Including Means Forming A Flat Shape (e.g., Ribbon) Patents (Class 117/211)
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Patent number: 12227877Abstract: An apparatus for growing a crystal includes a growth chamber and a melt chamber thermally isolated from the growth chamber. The growth chamber includes: a growth crucible configured to contain a liquid melt; and a die located in the growth crucible, the die having a die opening and one or more capillaries extending from within the growth crucible toward the die opening. The melt chamber includes: a melt crucible configured to receive feedstock material; and at least one heating element positioned within the melt chamber relative to the melt crucible to melt the feedstock material within the melt crucible to form the liquid melt. The apparatus also includes at least one capillary conveyor in fluid communication with the melt crucible and the growth crucible to transport the liquid melt from the melt crucible to the growth crucible.Type: GrantFiled: June 23, 2023Date of Patent: February 18, 2025Assignee: II-VI DELAWARE, INC.Inventor: Nathan Stoddard
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Patent number: 12188147Abstract: A single crystal of the present disclosure is a plate-shaped body having two main surfaces that are opposite to each other, and has bubbles arranged in a plurality of line shapes parallel to the main surface in a region within a depth of 0.5 mm from either one of the main surfaces. Additionally, a single crystal of the present disclosure is a plate-shaped body having two main surfaces that are opposite to each other, and has bubbles arranged in a plurality of line shapes parallel to the main surface within a region from either one of the main surfaces to ¼ of the thickness which is a distance between the main surfaces.Type: GrantFiled: December 6, 2018Date of Patent: January 7, 2025Assignee: KYOCERA CORPORATIONInventors: Akeo Fukui, Masatoshi Harada
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Patent number: 11979965Abstract: Embodiments of the present disclosure describe a susceptor for chemical vapor deposition comprising a horizontal component with a top surface and a bottom surface, wherein the top surface is configured to support one or more wafers; a vertical component extending from the bottom surface of the horizontal component along a longitudinal axis that is substantially perpendicular to the horizontal component; and a hollow region within the vertical component. Embodiments of the present disclosure describe a susceptor for chemical vapor deposition comprising a horizontal plate with a top surface configured to support one or more wafers, a vertical rod integrated with and perpendicular to the horizontal plate, and a hollow region within the vertical rod for promoting temperature uniformity across the top surface of the horizontal plate.Type: GrantFiled: July 10, 2019Date of Patent: May 7, 2024Assignees: King Abdullah University of Science and Technology, King Fahd University of Petroleum and MineralsInventors: Xiaohang Li, Kuang-Hui Li, Hamad Saud Alotaibi
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Patent number: 11725304Abstract: An apparatus for growing a crystal includes a growth chamber and a melt chamber thermally isolated from the growth chamber. The growth chamber includes: a growth crucible configured to contain a liquid melt; and a die located in the growth crucible, the die having a die opening and one or more capillaries extending from within the growth crucible toward the die opening. The melt chamber includes: a melt crucible configured to receive feedstock material; and at least one heating element positioned within the melt chamber relative to the melt crucible to melt the feedstock material within the melt crucible to form the liquid melt. The apparatus also includes at least one capillary conveyor in fluid communication with the melt crucible and the growth crucible to transport the liquid melt from the melt crucible to the growth crucible.Type: GrantFiled: January 4, 2022Date of Patent: August 15, 2023Assignee: II-VI DELAWARE, INC.Inventor: Nathan Stoddard
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Patent number: 11248311Abstract: A sapphire ribbon of the present disclosure has a width, a thickness, and a length that are orthogonal to one another, a length direction is a growth direction, and the sapphire ribbon further has two main surfaces separate from each other in a thickness direction, and the width is at least 40 cm. Further, a monocrystalline ribbon manufacturing apparatus using EFG method according to the present disclosure includes a crucible having a width greater than a depth thereof, a die pair installed in the crucible and facing each other across a slit in the depth direction, a first heater and a second heater disposed around the crucible and facing each other in the depth direction, and a third heater and a fourth heater disposed around the crucible and facing each other in the width direction.Type: GrantFiled: March 23, 2020Date of Patent: February 15, 2022Assignee: KYOCERA CorporationInventors: Akeo Fukui, Keigo Hoshikawa
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Patent number: 11248312Abstract: An apparatus for growing a crystal includes a growth chamber and a melt chamber thermally isolated from the growth chamber. The growth chamber includes: a growth crucible configured to contain a liquid melt; and a die located in the growth crucible, the die having a die opening and one or more capillaries extending from within the growth crucible toward the die opening. The melt chamber includes: a melt crucible configured to receive feedstock material; and at least one heating element positioned within the melt chamber relative to the melt crucible to melt the feedstock material within the melt crucible to form the liquid melt. The apparatus also includes at least one capillary conveyor in fluid communication with the melt crucible and the growth crucible to transport the liquid melt from the melt crucible to the growth crucible.Type: GrantFiled: November 25, 2019Date of Patent: February 15, 2022Assignee: II-VI DELAWARE, INC.Inventor: Nathan Stoddard
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Patent number: 10995039Abstract: Methods for preparing ceramic matrix composites using melt infiltration are provided as well as the resulting ceramic matrix composites. The methods and products include the incorporation of a non-wetting coating to one or more sacrificial fibers. The one or more sacrificial fibers are removed, such as decomposed during pyrolysis, resulting in the formation of a plurality of functional features, in the form of regular and elongate channels along the ceramic matrix composite. During the removing of the one or more sacrificial fibers, the non-wetting coating remains on an interior surface of the plurality of functional features to block infiltration of an infiltrant to the plurality of functional features and deposition thereon. Alternatively, the sacrificial fibers may be removed subsequent to melt infiltration.Type: GrantFiled: December 20, 2019Date of Patent: May 4, 2021Assignee: GENERAL ELECTRIC COMPANYInventors: Daniel Gene Dunn, Henry Charles McGuigan
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Patent number: 10640304Abstract: An apparatus for locating a preform on a mold includes a preform handling tool and a force sensor coupled to the preform handling tool such that the force sensor is capable of sensing forces applied to the preform during handling of the preform by the preform handling tool. The apparatus includes a control device that is arranged and operable to move the preform handling tool relative to the mold. A method of locating the preform on the mold includes picking up the preform using the preform handling tool and placing the preform in a vicinity of the mold. Positions on the mold are mapped with an edge of the preform with the aid of the force sensor. The preform is paced on the mold according to the mapped positions.Type: GrantFiled: December 11, 2015Date of Patent: May 5, 2020Assignee: CORNING INCORPORATEDInventors: Kevin Thomas Morris, Andrew Nathan Nassau, Michael George Shultz, Matthew John Towner, Kevin William Uhlig, Ljerka Ukrainczyk, Thomas Achille Yorio
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Patent number: 10100432Abstract: An apparatus (10) for producing an SiC single crystal is used in the solution growth includes a seed shaft (28) and a crucible (14). The seed shaft (28) has a lower end surface (28S) to which an SiC seed crystal (32) is to be attached. The crucible (14) holds an Si—C solution (15). The seed shaft (28) includes a cylinder part (28A), a bottom part (28B), and a low heat conductive member (28C). The bottom part (28B) is located at the lower end of the cylinder part (28A) and has the lower end surface (28S). The low heat conductive member (28C) is arranged on the upper surface of the bottom part (28B) and has a thermal conductivity lower than that of the bottom part (28B). This production apparatus can make the temperature within the crystal growth surface of the SiC seed crystal less liable to vary.Type: GrantFiled: July 10, 2013Date of Patent: October 16, 2018Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Nobuhiro Okada, Kazuhito Kamei, Kazuhiko Kusunoki, Nobuyoshi Yashiro, Koji Moriguchi, Hironori Daikoku, Motohisa Kado, Hidemitsu Sakamoto
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Patent number: 9963800Abstract: Various single crystals are disclosed including sapphire. The single crystals have desirable geometric properties, including a width not less than about 15 cm and the thickness is not less than about 0.5 cm. The single crystal may also have other features, such as a maximum thickness variation, and as-formed crystals may have a generally symmetrical neck portion, particularly related to the transition from the neck to the main body of the crystal. Methods and for forming such crystals and an apparatus for carrying out the methods are disclosed as well.Type: GrantFiled: September 18, 2017Date of Patent: May 8, 2018Assignee: SAINT-GOBAIN CERAMICS & PLASTICS, INC.Inventors: John Walter Locher, Steven Anthony Zanella, Ralph Lampson MacLean, Jr., Herbert Ellsworth Bates
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Patent number: 9903043Abstract: The invention provides a crucible assembly and method of manufacturing a crystalline silicon ingot by use of such crucible assembly. The crucible assembly of the invention includes a crucible body and a fiber textile article. The fiber textile article is made of a plurality of carbon fibers, and is loaded on a bottom of the crucible body. The fiber textile article has a plurality of intrinsic pores randomly arranged.Type: GrantFiled: January 16, 2015Date of Patent: February 27, 2018Assignee: SINO-AMERICAN SULICON PRODUCTS INC.Inventors: Wen-Huai Yu, Hung-Sheng Chou, Yu-Min Yang, Kuo-Wei Chuang, Sung-Lin Hsu, I-Ching Li, Wen-Ching Hsu
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Patent number: 9551089Abstract: The present disclosure is directed to an apparatus and method for growing a sapphire sheet via edge-defined film-fed growth (EFG) including an angled heat shield with respect to the a side surface of a die tip. The present disclosure is further directed to an sapphire sheets and batches of such sheets having features such as a particular maximum low spot thickness.Type: GrantFiled: March 14, 2014Date of Patent: January 24, 2017Assignee: SAINT-GOBAIN CERAMICS & PLASTICS, INC.Inventors: Marc Ouellette, Joseph M. Collins, John Walter Locher, Guilford L. Mack, III, Abbie M. Jennings, Jan J. Buzniak, Christopher D. Jones
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Publication number: 20140311402Abstract: The present disclosure is directed to an apparatus and method for growing a sapphire sheet via edge-defined film-fed growth (EFG) including an angled heat shield with respect to the a side surface of a die tip. The present disclosure is further directed to an sapphire sheets and batches of such sheets having features such as a particular maximum low spot thickness.Type: ApplicationFiled: March 14, 2014Publication date: October 23, 2014Applicant: Saint-Gobain Ceramics & Plastics, Inc.Inventors: Marc Ouellette, Joseph M. Collins, John Walter Locher, Guilford L. Mack, III, Abbie M. Jennings, Jan J. Buzniak, Christopher D. Jones
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Publication number: 20140150716Abstract: Various single crystals are disclosed including sapphire. The single crystals have desirable geometric properties, including a width not less than about 15 cm and the thickness is not less than about 0.5 cm. The single crystal may also have other features, such as a maximum thickness variation, and as-formed crystals may have a generally symmetrical neck portion, particularly related to the transition from the neck to the main body of the crystal. Methods and for forming such crystals and an apparatus for carrying out the methods are disclosed as well.Type: ApplicationFiled: February 10, 2014Publication date: June 5, 2014Inventors: John Walter Locher, Stephen Anthony Zanella, Ralph Lampson MacLean, JR., Herbert Ellsworth Bates
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Publication number: 20140102358Abstract: An apparatus, die, and method can be used form a ribbon from a melt, where capillaries are relatively short and spacers are relatively long as compared to a die opening. Such a configuration can cause the melt to flow is a transverse direction that is substantially parallel to the solid/liquid interface to help move impurities to desired locations. In a particular embodiment, a crystal ribbon can be formed where defects, such as microvoids and impurities, are at higher concentrations near outer edges of the crystal ribbon. The outer edges can be removed to produce crystal substrates that are substantially free of microvoids and have no or a relatively low concentration of impurities. In another particular embodiment, the transverse flow can also help to increase the crystal growth rate.Type: ApplicationFiled: September 30, 2013Publication date: April 17, 2014Inventors: Jan J. Buzniak, Naveen Tiwari, Vignesh Rajamani, Charles Gasdaska, Christopher D. Jones, Guilford L. Mack, III, Fery Pranadi, Maureen DeLoffi, Martin Z. Bazant
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Publication number: 20140083353Abstract: Systems and method for creating crystalline parts having a desired primary and secondary crystallographic orientations are provided. One embodiment may take the form of a method of manufacturing a part having a crystalline structure. The method includes melting aluminum oxide and drawing the melted aluminum oxide up a slit. Additionally, the method includes orienting the seed crystal relative to a growth apparatus such that a crystalline structure grows having a desired primary plane and a desired secondary plane orientation. Moreover, the method includes pulling the crystal as it forms to create a ribbon shaped crystalline structure and cutting a part from the crystalline structure.Type: ApplicationFiled: September 25, 2012Publication date: March 27, 2014Applicant: Apple Inc.Inventors: Benjamin J. Pope, Christopher D. Prest, Dale N. Memering, Scott A. Myers
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Patent number: 8673075Abstract: A method and apparatus for growing a semiconductor crystal include pulling the semiconductor crystal from melt at a pull speed and modulating the pull speed by combining a periodic pull speed with an average speed. The modulation of the pull speed allows in-situ determination of characteristic temperature gradients in the melt and in the crystal during crystal formation. The temperature gradients may be used to control relevant process parameters that affect morphological stability or intrinsic material properties in the finished crystal such as for instance the target pull speed of the crystal or the melt gap, which determines the thermal gradient in the crystal during growth.Type: GrantFiled: March 29, 2012Date of Patent: March 18, 2014Assignees: Sumco Phoenix Corporation, Sumco CorporationInventors: Benno Orschel, Andrzej Buczkowski, Joel Kearns, Keiichi Takanashi, Volker Todt
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Patent number: 8580036Abstract: The method and apparatus includes a vessel having a bottom and sidewalls arranged to house the material in a molten state. A temperature controlled horizontally oriented, cooling plate is movable into and out of the top of the molten material. When the cooling plate is lowered into the top of the melt, an ingot of solid silicon is solidified downwards.Type: GrantFiled: May 10, 2006Date of Patent: November 12, 2013Assignee: Elkem Solar ASInventor: Kenneth Friestad
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Patent number: 8388751Abstract: A method of growing a ribbon crystal provides a crucible containing molten material and passes string through the molten material to grow the ribbon crystal. The method further directs gas flow around the ribbon crystal such that the gas flows down along the ribbon crystal toward the crucible.Type: GrantFiled: August 17, 2009Date of Patent: March 5, 2013Assignee: Max Era, Inc.Inventors: David Harvey, Weidong Huang, Scott Reitsma, Minh Sy Le
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Publication number: 20120145069Abstract: Various single crystals are disclosed including sapphire. The single crystals have desirable geometric properties, including a width not less than about 15 cm and the thickness is not less than about 0.5 cm. The single crystal may also have other features, such as a maximum thickness variation, and as-formed crystals may have a generally symmetrical neck portion, particularly related to the transition from the neck to the main body of the crystal. Methods and for forming such crystals and an apparatus for carrying out the methods are disclosed as well.Type: ApplicationFiled: February 14, 2012Publication date: June 14, 2012Applicant: SAINT-GOBAIN CERAMICS & PLASTICS, INC.Inventors: John Walter Locher, Steven Anthony Zanella, Ralph Lampson MacLean, JR., Herbert Ellsworth Bates
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Publication number: 20110155045Abstract: A sheet wafer growth system includes a crucible for containing molten material and an afterheater positioned above the crucible. The afterheater has an inner surface disposed toward the crucible. The system further includes one or more shields adjacent to the inner surface of the afterheater. The afterheater and the shield(s) are configured to allow a sheet wafer to pass adjacent to the shield(s). Each shield has two or more substantially different thermally conductive regions such that the two or more regions are configured to control the temperature profile of the growing sheet wafer.Type: ApplicationFiled: January 27, 2011Publication date: June 30, 2011Applicant: EVERGREEN SOLAR, INC.Inventors: Kaitlin Olsen, Weidong Huang, Christine Richardson
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Publication number: 20100288186Abstract: Techniques are generally disclosed for forming crystalline bodies. An example system, device or method for forming crystalline bodies may include a crucible for containing molten crystalline material and a support for accommodating a seed on an end thereof, the support being movable along a translation axis in a pull direction to draw the seed crystal from the molten crystalline, thereby initiating growth of a crystalline body along a growth path. Further examples may include one or more nozzles configured to be coupled to a fluid source, the nozzles being positioned relative to the growth path for shaping the crystal body as the molten crystalline is pulled in the pull direction along the growth path.Type: ApplicationFiled: May 18, 2009Publication date: November 18, 2010Inventor: Christopher A. Bang
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Patent number: 7799131Abstract: The present invention provides a method for the continuous production of semiconductor ribbons by growth from a linear molten zone. The creation of the molten zone is achieved by application of an electric current, direct or alternating, parallel to the surface of the ribbon and perpendicular to the direction of growth, and intense enough to melt the said material, preferably using electrodes of the said material. The molten zone is fed by transference of the material, in the liquid state, from one or more reservoirs, where melting of the feedstock occurs. Preferably, the said electrodes and the said reservoir(s) are only constituted by the said material, thus avoiding contamination by foreign materials. The present invention is applicable, for example, in the industry of silicon ribbons production for photovoltaic application.Type: GrantFiled: April 15, 2004Date of Patent: September 21, 2010Assignee: Faculdade de Ciencias Da Universidade de LisboaInventors: António Vallêra, João Serra, Jorge Maia Alves, Miguel Brito, Roberto Gamboa, João Henriques
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Patent number: 7718003Abstract: A method and apparatus for growing a crystalline or poly-crystalline body from a melt is described, wherein the melt is retained by capillary attachment to edge features of a mesa crucible. The boundary profile of the resulting melt surface results in an effect which induces a ribbon grown from the surface of the melt to grow as a flat body. Further, the size of the melt pool is substantially reduced by bringing these edges close to the ribbon, thereby reducing the materials cost and electric power cost associated with the process.Type: GrantFiled: November 26, 2007Date of Patent: May 18, 2010Assignee: Evergreen Solar, Inc.Inventor: Emanuel Michael Sachs
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Patent number: 7708829Abstract: A method and apparatus for growing a crystalline or poly-crystalline body from a melt is described, wherein the melt is retained by capillary attachment to edge features of a mesa crucible. The boundary profile of the resulting melt surface results in an effect which induces a ribbon grown from the surface of the melt to grow as a flat body. Further, the size of the melt pool is substantially reduced by bringing these edges close to the ribbon, thereby reducing the materials cost and electric power cost associated with the process.Type: GrantFiled: July 10, 2006Date of Patent: May 4, 2010Assignee: Evergreen Solar, Inc.Inventor: Emanuel Michael Sachs
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Patent number: 7572334Abstract: A method and apparatus for forming a semiconductor sheet suitable for use as a solar cell by depositing an array of solidified drops of a feed material on a sheet support. The desired properties of the sheet fabricated with the teaching of this invention are: flatness, low residual stress, minority carrier diffusion length greater than 40 microns, and minimum grain dimension at least two times the minority carrier diffusion length. In one embodiment, the deposition chamber is adapted to form and process sheets that have a surface area of about 1,000-2,400 cm2.Type: GrantFiled: January 3, 2006Date of Patent: August 11, 2009Assignee: Applied Materials, Inc.Inventors: Arnold V. Kholodenko, Robert Z. Bachrach, Mark Mandelboym
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Patent number: 7507291Abstract: Methods and apparatus for concurrent growth of multiple crystalline ribbons from a single crucible employ meniscus shapers to facilitate continuous growth of discrete and substantially flat crystalline ribbons having controlled width.Type: GrantFiled: April 3, 2006Date of Patent: March 24, 2009Assignee: Evergreen Solar, Inc.Inventor: Richard Lee Wallace, Jr.
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Publication number: 20080308034Abstract: A ribbon crystal pulling furnace has an interior for enclosing at least a portion of one or more ribbon crystals, and an afterheater positioned within the interior. The afterheater has at least one wall with one or more openings that facilitate control of the temperature profile within the furnace.Type: ApplicationFiled: June 13, 2008Publication date: December 18, 2008Applicant: EVERGREEN SOLAR, INC.Inventors: Weidong Huang, David Harvey, Scott Reitsma
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Publication number: 20080134964Abstract: A system for producing a crystal formed from a material with impurities has a crucible for containing the material. The crucible has, among other things, a crystal region for forming the crystal, an introduction region for receiving the material, and a removal region for removing a portion of the material. The crucible is configured to produce a generally one directional flow of the material (in liquid form) from the introduction region toward the removal region. This generally one directional flow causes the removal region to have a higher concentration of impurities than the introduction region.Type: ApplicationFiled: April 27, 2007Publication date: June 12, 2008Applicant: Evergreen Solar, Inc.Inventors: David Harvey, Weidong Huang, Richard L. Wallace, Leo van Glabbeek, Emanuel M. Sachs
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Patent number: 7036387Abstract: A printed circuit board (PCB) having an integrated strain gage. In one embodiment, a PCB includes a component footprint suitable for mounting an electronic component. A strain gage is integrated into the PCB in a location under the component footprint. The strain gage includes at least one electrical conductor that is accessible for resistance measurements.Type: GrantFiled: May 11, 2004Date of Patent: May 2, 2006Assignee: Sun Microsystems, Inc.Inventors: Brett C. Ong, Keith G. Newman
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Patent number: 7022180Abstract: Methods and apparatus for concurrent growth of multiple crystalline ribbons from a single crucible employ meniscus shapers to facilitate continuous growth of discrete and substantially flat crystalline ribbons having controlled width.Type: GrantFiled: September 16, 2004Date of Patent: April 4, 2006Assignee: Evergreen Solar, Inc.Inventor: Richard Lee Wallace, Jr.
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Patent number: 6874378Abstract: A pressure transducer suitable for use as a component of a passive occupant detection system installed in a passenger vehicle. The transducer comprises first and second contact members separated by a spacing member. The first contact member has on a surface thereof a primary contact comprising first and second terminations and portions spaced apart in a first direction. The second contact member has on a surface thereof a plurality of secondary contacts crossing and facing the spaced-apart portions of the primary contact through an opening in the spacing member. Application of an increasing force causes the contact members to move toward each other, causing an increasing number of the spaced-apart portions to be shorted out by the secondary contacts and causing an increasing number of secondary contacts to contact the primary contact, thereby altering the electrical path between the terminations of the primary contact.Type: GrantFiled: July 30, 2003Date of Patent: April 5, 2005Assignee: Delphi Technologies, Inc.Inventors: Frans P. Lautzenhiser, Anthony J. Stankavich, John D Myers, Terrence Evans
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Patent number: 6814802Abstract: Methods and apparatus for concurrent growth of multiple crystalline ribbons from a single crucible employ meniscus shapers to facilitate continuous growth of discrete and substantially flat crystalline ribbons having controlled width.Type: GrantFiled: October 30, 2002Date of Patent: November 9, 2004Assignee: Evergreen Solar, Inc.Inventor: Richard Lee Wallace, Jr.
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Patent number: 6663710Abstract: An apparatus and a method that permits a seed crystal to be directed to a precise location of a melt for growing a ribbon-shaped crystal, but after the crystal has commenced growing, the ribbon-shaped crystal is continuously pulled up so as to produce a longitudinally extending crystal using a continuous pulling device. The method for producing a ribbon-shaped crystal includes growing a ribbon-shaped crystal on a seed crystal using a linear pulling device for pulling the seed crystal and a crystal growing at the end of the seed crystal in a vertical direction, and continuing to pull the ribbon-shaped crystal by using a continuous pulling device having a continuous pulling mechanism.Type: GrantFiled: October 29, 2001Date of Patent: December 16, 2003Assignee: Ebara CorporationInventors: Kentaro Fujita, Kenji Terao, Hideyuki Isozaki, Iwao Satoh
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Patent number: 6471768Abstract: A seed crystal is lowered toward a melt, and a contact between the seed crystal and the melt is detected using an image captured by an imaging device. The temperature of the melt is adjusted to keep a meniscus of the melt in contact with the seed crystal. The temperature of the melt is then lowered to create a wingout extending from the seed crystal. The length and symmetry of the wingout is detected with an image captured by the imaging device, and a ribbon of crystal following the wingout starts to be lifted from the melt.Type: GrantFiled: September 6, 2001Date of Patent: October 29, 2002Assignee: Ebara CorporationInventors: Kenji Terao, Hideyuki Isozaki, Taro Takahashi, Motohiro Niijima
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Patent number: 6325852Abstract: A die for drawing crystals from a molten bath, has a body bored with at least one longitudinal capillary channel arranged between a lower face of the body. The die is intended to be immersed in the molten bath and an upper face of the body intended to support the liquid coming from the molten bath through the capillary channel. The die upper face has a flat surface onto which the capillary channel emerges, and this flat surface forms an angle &thgr; less than 90° with the longitudinal axis of the capillary channel.Type: GrantFiled: June 8, 2000Date of Patent: December 4, 2001Assignee: Commissariat a l'Energie AtomiqueInventors: Fred Theodore, Jean Delepine, Jean-Philippe Nabot, Vladimir Kurlov
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Patent number: 6217649Abstract: The invention features a method of continuous crystalline growth. A granular source material is introduced into a hopper. A volume of the granular source material exiting the hopper is disposed on a translationally moving belt. The volume of the granular source material forms an angle of repose with the moving belt. The granular source material disposed on the moving belt is continuously fed into a crucible comprising a melt of the granular source material at a rate based on the angle of repose, the speed of the belt, and the size of the opening of the hopper. A crystalline ribbon is continuously grown by solidifying the melt.Type: GrantFiled: January 13, 2000Date of Patent: April 17, 2001Assignee: Evergreen Solar, Inc.Inventors: Richard L. Wallace, Jr., Emanuel M. Sachs, Jennifer Martz
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Patent number: 6200383Abstract: The invention features a method of controlling the depth of a melt for or crystal growth. According to the method, an input signal is applied through a crucible and a material disposed within the crucible. An output signal generated in response to the input signal is measured. The output signal relates to the depth of the melt. An amount of the source material introduced into the melt is adjusted to maintain the depth of the melt at a substantially constant level using the output signal.Type: GrantFiled: May 3, 1999Date of Patent: March 13, 2001Assignee: Evergreen Solar, Inc.Inventors: Richard L. Wallace, Jr., Richard C. Krauchune
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Patent number: 6093244Abstract: A method and system for controlling the thickness of a pair of dendrites in a dendritic silicon web growth process to improve dendritic silicon web production. An image of each dendrite in a web emerging from a silicon melt in a furnace is produced by a pair of cameras focused on the dendrite pair. The dendrite images are digitized, the average thickness of the dendrites is calculated, and compared to set point parameters. The average difference between the dendrite thicknesses and the set point parameters is used to control the overall furnace temperature, while the differences between the thickness of each pair are used to control the lateral temperature distribution in the furnace in order to maintain the dendrite thickness within predetermined limits.Type: GrantFiled: April 10, 1997Date of Patent: July 25, 2000Assignee: Ebara Solar, Inc.Inventors: John R. Easoz, Barry Munshower
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Patent number: 6090199Abstract: The invention features a method of continuous crystalline growth. A granular source material is introduced into a hopper. A volume of the granular source material exiting the hopper is disposed on a translationally moving belt. The volume of the granular source material forms an angle of repose with the moving belt. The granular source material disposed on the moving belt is continuously fed into a crucible comprising a melt of the granular source material at a rate based on the angle of repose, the speed of the belt, and the size of the opening of the hopper. A crystalline ribbon is continuously grown by solidifying the melt.Type: GrantFiled: May 3, 1999Date of Patent: July 18, 2000Assignee: Evergreen Solar, Inc.Inventors: Richard L. Wallace, Jr., Emanuel M. Sachs, Jennifer Martz
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Patent number: 6071339Abstract: A crystal plate 1 is grown in a continuous process by first purifying a crystal source material, a crystal melt or powder, in a purification station 3. Valves 7 control the flow of purified crystal melt or source powder 9 to a first hot zone 11, whose temperature is above the melt temperature of the crystal. A dopant source 17 with controller 19 provides dopant to the liquefied crystal 15. The first heater zone 21 surrounding the first hot zone 11 heats the crystal above its melting temperature. The second heater zone 27 produces a temperature in the second zone which is below the melt temperature of the crystal. The liquefied crystal, the liquid solid interface and the first portion of the crystal are supported in a boat-shaped crucible container with a bottom 31 and side walls. As the crystal leaves the support plate 31 it passes on to a conveyor 33. The crystal moves within an enclosure 43, which has a noble gas or noble gas and reactant gas atmosphere 45.Type: GrantFiled: January 21, 1999Date of Patent: June 6, 2000Assignee: Optoscint, Inc.Inventor: Kiril A. Pandelisev
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Patent number: 5919304Abstract: When producing an oxide-series single crystal by continuously pulling downwardly by .mu. pulling down method, the composition of the single crystal can properly and quickly controlled to continuously produce the single crystal of a constant composition by changing the pulling rate of the single crystal. Preferably, the pulling rate is 20-300 mm/hr, and the pulling rate is decreased with the proceeding of growing of the single crystal.Type: GrantFiled: August 23, 1996Date of Patent: July 6, 1999Assignee: NGK Insulators, Ltd.Inventors: Minoru Imaeda, Katsuhiro Imai, Tsuguo Fukuda
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Patent number: 5820649Abstract: A liquid material such as molten silicon is stored in a crucible. A liquid material, which is identical to and held in the same conditions as the liquid material in the crucible, is continuously supplied from an auxiliary crucible to the crucible to keep constant the surface level of the liquid material in the crucible. The liquid material is continuously pulled up from the crucible at a predetermined speed while the liquid material is being solidified into a solid material such as a ribbon-like thin web of single-crystal silicon.Type: GrantFiled: April 14, 1997Date of Patent: October 13, 1998Assignee: Ebara CorporationInventors: Naoaki Ogure, Kazuyoshi Terashima
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Patent number: 5667583Abstract: A method of growing a single crystal of a rare-earth silicate is disclosed which comprises heating raw materials in a crucible to thereby obtain a melt of the raw materials, contacting a lower end of a seed crystal with the melt and pulling the seed crystal to thereby grow a single crystal, and wherein the pulling is conducted along an axis of pulling having a gradient of at least 30.degree. from the b-axis ([010] axis) of the single crystal and a gradient of at least 25.degree. from the c-axis ([001] axis) of the single crystal. The invention also provides a method of machining a single crystal of a rare-earth silicate into a cylindrical form, comprising grinding a cylinder whose axis is directed so as to have a gradient of 0.degree. to 65.degree. from the c-axis ([001] axis) of the single crystal.Type: GrantFiled: March 30, 1995Date of Patent: September 16, 1997Assignee: Hitachi Chemical Co. Ltd.Inventors: Yasushi Kurata, Kazuhisa Kurashige, Hiroyuki Ishibashi
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Patent number: 3932180Abstract: Process for direct alpha to X phase conversion of metal-free phthalocyanine. In this process, the alpha polymorph of a metal-free phthalocyanine pigment can be directly converted to the X form by depositing the alpha form of the pigment on a suitable substrate followed by in situ conversion of this deposit by controlled heating. The X form of metal-free phthalocyanine is known to possess good electrophotographic speed, and, thus, can be used either alone or in combination with other photoconductive materials in electrophotography.Type: GrantFiled: June 4, 1973Date of Patent: January 13, 1976Assignee: Xerox CorporationInventors: Clifford H. Griffiths, Michael S. Walker
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Patent number: 3932454Abstract: A process for the preparation of substantially hexagonal crystals of metal-free alpha phthalocyanine, said crystals ranging in size from about 1 micron to about 75 microns is disclosed. Photoelectrophoretic and manifold processes employing said crystals are also disclosed.Type: GrantFiled: August 7, 1973Date of Patent: January 13, 1976Assignee: Xerox CorporationInventor: Ray H. Luebbe, Jr.