Working Patents (Class 148/111)
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Patent number: 7763122Abstract: The invention relates to a non-oriented electrical steel sheet, widely used as an iron core in electric devices, and to a method of manufacturing the same. The non-oriented electrical sheet includes 0.004 wt. % or less C; 1.0-3.5 wt. % Si; 0.02 wt. % or less P; 0.001 wt. % or less S; 0.2˜2.5 wt. % Al; 0.003 wt. % or less N; 0.004 wt. % or less Ti; Mn, in which the amount thereof is represented by the following formula (1): 0.10+100×S(wt. %)?Mn(wt. %)?0.21+200×S(wt. %)—(1); a balance of iron; and inevitable impurities.Type: GrantFiled: December 18, 2006Date of Patent: July 27, 2010Assignee: POSCO Co., Ltd.Inventors: Byung-Keun Bae, Jae-Kwan Kim
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Patent number: 7736444Abstract: Grain oriented electrical steel is made in a manner that the grains are selectively grown to obtain a crystal structure known as cube-on-edge and the grains are largely aligned in the rolling direction. Selection of chemistry and process route along with thin slab continuous casting enables the production of Grain oriented electrical steel such that less energy is consumed in the process, certain process steps can be combined, yield is better and the product can be manufactured within a wider process control tolerance.Type: GrantFiled: April 16, 2007Date of Patent: June 15, 2010Assignee: Silicon Steel Technology, Inc.Inventors: Vladimir Pavlovich Shumilov, Alexandr G. Shalimov, Leonard Mironov, Urij Christiakov
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Patent number: 7727644Abstract: In a grain-oriented electrical steel sheet having phosphate-based coatings, which contain no chromium and which impart a tension, on the surfaces of a steel sheet with ceramic underlying films therebetween, the coating amount of oxygen in the underlying film is 2.0 g/m2 or more and 3.5 g/m2 or less relative to both surfaces of the steel sheet. Consequently, a grain-oriented electrical steel sheet with a chromium-less coating is provided. The resulting steel sheet has coating properties at the same level as those of a steel sheet with chromium-containing coatings and realizes high hygroscopicity resistance and a low iron loss without variations.Type: GrantFiled: November 7, 2005Date of Patent: June 1, 2010Assignee: JFE Steel CorporationInventors: Makoto Watanabe, Hiroaki Toda, Mineo Muraki
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Patent number: 7662242Abstract: Non-oriented electrical steel sheet superior in core loss characterized by containing, by mass %, C: 0.01% or less, Si: 0.1% to 7.0%, Al: 0.1% to 3.0%, Mn: 0.1% to 2.0%, N: 0.005% or less, Ti: 0.02% or less, REM: 0.05% or less, S: 0.005% or less, O: 0.005% or less, and a balance of iron and unavoidable impurities and having a mass % of S shown by [S], a mass % of O shown by [O], a mass % of REM shown by [REM], a mass % of Ti shown by [Ti], and a mass % of N shown by [N] satisfying [Formula 1] and [Formula 2]: [REM]2×[O]2×[S]?1×10?15??[Formula 1] ([REM]2×[O]2×[S])÷([Ti]×[N])?1×10?10??[Formula 2].Type: GrantFiled: September 28, 2005Date of Patent: February 16, 2010Assignee: Nippon Steel CorporationInventors: Masafumi Miyazaki, Wataru Ohashi, Yousuke Kurosaki, Takeshi Kubota, Hiroshi Harada, Tomohiro Konno, Yutaka Matsumoto, Koichi Kirishiki
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Patent number: 7658807Abstract: The present invention relates to a hot-rolled steel strip for further processing to form non-grain oriented electrical sheet with the following composition (in % by weight) C: <0.02%, Mn: ?1.2%, Si: 0.1-4.4%, Al 0.1-4.4%, wherein the sum formed from the Si content and twice the Al content is <5%, P: <0.15%, Sn: ?0.20%, Sb: ?0.20%, the remainder iron and unavoidable impurities, with a strip thickness which is at most 1.8 mm, and with a partially softened structure which is characterised by a high intensity for the ? fibre (fibre representation of orientation distribution functions) in the region of 0° to 60°, wherein the ratio I112/I001 formed from the intensity I112 of the position (112) <110> to the intensity I001 of the position (001) <110> is >0.4 and the ratio I111/I001 formed from the intensity I111 of the position (111) <110> to the intensity I001 of the position (001) <110> is >0.2.Type: GrantFiled: October 23, 2002Date of Patent: February 9, 2010Assignee: ThyssenKrupp Steel AGInventors: Karl Ernst Friedrich, Wolfgang Rasim, Joergen Schneider, Rudolf Kawalla, Carl-Dieter Wuppermann
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Patent number: 7608154Abstract: A nonoriented electrical steel sheet excellent in core loss comprising copper sulfides with a sphere-equivalent radius of 100 nm or less, wherein the number density of the copper sulfides is less than 1×1010 [inclusions/mm3]. Preferably, the percentage of the number of copper sulfides with a (major axis)/(minor axis) ratio of more than 2 per total number of copper sulfides is 30% or less. The steel preferably further comprises Cu of 0.5 mass % or less and REM of 0.0005% or more and 0.03% or less, wherein the following expression (1) or expressions (1) and (2) are met: [REM]×[Cu]3?7.5×10?11??(1), ([REM]?0.003)0.1×[Cu]2?1.25×10?4??(2).Type: GrantFiled: September 9, 2005Date of Patent: October 27, 2009Assignee: Nippon Steel CorporationInventors: Wataru O-hashi, Masafumi Miyazaki, Yousuke Kurosaki, Takeshi Kubota
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Patent number: 7566371Abstract: Non-oriented electrical steel sheet remarkably improved in magnetic properties in the rolling direction by a method superior in cost and productivity, that is, non-oriented electrical steel sheet excellent in magnetic properties in the rolling direction comprising, by wt %, Si in an amount of 2.0% or less, Mn in 3.0% or less, Al in 1.0% to 3.0%, at least one of Sn, Sb, Cu, Ni, Cr, P, REM, Ca, and Mg in a total of 0.002% to 0.5%, and a balance of Fe and unavoidable impurities and having a ratio (B50L/Bs) of the magnetic flux density B50L in the rolling direction after stress relief annealing and a saturated magnetic flux density Bs of 0.85 or more and an core loss W15/50L of 2.0 W/kg or less, produced by the method of annealing the hot band at 800° C. to 1100° C. for 30 seconds or more to achieve a crystal grain size after final annealing of 50 ?m or less, skin pass rolling the sheet by a reduction of 3% to 10%, then stress relief annealing it. Further, a cold rolling reduction of 60% to 75% is preferable.Type: GrantFiled: February 17, 2006Date of Patent: July 28, 2009Assignee: Nippon Steel CorporationInventors: Yoshihiro Arita, Kenichi Murakami
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Publication number: 20090139609Abstract: A method, which makes it possible to economically produce high-quality grain oriented magnetic steel sheet, utilizes a steel alloy with (in wt %) Si: 2.5-4.0%, C: 0.01-0.10%, Mn: 0.02-0.50%, S and Se in contents, whose total amounts to 0.005-0.04%. The method utilizes an operational sequence whose individual routine steps (secondary metallurgical treatment of the molten metal in a vacuum—or ladle facility, continuous casting of the molten metal into a strand, dividing of the strand, heating in a facility standing inline, continuous hot rolling in a multi-stand hot rolling mill standing inline, cooling, coiling, cold rolling, recrystallization and decarburization annealing, application of an annealing separator, final annealing to form a Goss texture) are harmonized with one another, so that a magnetic steel sheet with optimized electromagnetic properties is obtained using conventional apparatus.Type: ApplicationFiled: July 20, 2006Publication date: June 4, 2009Applicant: ThyssenKrupp Steel AGInventors: Klaus Gunther, Ludger Lahn, Andreas Ploch, Eberhard Sowka
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Patent number: 7513959Abstract: When a non-oriented electrical steel sheet is manufactured, simultaneously having superior magnetic properties and high strengths, a composition containing 0.02% or less of C, 4.5% or less of Si, 5.0% or less (including 0) of Ni, and 0.2% to 4.0% of Cu is used, and a solute Cu is allowed to appropriately remain in finish annealing. In the steel sheet thus obtained, finely shaped Cu is precipitated by aging treatment, and while the magnetic properties are not degraded, the yield stress is increased to not less than CYS (MPa) represented by the following formula: note CYS=180+5,600[% C]+95[% Si]+50[% Mn]+37[% Al]+435[% P]+25[% Ni]+22d?1/2 where d is an average grain diameter (mm) of crystal grains.Type: GrantFiled: December 3, 2003Date of Patent: April 7, 2009Assignee: JFE Steel CorporationInventors: Minoru Takashima, Masaaki Kohno, Katsumi Yamada, Masaki Kawano, Kaoru Sato
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Patent number: 7501028Abstract: The invention relates to non-grain oriented magnetic steel sheets which can be produced as final annealed and as a non-final annealed types in such a way that they have improved magnetic polarisation and reduced magnetic reversal losses compared with the previously achieved values. This is achieved in that a suitably composed steel, during its cooling starting from a maximum initial temperature of 1,300° C., passes through a temperature range with substantially complete exclusion of a purely austenitic structure (? phase), in which range it comprises an austenite/ferrite dual phase multi-structure (?, ? multi-phases), so the magnetic steel sheet, after hot rolling, etching, cold rolling and annealing of the hot strip obtained after hot rolling, has a magnetic polarisation J2500?1.74 T, measured in the longitudinal direction of the strip or sheet and at a magnetic field strength of 2,500 A/m and a value P1.5(50) of the magnetic losses of <4.5 W/kg, measured in the longitudinal direction of the strip at J=1.Type: GrantFiled: May 15, 2003Date of Patent: March 10, 2009Assignee: ThyssenKrupp Stahl AGInventors: Brigitte Hammer, Karl Ernst Friedrich, Olaf Fischer, Jürgen Schneider, Carl-Dieter Wuppermann
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Patent number: 7501029Abstract: A high-strength, high-permeability steel sheet for picture tube band comprises, in mass percent, C: 0.003-0.010%, Si: 0.5-1.0%, Mn: 1.0-2.0%, P: 0.04-0.15%, S: not more than 0.02%, Al: not more than 0.030%, N: not more than 0.004% and the balance of Fe and unavoidable impurities, has a chemical composition satisfying C×Mn×P?2.5×10?4, and has a ferrite crystal grain diameter of 10-100 ?m and a yield stress of 300 N/mm2 or higher, and preferably has a specific permeability ?0.35 in a DC magnetic field of 0.35 Oe of 400 or higher. The steel sheet can be produced by regulating the hot-rolling coiling temperature to 600-700° C. and selecting an appropriate combination of the cold rolling reduction ratio and a final annealing temperature in the range of 750-900° C.Type: GrantFiled: April 12, 2004Date of Patent: March 10, 2009Assignee: Nisshin Steel Co., Ltd.Inventors: Tsunetoshi Suzaki, Kentaro Hirata, Yuichi Higo
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Publication number: 20090044881Abstract: Reheating a grain-oriented electrical steel sheet slab comprising predetermined components to 1280° C. or more and a solid solution temperature of inhibitor substances or more, hot rolling, annealing, and cold rolling it, decarburization annealing it, nitriding it in a strip running state, coating an annealing separator, and finish annealing it during which making a precipitation ratio of N as AlN after hot rolling 20% or less, making a mean grain size of primary recrystallization 7 ?m to less than 20 ?m, and making a nitrogen increase ?N in the nitridation within a range of Equation (1) and making nitrogen contents ?N1 and ?N2 (front and back, mass %) of a 20% thickness portion of one surface of the steel strip (sheet) within a range of Equation (2): 0.007?([N]?14/48×[Ti])??N?[solAl]×14/27?([N]?14/48×[Ti])+0.0025??Equation (1) |?N1??N2|/?N?0.Type: ApplicationFiled: May 19, 2006Publication date: February 19, 2009Inventors: Tomoji Kumano, Kenichi Murakami, Yoshiyuki Ushigami
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Publication number: 20090032142Abstract: The invention provides a method of producing a grain-oriented electrical steel sheet of the complete solid solution nitrided type that is good in glass film formation and excellent in magnetic properties, which method comprises: C: 0.025 to 0.09%, hot-rolling the steel slab containing Si: 2.5 to 4.0% and acid-soluble Al into a hot-rolled steel strip; controlling the rate at which N contained in the hot-rolled steel strip is precipitated as AlN to a precipitation rate of 20% or less; conducting hot-rolled strip annealing and cold rolling conducting decarburization-annealing combined with primary recrystallization by during the former part of the process in an atmosphere whose PH2O/PH2 is 0.30 to 0.70 and then during the latter part thereof in an atmosphere whose PH2O/PH2 is 0.Type: ApplicationFiled: January 12, 2007Publication date: February 5, 2009Applicants: Nippon Steel Corporation, Nittetsu Plant Designing CorporationInventors: Tomoji Kumano, Shyuichi Yamazaki, Osamu Tanaka
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Patent number: 7470333Abstract: A non-oriented electrical steel sheet is characterized in that the number density of inclusions with an equivalent volume diameter of less than 100 nm contained in the steel sheet is 1×1010 [/mm3] or less, and that the steel sheet contains, by mass %, C: up to 0.01%, Si: 0.1% to 7.0%. Al: 0.1% to 3.0%. Mn: 0.1% to 2.0%, REM: 0.0003% to 0.05%. Ti: up to 0.02%. S: up to 0.005%. and N: up to 0.005%. the balance Fe and inevitable impurities and the mass % of Al represented by [Al] and the mass % of Ti represented by [Ti] satisfy the equation log([Ti]×[N])?1.19×log([Al]×[N])+1.84>0 . . . (1).Type: GrantFiled: April 28, 2004Date of Patent: December 30, 2008Assignee: Nippon Steel Corp.Inventors: Wataru Ohashi, Akihito Kiyose, Masafumi Miyazaki, Takeshi Kubota, Yousuke Kurosaki, Yoshihiro Arita, Ken-ichiro Miyamoto, Takashi Sawai
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Patent number: 7465361Abstract: In a method for manufacturing a grain-oriented electrical steel sheet using steel containing less than 100 ppm of Al and 50 ppm or less each of N, S, and Se as a starting material, purification annealing is performed at 1050° C. or more, the partial pressure of hydrogen in the atmosphere being adjusted to 0.4 atm or less in a temperature range above 1170° C. for a purification annealing conducted at a temperature above 1170° C., or 0.8 atm or less in a temperature range of 1050° C. or more for a purification annealing conducted at a temperature of 1170° C. or less, to prevent deterioration of the bend properties due to the impurities.Type: GrantFiled: October 27, 2003Date of Patent: December 16, 2008Assignee: JFE Steel CorporationInventors: Takashi Terashima, Minoru Takashima, Yasuyuki Hayakawa
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Patent number: 7465364Abstract: An Fe—Cr—Si based non-oriented electrical steel sheet contains 2.5% to 10% by mass of Si, 1.5% to 20% by mass of Cr, 0.006% by mass or less of C, 0.002% by mass or less of N, 0.005% by mass or less of S, 0.005% by mass or less of Ti, 0.005% by mass or less of Nb, and as necessary, 0.1% to 2% by mass of Al and at least one of 0.005% to 1% by mass of Sb and 0.005% to 1% by mass of Sn, and the balance being Fe and incidental impurities, wherein the electrical resistivity of the steel is 60 ??cm or more, and the number of nitrides containing chromium per mm2 in the interior of the steel sheet is 2,500 or less. Consequently, the problem that high electrical resistance resulting from the high Si content and high Cr content is not satisfactorily utilized is advantageously solved, and it is possible to provide a non-oriented electrical steel sheet having excellent magnetic properties in the high-frequency range, in particular, in a frequency range of 1 kHz or more.Type: GrantFiled: December 18, 2003Date of Patent: December 16, 2008Assignee: JFE Steel CorporationInventors: Takeshi Omura, Masaaki Kohno, Masaki Kawano
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Publication number: 20080271819Abstract: The present invention is a grain-oriented electrical steel sheet characterized in that Bi is present at 0.01 to less than 1,000 ppm in terms of mass at the interface of the substrate steel and the primary film of the grain-oriented electrical steel sheet. The grain-oriented electrical steel sheet is produced by any of the processes of: before decarburization annealing, applying preliminary annealing for 1 to 20 sec. at 700° C. or higher and controlling an atmosphere in the temperature range; controlling the maximum attaining temperature B (° C.) before final cold rolling so that the maximum attaining temperature B may satisfy the expression, ?10×ln(A)+1,100?B?10×ln(A)+1,220, in accordance with a Bi content A (ppm) and at the same time heating the steel sheet cold rolled to the final thickness to 700° C. or higher within 10 sec. or at a heating rate of 100° C./sec. or more before decarburization annealing, or immediately thereafter applying preliminary annealing for 1 to 20 sec. at 700° C.Type: ApplicationFiled: June 27, 2008Publication date: November 6, 2008Applicant: Nippon Steel Corporation,Inventors: Eiichi Nanba, Katsuyuki Yanagihara, Satoshi Arai, Shuichi Yamazaki, Fumikazu Ando, Kazutoshi Takeda, Yousuke Kurosaki, Nobuo Tachibana
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Patent number: 7442260Abstract: The present invention provides a grain-oriented electrical steel sheet with an extremely low core loss by scanning by a small focused laser beam spot and a method of production of the same, that is, a grain-oriented electrical steel sheet improved in electrical characteristics by scanning by a continuous wave fiber laser of the TEM00 mode with a wavelength ? of 1.07???2.10 ?m substantially perpendicular to the steel sheet rolling direction and at substantially constant spacing and a method of production of the same, wherein a rolling direction focused spot diameter d (mm) of the irradiated beam, a linear scan rate V (mm/s) of the laser beam, an average output P (W) of the laser, a width of the formed laser scribing traces or with of the electrical domains Wl (mm), and a rolling direction Pl (mm) of the laser scribing traces are in the following ranges: 0<d?0.20 0.001?P/V?0.012 0<Wl?0.20 1.5?Pl?11.0.Type: GrantFiled: March 5, 2004Date of Patent: October 28, 2008Assignee: Nippon Steel CoroorationInventors: Tatsuhiko Sakai, Hideyuki Hamamura, Naoya Hamada
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Patent number: 7399369Abstract: The present invention is a grain-oriented electrical steel sheet characterized in that Bi is present at 0.01 to less than 1,000 ppm in terms of mass at the interface of the substrate steel and the primary film of the grain-oriented electrical steel sheet. The grain-oriented electrical steel sheet is produced by any of the processes of: before decarburization annealing, applying preliminary annealing for 1 to 20 sec. at 700° C. or higher and controlling an atmosphere in the temperature range; controlling the maximum attaining temperature B (° C.) before final cold rolling so that the maximum attaining temperature B may satisfy the expression, ?10×ln(A)+1,100?B?10×ln(A)+1,220, in accordance with a Bi content A (ppm) and at the same time heating the steel sheet cold rolled to the final thickness to 700° C. or higher within 10 sec. or at a heating rate of 100° C./sec. or more before decarburization annealing, or immediately thereafter applying preliminary annealing for 1 to 20 sec. at 700° C.Type: GrantFiled: July 16, 2002Date of Patent: July 15, 2008Assignee: Nippon Steel CorporationInventors: Eiichi Nanba, Katsuyuki Yanagihara, Satoshi Arai, Shuichi Yamazaki, Fumikazu Ando, Kazutoshi Takeda, Yousuke Kurosaki, Nobuo Tachibana
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Publication number: 20080121314Abstract: The present invention relates to technology for manufacturing electrical steel sheets having excellent magnetic properties through the control of a hot-rolled texture using the phase transformation of steel. More particularly, it relates to a non-oriented electrical steel sheet that has reduced iron loss and increased magnetic flux density by controlling alloy component elements and optimizing hot-rolling conditions, even though hot-rolled sheet annealing is not carried out, as well as a manufacturing method thereof. More specifically, the invention provides a non-oriented electrical steel sheet which has excellent magnetic properties while hot-rolled sheet annealing can be omitted, the steel sheet being comprised of 0.005 wt % or less of C, 1.0-3.0 w % of Si, 0.1-2.0 wt % of Mn, 0.1 wt % or less of P, 0.1-1.5 wt % of Al, and a remainder of Fe and other inevitable impurities, in which the relationship between the elements Mn and Al satisfies an equation of ?0.2 <m(=Mn?Al)<1.Type: ApplicationFiled: December 20, 2005Publication date: May 29, 2008Inventors: Jae-Young Choi, Byung-Keun Bae, Jong-Tae Park, Jae-Kwan Kim, Chel-Min Park
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Patent number: 7377986Abstract: The present invention relates to a method for producing a non-oriented electrical steel with improved magnetic properties and improved resistance to ridging, brittleness, nozzle clogging and magnetic aging. The chromium bearing steel is produced from a steel melt which is cast as a thin slab or conventional slab, cooled, hot rolled and/or cold rolled into a finished strip. The finished strip is further subjected to at least one annealing treatment wherein the magnetic properties are developed, making the steel sheet of the present invention suitable for use in electrical machinery such as motors or transformers.Type: GrantFiled: July 27, 2006Date of Patent: May 27, 2008Assignee: AK Steel Properties, Inc.Inventors: Jerry W. Schoen, Robert J. Comstock, Jr.
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Patent number: 7371291Abstract: A grain oriented electromagnetic steel sheet is free from an undercoating mainly composed of forsterite (Mg2SiO4), excellent in processability and magnetic properties and useful to production cost, and has a composition containing, by % by mass, 2.0 to 8.0% of Si, wherein secondary recrystallized grains contains fine crystal grains having a grain diameter of 0.15 mm to 0.50 mm at a rate of 2 grains/cm2 or more. In the process of producing the steel sheet, inhibitors are not utilized, and the fine crystal grains are achieved by high purification and low temperature final annealing.Type: GrantFiled: June 6, 2005Date of Patent: May 13, 2008Assignee: JFE Steel CorporationInventors: Yasuyuki Hayakawa, Mitsumasa Kurosawa, Seiji Okabe, Takeshi Imamura
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Patent number: 7364629Abstract: In a method for manufacturing grain-oriented silicon steel with mirror-like surface by applying an aqueous slurry of an annealing separator, magnetic properties are stabilized by controlling the amount of moisture, carried in the annealing separator consisting mainly of alumina after application and drying thereof, to not more than 1.5%, controlling the partial water vapor pressure during finish-annealing and eliminating the variation (instability) in secondary recrystallization caused by the inhibitor reaction at the interface.Type: GrantFiled: January 7, 2003Date of Patent: April 29, 2008Assignee: Nippon Steel CorporationInventors: Yoshiyuki Ushigami, Shuichi Nakamura, Hiroyasu Fujii, Kenichi Murakami
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Patent number: 7291230Abstract: The present invention: relates to a grain-oriented electrical steel sheet and a double-oriented electrical steel sheet which are used as soft magnetic materials for electrical machinery and apparatus; and is a grain-oriented electrical steel sheet extremely excellent in film adhesiveness, characterized by: containing, in mass, 2.5 to 4.5% Si, 0.01 to 0.4% Ti, and not more than 0.005% as to each of C, N, S and O, with the balance substantially consisting of Fe and unavoidable impurities; and having films comprising compounds of C with Ti or Ti and one or more of Nb, Ta, V, Hf, Zr, Mo, Cr and W on the surfaces of said steel sheet, and a method for producing the steel sheet.Type: GrantFiled: March 28, 2003Date of Patent: November 6, 2007Assignee: Nippon Steel CorporationInventors: Hotaka Homma, Yoshiaki Hirota, Yasumitsu Kondo, Yuji Kubo, Takehide Senuma, Shuichi Nakamura
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Patent number: 7282102Abstract: A method for manufacturing a high silicon grain-oriented electrical steel sheet. In a method for manufacturing a high silicon grain-oriented electrical steel sheet, comprising the steps of: reheating and hot-rolling a steel slab to produce a hot-rolled steel sheet; annealing the hot-rolled sheet and cold rolling the annealed steel sheet so as to adjust a thickness of the steel sheet; decarburization annealing the cold rolled steel sheet; and finish-annealing the decarburization annealed steel sheet for secondary recrystallization, the improved method further comprising the step of: coating a powder coating agent for siliconization on a surface of the decarburization annealed steel sheet in a slurry state, the powder coating agent including 100 part by weight of MgO powder and 0.Type: GrantFiled: November 11, 2003Date of Patent: October 16, 2007Assignee: PoscoInventors: Kyu-Seung Choi, Jong-Soo Woo, Jae-Kwan Kim
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Patent number: 7214277Abstract: A quench solidification method, wherein a steel cast strip having a mean grain size 50 ?m or more is prepared and then the steel cast strip is rolled to produce a non-oriented electrical steel sheet having high magnetic flux density in both L and C directions. However the magnetic flux density reduces when the cold reduction rate exceeds 70%. To avoid this problem the non-oriented electrical steel sheet is manufactured with a ratio of at least 4 of the integrated intensity of the {100} plane for a given sample of steel to the integrated intensity of {100} plane for a “random” sample in which crystal grains have random orientations; and a cold reduction rate of the cold-rolling is between 70% and 85%. The superheating degree of the molten steel can be 70° C. or more.Type: GrantFiled: April 8, 2004Date of Patent: May 8, 2007Assignee: Nippon Steel CorporationInventors: Yousuke Kurosaki, Takeshi Kubota, Hideaki Yamamura, Takashi Arai, Eiichiro Ishimaru, Yoshihiro Arita, Isao Suichi, Kenji Kosuge
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Patent number: 7198682Abstract: A process for the production of electrical steel strips, in which a strip is directly cast from molten steel and contains alloy elements apt to generate a precipitation of sulphides and/or nitrides apt to inhibit the grain growth. The strip is hot rolled in-line with the casting operation at a temperature between 1250 and 1000° C., and in which the strip is coiled after hot rolling at a temperature of less than 780° C. if sulphides are utilized, or at a temperature of less than 600° C. if nitrides, or nitrides plus sulphides, are utilized.Type: GrantFiled: December 17, 2001Date of Patent: April 3, 2007Assignee: Thyssenkrupp Acciai Speciali Terni S.p.A.Inventors: Stefano Cicale′, Stefano Fortunati, Giuseppe Abbruzzese
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Patent number: 7192492Abstract: In the production of electrical steel strips, a special islab-reheating treatment before hot rolling is carried out so that the maximum temperature within the furnace is reached by the slab well before its extraction from the furnace. During the heating stage and performance at the highest temperatures of the thermal cycle, second phase particles are dissolved and segregated elements are distributed in the metallic matrix, while during cooling and temperature equalising steps of the slab in the furnace a controlled amount of small second phases particles are more homogeneously re-precipitated from the metallic matrix. Differently from all the conventional processes for the production of electrical steels, the slab reheating furnace become a site in which it is performed the precipitation of a controlled amount of second phases particles for the necessary grain growth control during the successive process steps.Type: GrantFiled: August 8, 2001Date of Patent: March 20, 2007Assignee: Thyssenkrupp Acciai Speciali Terni S.p.A.Inventors: Stefano Fortunati, Stefano Cicale′, Claudia Rocchi, Giuseppe Abbruzzese
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Patent number: 7045025Abstract: A low core loss grain-oriented electrical steel sheet that does not have a significant deterioration in a magnetic flux density and a decrease of a space factor, and which may withstand stress-relieving annealing is provided. Melted and re-solidified layers can be formed on either or both of the surfaces of the grain-oriented electrical steel sheet that extend in a direction that is perpendicular to the rolling direction (e.g., in the direction of the width thereof), at a cyclic interval of not less than approximately 2 mm to less than approximately 5 mm in the rolling direction. The melted and re-solidified layers may be provided on each surface of the grain-oriented electrical steel sheet, and can have an aspect ratio that is a ratio of the depth to the width of the melted and re-solidified layer of not less than approximately 0.20 and a depth of not less than approximately 15 ?m. In addition, the melted and re-solidified layers can be formed by using a laser.Type: GrantFiled: May 30, 2003Date of Patent: May 16, 2006Assignee: Nippon Steel CorporationInventors: Hideyuki Hamamura, Tatsuhiko Sakai, Naoya Hamada
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Patent number: 6964711Abstract: A process for the production of grain oriented electrical Fe-Si strips in which a Si-containing alloy is directly cast as a strip between 2.5–5.0 mm thick and cold rolled in one stage, or in more stages with intermediate annealing, to a final thickness of between 0.15–1.0 mm. The strip is then continuously annealed to carry out the primary recrystallization and then annealed to carry out the oriented secondary recrystallization. The process further includes that after solidification of the strip, and before its coiling, a phase transformation from Ferrite to Austenite is induced into the metal matrix for a volume fraction between 25–60%, obtained by controlling the alloy composition so that the Austenite fraction is allowed within the stability equilibrium between the two phases. The strip is then deformed by rolling in-line with the casting step to obtain a deformation higher than 20% in the temperature interval 1000–1300° C.Type: GrantFiled: December 18, 2001Date of Patent: November 15, 2005Assignee: Thyssenkrupp Acciai Speciali Terni S.p.A.Inventors: Stefano Fortunati, Stefano Cicale′, Giuseppe Abbruzzese
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Patent number: 6938324Abstract: A motor stator core for achieving improved magnetizing feature in lower magnetic fields and reduced iron loss, and improving motor power. The stator core fabriated out of non-oriented electrical steel sheets is annealed by applying a magnetic field to the heated stator core at least in the temperature range from a temperature immediately above a Curie point thereof to 300° C. in the process of cooling the stator core. The magnetic field has the same direction as the direction of exitation of a stator in the motor when used to drive a motor. This increases the magnetic induction in lower magnetic fields in particular and reduces the hysteresis loss, with a reduction in the total iron loss of the stator. A motor using this stator core increases in saturation induction under exciting currents of higher frequncies, allowing enhanced motor power.Type: GrantFiled: October 21, 2003Date of Patent: September 6, 2005Assignees: Toyo Tessin Kogyo Co., Ltd., Hi-Z Co., Ltd.Inventors: Hiromichi Koshiishi, Tomiya Ogata, Shigeki Eguchi, Hideo Hasegawa
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Patent number: 6929704Abstract: A grain-oriented electromagnetic steel sheet having a multiplicity of fine grains having a diameter of about 3 mm or less on the surface of the steel sheet, in a numerical ratio of about 65% or more and of about 98% or less relative to the constituting grains that penetrate the sheet along the direction parallel to its thickness, and a method for producing the same. The fine grains are artificially created and regularly disposed with a random orientation in the steel sheet, and contribute to decreasing the strain susceptibility of the steel. More preferably, a treatment for finely dividing magnetic domains is applied on the surface of the steel sheet. Transformers based upon the steel sheet have excellent magnetic characteristics (iron loss and magnetic flux density) together with strain resistance, and the steel sheet has good practical device characteristics (building factor) after being assembled into a transformer.Type: GrantFiled: June 6, 2002Date of Patent: August 16, 2005Assignee: JFE Steel CorporationInventors: Michiro Komatsubara, Toshito Takamiya, Kunihiro Senda
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Patent number: 6893510Abstract: Process for the production of oriented grain electrical steel strips, in which a silicon steel, comprising at least 30 ppm of S, is directly cast as strip 1.5-4.5 mm thick and cold rolled to a final thickness of between 1.0 and 0.15 mm; characterised by the following staged: Cooling and deformation of the solidified strip to obtain a second phases distribution in which 600 cm?1<Iz<1500 cm?1 and Iy=1.9 Fv/r (cm?1), Fv being the volume fraction of second phases stable at temperatures of less than 800° C., and r being the precipitates mean radius, in cm; Hot rolling between solidification and coiling of the strip at a temperature of not less than 750° C., with a reduction ratio of between 15 and 60%; Cold rolling with reduction ratio of 60-92%; Cold rolled strip annealing at 750-1100° C., with increase of the nitrogen content of at least 30 ppm with respect to the initial composition at the strip core, in nitriding atmosphere.Type: GrantFiled: December 17, 2001Date of Patent: May 17, 2005Assignee: Thyssenkrupp Acciai Speciali Terni S.p.A.Inventors: Stefano Fortunati, Stefano Cicale', Claudia Rocchi, Giuseppe Abbruzzese
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Patent number: 6858095Abstract: A grain-oriented electrical steel sheet comprising 2.5-4.5% Si by weight and measuring 0.36-1.00 mm in thickness is imparted with a good core loss value for its thickness by controlling its C content, flux density, grain boundary configuration, and deviation degree of crystal orientation in the grains.Type: GrantFiled: February 14, 2001Date of Patent: February 22, 2005Assignee: Nippon Steel CorporationInventors: Yasunari Yoshitomi, Hiroaki Masui, Nobuyuki Takahashi
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Publication number: 20040231752Abstract: The present invention is a grain-oriented electrical steel sheet characterized in that Bi is present at 0.01 to less than 1,000 ppm in terms of mass at the interface of the substrate steel and the primary film of the grain-oriented electrical steel sheet. The grain-oriented electrical steel sheet is produced by any of the processes of: before decarburization annealing, applying preliminary annealing for 1 to 20 sec. at 700° C. or higher and controlling an atmosphere in the temperature range; controlling the maximum attaining temperature B (° C.) before final cold rolling so that the maximum attaining temperature B may satisfy the expression, −10×ln(A)+1,100≦B≦10×ln(A)+1,220, in accordance with a Bi content A (ppm) and at the same time heating the steel sheet cold rolled to the final thickness to 700° C. or higher within 10 sec. or at a heating rate of 100° C./sec.Type: ApplicationFiled: June 22, 2004Publication date: November 25, 2004Inventors: Eiichi Nanba, Katsuyuki Yanagihara, Satoshi Arai, Shuichi Yamazaki, Fumikazu Ando, Kazutoshi Takeda
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Patent number: 6821358Abstract: Ferritic stainless steel, comprising the following composition by weight: 0%<C≦0.030% 1%≦Si≦3% 0%<Mn≦0.5% 10%≦Cr≦13% 0%<Ni≦0.5% 0%<Mo≦3% N≦0.030% Cu≦0.5% Ti≦0.5% Nb≦1% Ca≧1×10−4% 0≧10×10−4% S≦0.030% P≦0.030% the remainder being iron and the impurities which are inevitable from the production of the steel.Type: GrantFiled: March 8, 2002Date of Patent: November 23, 2004Assignee: Ugine-Savoie ImphyInventors: Etienne Havette, Christophe Bourgin, Benoît Pollet, Jean Lamontanara
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Publication number: 20040226632Abstract: A thermal quenching installation making use of induction heating. This installation has induction heater means comprising a stationary induction coil, handling means to cause the element to pass through said coil, and cooling means, preferably a shower, disposed downstream from the coil.Type: ApplicationFiled: October 2, 2003Publication date: November 18, 2004Inventor: Francois Lecoester
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Patent number: 6811619Abstract: A method of manufacturing a grain-oriented steel sheet including hot-rolling a slab prepared using molten steel containing, by mass %, C of not more than about 0.08%, Si of about 2.0 to about 8.0% and Mn of about 0.005 to about 3.0%; optionally annealing the hot-rolled steel sheet; performing cold rolling once, or twice or more with intermediate annealing therebetween; performing primary recrystallization annealing in a low- or non-oxidizative atmosphere and adjusting the C content in the steel sheet after primary recrystallization annealing to be held in the range of about 0.005 to about 0.025 mass %; performing secondary recrystallization annealing; decarburization annealing; and, preferably, performing additional high-temperature continuous or batch annealing. A grain-oriented electrical steel sheet having a sufficiently high magnetic flux density and a low iron loss can be advantageously obtained even when it is manufactured without using an inhibitor.Type: GrantFiled: July 23, 2002Date of Patent: November 2, 2004Assignee: JFE Steel CorporationInventors: Yasuyuki Hayakawa, Hideo Yamagami, Seiji Okabe, Takeshi Imamura, Minoru Takashima, Mitsumasa Kurosawa
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Publication number: 20040200548Abstract: A quench solidification method, wherein a steel cast strip having a mean grain size 50 &mgr;m or more is prepared and then the steel cast strip is rolled to produce a non-oriented electrical steel sheet having high magnetic flux density in both L and C directions. However the magnetic flux density reduces when the cold reduction rate exceeds 70%. To avoid this problem the non-oriented electrical steel sheet is manufactured with a ratio of at least 4 of the integrated intensity of the {100} plane for a given sample of steel to the integrated intensity of {100} plane for a “random” sample in which crystal grains have random orientations; and a cold reduction rate of the cold-rolling is between 70% and 85%. The superheating degree of the molten steel can be 70° C. or more.Type: ApplicationFiled: April 8, 2004Publication date: October 14, 2004Inventors: Yousuke Kurosaki, Takeshi Kubota, Hideaki Yamamura, Takashi Arai, Eiichiro Ishimaru, Yoshihiro Arita, Isao Suichi, Kenji Kosuge
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Patent number: 6773514Abstract: The present invention relates to a method for producing non grain-oriented magnetic steel sheets in which hot strip is produced from an input stock such as cast slabs, strip, roughed strip, or thin slabs, made of steel comprising (in weight %) C: 0.001-0.05%; Si: ≦1.5%; Al: ≦0.4% with Si+2Al≦1.7%; Mn: 0.1-1.2%; if necessary up to a total of 1.5% of alloying additions such as P, Sn, Sb, Zr, V, Ti, N, Ni, Co, Nb and/or B; with the remainder being iron as well as the usual accompanying elements; in that the input stock is hot-rolled directly from the casting heat or after preceding reheating to a reheating temperature between min. 1000° C. and max. 1180° C.Type: GrantFiled: June 6, 2002Date of Patent: August 10, 2004Assignee: Thyssen Krupp Stahl AGInventors: Rudolf Kawalla, Hans Pircher, Karl Ernst Friedrich, Brigitte Hammer, Jürgen Schneider, Olaf Fischer, Carl-Dieter Wuppermann
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Publication number: 20040149355Abstract: The present invention provides a non-oriented electrical steel sheet containing:Type: ApplicationFiled: December 24, 2003Publication date: August 5, 2004Inventors: Masaaki Kohno, Masaki Kawano, Atsuhito Honda, Akio Fujita
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Patent number: 6767412Abstract: The invention relates to a method for producing non-grain-oriented hot-rolled magnetic steel sheet in which from a raw material such as cast slabs, strip, roughed strip or thin slabs produced from a steel comprising (in weight %) C: 0.0001-0.05%; Si: ≦1.5%; Al: ≦0.5%, wherein [% Si]+2[% Al]≦1.8; Mn: 0.1-1.2%; if necessary up to a total of 1.5% of alloying additions such as P, Sn, Sb, Zr, V, Ti, N, Ni, Co, Nb and/or B, with the remainder being iron and the usual impurities, in a finishing roll line at temperatures above the Ar1 temperature, a hot strip with a thickness ≦1.5 mm is rolled, wherein at least the last forming pass of hot rolling is carried out in the mixed region austenite/ferrite and wherein the total deformation &egr;H achieved during rolling in the mixed region austenite/ferrite is <35%.Type: GrantFiled: January 14, 2003Date of Patent: July 27, 2004Assignee: ThyssenKrupp Stahl AGInventors: Karl Ernst Friedrich, Brigitte Hammer, Rudolf Kawalla, Olaf Fischer, Jürgen Schneider, Carl-Dieter Wuppermann
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Patent number: 6749693Abstract: In a method of producing a strip suitable for further processing to yield a (110)[001] grain oriented electrical steel from a thin strip such as a continuously cast thin strip the thin cast strip is processed to promote recrystallization from the surface layer of the strip (S=0) into the quarter thickness of the strip (S=0.2 to 0.3). The process parameters are selected so that the strain/recrystallization parameter (K*)−1, ≧about 6500 and wherein, ( K * ) - 1 = ( T HBA ) ⁢ ln ⁡ [ e . 0.Type: GrantFiled: September 13, 2002Date of Patent: June 15, 2004Assignee: AK PropertiesInventors: Jerry W. Schoen, Glenn S. Huppi
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Publication number: 20040099342Abstract: The present invention refers to a process for the production of electrical steel strips, in which a strip directly cast from molten steel and containing alloy elements apt to generate a precipitation of sulphides and/or nitrides apt to inhibit the grain growth, is hot rolled in-line with the casting operation, at a temperature comprised between (1250) and (1000)° C., and in which said strip is coiled after hot rolling at a temperature of less than (780)° C. if sulphides are utilised, or at a temperature of less than (600)° if nitrides, or nitrides plus sulphides, are utilised. A final product is thus obtained having excellent and constant magnetic properties.Type: ApplicationFiled: November 13, 2003Publication date: May 27, 2004Inventors: Stefano Cicale, Stefano Fortunati, Giuseppe Abbruzzese
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Patent number: 6739384Abstract: A method for continuously casting grain oriented electrical steel is disclosed. This method utilizes a controlled rapid cooling step, such as one using a water spray, to control the grain orientation in the finished product. The product formed not only has the appropriate grain orientation but also has good physical properties, for example, minimized cracking. In this process, after a continuously cast electrical steel strip is formed, the strip undergoes an initial secondary cooling to from about 1150 to about 1250° C., and finally undergoes a rapid secondary cooling (for example, by water spray) at a rate of from about 65° C./second to about 150° C./second to a temperature of no greater than about 950° C.Type: GrantFiled: September 13, 2002Date of Patent: May 25, 2004Assignee: AK Properties, Inc.Inventors: Jerry W. Schoen, Robert S. Williams, Glenn S. Huppi
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Patent number: 6733599Abstract: The present invention provides a method for producing a grain-oriented silicon steel sheet not having inorganic mineral films by using an annealing separator capable of preventing the inorganic mineral films composed of forsterite (Mg2SiO4), and so on, from forming during final annealing, comprising the steps of decarburization annealing followed by coating of annealing separator and final annealing, wherein alumina powder calcined at a calcination temperature of 900 to 1,400° C., or further having a BET specific surface area of 1 to 100 m2/g, an oil absorption of 1 to 70 ml/100 g, and/or having a gamma ratio of 0.001 to 2.0, is used as the annealing separator. Magnesia having a BET specific surface area of 0.5 to 5 m2/g may be added to said alumina powder.Type: GrantFiled: December 20, 2002Date of Patent: May 11, 2004Assignee: Nippon Steel CorporationInventors: Hiroyasu Fujii, Yoshiyuki Ushigami, Shuichi Nakamura, Kenichi Murakami, Norihiro Yamamoto, Kiyoshi Sawano, Shuichi Yamazaki
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Publication number: 20040074565Abstract: A grain oriented electromagnetic steel sheet is free from an undercoating mainly composed of forsterite (Mg2SiO4), excellent in processability and magnetic properties and useful to production cost, and has a composition containing, by % by mass, 2.0 to 8.0% of Si, wherein secondary recrystallized grains contains fine crystal grains having a grain diameter of 0.15 mm to 0.50 mm at a rate of 2 grains/cm2 or more. In the process of producing the steel sheet, inhibitors are not utilized, and the fine crystal grains are achieved by high purification and low temperature final annealing.Type: ApplicationFiled: November 27, 2002Publication date: April 22, 2004Inventors: Yasuyuki Hayakawa, Mitsumasa Kurosawa, Seiji Okabe, Takeshi Imamura
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Publication number: 20040069377Abstract: Process for the production of oriented grain electrical steel strips, in which a silicon steel, comprising at least 30 ppm of S, is directly cast as strip 1.5-4.5 mm thick and cold rolled to a final thickness of between 1.0 and 0.15 mm; characterised by the following staged: Cooling and deformation of the solidified strip to obtain a second phases distribution in which 600 cm−1<Iz<1500 cm−1 and Iy=1.9 Fv/r (cm−1), Fv being the volume fraction of second phases stable at temperatures of less than 800° C., and r being the precipitates mean radius, in cm.; Hot rolling between solidification and coiling of the strip at a temperature of not less than 750° C., with a reduction ratio of between 15 and 60%; Cold rolling with reduction ratio of 60-92%; Cold rolled strip annealing at 750-1100° C., with increase of the nitrogen content of at least 30 ppm with respect to the initial composition at the strip core, in nitriding atmosphere.Type: ApplicationFiled: November 13, 2003Publication date: April 15, 2004Inventors: Stefano Fortunati, Stefano Cicale, Claudia Rocchi, Giuseppe Abbruzzese
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Patent number: 6676771Abstract: Manufacturing a grain-oriented electrical steel sheet, a secondary recrystallization step and a forsterite coating forming step are separated into first batch annealing for developing secondary recrystallization and second batch annealing for forming a forsterite coating, with continuous annealing performed between these two steps of batch annealing, to produce a grain-oriented electrical steel sheet that is superior in both magnetic characteristics and coating characteristics.Type: GrantFiled: July 30, 2002Date of Patent: January 13, 2004Assignee: JFE Steel CorporationInventors: Minoru Takashima, Tetsuo Toge, Yasuyuki Hayakawa, Mitsumasa Kurosawa, Michiro Komatsubara
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Patent number: RE39482Abstract: Grain-oriented magnetic steel sheet made by the method-including hot rolling and final finish annealing, wherein (1) the O content in the steel slab is limited to up to about 30 ppm; (2) for the entire steel sheet having final thickness including an oxide film before final finish annealing, from among impurities, the Al content is limited to up to about 100 wtppm, and the respective contents of B, V, Nb, Se, S, P, and N, to up to about 50 wtppm each; and (3) during final finish annealing, the N content in the steel is, at least in the temperature region of from about 850 to 950° C., limited within the range of from about 6 to 80 wtppm.Type: GrantFiled: October 3, 2002Date of Patent: February 6, 2007Assignee: JFE Steel CorporationInventors: Yasuyuki Hayakawa, Mitsumasa Kurosawa, Michiro Komatsubara