Organic Material Containing Patents (Class 106/724)
  • Patent number: 8927097
    Abstract: A molded, decorative article having a fiber-reinforced geo-composite wall with a thickness of between 4-10 mm and a method of manufacturing the same, the fiber-reinforced geo-composite wall comprising, before curing, predominately 45-55 by weight % mineral-based type III clinker, 24-28 by weight % water, and 8-9 by weight % hydration control agent, the combination of clinker, water, and hydration control agent forming a basic water-reactive rapid-setting cementious binder, the hydration control agent controlling curing time of the water-reactive rapid-setting cementious binder, 1-2 by weight % combination of micro-fibers and macro-fibers dispersed evenly within the cementious binder, the micro-fibers being 3-6 mm and the macro-fibers being 7-25 mm in length, 0.03-0.10 by weight % combination of rheology modifier, polymer modifier, and moisture retention agent, 0-0.
    Type: Grant
    Filed: March 20, 2013
    Date of Patent: January 6, 2015
    Assignee: PEBA Trading & Manufacturing Corporation
    Inventor: David R. Mune
  • Patent number: 8926855
    Abstract: Building materials include a dampening layer which contains a plaster and a viscoelastic polymer, such as polyvinyl butyral. The dampening layer may also include a barium salt. Methods of making a sound dampening material include providing a plaster mixture. The mixture may include a viscoelastic polymer and/or a barium salt. The plaster mixture is combined with water and/or a viscoelastic polymer dispersion, to form a slurry. The slurry is applied to a surface and set to form a sound dampening layer.
    Type: Grant
    Filed: December 20, 2012
    Date of Patent: January 6, 2015
    Assignee: Georgia-Pacific Gypsum LLC
    Inventors: Vincent B. Thomas, Jeffrey Thomas Fields
  • Patent number: 8912255
    Abstract: The present disclosure describes a self-consolidating concrete (SCC) mixture having a compressive strength of at least 25 MPa at 28 days of age. In accordance with one embodiment, there is provided an SCC mixture, comprising: a mixture of coarse aggregate (CA), fine aggregate (FA), very fine aggregate (VFA), cementitious materials including Portland cement or Portland limestone cement, an ASTM C494 Type F polycarboxylate ether high range water reducer, and water, wherein the VFA has a particle size distribution in which 95% to 100% passes a 2.5 mm sieve and in which 20% to 100% passes a 75 ?m sieve.
    Type: Grant
    Filed: August 2, 2012
    Date of Patent: December 16, 2014
    Assignee: St. Marys Cement Inc. (Canada)
    Inventors: Mark Wells, Philip Zacarias, Bryan Schulz, Matthew Stokkermans
  • Patent number: 8869895
    Abstract: Compositions and methods are directed to a cement composition for use in a subterranean formation. In an embodiment the cement composition comprises: (A) cement; (B) water; and (C) a polymer, wherein the polymer: (i) consists essentially of a monomer or monomers selected from the group consisting of acrylic acid, esters of acrylic acid, maleic acid, methacrylic acid, esters of methacrylic acid, itaconic acid, fumeric acid, citraconic acid, mesoconic acid, and any alkali metal, alkaline earth metal, or ammonium salt of any of the foregoing, and any combination of any of the foregoing; (ii) has the following characteristics: (a) is water soluble; and (b) is biodegradable; and (iii) is capable of providing: (a) a thickening time of at least 2 hours for a test composition maintained under a temperature condition of 190° F. and a pressure of 5,160 psi; and (b) an initial setting time of less than 24 hours for the test composition maintained under a temperature condition of 217° F.
    Type: Grant
    Filed: December 8, 2009
    Date of Patent: October 28, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Girish Dinkar Sarap, Sandip Prabhakar Patil, Dibyadarshani Senapati, Abhijit Tarafdar
  • Patent number: 8871021
    Abstract: Concrete mixtures for use with air entraining agents and supplementary cementitious materials are achieved using a carbon encapsulating agent. The carbon encapsulating agent can include a nitrilotrisethanol aliphatic soap.
    Type: Grant
    Filed: March 8, 2012
    Date of Patent: October 28, 2014
    Assignee: Staker & Parson Companies
    Inventor: Lonnie James Gray
  • Patent number: 8864901
    Abstract: Inorganic polymer compositions and methods for their preparation are described herein. The compositions include the reaction product of a reactive powder, an activator, and optionally a retardant. The reactive powder includes fly ash, calcium sulfoaluminate cement, and less than 10% by weight portland cement. In some examples, the composition is substantially free from alkanolamines. In some examples, the ratio of water to reactive powder is from 0.06:1 to less than 0.2:1. Also described herein are building materials including the compositions.
    Type: Grant
    Filed: November 30, 2011
    Date of Patent: October 21, 2014
    Assignee: Boral IP Holdings (Australia) Pty Limited
    Inventors: Redmond Richard Lloyd, Louise Margaret Keyte, Russell L. Hill, Zhaozhou Zhang, Mark Hollett, Li Ai
  • Patent number: 8821630
    Abstract: The invention relates to compositions and methods for modifying cementitious materials such as by reducing setting time. Polymer compositions of the invention are derived by polyetherifying mono-glycerols, optionally with alkylene glycols, to obtain polyglycerol homopolymers or copolymers, and then carboxylating the obtained polyglycerol homopolymers and/or copolymers with an organic acid having at least two carboxylic functionalities. The set retardation effect of the carboxylated-carboxylic polyglycerol polymer compositions in cementitious materials is reduced is compared to polyglycerol polymer not having the carboxylated-carboxylic groups, while its water reducing ability is maintained without loss of early compressive strength. Cementitious compositions and methods involving the carboxylated-carboxylic polyglycerol are also covered by the invention.
    Type: Grant
    Filed: May 6, 2011
    Date of Patent: September 2, 2014
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Lawrence L. Kuo, Izabela Goc-Maciejewska, Romain Faivre
  • Publication number: 20140230696
    Abstract: The present invention relates to the production of ternesite clinkers containing 20 to 100% by weight C5S2$ and less than 15% by weight C4A3$, and to the use of ternesite as an additive to Portland cement or Portland composite cement, and to a binder containing 20 to 95% by weight Portland cement (clinker) and 80 to 5% by weight ternesite (clinker).
    Type: Application
    Filed: July 16, 2012
    Publication date: August 21, 2014
    Applicant: HEIDELBERGCEMENT AG
    Inventors: Frank Bullerjahn, Dirk Schmitt, Mohsen Ben Haha, Barbara Batog, Linda Irbe
  • Patent number: 8808450
    Abstract: A method of servicing a wellbore comprising placing a composition comprising cement, water, and a heat sink material into a wellbore, and allowing the composition to set, wherein at least a portion of the heat sink material undergoes a phase transition by absorbing at least a portion of the heat released upon hydration of the cement. A method of completing a wellbore, comprising forming a wellbore in a subterranean formation comprising permafrost, gas hydrates, or both, preparing a cement composition comprising cement, water, and a heat sink material, placing the cement composition into an annulus formed between a casing and the wellbore, and allowing the composition to set, wherein at least a portion of the heat sink material undergoes a phase transition by absorbing at least a portion of the heat released upon hydration of the cement, thereby reducing an amount of heat transferred from the annular cement to the surrounding permafrost and/or gas hydrates.
    Type: Grant
    Filed: January 21, 2010
    Date of Patent: August 19, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventors: B. Raghava Reddy, Bryan K. Waugh
  • Patent number: 8808449
    Abstract: A foamed concrete having a density from 100 to 800 kg/m3 including by mass relative to the total mass of the concrete: a cement; water; from 0.01 to 5% of a water-reducing agent, plasticizer or superplasticizer; from 0.45 to 5% of a foaming agent relative to the amount of water; from 0.01 to 5% of a water-soluble calcium salt; inorganic particles from 0.1 to 300 ?m in size; the ratio of foaming agent to calcium salt being from 0.3 to 0.8; the foamed concrete including 10% or more by mass of slag.
    Type: Grant
    Filed: February 16, 2011
    Date of Patent: August 19, 2014
    Assignee: Lafarge
    Inventors: Pierre-Henri Jezequel, Benoit Mathonier
  • Patent number: 8801851
    Abstract: A foamed concrete having a density from 100 to 800 kg/m3 including by mass relative to the total mass of the concrete: a cement; water; from 0.01 to 5% of a water-reducing agent, plasticizer or superplasticizer; from 0.45 to 5% of a foaming agent relative to the amount of water; from 0.01 to 5% of a water-soluble calcium salt; inorganic particles from 0.1 to 300 ?m in size; the ratio of foaming agent to calcium salt being from 0.3 to 0.8; excluding foamed concretes including 10% or more by mass of slag.
    Type: Grant
    Filed: February 16, 2011
    Date of Patent: August 12, 2014
    Assignee: Lafarge
    Inventors: Pierre-Henri Jezequel, Benoit Mathonier
  • Patent number: 8802753
    Abstract: An additive for manufacturing permeable concretes with improved properties and method for manufacturing the same are provided. The additive comprises in a total composition: 33.70 to 54.90% water; 0.30 to 0.50% defoamer; 0.30 to 0.40% bactericide; 0.30 to 0.50% polyglycol; 7.20 to 24.00% of a combination of emulsifiers; 15.50 to 17.00% moisturizer; 0.8 to 22.90% dispersant; and 0.70 to 1.00% biopolymer. The additive for manufacturing permeable concretes can be added to any type of stony aggregate and/or cement improving the product's mechanical properties required in each step before, during, and after of the setting.
    Type: Grant
    Filed: June 28, 2012
    Date of Patent: August 12, 2014
    Inventor: Jaime Grau Genesias
  • Publication number: 20140205751
    Abstract: A mortar composition in the form of a dry powder, ready for use, comprising at least one powdery binder and at least one aggregate, as well as possibly at least one standard additive and/or adjuvant, and formed from particles, at least some of which, referred to as fine particles, are liable to produce an emission of dust, characterised in that it also comprises a fluid additive that consists of least one non-polar hydrocarbon organic substance and that has a capacity for agglomeration of the said fine particles, and in that the dry mortar composition comprises agglomerates of line particles formed by the fluid additive.
    Type: Application
    Filed: March 7, 2014
    Publication date: July 24, 2014
    Applicant: PAREXGROUP SA
    Inventors: Alain Laudet, Daniel Daviller
  • Patent number: 8784557
    Abstract: A mix design for a polymer modified cement pavement overlay is disclosed along with a method of making and using the mix on a variety of pavement substrates. The mix includes a specific dry combination of: finely divided Elotex 2311 and 2322 or 2320 polymers; Type 2 or C144 aggregate or equivalent; Type I/II cement; Type F or Type C fly ash; intermediate length polymer microfibers; plasticizer; (optionally) calcium chloride or equivalent; (optionally) quikrete retarder or equivalent; and water. The mixture is combined and applied to the substrate in depths of about ? to about 1 inch in lifts. The mixture is allowed to cure for 3-4 hours before being returned to traffic. The placed mixture exhibits preferred qualities of substrate adhesion, flexibility, tire friction, and wearability.
    Type: Grant
    Filed: February 2, 2011
    Date of Patent: July 22, 2014
    Assignee: Pavement Surface Coatings, LLC
    Inventor: Nicholas Reck
  • Patent number: 8771414
    Abstract: A foaming agent solution, cement material and concrete replacement product are described which include blood hydrolysates. The blood hydrolysates may be present in the foaming agent solution in the range 5-30% by volume of the solution.
    Type: Grant
    Filed: December 30, 2009
    Date of Patent: July 8, 2014
    Assignee: Genesis Global Limited
    Inventor: Anthony S. M. George
  • Patent number: 8741388
    Abstract: Techniques and compositions for applying films to a variety of substrates, from water-borne coating compositions, are provided. The techniques involve providing desiccant and applying the desiccant with water-borne film-forming composition, in application to a substrate. The desiccant composition provides for take up of free water in of the film-forming composition, without total reliance on ambient conditions, to advantage. Compositions, methods, techniques and resulting constructions are described. The techniques can be applied in wet thick film applications, but are not limited to such applications.
    Type: Grant
    Filed: December 8, 2011
    Date of Patent: June 3, 2014
    Assignee: Ployguard Products, Inc.
    Inventors: Frank Wickert, Ted Edward DeZurik
  • Patent number: 8728229
    Abstract: The present invention provides a cement slurry composition, containing a hydraulic cement material, (A) a first water-soluble low molecular weight compound and (B) a second water-soluble low molecular weight compound differing from the compound (A), wherein a combination of the compounds (A) and (B) is (I) the compound (A) selected from cationic surfactants and the compound (B) selected from anionic aromatic compounds; or (II) the compound (A) selected from cationic surfactants and the compound (B) selected from brominated compounds, and in the compound (A), a ratio of compounds having a hydrocarbon group of 18 or more carbon atoms is not less than 45% by weight.
    Type: Grant
    Filed: June 11, 2009
    Date of Patent: May 20, 2014
    Assignee: Kao Corporation
    Inventors: Koji Koyanagi, Toshiharu Kojima, Hotaka Yamamuro
  • Patent number: 8728231
    Abstract: Compositions and methods are directed to a cement composition for use in a subterranean formation. In an embodiment the cement composition comprises: (A) cement; (B) water; and (C) a polymer, wherein the polymer: (i) consists essentially of a monomer or monomers selected from the group consisting of acrylic acid, esters of acrylic acid, maleic acid, methacrylic acid, esters of methacrylic acid, itaconic acid, fumeric acid, citraconic acid, mesoconic acid, and any alkali metal, alkaline earth metal, or ammonium salt of any of the foregoing, and any combination of any of the foregoing.
    Type: Grant
    Filed: March 29, 2012
    Date of Patent: May 20, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Girish Dinkar Sarap, Sandip Prabhakar Patil, Dibyadarshani Senapati, Abhijit Tarafdar
  • Patent number: 8709534
    Abstract: A formwork release composition containing formwork release oil, which contains a hydrophobic metal oxide and/or metal sulphide component is disclosed. Photocatalytically active compounds, such as particular semiconductors and in particular TiO2, are particularly suitable. The invention also concerns the use of the formwork release composition for producing exposed concrete. The concrete and mortar products thus produced are characterized by a homogeneous surface with self-cleaning properties that gives an enhanced resistance against weathering and a much longer lasting brilliance and whiteness.
    Type: Grant
    Filed: May 14, 2009
    Date of Patent: April 29, 2014
    Assignee: Construction Research & Technology GmbH
    Inventors: Andreas Eisenreich, Sergi Vilches, Andres Fernandez, Josep Gatell, Uwe Holland
  • Patent number: 8679247
    Abstract: The present invention relates to a hydraulic setting mixture comprising: a) 6% to 25% by weight of cement, b) 50% to 90% by weight of at least one aggregate, and c) 0.001% to 8% by weight of at least one fluoroorganyl-substituted silicon compound, and also to materials produced from this mixture, more particularly components, concrete articles or mouldings. The invention further relates to the use of a hydraulic setting mixture of the invention for producing materials, more particularly components, concrete articles or mouldings, for example as face concrete, where the surface of the materials exhibits only relatively low soiling tendency (“easy-to-clean” property) even on abrasion.
    Type: Grant
    Filed: March 30, 2011
    Date of Patent: March 25, 2014
    Assignee: Evonik Degussa GmbH
    Inventors: Manuel Friedel, Spomenko Ljesic, Philipp Albert, Burkhard Standke
  • Patent number: 8668773
    Abstract: A mortar composition in the form of a dry powder, ready for use, comprising at least one powdery binder and at least one aggregate, as well as possibly at least one standard additive and/or adjuvant, and formed from particles, at least some of which, referred to as fine particles, are liable to produce an emission of dust, characterized in that it also comprises a fluid additive that consists of least one non-polar hydrocarbon organic substance and that has a capacity for agglomeration of the said fine particles, and in that the dry mortar composition comprises agglomerates of fine particles formed by the fluid additive.
    Type: Grant
    Filed: November 2, 2006
    Date of Patent: March 11, 2014
    Assignee: Parexgroup SA
    Inventors: Alain Laudet, Daniel Daviller
  • Patent number: 8652250
    Abstract: A composition used for high-strength impermeable concrete. The composition contains sand, stone, cement, water reducer, water and reinforced impermeable sand. The reinforced impermeable sand includes aeolian sand and binder covering the surface of the aeolian sand. The reinforced impermeable sand can fill the gap between the sand and the stone, and well combine various components in the composition, and suppress the seepage phenomenon of the molded concrete, thereby greatly improving the strength and impermeability of the concrete.
    Type: Grant
    Filed: September 9, 2010
    Date of Patent: February 18, 2014
    Inventors: Shengyi Qin, Yihai Jia, Zhenbang Wang, Huan Wang, Wenxing Hu
  • Patent number: 8652580
    Abstract: A manufacturing method of tiles includes the steps of: preparing mixed powder having a water content of 2 to 7% by mixing 30 to 80 parts by weight of calcium hydroxide powder or dolomite plaster powder, 20 to 70 parts by weight of porous aggregate, 0.1 to 5 parts by weight of a first photocatalyst and water; filling the mixed powder into a mold of a molding machine; forming a formed body by pressurizing the filled mixed powder; curing the formed body in a carbon dioxide atmosphere; and forming a thin layer made of a second photocatalyst on a surface of the formed body.
    Type: Grant
    Filed: January 28, 2010
    Date of Patent: February 18, 2014
    Assignee: Tagawasangyo Co., Ltd.
    Inventors: Nobuyoshi Yukihira, Tetsuro Oike, Katsuyuki Nakano
  • Patent number: 8641818
    Abstract: Cement compositions containing biowaste ash and methods of cementing in subterranean formations using such cement compositions. Examples of suitable biowaste ash include agricultural waste ash, municipal waste ash, waste-water treatment waste ash, animal waste ash, non-human-non-animal industrial waste ash, and combinations thereof.
    Type: Grant
    Filed: March 12, 2012
    Date of Patent: February 4, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Craig W. Roddy
  • Patent number: 8623135
    Abstract: A method of cementing in a subterranean formation comprising the steps of: (A) introducing a cement composition into the subterranean formation, the cement composition comprising: (i) cement; (ii) water; and (iii) a high-density additive selected from the group consisting of silicon carbide, sintered bauxite, and any combination thereof, wherein the cement composition has a density of at least 16 pounds per gallon; and (B) allowing the cement composition to set. According to an embodiment, the high-density additive is in a concentration of at least 30% by weight of the cement. A cement composition for use in an oil or gas well comprises: (A) cement; (B) water; and (C) a high-density additive selected from the group consisting of silicon carbide, sintered bauxite, and a combination thereof, wherein the high-density additive is in a concentration of at least 30% by weight of the cement, and wherein the cement composition has a density of at least 16 pounds per gallon.
    Type: Grant
    Filed: February 7, 2013
    Date of Patent: January 7, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Rahul Chandrakant Patil, Sandip Prabhakar Patil, Keith Armstrong
  • Patent number: 8608847
    Abstract: The invention relates to additives for hydraulic binders and systems produced from them, such as concrete and mortar. In particular, the present invention relates to a setting and hardening accelerator for hydraulic binders produced by means of reaction of a calcium compound CV with a silicon compound SV and addition of a phosphonic acid derivative, as well as its production.
    Type: Grant
    Filed: August 24, 2011
    Date of Patent: December 17, 2013
    Assignee: Sika Technology AG
    Inventors: Christian Buerge, Franz Wombacher, Christophe Kurz, Beat Marazzani, Gilbert Maeder, Ueli Sulser
  • Patent number: 8596363
    Abstract: A cement composition for cementing an oil or gas well includes Portland cement, water and a sulfur component. The cement composition may be used to cement a well bore by creating a cement slurry including the sulfur component, pumping the slurry into the well bore to a selected location and allowing it to solidify.
    Type: Grant
    Filed: August 8, 2012
    Date of Patent: December 3, 2013
    Assignee: Sanjel Limited Partnership
    Inventors: Amir Mahmoudkhani, Neil Warrender
  • Patent number: 8591646
    Abstract: The present invention relates to construction materials comprising at least one binder, at least one oil-containing filler and at least one metallate additive according to formula (1): (RO)m-M-(Oa—Xb—R?c—Yd)n??(1) wherein M is one of titanium and zirconium. The present invention also relates to methods of preparing and using the inventive construction materials. The inventive construction material compositions are capable of utilizing oil-containing fillers in which the oil is stable in the final composition and the desired mechanical properties of the construction material are maintained or improved.
    Type: Grant
    Filed: August 17, 2011
    Date of Patent: November 26, 2013
    Assignee: S&E Innovative Technologies LLC
    Inventor: Salvatore J. Monte
  • Patent number: 8580030
    Abstract: A concrete mix useful for producing concrete products having anti-efflorescence properties and a method for making such concrete products are provided. The concrete mix includes a hydraulic cement binder, aggregates and as an additive an ultrafine particulate material including carrier particles being surface treated with an efflorescence control agent. The method for making concrete includes a first step of mixing the hydraulic cement binder, aggregates, water and the ultrafine particulate material, a second step of pouring the mixture so obtained into a form, and a third step of curing the mixture.
    Type: Grant
    Filed: September 17, 2010
    Date of Patent: November 12, 2013
    Assignee: Omya International AG
    Inventors: Berndt Kanduth, Jean-Bernard Gelinas
  • Publication number: 20130289167
    Abstract: Compositions comprising a hydraulic binder such as cement or gypsum and a hydroxypropyl guar derivative that comprises unsubstituted linear or branched C6-C8 alkyl chains possess excellent water retention characteristics.
    Type: Application
    Filed: December 15, 2011
    Publication date: October 31, 2013
    Applicant: Lamberti SpA
    Inventors: Barbara Biasotti, Max Giudici, Ugo Pfeiffer, Valentina Langella, Giovanni Floridi, Giuseppe Li Bassi
  • Patent number: 8568527
    Abstract: A durable concrete composition includes a cementitious material comprising cement and ground expanded perlite, coarse aggregate, fine aggregate, and sufficient water for adequate workability. The resulting concrete displays a number of superior properties to conventional concrete, including extremely high thermal resistance coupled with high strength, low chloride ion permeability, and good early strength. The ground expanded perlite is a readily available material and the finished concrete is extremely cost effective for applications where a high strength structural concrete must withstand high temperatures. The mixture can be handled and placed by conventional methods and is compatible with existing conventional concrete additives.
    Type: Grant
    Filed: January 24, 2012
    Date of Patent: October 29, 2013
    Inventors: Terry L. Anderson, John Andrew Coleman, Neal S. Berke
  • Patent number: 8562736
    Abstract: This invention relates to a new class of chemical admixtures for hydraulic cement compositions such as pastes, mortars, grouts and concretes. The cement compositions are comprised of ordinary Portland cement, blended cements, or non-Portland cements made with Supplementary Cementitious Materials. The admixtures contain complexes of metals with derivatives of hydroxycarboxylic acids, and improve properties of cement compositions, including setting, hardness, compressive strength, shrinkage, and freeze-thaw resistance. The invention discloses a method for improving the properties of hydraulic cements by adding the disclosed chemical admixtures to cement compositions, and also discloses methods of preparing said admixtures.
    Type: Grant
    Filed: September 22, 2012
    Date of Patent: October 22, 2013
    Inventor: Iqbal Gill
  • Patent number: 8551243
    Abstract: Concrete reinforced with nanostructures and reinforcing concrete methods are provided having cement and dispersion including water, a surfactant, carbon nanotubes having on the external surfaces thereof carbon atoms substituted by atoms of another element or other elements, and carbon nanotubes possessing chemical groups on the surface thereof.
    Type: Grant
    Filed: December 13, 2010
    Date of Patent: October 8, 2013
    Assignee: Urbanizaciones Imoboliarias del Centro S.A. de C.V.
    Inventors: Jose Antonio Soto Montoya, Mauricio Martinez Alanis, Mauricio Terrones Maldonado, Humberto Terrones Maldonado, Daniel Ramirez Gonzalez
  • Patent number: 8551241
    Abstract: A method of making a rapid setting lightweight cementitious composition with improved compressive strength for products such as boards is disclosed. The method mixes fly ash, alkali metal salt of citric acid and lightweight aggregate with water. Compositions which include fly ash, alkali metal salts of citric acid and lightweight aggregate are also disclosed.
    Type: Grant
    Filed: January 31, 2013
    Date of Patent: October 8, 2013
    Assignee: United States Gypsum Company
    Inventor: Marianela Perez-Pena
  • Patent number: 8551244
    Abstract: A self-adaptive cement system includes cement, water and at least one additive that reacts or/and expands in contact with oil and gas. Several chemical products have been identified including rubber alkylstyrene, polynorbornene, resins such precrosslinked substituted vinyl acrylate copolymers and diatomaceous earth. These additives have the effect of making the cement self-healing in the event of physical failure or damage such as micro-annuli. The self healing property is produced by the contact with subterranean hydrocarbon fluids, the potential repair mechanism is thus activated if and when needed in case of start of loss of zonal isolation. In another embodiment, the expansion is deliberately induced by pumping a hydrocarbon fluid in the vicinity of the set cement.
    Type: Grant
    Filed: October 19, 2010
    Date of Patent: October 8, 2013
    Assignee: Schlumberger Technology Corporation
    Inventors: Sylvaine Le Roy-Delage, Dominique Guillot, Keith Dismuke, Erik Nelson
  • Patent number: 8551240
    Abstract: A cement retarder system for use in underground wells included a borate compound, an organophosphonate salt, and a copolymer formed from AMPS and a monomer selected from the group consisting of acrylic acid, acrylamide and mixtures thereof.
    Type: Grant
    Filed: March 3, 2010
    Date of Patent: October 8, 2013
    Assignee: Schlumberger Technology Corporation
    Inventors: Michel Michaux, Tatiana Pyatina
  • Patent number: 8550162
    Abstract: A retarder aid increases the applicable temperature range of phosphonate/borate cement-retarder systems to at least 302° C. (575° F.), and 207 MPa (30,000 psi). The retarder aid comprises a terpolymer of styrene sulfonate, maleic anhydride and acrylate of ethylene oxide. Cement slurries containing the retarder and retarder aid may be used for both primary-cementing and remedial-cementing applications.
    Type: Grant
    Filed: June 28, 2011
    Date of Patent: October 8, 2013
    Assignee: Schlumberger Technology Corporation
    Inventors: Michel Michaux, Jean-Philippe Caritey
  • Patent number: 8552092
    Abstract: A self-repairing concrete includes urea-formaldehyde resin polymer micro-capsules, in which the urea-formaldehyde resin polymer micro-capsules are mixed for a fixed function of micro-cracks. The quality mixture ratio is: concrete/micro capsules/water=100:1-15:15-50. The manufacturing method is weighing a full amount of water in a container, adding urea-formaldehyde resin polymer micro-capsules, stirring, until fully dispersed microcapsules; pouring the water into the mixing container, adding the corresponding quality of cement; stirring; adding sand and gravel filling materials, conducting worksite watering, ? volume for each time, vibrating, and air exhausting; until the paste filling mold.
    Type: Grant
    Filed: October 24, 2008
    Date of Patent: October 8, 2013
    Assignees: Shenzhen University
    Inventors: Feng Xing, Zhuo Ni
  • Patent number: 8535436
    Abstract: The use of cyclohexanepolycarboxylic acid derivatives for reducing or minimizing the dust emission when handling pulverulent construction chemistry products, processes for the preparation of the pulverulent construction chemistry products and hydraulically setting materials containing the cyclohexanepolycarboxylic acid derivatives according to the invention are proposed.
    Type: Grant
    Filed: May 28, 2009
    Date of Patent: September 17, 2013
    Assignee: Construction Research & Technology GmbH
    Inventors: Josef Weichmann, Werner Stohr, Volker Schwarz, Klaus-Dieter Hoetzl, Boris Breitscheidel
  • Patent number: 8518177
    Abstract: Concrete mixtures containing a biological catalyst with silica leaching activity are generally described. In an example, in the presence of the biological catalyst a high strength, environmentally friendly, sustainable concrete mixture is produced. Further, described herein are methods for producing the concrete mixtures.
    Type: Grant
    Filed: December 7, 2010
    Date of Patent: August 27, 2013
    Assignee: Jadavpur University, West Bengal
    Inventors: Brajadulal Chattopadhyay, Saroj Mandal
  • Patent number: 8519016
    Abstract: A method of making a lightweight cementitious binder composition with improved compressive strength for products such as cementitious panels is disclosed. The method mixes fly ash, alkali metal salt of citric acid, alkali metal silicate, foaming agent for entraining air, water and in the preferred embodiment a foam stabilizing agent. Compositions which include fly ash selected from the group consisting of class C fly ash, class F fly ash and mixtures thereof, alkali metal salts of citric acid, alkali metal silicates, foaming agents, and preferably a foam stabilizer, such as polyvinyl alcohol, and do not require use of set retarders. Compositions containing class F fly ash can optionally contain Type III Portland cement.
    Type: Grant
    Filed: December 6, 2011
    Date of Patent: August 27, 2013
    Assignee: United States Gypsum Company
    Inventor: Marianela Perez-Pena
  • Patent number: 8506700
    Abstract: A dry composition including at least one binder and at least one silicone oil with the following formula (I): in which: Z1 and Z2, identical or different, independently represent a terminal group selected from the group consisting of a hydrogen atom; a hydroxyl; a linear or branched, optionally substituted C1 to C12 alkyl; a linear or branched, optionally substituted C2 to C12 alkenyl radical; a linear or branched, optionally substituted C1 to C12 heteroalkyl; an optionally substituted C5 to C10 cycloalkyl radical; and an optionally substituted C6 to C18 aryl radical; R1 and R2, identical or different, independently represent a hydrogen atom; a hydroxyl; a linear or branched, optionally substituted C1 to C12 alkyl; a linear or branched, optionally substituted C2 to C12 alkenyl radical; a linear or branched, optionally substituted C1 to C12 heteroalkyl; an optionally substituted C5 to C10 cycloalkyl radical; or an optionally substituted C6 to C18 aryl radical; m and n, identical or different, independen
    Type: Grant
    Filed: August 25, 2011
    Date of Patent: August 13, 2013
    Assignee: Sika Technology AG
    Inventors: Christophe Guyot, Laurent Guillot
  • Publication number: 20130192494
    Abstract: The present invention relates to a hydraulic setting mixture comprising: a) 6% to 25% by weight of cement, b) 50% to 90% by weight of at least one aggregate, and c) 0.001% to 8% by weight of at least one fluoroorganyl-substituted silicon compound, and also to materials produced from this mixture, more particularly components, concrete articles or mouldings. The invention further relates to the use of a hydraulic setting mixture of the invention for producing materials, more particularly components, concrete articles or mouldings, for example as face concrete, where the surface of the materials exhibits only relatively low soiling tendency (“easy-to-clean” property) even on abrasion.
    Type: Application
    Filed: March 30, 2011
    Publication date: August 1, 2013
    Applicant: EVONIK DEGUSSA GmbH
    Inventors: Manuel Friedel, Spomenko Ljesic, Philipp Albert, Burkhard Standke
  • Patent number: 8459356
    Abstract: A well treatment composition comprises a surfactant comprising a substituted ethoxylated phenol having at least one substituent, 1 to 14 moles of ethylene oxide, and the substituent being an alkyl, alkene, or alkyne with a carbon chain length in the range of 4 to 25, wherein the substituted ethoxylated phenol is selected from the group consisting of: ortho-, para-, or meta-substituted ethoxylated phenol; cardanol ethoxylate; derivatives thereof; and combinations of any of the foregoing. Preferably, the surfactant comprises cardanol ethoxylate, a substituted cardanol ethoxylate, and derivatives thereof. A method of cementing in a subterranean formation comprises: introducing a cement composition into the subterranean formation, wherein the cement composition comprises: (A) cement; (B) water; and (C) the surfactant; and allowing the cement composition to set.
    Type: Grant
    Filed: December 13, 2012
    Date of Patent: June 11, 2013
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Abhijit Tarafdar, Trissa Joseph, Vineet Vasant Sathe
  • Patent number: 8460458
    Abstract: A process for the preparation of the healing agent in cement-based materials and structures, wherein said healing agent comprises organic compounds and/or bacteria-loaded porous particles, which porous particles comprise expanded clay- or sintered fly-ash. Furthermore, said porous particles are intact spheres, broken or crushed particles derived from said intact spheres, having a specific density between 0.4 and 2 g cm?3.
    Type: Grant
    Filed: April 20, 2012
    Date of Patent: June 11, 2013
    Assignee: Technische Universiteit Delft
    Inventor: Hendrik Marius Jonkers
  • Patent number: 8460457
    Abstract: The present invention discloses compositions and methods wherein air entrained in cementitious materials at least one air-entraining cement additive is detrained using an ethoxylated, propoxylated fatty alcohol or alkylphenol having robustness for withstanding the harsh temperature and mechanical shearing effects of cement grinding mills. Exemplary air-entraining cement additives include a tertiary alkanolamine, a lignosulfonic acid or salt thereof, naphthalene sulfonate formaldehyde condensate, melamine sulfonate formaldehyde condensate, a glycol, a glycerin, or mixtures thereof.
    Type: Grant
    Filed: August 5, 2010
    Date of Patent: June 11, 2013
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Josephine Cheung
  • Patent number: 8454744
    Abstract: The use of a mixture of at least one polyol and at least one cyclohexanepolycarboxylic acid derivative for reducing or minimizing the dust emission when handling pulverulent construction chemistry products, processes for the preparation of the pulverulent construction chemistry products and hydraulically setting materials containing the mixture according to the invention are proposed.
    Type: Grant
    Filed: September 7, 2009
    Date of Patent: June 4, 2013
    Assignee: Construction Research & Technology GmbH
    Inventors: Klaus-Dieter Hoetzl, Silvia Dürndorfer, Joachim Riedmiller, Volker Schwarz, Werner Stohr
  • Patent number: 8419852
    Abstract: An application for a pre-mixed mortar, stucco or masonry composition includes a approximately 75% sand and 25% of a light-weight cement mix comprising a cement (either Portland cement or Gypsum), ground granulated blast furnace slag, sodium tall oil, sodium stearate, sodium C14-16 Alpha Olefin, linear alkyl benzene; and silicon dioxide.
    Type: Grant
    Filed: August 1, 2012
    Date of Patent: April 16, 2013
    Inventor: Jorge G Chiappo
  • Publication number: 20130087080
    Abstract: The present invention relates to a hydraulically setting mixture comprising: a) 6% to 25% by weight of cement, b) 50% to 90% by weight of at least one aggregate, and c) 0.01% to 8% by weight of at least one fluoroorganyl-substituted silicon compound, and also to materials produced from this mixture, more particularly components, concrete articles or mouldings. The invention further relates to the use of a hydraulically setting mixture of the invention for producing materials, more particularly components, concrete articles or mouldings, for example as facing concrete, where the surface of the materials exhibits only relatively low soiling tendency (“easy-to-clean” property) even on abrasion.
    Type: Application
    Filed: March 30, 2011
    Publication date: April 11, 2013
    Applicant: Evonik Degussa GmbH
    Inventors: Manuel Friedel, Philipp Albert, Burkhard Standke, Spomenko Ljesic
  • Patent number: 8394191
    Abstract: A cementitious composition including cement, water, and a rheology modifying additive (RMA) is provided. The inclusion of the RMA improves the cementitiuous composition's response to vibration, and dampens out differences due to minor fluctuations in initial slump of the composition. The RMA may include a dispersant for cementitiuous compositions. The cementitious composition may optionally include other admixtures or additives known in the industry. A method for making the cementitious composition is also provided.
    Type: Grant
    Filed: December 5, 2007
    Date of Patent: March 12, 2013
    Assignee: Construction Research & Technology GmbH
    Inventor: Jeffrey R. Bury