Physical Separation Of Impurities Patents (Class 127/53)
  • Patent number: 4995911
    Abstract: A process for recovering unreacted sucrose from a reaction mixture of sucrose and a fatty acid alkyl ester in an organic solvent as reaction medium in the presence of a catalyst in the production of a sucrose fatty acid ester which comprises adjusting the reaction mixture from which a part of the organic solvent as reaction medium may be previously removed and to which water is added, to a neutral pH region, adding a neutral salt and sucrose to the reaction mixture to precipitate the sucrose fatty acid ester, filtering off the precipitate, and bringing the filtrate into contact with a reverse osmosis membrane to recover the unreacted sucrose. According to the invention, unreacted sucrose can be easily recovered, while the sucrose fatty acid ester not contaminated with the organic solvent as reaction medium can be obtained from the reaction mixture without using an organic solvent for purification.
    Type: Grant
    Filed: June 13, 1989
    Date of Patent: February 26, 1991
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Shusaku Matsumoto, Yoshio Hatakawa, Akihiko Nakajima
  • Patent number: 4816078
    Abstract: The invention concerns a process for production of L-arabionose in crystalline form. Starting material are extracted sugar beet pulp or other L-araban containing plant materials. These are heated in an autoclave as an aqueous suspension in the presence of Ca(OH).sub.2. The so obtained solution is chromatographed on a cationic exchanger in the Ca-form. The araban containing fraction is hydrolyzed after adding H.sub.2 SO.sub.4, neutralized and rechromatographed on a cationic exchanger in Ca-form. After concentrating the arabinose containing fractions L-arabinose is obtained in form of crystals by cooling crystallization.
    Type: Grant
    Filed: January 21, 1988
    Date of Patent: March 28, 1989
    Assignee: Suddeutsche Zucker-Aktiengesellschaft
    Inventors: Hubert Schiweck, Manfred Vogel
  • Patent number: 4816079
    Abstract: A process for continuous dextrose-monohydrate crystallization whereby an evaporated concentrated liquor is mixed with a recirculated dilute phase to form a feeding liquor. At least a portion of this feeding liquor is fed through the shearing zone of a homogenizer. The sheared mother liquor is then fed to a vertical cooling-crystallizer to form a suspension. The suspension is separated into a concentrated phase and a dilute phase. The dilute phase separated from the suspension is employed as the dilute phase which is mixed with the evaporated concentrated liquor.
    Type: Grant
    Filed: November 25, 1986
    Date of Patent: March 28, 1989
    Assignee: Fried Krupp GmbH
    Inventors: Karl-Heinz Ahrens, Georg Osthaus
  • Patent number: 4788145
    Abstract: A process for preparing 1-O-.alpha.-glucopyranoside-D-fructose by enzymatically converting sucrose is described, wherein a sucrose solution is brought into contact with free or immobilized, living or dead whole cells or with microorganisms forming the free or immobilized enzyme extract of isomaltulose from saccharose, the solution so treated being next subjected to chromatographic separation at ion exchangers or other suitable separation materials to obtain the 1-O-.alpha.-D-glucopyranosido-D-fructose as an aqueous solution which is then converted by methods known per se into the dry form.
    Type: Grant
    Filed: October 14, 1986
    Date of Patent: November 29, 1988
    Assignee: Suddeutsch Zucker Aktiengesellschaft
    Inventor: Mohammad Munir
  • Patent number: 4758283
    Abstract: This invention relates to a process for readily and efficiently preparing L-rhamnose with the use of a marine alga belonging to the family Monostromaceae, Ulvales.According to the process of the present invention, rhamnan sulfate is extracted from a marine alga belonging to the family Monostromaceae such as Monostroma nitidium Wittrock and the obtained extract is hydrolyzed by adding acid(s) thereto followed by heating or treating thereof with a cation exchange resin followed by heating to thereby give a solution containing free L-rhamnose.Since the solution thus obtained contains a large amount of salts, the removal of these salts is significantly important in the preparation of L-rhamnose. In the present invention, an effective process therefor is combined with a conventional method by using an ion exchange resin to thereby establish an efficient desalting process.
    Type: Grant
    Filed: December 22, 1986
    Date of Patent: July 19, 1988
    Assignee: Towa Chemical Industry Co. Ltd.
    Inventors: Motohiro Takemura, Mochihiro Iljima, Yoshiaki Tateno, Naoki Okamoto, Masaaki Fuse
  • Patent number: 4376023
    Abstract: This invention describes the process of separating dextrose preferentially from a mixture of dextrose and oligosaccharides by using ion exchange membranes. More particularly it relates to the process comprising the steps of (1) passing a liquid mixture of dextrose and oligosaccharides through a first feed chamber of an electro-osmosis cell comprising at least two chambers defined between ion exchange membranes having alternating high and low permeability coefficients with respect to each other, (2) passing a direct electric current transversely through said membranes and chambers in a direction to cause the dextrose to pass from said feed chamber through said high permeability coefficient membrane into a second chamber with said dextrose being substantially retained in the second chamber, and (3) recovering an oligosaccharide enriched and a dextrose enriched effluent from the separate chambers.
    Type: Grant
    Filed: October 19, 1981
    Date of Patent: March 8, 1983
    Assignee: The Hubinger Company
    Inventors: Kalyanasundram Venkatsubramanian, Surendar M. Jain, Anthony J. Giuffrida
  • Patent number: 4359430
    Abstract: Betaine is recovered from natural sources such as beet molasses, rest molasses and vinasse by diluting the molasses to 25-50% solids, introducing the molasses to the top of a chromatographic column containing a salt of a polystyrene sulfonate cation exchange resin cross-coupled with from about 2 to about 12 weight percent of divinylbenzene, eluting with water and collecting a fraction of betaine from the downstream side of the resin. When successive feeds with predetermined intervals are made, the feeds may be partly overlapped. The betaine from the preceding feed is then eluted by the dilute molasses from the following feed. The betaine fraction is evaporated under vacuum and the betaine crystallized as anhydrous crystals or as betaine monohydrate.
    Type: Grant
    Filed: February 24, 1981
    Date of Patent: November 16, 1982
    Assignee: Suomen Sokeri Osakeyhtio
    Inventors: Heikki O. Heikkila, Jaakko A. Melaja, Dan E. D. Millner, Jouko J. Virtanen
  • Patent number: 4182634
    Abstract: From a maltose solution of a purity of 75 to 90%, a high-purity maltose solution having a maltose purity of more than 98.5% is obtained in a high yield by preparatorily treating activated carbon with the aqueous solution of an organic solvent, adding the same organic solvent to the maltose solution under treatment until the concentration of the organic solvent equals that in the aqueous solution used for the treatment of the activated carbon, and subsequently bringing the resultant solution into contact with the activated carbon for thereby allowing the activated carbon to adsorb selectively out of the solution only the saccharides such as maltotriose and maltotetraose which are composed of three or more glucoses.
    Type: Grant
    Filed: April 20, 1978
    Date of Patent: January 8, 1980
    Assignee: Hokkaido Sugar Co., Ltd.
    Inventors: Masaru Yamada, Atsushi Mori, Yoshiyasu Sato, Kenichi Terayama, Shogo Miyatani
  • Patent number: 4116712
    Abstract: There are numerous impurities in beet and cane sugar in the two phases in which it appears in the food industry and in commerce: -- as a solid phase in crystalline raw sugar, and as a liquid phase in concentrated syrups or molasses. These impurities, varying greatly with the source of the sugar, are extracted therefrom by solvents which are completely miscible with water, have molecular weights below 62 and contain a hydroxyl group: preferred solvents ethanol and acetic acid, also methanol. The crystalline nature of the solid raw sugar and the high solids content (40 to 80%) of such liquid solutions minimizes mutual solubility with the solvent which is enhanced by the use of a co-solvent -- acetone, also completely miscible with water, also with a molecular weight below 62, and allows counter current washing of the raw sugar or the liquid-liquid extraction of the sugar syrups.
    Type: Grant
    Filed: September 6, 1977
    Date of Patent: September 26, 1978
    Inventor: Donald F. Othmer
  • Patent number: 3961981
    Abstract: A process for purifying sugar containing liquids or solutions, optionally at a sugar mill site, in which the hot sugar liquids are initially contacted with a weakly basic anion exchange resin in the bicabonate form, the salt impurities in the juices being converted to their corresponding bicarbonates, then passing the liquids under pressure through a cation exchange resin in the calcium form to remove alkali metals and then treating the resulting liquids pressure free to bring about the conversion of salts of hardness ions such as calcium bicarbonate in the liquid to insoluble calcium carbonate thereby giving a clarified, deionized and decolorized liquid product which is easily crystallized to a purified crystallized sugar product.
    Type: Grant
    Filed: August 22, 1974
    Date of Patent: June 8, 1976
    Assignee: Rohm and Haas Company
    Inventors: Frank Xavier Pollio, Omar Campos