Working Patents (Class 148/111)
  • Publication number: 20010042576
    Abstract: A grain-oriented electrical steel sheet comprising 2.5-4.5% Si by weight and measuring 0.36-1.00 mm in thickness is imparted with a good core loss value for its thickness by controlling its C content, flux density, grain boundary configuration, and deviation degree of crystal orientation in the grains.
    Type: Application
    Filed: February 14, 2001
    Publication date: November 22, 2001
    Inventors: Yasunari Yoshitomi, Hiroaki Masui, Nobuyuki Takahashi
  • Publication number: 20010037841
    Abstract: The present invention provides a non-oriented electrical steel sheet having crystal grains of small diameter and excellent workability before stress relief annealing and having crystal grains of largely grown diameter and excellent iron loss property after stress relief annealing and a method for producing the same, and relates to a low iron loss non-oriented electrical steel sheet excellent in workability, containing, in weight %, 0.010% or less of C, 0.1 to 1.5% of Mn, 0.1 to 4% of Si, 0.1 to 4% of Al, wherein the latter three elements satisfy the formula Si+Mn+Al≦5.0%, and 0.0005 to 0.0200% of Mg, or further containing 0.005% or more of Ca, wherein the total amount of Mg and Ca is 0.0200% or less, or further containing 0.005% or more of REM, wherein the total amount of Mg and REM is 0.0200% or less, or further containing 0.005% or more of Ca and REM, wherein the total amount of Mg, Ca and REM is 0.0200% or less, and containing the remainder consisting of Fe and unavoidable impurities.
    Type: Application
    Filed: April 6, 2001
    Publication date: November 8, 2001
    Inventors: Ken-ichi Murakami, Takashi Morohoshi, Tomoji Kumano, Ryutaro Kawamata, Takeshi Kubota, Masafumi Zeze, Hidekuni Murakami, Shinichi Kanao
  • Patent number: 6309473
    Abstract: Grain-oriented magnetic steel sheet made by the method-including hot rolling and final finish annealing, wherein (1) the O content in the steel slab is limited to up to about 30 ppm; (2) for the entire steel sheet having final thickness including an oxide film before final finish annealing, from among impurities, the Al content is limited to up to about 100 wtppm, and the respective contents of B, V, Nb, Se, S, P, and N, to up to about 50 wtppm each; and (3) during final finish annealing, the N content in the steel is, at least in the temperature region of from about 850 to 950° C., limited within the range of from about 6 to 80 wtppm.
    Type: Grant
    Filed: October 5, 1999
    Date of Patent: October 30, 2001
    Assignee: Kawasaki Steel Corporation
    Inventors: Yasuyuki Hayakawa, Mitsumasa Kurosawa, Michiro Komatsubara
  • Publication number: 20010032684
    Abstract: The present invention relates to a grain-oriented electrical steel sheet excellent in magnetic properties, which are improved by irradiating laser beams onto the positions paired on the both surfaces of the steel sheet and forming fine closure domains, characterized in that the width of the closure domains in the rolling direction is 0.3 mm or less and the deviation in the rolling direction between the positions of the paired closure domains on the both surfaces is equal to or smaller than the width of said closure domains in the rolling direction. Further, the present invention relates to a grain-oriented electrical steel sheet excellent in magnetic properties, characterized in that the steel sheet has the marks of laser irradiation on its surface. Yet further, the present invention relates to a grain-oriented electrical steel sheet excellent in magnetic properties, characterized in that the substrate steel is not exposed at the portions of laser irradiation on the surface of the steel sheet.
    Type: Application
    Filed: April 24, 2001
    Publication date: October 25, 2001
    Inventors: Tatsuhiko Sakai, Naoya Hamada
  • Publication number: 20010030001
    Abstract: Grain-oriented magnetic steel sheet made by the method comprising of hot rolling and final finish annealing, wherein
    Type: Application
    Filed: March 5, 2001
    Publication date: October 18, 2001
    Applicant: Kawasaki Steel Corporation
    Inventors: Yasuyuki Hayakawa, Mitsumasa Kurosawa, Michiro Komatsubara
  • Patent number: 6296719
    Abstract: In the production of high permeability electrical steel, the control of condition of thin slab continuous casting allows to obtain advantageous solidification structures and precipitates. This, in turn, allows to decritize the process for controlling the grain dimensions and to add nitrogen to the cold rolled sheet, such as to immediately form aluminum nitride.
    Type: Grant
    Filed: February 26, 1999
    Date of Patent: October 2, 2001
    Assignee: Acciai Speciali Terni S.p.A.
    Inventors: Stefano Fortunati, Stefano Cicale', Giuseppe Abbruzzese
  • Publication number: 20010020497
    Abstract: Electromagnetic steel sheet having excellent magnetic properties and a texture gratly integrated in the {100}<001> orientation, and an uncomplicated and low cost production method; with about a 15 &mgr;&OHgr;·cm or more specific resistivity, about a 2.0 or more {100}<001> integration degree/{111}<uvw> integration degree and about a 10 &mgr;m to 500 &mgr;m grain diameter; when about 0.1 to 3.5% by weight of Si is present, the {100}<001> integration degree is about 10 or more; when about 0.2 to 1.2% by weight of P is present, the{100}<001> integration degree is about 3 or more; by applying a large reduction ratio to a steel slab in the vicinity of the final stage of hot rolling, with the hot rolling finishing temperature controlled at about 750 to 1150° C., hot rolled steel having a texture highly integrated in the {100}<001> orientation is economically produced.
    Type: Application
    Filed: February 8, 2001
    Publication date: September 13, 2001
    Applicant: Kawasaki Steel Corporation
    Inventors: Osamu Kondo, Akihiro Matsuzaki, Shigeaki Takajo
  • Patent number: 6287392
    Abstract: Grain-oriented silicon steel sheet with Bi as an auxiliary inhibitor and a forsterite coating film having a Cr spinel oxide subscale of FeCr2O4 or FexMn1−xCr2O4 (0.6≦x≦1), made from a steel slab containing 0.005-0.20 wt % of Bi and 0.1-1.0 wt % of Cr.
    Type: Grant
    Filed: September 17, 1999
    Date of Patent: September 11, 2001
    Assignee: Kawasaki Steel Corporation
    Inventors: Hiroaki Toda, Kunihiro Senda, Mitsumasa Kurosawa, Makoto Watanabe, Atsuhito Honda
  • Patent number: 6280534
    Abstract: Method of making a grain oriented electromagnetic steel sheet having excellent magnetic properties, by a series of steps ranging from hot rolling to final finishing annealing for a silicon steel slab containing from about 0.001 to 0.07 wt % bismuth, wherein the average cooling rate for about five seconds measured immediately after the end of hot rolling is controlled within a range of from about 30 to 120° C./second; the value of the ratio PH2O/PH2 of the atmosphere for the soaking step in decarburization annealing is adjusted within a range of from about 0.45 to 0.70; and a treatment is provided for inhibiting decomposition of the surface inhibitor during final finishing annealing.
    Type: Grant
    Filed: May 10, 1999
    Date of Patent: August 28, 2001
    Assignee: Kawasaki Steel Corporation
    Inventors: Kunihiro Senda, Toshito Takamiya, Makoto Watanabe, Mitsumasa Kurosawa
  • Patent number: 6273964
    Abstract: In the production of grain oriented electrical steel sheet, controlling the condition of thin slab continuous casting results in advantageous solidification structures and precipitates. The steel has an initial content of carbon less than 300 ppm and an initial content of acid-soluble aluminum higher than that normally used for said type of steel. During the final processing steps, the annealed sheet is nitrided through a limited amount of nitrogen. This, in turn, renders the process for controlling the grain dimensions much less critical and results in a constant quality product.
    Type: Grant
    Filed: February 26, 1999
    Date of Patent: August 14, 2001
    Assignee: Acciali Speciali Terni S.p.A.
    Inventors: Stefano Fortunati, Stefano Cicale', Giuseppe Abbruzzese
  • Patent number: 6241829
    Abstract: A silicon steel sheet contains 0.01 wt. % or less C, 4 to 10 wt. % Si, 0.5 wt. % or less Mn, 0.01 wt. % or less P, 0.01 wt. % or less S, 0.2 wt. % or less sol. Al, 0.01 wt. % or less N, 0.02 wt. % or less O and the balance being Fe. The silicon steel sheet has grain boundaries and carbides which are precipitated on the grain boundaries. The carbides have an area of 20% or less to an area of the grain boundaries. The steel sheet is cooled at a cooling speed of 5° C./sec. or more in a temperature range of from 300 to 700° C.
    Type: Grant
    Filed: December 9, 1999
    Date of Patent: June 5, 2001
    Assignee: NKK Corporation
    Inventors: Koichiro Fujita, Yasushi Tanaka, Hironori Ninomiya, Tatsuhiko Hiratani, Shoji Kasai
  • Patent number: 6231685
    Abstract: A method of making electrical steel strip characterized by low core loss and high permeability in the rolling direction includes the steps of: hot rolling a slab of an electrical steel composition into a strip, hot band annealing in a temperature range effective to coarsen the grains sufficient to improve magnetic properties in a rolling direction of the strip, cold rolling, batch annealing in a temperature range effective to produce a batch annealed grain size of not greater than 40 &mgr;m and, preferably not greater than 20 &mgr;m , and temper rolling to provide the strip with a transfer surface roughness (Ra) of less than 49 &mgr;in. Electrical steel articles are manufactured from the steel strip upon final annealing. The electrical steel articles have a gain texture including a {110}<001> orientation and improved permeability in the rolling direction.
    Type: Grant
    Filed: June 19, 1998
    Date of Patent: May 15, 2001
    Assignee: LTV Steel Company, Inc.
    Inventor: Jeffrey P. Anderson
  • Patent number: 6228182
    Abstract: A method and a low iron loss grain-oriented electromagnetic steel sheet are disclosed. The method comprises the steps of: hot-rolling a grain-oriented electromagnetic steel sheet; cold-rolling the hot-rolled steel sheet once or twice intervened by intermediate annealing, so as to achieve the sheet thickness of a final product; annealing the cold-rolled steel sheet for decarburization; finish-annealing the decarburized steel sheet; forming linear grooves on the steel sheet substantially perpendicularly to the rolling direction, after the final cold-rolling step and before the finish-annealing step, by, for example, electrolytic etching or acid dipping; and filling the linear grooves with an element selected from the group consisting of Sn, B and Sb, or an oxide or a sulfate of an element selected therefrom.
    Type: Grant
    Filed: December 28, 1994
    Date of Patent: May 8, 2001
    Assignee: Kawasaki Steel Corporation
    Inventors: Koh Nakano, Atsuhito Honda, Keiji Sato
  • Patent number: 6217673
    Abstract: Batch annealed, semi-processed and fully processed motor lamination steels are made by processes which subject a slab having a particular ultra low carbon composition (less than 0.01%) to steps which include hot rolling a slab into a strip and coiling the strip. This is followed by the sequential steps of preferably annealing the strip in coil form, cold rolling the strip and batch annealing the strip in coil form. The strip is flattened by a temper rolling or leveling process. The flattening step reduces the thickness of the strip by an amount ranging from greater than 0% to not greater than 1.0% to provide the strip with a permeability when stress relief annealed of at least 2500 Gauss/Oersted.
    Type: Grant
    Filed: September 29, 1997
    Date of Patent: April 17, 2001
    Assignee: LTV Steel Company, Inc.
    Inventors: John F. Butler, Barry A. Lauer, Gerald F. Beatty, Ann M. R. Larson, Richard J. Blotzer
  • Patent number: 6159309
    Abstract: The present invention provides a grain-oriented electrical steel sheet having magnetic properties equal to, or higher than, those of conventional steel sheets can be produced economically with high productivity, and a method for producing such a steel sheet. The producing method comprises the steps of using, as a starting material, a coil obtained by heating a slab having a composition comprising, in terms of percent by weight, 0.02 to 0.15% of C, 2.5 to 4.0% of Si, 0.02 to 0.20% of Mn, 0.015 to 0.065% of Sol. Al, 0.0030 to 0.0150% of N, 0.005 to 0.040% as the sum of at least one of S and Se and the balance substantially consisting of Fe and hot rolling the slab to a coil, or a coil directly cast from a molten steel having the same components as the slab, conducting hot rolled sheet annealing at 900 to 1,100.degree. C.
    Type: Grant
    Filed: November 2, 1998
    Date of Patent: December 12, 2000
    Assignee: Nippon Steel Corporation
    Inventors: Yousuke Kurosaki, Norito Abe, Nobuo Tachibana, Kentaro Chikuma, Kiyokazu Ichimura, Sadanobu Hirokami, Masayuki Yamashita
  • Patent number: 6159305
    Abstract: An induction motor rotor comprises a rotor shaft (12), a rotor core (14), which may be solid (114) or may include a plurality of rotor laminations (13), having rotor bar slots (15), a plurality of rotor bars (16) extending through the rotor bar slots, and two rotor end rings (18) brazed to the rotor bars and extending to the rotor shaft, the rotor bars and rotor end rings pre-stressing the rotor core.
    Type: Grant
    Filed: July 14, 1998
    Date of Patent: December 12, 2000
    Assignee: General Electric Company
    Inventors: Gerald Burt Kliman, Raymond Alan White, Wen Liang Soong, Roger Neal Johnson, Joseph Eugene Miller, John Raymond Hughes
  • Patent number: 6153019
    Abstract: A process for producing a grain-oriented magnetic steel sheet in which a slab, made from a steel containing (in mass %) more than 0.005 to 0.10% C, 2.5 to 4.5% Si, 0.03 to 0.15% Mn, more than 0.01 to 0.05% S, 0.01 to 0.035% Al, 0.0045 to 0.012% N, 0.02 to 0.3% Cu, the remainder being Fe, including unavoidable impurities, is heated through and hot rolled to a final thickness between 1.5 and 7.0 mm. The hot strip is annealed and immediately cooled and cold rolled in one or several cold-rolling steps to the final thickness of the cold strip. The cold strip is subjected to a recrystallizing annealing process in a humid atmosphere containing hydrogen and nitrogen, with synchronous decarburization. A non-stick layer, essentially containing MgO, is applied to the surface of the decarburized cold strip which is then subjected to final annealing. The cold strip is then rolled into coils.
    Type: Grant
    Filed: October 26, 1998
    Date of Patent: November 28, 2000
    Assignee: Thyssen Stahl AG
    Inventors: Manfred Espenhahn, Andreas Bottcher, Klaus Gunther
  • Patent number: 6139650
    Abstract: A non-oriented electromagnetic steel sheet contains 0.005 wt. % or less C, 0.2 wt. % or less P, 0.005 wt. % or less N, 4.5 wt. % or less Si, 0.05 to 1.5 wt. % Mn, 1.5 wt. % or less Al and 0.001 wt. % or less S, at least one element selected from the group of 0.001 to 0.05 wt. % Sb, 0.002 to 0.1 wt. % Sn, 0.0005 to 0.01 wt. % Se and 0.0005 to 0.01 wt. % Te; and the balance being Fe and inevitable impurities. The non-oriented electromagnetic steel sheet is produced by the steps of: hot-rolling a slab to form a hot-rolled steel sheet, cold-rolling the hot-rolled steel sheet to form a cold-rolled steel sheet; and finish annealing the cold-rolled steel sheet.
    Type: Grant
    Filed: March 12, 1998
    Date of Patent: October 31, 2000
    Assignee: NKK Corporation
    Inventors: Yoshihiko Oda, Nobuo Yamagami, Akira Hiura, Yasushi Tanaka, Noritaka Takahashi, Hideki Matsuoka, Atsushi Chino, Katsumi Yamada, Shunji Iizuka
  • Patent number: 6129992
    Abstract: Provided are a high strength cold rolled steel sheet and a high strength plated steel sheet possessing improved geomagnetic shielding properties, that is, having a high relative permeability in a d.c. magnetic field around 0.3 Oe, a process for producing the same, and an explosion-proof band or an outer magnetic shielding material, for television cathode-ray tubes, using the steel sheet. An ultra low carbon steel, which has a carbon content of not more than 0.0060% and has been subjected to solid solution strengthening utilizing silicon and magnesium without relying upon precipitation strengthening, is deoxidized with silicon so that aluminum is substantially absent in the steel. Alternatively, when the ultra low carbon steel is deoxidized with aluminum, boron is added to inhibit the precipitation of AlN. Next, the deoxidized steel is finish rolled at 750 to 980.degree. C., cold rolled with a reduction ratio of 60 to 90%, and then annealed in the temperature range of 750.degree. C. to the Ac.sub.
    Type: Grant
    Filed: July 6, 1999
    Date of Patent: October 10, 2000
    Assignees: Nippon Steel Corporation, Sony Corporation
    Inventors: Yasuharu Sakuma, Satoru Tanaka, Kazuo Koyama, Yujiro Miyauchi, Takeshi Kubota, Atsushi Itami, Hiroaki Kato, Chohachi Sato, Teruo Takeuchi
  • Patent number: 6110298
    Abstract: Grain-oriented electrical steel sheet having excellent magnetic characteristics in which shearing angles of grain directions [001] of secondary recrystallized grains from a rolling direction have an average value of about 4.degree. or less, wherein the area % of secondary recrystallized grains having a length of about 60 mm or more in the rolling-orthogonal direction is about 85% or more; with respect to recrystallized micro grains, the area % of crystal grains having a grain diameter of 2 to 20 mm is about 0.2% or more and about 10% or less; and the average value of angles formed with the steel sheet surface by grain directions [001] is about 1.5.degree. or more and about 5.0.degree. or less; in a grain-oriented electrical steel sheet of a high magnetic flux density (B.sub.8 .gtoreq.1.96 T) low iron loss is achieved without providing magnetic domain-refining treatment, very low iron loss value by forming grooves on the steel sheet surface, smoothening the steel sheet surface or a combination thereof.
    Type: Grant
    Filed: July 16, 1998
    Date of Patent: August 29, 2000
    Assignee: Kawasaki Steel Corporation
    Inventors: Kunihiro Senda, Toshito Takamiya, Michiro Komatsubara
  • Patent number: 6068708
    Abstract: A method of making electrical steel strip characterized by low core loss, high permeability and good cleanliness includes producing a slab having a composition consisting essentially of (% by weight): up to 0.02 C, 0.20-1.35 Si, 0.10-0.45 Al, 0.10-1.0 Mn, up to 0.015 S, up to 0.006 N, up to 0.07 Sb, up to 0.12 Sn, and the balance being substantially iron. The slab is hot rolled into a strip with a finishing temperature in the ferrite region. The strip is coiled at a temperature less than 1200.degree. F. and, preferably, less than 1000.degree. F. The strip which has not been subjected to an annealing operation after the coiling is subjected to cold rolling. The strip is then batch annealed and temper rolled.
    Type: Grant
    Filed: March 10, 1998
    Date of Patent: May 30, 2000
    Assignee: LTV Steel Company, Inc.
    Inventors: Barry A. Lauer, Gerald F. Beatty, Jeffrey P. Anderson
  • Patent number: 6007642
    Abstract: The present invention is directed to a low loss motor lamination steel having a relatively low alloy content, which has a composition such that the motor lamination steel is fully ferritic at all solid temperatures. The steel preferably includes 1.20-1.40 wt. % silicon, 0.25-0.40 wt. % aluminum, 0.15-0.30 wt. % manganese and not more than 0.005 wt. % carbon. The processes for producing the fully ferritic low loss motor lamination steel include a hot band anneal followed by cold rolling, and a two-stage or double cold roll process.
    Type: Grant
    Filed: December 8, 1997
    Date of Patent: December 28, 1999
    Assignee: National Steel Corporation
    Inventor: Eric E. Gallo
  • Patent number: 5961744
    Abstract: Grain oriented silicon steel sheet on which is formed an insulating coating having a thickness that is not less than 2.5 .mu.m that imparts tension to the steel sheet which does not have an inorganic mineral layer formed during a final annealing step (glass film) and a method of forming on grain oriented silicon steel sheet an insulating coating that is not less than 2.5 .mu.m thick and which imparts tension to the steel sheet which does not have the inorganic mineral layer (glass film) that forms during finish annealing, and a method of forming a tensioning insulating coating on grain oriented silicon steel sheet which has been finish annealed and does not have an inorganic mineral surface layer (glass film), after first forming a layer of SiO.sub.2 not less than 0.001 .mu.m thick on the oriented silicon steel sheet.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: October 5, 1999
    Assignee: Nippon Steel Corporation
    Inventors: Shuichi Yamazaki, Hiroyasu Fujii, Takeo Nagashima, Yoshiyuki Ushigami, Osamu Tanaka, Katsurou Kuroki, Hiroaki Masui
  • Patent number: 5951788
    Abstract: A stainless steel alloy useful as a construction material in superconducting magnetic components, said alloy containing in weight percent 0.05-0.25% C, 0.1-1.5% Si, 3.5-7.5% Mn, 17-21% Cr, 6-10% Ni, 0.10-0.50% N, the remainder being Fe and normal impurities.
    Type: Grant
    Filed: August 1, 1997
    Date of Patent: September 14, 1999
    Assignee: Sandvik AB
    Inventor: H.ang.kan Holmberg
  • Patent number: 5942051
    Abstract: In a non-oriented electromagnetic steel sheet including about 0.01 wt % or less of C, about 1.0 wt % or less of Si, Mn in a range of about 0.1 wt % to 1.5 wt %, Al in a range of about 0.2 wt % to 1.5 wt %; the steel sheet having a critical amount of about 2 to 80 ppm rare earth metal, and the quantities of Ti and Zr in the steel sheet being limited to about 15 ppm or less of Ti, and about 80 ppm or less of Zr. The sheet exhibits excellent magnetic characteristics, such as iron loss, even when punched and laminated sheets are stress relief annealed at a low temperature for a short period of time.
    Type: Grant
    Filed: September 26, 1997
    Date of Patent: August 24, 1999
    Assignee: Kawasaki Steel Corporation
    Inventors: Minoru Takashima, Keiji Sato, Takashi Obara
  • Patent number: 5913987
    Abstract: A method for manufacturing a soft magnetic steel sheet is disclosed. The silicon steel sheet is made to undergo a finish treatment so that it can be put to the practical use. The finish treatment method for an Fe-Si silicon steel sheet manufactured by a direct casting method by directly contacting a molten pool to a cooling roll according to the present invention includes the step of pickling the manufactured Fe-Si silicon steel sheet, and carrying out a cold rolling. Then the silicon steel sheet thus cold-rolled is heat-treated at a temperature above 0.5 Tm (Tm: melting temperature of the steel sheet).
    Type: Grant
    Filed: December 11, 1997
    Date of Patent: June 22, 1999
    Assignees: Pohang Iron & Steel Co., Ltd., Research Institute of Industrial Science & Technology
    Inventors: Jin Kyung Sung, Moon Chul Kim, Byoung Mu Do
  • Patent number: 5888314
    Abstract: In a process for the preparation of oriented electrical steel sheet having a high magnetic flux density a primary recrystallization annealed steel sheet is nitrided for a short period of time in a temperature range of 800.degree. C. or less whereby growth of crystal grains does not substantially occur. The nitrided sheet is held at a temperature range of 700.degree. C. to 800.degree. C. for at least four hours during temperature raising to final annealing temperature whereby nitride formed by the nitriding dissolves and re-precipitates allowing the nitride to transform to a thermally stable nitride containing aluminium.
    Type: Grant
    Filed: January 21, 1994
    Date of Patent: March 30, 1999
    Assignee: Nippon Steel Corporation
    Inventors: Yoshiyuki Ushigami, Fumio Kurosawa, Hajime Komatsu
  • Patent number: 5885371
    Abstract: A method of producing a grain-oriented magnetic steel sheet exhibiting a very low core loss and high magnetic flux density uses a slab of silicon steel containing Al, B, N, and S and/or Se. The method employs hot rolling conducted such that the rolling reduction falls within the range of from about 85 to 99%, and the hot-rolling finish temperature falls within the range of from 950.degree. to 1150.degree. C. and is based on the contents of Si, Al and B. The hot-rolled steel sheet is rapidly cooled at a cooling rate of about 20.degree. C./s and is coiled at a temperature of about 670.degree. C. or lower. Hot-rolled sheet annealing or intermediate annealing is executed by heating the hot-rolled steel sheet up to about 800.degree. C. at a heating rate of from 5.degree. to 25.degree. C./s and holding at a temperature of from about 800.degree. to 1125.degree. C. for a period not longer than about 150 seconds.
    Type: Grant
    Filed: October 9, 1997
    Date of Patent: March 23, 1999
    Assignee: Kawasaki Steel Corporation
    Inventors: Michiro Komatsubara, Toshito Takamiya, Kunihiro Senda, Mineo Muraki, Chizuko Goto, Mitsumasa Kurosawa, Kazuaki Tamura
  • Patent number: 5876520
    Abstract: The present invention relates to a semiprocessed nonoriented magnetic steel sheet which is used in iron cores of motors and transformers, finished to a final product by rolling having a reduction rate of 2 to 18% after final annealing by a manufacturer, and assures desired magnetic characteristics due to coarsening of crystal grains during strain-relief annealing after processing by a user. The excellent magnetic characteristics can be achieved by increasing lubrication during second cold rolling so as to satisfy the equation: e.sub.c .ltoreq.e.sub.s .ltoreq.1.18e.sub.c wherein e.sub.s represents a strain value at the surface layer of the steel sheet and e.sub.c represents a strain value at the central layer.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: March 2, 1999
    Assignee: Kawasaki Steel Corporation
    Inventors: Minoru Takashima, Akio Fujita, Keiji Sato, Masaki Kawano
  • Patent number: 5855694
    Abstract: Production of grain-oriented silicon steel sheet, in which the heating temperature of slabs is as low as that in common steels and good magnetic properties are maintained, without applying a nitriding process. The contents of Al, Se and S substantially satisfy formulae (1) and (2), and both or either of formulae (3) and (4):?Al (wt %)!+(5/9){?Se (wt %)!+2.47?S(wt %)!}.ltoreq.0.027 (1)?Se (wt %)!+2.47?S (wt %)!.ltoreq.0.025 (2)0.016.ltoreq.?Al (wt %)!+(5/9){?Se (wt %)!+2.47 ?S (wt %)!}(3)0.010.ltoreq.?Al (wt %)! (4)Annealing of the hot rolling sheet is applied at a temperature of about 800.degree. C. or more, and about 1000.degree. C. or below; preferably, cold rolling is applied at about 100.degree. C. or more, using a tandem mill.
    Type: Grant
    Filed: August 6, 1997
    Date of Patent: January 5, 1999
    Assignee: Kawasaki Steel Corporation
    Inventors: Tetsuo Toge, Atsuhito Honda, Mineo Muraki, Kenichi Sadahiro, Minoru Takashima
  • Patent number: 5853499
    Abstract: Grain-oriented electrical steel sheet having a very low iron loss with controlled area ratio of fine grains, average grain size of coarse grains, obliquity of the grain boundary line of coarse grains, permeability under 1.0 T, and film tension.
    Type: Grant
    Filed: August 28, 1997
    Date of Patent: December 29, 1998
    Assignee: Kawasaki Steel Corporation
    Inventors: Michiro Komatsubara, Kunihiro Senda, Takafumi Suzuki, Hiroaki Toda, Hiroi Yamaguchi
  • Patent number: 5833768
    Abstract: A method of producing a grain-oriented electrical steel sheet with a very low core loss comprises the steps of obtaining a rolled strip of final product thickness using as a starting material molten steel consisting of not more than 0.10 wt % C, 2.5-7.0 wt % Si, ordinary inhibitor components and the balance of iron and unavoidable impurities, heating the strip to a temperature range of not less than 700.degree. C. at a heating rate of not less than 80.degree. C./s and within 0.1 second after the maximum temperature has been reached cooling the strip at a cooling rate of not less than 50.degree. C./s, and subjecting the strip to decarburization annealing and final finish annealing.
    Type: Grant
    Filed: March 8, 1996
    Date of Patent: November 10, 1998
    Assignee: Nippon Steel Corporation
    Inventors: Kenji Kosuge, Mikio Itoh, Shinji Ueno, Haruo Hukazawa, Takashi Yoshimura
  • Patent number: 5803988
    Abstract: The annealing conditions of a cold rolled steel sheet are properly controlled so as to form a dense surface oxide layer, thereby improving the adherence strength of the insulating layer on non-oriented electrical steel sheet. The method includes the following steps. A steel slab is prepared which is composed of in weight %: 0.05% or less of C, 3.5% or less of Si, 1.5% or less of Mn, 0.15% or less of P, 0.015% or less of S, 1.0% or less of Al, one or more elements selected from a group consisting of 0.03-0.30% of Sn, 0.03-0.3% of Sb, 0.03-1.0% of Ni and 0.03-0.50% of Cu, the balance of Fe and unavoidable impurities. The steel slab is reheated, hot rolled, pickled after annealing or without annealing and cold-rolled. A low temperature annealing is carried out on the cold rolled steel sheet at a temperature of 750.degree.-850.degree. C. for 30 seconds to 5 minutes under a humid atmosphere having a dew point of 25.degree.-65.degree. C.
    Type: Grant
    Filed: August 18, 1997
    Date of Patent: September 8, 1998
    Assignee: Pohang Iron & Steel Co., Ltd.
    Inventors: Byung Keun Bae, Sam Kyu Chang, Jong Soo Woo, Wun Gul Lee
  • Patent number: 5803989
    Abstract: A process for producing a non-oriented electrical steel sheet, comprising the steps of: hot rolling a non-oriented electrical steel sheet of a steel comprising at least one element selected from the group consisting of Si, Mn, and Al in respective amounts, in terms of by weight, satisfying the requirements 0.10%.ltoreq.Si.ltoreq.2.50%, 0.10%.ltoreq.Al.ltoreq.1.00%, 0.10%.ltoreq.Mn.ltoreq.2.00%, and the total amount of Si and Al being (Si+2Al).ltoreq.2.50%, with the balance consisting of Fe and unavoidable impurities, to prepare a hot rolled sheet; either subjecting the hot rolled sheet to single pass rolling to a final sheet thickness followed by finish annealing, or cold rolling the hot rolled sheet and then finish annealing the cold rolled sheet followed by skin pass rolling with a reduction ratio of 2 to 20% to a final sheet thickness, wherein the finishing in the step of finish hot rolling is performed in a temperature region of (Ar.sub.3 +50).degree. C.
    Type: Grant
    Filed: December 19, 1996
    Date of Patent: September 8, 1998
    Assignee: Nippon Steel Corporation
    Inventors: Ryutaro Kawamata, Takeshi Kubota, Tomoji Kumano
  • Patent number: 5800633
    Abstract: A method for producing a grain oriented electromagnetic steel sheet exhibiting excellent magnetic flux density and excellent iron loss, including preparing a slab from steel capable of being formed into an oriented electromagnetic steel sheet, the steel comprising about 2.5 to 4.0 weight percent of Si and about 0.005 to 0.06 weight percent of Al; hot rolling the slab to a hot-rolled plate; cold rolling the hot-rolled plate up to two times, including an intermediate annealing between cold rollings, to form a cold-rolled steel sheet; decarburization and primary recrystallization annealing the steel sheet, the decarburization and primary recrystallization annealing including a first half and a second half, the decarburization and primary recrystallization annealing comprising rapidly heating the cold-rolled steel sheet at a rate of about 10.degree. C./min or more from about 450.degree. C. to a predetermined constant temperature between about 800.degree. to 880.degree. C.
    Type: Grant
    Filed: May 16, 1997
    Date of Patent: September 1, 1998
    Assignee: Kawasaki Steel Corporation
    Inventor: Yukio Inokuti
  • Patent number: 5782998
    Abstract: In order to provide a very low iron loss, it is necessary to render the surface of a steel sheet smooth (specular). In the present invention, this is effected in a finish annealing furnace to simultaneously attain a high magnetic flux density and a specular surface. Specifically, after the completion of decarburization annealing, a steel material is pickled to remove an oxide layer present on the surface of the steel sheet, coated with an annealing separator comprising a substance nonreactive or less reactive with SiO.sub.2 and then subjected to finish annealing to provide a grain oriented electrical steel sheet having a specular surface. Magnetic domain division and tension coating of the steel sheet can provide a low iron loss value. In the finish annealing, since no time is required for dehydration, the annealing time can be shortened.
    Type: Grant
    Filed: January 7, 1994
    Date of Patent: July 21, 1998
    Assignee: Nippon Steel Corporation
    Inventors: Yoshiyuki Ushigami, Takeo Nagashima, Shuichi Yamazaki, Hiroyasu Fujii, Yozo Suga, Tadashi Nakayama, Katsuro Kuroki, Yosuke Kurosaki
  • Patent number: 5759293
    Abstract: A decarburization-annealed steel strip as an intermediate material for grain-oriented electrical steel strip having good secondary recrystallization and excellent electrical properties is provided by causing a steel strip to possess a micro-structure in which the primary recrystallization grains have an average diameter d of not less than 15 .mu.m and a coefficient of diameter deviation .sigma.* of not more than 0.6.
    Type: Grant
    Filed: November 6, 1995
    Date of Patent: June 2, 1998
    Assignee: Nippon Steel Corporation
    Inventors: Nobuyuki Takahashi, Yasunari Yoshitomi, Tadashi Nakayama, Yoshiyuki Ushigami
  • Patent number: 5759294
    Abstract: A process for the production of grain oriented magnetic steel sheets having improved remagnetization losses consisting essentially of (in % by weight) more than 0.005% to 0.10% C, 2.5 to 6.5% Si, 0.03 to 0.15% Mn, 0.010 to 0.050% S, 0.010 to 0.035% Al, 0.0045 to 0.0120% N, and 0.020 to 0.300% Cu, and up to 0.15% Sn, the balance being iron and inevitable impurities. The process includes continuous casting or strip casting slabs with the above composition.
    Type: Grant
    Filed: October 23, 1996
    Date of Patent: June 2, 1998
    Assignee: Thyssen Stahl AG
    Inventors: Fritz Bolling, Andreas Bottcher, Manfred Espenhahn, Christof Holzapfel
  • Patent number: 5711825
    Abstract: A process for the production of grain oriented magnetic steel sheets comprises through-heating slabs containing more than 0.005% C, 2.5 to 6.5% Si, 0.03 to 0.15% Mn, 0.010 to 0.050% S, 0.010 to 0.035% Al, 0.0045 to 0.0120% N, and 0.020 to 0.300% Cu, the balance being iron and residual impurities, to a temperature which is lower than the solubility temperature T.sub.1 of magnesium sulfide and higher than the solubility temperature T.sub.2 of copper sulfide, T.sub.1 and T.sub.2 being dependent on the silicon content. The through-heated slabs are then hot roughed, followed by hot finish rolling at an initial temperature of at least 960.degree. C. and a final rolling temperature of 880.degree. C. to 1,000.degree. C., to produce a hot rolled strip having a thickness in the range of 1.5 to 7 mm. During this last step, at least 60% of the total nitrogen content precipitates in the form of coarse AlN particles. Thereafter, the hot rolled strips are annealed at temperature of 880.degree. C. to 1,150.degree. C.
    Type: Grant
    Filed: April 4, 1994
    Date of Patent: January 27, 1998
    Assignee: Thyssen Stahl AG
    Inventors: Fritz Bolling, Andres Bottcher, Manfred Espenhahn, Christof Holzapfel
  • Patent number: 5702539
    Abstract: The present invention provides a method of producing grain oriented electrical steel having excellent mechanical and magnetic properties. A hot processed strip having a thickness of 1.5-4.0 mm thickness a composition consisting essentially of 2.5-4.5% silicon, 0.1-1.2% chromium, less than 0.050% carbon, less than 0.005% aluminum, up to 0.1% sulfur, up to 0.14% selenium, 0.01-1% manganese and balance being essentially iron and residual elements, all percentages by weight. The strip has a volume resistivity of at least 45 .mu..OMEGA.-cm, at least 0.010% carbon so that an austenite volume fraction (.gamma..sub.1150.degree. C.) of at least 2.5% is present in the hot processed strip and each surface of the strip has an isomorphic layer having a thickness of at least 10% of the total thickness of the hot processed strip. The strip is cold reduced to an intermediate thickness, annealed, cold reduced to a final thickness and decarburized to less than 0.003% carbon.
    Type: Grant
    Filed: February 28, 1997
    Date of Patent: December 30, 1997
    Assignee: Armco Inc.
    Inventors: Jerry W. Schoen, Norris A. Dahlstrom, Christopher G. Klapheke
  • Patent number: 5679178
    Abstract: A method of manufacturing a grain-oriented silicon steel sheet exhibiting excellent magnetic characteristics over the entire length of a coil thereof, which involves hot rolling a silicon steel slab containing aluminum and suitable for making a grain-oriented silicon steel sheet; annealing the steel sheet, as the need arises; cold rolling the steel sheet to a final thickness, the cold rolling including an intermediate annealing process; performing a heat effect treatment before, during or after the cold rolling; performing a decarburizing annealing; and performing a final annealing process. The method inhibits oxidation of the surfaces of the steel sheet during the cold rolling.
    Type: Grant
    Filed: July 20, 1995
    Date of Patent: October 21, 1997
    Assignee: Kawasaki Steel Corporation
    Inventors: Michiro Komatsubara, Kazuaki Tamura, Masako Hisata, Masaki Kawano
  • Patent number: 5667598
    Abstract: Method for producing a grain oriented silicon steel sheet comprises heating a silicon steel slab containing about:C : 0.01 to 0.10 wt %, Si: 2.5 to 4.5 wt %,Mn: 0.02 to 0.12 wt %, Al: 0.005 to 0.10 wt %,N : 0.004 to 0,015 wt %,to about 1280.degree. C. or higher and then subjecting it to hot rolling to prepare a hot-rolled steel sheet, subjecting the steel sheet to hot-rolled sheet annealing according to necessity, then subjecting it to one cold-rolling step or two or more cold-rolling steps with interposed intermediate annealing steps to prepare a cold-rolled steel sheet, and subjecting the cold-rolled steel sheet to decarburization annealing and finishing annealing, wherein the finishing rolling terminating temperature of the hot-rolling step is controlled to a range of about 900.degree. to 1100.degree. C., and the rolled sheet is processed so that the steel sheet temperature T(t) (.degree. C.
    Type: Grant
    Filed: March 27, 1996
    Date of Patent: September 16, 1997
    Assignee: Kawasaki Steel Corporation
    Inventors: Yoshihiro Ozaki, Akio Fujita, Mineo Muraki
  • Patent number: 5665178
    Abstract: A method of manufacturing a grain-oriented silicon steel sheet having excellent and stable magnetic characteristics which includes the steps of subjecting a silicon steel slab to hot rolling to form a hot-rolled sheet, cold rolling the hot-rolled sheet at least once with intermediate annealings between successive cold rollings to form a cold-roiled sheet, and thereafter primary recrystallization annealing the cold-rolled sheet to form a primary recrystallized sheet. The primary recrystallized sheet is then final finish annealed, which includes a secondary recrystallization annealing and a purifying annealing during which the steel slab is coated with an annealing separator. The coercive force of the primary recrystallized steel sheet is controlled to a predetermined range before the start of secondary recrystallization.
    Type: Grant
    Filed: February 5, 1996
    Date of Patent: September 9, 1997
    Assignee: Kawasaki Steel Corporation
    Inventors: Michiro Komatsubara, Masayoshi Ishida, Kunihiro Senda
  • Patent number: 5653821
    Abstract: A method for manufacturing an oriented electrical steel sheet includes the step of preparing a steel slab composed of in weight %: 0.035-0.050% of C, 2.9-3.3% of Si, less than 0.016% of P, 0.011-0.017% of soluble Al, 0.0080-0.012% of N, less than 0.007% of S, 0.06-0.18% of Ni+Cr, less than 0.32% of Mn with an Mn/S ratio of 20 or more, less than 0.6% of Cu with a Cu/Mn ratio of 1.5 or more, and balance of Fe and other inevitable impurities. The steel slab is heated at a temperature of 1250.degree.-1320.degree. C., and then hot rolled. The hot rolled slab is then cold rolled in two stages to a final sheet thickness, with a decarburization annealing being carried out at an intermediate thickness. The decarburized cold rolled sheet is coated with an annealing separator containing MgO as the main ingredient and then a finish annealing treatment is conducted, thereby obtaining a magnetically superior oriented electrical steel sheet.
    Type: Grant
    Filed: July 7, 1995
    Date of Patent: August 5, 1997
    Assignees: Pohang Iron & Steel Co., Ltd., Research Institute of Industrial Science & Technology
    Inventors: Gyu Seung Choi, Chung San Lee, Jong Soo Woo, Byung Deug Hong
  • Patent number: 5643370
    Abstract: The present invention relates to the production of a grain oriented electrical steel composition having a volume resistivity of at least 50 micro-ohm-cm. The melt composition of the steel consists essentially of, in weight %, about 0.08% max carbon, about 0.015 to about 0.05% aluminum, 2.25 to 7% silicon, greater than about 0.5% manganese.sub.eq, about 0.001 to about 0.011% nitrogen, about 0.01% max sulfur, about 3% max chromium, about 1% max copper, about 2% max nickel and balance essentially iron. High levels of silicon are balanced with a manganese equivalent relationship which permits lower levels of carbon while still providing the desired levels of austenite during rolling and annealing. The processing also includes the addition of excess nitrogen to the steel prior to secondary grain growth which is subsequently removed during a purification treatment.
    Type: Grant
    Filed: May 16, 1995
    Date of Patent: July 1, 1997
    Assignee: Armco Inc.
    Inventor: Glenn Stuart Huppi
  • Patent number: 5639315
    Abstract: A process is disclosed for the production of a non-oriented electromagnetic steel strip having its magnetic characteristics uniformly retained in the product coil. The process involves by full- or semi-processing, hot rolling a steel slab containing not more than about 0.03% by weight of C, not more than about 3% by weight of Si and not more than about 2% by weight of Al such that the equation [Si wt %]+3 [Al wt %]-6 [C wt %] is in the range of about 0 to 2; and cold rolling the hot rolled steel strip in a known manner, followed optionally by finish annealing and also optionally by skin-pass rolling. The coil is finish rolled at a peripheral roll speed between about 500 to 1,500 mpm at the final stand. The peripheral roll speed at the final finish rolling stand is also controlled within a range of no more than about 300 mpm. Hot rolling is completed at a temperature Tf (.degree. C.) in an alpha-phase temperature zone and not less than about {750+30 ([Si wt %]+3 [Al wt %]-6 [C wt %])}.
    Type: Grant
    Filed: December 15, 1995
    Date of Patent: June 17, 1997
    Assignee: Kawasaki Steel Corporation
    Inventors: Minoru Takashima, Keiji Sato, Takashi Obara
  • Patent number: 5637157
    Abstract: This invention is directed to a method of producing a non-oriented magnetic steel sheet involving a series of processes including performing hot rolling process on a steel slab containing no more than about 0.01 wt % C, no more than about 4.0 wt % Si, no more than about 1.5 wt % Mn, no more than about 1.5 wt % Al, no more than about 0.2 wt % P, and no more than about 0.01 wt % S, performing thereto at least one cold rolling process including an optional intermediate annealing process, and then performing a finishing annealing process. The hot rolling process further includes a step which reduces thermal irregularity formed during slab heating; this step involves maintaining a sheet bar, obtained by rough-rolling of the steel slab, at a temperature ranging from about 850.degree. to 150.degree. C. The hot rolling process also includes a step which promotes the growth of fine precipitated particles by applying strain to the sheet bar.
    Type: Grant
    Filed: September 26, 1995
    Date of Patent: June 10, 1997
    Assignee: Kawasaki Steel Corporation
    Inventors: Minoru Takashima, Atsushi Ogino, Keiji Sato
  • Patent number: 5620533
    Abstract: A method for producing a grain-oriented silicon steel sheet in the coil shape having high magnetic induction and including AlN and MnSe as principal inhibitors is disclosed. In a series of processes for producing a grain-oriented silicon steel sheet, the oxide content on the steel sheet surface is controlled within a range of about 0.02 to 0.10 g/m.sup.2 before the temperature elevation phase of a decarburization annealing process, and the ratio of the steam partial pressure to the hydrogen partial pressure is controlled within a range of about 0.2 to 0.65 at a steel sheet surface temperature ranging from about 500.degree. to 750.degree. C. during the temperature elevation phase in a decarburization annealing process. The method promotes stable secondary recrystallized grain formation even in different coils or at different places in the same coil, such that fluctuation of magnetic properties is depressed.
    Type: Grant
    Filed: September 26, 1995
    Date of Patent: April 15, 1997
    Assignee: Kawasaki Steel Corporation
    Inventors: Keisuke Kotani, Mitsumasa Kurosawa, Masaki Kawano, Hirotake Ishitobi, Masayuki Sakaguchi, Takafumi Suzuki, Ujihiro Nishiike
  • Patent number: RE35967
    Abstract: Batch annealed, semi-processed and fully processed motor lamination steels are made by processes which subject a slab having an ultra low carbon composition (less than 0.01%) to at least the following steps: hot rolling with an austenite finishing temperature, coiling at a temperature ranging from 1300.degree.-1450.degree. F., and light temper rolling (less than 1.0% reduction) or leveling; reheating at a temperature less than 2300.degree. F., hot rolling with a ferrite finishing temperature, coiling at a temperature less than 1200.degree. F., and light temper rolling or leveling; or hot rolling with a ferrite finishing temperature, coiling at a temperature ranging from 1100.degree.-1350.degree. F. without a subsequent hot band anneal, and light temper rolling or leveling.
    Type: Grant
    Filed: July 21, 1997
    Date of Patent: November 24, 1998
    Assignee: LTV Steel Company, Inc.
    Inventors: Barry A. Lauer, Gerald F. Beatty, Ann M. R. Larson, Richard J. Blotzer
  • Patent number: RE36423
    Abstract: A method of manufacturing a grain-oriented silicon steel sheet exhibiting excellent magnetic characteristics over the entire length of a coil thereof, which involves hot rolling a silicon steel slab containing aluminum and suitable for making a grain-oriented silicon steel sheet; annealing the steel sheet, as the need arises; cold rolling the steel sheet to a final thickness, the cold rolling including an intermediate annealing process; performing a heat effect treatment before, during or after the cold rolling; performing a decarburizing annealing; and performing a final annealing process. The method inhibits oxidation of the surfaces of the steel sheet during the cold rolling.
    Type: Grant
    Filed: January 26, 1998
    Date of Patent: December 7, 1999
    Assignee: Kawasaki Steel Corporation
    Inventors: Michiro Komatsubara, Kazuaki Tamura, Masako Hisata, Masaki Kawano