Heterocyclic Patents (Class 131/277)
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Patent number: 11872231Abstract: The disclosure provides a composition configured for oral use, the composition including a filler in an amount of at least 20% by weight, based on the total weight of the composition, and at least one active ingredient including one or more botanical materials, stimulants, amino acids, vitamins, antioxidants, cannabinoids, pharmaceutical agents, or a combination thereof. The composition further includes a salt and at least one sweetener. The composition has a moisture content of at least about 40% by weight, based on the total weight of the composition.Type: GrantFiled: December 9, 2019Date of Patent: January 16, 2024Assignee: Nicoventures Trading LimitedInventors: Christopher Keller, Ronald K. Hutchens, Thomas H. Poole, Nicolas von Cosmos, Anthony Richard Gerardi, Chris J. Grimes, Steven Lee Alderman, Darrell Eugene Holton, Jr.
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Patent number: 10752862Abstract: A compound is provided of Formula (I) wherein R1 represents a C3 to C20 hydrocarbon group derived from an alcohol of formula R1OH, from a formate of formula R1OCH?O, or a cinnamyl aldehyde of Formula (II) wherein a compound of Formula I is capable of releasing a compound, when oxidized, selected from the group consisting of a fragrant alcohol of formula R1OH, a fragrant formate ester of formula R1OCH?O and aryl aldehyde of Formula (III) wherein R2 is, independently, hydrogen atom, hydroxyl group, optionally substituted C1-C6 alkyl group, C1-C6 alkoxy group, or —O(C?O)CH(CH3)2 wherein any two of R2 may form an optionally substituted 5 or 6 membered ring. The compounds are useful for example as a precursor for the prolonged delivery or release of fragrant compounds such as fragrant alcohols, fragrant aldehydes or fragrant formates.Type: GrantFiled: June 23, 2017Date of Patent: August 25, 2020Assignee: Firmenich SAInventors: Brinda Indradas, Gilbert Virtucio, Gary Womack
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Patent number: 9572369Abstract: Disclosed are sweetened consumables and methods of forming said sweetened consumables that comprise certain sweeteners and at least one sweetness enhancer in a concentration near its sweetness detection threshold. The sweeteners include sucrose, fructose, glucose, high fructose corn syrup, corn syrup, xylose, arabinose, rhamnose, erythritol, xylitol, mannitol, sorbitol, inositol, acesulfame potassium, aspartame, neotame, sucralose, saccharine, or combinations thereof. The sweetness enhancer is selected from naringin dihydrochalcone, mogroside V, swingle extract, rubusoside, rubus extract, rebaudioside, and stevioside.Type: GrantFiled: May 13, 2015Date of Patent: February 21, 2017Assignee: Givaudan S.A.Inventors: Chad Allen Hansen, Jay Patrick Slack, Christopher Todd Simons
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Patent number: 9572368Abstract: Disclosed are sweetened consumables and methods of forming said sweetened consumables that comprise certain sweeteners and at least one sweetness enhancer in a concentration near its sweetness detection threshold. The sweeteners include sucrose, fructose, glucose, high fructose corn syrup, corn syrup, xylose, arabinose, rhamnose, erythritol, xylitol, mannitol, sorbitol, inositol, acesulfame potassium, aspartame, neotame, sucralose, saccharine, or combinations thereof. The sweetness enhancer is selected from naringin dihydrochalcone, mogroside V, swingle extract, rubusoside, rubus extract, rebaudioside, and stevioside.Type: GrantFiled: May 13, 2015Date of Patent: February 21, 2017Assignee: Givaudan S. A.Inventors: Chad Allen Hansen, Jay Patrick Slack, Christopher Todd Simons
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Patent number: 9060545Abstract: A smoking article has an outer surface and a plurality of frangible microcapsules provided on the outer surface, wherein the microcapsules are capable of being manually ruptured by a consumer to release an odorant encapsulated therein. The smoking article preferably comprises a wrapped tobacco rod; and a filter attached to the wrapped tobacco rod by tipping paper, a mouth end portion of which is “over tipped” with a band or strip of “Peel and Sniff” microcapsules and/or a band or strip of “Scratch and Sniff” microcapsules.Type: GrantFiled: November 1, 2006Date of Patent: June 23, 2015Assignee: Philip Morris USA Inc.Inventors: Clement Besso, Anne Wyss-Peters, Charles Kuersteiner
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Patent number: 8816102Abstract: A method of modulating the flavor of an orally-receivable product, such as a foodstuff, beverage, dentifrice or medicine, comprising the addition thereto of a flavor-modulating proportion of at least one compound of the formula I in which X is selected from CHOH, C?O, CH2—CO and CH?C(OH), Y is selected from C1-C7 linear and branched alkyl and CH2CH2OH, Z is selected from CH3 and a moiety of the formula II in which the wavy bond represents bond linking Z to X and R1 and R2 are selected from the possibilities (i) both hydrogen; (ii) independently OH and OCH3; and (iii) R1 and R2 together with their bonds to the phenyl ring form a ring of the formula —O—CH2—O—; such that, when Z is CH3, X is C?O and Y is CH2CH2OH.Type: GrantFiled: June 24, 2010Date of Patent: August 26, 2014Assignee: Givaudan S.A.Inventors: Abdelmajid Kaouas, Harry Renes, Alexander P. Tondeur, Cornelis Winkel
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Publication number: 20130087159Abstract: A cigar comprises a mouth end; a tobacco section comprising tobacco material; at least one sweetener dispersed throughout the tobacco section; and/or a flavor potentiator and/or a taste modifier on an outer surface of the mouth end for enhancing the sweet taste of the cigar.Type: ApplicationFiled: June 4, 2012Publication date: April 11, 2013Applicant: Altria Client Services Inc.Inventors: William R. Sweeney, Pauline Marcq, Joseph Pierotti, Deborah Thiem
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Publication number: 20120138074Abstract: A smokeless tobacco composition configured for insertion into the mouth of a user is provided. The smokeless tobacco composition includes a tobacco material, a sugar alcohol, and a natural gum binder component, wherein the composition is in the form of a pastille. A process for preparing a smokeless tobacco composition pastille configured for insertion into the mouth of a user is also provided. The process includes providing an aqueous mixture comprising a hydrated natural gum binder component, mixing a tobacco material with the aqueous mixture to form a smokeless tobacco mixture, heating the smokeless tobacco mixture, depositing the heated smokeless tobacco mixture into a mould, and curing the smokeless tobacco mixture to form a smokeless tobacco composition pastille.Type: ApplicationFiled: December 1, 2010Publication date: June 7, 2012Inventors: Daniel Verdin Cantrell, Joshua D. Morton, Steven D. Hume, Barry Bratcher, Robert Frank Boutin, Thomas Hinkemeyer
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Publication number: 20120067359Abstract: A tobacco smoke filter or filter element comprising: a tobacco smoke filtering material including paper; and a flavour enhancing additive.Type: ApplicationFiled: May 25, 2010Publication date: March 22, 2012Inventors: Paul Francis Clarke, Anthony Denis McCormick, Tom Cravotta, Jack Rothenhoefer
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Publication number: 20110232655Abstract: A smoking composition for inclusion in a combustible smoking article includes a combustible organic material, such as tobacco and/or tobacco substitutes and at least one alkanoylated glycoside for enhancing the flavor of mainstream smoke. Optionally, dry hops extract can also be included in the smoking composition.Type: ApplicationFiled: March 26, 2010Publication date: September 29, 2011Applicant: Philip Morris USA Inc.Inventors: W. Geoffrey Chan, Christophe Galopin, Andreas Czepa, Mike Nuckols, Beverley Woodson
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Publication number: 20110155151Abstract: Electrically heated cigarettes used in an electrical smoking system include a flavoring-release additive and sorbent effective to remove one or more gas-phase constituents of mainstream tobacco smoke. The flavoring-release additive includes at least one flavoring. The flavoring is released in the cigarette upon the flavoring-release additive reaching at least a minimum temperature during smoking. The flavoring-release additive can have various forms including, for example, beads, films and inclusion complexes. Electrical smoking systems including the electrically heated cigarettes, methods of making the cigarettes, and methods of smoking the cigarettes are also provided.Type: ApplicationFiled: March 9, 2011Publication date: June 30, 2011Inventors: Deborah J. NEWMAN, Beverley C. Woodson
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Patent number: 7866325Abstract: The present invention relates to a smoking article comprising two layers of wrapper material, the outer wrapper having an air permeability of at least 200 C.U. and having a greater permeability than the inner wrapper. Encapsulated flavour is held between the inner and outer wrappers. The encapsulation technique is dependent upon the flavour to be encapsulated and the sidestream to mainstream flavour delivery ratio required. Sidestream smoke may be altered without altering the mainstream smoke, thereby altering room odors.Type: GrantFiled: December 5, 2003Date of Patent: January 11, 2011Assignee: British American Tobacco (Investments) LimitedInventor: Debra Demeter Woods
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Publication number: 20100126520Abstract: A smokeless oral tobacco product comprises a cyclodextrin or cyclodextrin derivative. Such a product can further comprise a flavourant complexed with the cyclodextrin or derivative thereof. Cyclodextrins or their derivative can be used in smokeless oral tobacco products to complex with molecules which arise or solubilize during use of the product and optionally to also release, e.g., flavour or aroma during use of the product.Type: ApplicationFiled: January 16, 2008Publication date: May 27, 2010Inventor: Peter Clayton
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Publication number: 20090253754Abstract: A fast-dissolving film for use as a platform for the delivery of material to the oral cavity, comprising a film forming agent; a plasticizing agent; and a fast-dissolving, water-soluble agent; and methods for producing same.Type: ApplicationFiled: December 4, 2008Publication date: October 8, 2009Inventors: Francesca Selmin, Paolo Blasi, David R. Worthen, David Johnson, Patrick P. DeLuca
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Publication number: 20080276948Abstract: A chewing article for oral tobacco delivery includes a mouth portion and a handle portion. Preferably, the mouth portion includes a mouthpiece containing tobacco material and a cap. The mouthpiece includes at least one perforation that selectively releases the enclosed tobacco material when chewed, sucked, or manipulated. The handle portion is attached to the mouth portion.Type: ApplicationFiled: May 7, 2008Publication date: November 13, 2008Applicant: Philip Morris USA Inc.Inventors: Shalva Gedevanishvili, Dennis Geib, Bruce Waymack, Karen Brooks, William R. Sweeney
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Patent number: 6428624Abstract: A method for providing flavorful and aromatic substances for use in a smoking article is disclosed. In the method, a mixture is provided including a reducing sugar source and a base catalyst. The mixture has a selectively enriched content of at least one free amino acid selected from the group consisting of serine, threonine, valine, leucine, and isoleucine.Type: GrantFiled: July 19, 2001Date of Patent: August 6, 2002Assignee: R. J. Reynolds Tobacco Co.Inventors: William Monroe Coleman, III, Michael Francis Dube, Luis Mayan Dominguez
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Patent number: 5416069Abstract: Novel naphthofuran derivatives of the formula ##STR1## wherein R represents hydrogen, methyl or ethyl. The compounds of formula I are valuable (amber) odorants and also flavorants. Odorant and flavorant compositions employing (I) as well as processes for making them are also described.Type: GrantFiled: July 14, 1994Date of Patent: May 16, 1995Assignee: Givaudan-Roure CorporationInventor: Peter Naegeli
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Patent number: 5368876Abstract: Flavoring and perfume compositions as well as flavored foodstuffs and allied products and also perfumed products characterized by a content of one or more substituted thiophenes with the formula ##STR1## wherein none, one or two of the dotted lines represent a double bond with the proviso that no cumulated double bonds are present.Type: GrantFiled: October 28, 1992Date of Patent: November 29, 1994Assignee: Naarden-International N.V.Inventors: Henry L. A. Van den Heuvel, Paulus P. J. M. Jaegers
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Patent number: 5147463Abstract: This invention provides novel cyclic acetals useful as delayed release flavorants and odorants having the general formula: ##STR1## These compounds possess no detectable flavor or odor themselves at normal temperatures and atmospheric conditions but release an aldehyde flavorant upon heating at higher temperatures. The novel cyclic acetals of the present invention may be used as flavorants in tobacco compositions or tobacco substitutes, as sustained flavorants and odorants to mask or enhance the flavors and odors of burning tobacco products, as flavor additives to microwaveable foods, and in the preparation of chewing gums.Type: GrantFiled: August 18, 1989Date of Patent: September 15, 1992Assignee: BASF K&F CorporationInventors: Robert G. Eilerman, Philip A. Christenson, John M. Yurecko, Jr., Frank Mild, Peter E. Kucharski
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Patent number: 5144964Abstract: This invention provides smoking compositions which contain a novel flavorant-release additive.Under cigarette smoking conditions, a combustible filler and/or paper wrapper additive such as a molecular inclusion complex of a .beta.-cyclodextrin derivative and vanillin releases vanillin as a volatile flavorant component of the cigarette smoke. The released vanillin flavorant improves the taste of the mainstream smoke and imparts a pleasant aroma to the sidestream smoke.Type: GrantFiled: March 14, 1991Date of Patent: September 8, 1992Assignees: Philip Morris Incorporated, Philip Morris Products Inc.Inventor: Barbu A. Demain
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Patent number: 5139034Abstract: In one embodiment, this invention provides a smoking composition which contains a flavorant additive which releases menthol under normal cigarette smoking conditions.The menthol-release additive is a mixture of menthyloxycarbonylglucose compounds which include more than 35 mole percent of 1-O-menthyloxycarbonyl-.beta.-D-glucopyranose and more than about 20 mole percent of 1,6-di-O-menthyloxycarbonyl-.beta.-D-glucopyranose.Type: GrantFiled: November 15, 1990Date of Patent: August 18, 1992Assignees: Philip Morris Incorporated, Philip Morris Products Inc.Inventor: W. Geoffrey Chan
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Patent number: 5137035Abstract: This invention provides a process for the production of novel smoking compositions which contain a benzofuranone flavorant additive, and further provides novel benzofuranone compounds as illustrated by the cis 6-phenyl-3a, 4,5,7a-tetrahydro-2(3H)-benzofuranone: ##STR1## Under normal cigarette smoking conditions, the benzofuranone additive in an invention smoking composition enhances the flavor and aroma of the mainstream and sidestream smoke.Type: GrantFiled: March 21, 1990Date of Patent: August 11, 1992Assignees: Philip Morris Incorporated, Philip Morris Products Inc.Inventor: Kenneth F. Podraza
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Patent number: 5137036Abstract: This invention provides smoking compositions which contain a novel di-vanillyl ester flavorant-release additive.Under cigarette smoking conditions, a combustible filler and/or paper wrapper additive such as di-ethylvanillyl oxalate pyrolyzes and releases ethylvanillin as a volatile flavorant component of the cigarette smoke.Type: GrantFiled: August 10, 1990Date of Patent: August 11, 1992Assignees: Philip Morris Incorporated, Philip Morris Products Inc.Inventor: Everett W. Southwick
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Patent number: 5137579Abstract: Menthyl pyran compounds are provided repesented by the formula 1: ##STR1## wherein R is H or lower acyl or 1-3 carbon atoms; R' is H, hydroxyl, or C.sub.1-3 acyloxy, and the dotted line represents an optional double bond.Use of the compounds provides a menthol note upon pyrolysis or hydrolysis. Smoking compositions containing a compound of formula 1 are also included.Type: GrantFiled: March 31, 1989Date of Patent: August 11, 1992Assignee: BASF K&F CorporationInventors: Philip Christenson, Robert Eilerman
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Patent number: 5137578Abstract: This invention provides smoking compositions which contain a novel flavorant-release additive.Under cigarette smoking conditions, a combustible filler and/or paper wrapper additive such as 4'-formyl-2'-methoxyphenyl 4,6-O-cinnamylidene-.beta.-D-glucopyranoside pyrolyzes into cinnamaldehyde and vanillin flavorants as volatile components of the cigarette smoke.Type: GrantFiled: February 26, 1991Date of Patent: August 11, 1992Assignees: Philip Morris Incorporated, Philip Morris Products Inc.Inventor: Wootung G. Chan
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Patent number: 5114493Abstract: This invention provides smoking compositions which contains a 6-substituted hexahydrobenzofuranone flavorant additive.Under cigarette smoking conditions the flavorant additive enhances the aroma and flavor of the cigarette smoke.Type: GrantFiled: November 2, 1988Date of Patent: May 19, 1992Assignees: Philip Morris Inc., Philip Morris Products Inc.Inventor: Kenneth F. Podraza
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Patent number: 5021184Abstract: Described are adamantane derivatives defined according to the generic structure: ##STR1## wherein R.sub.1 ' is hydrogen or acetyl; R.sub.2 ' is hydrogen or lower alkyl and the dashed line is a carbon-carbon single bond or a carbon-carbon double bond as well as uses thereof for augmenting or enhancing the aroma or taste of consumable materials selected from the group consisting of perfume compositions, perfumed articles, colognes, smoking tobacco compositions, smoking tobacco articles, deodorizing articles, doedorizing compositions and malodor maskants.Type: GrantFiled: September 29, 1989Date of Patent: June 4, 1991Assignee: International Flavors & Fragrances Inc.Inventors: William Gillaspey, Myrna L. Hagedorn, Marie R. Hanna, Kathleen E. Boardwick, Charles E. J. Beck, Futoshi Fujioka, Anthony G. Branco, Anubhav Narula, Richard M. Boden
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Patent number: 4974609Abstract: A smoking composition comprising an admixture of (1) combustible filler selected from natural tobacco, reconstituted tobacco, non-tobacco substitutes, and mixtures thereof, and (2) between about 0.00001 and 2 percent, by weight of the composition of a flavorant selected from the group consisting of compounds of the formulae ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.6, and R.sup.7 are independently selected from the group consisting of: hydrogen; C.sub.1 to C.sub.6 alkyl; C.sub.1 to C.sub.6 alkoxy-C.sub.1 to C.sub.6 alkyl; C.sub.3 to C.sub.12 cycloalkyl; phenyl; benzyl; substituted phenyl and substituted benzyl, wherein the substituted phenyl and substituted benzyl are substituted with one or more substituents, each of said substituents being independently selected from the group consisting of C.sub.1 to C.sub.6 alkyl, methoxy and hydroxy.Type: GrantFiled: August 18, 1986Date of Patent: December 4, 1990Assignee: Philip Morris IncorporatedInventors: Everett W. Southwick, John B. Paine, III
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Patent number: 4937229Abstract: A compound of the general formula, ##STR1## wherein R.sub.1 and R.sub.2 independently are --H, --CH.sub.3, or --CH.sub.2 CH.sub.3 ; and R.sub.3 is alkyl of from 1 to 10 carbons or aryl of from 6 to 10 carbons.Type: GrantFiled: June 26, 1989Date of Patent: June 26, 1990Assignee: Hercules IncorporatedInventors: Brian Byrne, Louise M. L. Lawter
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Patent number: 4889735Abstract: Furanic esters of formula ##STR1## wherein R designates a linear or branched, saturated or unsaturated C.sub.2 -C.sub.6 alkyl radical, are novel compounds having useful organoleptic properties and, consequently, can be used advantageously in the manufacture of flavor compositions, and in the aromatization of foodstuffs, beverages, pharmaceutical preparations and tobacco products.Type: GrantFiled: August 8, 1988Date of Patent: December 26, 1989Assignee: Firmenich S.A.Inventors: Wilhelm Pickenhagen, Alain Velluz
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Patent number: 4872918Abstract: This invention provides novel heterocyclic ester compounds. This invention further provides smoking compositions which contain an invention heterocyclic ester as a flavorant-release additive, as illustrated by the following structure: ##STR1## Under normal cigarette smoking conditions, tetramethylpyrazine and an olefin are released as pyrolysis products, and they enhance the flavor and aroma of the mainstream and sidestream smoke.Type: GrantFiled: May 12, 1986Date of Patent: October 10, 1989Assignee: Philip Morris IncorporatedInventors: Kenneth F. Podraza, Yoram Houminer
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Patent number: 4872917Abstract: This invention provides novel sclaral alkyl ether compounds, and smoking compositions which contain a sclaral alkyl ether compound as a flavorant additive. ##STR1## Under cigarette smoking conditions the sclaral ether is a volatile component which enhances the flavor of the mainstream smoke and the aroma of sidestream smoke.Type: GrantFiled: January 13, 1986Date of Patent: October 10, 1989Assignee: Philip Morris IncorporatedInventors: Charles R. Howe, Everett W. Southwick, Richard H. Cox
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Patent number: 4781762Abstract: Flavoring method and composition which include a carboxylate having the general formula: ##STR1## where R.sub.1 is an alkyl having from 1 to 14 carbons, alkenyl having from 2 to 14 carbons, cycloalkyl, cycloalkenyl, aryl, or furyl having from 4 to 14 carbons; R.sub.2 is alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, or cycloalkynyl of from 1 to 7 carbons, aryl or oxyaryl of from 5 to 18 carbons, or a cycloaliphatic ether of from 5 to 6 carbons; and R.sub.3 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, or cycloalkynyl of from 1 to 7 carbons, aryl, or oxyaryl of from 5 to 18 carbons, or a cycloaliphatic ether of from 5 to 6 carbons, or a radical of the general formula: ##STR2## where R.sub.4 and R.sub.5 independently are hydrogen or alkyl of from 1 to 6 carbons; and R.sub.6 is aryl, alkylaryl, aryloxy, alkoxy, cyclic acetal of from 3 to 7 carbons, dioxyalkyenyl ether of from 4 to 8 carbons; and M is cation other than hydrogen ion.Type: GrantFiled: May 20, 1987Date of Patent: November 1, 1988Assignee: Hercules IncorporatedInventor: Brian Byrne
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Patent number: 4701282Abstract: This invention provides smoking compositions which contain a .beta.-hydroxy-.gamma.-ketoester compound as a flavorant-release additive.In one of its embodiments, this invention provides tobacco compositions which contain a flavorant-release additive such as dodecyl 3-hydroxy-2,2,3-trimethyl-4-oxopentanoate: ##STR1## Under cigarette smoking conditions the above illustrated .beta.-hydroxy-.gamma.-keto ester pyrolyzes into 2,3-butanedione and other products which enhance the flavor of the mainstream smoke and the aroma of sidestream smoke.Type: GrantFiled: August 30, 1985Date of Patent: October 20, 1987Assignee: Philip Morris IncorporatedInventors: W. Geoffrey Chan, Yoram Houminer
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Patent number: 4690157Abstract: This invention provides smoking compositions which contain a novel hydroxylactone flavorant-release additive.Under cigarette smoking conditions, an additive such as 2-(1-hydroxy-1-phenylmethyl)-.gamma.-butyrolactone pyrolyzes into volatile benzaldehyde and .gamma.-butyrolactone constituents which enhance the flavor and aroma of the cigarette smoke.Type: GrantFiled: March 21, 1986Date of Patent: September 1, 1987Assignee: Philip Morris IncorporatedInventor: Kenneth F. Podraza
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Patent number: 4590284Abstract: A compound of the general formula, ##STR1## wherein R.sub.1 and R.sub.2 independently are --H, --CH.sub.3, or --CH.sub.2 CH.sub.3 ; and R.sub.3 and R.sub.4 are independently alkyl or alkenyl of from 1 to 10 carbons, or aryl of from 6 to 10 carbons, or R.sub.4 =hydrogen.Type: GrantFiled: April 29, 1985Date of Patent: May 20, 1986Assignee: Hercules IncorporatedInventors: Brian Byrne, Louise M. L. Lawter
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Patent number: 4585737Abstract: In a method for the production of an agent for modifying a smoke-flavor, ambroxide is contacted with a microbial culture to effect a transformation of at least a proportion of the ambroxide to a product comprising at least one oxygenated derivative of ambroxide. The said product may comprise at least one of the compounds A, B and C, each as defined in the specification. The respective Compound, (particularly Compound A), may be extracted from said product for incorporation with a smoking material. Thus a smoke-flavor modifying agent produced by the aforesaid method for incorporation with, or included in, a smoking material or smoking article may comprise at least one compound of the aforesaid group.The loading level of the said agent may be within a range of 0.1 to 100 parts per million or, suitably, of 0.5 to 10 parts per million, of the said smoking material.Type: GrantFiled: October 29, 1984Date of Patent: April 29, 1986Assignee: British-American Tobacco Company LimitedInventors: Adrian G. Barnes, Peter C. Bevan
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Patent number: 4540004Abstract: This invention provides smoking compositions which contain a tetracarbonate ester compound as a flavorant additive.In one of its embodiments, this invention provides tobacco compositions which contain a tetracarbonate ester flavorant additive such as 2,5-bis(menthoxycarbonyloxymethylene)-3,6-bis(menthoxycarbonyloxy)-1,4-dio xane: ##STR1## Under cigarette smoking conditions the above illustrated tetracarbonate ester pyrolyzes into menthol and other products which enhance the flavor of the mainstream smoke and the aroma of sidestream smoke.Type: GrantFiled: August 1, 1983Date of Patent: September 10, 1985Assignee: Philip Morris, IncorporatedInventors: Kenneth F. Podraza, Yoram Houminer
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Patent number: 4538628Abstract: This invention provides smoking compositions which contain a dioxane diester compound as a flavorant additive.In one of its embodiments, this invention provides tobacco compositions which contain a dioxane diester flavorant additive such as 2,5-bis(3-methylvaleryloxy)-1,4-dioxane: ##STR1## Under cigarette smoking conditions the above illustrated dioxane diester pyrolyzes into 3-methylvaleric acid and other products which enhance the flavor of the mainstream smoke and the aroma of sidestream smoke.Type: GrantFiled: October 10, 1984Date of Patent: September 3, 1985Assignee: Philip Morris, IncorporatedInventor: Kenneth F. Podraza
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Patent number: 4532944Abstract: This invention provides smoking compositions which contain a dicarbonate ester compound as a flavorant additive.In one of its embodiments, this invention provides tobacco compositions which contain a dicarbonate ester flavorant additive such as 2,5-bis(2-methoxyphenoxycarbonyloxy)-1,4-dioxane: ##STR1## Under cigarette smoking conditions the above illustrated dicarbonate ester pyrolyzes into guaiacol and other products which enhance the flavor of the mainstream smoke and the aroma of sidestream smoke.Type: GrantFiled: April 23, 1984Date of Patent: August 6, 1985Assignee: Philip Morris Inc.Inventor: Kenneth F. Podraza
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Patent number: 4485036Abstract: The novel odorants and/or flavorants have the formulae: ##STR1##Type: GrantFiled: September 29, 1980Date of Patent: November 27, 1984Assignee: Givaudan CorporationInventor: Roman Kaiser
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Patent number: 4479003Abstract: This invention provides heterocyclic-hydroxy-substituted carboxylate esters which are useful as flavorant additives for smoking compositions.Type: GrantFiled: May 20, 1981Date of Patent: October 23, 1984Assignee: Philip Morris, IncorporatedInventors: Yoram Houminer, Harvey J. Grubbs
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Patent number: 4473085Abstract: This invention provides tobacco compositions which contain a hydroxy-substituted carboxylate compound as a flavorant additive.In one of its embodiments, this invention provides tobacco compositions which contain a hydroxy-substituted alkanoate flavorant additive such as ethyl 2-(2-butyl)-3-hydroxy-3-methyl-3-phenylpropionate: ##STR1## Under smoking conditions the above illustrated hydroxy-substituted alkanoate additive and its pyrolysis products flavor the mainstream and sidestream smoke.Type: GrantFiled: April 30, 1981Date of Patent: September 25, 1984Assignee: Philip Morris IncorporatedInventors: Harvey J. Grubbs, Yoram Houminer
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Patent number: 4471789Abstract: Described is the genus of compound having the structure: ##STR1## wherein R.sub.1 represents C.sub.1 -C.sub.3 lower alkyl; R.sub.2, R.sub.3, R.sub.4 and R.sub.5 represent the same or different hydrogen or C.sub.1 -C.sub.3 lower alkyl; X and Y represent the same or different oxygen or sulfur; and one of the dashed lines represents a carbon-carbon double bond and the other of the dashed lines represent carbon-carbon single bonds as well as methods for augmenting or enhancing the aroma and/or taste of consumable materials including foodstuffs, chewing gums, medicinal products, toothpastes, chewing tobaccos, perfume compositions, perfumed articles, smoking tobaccos and smoking tobacco articles using such dioxolanes, oxathiolanes and dithiolanes. The perfumed articles include solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, dryer-added fabric softener articles, hair preparations, deodorant compositions, as well as bleaching compositions containing the same.Type: GrantFiled: December 10, 1981Date of Patent: September 18, 1984Assignee: International Flavors & Fragrances Inc.Inventor: Richard M. Boden
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Patent number: 4470963Abstract: Described are mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives having the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond; wherein R.sub.1, R.sub.1 ', R.sub.1 ", R.sub.1 '", R.sub.1 "", R.sub.3, R.sub.5, R.sub.5 ', R.sub.5 ", R.sub.5 '", R.sub.5 "" and R.sub.6 represent hydrogen or methyl with the provisos:(i) at least four of R.sub.1, R.sub.1 ', R.sub.1 ", R.sub.1 '" and R.sub.1 "" are hydrogen; and (ii) at least four of R.sub.5, R.sub.5 ', R.sub.5 ", R.sub.5 '" and R.sub.5 "" represent hydrogen;and wherein Z represents one of the moieties:(i) carboxaldehyde having the structure: ##STR2## (ii) alkylene dioxy or dialkoxy methyl having the structure: ##STR3## (iii) hydroxy methyl having the structure: ##STR4## (iv) acetoxymethyl having the structure: ##STR5## and wherein R.sub.7 and R.sub.8 taken separately represent C.sub.1 -C.sub.4 lower alkyl or R.sub.7 and R.sub.8 taken together represent C.sub.2 -C.sub.Type: GrantFiled: October 28, 1983Date of Patent: September 11, 1984Assignee: International Flavors & Fragrances, Inc.Inventors: Mark A. Sprecker, Marie R. Hanna, Richard J. Tokarzewski, Robert P. Belko, Hugh Watkins, Manfred H. Vock
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Patent number: 4465618Abstract: New spiranic compound, viz. 6-ethyl-2,10,10-trimethyl-1-oxaspiro[4.5]deca-3,6-diene, for use therefor as perfume or flavor-modifying ingredient.Type: GrantFiled: February 24, 1982Date of Patent: August 14, 1984Assignee: Firmenich SAInventor: Peter Fankhauser
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Patent number: 4432378Abstract: The present invention relates to substituted cyclohexane derivatives having the structure: ##STR1## wherein the dotted line may be a carbon-carbon double bond or a carbon-carbon single bond; wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 may be hydrogen or lower alkyl; wherein Z may be any of the following: ##STR2## wherein R.sub.9 may be hydrogen or lower alkyl; and wherein R.sub.10 and R.sub.11 are lower alkyl. This invention also provides methods of preparing and using the compounds as odor-modifying ingredients in perfumes and perfumed products, and as flavor-modifying ingredients in foodstuffs and tobacco products.Type: GrantFiled: November 30, 1981Date of Patent: February 21, 1984Assignee: Fritzsche, Dodge & Olcott, Inc.Inventors: Brian J. Willis, Robert G. Eilerman
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Patent number: 4430354Abstract: Described is a genus of compounds defined according to the structure: ##STR1## (Z) represents one of the moieties ##STR2## as well as the substantially pure compound defined according to the structure: ##STR3## and the use thereof for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, medicinal products, toothpastes, chewing tobaccos, smoking tobaccos, smoking tobacco articles, perfumes, colognes and perfumed articles including solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softeners, fabric softener articles, perfumed articles, hair preparations and the like.Type: GrantFiled: May 20, 1983Date of Patent: February 7, 1984Assignee: International Flavors & Fragrances Inc.Inventors: Richard M. Boden, Theodore J. Tyszkiewicz, Michael Licciardello, Manfred H. Vock, Joaquin F. Vinals, Patrick Whalen, Marie R. Hanna
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Patent number: 4413639Abstract: Described is a process for augmenting or enhancing the aroma or taste of a smoking tobacco composition or smoking tobacco article component comprising the step of adding to a smoking tobacco composition or at least a portion of a smoking tobacco article, an aroma or taste augmenting or enhancing quantity of at least one compound defined according to the structure: ##STR1## wherein one of the dashed lines is a carbon-carbon double bond and each of the other of the dashed lines is a carbon-carbon single bond; wherein the wavy line: is a carbon-carbon single bond or no bond at all; wherein Z represents hydrogen, --CH.sub.2 --, or C.sub.2 -C.sub.4 acyl; with the proviso that when the wavy line: is no bond at all, Z represents hydrogen or C.sub.2 -C.sub.4 acyl and when the wavy line: is a carbon-carbon single bond, then Z represents --CH.sub.2 --.Type: GrantFiled: June 24, 1982Date of Patent: November 8, 1983Assignee: International Flavors & Fragrances Inc.Inventor: Richard M. Boden
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Patent number: 4407740Abstract: Di- and tetrahydrobenzofuranone of the formula ##STR1## are useful in scenting and/or flavoring agents for imparting thereto a coumarin and coconut note.Type: GrantFiled: April 23, 1981Date of Patent: October 4, 1983Assignee: Haarmann & Reimer GmbHInventors: Manfred Kopsel, Roland Emberger