With Working Patents (Class 148/608)
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Patent number: 11597982Abstract: A process of producing a fine-grained austenitic stainless steel, the process comprising a step of subjecting a fine-grained austenitic stainless steel comprising: C: 0.15 wt % or less, Si: 1.00 wt % or less, Mn: 2.0 wt % or less, Ni: 6.0 to 14.0 wt %, Cr: 16.0 to 22.0 wt %, and Mo: 3.0 wt % or less, with the balance being Fe and inevitable impurities, and having an average grain size of 10 ?m or lower, to an annealing treatment at a temperature from 600° C. to 700° C. for 48 hours or longer.Type: GrantFiled: September 23, 2019Date of Patent: March 7, 2023Assignee: JAPAN ATOMIC ENERGY AGENCYInventors: Noriaki Hirota, Tomoaki Takeuchi, Hiroko Nakano, Atsushi Kikuchi
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Patent number: 11248284Abstract: A non-magnetic austenitic steel with good corrosion resistance and a high hardness is provided. The non-magnetic austenitic steel comprises less than 0.15 wt % of carbon, less than 1.5 wt % of titanium, from 19 wt % to 26 wt % of chromium, from 3.5 wt % to 7.0 wt % molybdenum, from 11 wt % to 20 wt % nickel, from 2.0 wt % to 7.0 wt % of manganese, less than 0.8 wt % of nitrogen, less than 0.5 wt % of niobium, less than 0.5 wt % of vanadium, less than 1.2 wt % of silicon, less than 4 wt % of copper, and less than 2 wt % of tungsten and the balance being iron.Type: GrantFiled: August 22, 2019Date of Patent: February 15, 2022Assignee: HPM LABS CO., LTD.Inventor: Kuen-Shyang Hwang
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Patent number: 10000832Abstract: Provided is duplex stainless steel having high strength, SCC resistance and SSC resistance excellent in a high-temperature chloride environment, and capable of suppressing precipitation of a ? phase. The duplex stainless steel of the present embodiment includes, in mass %, of: C: at most 0.03%; Si: 0.2 to 1%; Mn: more than 5.0% to at most 10%; P: at most 0.040%; S: at most 0.010%; Ni: 4.5 to 8%; sol. Al: at most 0.040%; N: more than 0.2% to at most 0.4%; Cr: 24 to 29%; Mo: 0.5 to less than 1.5%; Cu: 1.5 to 3.5%; W: 0.05 to 0.2%; the balance being Fe and impurities, wherein the duplex stainless steel satisfies Formula (1): Cr+8Ni+Cu+Mo+W/2?65 . . . (1), where a symbol of each element in Formula (1) represents a content of the element (in mass %).Type: GrantFiled: August 28, 2012Date of Patent: June 19, 2018Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Hideki Takabe, Hisashi Amaya, Kazuhiro Ogawa
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Patent number: 9938598Abstract: The present invention provides a low-alloy high-purity ferritic stainless steel sheet provided with improved oxidation resistance and high-temperature strength by utilizing Sn addition in trace amounts without relying on excessive alloying of Al and Si which reduces fabricability and weldability or addition of rare elements such as Nb, Mo, W, and rare earths, and a process for producing the same. The high-purity ferritic stainless steel sheet includes C: 0.001 to 0.03%, Si: 0.01 to 2%, Mn: 0.01 to 1.5%, P: 0.005 to 0.05%, S: 0.0001 to 0.01%, Cr: 16 to 30%, N: 0.001 to 0.03%, Al: 0.05 to 3%, and Sn: 0.01 to 1% (% by mass), with the remainder being Fe and unavoidable impurities. A stainless steel slab having such steel components is heated, wherein an extraction temperature is 1100 to 1250° C., and a winding temperature after hot rolling is 650° C. or lower. A hot-rolled sheet is annealed at 900 to 1050° C., and cooled at 10° C./sec or less over a temperature range of 550 to 850° C.Type: GrantFiled: January 23, 2012Date of Patent: April 10, 2018Assignee: NIPPON STEEL & SUMIKIN STAINLESS STEEL CORPORATIONInventors: Masaharu Hatano, Eiichiro Ishimaru, Akihiko Takahashi
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Publication number: 20150101714Abstract: This disclosure deals with a class of metal alloys with advanced property combinations applicable to metallic sheet production. More specifically, the present application identifies the formation of metal alloys of relatively high strength and ductility and the use of one or more cycles of elevated temperature treatment and cold deformation to produce metallic sheet at reduced thickness with relatively high strength and ductility.Type: ApplicationFiled: December 18, 2014Publication date: April 16, 2015Inventors: Daniel James BRANAGAN, Grant G. JUSTICE, Andrew T. BALL, Jason K. WALLESER, Brian E. MEACHAM, Kurtis CLARK, Longzhou MA, Igor YAKUBTSOV, Scott Larish, Sheng CHENG, Taylor L. GIDDENS, Andrew E. FRERICHS, Alla V. SERGUEEVA
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Publication number: 20150090372Abstract: This disclosure deals with a class of metal alloys with advanced property combinations applicable to metallic sheet production. More specifically, the present application identifies the formation of metal alloys of relatively high strength and ductility and the use of one or more cycles of elevated temperature treatment and cold deformation to produce metallic sheet at reduced thickness with relatively high strength and ductility.Type: ApplicationFiled: October 2, 2014Publication date: April 2, 2015Inventors: Daniel James BRANAGAN, Grant G. JUSTICE, Andrew T. BALL, Jason K. WALLESER, Brian E. MEACHAM, Kurtis CLARK, Longzhou MA, Igor YAKUBTSOV, Scott Larish, Sheng CHENG, Taylor L. GIDDENS, Andrew E. FRERICHS, Alla V. SERGUEEVA
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Patent number: 8980018Abstract: Ferritic stainless steel sheet for an exhaust part which has little deterioration in strength even if undergoing long term heat history and is low in cost, excellent in heat resistance and workability characterized by containing, characterized by containing, by mass %, C: less than 0.010%, N: 0.020% or less, Si: over 0.1% to 2.0%, Mn: 2.0% or less, Cr: 12.0 to 25.0%, Cu: over 0.9 to 2%, Ti: 0.05 to 0.3%, Nb: 0.001 to 0.1%, Al: 1.0% or less, and B: 0.0003 to 0.003%, having a Cu/(Ti+Nb) of 5 or more, and having a balance of Fe and unavoidable impurities.Type: GrantFiled: March 25, 2011Date of Patent: March 17, 2015Assignee: Nippon Steel & Sumikin Stainless Steel CorporationInventors: Junichi Hamada, Shinichi Teraoka, Yoshiharu Inoue, Norihiro Kanno
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Publication number: 20150013820Abstract: Provided is a method of rolling/drawing a nickel-free high-nitrogen stainless steel material, the method including: an intermediate annealing process S11 in which a nickel-free high-nitrogen stainless steel material made of a fine grain structure having a maximum crystal grain size of 30 ?m or less is annealed at a temperature of 900° C. or higher and 1000° C. or lower and then is air-cooled to room temperature; a rolling/drawing process S12 in which the nickel-free high-nitrogen stainless steel material is extended while being thinned or being reduced in diameter; and a final solution treatment process S13 in which the nickel-free high-nitrogen stainless steel material is heated to a temperature of 1200° C. or higher and 1400° C. or lower and then is air-cooled to room temperature.Type: ApplicationFiled: November 30, 2012Publication date: January 15, 2015Applicant: NATIONAL INSTITUTE FOR MATERIALS SCIENCEInventors: Tetsushi Taguchi, Yasuyuki Katada
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Publication number: 20140209220Abstract: It is an object of the present invention to provide a metal diaphragm capable of achieving a higher strength, excellent corrosion resistance, and a smooth surface condition, and a pressure sensor including the diaphragm. The diaphragm according to the present invention includes a two-phase stainless steel having a composition of 24 to 26 mass % Cr, 2.5 to 3.5 mass % Mo, 5.5 to 7.5 mass % Ni, 0.03 mass % or less C, 0.08 to 0.3 mass % N, and the balance Fe and inevitable impurities, and having a 0.2% proof stress of 1300 MPa or higher.Type: ApplicationFiled: January 23, 2014Publication date: July 31, 2014Applicant: Seiko Instruments Inc.Inventors: Takuma OTOMO, Keita NAITO, Ryo SUGAWARA, Tomoo KOBAYASHI
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Patent number: 8747575Abstract: A martensitic stainless steel for inexpensive seamless pipe having 655 MPa yield strength, high toughness and excellent corrosion resistance in high CO2 environments, and a method for manufacturing thereof is provided. The steel comprises C: 0.005-0.05%, Si: 0.1-0.5%, Mn: 0.1-2.0%, P: ?0.05%, S: ?0.005%, Cr: 10.0-12.5%, Mo: 0.1-0.5%, Ni: 1.5-3.0%, N: ?0.02%, Al: 0.01-0.1%, by weight, while FI value defined by the formula [FI=Cr+Mo?Ni?30(C+N)] being 5.00 to 8.49, and balance of substantially Fe. The method comprises the steps of reheating the cooled steel at temperatures from 780° C. to 960° C., quenching the reheated steel, and then tempering the quenched steel at temperatures from 550° C. to 650° C.Type: GrantFiled: December 30, 2009Date of Patent: June 10, 2014Assignee: NKKTUBESInventors: Shuji Hashizume, Yusuke Minami, Tatsuo Ono
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Publication number: 20140137994Abstract: Austenitic stainless steel having high temperature strength and excellent nitric acid corrosion resistance is provided. The austenitic stainless steel according to the present embodiment including, in mass percent, C: at most 0.050%, Si: 0.01 to 1.00%, Mn: 1.75 to 2.50%, P: at most 0.050%, S: at most 0.0100%, Ni: 20.00 to 24.00%, Cr: 23.00 to 27.00%, Mo: 1.80 to 3.20%, and N: 0.110 to 0.180%, the balance being Fe and impurities, a grain size number of crystal grains based on JIS G0551 (2005) is at least 6.0, and an area fraction of a ? phase is at most 0.1%.Type: ApplicationFiled: June 20, 2012Publication date: May 22, 2014Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventor: Masaki Ueyama
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Patent number: 8506729Abstract: An austenitic stainless steel hot-rolled steel material can be provided which has sea-water resistance and strength superior to conventional steel. Low-temperature toughness can be maintained, which is preferable in a structural member of speedy craft. The steel material can include an austenitic stainless steel hot-rolled steel material which excels in the properties of corrosion resistance, proof stress, and low-temperature toughness. In such austenitic stainless steel hot-rolling steel material, e.g., PI [=Cr+3.3(Mo+0.5W)+16N] ranges from 35 to 40, ? cal [=2.9 (Cr+0.3Si+Mo+0.5W)?2.6 (Ni+0.3Mn+0.25Cu+35C+20N)?18] ranges from ?6 to +2, and a 0.2% proof stress at room temperature is not less than 550 MPa, Charpy impact value measured using a V-notch test piece at ?40° C. is not less than 100 J/cm2, and the pitting potential measured in a deaerated aqueous solution of 10% NaCl at 50° C. (Vc?100) is not less than 500 mV (as it relates to saturated Ag/AgCl).Type: GrantFiled: January 13, 2012Date of Patent: August 13, 2013Assignee: Nippon Steel & Sumikin Stainless Steel CorporationInventors: Yuusuke Oikawa, Shinji Tsuge, Shigeo Fukumoto, Kazuhiro Suetsugu, Ryo Matsuhashi, Hiroshige Inoue
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Patent number: 8440029Abstract: A stainless steel having good conductivity and ductility for use in a fuel cell separator is provided. In particular, the stainless steel has a composition of, in terms of % by mass, C: 0.01% or less, Si: 1.0% or less, Mn: 1.0% or less, S: 0.01% or less, P: 0.05% or less, Al: 0.20% or less, N: 0.02% or less, Cr: 20 to 40%, Mo: 4.0% or less, and at least one selected from Nb, Ti, and Zr: 0.05 to 0.60% in total, the balance being Fe and unavoidable impurities. At least one precipitate having an equivalent circle diameter of 0.1 ?m or more is present per 100 ?m2, a ratio of a thickness t (?m) to a maximum diameter Dmax (?m) of the precipitates satisfies formula (1) below 20?t/Dmax??(1) and the thickness is 200 ?m or less.Type: GrantFiled: July 26, 2010Date of Patent: May 14, 2013Assignee: JFE Steel CorporationInventors: Shinsuke Ide, Atsutaka Honda, Shin Ishikawa, Takumi Ujiro
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Patent number: 8323428Abstract: Dispersion strengthened aluminum base alloys are shaped into metal parts by high strain rate forging compacts or extruded billets composed thereof. The number of process steps required to produce the forged part are decreased and strength and toughness of the parts are increased. The dispersion strengthened alloy may have the formula Albal,Fea,SibXc, wherein X is at least one element selected from Mn, V, Cr, Mo, W, Nb, and Ta, “a” ranges from 2.0 to 7.5 weight-%, “b” ranges from 0.5 to 3.0 weight-%, “c” ranges from 0.05 to 3.5 weight-%, and the balance is aluminum plus incidental impurities. Alternatively, the dispersion strengthened alloy may be described by the formula Albal,Fea,SibVdXc, wherein X is at least one element selected from Mn, Mo, W, Cr, Ta, Zr, Ce, Er, Sc, Nd, Yb, and Y, “a” ranges from 2.0 to 7.5 weight-%, “b” ranges from 0.5 to 3.0 weight-%, “d” ranges from 0.05 to 3.5 weight-%, “c” ranges from 0.02 to 1.50 weight-%, and the balance is aluminum plus incidental impurities.Type: GrantFiled: September 8, 2006Date of Patent: December 4, 2012Assignee: Honeywell International Inc.Inventors: Paul Chipko, Derek Raybould
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Patent number: 8313592Abstract: A thermal mechanical treatment method includes hot working a precipitation hardening martensitic stainless steel, quenching the stainless steel, and aging the stainless steel. According to certain embodiments, the thermal mechanical treatment does not include solution heat treating the stainless steel prior to aging or cryogenically cooling the stainless steel. An article includes a precipitation hardening martensitic stainless steel having a process history that includes hot working the stainless steel, quenching the stainless steel, and aging the stainless steel. According to certain embodiments, the process history does not include solution heat treating the stainless steel prior to aging or cryogenically cooling the stainless steel.Type: GrantFiled: March 15, 2011Date of Patent: November 20, 2012Assignee: ATI Properties, Inc.Inventors: Wei-Di Cao, Erin T. McDevitt
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Patent number: 8303733Abstract: This stainless steel sheet includes, in terms of mass %, C: 0.001 to 0.1%, N: 0.01 to 0.15%, Si: 0.01 to 2%, Mn: 0.1 to 10%, P: 0.05% or less, S: 0.01% or less, Ni: 0.5 to 5%, Cr: 10 to 25%, and Cu: 0.5 to 5%, with a remainder being Fe and unavoidable impurities, and contains a ferrite phase as a main phase and 10% or more of an austenite phase, wherein a work-hardening rate in a strain range of up to 30% is 1000 MPa or more which is measured by a static tensile testing and a difference between static and dynamic stresses which occur when 10% of deformation is caused is 150 MPa or more. This method for producing a stainless steel includes annealing a cold-rolled steel sheet under conditions where a holding temperature is set to be in a range of 950 to 1150° C. and a cooling rate until 400° C. is set to be in a range of 3° C./sec or higher.Type: GrantFiled: January 22, 2009Date of Patent: November 6, 2012Assignee: Nippon Steel & Sumikin Stainless Steel CorporationInventors: Junichi Hamada, Haruhiko Kajimura, Eiichiro Ishimaru
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Patent number: 8273191Abstract: Provided is a high-strength stainless steel material having less deterioration in mechanical strength and improved workability, particularly bending workability compared with conventional steel materials. The high-strength stainless steel material of the present invention has a specific composition, has a metal microstructure composed of two phases, that is a ferrite phase and a martensite phase, has a ?max of from 50 to 85, the ?max being represented by the following equation (1): ?max=420Wc+470WN+23WNi+7WMn?11.5WCr?11.5WSi+189??(1) wherein, Wc, WN, WNi, WMn, WCr, and WSi; represent contents (unit: mass %) of C, N, Ni, Mn, Cr, and Si relative to the total mass of the stainless steel material, respectively; and has a difference of 300 HV or less in hardness between the ferrite phase and the martensite phase.Type: GrantFiled: February 2, 2009Date of Patent: September 25, 2012Assignee: Nisshin Steel Co., Ltd.Inventors: Naoki Hirakawa, Hiroshi Fujimoto, Satoshi Suzuki
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Patent number: 8262815Abstract: The present invention provides high purity ferrite stainless steel able to reduce deterioration in surface conditions due to pitting corrosion or rusting or other corrosion to an extent no different from SUS304 or better without inviting a drop in manufacturability or workability and without relying on the addition of rare elements, and a method of production of the same, that is, ferritic stainless steel containing, by mass %, C: 0.01% or less, Si: 0.01 to 0.20%, Mn: 0.01 to 0.30%, P: 0.04% or less, S: 0.01% or less, Cr: 13 to 22%, N: 0.001 to 0.020%, Ti: 0.05 to 0.35%, Al: 0.005 to 0.050%, Sn: 0.001 to 1%, and a balance of Fe and unavoidable impurities to which Sn is added to modify the passive film and improve the corrosion resistance. To improve the effect of modification of the passive film by the addition of Sn, after the final annealing, the steel is held in the 200 to 700° C. temperature range for 1 minute or more.Type: GrantFiled: January 13, 2009Date of Patent: September 11, 2012Assignee: Nippon Steel & Sumikin Stainless Steel CorporationInventors: Masaharu Hatano, Akihiko Takahashi
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Publication number: 20120190321Abstract: A nonmagnetic stainless steel which has a higher electrical resistivity than existing nonmagnetic alloys, a production process for producing the stainless steel, and a radio wave receiver. The receiver has a main case and rear cover constituted of a nonmagnetic stainless steel having an electrical resistivity as high as more than 100 ??·cm and consisting of C: not more than 0.1%, Si: 4.0-7.5%, Mn: not more than 2.0%, Ni: 25.5-30.0%, Cr: 15.0-20.0%, Mo: 0.1-3.0%, Cu: 0-2.0%, in mass % and the balance Fe and impurities. Even if some variable magnetic flux generated by a coil of an antenna runs through the main case and the rear cover, the receiving efficiency of the antenna can be prevented from being reduced by eddy current loss and a sufficient radio receiving sensitivity can be obtained. This nonmagnetic stainless steel is produced by hot and/or cold plastic working and subsequent solution treating conducted at 1,000-1,180° C.Type: ApplicationFiled: July 29, 2010Publication date: July 26, 2012Applicants: HITACHI METALS, LTD., CASIO COMPUTER CO., LTD.Inventors: Junichi Sato, Toshihiro Uehara, Kenji Yokoyama
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Publication number: 20120145285Abstract: The invention relates to a method for producing a component, made of an iron-chromium alloy that precipitates Laves phases and/or particles containing Fe and/or particles containing Cr and/or particles containing Si and/or carbides, by subjecting a semi-finished product made of the alloy to a thermomechanical treatment, wherein in a first step, the alloy is solution heat treated at temperatures?the solution heat treatment temperature and is subsequently quenched in stationary protective gas or air, moving (blown) protective gas or air, or water. In a second step, a mechanical forming of the semi-finished product in a range from 0.05 to 99% is performed, and in a subsequent step, Laves phases Fe2(M, Si) or Fe7(M, Si)6 and/or particles containing Fe and/or particles containing Cr and/or particles containing Si and/or carbides are precipitated in a specific and finely distributed manner in that the component produced from the formed semi-finished product is brought to an application temperature between 550° C.Type: ApplicationFiled: August 18, 2010Publication date: June 14, 2012Applicant: THYSSENKRUPP VDM GMBHInventors: Heike Hattendorf, Osman Ibas
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Patent number: 8177929Abstract: A metal gasket formed from a suitable iron-nickel chromium alloy includes at least one embossment that exhibits essentially full functional recovery at temperatures exceeding 1000° F. and including in the range of 1100° F. to 1600° F. or more and which is made from sheet material that is work hardened and strengthened by cold rolling, or a combination of cold rolling and precipitation hardening, without any post embossment heat treating that would act to further harden the material. Suitable iron-nickel-chromium alloys include those comprising, by weight, greater than 18% nickel; greater than 14% chrome and 0.1-10% of at least one element selected from the group consisting of Mo, Ti, V, Al, Co, Nb, Ta and Cu, with the balance being substantially Fe, wherein the gasket sheet alloy has a deformed microstructure.Type: GrantFiled: March 18, 2010Date of Patent: May 15, 2012Assignee: Federal-Mogul World Wide, Inc.Inventor: Thomas Zurfluh
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Patent number: 8097098Abstract: The invention concerns martensitic stainless steel, characterized in that its composition in weight percentages is as follows: 9%=Cr=13%; 1.5%=Mo=3%; 8%=Ni=14%; 1%=Al=2%; 0.5%=Ti=1.5% with AI+Ti=2.25%; traces=Co=2%; traces=W=1% with Mo+(W/2)=3%; traces=P=0.02%; traces=S=0.0050%; traces=N=0.0060%; traces=C=0.025%; traces=Cu=0.5%; traces=Mn=3%; traces=Si=0.25%; traces=O=0.0050%; and is such that: Ms (° C.)=1302 42 Cr 63 Ni 30 Mo+20AI-15W-33Mn-28Si-30Cu-13Co+10 Ti=50Cr eq/Ni eq=1.05 with Cr eq (%)=Cr+2Si+Mo+1.5 Ti+5.5 AI+0.6W Ni eq (%)=2Ni+0.5 Mn+3O C+25 N+Co+0.3 Cu. The invention also concerns a method for making a mechanical part using said steel, and the resulting part.Type: GrantFiled: June 26, 2006Date of Patent: January 17, 2012Assignee: Aubert & DuvalInventor: Jacques Montagnon
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Patent number: 8043446Abstract: A high manganese duplex stainless steel with excellent hot workability, comprising (in weight %): less than 0.1% of C; 0.05-2.2% of Si; 2.1-7.8% of Mn; 20-29% of Cr; 3.0-9.5% of Ni; 0.08-0.5% of N; less than 5.0% of Mo and 1.2-8% of W, alone or composite; the balance Fe and inevitable impurities; and a method for manufacturing the duplex stainless steel, comprising the steps of: solution heating the duplex stainless steel composition at a temperature of 1,050 to 1,250° C., hot working at a starting temperature of 1,130 to 1,280° C. and then ending at a temperature greater than 1,000° C., and then cooling within the temperature range from 1,000 to 700° C. at a cooling rate of more than 3° C./min. The duplex stainless steel exhibits a reduction in area of more than 50% at 1,050° C., and possesses a yield strength of more than 400 MPa, and a corrosion rate of less than 0.36 mm/year, after solution heating.Type: GrantFiled: April 26, 2002Date of Patent: October 25, 2011Assignee: Research Institute of Industrial Science and TechnologyInventors: Jae-Young Jung, Bong-Year Ma
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Patent number: 7967927Abstract: A nanocarbide precipitation strengthened ultrahigh-strength, corrosion resistant, structural steel possesses a combination of strength and corrosion resistance comprising in combination, by weight, about: 0.1 to 0.3% carbon (C), 8 to 17% cobalt (Co), 0 to 10% nickel (Ni), 6 to 12% chromium (Cr), less than 1% silicon (Si), less than 0.5% manganese (Mn), and less than 0.15% copper (Cu), with additives selected from the group comprising about: less than 3% molybdenum (Mo), less than 0.3% niobium (Nb), less than 0.8% vanadium (V), less than 0.2% tantalum (Ta), less than 3% tungsten (W), and combinations thereof, with additional additives selected from the group comprising about: less than 0.2% titanium (Ti), less than 0.2% lanthanum (La) or other rare earth elements, less than 0.15% zirconium (Zr), less than 0.005% boron (B), and combinations thereof, impurities of less than about: 0.02% sulfur (S), 0.012% phosphorus (P), 0.015% oxygen (O) and 0.Type: GrantFiled: January 9, 2007Date of Patent: June 28, 2011Assignee: QuesTek Innovations, LLCInventors: Charles J. Kuehmann, Gregory B. Olson, Herng-Jeng Jou
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Patent number: 7947136Abstract: An austenitic, substantially ferrite-free steel alloy and a process for producing components therefrom. This Abstract is not intended to define the invention disclosed in the specification, nor intended to limit the scope of the invention in any way.Type: GrantFiled: March 16, 2010Date of Patent: May 24, 2011Assignees: Boehler Edelstahl GmbH & Co KG, Schoeller-Bleckmann Oilfield Technology GmbHInventors: Gabriele Saller, Herbert Aigner, Josef Bernauer, Raimund Huber
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Patent number: 7931758Abstract: A thermal mechanical treatment method includes hot working a precipitation hardening martensitic stainless steel, quenching the stainless steel, and aging the stainless steel. According to certain embodiments, the thermal mechanical treatment does not include solution heat treating the stainless steel prior to aging or cryogenically cooling the stainless steel. An article includes a precipitation hardening martensitic stainless steel having a process history that includes hot working the stainless steel, quenching the stainless steel, and aging the stainless steel. According to certain embodiments, the process history does not include solution heat treating the stainless steel prior to aging or cryogenically cooling the stainless steel.Type: GrantFiled: July 28, 2008Date of Patent: April 26, 2011Assignee: ATI Properties, Inc.Inventors: Wei-Di Cao, Erin T. McDevitt
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Patent number: 7905967Abstract: The occurrence of delayed fracture which is found in a hot worked martensitic stainless steel is prevented by subjecting the steel, after hot working and prior to heat treatment for hardening by quenching from a temperature of at least Ac1 point of the steel, to preliminary softening heat treatment under such conditions that the softening parameter P defined below is at least 15,400 and the softening temperature T is lower than the Ac1 point: P(softening parameter):P=T(20+log t) T: softening temperature [K] t: duration of softening treatment [Hr]. The present invention is particularly effective for a martensitic stainless steel having a steel composition in which the amount of effective dissolved C and N (=[C*+10N*]) where C* and N* are calculated by the following formulas is larger than 0.45: C*=C?[12{(Cr/52)×(6/23)}/10, and N*=N?[14{(V/51)+(Nb/93)}/10]?[14{(Ti/48)+(B/11)+(Al/27)}/10].Type: GrantFiled: September 28, 2007Date of Patent: March 15, 2011Assignee: Sumitomo Metal Industries, Ltd.Inventor: Nobuyuki Mori
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Patent number: 7806993Abstract: The present invention provides a ferritic stainless steel that has excellent strength at high temperature, oxidation resistance at high temperature, and salt corrosion resistance at high temperature and that can be used under high temperatures exceeding 900° C., and a method of producing the same. Specifically, the composition thereof is adjusted, on a % by mass basis, so as to include C: 0.02% or less; Si: 2.0% or less; Mn: 2.0% or less; Cr: from 12.0 to 40.0%; Mo: from 1.0 to 5.0%; W: more than 2.0% and 5.0% or less; wherein the total content of Mo and W: (Mo+W)?4.3%, Nb: from 5 (C+N) to 1.0%, N: 0.02% or less, and Fe and inevitable impurities as residual.Type: GrantFiled: June 2, 2003Date of Patent: October 5, 2010Assignee: JFE Steel CorporationInventors: Atsushi Miyazaki, Kenji Takao, Osamu Furukimi
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Publication number: 20100180990Abstract: The present invention relates to an impact beam for use in a vehicle. More specifically, the invention relates to an impact beam comprising precipitation hardenable stainless steel, and a method of producing such a beam. The precipitation hardenable stainless steel has a composition, all in percent by weight, of: C max 0.07 Si max 1.2 Mn max 0.7 Cr 10-14 Mo max 1.5 Ni 7-12 Cu max 2.6 Ti 0.6-2.0 (Nb+Ta) max 0.7 balance Fe and normally occurring impurities. An impact beam comprising precipitation hardenable stainless steel, according to the invention, provides improved impact absorbing properties per unit of weight, and can be formed by conventional hot forming techniques.Type: ApplicationFiled: May 29, 2008Publication date: July 22, 2010Applicant: SANDVIK INTELLECTUAL PROPERTY ABInventor: Carl-Johan Irander
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Patent number: 7758707Abstract: The invention relates to a martensitic stainless steel to be used for making a razor, surgical and similar blades or other cutting tools, which steel contains 0.40 to 0.55 wt % carbon, 0.8 to 1.5 wt % silicon, 0.7 to 0.85 wt % manganese, 13.0 to 14.0 wt % chromium, 1.0 to 1.5 wt % molybdenum and 0.2 to 0.4 wt % nickel, 0.02 to 0.04 wt % nitrogen, the balance of the steel being iron and inevitable impurities. The invention also relates to a method of manufacturing the said steel.Type: GrantFiled: June 16, 2006Date of Patent: July 20, 2010Assignee: Outokumpu OyjInventor: Chris Millward
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Publication number: 20100170597Abstract: A metal gasket formed from a suitable iron-nickel chromium alloy includes at least one embossment that exhibits essentially full functional recovery at temperatures exceeding 1000° F. and including in the range of 1100° F. to 1600° F. or more and which is made from sheet material that is work hardened and strengthened by cold rolling, or a combination of cold rolling and precipitation hardening, without any post embossment heat treating that would act to further harden the material. Suitable iron-nickel-chromium alloys include those comprising, by weight, greater than 18% nickel; greater than 14% chrome and 0.1-10% of at least one element selected from the group consisting of Mo, Ti, V, Al, Co, Nb, Ta and Cu, with the balance being substantially Fe, wherein the gasket sheet alloy has a deformed microstructure.Type: ApplicationFiled: March 18, 2010Publication date: July 8, 2010Inventor: Thomas Zurfluh
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Publication number: 20100170596Abstract: An austenitic, substantially ferrite-free steel alloy and a process for producing components therefrom. This Abstract is not intended to define the invention disclosed in the specification, nor intended to limit the scope of the invention in any way.Type: ApplicationFiled: March 16, 2010Publication date: July 8, 2010Applicants: Boehler Edelstahl GmbH & Co KG, Schoeller-Bleckmann Oilfield Technology GmbHInventors: Gabriele Saller, Herbert Aigner, Josef Bernauer, Raimund Huber
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Publication number: 20100116382Abstract: An austenitic stainless steel excellent in intergranular corrosion resistance and stress corrosion cracking resistance, comprising: C: 0.005 wt % or less; Si: 0.5 wt % or less; Mn: 0.5 wt % or less; P: 0.005 wt % or less; S: 0.005 wt % or less; Ni: 15.0 to 40.0 wt %, Cr: 20.0 to 30.0 wt %, N: 0.01 wt % or less; O: 0.01 wt % or less; and the balance of Fe and inevitable impurities, wherein the content of B included in the inevitable impurities is 3 wt ppm or less.Type: ApplicationFiled: April 24, 2008Publication date: May 13, 2010Applicants: Japan Atomic Energy Agency, Kobelco Research Institute, Inc., Kabushiki Kaisha Kobe Seiko ShoInventors: Kiyoshi Kiuchi, Ikuo Ioka, Chiaki Kato, Nobutoshi Maruyama, Ichiro Tsukatani, Makoto Tanabe, Jumpei Nakayama
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Patent number: 7708841Abstract: An austenitic, substantially ferrite-free steel alloy and a process for producing components therefrom. This Abstract is not intended to define the invention disclosed in the specification, nor intended to limit the scope of the invention in any way.Type: GrantFiled: December 2, 2004Date of Patent: May 4, 2010Assignees: Boehler Edelstahl GmbH & Co KG, Schoeller-Bleckmann Oilfield Technology GmbHInventors: Gabriele Saller, Herbert Aigner, Josef Bernauer, Raimund Huber
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Publication number: 20100018615Abstract: A thermal mechanical treatment method includes hot working a precipitation hardening martensitic stainless steel, quenching the stainless steel, and aging the stainless steel. According to certain embodiments, the thermal mechanical treatment does not include solution heat treating the stainless steel prior to aging or cryogenically cooling the stainless steel. An article includes a precipitation hardening martensitic stainless steel having a process history that includes hot working the stainless steel, quenching the stainless steel, and aging the stainless steel. According to certain embodiments, the process history does not include solution heat treating the stainless steel prior to aging or cryogenically cooling the stainless steel.Type: ApplicationFiled: July 28, 2008Publication date: January 28, 2010Applicant: ATI Properties, Inc.Inventors: Wei-Di Cao, Erin T. McDevitt
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Publication number: 20090178739Abstract: It is an object of the present invention to provide a ferromagnetic Fe-based alloy having a large reversible strain obtained by application and removal of a magnetic field gradient. The Fe-based alloy contains one or two or more types selected from Al: 0.01 to 11%, Si: 0.01 to 7% and Cr: 0.01 to 26%, or Al: 0.01 to 11%, Si: 0.01 to 7%, Cr: 0.01 to 26% and Ni: 35 to 50%. A twin crystal interface is introduced by working the Fe-based alloy at a working rate: 10% or more. An area ratio of the twin crystal interface to a crystal grain boundary is 0.2 or more. One or two or more types of Ti: 0.01 to 5%, V: 0.01 to 10%, Mn: 0.01 to 5%, Co: 0.01 to 30%, Ni: 0.01 to 10%, Cu: 0.01 to 5%, Zr: 0.01 to 5%, Nb: 0.01 to 5%, Mo: 0.01 to 5%, Hf: 0.01 to 5%, Ta: 0.01 to 5%, W: 0.01 to 5%, B: 0.001 to 1%, C: 0.001 to 1%, P: 0.001 to 1% and S: 0.001 to 1% may be added to the Fe-based alloy if needed.Type: ApplicationFiled: February 20, 2009Publication date: July 16, 2009Applicant: JAPAN SCIENCE AND TECHNOLOGY AGENCYInventors: Kiyohito Ishida, Ryosuke Kainuma, Katunari Oikawa, Yuji Sutou, Toshihiro Omori, Keisuke Ando
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Patent number: 7531053Abstract: An inexpensive metallic material for interconnects of solid-oxide fuel cells, a fuel cell using the metallic material, and a method for producing the metallic material having excellent oxidation resistance and spalling resistance of an oxide layer, high electrical conductivity, and a small difference in thermal expansion from an electrolyte. Specifically, 0.20 percent by mass or less of C, 0.02 to 1.0 percent by mass of Si, 2.0 percent by mass or less of Mn, 10 to 40 percent by mass of Cr, 0.03 to 5.0 percent by mass of Mo, 0.1 to 3.0 percent by mass of Nb, and at least one element selected from the group consisting of Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Zr, and Hf in a total of 1.0 percent by mass or less are added so as to satisfy 0.1?Mo/Nb?30, for decreasing the growth rate of the oxide layer and improving the spalling resistance.Type: GrantFiled: August 7, 2003Date of Patent: May 12, 2009Assignee: JFE Steel CorporationInventors: Shinsuki Ide, Shin Ishikawa, Kenji Takao, Osamu Furukimi, Kunio Fukuda, Atsushi Miyazaki
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Patent number: 7494551Abstract: A Ti-containing ferritic stainless steel sheet and a manufacturing method thereof include stainless steels being formed while a refining load is decreased and having a low yield strength which exhibits superior workability. The Ti-containing ferritic stainless steel sheet contains on mass percent basis: 0.01% or less of C; 0.5% or less of Si; 0.3% or less of Mn; 0.01% to 0.04% of P; 0.01% or less of S; 8% to 30% of Cr; 1.0% or less of Al; 0.05% to 0.5% of Ti; 0.04% or less of N, 8?Ti/(C+N)?30 being satisfied; and the balance being substantially Fe and incidental impurities, wherein a grain size number of ferrite grain is 6.0 or more, and an average diameter Dp of precipitation diameters, each being [(a long axis length of a Ti base precipitate+a short axis length thereof)/2], of the Ti base precipitates in the steel sheet is in the range of from 0.05 ?m to 1.0 ?m.Type: GrantFiled: June 16, 2003Date of Patent: February 24, 2009Assignee: JFE Steel CorporationInventors: Yoshihiro Yazawa, Osamu Furukimi, Yasushi Kato
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Patent number: 7475478Abstract: A method for making structural automotive components and the like includes providing a blank of air hardenable martensitic stainless steel in the annealed condition. The steel blank has a thickness in the range of 0.5-5.0 mm., and is formed utilizing stamping, forging, pressing, or roller forming techniques or the like into the form of an automotive structural member. The automotive structural member is then hardened by application of heat, preferably to between 950° C. and 1100° C. for standard martensitic stainless steels. Thereafter, the automotive structural member is preferably cooled at a rate greater than 25° C. per minute to achieve a Rockwell C hardness of at least 39. The automotive structural member may undergo additional heat treating processes including high temperature or low temperature tempering processes which may incorporate electro-coating.Type: GrantFiled: September 11, 2006Date of Patent: January 13, 2009Assignee: KVA, Inc.Inventors: Edward J. McCrink, Danny Codd
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Patent number: 7470336Abstract: A martensitic alloy in which the ASTM grain size number is at least 5, including (wt. %) up to about 0.5% C, at least about 5% Cr, at least about 0.5% Ni, up to about 15% Co, up to about 8% Cu, up to about 8% Mn, up to about 4% Si, up to about 6% (Mo+W), up to about 1.5% Ti, up to about 3% V, up to about 0.5% Al, and at least about 40% Fe.Type: GrantFiled: October 5, 2007Date of Patent: December 30, 2008Assignee: Advanced Steel Technology LLCInventor: Robert F. Buck
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Publication number: 20080308198Abstract: There are provided an austenitic stainless steel having high stress corrosion crack resistance, characterized by containing, in percent by weight, 0.030% or less C, 0.1% or less Si, 2.0% or less Mn, 0.03% or less P, 0.002% or less S, 11 to 26% Ni, 17 to 30% Cr, 3% or less Mo, and 0.01% or less N, the balance substantially being Fe and unavoidable impurities; a manufacturing method for an austenitic stainless steel, characterized in that a billet consisting of the said austenitic stainless steel is subjected to solution heat treatment at a temperature of 1000 to 1150° C.; and a pipe and a in-furnace structure for a nuclear reactor to which the said austenitic stainless steel is applied.Type: ApplicationFiled: January 13, 2005Publication date: December 18, 2008Applicants: MITSUBISHI HEAVY INDUSTRIES, LTD., THE TOKYO ELECTRIC POWER COMPANY, INC.Inventors: Yasuhiro Sakaguchi, Toshihiko Iwamura, Hiroshi Kanasaki, Hidehito Mimaki, Masaki Taneike, Shunichi Suzuki, Kenrou Takamori, Suguru Ooki, Naoki Anahara, Naoki Hiranuma, Toshio Yonezawa
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Patent number: 7429302Abstract: A structural hot-rolled or cold-rolled stainless steel sheet having improved intergranular corrosion resistance and toughness at the welding heat affected zone and further having low strength and high elongation. The composition of the steel sheet contains less than about 0.008 mass percent of C; about 1.0 mass percent or less of Si; about 1.5 mass percent or less of Mn; about 11 to about 15 mass percent of Cr; more than about 1.0 mass percent and about 2.5 mass percent or less of Ni; less than about 0.10 mass percent of Al; about 0.009 mass percent or less of N; about 0.04 mass percent or less of P; about 0.01 mass percent or less of S; and the balance being Fe and incidental impurities. These contents satisfy the expressions: (Cr)+1.2×(Ni)?15.0; (Ni)+0.5×(Mn)+30×(C)?3.0; (C)+(N)?0.015; and (Cr)?(Mn)?1.7×(Ni)?27×(C)?100×(N)?9.0.Type: GrantFiled: March 24, 2003Date of Patent: September 30, 2008Assignee: JFE Steel CorporationInventors: Junichiro Hirasawa, Takumi Ujiro, Osamu Furukimi
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Patent number: 7399372Abstract: A metallic bellows, composed of precipitation hardening stainless steel, includes ridge portions and valley portions formed alternately and continuously, an average grain size of 10 to 15 ?m, and compressive residual stress of not less than 500 MPa provided to at least surfaces of the ridge portions and the valleys by surface working.Type: GrantFiled: November 1, 2004Date of Patent: July 15, 2008Assignee: NHK Spring Co., Ltd.Inventor: Hideki Okada
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Publication number: 20080110534Abstract: A nickel alloy having an excellent corrosion resistance (hereinafter referred to as “nickel alloy”) used for pipes, structural materials and structural members, such as bolts or the like, in a nuclear power plant or in a chemical plant, and a manufacturing method for the same are provided. In the nickel alloy according to the present invention, an excellent corrosion resistance, in particular an excellent resistance against the IGSCC, is obtained by specifying the low angle boundary rate of 4% or more in the grain boundaries, along with the restriction of the chemical composition in the alloy, thereby making it possible to provide a nickel alloy which is most suitably used for pipes, structural materials and structural members, such as bolts or the like. Accordingly, the nickel alloy according to the present invention is widely applicable to structural members used in a nuclear station or in a chemical plant.Type: ApplicationFiled: October 17, 2007Publication date: May 15, 2008Inventor: Manabu Kanzaki
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Patent number: 7294212Abstract: Material for stainless steel sheets is heated to a temperature within a range of 850 to 1250° C. and cooled at a rate 1° C./s or faster, the material including 0.02% by mass or less of C, 1.0% by mass or less of Si, 2.0% by mass or less of Mn, 0.04% by mass or less of P, 0.01% by mass or less of S, 0.1% by mass or less of Al, 11% by mass or more but less than 17% by mass of Cr, 0.5% by mass or more but, less than 3.0% by mass of Ni, and 0.02% by mass or less of N, so as to satisfy specific relationships between the compositions.Type: GrantFiled: April 30, 2004Date of Patent: November 13, 2007Assignee: JFE Steel CorporationInventors: Junichiro Hirasawa, Takumi Ujiro, Osamu Furukimi
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Patent number: 7070663Abstract: A ferritic or martensitic stainless steel has the structure that Cu-enriched particles with concentration of C not less than 0.1 mass % or concentration of Sn and/or In not less than 10 mass % were dispersed in a matrix. Precipitation and dispersion of Cu-enriched particles is realized by aging the stainless steel at 500–900° C. for 1 hour or longer on any stage after a hot-rolling step until a forming step to a final product. The ferritic stainless steel contains 0.01–1.0% C, Si up to 1.0%, Mn up to 1.0%, 15–30% Cr, Ni up to 6.0% and 0.5–6.0% Cu. The martensitic stainless steel contains 0.01–0.5% C, Si up to 1.0%, Mn up to 1.0%, 10–15% Cr, Ni up to 6.0% and 0.5–6.0% Cu. Since Cu-enriched particles are dispersed for improvement of machinability instead of addition of S, Pb, Bi or Se, the stainless steel is machined to an objective shape without any harmful influence on workability, corrosion-resistance and the environment.Type: GrantFiled: November 14, 2003Date of Patent: July 4, 2006Assignee: Nisshin Steel Co., Ltd.Inventors: Satoshi Suzuki, Hideki Tanaka, Naoto Hiramatsu
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Patent number: 6893608Abstract: Maraging steel with improved machinability, good weldability, and high corrosion resistance, a process for the heat treatment of such a steel, as well as its use. According to the invention this steel contains (in % by weight) 0.02-0.075% carbon; 0.1-0.6% silicon; 0.5-0.9% manganese; 0.08-0.25% sulfur; maximum 0.04%; phosphorus; 12.4-15.2% chromium; 0.05-1.0% molybdenum; 0.2-1.8% nickel; maximum 0.15% vanadium; 0.1-0.45% copper; maximum 0.03% aluminum; 0.02-0.08% nitrogen; as well as optionally one or more additional alloying elements up to maximum 2.0%, residual iron, and impurities caused in manufacturing, and a ferrite percentage in the structure of less than 28% by volume.Type: GrantFiled: February 13, 2002Date of Patent: May 17, 2005Assignee: Boehler Edelstahl GmbHInventors: Klaus Sammt, Johann Sammer, Gerhard Lichtenegger
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Patent number: 6893727Abstract: This invention relates to a stainless steel gasket having markedly improved strength and fatigue properties due to precipitation strengthening. Its composition comprises C: at most 0.03%, Si: at most 1.0%, Mn: at most 2%, Cr: 16.0%-18.0%, Ni: 6.0%-8.0%, N: at most 0.25%, if necessary Nb: at most 0.30%, and a remainder of Fe and unavoidable impurities. After cold rolling, final annealing is carried out, and after a structure is formed of recrystallized grains with an average grain diameter of at most 5 ?m having an area ratio of 50-100% and an unrecrystallized portion having an area ratio of 0-50%, a metal gasket is formed by steps including temper rolling with a reduction of at least 30% to make the area ratio of a strain induced martensite phase at least 40%, and forming and heat treatment at 200-350° C.Type: GrantFiled: October 24, 2003Date of Patent: May 17, 2005Assignees: Sumitomo Metal Industries, Ltd., Honda Giken Kogyo Kabushiki KaishaInventors: Kazuhiko Adachi, Seishi Ishiyama, Kenichi Goshokubo, Takashi Katsurai
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Patent number: 6884388Abstract: A martensitic stainless steel sheet which is hard to be softened by tempering caused by heating during the use of a disk brake, can maintain the predetermined hardness, and has excellent punching workability, bending workability before quenching, and a particularly small shear drop, and in which a predetermined hardness after quenching is constantly achieved, in a low carbon martensitic stainless steel sheet used only after quenching. Specifically, the sheet contains, on the basis of mass percent, 0.030% to 0.100% C; 0.50% or less of Si; 1.00% to 2.50% Mn; more than 10.00% to 15.00% Cr; at least one selected from the group consisting of 0.01% to 0.50% Ti, 0.01% to 0.50% V, 0.01% to 1.00% Nb, and 0.01% to 1.00% Zr; N in an amount defined by the following expression, N: 0.005% to (Ti+V)×14/50+(Nb+Zr)×14/90; and the balance being Fe and incidental impurities.Type: GrantFiled: August 31, 2001Date of Patent: April 26, 2005Assignee: JFE Steel CorporationInventors: Yoshihiro Ozaki, Toshimitsu Nagaya, Atsushi Miyazaki, Susumu Satoh, Mineo Muraki, Setsuo Kakihara, Toshihiro Kasamo
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Patent number: 6855213Abstract: A ferritic non-ridging stainless steel and process therefor. A chromium alloyed steel melt containing sufficient titanium and nitrogen but a controlled amount of aluminum is cast into an ingot or continuously cast into a strip or a slab having an as-cast fine equiaxed grain structure substantially free of columnar grains. The as-cast steel contains 0.08% C, at least about 8% Cr, up to 1.50% Mn, <0.020% Al, ?0.05% N, ?1.5% Si, <2.0% Ni, Ti?0.10%, the ratio of (Ti×N)/Al?0.14, all percentages by weight, the balance Fe and residual elements. Preferably, the titanium is controlled so that (Ti/48)/[(C/12)+(N/14)]>1.5. A hot processed sheet may be formed from a continuously cast slab without grinding the surfaces of the slab. The hot processed sheet may be descaled, cold reduced to a final thickness and recrystallization annealed. Annealing the hot processed sheet prior to cold reduction is not required to obtain an annealed sheet essentially free of ridging and having high formability.Type: GrantFiled: September 15, 1998Date of Patent: February 15, 2005Assignee: Armco Inc.Inventors: Eizo Yoshitake, Alan R. McKague