Ageing, Solution Treating (i.e., For Hardening), Precipitation Strengthening Or Precipitation Hardening Patents (Class 148/607)
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Patent number: 10934847Abstract: A steam turbine rotor blade includes a protrusion portion (7) which is provided on a tip end portion of a blade body (61), on which a leading edge portion (61a) is formed, in a blade height direction and protrudes from a suction-side surface (612) toward the leading edge portion (61a) side, and a transition-region seal member which is provided so as to cover at least a portion of a base end-side surface of the protrusion portion (7) and a leading edge-side transition region, which faces the leading edge portion (61a) side, of a connection portion between the protrusion portion (7) and the suction-side surface (612), the transition-region seal member being formed of a material having a hardness higher than that of the blade body (61).Type: GrantFiled: April 14, 2017Date of Patent: March 2, 2021Assignee: MITSUBISHI POWER, LTD.Inventors: Shohei Danno, Takashi Maruyama, Keiichiro Miyajima
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Patent number: 10626487Abstract: An austenitic heat-resistant cast steel includes 0.1% to 0.6% by mass of C, 1.0% to 3.0% by mass of Si, 0.5% to 1.5% by mass of Mn, 0.05% by mass or less of P, 0.05% to 0.3% by mass of S, 9% to 16% by mass of Ni, 14% to 20% by mass of Cr, 0.1% to 0.2% by mass of N, and the balance of iron and inevitable impurities, in which a matrix structure of the austenitic heat-resistant cast steel is composed of austenite crystal grains, and a ferrite phase is dispersed and interposed between the austenite crystal grains so as to cover the austenite crystal grains.Type: GrantFiled: March 18, 2014Date of Patent: April 21, 2020Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, AISIN TAKAOKA CO., LTD.Inventors: Kazumi Ohtake, Takamichi Ueda, Yoshikazu Genma, Takahiro Sato, Hiroshi Fujii
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Patent number: 10589342Abstract: A method of forming a fastener includes inserting a blank precursor into a bore of a forming die having an enlarged bore portion, applying a first axial compression force to the blank precursor, and forming a cold-worked head section and an enlarged shank portion on the blank precursor corresponding to the enlarged bore portion. The enlarged shank portion has a nominal shank portion extending therefrom. The method additionally includes inserting the nominal shank portion into a bore of a final reduction die, applying a second axial compression force to the enlarged shank portion, and urging the enlarged shank portion into the bore of the final reduction die. The method includes reducing a cross-sectional area of the enlarged shank portion by approximately 2 to 5 percent to form a cold-worked shank section.Type: GrantFiled: April 5, 2017Date of Patent: March 17, 2020Assignee: The Boeing CompanyInventor: Steven G. Keener
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Patent number: 10486223Abstract: A method for manufacturing a golf club head includes providing a club head body produced by electric smelting an alloy base material including 0.04-0.07 wt % of carbon, 0.5-1.0 wt % of manganese, 0.5-1.0 wt % of silicon, less than 0.04 wt % of phosphorus, less than 0.03 wt % of sulfur, 15-17.7 wt % of chromium, 3.6-5.1 wt % of nickel, 2.8-3.5 wt % of copper, with the rest being iron and inevitable impurities. A solid solution treatment is proceeded at 1020-1080° C. for 80-100 minutes to form austenite and martensite in the club head body. A deep cooling treatment is proceeded between ?120° C. and ?80° C. for 7-9 hours to turn the austenite in the club head body into martensite. An aging treatment is proceeded on the club head body at 460-500° C. for 210-270 minutes to provide a hardness of HRC 36-46. A hosel is heated with high frequency waves at 900-1000° C. to posses a hardness lower than HRC 20.Type: GrantFiled: July 19, 2017Date of Patent: November 26, 2019Assignee: Fusheng Precision Co., Ltd.Inventors: Bao-Bin Li, Zhi-Nan Lin
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Patent number: 9416436Abstract: The present invention aim at providing a steel for steam turbine blades which is excellent in terms of strength and toughness. The steel of the present invention has a composition which contains, in terms of % by mass, 0.02-0.10% of C, up to 0.25% of Si, 0.001-0.10% of Mn, up to 0.010% of P, up to 0.010% of S, 8.5-10.0% of Ni, 10.5-13.0% of Cr, 2.0-2.5% of Mo, 0.001-0.010% of N, 1.15-1.50% of Al, less than 0.10% of Cu, up to 0.20% of Ti, and the remainder being incidental impurities and Fe, and which satisfies 6.0?Ni/Al?8.0, 9.0?Nieq?11.0 and 17.0?Creq?19.0, in which Nieq=[Ni]+0.11[Mn]?0.0086([Mn]2)+0.44[Cu]+18.4[N]+24.5[C] Creq=[Cr]+1.21[Mo]+0.48[Si]+2.2[Ti]+2.48[A1].Type: GrantFiled: April 24, 2013Date of Patent: August 16, 2016Assignee: DAIDO STEEL CO., LTD.Inventors: Hiroyuki Takabayashi, Shigeki Ueta
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Publication number: 20150136280Abstract: This method for setting aging conditions is provided with: a step for acquiring a master curve (20) indicating the relationship between an aging condition parameter and a material strength parameter by executing an aging process on a standard material; a step for acquiring a fitting point (A) indicating the value of the material strength parameter of a subject material of which the chemical component parameters and/or metal structure parameters differ from those of the standard material; a step for acquiring a corrected aging curve (30) by correcting the master curve (20) in a manner so that a portion of the master curve (20) corresponds to the fitting point (A); and a step for setting aging conditions for the subject material on the basis of the corrected aging curve (30).Type: ApplicationFiled: August 19, 2013Publication date: May 21, 2015Applicant: MITSUBISHI HITACHI POWER SYSTEMS, LTD.Inventors: Yuichi Hirakawa, Takayuki Kurimura, Hiroharu Oyama
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Publication number: 20150075681Abstract: A martensitic stainless steel alloy is strengthened by copper-nucleated nitride precipitates. The alloy includes, in combination by weight percent, about 10.0 to about 12.5 Cr, about 2.0 to about 7.5 Ni, up to about 17.0 Co, about 0.6 to about 1.5 Mo, about 0.5 to about 2.3 Cu, up to about 0.6 Mn, up to about 0.4 Si, about 0.05 to about 0.15 V, up to about 0.10 N, up to about 0.035 C, up to about 0.01 W, and the balance Fe and incidental elements and impurities. The nitride precipitates may be enriched by one or more transition metals.Type: ApplicationFiled: August 18, 2014Publication date: March 19, 2015Inventors: James A. Wright, Gregory B. Olson, Weija Tang
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Publication number: 20150076386Abstract: An iron-based alloy includes (in weight percent) carbon from about 1 to about 2 percent; manganese up to about 1 percent; silicon up to about 1 percent; nickel up to about 4 percent; chromium from about 10 to about 25 percent; molybdenum from about 5 to about 20 percent; tungsten up to about 4 percent; cobalt from about 17 to about 23 percent; vanadium up to about 1.5 percent; boron up to about 0.2 percent; sulfur up to about 0.03 percent; nitrogen up to about 0.4 percent; phosphorus up to about 0.06 percent; niobium up to about 4 percent; iron from about 35 to about 55 percent; and incidental impurities. The chromium/molybdenum ratio of the iron-based alloy is from about 1 to about 2.5. The alloy is suitable for use in elevated temperature applications, such as valve seat inserts for combustion engines.Type: ApplicationFiled: September 19, 2013Publication date: March 19, 2015Applicant: L.E. Jones CompanyInventors: Cong Yue Qiao, David Doll, Todd Trudeau, Peter Vennema
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Publication number: 20150034037Abstract: An iron-based alloy includes, in weight percent, carbon from about 2 to about 3 percent; manganese from about 0.1 to about 0.4 percent; silicon from about 0.3 to about 0.8 percent; chromium from about 11.5 to about 14.5 percent; nickel from about 0.05 to about 0.6 percent; vanadium from about 0.8 to about 2.2 percent; molybdenum from about 4 to about 7 percent; tungsten from about 3 to about 5 percent; niobium from about 1 to about 3 percent; cobalt from about 3 to about 5 percent; boron from zero to about 0.2 percent; and the balance containing iron and incidental impurities. The alloy is suitable for use in elevated temperature applications such as in valve seat inserts for combustion engines.Type: ApplicationFiled: July 31, 2013Publication date: February 5, 2015Applicant: L. E. Jones CompanyInventors: Cong Yue Qiao, Peter Vennema, Douglas W. Dooley, David Doll
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Patent number: 8808474Abstract: A method fabricating a stainless martensitic steel, including electroslag remelting then cooling an ingot of the steel, then at least one austenitic thermal cycle heating the ingot above its austenitic temperature followed by a cooling. During each cooling: if the cooling is not followed by an austenitic thermal cycle, holding the ingot at a holding temperature included in the ferritic-pearlitic transformation nose for a hold time longer than sufficient for transforming the austenite into a ferritic-pearlitic structure in the ingot as completely as possible at the holding temperature; if the cooling is followed by an austenitic thermal cycle, before its minimum temperature falls below the martensitic transformation start temperature, the ingot is either held throughout the period between the two austenitic thermal cycles at a temperature above the austenitic transformation completion temperature on heating, or held at the holding temperature included in the ferritic-pearlitic transformation nose.Type: GrantFiled: October 11, 2010Date of Patent: August 19, 2014Assignee: SNECMAInventors: Laurent Ferrer, Patrick Philipson
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Patent number: 8663403Abstract: A precipitation-hardened stainless steel alloy comprises, by weight: about 14.0 to about 16.0 percent chromium; about 6.0 to about 8.0 percent nickel; about 1.25 to about 1.75 percent copper; greater than about 1.5 to about 2.0 percent molybdenum; about 0.001 to about 0.025 percent carbon; niobium in an amount greater than about twenty times that of carbon; and the balance iron and incidental impurities. The alloy has an aged microstructure and an ultimate tensile strength of at least about 1100 MPa and a Charpy V-notch toughness of at least about 69 J. In one embodiment, the aged microstructure includes martensite and not more than about 10% reverted austenite. In another embodiment, the alloy includes substantially all martensite and substantially no reverted austenite. The alloy is useful for making turbine airfoils.Type: GrantFiled: June 8, 2011Date of Patent: March 4, 2014Assignee: General Electric CompanyInventors: Jianqiang Chen, Thomas Michael Moors, Jon Conrad Schaeffer
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Patent number: 8647448Abstract: A steel piston ring and a steel cylinder liner are described which comprise as the main body a steel composition which has good nitridability. The steel composition consists of the following elements: 0-0.5 weight % B, 0.5-1.2 weight % C, 4.0-20.0 weight % Cr, 0-2.0 weight % Cu, 45.30-91.25 weight % Fe, 0.1-3.0 weight % Mn, 0.1-3.0 weight % Mo, 0-0.05 weight % Nb, 2.0-12.0 weight % Ni, 0-0.1 weight % P, 0-0.05 weight % Pb, 0-0.05 weight % S, 2.0-10.0 weight % Si, 0-0.05 weight % Sn, 0.05-2.0 weight % V, 0-0.2 weight % Ti and 0-0.5 weight % W. The steel piston ring and the steel cylinder liner can be manufactured in a casting process using the machinery and technology employed for the manufacture of cast iron parts.Type: GrantFiled: March 25, 2010Date of Patent: February 11, 2014Assignee: Federal-Mogul Burscheid GmbHInventor: Laszlo Pelsoeczy
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Publication number: 20130312880Abstract: Provided is a duplex stainless steel having a high strength and a high toughness. A stainless steel according to the present invention includes: a chemical composition containing, in mass percent, C: at most 0.030%, Si: 0.20 to 1.00%, Mn: at most 8.00%, P: at most 0.040%, S: at most 0.0100%, Cu: more than 2.00% and at most 4.00%, Ni: 4.00 to 8.00%, Cr: 20.0 to 30.0%, Mo: at least 0.50% and less than 2.00%, N: 0.100 to 0.350%, and sol. Al: at most 0.040%, the balance being Fe and impurities; and a structure, wherein a rate of ferrite in the structure is 30 to 70%, and a hardness of the ferrite in the structure is at least 300 Hv10gf.Type: ApplicationFiled: February 10, 2012Publication date: November 28, 2013Applicant: NIPPON STEEL & SUMITOMO METAL CORORATIONInventors: Daisuke Motoya, Masahiko Hamada, Hisashi Amaya, Hiroyuki Nagayama, Kenta Yamada
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Patent number: 8506729Abstract: An austenitic stainless steel hot-rolled steel material can be provided which has sea-water resistance and strength superior to conventional steel. Low-temperature toughness can be maintained, which is preferable in a structural member of speedy craft. The steel material can include an austenitic stainless steel hot-rolled steel material which excels in the properties of corrosion resistance, proof stress, and low-temperature toughness. In such austenitic stainless steel hot-rolling steel material, e.g., PI [=Cr+3.3(Mo+0.5W)+16N] ranges from 35 to 40, ? cal [=2.9 (Cr+0.3Si+Mo+0.5W)?2.6 (Ni+0.3Mn+0.25Cu+35C+20N)?18] ranges from ?6 to +2, and a 0.2% proof stress at room temperature is not less than 550 MPa, Charpy impact value measured using a V-notch test piece at ?40° C. is not less than 100 J/cm2, and the pitting potential measured in a deaerated aqueous solution of 10% NaCl at 50° C. (Vc?100) is not less than 500 mV (as it relates to saturated Ag/AgCl).Type: GrantFiled: January 13, 2012Date of Patent: August 13, 2013Assignee: Nippon Steel & Sumikin Stainless Steel CorporationInventors: Yuusuke Oikawa, Shinji Tsuge, Shigeo Fukumoto, Kazuhiro Suetsugu, Ryo Matsuhashi, Hiroshige Inoue
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Patent number: 8479549Abstract: A method of producing a seamless, tubular product includes centrifugally casting a corrosion resistant alloy into a tubular workpiece having an inner diameter and an outer diameter. The method then removes material from the inner diameter of the workpiece and subjects the workpiece to at least about a 25% wall reduction at a temperature below a recrystallization temperature of the workpiece using a metal forming process. The metal forming process includes radial forging, rolling, pilgering, and/or flowforming.Type: GrantFiled: August 13, 2010Date of Patent: July 9, 2013Assignee: Dynamic Flowform Corp.Inventor: Matthew V. Fonte
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Publication number: 20130160905Abstract: A method for producing a tempered martensitic heat resistant steel for high temperature applications at an application temperature of up to 650° C. and to a steel produced by the method. The use of the steel in the production of components for high temperature applications such as turbine blades or casings, bolting and boiler tubes, heat exchangers or other elements in power generation systems.Type: ApplicationFiled: June 10, 2011Publication date: June 27, 2013Applicant: TATA STEEL NEDERLAND TECHNOLOGY BVInventors: Urszula Alicja Sachadel, Peter Francis Morris, Philip Clarke, Cheng Liu
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Patent number: 8317944Abstract: One or more embodiments relates to a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650° C. The 9 Cr-1 Mo steel has a tempered martensite microstructure and is comprised of both large (0.5-3 ?m) primary titanium carbides and small (5-50 nm) secondary titanium carbides in a ratio of. from about 1:1.5 to about 1.5:1. The 9 Cr-1 Mo steel may be fabricated using exemplary austenizing, rapid cooling, and tempering steps without subsequent hot working requirements. The 9 Cr-1 Mo steel exhibits improvements in total mass gain, yield strength, and time-to-rupture over ASTM P91 and ASTM P92 at the temperature and time conditions examined.Type: GrantFiled: October 26, 2011Date of Patent: November 27, 2012Assignee: U.S. Department of EnergyInventors: Paul D. Jablonski, David Alman, Omer Dogan, Gordon Holcomb, Christopher Cowen
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Patent number: 8313592Abstract: A thermal mechanical treatment method includes hot working a precipitation hardening martensitic stainless steel, quenching the stainless steel, and aging the stainless steel. According to certain embodiments, the thermal mechanical treatment does not include solution heat treating the stainless steel prior to aging or cryogenically cooling the stainless steel. An article includes a precipitation hardening martensitic stainless steel having a process history that includes hot working the stainless steel, quenching the stainless steel, and aging the stainless steel. According to certain embodiments, the process history does not include solution heat treating the stainless steel prior to aging or cryogenically cooling the stainless steel.Type: GrantFiled: March 15, 2011Date of Patent: November 20, 2012Assignee: ATI Properties, Inc.Inventors: Wei-Di Cao, Erin T. McDevitt
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Patent number: 8273191Abstract: Provided is a high-strength stainless steel material having less deterioration in mechanical strength and improved workability, particularly bending workability compared with conventional steel materials. The high-strength stainless steel material of the present invention has a specific composition, has a metal microstructure composed of two phases, that is a ferrite phase and a martensite phase, has a ?max of from 50 to 85, the ?max being represented by the following equation (1): ?max=420Wc+470WN+23WNi+7WMn?11.5WCr?11.5WSi+189??(1) wherein, Wc, WN, WNi, WMn, WCr, and WSi; represent contents (unit: mass %) of C, N, Ni, Mn, Cr, and Si relative to the total mass of the stainless steel material, respectively; and has a difference of 300 HV or less in hardness between the ferrite phase and the martensite phase.Type: GrantFiled: February 2, 2009Date of Patent: September 25, 2012Assignee: Nisshin Steel Co., Ltd.Inventors: Naoki Hirakawa, Hiroshi Fujimoto, Satoshi Suzuki
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Patent number: 8246767Abstract: The invention relates to a composition and heat treatment for a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650° C. The novel combination of composition and heat treatment produces a heat treated material containing both large primary titanium carbides and small secondary titanium carbides. The primary titanium carbides contribute to creep strength while the secondary titanium carbides act to maintain a higher level of chromium in the finished steel for increased oxidation resistance, and strengthen the steel by impeding the movement of dislocations through the crystal structure. The heat treated material provides improved performance at comparable cost to commonly used high-temperature steels such as ASTM P91 and ASTM P92, and requires heat treatment consisting solely of austenization, rapid cooling, tempering, and final cooling, avoiding the need for any hot-working in the austenite temperature range.Type: GrantFiled: September 12, 2008Date of Patent: August 21, 2012Assignee: The United States of America, as represented by the United States Department of EnergyInventors: Paul D. Jablonski, David Alman, Omer Dogan, Gordon Holcomb, Christopher Cowen
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Patent number: 8172959Abstract: There are provided an austenitic stainless steel having high stress corrosion crack resistance, characterized by containing, in percent by weight, 0.030% or less C, 0.1% or less Si, 2.0% or less Mn, 0.03% or less P, 0.002% or less S, 11 to 26% Ni, 17 to 30% Cr, 3% or less Mo, and 0.01% or less N, the balance substantially being Fe and unavoidable impurities; a manufacturing method for an austenitic stainless steel, characterized in that a billet consisting of the said austenitic stainless steel is subjected to solution heat treatment at a temperature of 1000 to 1150° C.; and a pipe and a in-furnace structure for a nuclear reactor to which the said austenitic stainless steel is applied.Type: GrantFiled: January 13, 2005Date of Patent: May 8, 2012Assignees: Mitsubishi Heavy Industries, Ltd., The Tokyo Electric Power Company, Inc.Inventors: Yasuhiro Sakaguchi, Toshihiko Iwamura, Hiroshi Kanasaki, Hidehito Mimaki, Masaki Taneike, Shunichi Suzuki, Kenrou Takamori, Suguru Ooki, Naoki Anahara, Naoki Hiranuma, Toshio Yonezawa
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Patent number: 8168014Abstract: The method for manufacturing a martensitic stainless pipe includes heating the steel pipe until the external surface temperature thereof reaches a predetermined temperature not lower than A3 transformation point+20° C. and not higher than 980° C. The heated steel pipe is first water cooled until the external surface temperature thereof reaches a predetermined temperature not lower than 350° C. The water cooled steel pipe is air cooled until the external surface temperature thereof reaches a predetermined temperature not higher than 250° C. The air cooled steel pipe is either water or air cooled until the external surface temperature thereof reaches normal temperature. The cooling rate of the steel pipe in the first cooling step is determined according to the wall thickness of the steel pipe so that the amount of heat recuperation for the external surface temperature of the steel pipe in the second cooling step is not higher than 50° C.Type: GrantFiled: March 26, 2008Date of Patent: May 1, 2012Assignee: Sumitomo Metal Industries, Ltd.Inventor: Nobuyuki Mori
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Patent number: 8097097Abstract: Disclosed is a stainless steel containing, by mass, 0.05% or less carbon, 1.5 to smaller than 3.5% Si, 3.0% or less Mn, 6.0 to 12.0% Cr, 4.0 to 10.0% Ni, 10.0% or less Co, 6.0% or less Cu, 0.5 to 3.0% Ti, 0 to 2.0% Al, less than 0.4% Mo, not more than 0.01% nitrogen, and the balance of Fe and unavoidable impurities. Preferably, it has a hardness of not lower than 59 HRC and may contain not more than 1.0% Nb and/or not more than 1.0% Ta. Alternatively, the stainless steel may further contain not more than 0.1% of Zr. The process for producing the steel includes producing a steel having a composition as described above by a consumable electrode remelting process, and then subjecting the steel to a solution treatment at a temperature of 1000 to 1150° C. and an aging treatment at a temperature of 400 to 550° C., thereby aging the stainless steel to a hardness of not lower than 59 HRC.Type: GrantFiled: December 22, 2008Date of Patent: January 17, 2012Assignee: Hitachi Metals Ltd.Inventors: Yoshiyuki Inoue, Fumio Tohyama
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Patent number: 8097098Abstract: The invention concerns martensitic stainless steel, characterized in that its composition in weight percentages is as follows: 9%=Cr=13%; 1.5%=Mo=3%; 8%=Ni=14%; 1%=Al=2%; 0.5%=Ti=1.5% with AI+Ti=2.25%; traces=Co=2%; traces=W=1% with Mo+(W/2)=3%; traces=P=0.02%; traces=S=0.0050%; traces=N=0.0060%; traces=C=0.025%; traces=Cu=0.5%; traces=Mn=3%; traces=Si=0.25%; traces=O=0.0050%; and is such that: Ms (° C.)=1302 42 Cr 63 Ni 30 Mo+20AI-15W-33Mn-28Si-30Cu-13Co+10 Ti=50Cr eq/Ni eq=1.05 with Cr eq (%)=Cr+2Si+Mo+1.5 Ti+5.5 AI+0.6W Ni eq (%)=2Ni+0.5 Mn+3O C+25 N+Co+0.3 Cu. The invention also concerns a method for making a mechanical part using said steel, and the resulting part.Type: GrantFiled: June 26, 2006Date of Patent: January 17, 2012Assignee: Aubert & DuvalInventor: Jacques Montagnon
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Publication number: 20110232809Abstract: A precipitation-hardened stainless steel alloy comprises, by weight: about 14.0 to about 16.0 percent chromium; about 6.0 to about 8.0 percent nickel; about 1.25 to about 1.75 percent copper; greater than about 1.5 to about 2.0 percent molybdenum; about 0.001 to about 0.025 percent carbon; niobium in an amount greater than about twenty times that of carbon; and the balance iron and incidental impurities. The alloy has an aged microstructure and an ultimate tensile strength of at least about 1100 MPa and a Charpy V-notch toughness of at least about 69 J. In one embodiment, the aged microstructure includes martensite and not more than about 10% reverted austenite. In another embodiment, the alloy includes substantially all martensite and substantially no reverted austenite. The alloy is useful for making turbine airfoils.Type: ApplicationFiled: June 8, 2011Publication date: September 29, 2011Applicant: GENERAL ELECTRIC COMPANYInventors: Jianqiang Chen, Thomas Michael Moors, Jon Conrad Schaeffer
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Patent number: 7985306Abstract: A precipitation-hardened stainless steel alloy comprises, by weight: about 14.0 to about 16.0 percent chromium; about 6.0 to about 7.0 percent nickel; about 1.25 to about 1.75 percent copper; about 0.5 to about 2.0 percent molybdenum; about 0.025 to about 0.05 percent carbon; niobium in an amount greater than about twenty times to about twenty-five times that of carbon; and the balance iron and incidental impurities. The alloy has an aged microstructure and an ultimate tensile strength of at least about 1100 MPa and a Charpy V-notch toughness of at least about 69 J. The aged microstructure includes martensite and not more than about 10% reverted austenite and is useful for making turbine airfoils.Type: GrantFiled: February 4, 2009Date of Patent: July 26, 2011Assignee: General Electric CompanyInventors: Jianqiang Chen, Thomas Michael Moors, Jon Conrad Schaeffer
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Publication number: 20110094637Abstract: A martensitic stainless steel alloy is strengthened by copper-nucleated nitride precipitates. The alloy includes, in combination by weight percent, about 10.0 to about 12.5 Cr, about 2.0 to about 7.5 Ni, up to about 17.0 Co, about 0.6 to about 1.5 Mo, about 0.5 to about 2.3 Cu, up to about 0.6 Mn, up to about 0.4 Si, about 0.05 to about 0.15 V, up to about 0.10 N, up to about 0.035 C, up to about 0.01 W, and the balance Fe and incidental elements and impurities. The nitride precipitates may be enriched by one or more transition metals.Type: ApplicationFiled: April 13, 2009Publication date: April 28, 2011Applicant: QUESTEK INNOVATIONS LLCInventors: James A. Wright, Gregory B. Olson, Weija Tang
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Patent number: 7931758Abstract: A thermal mechanical treatment method includes hot working a precipitation hardening martensitic stainless steel, quenching the stainless steel, and aging the stainless steel. According to certain embodiments, the thermal mechanical treatment does not include solution heat treating the stainless steel prior to aging or cryogenically cooling the stainless steel. An article includes a precipitation hardening martensitic stainless steel having a process history that includes hot working the stainless steel, quenching the stainless steel, and aging the stainless steel. According to certain embodiments, the process history does not include solution heat treating the stainless steel prior to aging or cryogenically cooling the stainless steel.Type: GrantFiled: July 28, 2008Date of Patent: April 26, 2011Assignee: ATI Properties, Inc.Inventors: Wei-Di Cao, Erin T. McDevitt
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Patent number: 7926180Abstract: A method for making gas and liquid storage tanks such as automotive fuel tanks includes providing two or more blanks of air hardenable martensitic stainless steel in the annealed condition. The steel blanks have a thickness in the range of 0.5-5.0 mm., and are formed utilizing stamping, forging, pressing, or roller forming techniques or the like into the form of a tank shell components. The shell components are hardened and assembled into a storage tank. The shell components are hardened by application of heat, preferably to between 950° C. and 1100° C. for standard air hardenable martensitic stainless steels. Thereafter, the automotive fuel tank is preferably cooled at a rate greater than 25° C. per minute to achieve a Rockwell C hardness of at least 39. The automotive fuel tank may undergo additional heat treating processes including high temperature or low temperature tempering processes which may incorporate electro-coating.Type: GrantFiled: October 4, 2006Date of Patent: April 19, 2011Inventors: Edward J. McCrink, Danny Codd
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Patent number: 7901519Abstract: A precipitation hardenable martensitic stainless steel that includes, in percent by weight, 11.0 to 12.5 percent chromium, 1.0 to 2.5 percent molybdenum, 0.15 to 0.5 percent titanium, 0.7 to 1.5 percent aluminum, 0.5 to 2.5 percent copper, 9.0 to 11.0 percent nickel, up to 0.02 percent carbon, up to 2.0 percent tungsten, and up to 0.001 percent boron. Articles formed from the stainless steel and methods of forming the same are also disclosed.Type: GrantFiled: December 10, 2003Date of Patent: March 8, 2011Assignee: ATI Properties, Inc.Inventor: Wei-Di Cao
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Patent number: 7849599Abstract: A process to manufacture an oilfield component comprises selectively reinforcing a base material with an age-hardenable clad material and age-hardening the clad material for a selected time and at a selected temperature profile, wherein the age-hardening results in the clad material developing a selected strength gradient. A body of a ram blowout preventer comprises, a low-ally base material, a vertical bore through the body, and a horizontal bore through the body intersecting the vertical bore, wherein at least a portion of the body is selectively reinforced with a clad material, and wherein the clad material is age-hardened for a selected time and at a selected temperature profile resulting in the clad material developing a selected strength gradient.Type: GrantFiled: March 1, 2007Date of Patent: December 14, 2010Assignee: Hydril USA Manufacturing LLCInventors: Philip A. Huff, Shafiq Khandoker
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Publication number: 20100193083Abstract: A hydrogen-resistant high strength material made of a Ni-based alloy or an Fe—Ni-based alloy includes an aged portion and a hydrogen embrittlement suppressing layer that is to be exposed to hydrogen. The hydrogen embrittlement suppressing layer has a hydrogen embrittlement index of not less than 0.9, wherein the hydrogen embrittlement index is defined as a ratio of an elongation after hydrogen charging in relation to an elongation before hydrogen charging. The aged portion has a tensile strength exceeding 1000 MPa.Type: ApplicationFiled: February 1, 2010Publication date: August 5, 2010Applicant: HITACHI, LTD.Inventors: Hironori KAMOSHIDA, Shinya IMANO
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Publication number: 20100193088Abstract: A precipitation-hardened stainless steel alloy comprises, by weight: about 14.0 to about 16.0 percent chromium; about 6.0 to about 7.0 percent nickel; about 1.25 to about 1.75 percent copper; about 0.5 to about 2.0 percent molybdenum; about 0.025 to about 0.05 percent carbon; niobium in an amount greater than about twenty times to about twenty-five times that of carbon; and the balance iron and incidental impurities. The alloy has an aged microstructure and an ultimate tensile strength of at least about 1100 MPa and a Charpy V-notch toughness of at least about 69 J. The aged microstructure includes martensite and not more than about 10% reverted austenite and is useful for making turbine airfoils.Type: ApplicationFiled: February 4, 2009Publication date: August 5, 2010Applicant: General Electric CompanyInventors: Jianqiang Chen, Thomas Michael Moors, Jon Conrad Schaeffer
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Publication number: 20100051145Abstract: Disclosed herein is an EGR cooler for a vehicle, which is made of ferrite stainless steel, the ferrite stainless steel including: 0.025˜0.03 wt % of carbon (C), 0.2˜0.8 wt % of silicon (Si), 0.05˜0.8 wt % of manganese (Mn), 0.01˜0.04 wt % of phosphorus (P), 0.01˜0.03 wt % of sulfur (S), 19˜22 wt % of chromium (Cr), 0.2˜0.6 wt % of copper (Cu), 0.25˜0.8 wt % of niobium (Nb) or titanium (Ti), and the balance of iron. A method of manufacturing the EGR cooler for a vehicle includes: heating ferrite stainless steel to a temperature of 1000˜1100° C., maintaining the heated ferrite stainless steel for 30˜60 minutes and then cooling the resulting heated ferrite stainless steel with water; and acid-treating the ferrite stainless steel using an acid solution in which nitric acid and fluoric acid are mixed with distilled water.Type: ApplicationFiled: May 15, 2009Publication date: March 4, 2010Applicant: HYUNDAI MOTOR COMPANYInventor: Jae Gyu Jung
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Patent number: 7513960Abstract: Disclosed is a stainless steel containing, by mass, 0.05% or less carbon, 1.5 to smaller than 3.5% Si, 3.0% or less Mn, 6.0 to 12.0% Cr, 4.0 to 10.0% Ni, 10.0% or less Co, 6.0% or less Cu, 0.5 to 3.0% Ti, 0 to 2.0% Al, not more than 1.0% Mo, not more than 0.01% nitrogen, and the balance of Fe and unavoidable impurities. Preferably, it has a hardness of not lower than 59 HRC and may contain not more than 1.0% Nb and/or not more than 1.0% Ta. Alternatively, the stainless steel may further contain not more than 0.1% of Zr. The process for producing the steel includes producing a steel having a composition as described above by a consumable electrode remelting process, and then subjecting the steel to a solution treatment at a temperature of 1000 to 1150° C. and an aging treatment at a temperature of 400 to 550° C., thereby aging the stainless steel to a hardness of not lower than 59 HRC.Type: GrantFiled: February 15, 2006Date of Patent: April 7, 2009Assignee: Hitachi Metals, Ltd.Inventors: Yoshiyuki Inoue, Fumio Tohyama
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Patent number: 7485197Abstract: In a martensitic stainless steel tube according to the present invention, the content is determined by each of elements C, Si, Mn and Cr, and the bubble content ratio is further prescribed in accordance with the scale thickness on the outer surface of the steel tube, so that defects can be detected with high precision in the non-destructive inspection, such as ultrasonic test or the like. This allows the non-destructive inspection to be carried out with high efficiency. Moreover, there is another advantage that the weather resistance can be enhanced. The steel tube according to the present invention and the manufacturing method thereof can be suitably used in all of the technical fields in which a martensitic stainless steel tube having equal chemical composition is treated.Type: GrantFiled: March 31, 2006Date of Patent: February 3, 2009Assignee: Sumitomo Metal Industries, Ltd.Inventor: Mutsumi Tanida
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Patent number: 7475478Abstract: A method for making structural automotive components and the like includes providing a blank of air hardenable martensitic stainless steel in the annealed condition. The steel blank has a thickness in the range of 0.5-5.0 mm., and is formed utilizing stamping, forging, pressing, or roller forming techniques or the like into the form of an automotive structural member. The automotive structural member is then hardened by application of heat, preferably to between 950° C. and 1100° C. for standard martensitic stainless steels. Thereafter, the automotive structural member is preferably cooled at a rate greater than 25° C. per minute to achieve a Rockwell C hardness of at least 39. The automotive structural member may undergo additional heat treating processes including high temperature or low temperature tempering processes which may incorporate electro-coating.Type: GrantFiled: September 11, 2006Date of Patent: January 13, 2009Assignee: KVA, Inc.Inventors: Edward J. McCrink, Danny Codd
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Publication number: 20080308198Abstract: There are provided an austenitic stainless steel having high stress corrosion crack resistance, characterized by containing, in percent by weight, 0.030% or less C, 0.1% or less Si, 2.0% or less Mn, 0.03% or less P, 0.002% or less S, 11 to 26% Ni, 17 to 30% Cr, 3% or less Mo, and 0.01% or less N, the balance substantially being Fe and unavoidable impurities; a manufacturing method for an austenitic stainless steel, characterized in that a billet consisting of the said austenitic stainless steel is subjected to solution heat treatment at a temperature of 1000 to 1150° C.; and a pipe and a in-furnace structure for a nuclear reactor to which the said austenitic stainless steel is applied.Type: ApplicationFiled: January 13, 2005Publication date: December 18, 2008Applicants: MITSUBISHI HEAVY INDUSTRIES, LTD., THE TOKYO ELECTRIC POWER COMPANY, INC.Inventors: Yasuhiro Sakaguchi, Toshihiko Iwamura, Hiroshi Kanasaki, Hidehito Mimaki, Masaki Taneike, Shunichi Suzuki, Kenrou Takamori, Suguru Ooki, Naoki Anahara, Naoki Hiranuma, Toshio Yonezawa
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Patent number: 7448134Abstract: Pressed shape steel, made of a low cost general steel material that is not hardened, forms a frame with long grooves cut therein. Guide rails, made of a specialized steel material that can be subjected to a hardening treatment, are hardened. Thereafter, outer surfaces of the hardened guide rails are ground and the guide rails are integrally joined in the long grooves. Ball-rolling grooves are formed in the guide rails, thereby completing a guide-equipped frame for an actuator. Because the general steel material and the specialized steel material are principally ferrous materials, both exhibiting a Young's modulus at or above 170 GPa with substantially the same coefficient of linear thermal expansion, the frame needn't be increased in size or have a complex internal structure to reinforce the strength of the frame, and the guide rails remain securely retained in the grooves even if the actuator experiences changes in temperature.Type: GrantFiled: November 29, 2006Date of Patent: November 11, 2008Assignee: SMC Kabushiki KaishaInventors: Shigekazu Nagai, Akio Saitoh, Masaru Saitoh
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Publication number: 20080105340Abstract: A process to manufacture an oilfield component including a base material and an age hardenable clad material comprises finish tempering the oilfield component at a selected time and at a selected temperature to temper the base material and age harden the clad material. A body of a ram blowout preventer comprises, a vertical bore through the body and a horizontal bore through the body intersecting the vertical bore, wherein the body is selectively reinforced with a clad material, and wherein the body is formed by a process comprising finish tempering at a selected time and at a selected temperature to temper the base material and age harden the clad material.Type: ApplicationFiled: November 2, 2006Publication date: May 8, 2008Inventors: Philip A. Huff, Keith Pruden
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Publication number: 20080091267Abstract: Medical devices, such as endoprostheses, and methods of making the devices are disclosed. The endoprostheses comprise a tubular member capable of maintaining patency of a bodily vessel. The tubular member includes a mixture of at least two compositions, where the presence of the second composition gives the mixture a greater hardness than that of the first composition alone. The first composition includes less than about 25 weight percent chromium, less than about 7 weight percent molybdenum, from about 10 to about 35 weight percent nickel, and iron. The second composition is different from the first and is present from about 0.1 weight percent to about 5 weight percent of the mixture.Type: ApplicationFiled: March 29, 2007Publication date: April 17, 2008Inventors: Jonathan S. Stinson, Matthew Cambronne, Richard B. Frank, Richard A. Gleixner, James E. Heilmann
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Patent number: 7294212Abstract: Material for stainless steel sheets is heated to a temperature within a range of 850 to 1250° C. and cooled at a rate 1° C./s or faster, the material including 0.02% by mass or less of C, 1.0% by mass or less of Si, 2.0% by mass or less of Mn, 0.04% by mass or less of P, 0.01% by mass or less of S, 0.1% by mass or less of Al, 11% by mass or more but less than 17% by mass of Cr, 0.5% by mass or more but, less than 3.0% by mass of Ni, and 0.02% by mass or less of N, so as to satisfy specific relationships between the compositions.Type: GrantFiled: April 30, 2004Date of Patent: November 13, 2007Assignee: JFE Steel CorporationInventors: Junichiro Hirasawa, Takumi Ujiro, Osamu Furukimi
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Patent number: 7094295Abstract: A method of manufacturing a ferritic stainless steel sheet having good workability with less anisotropy. The steps include providing a ferritic stainless steel comprising C up to about 0.03 mass %, N up to about 0.03 mass %, Si up to about 2.0 mass %, Mn up to about 2.0 mass %, Ni up to about 0.6 mass %, Cr about 9–35 mass %, Nb about 0.15–0.80 mass % and the balance being Fe except inevitable impurities; precipitation-heating said stainless steel at a temperature in a range of 700–850° C. for a time period not longer than 25 hours; and finish-annealing said stainless steel at a temperature in a range of 900–1100° C. for a time period not longer than 1 minute.Type: GrantFiled: October 28, 2003Date of Patent: August 22, 2006Assignee: Nisshin Steel Co., Ltd.Inventors: Manabu Oku, Yoshitomo Fujimura, Yoshiaki Hori, Toshirou Nagoya, Yasutoshi Kunitake, Takeo Tomita
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Patent number: 7037383Abstract: A process for producing a component of metal includes a) carrying out a heat treatment to harden the component, which ends with a heating process, especially with a tempering or microstructural transformation process, at a given temperature (TE); b) carrying out at least machining of the component at room temperature (TU) in order to provide its desired geometrical shape; and c) subsequent heating of the component to a temperature (T) which is greater than room temperature (TU).Type: GrantFiled: February 25, 2003Date of Patent: May 2, 2006Assignee: AB SKFInventor: Jürgen Gegner
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Patent number: 6893727Abstract: This invention relates to a stainless steel gasket having markedly improved strength and fatigue properties due to precipitation strengthening. Its composition comprises C: at most 0.03%, Si: at most 1.0%, Mn: at most 2%, Cr: 16.0%-18.0%, Ni: 6.0%-8.0%, N: at most 0.25%, if necessary Nb: at most 0.30%, and a remainder of Fe and unavoidable impurities. After cold rolling, final annealing is carried out, and after a structure is formed of recrystallized grains with an average grain diameter of at most 5 ?m having an area ratio of 50-100% and an unrecrystallized portion having an area ratio of 0-50%, a metal gasket is formed by steps including temper rolling with a reduction of at least 30% to make the area ratio of a strain induced martensite phase at least 40%, and forming and heat treatment at 200-350° C.Type: GrantFiled: October 24, 2003Date of Patent: May 17, 2005Assignees: Sumitomo Metal Industries, Ltd., Honda Giken Kogyo Kabushiki KaishaInventors: Kazuhiko Adachi, Seishi Ishiyama, Kenichi Goshokubo, Takashi Katsurai
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Patent number: 6893608Abstract: Maraging steel with improved machinability, good weldability, and high corrosion resistance, a process for the heat treatment of such a steel, as well as its use. According to the invention this steel contains (in % by weight) 0.02-0.075% carbon; 0.1-0.6% silicon; 0.5-0.9% manganese; 0.08-0.25% sulfur; maximum 0.04%; phosphorus; 12.4-15.2% chromium; 0.05-1.0% molybdenum; 0.2-1.8% nickel; maximum 0.15% vanadium; 0.1-0.45% copper; maximum 0.03% aluminum; 0.02-0.08% nitrogen; as well as optionally one or more additional alloying elements up to maximum 2.0%, residual iron, and impurities caused in manufacturing, and a ferrite percentage in the structure of less than 28% by volume.Type: GrantFiled: February 13, 2002Date of Patent: May 17, 2005Assignee: Boehler Edelstahl GmbHInventors: Klaus Sammt, Johann Sammer, Gerhard Lichtenegger
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Patent number: 6811622Abstract: The invention relates to semifinished and finished products made from special corrosion-resistant precipitation-hardened austenitic steel containing a large amount of intersticially dissolved nitrogen, comprising substantially smooth surfaces. The invention also relates to a method for producing corresponding semifinished and finished items. The aim of the invention is to produce semifinished and finished item and to provide an economical method for the production thereof, combining both solidity and resistance to corrosion. This is achieved by precipitation-hardening areas of the steel material.Type: GrantFiled: June 26, 2002Date of Patent: November 2, 2004Inventors: Heinrich Friederich, Reinhard Schmoock
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Patent number: 6793744Abstract: The present invention relates to a martensitic stainless steel that can be used in manufacturing articles such as a shaft or an impeller which require high mechanical strength and corrosion resistance and provides a martensitic stainless steel comprising less than 0.06 wt. % C, less than 2.5 wt. % Si, less than 2.5 wt. % Mn, 1.0-6.0 wt. % Ni, 10.0-19.0 wt. % Cr, 0.5-6.0 wt. % W, less than 3.5 wt. % Mo, less than 0.5 wt. % Nb, less than 0.5 wt. % V, less than 3.0 wt. % Cu, 0.05-0.25 wt. % N, and the remainder being Fe and minor impurities.Type: GrantFiled: November 15, 2000Date of Patent: September 21, 2004Assignee: Research Institute of Industrial Science & TechnologyInventor: Jae-Young Jung
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Publication number: 20040121169Abstract: This invention relates to a stainless steel gasket having markedly improved strength and fatigue properties due to precipitation strengthening. Its composition comprises C: at most 0.03%, Si: at most 1.0%, Mn: at most 2%, Cr: 16.0%-18.0%, Ni: 6.0%-8.0%, N: at most 0.25%, if necessary Nb: at most 0.30%, and a remainder of Fe and unavoidable impurities. After cold rolling, final annealing is carried out, and after a structure is formed of recrystallized grains with an average grain diameter of at most 5 &mgr;m having an area ratio of 50-100% and an unrecrystallized portion having an area ratio of 0-50%, a metal gasket is formed by steps including temper rolling with a reduction of at least 30% to make the area ratio of a strain induced martensite phase at least 40%, and forming and heat treatment at 200-350° C.Type: ApplicationFiled: October 24, 2003Publication date: June 24, 2004Inventors: Kazuhiko Adachi, Seishi Ishiyama, Kenichi Goshokubo, Takashi Katsurai
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Publication number: 20040092334Abstract: A golf club head comprises a part made of a martensitic iron alloy which has: a nickel (Ni) content of from 9.0 to 12.0 weight %; a chromium (Cr) content of from 11.0 to 12.5 weight %; a titanium (Ti) content of from 1.5 to 1.8 weight %; a molybdenum (Mo) content of from 0.75 to 1.2 weight %; a carbon (C) content of not more than 0.05 weight %; a phosphorus (P) content of not more than 0.015 weight %; a silicon (Si) content of not more than 0.25 weight %; a magnesium (Mg) content of not more than 0.25 weight %; and a sulfur (S) content of not more than 0.01 weight %.Type: ApplicationFiled: November 4, 2003Publication date: May 13, 2004Inventor: Akio Yamamoto