With Working Patents (Class 148/556)
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Patent number: 11591683Abstract: There is provided a method of treating a nickel base super alloy (NiSa) article. First, the NiSa article having fine grains is obtained. The NiSa article has a uniform distribution of the fine grains and substantially uniform mechanical properties throughout. One or more regions within the NiSa article are mechanically deformed. Then, the NiSa article is heat treated to obtain coarse grains in the one or more regions, the coarse grains having a size that is larger than that of the fine grains of the NiSa article outside of the one or more regions.Type: GrantFiled: February 18, 2020Date of Patent: February 28, 2023Assignee: PRATT & WHITNEY CANADA CORP.Inventors: Thomas Georges, Orlando Scalzo, Marc Lorenzo Campomanes
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Patent number: 10823009Abstract: A method for working a housing of a turbocharger, namely a bearing housing or a compressor housing or a turbine housing of the turbocharger has the following steps: providing the housing to be worked, filling at least one hollow space of the housing to be worked with an incompressible fluid; and building-up a fluid pressure in the respective hollow space filled with the incompressible fluid, at least locally deforming plastically a housing portion of the housing limiting the respective hollow space of the housing at least in portions.Type: GrantFiled: November 6, 2019Date of Patent: November 3, 2020Assignee: MAN Energy Solutions SEInventors: Jirí Klima, Lukás Bozek
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Patent number: 9738953Abstract: The present invention provides a hot-forgeable Ni-based superalloy excellent in high temperature strength, including, in terms of % by mass: C: more than 0.001% and less than 0.100%, Cr: 11.0% or more and less than 19.0%, Co: 0.5% or more and less than 22.0%, Fe: 0.5% or more and less than 10.0%, Si: less than 0.1%, Mo: more than 2.0% and less than 5.0%, W: more than 1.0% and less than 5.0%, Mo+½W: 2.5% or more and less than 5.5%, S: 0.010% or less, Nb: 0.3% or more and less than 2.0%, Al: more than 3.00% and less than 6.50%, and Ti: 0.20% or more and less than 2.49%, with the balance being Ni and unavoidable impurities, in which (Ti/Al)×10 is 0.2 or more and less than 4.0 in terms of atomic ratio, and in which Al+Ti+Nb is 8.5% or more and less than 13.0% in terms of atomic %.Type: GrantFiled: January 29, 2014Date of Patent: August 22, 2017Assignee: DAIDO STEEL CO., LTD.Inventors: Mototsugu Osaki, Shigeki Ueta, Takuma Okajima, Ayumi Hori
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Patent number: 9683279Abstract: An alloy is composed essentially of, in terms of weight percent: 6 to 8.5 Cr, 5.5 to 13.5 Mo, 0.4 to 7.5 W, 1 to 2 Ti, 0.7 to 0.85 Mn, 0.05 to 0.3 Al, 0.08 to 0.5 C, 0 to 1 Nb, with the balance Ni, the alloy being characterized by, at 850° C., a yield strength of at least 25 Ksi, a tensile strength of at least 30 Ksi, a creep rupture life at 12 Ksi of at least 45 hours, and a corrosion rate, expressed in weight loss [g/(cm2 sec)]10?11 during a 1000 hour immersion in liquid FLiNaK at 850° C., in the range of 6 to 39.Type: GrantFiled: May 15, 2014Date of Patent: June 20, 2017Assignee: UT-BATTELLE, LLCInventors: Govindarajan Muralidharan, Dane Francis Wilson, David Eugene Holcomb
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Patent number: 9683280Abstract: An alloy consists essentially of, in terms of weight percent: 6 to 8.5 Cr, 5.5 to 13.5 Mo, 0.4 to 7.5 W, 1 to 2 Ti, 0.7 to 0.85 Mn, 0.05 to 0.3 Al, up to to 0.1 Co, 0.08 to 0.5 C, 1 to 5 Ta, 1 to 4 Nab, 1 to 3 Hf, balance Ni. The alloy is characterized by, at 850° C., a yield strength of at least 36 Ksi, a tensile strength of at least 40 Ksi, a creep rupture life at 12 Ksi of at least 72.1 hours, and a corrosion rate, expressed in weight loss [g/(cm2sec)]×10?11 during a 1000 hour immersion in liquid FLiNaK at 850° C., in the range of 8 to 25.Type: GrantFiled: January 10, 2014Date of Patent: June 20, 2017Assignee: UT-BATTELLE, LLCInventors: Govindarajan Muralidharan, Dane Francis Wilson, David Eugene Holcomb
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Patent number: 9540714Abstract: An essentially cobalt-free alloy consists essentially of, in terms of weight percent: 6.3 to 7.2 Cr, 0.5 to 2 Al, 0 to 5 Fe, 0.7 to 0.8 Mn, 9 to 12.5 Mo, 0 to 6 Ta, 0.75 to 3.5 Ti, 0.01 to 0.25 Nb, 0.2 to 0.6 W, 0.02 to 0.04 C, 0 to 0.001 B, 0.0001 to 0.002 N, balance Ni. The alloy is characterized by a ?? microstructural component in the range of 3 to 17.6 weight percent of the total composition. The alloy is further characterized by, at 850° C., a yield strength of at least 60 Ksi, a tensile strength of at least 70 Ksi, a creep rupture life at 12 Ksi of at least 700 hours, and a corrosion rate, expressed in weight loss [g/(cm2sec)]10?11 during a 1000 hour immersion in liquid FLiNaK at 850° C., in the range of 5.5 to 17.Type: GrantFiled: March 15, 2013Date of Patent: January 10, 2017Assignee: UT-BATTELLE, LLCInventors: David E. Holcomb, Govindarajan Muralidharan, Dane F. Wilson
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Patent number: 9447486Abstract: An Ni-based alloy for casting used for a steam turbine of an embodiment contains in percent (%) by mass C (carbon): 0.01 to 0.1, Cr (chromium): 15 to 25, Co (cobalt): 10 to 15, Mo (molybdenum): 5 to 12, Al (aluminum): 0.5 to 2, Ti (titanium): 0.3 to 2, B (boron): 0.001 to 0.006, Ta (tantalum): 0.05 to 1, Si (silicon): 0.1 to 0.5, Mn (manganese): 0.1 to 0.5, and the balance of Ni (nickel) and unavoidable impurities.Type: GrantFiled: June 4, 2012Date of Patent: September 20, 2016Assignee: KABUSHIKI KAISHA TOSHIBAInventors: Kuniyoshi Nemoto, Yomei Yoshioka, Kiyoshi Imai, Shigekazu Miyashita, Takeo Suga
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Patent number: 9328402Abstract: In one embodiment, a nickel-base alloy for forging or rolling contains, in weight %, carbon (C): 0.05 to 0.2, silicon (Si) 0.01 to 1, manganese (Mn): 0.01 to 1, cobalt (Co): 5 to 20, iron (Fe): 0.01 to 10, chromium (Cr): 15 to 25, and one kind or two kinds or more of molybdenum (Mo), tungsten (W) and rhenium (Re), with Mo+(W+Re)/2: 8 to 25, the balance being nickel (Ni) and unavoidable impurities.Type: GrantFiled: August 11, 2010Date of Patent: May 3, 2016Assignee: Kabushiki Kaisha ToshibaInventors: Masayuki Yamada, Kiyoshi Imai, Kuniyoshi Nemoto, Shigekazu Miyashita, Takeo Suga
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Patent number: 9238853Abstract: A Ni-base casting superalloy containing, in masse, C: 0.05 to 0.2, Si: 0.01 to 1, Mn: 0.01 to 1, Co: 5 to 20, Fe: 10 or less, Cr: 15 to 25, and one kind or two kinds or more of Mo, W, and Re, with Mo+(W+Re)/2: 8 to 25, the balance being Ni and unavoidable impurities.Type: GrantFiled: May 20, 2009Date of Patent: January 19, 2016Assignee: KABUSHIKI KAISHA TOSHIBAInventors: Masayuki Yamada, Kiyoshi Imai, Kuniyoshi Nemoto, Shigekazu Miyashita, Kazutaka Ikeda, Takeo Suga
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Publication number: 20140261910Abstract: Disclosed herein are nickel beryllium alloys having improved corrosion and hardness characteristics relative to known nickel beryllium alloys. The alloys have a chemical composition with about 1.5% to 5% beryllium (Be) by weight, about 0.5% to 7% niobium (Nb) by weight; and nickel (Ni). Up to about 5 wt % chromium (Cr) may also be included. The alloys display improved hardness and corrosion resistance properties.Type: ApplicationFiled: March 7, 2014Publication date: September 18, 2014Applicant: MATERION CORPORATIONInventors: Carole L. Trybus, John C. Kuli, Fritz C. Grensing
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Publication number: 20140261905Abstract: A method for making alloy strip by continuous casting with tensile strength of at least 900 MPa and total elongation of at least 30%, strip with tensile strength of at least 1200 MPa and total elongation of at least 20%, or strip with tensile strength of at least 1500 MPa and total elongation of at least 15%. Molten metal is introduced forming a casting pool supported on the casting rolls and counter-rotating the A heat flux is provided with a peak heat flux >20 Mw/m2. The strip is cooled at 1000-3000 K/sec. A roll biasing force >40 kN/meter of casting roll length is applied to form thin metal strip. The strip is then conveyed through a first enclosure with an atmosphere having an oxygen content of <5%. The cast strip is rolled through a rolling mill and reduced and modification of the microstructure is initiated.Type: ApplicationFiled: March 15, 2013Publication date: September 18, 2014Applicant: CASTRIP, LLCInventors: Walter N. Blejde, Rama Ballav Mahapatra, Daniel Geoffrey Edelman
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Publication number: 20130255843Abstract: A precipitation-strengthened Ni-based heat-resistant alloy of the present invention includes 0.03 wt % or less of C, 0.5 wt % or less of Mn, 0.01 wt % or less of P, 0.01 wt % or less of S, 2.0 to 3.0 wt % of Si, 23 to 30 wt % of Cr, 7.0 to 14.0 wt % of W, 10 to 20 wt % of Fe, and 40 to 60 wt % of Ni, wherein a total content of C, N, O, P and S is 0.01 wt % or less. A silicide is dispersed and precipitated and a grain size of a matrix austenite is controlled through a thermo-mechanical treatment. As a result, the precipitation-strengthened Ni-based heat-resistant alloy excellent in irradiation resistance, heat resistance and corrosion resistance can be obtained with a low cost.Type: ApplicationFiled: May 29, 2013Publication date: October 3, 2013Inventors: Kiyoshi KIUCHI, Kiyoyuki Shiba, Tsuyoshi Noura, Jumpei Nakayama
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Patent number: 8444778Abstract: Disclosed is a low-thermal-expansion Ni-based super-heat-resistant alloy for a boiler, which has excellent high-temperature strength. The alloy can be welded without the need of carrying out any aging treatment. The alloy has a Vickers hardness value of 240 or less. The alloy comprises (by mass) C in an amount of 0.2% or less, Si in an amount of 0.5% or less, Mn in an amount of 0.5% or less, Cr in an amount of 10 to 24%, one or both of Mo and W in such an amount satisfying the following formula: Mo+0.5 W=5 to 17%, Al in an amount of 0.5 to 2.0%, Ti in an amount of 1.0 to 3.0%, Fe in an amount of 10% or less, and one or both of B and Zr in an amount of 0.02% or less (excluding 0%) for B and in an amount of 0.2% or less (excluding 0%) for Zr, with the remainder being 48 to 78% of Ni and unavoidable impurities.Type: GrantFiled: August 29, 2008Date of Patent: May 21, 2013Assignees: Hitachi Metals, Ltd., Babcock-Hitachi Kabushiki Kaisha, Hitachi, Ltd.Inventors: Toshihiro Uehara, Takehiro Ohno, Akihiro Toji, Takashi Sato, Gang Bao, Shinya Imano, Hiroyuki Doi
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Patent number: 8246766Abstract: The high-strength Ni-based alloy tube for nuclear power use consists, by mass percent, of C: 0.04% or less, Si: 0.10 to 0.50%, Mn: 0.05 to 0.50%, Ni: 55 to 70%, Cr: more than 26% and not more than 35%, Al: 0.005 to 0.5%, N: 0.02 to 0.10%, and one or more kinds of Ti: 0.01 to 0.5% and Nb: 0.02 to 1.0%, the balance being Fe and impurities. For this alloy tube, the grain size is as fine as grain size No. 6 or higher in JIS G 0551. It is preferable that the high-strength Ni-based alloy tube be manufactured by the process of preparing a Ni-based alloy stock through a remelting process, hot forging, heating to 1000 to 1160° C., hot extruding at a working ratio such that an extrusion ratio is 4 or higher, and performing solution annealing and thermal treatment.Type: GrantFiled: November 20, 2010Date of Patent: August 21, 2012Assignee: Sumitomo Metal Industries, Ltd.Inventors: Tetsuo Yokoyama, Hiroyuki Anada
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Publication number: 20120037280Abstract: A method for manufacturing a blank part in Ni-base superalloy, wherein an alloy is prepared and heat treatments are conducted characterized in that: the said superalloy contains at least a total of 2.5% of Nb and Ta; heat treatment is conducted comprising a plurality of steps: a first step at between 850 and 1000° C. held for at least 20 minutes to precipitate the ? phase at the grain boundaries; a second step held at a temperature higher than the temperature of the first step allowing partial dissolution of the ? phase obtained at the first step; ageing treatment comprising a third step and optionally one or more additional steps at a temperature below the temperature of the first step and allowing precipitation of the hardening phases ?? and ??. Part thus obtained.Type: ApplicationFiled: February 5, 2010Publication date: February 16, 2012Applicants: AUBERT & DUVAL, SNECMA, TURBOMECAInventor: Alexandre Devaux
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Publication number: 20110183151Abstract: [Problem to be Solved] There are provided a high-strength Ni-based alloy tube for nuclear power use having uniform high temperature strength throughout the overall length of tube and a method for manufacturing the same. [Solution] The high-strength Ni-based alloy tube for nuclear power use consists, by mass percent, of C: 0.04% or less, Si: 0.10 to 0.50%, Mn: 0.05 to 0.50%, Ni: 55 to 70%, Cr: more than 26% and not more than 35%, Al: 0.005 to 0.5%, N: 0.02 to 0.10%, and one or more kinds of Ti: 0.01 to 0.5% and Nb: 0.02 to 1.0%, the balance being Fe and impurities. For this alloy tube, the grain size is as fine as grain size No. 6 or higher in JIS G 0551. It is preferable that the high-strength Ni-based alloy tube be manufactured by the process described below: preparing a Ni-based alloy stock through a remelting process, hot forging, heating to 1000 to 1160° C., hot extruding at a working ratio such that an extrusion ratio is 4 or higher, and performing solution annealing and thermal treatment.Type: ApplicationFiled: November 20, 2010Publication date: July 28, 2011Applicant: SUMITOMO METAL INDUSTRIES, LTD.Inventors: Tetsuo YOKOYAMA, Hiroyuki ANADA
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Publication number: 20100329883Abstract: A gamma prime precipitation-strengthened nickel-base superalloy and method of forging an article from the superalloy to promote a low cycle fatigue resistance and high temperature dwell behavior of the article. The superalloy has a composition of, by weight, 16.0-22.4% cobalt, 6.6-14.3% chromium, 2.6-4.8% aluminum, 2.4-4.6% titanium, 1.4-3.5% tantalum, 0.9-3.0% niobium, 1.9-4.0% tungsten, 1.9-3.9% molybdenum, 0.0-2.5% rhenium, greater than 0.05% carbon, at least 0.1% hafnium, 0.02-0.10% boron, 0.03-0.10% zirconium, the balance nickel and incidental impurities. A billet is formed of the superalloy and worked at a temperature below the gamma prime solvus temperature of the superalloy so as to form a worked article, which is then heat treated above the gamma prime solvus temperature of the superalloy to uniformly coarsen the grains of the article, after which the article is cooled to reprecipitate gamma prime.Type: ApplicationFiled: June 30, 2009Publication date: December 30, 2010Applicant: GENERAL ELECTRIC COMPANYInventors: David Paul Mourer, Kenneth Rees Bain
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Patent number: 7854064Abstract: A method for repairing a turbine engine component comprises the steps of providing a turbine engine component formed from a nickel-based superalloy, removing any defects from the turbine engine component, the removing step comprising subjecting the turbine engine component to a solutioning heat treatment using a heating rate in the range of from 29 degrees Fahrenheit/minute to approximately 40 degrees Fahrenheit/minute as the component passes through a temperature in the range of from 1100 degrees Fahrenheit to 1600 degrees Fahrenheit, and welding the turbine engine component to effect the repair. A deliberately slow post-solution treatment cooling rate is used to substantially prevent weld cracks.Type: GrantFiled: June 5, 2006Date of Patent: December 21, 2010Assignee: United Technologies CorporationInventor: David R. Malley
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Patent number: 7846276Abstract: The present disclosure provides alloys having an ultra-low coefficient of thermal expansion in the range of 60° F. to 80° F. The alloys have coefficient of thermal expansion no greater than 0.35×10?6° F.?1 in the range of 60° F. to 80° F. Methods of making such alloys also are provided, as well articles of manufacture including such alloys and methods of making such articles.Type: GrantFiled: May 1, 2007Date of Patent: December 7, 2010Assignee: ATI Properties, Inc.Inventors: David R. Hasek, Thomas R. Parayil
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Publication number: 20100226814Abstract: Disclosed is a low-thermal-expansion Ni-based super-heat-resistant alloy for a boiler, which has excellent high-temperature strength. The alloy can be welded without the need of carrying out any aging treatment. The alloy has a Vickers hardness value of 240 or less. The alloy comprises (by mass) C in an amount of 0.2% or less, Si in an amount of 0.5% or less, Mn in an amount of 0.5% or less, Cr in an amount of 10 to 24%, one or both of Mo and W in such an amount satisfying the following formula: Mo+0.5 W=5 to 17%, Al in an amount of 0.5 to 2.0%, Ti in an amount of 1.0 to 3.0%, Fe in an amount of 10% or less, and one or both of B and Zr in an amount of 0.02% or less (excluding 0%) for B and in an amount of 0.2% or less (excluding 0%) for Zr, with the remainder being 48 to 78% of Ni and unavoidable impurities.Type: ApplicationFiled: August 29, 2008Publication date: September 9, 2010Applicants: HITACHI METALS, LTD., BABCOCK-HITACHI KABUSHIKI KAISHA, HITACHI, LTD.Inventors: Toshihiro Uehara, Takehiro Ohno, Akihiro Toji, Takashi Sato, Gang Bao, Shinya Imano, Hiroyuki Doi
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Patent number: 7507306Abstract: An Fe—Ni—Cr alloy formulated to contain a strengthening phase that is able to maintain a fine grain structure during forging and high temperature processing of the alloy. The alloy contains a sufficient amount of titanium, zirconium, carbon and nitrogen so that fine titanium and zirconium carbonitride precipitates formed thereby are near their solubility limit in the alloy when molten. In the production of an article from such an alloy by thermomechanical processing, a dispersion of the fine titanium and zirconium carbonitride precipitates form during solidification of the melt and remain present during subsequent elevated processing steps to prohibit austenitic grain growth.Type: GrantFiled: February 28, 2006Date of Patent: March 24, 2009Assignee: General Electric CompanyInventors: Jianqiang Chen, Jon Conrad Schaeffer, Anjilivelil Kuruvilla
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Publication number: 20090000706Abstract: A method of forming a component from a gamma prime precipitation-strengthened nickel-base superalloy. The method entails formulating the superalloy to have a sufficiently high carbon content and forging the superalloy at sufficiently high local strain rates so that, following a supersolvus heat treatment, the component is characterized by a fine and substantially uniform grain size distribution, preferably finer than ASTM 7 and more preferably in a range of about ASTM 8 to 10.Type: ApplicationFiled: June 28, 2007Publication date: January 1, 2009Applicant: GENERAL ELECTRIC COMPANYInventors: Eric Scott Huron, Joseph Aloysius Heaney, David Paul Mourer, Jon Raymond Groh, Edward Lee Raymond, David Alan Utah, Michael James Weimer, Kenneth Rees Bain
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Publication number: 20080053577Abstract: Disclosed herein is a nickel-titanium alloy comprising nickel, titanium, and at least one rare earth element. The nickel-titanium alloy comprises from about 34 at. % to about 60 at. % nickel, from about 34 at. % to about 60 at. % titanium, and from about 0.1 at. % to about 15 at. % at least one rare earth element. The nickel-titanium alloy may further include one or more additional alloying elements. In addition to radiopacity, the nickel-titanium alloy preferably exhibits superelastic or shape memory behavior. Medical devices comprising the nickel-titanium alloy and a method of making them are also disclosed.Type: ApplicationFiled: September 6, 2007Publication date: March 6, 2008Applicants: Cook Incorporated, Cook Ireland LimitedInventors: Tofail Ansar Syed, James M. Carlson, Shane Carr, Paul Devereux, Donncha Haverty, Shay J. Lavelle, Tim McGloughlin
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Patent number: 7198684Abstract: A plurality of gas turbine components or other articles are manufactured from a plurality of metallic-alloy workpieces using a manufacturing apparatus having a metalworking apparatus, and an annealing apparatus wherein the individual workpieces are annealed by single-workpiece annealing and not by large-batch annealing. A workpiece flow of the plurality of workpieces is established sequentially through the metalworking apparatus and the annealing apparatus.Type: GrantFiled: March 14, 2003Date of Patent: April 3, 2007Assignee: General Electric CompanyInventors: Thomas Froats Broderick, Jeffrey Lynn Myers, Francois Laurent Giguere, Peter Brian Haley, Paul Raymond Phaneuf, William Francis Bergeron, Thomas Caudwell Straub
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Patent number: 7115175Abstract: The present invention relates to an improved single crystal nickel base superalloy and a process for making same. The single crystal nickel base superalloy has a composition comprising 3 to 12 wt % chromium, up to 3 wt % molybdenum, 3 to 10 wt % tungsten, up to 5 wt % rhenium, 6 to 12 wt % tantalum, 4 to 7 wt % aluminum, up to 15 wt % cobalt, up to 0.05 wt % carbon, up to 0.02 wt % boron, up to 0.1 wt % zirconium, up to 0.8 wt % hafnium, up to 2.0 wt % niobium, up to 1.0 wt % vanadium, up to 0.7 wt % titanium, up to 10 wt % of at least one element selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium, platinum, and mixtures thereof, and the balance essentially nickel. The single crystal nickel base superalloy has a microstructure which is pore-free and eutectic ?–?? free and which has a gamma prime morphology with a bimodal ?? distribution.Type: GrantFiled: July 19, 2004Date of Patent: October 3, 2006Assignee: United Technologies CorporationInventors: Daniel P. DeLuca, Charles M. Biondo
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Patent number: 6942947Abstract: Hydrogen storage alloy has: (1) a main composition expressed by the formula of Mm?(Ni?Al?Co?Mn?Cu); (2) a ratio of the number of atoms expressed by the formula (Ni?Al?Co?Mn?Cu) is 5.5<(Ni+Al+Co+Mn+Cu)?7.0, and 4.0?Ni, when Mm is set at 1 in a ratio of the number of atoms; and (3) an internal structure having hydrogen storage alloy phase expressed by the general formula of AB5 and a second phase existing in the hydrogen storage alloy phase, wherein the whole the composition is expressed by the formula of MmiNi(3.95+p)Al(0.3+q)Co(0.4+r)Mn(0.45+s)Cu(0.10+t), and 0.3<(p+q+r+s+t)?1.8.Type: GrantFiled: March 24, 2003Date of Patent: September 13, 2005Assignee: Toyota Jidosha Kabushiki KaishaInventor: Kenji Nakamura
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Patent number: 6890480Abstract: Medium- and high-density articles are formed from melting and casting alloys containing tungsten, iron, nickel and optionally manganese and/or steel. In some embodiments, the articles have densities in the range of 8-10.5 g/cm3, and in other embodiments, the articles have densities in the range of 10.5-15 g/cm3. In some embodiments, the articles are ferromagnetic, and in others the articles are not ferromagnetic. In some embodiments, tungsten forms the largest weight percent of the alloy, and in other embodiments the alloy contains no more than 50 wt % tungsten. In some embodiments, the articles are shell shot.Type: GrantFiled: February 3, 2003Date of Patent: May 10, 2005Inventor: Darryl D. Amick
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Publication number: 20030136480Abstract: A process for producing a heat-resistant intermetallic compound Ni3Al foil having a room-temperature ductility, which comprises a first step of arc-melting an alloy having a chemical composition containing Ni as a main component and Al to form a starting rod, a second step of growing the starting rod in columnar crystal form by unidirectional solidification, a third step of cutting out the unidirectionally solidified rod to form a plate, and a fourth step of cold-rolling the plate cut at room temperature to form a foil. The invention can provide a process for producing a thin Ni3Al foil which has a thickness of 200 microns or less and which is excellent in high-temperature strength, oxidation and corrosion resistances and room-temperature ductility.Type: ApplicationFiled: January 8, 2002Publication date: July 24, 2003Inventors: Toshiyuki Hirano, Masahiko Demura
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Patent number: 6571857Abstract: A process for casting and preparing an ingot of a beta-phase NiAl-based material, particularly for use in PVD coating processes. The method entails melting a nickel-aluminum composition having an aluminum content below that required for stoichiometric beta-phase NiAl intermetallic so as to form a melt that includes nickel and Ni3Al. Aluminum is then added to the melt, causing an exothermic reaction between nickel and aluminum as the melt equilibrium shifts from Ni3Al to NiAl. However, the aluminum is added at a rate sufficiently low to avoid a violent exothermic reaction. The addition of aluminum continues until sufficient aluminum has been added to the melt to yield a beta-phase NiAl-based material. The beta-phase NiAl-based material is then solidified to form an ingot, which is then heated and pressed to close porosity and homogenize the microstructure of the ingot.Type: GrantFiled: November 7, 2001Date of Patent: June 3, 2003Assignee: General Electric CompanyInventors: Ramgopal Darolia, Joseph David Rigney
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Publication number: 20030085020Abstract: A process for casting and preparing an ingot of a beta-phase NiAl-based material, particularly for use in PVD coating processes. The method entails melting a nickel-aluminum composition having an aluminum content below that required for stoichiometric beta-phase NiAl intermetallic so as to form a melt comprising nickel and Ni3Al. Aluminum is then added to the melt, causing an exothermic reaction between nickel and aluminum as the melt equilibrium shifts from Ni3Al to NiAl. However, the aluminum is added at a rate sufficiently low to avoid a violent exothermic reaction. The addition of aluminum continues until sufficient aluminum has been added to the melt to yield a beta-phase NiAl-based material. The beta-phase NiAl-based material is then solidified to form an ingot, which is then heated and pressed to close porosity and homogenize the microstructure of the ingot.Type: ApplicationFiled: November 7, 2001Publication date: May 8, 2003Inventors: Ramgopal Darolia, Joseph David Rigney
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Publication number: 20030041930Abstract: The present invention relates to an improved single crystal nickel base superalloy and a process for making same. The single crystal nickel base superalloy has a composition comprising 3 to 12 wt % chromium, up to 3 wt % molybdenum, 3 to 10 wt % tungsten, up to 5 wt % rhenium, 6 to 12 wt % tantalum, 4 to 7 wt % aluminum, up to 15 wt % cobalt, up to 0.05 wt % carbon, up to 0.02 wt % boron, up to 0.1 wt % zirconium, up to 0.8 wt % hafnium, up to 2.0 wt % niobium, up to 1.0 wt % vanadium, up to 0.7 wt % titanium, up to 10 wt % of at least one element selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium, platinum, and mixtures thereof, and the balance essentially nickel. The single crystal nickel base superalloy has a microstructure which is pore-free and eutectic &ggr;-&ggr;′ free and which has a gamma prime morphology with a bimodal &ggr;′ distribution.Type: ApplicationFiled: August 30, 2001Publication date: March 6, 2003Inventors: Daniel P. DeLuca, Charles M. Biondo
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Publication number: 20030034098Abstract: An article, such as a turbine engine component, formed from a nickel-base superalloy, the nickel-base superalloy containing a &ggr;″ tetragonal phase and comprising aluminum, titanium, tantalum, niobium, chromium, molybdenum, and the balance nickel, wherein the article has a time dependent crack propagation resistance of at least about 20 hours to failure at about 1100° F. in the presence of steam. The invention also includes a nickel-base superalloy for forming such and article and methods of forming the article and making the nickel-base superalloy.Type: ApplicationFiled: April 24, 2001Publication date: February 20, 2003Applicant: General Electric CompanyInventors: Michael Francis Henry, Elena Rozier Gearing, Samuel Vinod Thamboo, Sarwan Kumar Mannan, John Joseph deBarbadillo
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Patent number: 6478895Abstract: The sputter target deposits nickel from a binary alloy. The binary alloy contains, by weight percent, 9 to 15 titanium and the balance nickel and incidental impurities. The binary alloy has, by weight percent, 35 to 50 TiNi3 needle-like intermetallic phase and balance &agr;-nickel phase. The TiNi3 needle-like intermetallic phase and &agr;-nickel phase are formed from a eutectic decomposition. The &agr;-nickel phase has a grain size between 50 and 180 &mgr;m. The binary alloy has a Curie temperature of less than or equal to a temperature of 25° C. and exhibits paramagnetic properties at temperatures of 25° C. or lower.Type: GrantFiled: April 25, 2001Date of Patent: November 12, 2002Assignee: Praxair S.T. Technology, Inc.Inventors: Holger J. Koenigsmann, Paul S. Gilman, Thomas J. Hunt
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Publication number: 20020159911Abstract: The sputter target deposits nickel from a binary alloy. The binary alloy contains, by weight percent, 9 to 15 titanium and the balance nickel and incidental impurities. The binary alloy has, by weight percent, 35 to 50 TiNi3 needle-like intermetallic phase and balance &agr;-nickel phase. The TiNi3 needle-like intermetallic phase and &agr;-nickel phase are formed from a eutectic decomposition. The &agr;-nickel phase having a grain size between 50 and 180 &mgr;m. The binary alloy has a Curie temperature of less than or equal to a temperature of 25° C. and exhibits paramagnetic properties at temperatures of 25° C. or lower.Type: ApplicationFiled: April 25, 2001Publication date: October 31, 2002Inventors: Holger J. Koenigsmann, Paul S. Gilman, Thomas J. Hunt
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Patent number: 6444061Abstract: A process for producing a heat-resistant intermetallic compound Ni3Al foil having a room-temperature ductility, which comprises a first step of arc-melting an alloy having a chemical composition containing Ni as a main component and Al to form a starting rod, a second step of growing the starting rod in columnar crystal form by unidirectional solidification, a third step of cutting out the unidirectionally solidified rod to form a plate, and a fourth step of cold-rolling the plate cut at room temperature to form a foil. The invention can provide a process for producing a thin Ni3Al foil which has a thickness of 200 microns or less and which is excellent in high-temperature strength, oxidation and corrosion resistances and room-temperature ductility.Type: GrantFiled: October 20, 2000Date of Patent: September 3, 2002Assignee: Agency of National Research Institute for MetalsInventors: Toshiyuki Hirano, Masahiko Demura
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Patent number: 6436207Abstract: Improved targets for use in DC magnetron sputtering of nickel or like ferromagnetic face-centered cubic (FCC) metals are disclosed for forming metallization films having effective edge-to-edge deposition uniformity of 5% (3&sgr;) or better. Such targets may be characterized as having: (a) a homogeneous texture mix that is at least 20% of a <200> texture content and less than 50% of a <111>texture content, (b) an initial pass-through flux factor (%PTF) of about 30% or greater; and(c) a homogeneous grain size of about 200 &mgr;m or less.Type: GrantFiled: May 8, 2000Date of Patent: August 20, 2002Assignee: Applied Material, Inc.Inventors: Murali Abburi, Seshadri Ramaswami
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Patent number: 6428637Abstract: Method for producing a large, substantially hot tear-free superalloy gas turbine bucket useful in a large, land-based utility gas turbine engine, wherein a melt of a superalloy consisting essentially of, by weight: 13.7 to 14.3 percent chromium, 9.0 to 10.0 percent cobalt, 4.8 to 5.2 percent titanium, 2.8 to 3.2 percent aluminum, 2.8 to 4.3 percent tungsten, 1.0 to 1.5 percent molybdenum, 0.005 to 0.02 percent boron, 0 to 0.03 percent zirconium, 0.08 to 0.15 percent carbon, and 2.0 to 3.0 percent tantalum, or 1.0 to 1.5 percent columbium, or 2.0 to 2.5 percent hafnium, or 1.5 to 3.5 percent of a mixture of containing at least two of tantalum, columbium and hafnium, balance substantially nickel, is cast to produce said large gas turbine bucket.Type: GrantFiled: June 7, 1995Date of Patent: August 6, 2002Assignee: General Electric CompanyInventors: John H Wood, David A Shores, Norman R Lindblad
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Publication number: 20020068007Abstract: A Fe—Ni based permalloy comprises Ni: 30-85 wt %, C: not more than 0.015 wt %, Si: not more than 1.0 wt %, Mn: not more than 1.0 wt %, P: not more than 0.01 wt %, S: not more than 0.005 wt %, O: not more than 0.0060 wt %, Al: not more than 0.02 wt % and, if necessary, not more than 15 wt % of at least one selected from the group consisting of Mo, Cu, Co and Nb within a range of not more than 20 wt % in total.Type: ApplicationFiled: September 25, 2001Publication date: June 6, 2002Applicant: Nippon Yakin Kogyo Co., Ltd.Inventors: Tatsuya Itoh, Tsutomu Omori
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Patent number: 6350355Abstract: The object of this invention was to create starting copper cathodes which prevent a memory effect during copper electrolysis, achieving a high production output of electrolytic copper and which can also be manufactured from directly shaped copper sheeting material in the form of a coil. A suitable method of producing starting cathodes for processing copper sheet produced by conventional methods. The proposed starting cathodes are made of milled copper sheets with a thickness of 0.3 to 1.2 mm, is soft annealed after milling and has a strength of 210 to 240 N/mm2. The copper sheet is cut to the length and width determined by the dimensions of the electrolysis bath and has a flat, fat-free, burless surface. Ear strips of copper sheet with a thickness of 0.3 to 0.6 mm are mounted on the suspension side.Type: GrantFiled: May 31, 2000Date of Patent: February 26, 2002Assignee: Lamitref Industries N.V.Inventor: Leon Raphael Lucienne G. Cloostermans-Huwaert
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Patent number: 6348111Abstract: Fe—Ni alloy sheet having improved press-punching formability is produced by specifying the sulfide-forming elements [X%] and sulfur [%S] and by heating, prior to hot-working, to a temperature dependent upon the contents of these elements. The Fe—Ni alloy contains from 30 to 55% of Ni, not more than 0.8% of Mn, from 0.001 to 0.050% of S, from 0.005 to less than 0.5% of Ti, Mg, Ce and/or Ca, the balance being Fe and unavoidable impurities, and in which the product of the total content of the Ti, Mg, Ce and Ca and the total content of S ([%X]×[%S]) is limited to a range of from 0.00005 to 0.010. The heating temperature (T) is: 1050° C.≦T(°C.)≦{19500/[8.5−log[%X][%S]]}−350.Type: GrantFiled: March 2, 1999Date of Patent: February 19, 2002Assignee: Nippon Mining & Metals Co., Ltd.Inventors: Norio Yuki, Yoshihisa Kita
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Patent number: 6342114Abstract: A nickel/vanadium sputter target for depositing magnetic nickel is provided having high homogeneity, high purity and an ultra-low level of alpha emission. Source materials having high purity and alpha emissions of equal or less than 10−2 counts/cm2-hr are melted and cast under a vacuum and low pressure, hot or cold rolled, and heat treated to form a sputter target having an alpha emission of equal or less than 10−2counts/cm2-hr, and preferably less than 10−3 counts/cm2-hr. From this target may be deposited a thin film of magnetic nickel having an alpha emission equal or less than 10−2 counts/cm2-hr, preferably less than 10−3 counts/cm2-hr and more preferably less than 10−4 counts/cm2-hr.Type: GrantFiled: March 31, 1999Date of Patent: January 29, 2002Assignee: Praxair S.T. Technology, Inc.Inventors: Raymond K. F. Lam, Tony Sica
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Patent number: 6328827Abstract: In order to obtain sheets made of a nickel-based superalloy of type 718 having properties of superplasticity, the sheets are manufactured with a final cycle comprising the steps of: a) solution treatment at 1060° C. for 15 minutes; b) precipitation at 730° C. to 800° C. for 1 to 2 hours; c) cold rolling at a ratio greater than 60%, and d) recrystallization at 900° C. for 30 minutes. Superplastic deformation of such sheets is carried out at about 970±10° C. and under pressures inducing stresses between 45 and 60 MPa.Type: GrantFiled: July 5, 1995Date of Patent: December 11, 2001Assignee: Societe Nationale d'Etude et de Construction de Moteurs d'Aviation “Snecma”Inventors: Mohamed Bouzidi, Philippe Caburet, Pierre Clement, André Claude Félix Collot, Jean-Lou Lebrun, Benoit Marty
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Patent number: 6322643Abstract: An Ni-base heat resistant alloy, has a composition which contains, by weight, Cr: from 12.0 to 14.3%, Co: from 8.5 to 11.0%, Mo: from 1.0 to 3.5%, W: from 3.5 to 6.2%, Ta: from 3.0 to 5.5%, Al: from 3.5 to 4.5%, Ti: from 2.0 to 3.2%, C: from 0.04 to 0.12%, B: from 0.005 to 0.05%, and the balance substantially Ni and inevitable impurities. A large-size casting, as well as a large-size turbine blade, having a columnar crystalline Ni-base heat-resistant alloy formed from the Ni-base heat-resistant alloy, have sound cast surfaces and a sound internal structure.Type: GrantFiled: November 16, 1999Date of Patent: November 27, 2001Assignees: Mitsubishi Materials Corporation, Mitsubishi Heavy Industries, Ltd.Inventors: Akira Mitsuhashi, Michi Misumi, Saburou Wakita, Hisataka Kawai, Kouji Takahashi, Ikuo Okada
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Patent number: 6068714Abstract: The process for making a forged nickel-base superalloy part for use in the 700-900.degree. C. range which includes the steps of:a) providing a nickel-base superalloy having the following composition:______________________________________ percentage by weight ______________________________________ Cr 15.5-18 Co 14.0-15.5 Mo 2.75-3.25 W 1.00-1.50 Ti 4.75-5.25 Al 2.25-2.75 Zr 0.025-0.050 B 0.01-0.02 C 0.006-0.025 Cu .ltoreq.0.10 Mn .ltoreq.0.15 Fe .ltoreq.0.50 Si .ltoreq.0.2 P .ltoreq.0.05 S .ltoreq.0.05 Ni balance ______________________________________and eventual impurities, where the weight ration B/C is equal to or greater than 1.1;b) forging said nickel-base superalloy to obtain an as-forged part;c) submitting the as-forged part of step b) to a solution heat treatment at a temperature ranging from 10 to 30.degree. C. above the .gamma.' phase solvus temperature;d) quenching the solution heat treated forged part resulting from step c) at a quenching rate above 100.degree. C.Type: GrantFiled: April 16, 1998Date of Patent: May 30, 2000Assignee: TurbomecaInventor: Dominique Fran.cedilla.ois Fournier
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Patent number: 6053995Abstract: A method of producing an age precipitation-containing rare earth metal-nickel alloy of AB.sub.5 type having a composition represented by a formula (1)R(ni.sub.1-x M.sub.x).sub.5+y (1)wherein R stands for a rare earth element including Y or mixtures thereof, M stands for Co, Al, Mn, Fe, Cu, Zr, Ti, Mo, W, B, or mixtures thereof, x satisfies the relation of 0.05.ltoreq.x.ltoreq.0.5, and y satisfies the relation of -0.45.ltoreq.y.ltoreq.0.45, the alloy containing a precipitated phase having an average size of 0.1 to 20 .mu.m as measured along the longitudinal axis is disclosed. The method includes the steps of subjecting a raw alloy material having a composition represented by the formula (1) to a solid solution treatment at a temperature of not less than 1000.degree. C. and ageing the alloy material subjected to said solution heat treatment at a temperature T (.degree. C) of not less than 700.degree. C. and less than 1000.degree. C.Type: GrantFiled: July 3, 1996Date of Patent: April 25, 2000Assignee: Santoku Metal Industry Co., Ltd.Inventors: Yuji Tanibuchi, Kazuhiko Yamamoto, Chikara Okada
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Patent number: 6036791Abstract: An Ni-base heat resistant alloy, has a composition which contains, by weight, Cr: from 12.0 to 14.3%, Co: from 8.5 to 11.0%, Mo: from 1.0 to 3.5%, W: from 3.5 to 6.2%, Ta: from 3.0 to 5.5%, Al: from 3.5 to 4.5%, Ti: from 2.0 to 3.2%, C: from 0.04 to 0.12%, B: from 0.005 to 0.05%, and the balance substantially Ni and inevitable impurities. A large-size casting, as well as a large-size turbine blade, having a columnar crystalline Ni-base heat-resistant alloy formed from the Ni-base heat-resistant alloy, have sound cast surfaces and a sound internal structure.Type: GrantFiled: January 23, 1998Date of Patent: March 14, 2000Assignees: Mitsubishi Materials Corporation, Mitsubishi Heavy Industries, Ltd.Inventors: Akira Mitsuhashi, Michi Misumi, Saburou Wakita
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Patent number: 5938863Abstract: A high strength nickel base superalloy article having a machined surface is disclosed. The superalloy comprises, in weight percent, 1.2-3.5 Al, 3.0-7.0 Ti, 12.0-20.0 Cr, 2.0-3.9 Mo, 10.0-20.0 Co, 0-4.5 W, 0.005-0.025 C, 0.005-0.05 B, 0.01-0.1 Zr, 0-0.005 Mg, 0-1.0 Ta, 0-1.0 Nb, 0-2.0 Fe, 0-0.3 Hf, 0-0.02 Y, 0-0.1 V, 0-1.0 Re, balance essentially Ni. The superalloy further comprises a plurality of discrete carbides essentially free from molybdenum for increased fatigue strength.Type: GrantFiled: December 17, 1996Date of Patent: August 17, 1999Assignee: United Technologies CorporationInventor: David R. Malley
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Patent number: 5900334Abstract: The present invention provides a hydrogen occluding alloy exhibiting high hydrogen absorption and desorption rates, and excellent initial activation in practical use, and a method of making it. There is provided a hydrogen occluding alloy having a composition comprising, by wt %, 32 to 38% of rare earth elements essentially consisting of La and/or Ce, 0.5 to 3.5% of Al, 0.5 to 10% of Mn, 0.005 to 0.5% of hydrogen, optionally 0.1 to 17% of Co, and the balance being Ni and unavoidable impurities; wherein the alloy has a microstructure characterized in that fine rare earth element hydride is dispersively distributed in a matrix having a CaCu.sub.5 -type crystal structure in a ratio of 0.5 to 20% by area. There are also provided electrodes and batteries containing such alloys, and methods of making and using such electrodes and batteries.Type: GrantFiled: May 7, 1997Date of Patent: May 4, 1999Assignee: Mitsubishi Materials CorporationInventors: Masahiro Wada, Yoshio Takizawa
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Patent number: 5840166Abstract: A rare earth metal-nickel hydrogen storage alloy having a composition represented by the formula (1) (R.sub.1-x L.sub.x) (Ni.sub.1-y M.sub.y).sub.z . . . (1) (R: La, Ce, Pr, Nd; L: Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Y, Sc, Mg, Ca; M: Co, Al, Mn, Fe, Cu, Zr, Ti, Mo, Si, V, Cr, Nb, Hf, Ta, W, B, C; 0.05.ltoreq.x.ltoreq.0.4, 0.ltoreq.y.ltoreq.0.5, 3.0.ltoreq.z<4.5), the alloy including in an amount of not less than 30 volume % and less than 95 volume % thereof crystals each containing not less than 5 and less than 25 antiphase boundaries extending perpendicular to C-axis of a crystal grain of the alloy per 20 nm along the C-axis, not less than 60% and less than 95% of added amount of the element represented by L in the formula (1) being arranged in antiphase areas, and a method for producing the same.Type: GrantFiled: March 7, 1997Date of Patent: November 24, 1998Assignee: Santoku Metal Industry Co. Ltd.Inventor: Akihito Kaneko
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Patent number: H2245Abstract: A precipitation hardenable nickel base alloy that provides a novel combination of elevated temperature strength, ductility, and reduced notch sensitivity at temperatures up to about 1300° F. is described. The alloy contains, in weight percent, about Carbon 0.10 max. Manganese 0.35 max. Silicon 0.2-0.7 Phosphorus 0.03 max. Sulfur 0.015 max. Chromium 12-20 Molybdenum 4 max. Tungsten 6 max. Cobalt 5-12 Iron 14 max. Titanium 0.4-1.4 Aluminum 0.6-2.6 Niobium 3-7 Boron 0.003-0.015 the balance being nickel and usual impurities. An article made from the alloy and a method of making the alloy are also disclosed.Type: GrantFiled: March 12, 2008Date of Patent: August 3, 2010Assignee: CRS Holdings, Inc.Inventors: Karl A. Heck, Richard B. Frank