With Post-nitriding Heat Or Quenching Patents (Class 148/232)
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Patent number: 11644795Abstract: A watch component includes an austenized ferritic stainless steel including a base including a ferrite phase, a surface layer formed on a surface of the base, the surface layer including an austenized phase, and a mixed layer formed between the base and the surface layer, the mixed layer being a layer in which the ferrite phase and the austenized phase are mixed. In a cross section taken along a depth direction from the surface, a thickness of the mixed layer is 45% or less of a thickness of the surface layer.Type: GrantFiled: September 4, 2020Date of Patent: May 9, 2023Inventor: Koki Takasawa
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Patent number: 10748687Abstract: A method of forming a component having a variation in saturation magnetization is presented. The method includes selectively diffusing nitrogen into a metallic component of a masked metallic component by exposing the masked metallic component to a nitrogen-rich atmosphere. The masked metallic component includes a patterned oxide layer formed on a surface of the metallic component, and the patterned oxide layer includes an oxide of a metal present in the metallic component. A related component is also presented.Type: GrantFiled: March 12, 2018Date of Patent: August 18, 2020Assignee: General Electric CompanyInventors: Wanming Zhang, Min Zou, Francis Johnson
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Patent number: 10071406Abstract: In a steel sheet pile according to the present invention, a carbon equivalent CEN is 0.260 to 0.500, a structure includes a ferrite, a pearlite, a Widmanstätten ferrite, and a precipitate, the precipitate is one or both of Nb carbonitride and V carbonitride, a total number density of the precipitate is 0.10 to 0.30 pieces/?m2, a total area ratio of the ferrite and the pearlite is 70% or more, an area ratio of the Widmanstätten ferrite is 1% or more, an average grain size of the ferrite and the pearlite is 10 to 80 ?m, and a yield strength is 460 MPa or more.Type: GrantFiled: March 24, 2014Date of Patent: September 11, 2018Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Kazutoshi Ichikawa, Hidetoshi Ito, Noriaki Onodera
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Patent number: 9914987Abstract: A martensitic stainless steel alloy is strengthened by copper-nucleated nitride precipitates. The alloy includes, in combination by weight percent, about 10.0 to about 12.5 Cr, about 2.0 to about 7.5 Ni, up to about 17.0 Co, about 0.6 to about 1.5 Mo, about 0.5 to about 2.3 Cu, up to about 0.6 Mn, up to about 0.4 Si, about 0.05 to about 0.15 V, up to about 0.10 N, up to about 0.035 C, up to about 0.01 W, and the balance Fe and incidental elements and impurities. The nitride precipitates may be enriched by one or more transition metals. A case hardened, corrosion resistant variant has a reduced weight percent of Ni, enabling increased use of Cr, and decreased Co.Type: GrantFiled: December 18, 2014Date of Patent: March 13, 2018Assignee: QuesTek Innovations LLCInventors: David R. Snyder, Jiadong Gong, Jason T. Sebastian, James A. Wright, Herng-Jeng Jou, Zechariah Feinberg
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Publication number: 20150132079Abstract: A method for method for solution hardening of a cold deformed workpiece of a passive alloy containing at least 10% chromium, which method includes dissolving at least nitrogen in the workpiece at a temperature T1, which is higher than the solubility temperature for carbide and/or nitride and lower than the melting point of the passive alloy, wherein dissolution of nitrogen at temperature T1 is performed to obtain a diffusion depth in the range of 50 ?m to 5 mm, and cooling the workpiece after the dissolution step at temperature T1 to a temperature which is lower than the temperature at which carbides and/or nitrides form in the passive alloy, wherein the cooling step takes place in an inert gas not containing nitrogen. Further, a member, such as a lock washer for securing bolts or nuts prepared using the method.Type: ApplicationFiled: April 25, 2013Publication date: May 14, 2015Inventors: Thomas Lundin Christiansen, Thomas Strabo Hummelshoj, Marcel A.J. Somers
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Patent number: 8961711Abstract: A method and apparatus for nitriding of highly-alloyed metal article is disclosed herein. In one embodiment, the method and apparatus uses at least one nitrogen source gas such as nitrogen and/or ammonia in an oxygen-free nitriding gas atmosphere, with small additions of one or more hydrocarbons. In this or other embodiments, the method and apparatus described herein is applicable to metal articles comprising iron, nickel and cobalt based alloys and which tend to form passive oxide films on at least a portion of their surface, heated to and nitrided at a certain temperature without prior surface preparation. The apparatus includes an external gas injector comprising 50-60 Hz AC, high voltage/low-current arc discharge electrodes, activating the nitriding atmosphere stream on its way from source to nitriding furnace.Type: GrantFiled: May 18, 2011Date of Patent: February 24, 2015Assignee: Air Products and Chemicals, Inc.Inventors: Zbigniew Zurecki, Xiaolan Wang
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Patent number: 8920581Abstract: Nitriding process of a steel strip is performed. Next, annealing is performed to form a forsterite based glass coating film at a surface of the steel strip. Heating is performed up to 1000° C. or more in a mixed gas atmosphere containing H2 gas and N2 gas, and a rate of N2 gas is 20 volume % or more, next, the atmosphere is switched into H2 gas atmosphere at the temperature of 1000° C. or more and 1100° C. or less, when the annealing is performed. An oxygen potential P (H2O)/P (H2) is set to be 0.05 to 0.3 when the temperature is 850° C. or less during the heating in the mixed gas atmosphere.Type: GrantFiled: September 30, 2009Date of Patent: December 30, 2014Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Yoshiaki Natori, Shuichi Yamazaki, Fumiaki Takahashi, Seiki Takebayashi
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Patent number: 8845825Abstract: The present invention provides spring use heat treated steel which is cold coiled, can achieve both sufficient atmospheric strength and coilability, has a tensile strength of 2000 MPa or more, and can improve the performance as a spring by heat treatment after spring fabrication, that is, high strength spring-use heat treated steel characterized by containing, by mass %, C: 0.45 to 0.9%, Si: 1.7 to 3.0%, and Mn: 0.1 to 2.0%, restricting N: to 0.007% or less, having a balance of Fe and unavoidable impurities, and satisfying, in terms of the analyzed value of the extracted residue after heat treatment, [amount of Fe in residue on 0.2 ?m filter/[steel electrolysis amount]×100?1.1.Type: GrantFiled: March 29, 2007Date of Patent: September 30, 2014Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Masayuki Hashimura, Tatsuro Ochi, Takayuki Kisu, Hiroshi Hagiwara
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Publication number: 20140197003Abstract: A sliding member includes a base material portion formed of steel; a nitrogen diffusion layer with a thickness of 10 ?m to 50 ?m; and a nitrogen compound layer with a thickness of 10 ?m to 50 ?m. The nitrogen compound layer and the nitrogen diffusion layer are formed by performing a first heating process of performing heat treatment on a material formed of steel in an ammonia atmosphere at a temperature of 570° C. to 660° C., a second heating process of performing heat treatment on the material in a non-oxidizing and non-ammonia atmosphere at a temperature of 660° C. to 690° C., the temperature in the second heating process being higher than the temperature in the first heating process, and an oil cooling process of performing oil cooling treatment at an oil temperature of 60° C. to 80° C. subsequently to the second heating process.Type: ApplicationFiled: January 15, 2014Publication date: July 17, 2014Applicants: CNK Co., Ltd., JTEKT CorporationInventors: Hiroyuki ANDO, Junji ANDO, Takuya TSUDA, Shuichi TAKAHASHI, Kiyoyuki HATTORI, Kazuhiro FUKUSHIMA, Tomoyuki NANBA, Hiroshi SHIRAYANAGI
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Patent number: 8713786Abstract: To provide a metal ring excellent in durability by reducing decrease in margin of strength and concentration of tensile stress at its both widthwise end portions and to efficiently realize a production method of the same, a metal ring is formed in an endless band-like body having a nitride layer on its surface portion and constituting part of a metal belt of a belt type continuously variable transmission, the nitride layer being constituted by a first nitride layer portion positioned on an outer circumferential side, a second nitride layer portion positioned on an inner circumferential side, and third nitride layer portions positioned on both widthwise end sides, and the layer thicknesses of the third nitride layer portions being smaller than either one of the layer thicknesses of the first nitride layer portion and the second nitride layer portion.Type: GrantFiled: April 28, 2010Date of Patent: May 6, 2014Assignee: Toyota Jidosha Kabushiki KaishaInventor: Ryo Adomi
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Publication number: 20140065003Abstract: The following specification describes a process for improving the hardness and other mechanical properties of iron and steel Powder Metallurgy (P/M) parts. The first stage of the novel process consists of heating to and holding at a temperature between 590° C. to 720° C. unalloyed or low alloyed P/M parts in an atmosphere containing a Nitrogen donor such as Ammonia in either batch or continuous furnaces. The concentration of ammonia during the first stage is maintained between 3% to 15%. The second stage of the inventive process is an ‘aging’ process which may be conducted either as an in-line process or as a stand-alone independent process that involves the heating of P/M parts that have fully or partially cooled after the first stage to a temperature between 180° C. and 660° C. in an atmosphere of plain air or Nitrogen.Type: ApplicationFiled: August 28, 2013Publication date: March 6, 2014Inventor: Gopinath Narasimhan
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Publication number: 20130302109Abstract: The invention relates to a screw having a head, an adjoining retaining section and a functional tip for use as a self-tapping screw. The functional tip is of greater hardness than the retaining section. The entire screw is made of hardened low-alloy carbon steel.Type: ApplicationFiled: November 28, 2011Publication date: November 14, 2013Applicant: EJOT GmbH & Co. KGInventor: Wilfried Pinzl
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Patent number: 8479396Abstract: A method for hardening running surfaces of roller bearing components, in particular outer bearing rings. In order to provide the edge area (functional layer) of the roller bearing components with a deep layer which is particularly hard and resistant to corrosion, the roller bearing component undergoes nitration for a long period of time at a temperature of between 450 and 650° C. for at least 25 hours. During treatment no carburizing and subsequently no quenching takes place.Type: GrantFiled: May 23, 2007Date of Patent: July 9, 2013Assignee: Schaeffler Technologies AG & Co. KGInventors: Edgar Streit, Oskar Beer
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Patent number: 8303168Abstract: A device has a magnetically shielded component that is magnetically shielded from an external magnetic field, and a housing. The housing is made from a ferritic stainless steel that has an austenitized surface layer rendered on the surface, and an internal layer portion having an internal ferrite phase that functions as a magnetic shield for the magnetically shielded component.Type: GrantFiled: September 11, 2008Date of Patent: November 6, 2012Assignee: Seiko Epson CorporationInventor: Koki Takasawa
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Publication number: 20120118435Abstract: A method and apparatus for nitriding of highly-alloyed metal article is disclosed herein. In one embodiment, the method and apparatus uses at least one nitrogen source gas such as nitrogen and/or ammonia in an oxygen-free nitriding gas atmosphere, with small additions of one or more hydrocarbons. In this or other embodiments, the method and apparatus described herein is applicable to metal articles comprising iron, nickel and cobalt based alloys and which tend to form passive oxide films on at least a portion of their surface, heated to and nitrided at a certain temperature without prior surface preparation. The apparatus includes an external gas injector comprising 50-60 Hz AC, high voltage/low-current arc discharge electrodes, activating the nitriding atmosphere stream on its way from source to nitriding furnace.Type: ApplicationFiled: May 18, 2011Publication date: May 17, 2012Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Zbigniew Zurecki, Xiaolan Wang
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Publication number: 20120118434Abstract: A process for duplex heat treatment of combined nitriding treatment and induction quenching treatment on an iron and steel material includes a chemical conversion treatment step for forming a chemical conversion film on a nitrogen compound layer formed on the iron and steel material by the nitriding treatment, after the nitriding treatment and before the induction quenching treatment. A compound layer formed on a surface of an iron and steel material by nitriding treatment is prevented from being oxidized by induction quenching, so that unevenness in film thickness between different portions of an oxidization-inhibiting film does not easily occur, with the result that a nitrogen-containing compound layer obtained after high-frequency heating remain uniformly.Type: ApplicationFiled: July 28, 2010Publication date: May 17, 2012Applicant: NIHON PARKERIZING CO., LTD.Inventors: Tomoyoshi Konishi, Yoshihiro Ikeda
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Publication number: 20110209798Abstract: Nitriding process of a steel strip is performed. Next, annealing is performed to form a forsterite based glass coating film at a surface of the steel strip. Heating is performed up to 1000° C. or more in a mixed gas atmosphere containing H2 gas and N2 gas, and a rate of N2 gas is 20 volume % or more, next, the atmosphere is switched into H2 gas atmosphere at the temperature of 1000° C. or more and 1100° C. or less, when the annealing is performed. An oxygen potential P (H2O)/P (H2) is set to be 0.05 to 0.3 when the temperature is 850° C. or less during the heating in the mixed gas atmosphere.Type: ApplicationFiled: September 30, 2009Publication date: September 1, 2011Inventors: Yoshiaki Natori, Shuichi Yamazaki, Fumiaki Takahashi, Seiki Takebayashi
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Patent number: 7875128Abstract: A Ni-free stainless steel product excellent in workability and corrosion resistance and a method for manufacturing such stainless steel product. A ferritic stainless steel product containing 18 to 24% by mass of Cr and 0 to 4% by mass of Mo is brought into contact with an inert gas containing a nitrogen gas at 800 degrees C. or above to subject it to nitrogen absorption treatment so that the product is austenitized partially or wholly to obtain such nickel-free product.Type: GrantFiled: April 20, 2007Date of Patent: January 25, 2011Assignees: National Institute for Materials Science, Myodo Metal Co., Ltd.Inventors: Daisuke Kuroda, Shinichi Yanadori, Mitsuo Watanabe, Kazuma Miura
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Patent number: 7828910Abstract: High toughness, high strength alloys are thermochemically processed by performing concurrent bulk alloy heat treatment and surface engineering processing. The concurrent steps can include high temperature solutionizing together with carburizing and tempering together with nitriding.Type: GrantFiled: December 9, 2005Date of Patent: November 9, 2010Assignee: United Technologies CorporationInventors: Raymond C. Benn, Clark V. Cooper
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Patent number: 7641742Abstract: There is provided a rolling bearing which has long life against rolling fatigue and exhibits no decrease in fracture strength and no increase in rate of dimensional change over time, even if the part size thereof is large, and which can obtain higher strength by crystal grains being further refined, if it has a size equal to or smaller than a prescribed size. The rolling bearing according to the present invention includes a race and a rolling element. At least one member of the race and the rolling element has a nitrogen-enriched layer in its surface layer, and a surface layer portion contains austenite crystal grains having a grain size number of at least 11. The member has hardenability allowing a position exhibiting HRC50 in a hardenability test method for steel to be apart from a quenched end by a distance of at least 12.7 mm ( 8/16 inch).Type: GrantFiled: January 11, 2005Date of Patent: January 5, 2010Assignee: NTN CorporationInventors: Chikara Ohki, Kohei Fujita
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Patent number: 7559995Abstract: A process for heat treating metal workpieces contains with respect to an efficient process control the following successive operations following directly one after the other: a heating phase; an enrichment phase; a first cooling phase; a bonding phase; a second cooling phase; and a concluding quenching phase. Workpieces processed by a method of this type are distinguished by a comparatively great fatigue limit and fatigue strength with simultaneous high resistance to wear and tear.Type: GrantFiled: December 23, 2002Date of Patent: July 14, 2009Assignee: Ipsen International GmbHInventor: Bernd Edenhofer
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Patent number: 7108756Abstract: A method of producing a workpiece of a heat-resistant steel, such as hot forming tool steel, where the workpiece may be hardened and depassivated after mechanical machining and electrochemical treatment. The hardening including a reduction step, so that no depassivation need be performed by pickling, for example, before nitriding. The result of the hardening treatment is a favorable surface condition for stepwise nitriding.Type: GrantFiled: September 24, 2002Date of Patent: September 19, 2006Assignee: Robert Bosch GmbHInventors: Nils Lippmann, Wolfgang Lerche
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Patent number: 6982120Abstract: The invention relates to components made of steel, more particularly outer joint parts and inner joint parts of constant velocity joints, and to a process of heat treating such components made of steel. The heat treatment operation includes the process stages of nitriding, induction surface layer hardening and tempering, which processes follow one another. As a result of the nitriding operation, the joint parts are provided with a surface layer (15) including nitrides and a diffusion layer (18) positioned thereunderneath. The subsequent induction hardening process causes the diffusion layer (18) to be hardened, so that it comprises good supporting characteristics for supporting the surface layer (15) positioned above same.Type: GrantFiled: July 20, 2002Date of Patent: January 3, 2006Assignee: GKN Driveline Duetschland GmbHInventor: Manfred Schuster
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Patent number: 6946038Abstract: A weldable structural steel product having fine complex precipitates of TiN and MnS is provided which contains, in terms of percent by weight, 0.03 to 0.17% C, 0.01 to 0.05% Si, 1.0 to 2.5% Mn, 0.05 to 0.2% Ti, 0.0005 to 0.1% Al, 0.008 to 0.030% N, 0.0003 to 0.01% B, 0.001 to 0.2% W, at most 0.03% P, 0.003 to 0.05% S, at most 0.005% O, and balance Fe and incidental impurities while satisfying conditions of 1.2?Ti/N?2.5, 10?N/B?40, 2.5?Al/N?7, 6.5?(Ti+2Al+4B)/N?14, and 220?Mn/S?400. The steel has a microstructure consisting essentially of a complex structure of ferrite and pearlite having a grain size of 20 ?m or less.Type: GrantFiled: November 20, 2001Date of Patent: September 20, 2005Assignee: PoscoInventors: Hong-Chul Jeong, Hae-Chang Choi, Wung-Yong Choo
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Patent number: 6884049Abstract: A screw compressor of which a female rotor is driven by a motor, and of which a male rotor is driven by the female rotor. The male or female rotor is composed of a member which is made of cast iron and is subjected to surface hardening treatment or heat treatment including quenching. The surface hardening treatment may include sulphonitriding or nitiriding treatment. In the case of subjecting the cast iron to the heat treatment, austemper treatment is applied.Type: GrantFiled: November 20, 2002Date of Patent: April 26, 2005Assignee: Hitachi, Ltd.,Inventors: Takeshi Hida, Masayuki Urashin, Shigekazu Nozawa, Hiroki Ohsumimoto, Hirotaka Kameya, Atsushi Watanabe
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Publication number: 20040040631Abstract: A piston ring having improved scuffing resistance, cracking resistance and fatigue resistance, consists of a high-chromium martensitic stainless steel and a sliding nitriding layer formed on the surface of said steel. The stainless steel consists of C: 0.3 to 1.0%; Cr: 14.0 to 21.0%, N: 0.05 to 0.50%, at least one of Mo, V, W and Nb: 0.03 to 3.0% in total, Si: 0.1 to 1.0%, Mn 0.1 to 1.0%, P: 0.05% or less, S: 0.05% or less, the balance being Fe and unavoidable impurities. The sliding nitriding layer comprises on its surface hard particles mainly consisting of nitrides in a range of from 0.2 to 2.0 &mgr;m of average particle size, 7 &mgr;m or less of the longest diameter, and from 5 to 30% in area ratio.Type: ApplicationFiled: June 17, 2003Publication date: March 4, 2004Inventors: Junya Takahashi, Toru Onuki, Shigeo Inoue, Mitsutaka Sasakura
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Patent number: 6579384Abstract: A ball for use in a constant-velocity joint, which is adapted to be interposed between an inner race and an outer race for transmitting rotational power therebetween, is produced by nitriding a surface of a ball made of bearing steel or a material equivalent thereto, and processing the nitrided ball for increased resistance to a crushing load. The nitrided ball is processed for increased resistance to a crushing load by tempering the ball at a temperature ranging from 180 to 230° C. The surface hardness of the ball should preferably be adjusted in the range from HRC 60 to 64.Type: GrantFiled: October 12, 2001Date of Patent: June 17, 2003Assignee: Honda Giken Kogyo Kabushiki KaishaInventors: Yoshimi Usui, Kazuto Fukuda
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Patent number: 6562151Abstract: In a rolling shaft relatively rolling with respect to rolling members provided in a radial needle roller bearing, the rolling shaft is composed of a steel containing 0.5 to 1.2 wt % carbon and is provided with a surface layer 3a containing 0.05 to 0.4 wt % nitrogen, having Vickers hardness being Hv650 or more through a high frequency quenching performed thereto and a residual austenite being 15 to 40 vol %, and a core portion of the rolling shaft contains 0 vol % of the residual austenite.Type: GrantFiled: June 22, 2001Date of Patent: May 13, 2003Assignee: NSK Ltd.Inventors: Kiyoshi Hirakawa, Hiroshi Fukushima
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Patent number: 6451137Abstract: A method for quenching steel parts having undergone a low-pressure thermal processing, which consists of submitting the parts to a high-pressure air flow.Type: GrantFiled: November 17, 2000Date of Patent: September 17, 2002Assignee: Etudes et Constructions MecaniquesInventor: Laurent Pelissier
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Patent number: 6447619Abstract: High surface pressure resistant steel parts and their producing methods are disclosed. These steel parts are useful as gears, cams, bearings and similar high-strength compact steel articles which are required to have wear resistance and strength to withstand fatigue in rolling or rolling-slipping applications. In a steel part formed according to the invention, a fine nitride and/or carbonitride having at least an average grain size of 0.3 &mgr;m or less is dispersed in the contact surface structure; a multi phase structure composed of martensite, which is divided into extremely fine pieces, forming a disordered shape, by the nitride and/or carbonitride, is formed; and a carbide having a grain size of 3 &mgr;m or less is dispersed to increase the hardness of the surface.Type: GrantFiled: November 8, 2000Date of Patent: September 10, 2002Assignee: Komatsu Ltd.Inventors: Takemori Takayama, Naoji Hamasaka
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Patent number: 6406557Abstract: During the treatment of electrical steel, a careful combination of heat treatment of the slab with a specific primary recrystallization and nitriding treatment allows for control of the distribution, quantity and dimensions of precipitates in order to obtain a homogeneous precipitation of nitrogen compounds by direct reaction of the absorbed nitrogen with aluminum during the nitriding step.Type: GrantFiled: June 17, 1999Date of Patent: June 18, 2002Assignee: Acciai Speciali Terni S.p.A.Inventors: Stefano Fortunati, Stefano Cicale′, Giuseppe Abbruzzese, Susanna Matera
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Publication number: 20020062882Abstract: A ball for use in a constant-velocity joint, which is adapted to be interposed between an inner race and an outer race for transmitting rotational power therebetween, is produced by nitriding a surface of a ball made of bearing steel or a material equivalent thereto, and processing the nitrided ball for increased resistance to a crushing load. The nitrided ball is processed for increased resistance to a crushing load by tempering the ball at a temperature ranging from 180 to 230° C. The surface hardness of the ball should preferably be adjusted in the range from HRC 60 to 64.Type: ApplicationFiled: October 12, 2001Publication date: May 30, 2002Inventors: Yoshimi Usui, Kazuto Fukuda
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Patent number: 6328818Abstract: The present invention features nitriding-treating the ferrous material to form a nitrided layer composed of at least one of iron nitride and iron carbide nitride on the surface thereof, and heating to maintain the ferrous material at a temperature of 500 to 700° C. in a treating agent (A), whereby chromium is diffused into the nitrided layer to form a compound layer composed of at least one of chromium nitride and chromium carbide nitride, wherein the treating agent (A) contains the following (a) as a main component and containing the following (b) and (c): (a) at least one of alkali metal chloride and alkaline earth metal chloride; (b) glass having silicone oxide as a main component; and (c) chromium.Type: GrantFiled: November 30, 1998Date of Patent: December 11, 2001Assignee: Maizuru CorporationInventors: Isao Miyagi, Wataru Taniguchi
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Patent number: 6325867Abstract: A rolling bearing contains no more than 0.3 wt % of nitrogen in a grinding allowance portion after carbonitriding and hardening heat treatments, contains from 0.9 wt % (inclusive) up to 1.6 wt % (inclusive) of carbon and from 0.05 wt % (inclusive) up to 0.3 wt % (inclusive) of nitrogen in the surface layer of the finished part and has a nitrogen gradient of no more than 0.5 wt %/mm in the surface layer of the finished part. The rolling bearings are improved in grinding efficiency and which have their rolling life extended significantly.Type: GrantFiled: May 31, 1994Date of Patent: December 4, 2001Assignee: NSK Ltd.Inventors: Shigeru Okita, Yasuo Utsumi, Akihiro Kiuchi
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Patent number: 6309475Abstract: For easily producing a toothed material for high-strength gears etc. with a plastic working technique, deformation resistance occurring in plastic working is reduced and stable high precision plastic working is enabled at lower temperatures. One or more types of heat treatment selected from carburization, carbonitriding and nitriding and a hardening process are applied to an alloy steel material containing: iron as a main component; at least 1.0 to 4.5 wt % Si; 0.35 wt % or less C; and balance Fe and unavoidable impurities, whereby a rolling element is obtained which has a surface layer mainly composed of martensite containing no &agr;-Fe phase and of residual austenite and an inner structure cooled from an (&agr;+&ggr;)-Fe two phase region.Type: GrantFiled: January 26, 1999Date of Patent: October 30, 2001Assignee: Komatsu Ltd.Inventors: Takemori Takayama, Chikara Nakao
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Patent number: 6284062Abstract: A member used in contact with a hot dip galvanizing bath, such as a sinker roll, a support roll or a bearing, is produced by nitriding stainless steel to form a nitride layer and a nitrogen-diffused layer on the surface thereof. The member used in contact with a hot dip galvanizing bath is formed on its surface with the nitride layer by nitriding it in a salt bath containing a cyanide, a cyanate, a carbonate and the like or by heat-treating it in an atmosphere containing ammonium or nitrogen.Type: GrantFiled: May 28, 1999Date of Patent: September 4, 2001Assignee: Taiyo Steel Co., Ltd.Inventors: Takeo Nagashima, Eizo Sakuma, Katsuaki Takano
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Patent number: 6235128Abstract: The present invention is a unique sequential process for treating carbon and alloy steels to improve resistance to tribological stresses while reducing conventional processing time required to obtain articles having a similar hardness. This process comprises carburizing or carbonitriding the article, tempering the carburized or carbonitrided article, net-shaping (machining) the tempered article, and plasma (ion) nitriding the tempered article for a significantly reduced period of time versus conventional plasma (ion) nitriding.Type: GrantFiled: March 8, 1999Date of Patent: May 22, 2001Inventors: John C. Chang, John Joseph Krieg, Richard Blanco Roe, Steve Stormzand, Tony Wu, Lynn Lu, Jeffrey W. Kunitzer
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Patent number: 6197125Abstract: A method for improving the corrosion resistance, increasing the hardness, providing superior ductility, and reducing surface-cracking of a diffusion coating by nitriding and heating-treating the diffusion coating is disclosed. The nitriding and heat-treating may occur subsequently or simultaneously. Further, the disclosed method may be practiced subsequent to or incorporated as an intergral part of any known diffusion coating process which utilizes a heating step in a furnace having a cover gas.Type: GrantFiled: December 13, 1999Date of Patent: March 6, 2001Assignee: McDermott Technology, Inc.Inventor: Steven C. Kung
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Patent number: 5669988Abstract: Object: Prevention of generation of press marks as well as increase of wear resistance at a corrugation tip portion and thereby providing a corrugating roll having a much improved life.Construction: A manufacturing method of a corrugating roll useful for forming a wave-shaped core paper of corrugated board, characterized in that the corrugating roll is worked to form tooth-shaped corrugation portions on the outer circumference and applying a nitriding treatment or a carbo-nitriding treatment, and then applying to the corrugation portion of the corrugating roll a quenching and tempering treatment, and further forming a wear resistant coating on the surface of the corrugation portion.Type: GrantFiled: August 9, 1995Date of Patent: September 23, 1997Assignee: Mitsubishi Jukogyo Kabushiki KaishaInventors: Hiroyuki Takenaka, Yorishige Tosaka, Yasunobu Sahara, Yoshiaki Maruyama, Hidenori Yamane, Akio Izuwa
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Patent number: 5667605Abstract: The invention relates to a method for fabricating a piece of structural steel that includes thermal or thermomechanical treatment steps that could ordinarily lower the fatigue strength and shock and impact resistance of the steel piece. In the method of the invention a workpiece of microalloy steel is fabricated containing the following elements in the mounts indicated and having a bainitic structure:______________________________________ C 0.05-0.5 wt. % Mo 0-0.5 wt. % Mn 1-2 wt. % V 0-0.30 wt. % Si 0.05-1.5 wt. % B 0-0.010 wt. % Cr 0.1-1 wt. % Ti 0-0.030 wt. % Nb 0-0.1 wt. % ______________________________________The workpiece is then subjected to a treatment that includes a heating stage wherein at least a part of said piece is subjected to a temperature in the range 500.degree.-900.degree. C., followed by a cooling stage in which at least the part of the piece is subjected to cooling at a rate greater than 500.degree. C./hr.Type: GrantFiled: December 8, 1995Date of Patent: September 16, 1997Assignee: AscometalInventors: Jacques Bellus, Claude Pichard, Pierre Jolly, Daniel Forest, Daniel Robat
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Patent number: 5650022Abstract: A method of nitriding steel which comprises reacting the steel surface with nitrogen so as to form a hard nitrided layer, and, prior to nitriding, holding steel under a gas atmosphere containing fluorine compound gas or fluorine gas and also containing air of 0.5 to 20 volume % of the total or oxygen gas of 0.1 to 4 volume % of the total with heating, whereby occurrence of uneven nitriding is prevented and at the same time savings in consumption of expensive fluorine- or fluoride-containing gas can be realized.Type: GrantFiled: May 16, 1996Date of Patent: July 22, 1997Assignee: Daido Hoxan Inc.Inventors: Kenzo Kitano, Akio Hashigami, Takashi Muraoka
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Patent number: 5503687Abstract: Enrichment of surface and near surface regions of stainless steel components that nearly have their final shape with dissolved nitrogen at temperatures between 1000.degree. and 1200.degree. C. is provided. In this way, ferritic and martensitic structure portions in the surface zone are changed to austenite. By means of mixed crystal hardening, nitrogen increases the strength of the surface layer that is formed and that at the same time is characterized by the degree of toughness of the austenitic structure. The combination of strength and toughness leads to a significantly increased resistance to wear, especially wear due to impact, cavitation, and impingement of drops. In contrast to carbon, the resistance to corrosion of the surface layer is not adversely affected when nitrogen diffuses in, but rather is even further increased. The thermal treatment process is suitable for increasing the service life of rust proof components in flow-producing mechanisms.Type: GrantFiled: October 5, 1994Date of Patent: April 2, 1996Inventor: Hans Berns
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Patent number: 5298091Abstract: A method is taught for protecting fuel contacting surfaces of a gas turbine engine from carbon deposition by heating the element in a nitrogen containing atmosphere for sufficient time to cause penetration and absorption of nitrogen into the grain boundaries of the alloy surface, which acts as a barrier between the hydrocarbon fuel and the catalytic elements in the surfaces. The method includes heating at a temperature of 1800-1850 F. for about one hour, cooling to 1525-1575 F. and holding for about four hours, and cooling to a temperature of 1375-1425 F. and holding for about 16 hours.Type: GrantFiled: December 20, 1991Date of Patent: March 29, 1994Assignee: United Technologies CorporationInventors: William H. Edwards, III, John A. Harris, III, Edward S. Smith
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Patent number: 5254181Abstract: This invention relates to a method for forming a uniform, deep nitride layer on and in steel works at low cost, wherein a steel work is fluorided in heated condition in an atmosphere of a mixed gas composed of fluorine gas and inert gas and, then, nitrided in heated condition in an atmosphere of nitriding gas.Type: GrantFiled: July 10, 1991Date of Patent: October 19, 1993Assignee: Daidousanso Co., Ltd.Inventors: Akira Yoshino, Masaki Tahara, Haruo Senbokuya, Kenzo Kitano, Teruo Minato
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Patent number: 5228929Abstract: Disclosed is a process for manufacturing a corrosion resistant iron-alloy, powered metal or sintered carbide component. In a first step, the component is subjected to an initial thermochemical treatment preferably consisting of nitriding, in a closed furnace in order to form onto the surface of the component a nitrogen diffusion zone followed by the superficial layer consisting of .gamma.' and .epsilon. nitride layers. In a second step, an aqueous solution comprising oxygen, carbon, nitrogen and sulfur is introduced into the furnace for a period of time sufficient to allow transformation of the .epsilon. nitride layer into a porous layer of ferrous oxide(s). This process is particularly efficient and permits to produce a superficial porous ferrous oxide layer thicker than 2 .mu.m onto a nitride steel component.Type: GrantFiled: May 8, 1991Date of Patent: July 20, 1993Inventors: Wladyslaw Panasiuk, Michel Korwin