
    Assignee: Tececo Pty Ltd
    Inventor: Aubry John Weston Harrison
  • Publication number: 20080000640
    Abstract: A method of servicing a wellbore comprising placing in the wellbore a cement composition comprising light-burned magnesium oxide, water and an alkaline metal chloride, and allowing the composition to set. A method of cementing comprising preparing a cement composition comprising a light-burned magnesium oxide, water and an alkaline metal chloride, and allowing the composition to set.
    Type: Application
    Filed: June 30, 2006
    Publication date: January 3, 2008
    Applicant: Halliburton Energy Services, Inc.
    Inventors: Ashok K. Santra, Rocky Fitzgerald
  • Patent number: 7246665
    Abstract: The present invention relates to settable compositions that comprise magnesium oxide and at least one divalent salt and associated methods of use. In some embodiments, the present invention discloses methods of a forming a hardened mass comprising providing a settable composition comprising magnesium oxide, and a brine comprising water and a divalent salt; placing the settable composition into a desired location; and allowing the settable composition to set to form the hardened mass. In other embodiments, the present invention discloses methods of forming a hardened mass in a subterranean formation comprising placing a brine comprising water and a divalent salt into the subterranean formation; contacting the brine with magnesium oxide; and allowing the brine and the magnesium oxide to react to form the hardened mass. In other embodiments, the present invention discloses methods forming a casing in a well bore, and converting a drilling fluid to a settable composition.
    Type: Grant
    Filed: May 3, 2004
    Date of Patent: July 24, 2007
    Inventors: Stephen W. Almond, Ryan M. Foster
  • Patent number: 6664215
    Abstract: The disclosure is directed to a composition for controlling wellbore fluid and gas invasion including methods for using said composition. The composition of the invention is a flowable slurry preferably comprising about 70 to 30% by weight of magnesium oxychloride and about 70 to 30% by weight of water. The composition is a flowable slurry at composition temperatures below about 60° C. and sets to form a substantially solid mass upon reaching a composition temperature of about 60-68° C. The phase transition is rapid, thereby limiting or avoiding formation of gel states which contribute to incomplete wellbore seals. The rapid set of the slurry further avoids invasive contamination of earthen formations surrounding the wellbore. The composition has a near-linear relationship between the time required for the phase transition to occur and the composition temperature at which the phase transition occurs.
    Type: Grant
    Filed: June 6, 2000
    Date of Patent: December 16, 2003
    Inventor: Brian H. Tomlinson
  • Patent number: 6159280
    Abstract: A cementitious material having improved resistance to water, increased strength, increased resistance to deteriorating processes and which is toxic to certain microorganisms and repellent to certain roach species, said material comprising on a dry mix basis, in % by weight, about 2% to 5% copper oxide, about 1% to 5% condensed silica fume, about 1.5% siloxane coated calcium hydroxide, about 53.5% to 60.5% dolomitic limestone and effective amounts of pigments and fillers.
    Type: Grant
    Filed: June 4, 1998
    Date of Patent: December 12, 2000
    Assignee: Hubbellite America, Inc.
    Inventor: William V. Ryan
  • Patent number: 5645637
    Abstract: Foamable magnesite cement, comprising a cement selected from magnesium oxychloride and magnesium oxysulphate cement, or a mixture thereof, together with one or more organic carboxylic acid(s) having a foaming coefficient lower than 1.80, and/or their anhydride(s) and/or their salt(s).
    Type: Grant
    Filed: May 26, 1995
    Date of Patent: July 8, 1997
    Assignee: Baran Advanced Materials 94 Ltd.
    Inventor: Itzhak Yaniv
  • Patent number: 5571317
    Abstract: Magnesite bonds reinforced with selected fibers have improved resistance to cracking and disintegration in use. Particular embodiments include fiber-reinforced abrasive tools based on magnesite bonds which have improved bond integrity in dry-grinding applications.
    Type: Grant
    Filed: February 14, 1995
    Date of Patent: November 5, 1996
    Assignee: Western Atlas Inc.
    Inventors: Stephen M. Freeman, David B Hanson
  • Patent number: 5281270
    Abstract: Retarded acid soluble well cement compositions which set into hard substantially impermeable masses and methods of using such compositions for forming removable cement plugs or seals in subterranean zones are provided. The compositions are comprised of magnesium oxychloride cement and a set retarder comprised of a water soluble borate and a sugar.
    Type: Grant
    Filed: December 23, 1992
    Date of Patent: January 25, 1994
    Assignee: Halliburton Company
    Inventors: Patty L. Totten, Bobby G. Brake, Edward F. Vinson
  • Patent number: 5180429
    Abstract: A magnesium concrete which comprises magnesium oxide in about 100 parts; magnesium chloride in a range of about 40 to about 80 parts; mineral aggregates in a range of about 300 to about 500 parts; sublimates of carnallite chlorates in a range of about 20 to about 40 parts; and sodium siliceous-fluoride in a range of about 1 to about 2 parts.
    Type: Grant
    Filed: November 22, 1991
    Date of Patent: January 19, 1993
    Assignee: Steven M. Lasell
    Inventor: Robert M. Khasanov
  • Patent number: 5110361
    Abstract: Magnesium oxychloride cement compositions, products, and uses thereof, are provided by mixing magnesium oxide, a magnesium chloride solution, and aggregate particles. The cement compositions are adapted for use in repairing damaged concrete surfaces, casting both functional and decorative forms, and coating surfaces with stucco. The addition of a small amount of acid to the cement composition promotes a more complete cementing reaction. The resulting cement product exhibits substantially increased strength and water resistance. Brine from the Great Salt Lake is a preferable source of the magnesium chloride solution. Brine from the Great Salt Lake results in a cement composition substantially stronger than cement produced from a pure magnesium chloride solution. Use of the Great Salt Lake brine as the gauging solution in lieu of a gauging solution made from magnesium chloride flakes (hexahydrate) reduces manufacturing costs of magnesium oxychloride cement products.
    Type: Grant
    Filed: April 1, 1991
    Date of Patent: May 5, 1992
    Assignee: CAC, Inc.
    Inventors: Russell I. Alley, George E. Caine
  • Patent number: 5049197
    Abstract: A settable magnesium cement composition, useful for floor leveling or for the preparation of molded products, has a two part mix. The first part includes magnesium oxide, while the second part includes magnesium chloride component and a particulate fibrous material compound, ideally a coarse, fibrous long-stranded sawdust, known as green fibrous sawdust, having a moisture content of about 40-50% by weight.
    Type: Grant
    Filed: April 19, 1990
    Date of Patent: September 17, 1991
    Assignee: Magnatex Industries Pty. Limited
    Inventor: Graham K. Brown