Abstract: There is provided a stainless steel sheet material, used for a semiconductor manufacturing device, to which it difficult for fine dust to be attached and from the surface of which the attaching dust can be easily washed away. Also, there is provided a method of manufacturing the stainless steel sheet material. A stainless steel sheet material characterized in that: the number of pinholes, the area of each pinhole exceeding 0.25 mm2, in the area of 10 cm2 on the surface of a skinpass-rolled stainless steel sheet material is not more than 10; and the average surface roughness Ra on the center line in the direction perpendicular to the rolling direction is not more than 0.15 &mgr;m. A method of manufacturing a stainless steel sheet material comprising the steps of: annealing a stainless steel cold-rolled sheet in a heat-treatment furnace having no support rollers in a temperature region exceeding 600° C.

Abstract: A shadow mask blank of Fe—Ni alloy which exhibits excellent uniformity of diameter of apertures formed by perforation with etching for the passage of electron beams, consisting of 34-38% Ni, 0.05-0.5% Mn, 4-20 ppm S, and the balance Fe and no more than specified limits of C, Si, Al, and P, with MnS inclusions 50-1,000 nm in diameter dispersed at the density of at least 1,500/mm2 or simply with etched holes 0.5-10 &mgr;m in diameter emerging at the density of at least 2,000/mm2 when the blank is immersed in a 3% nitric acid-ethyl alcohol solution at 20° C. for 30 seconds. A method of manufacturing the blank comprises hot rolling of a slab of the Fe—Ni alloy, cooling, recrystallization annealing, cold rolling, etc. under controlled conditions: e.g., hot rolling the slab at 950-1,250° C. to 2-6 mm thick, cooling the stock in the range of 900-700° C. at the rate of 0.5° C./second, continuously passing the stock through a heating furnace at 850-1,100° C.

Abstract: An invar alloy steel sheet for shadow masks is provided which has improved etchability, an economical production method, a shadow mask made of the invar alloy steel sheet, and a color picture tube which incorporates the shadow mask. The invar alloy steel sheet is produced by hot working an alloy slab consisting of 33 top 40 wt % nickel with the balance being iron, and then subjecting the slab to a primary cold rolling at a rolling reduction ratio of not more than 80%, annealing at a temperature of at least 550° C., and subjecting the slab to a secondary cold rolling at a rolling reduction ratio of not more than 50%. The invar alloy steel sheet has a percentage of {100} texture of 60 to 80%.

Abstract: A method of heat-treating a work piece of high-alloy steel by hardening involves relatively briefly annealing the work piece before hardening, followed by cooling the work piece. The brief annealing that is performed before the actual hardening and the ensuing cooling results in homogeneity of the material in the microscopic range. Following the annealing, the work piece is hardened, for instance by quenching in a salt bath, to achieve a super fine distribution of globular carbides in the microscopic structure with considerably reduced size as compared to the outset state. Also, the microscopic structure created by the method of the invention has improved toughness properties as well as increased microscopic structure stability to aging and leads to a longer service life.

Abstract: Composition segregation which results in streaks in an Fe--Ni alloy sheet shadow-mask is prevented by the following conditions. Heat-treatment from 1150.degree. C. to a temperature lower than the melting point for longer than 1 hour and not longer than 30 hours. Subsequent rough-rolling or forging at a reduction of area of 40% or more. A slab is subjected to removal of oxide scale on its surface and then heated in hydrogen atmosphere having dew point of 10.degree. C. or lower at a temperature of not less than 1100.degree. C. and lower than the melting point for time (t - hour) which is defined by:t.gtoreq.[3.8.times.10.sup.-7 exp (23830/T)]/R,where R is reduction area (%) at the slab production.

Abstract: The present invention provides a highly corrosion-resistant alloy used as a boiler tube in equipment the energy source of which is obtained by burning fossil fuel or waste, a steel tube for which the alloy is used, and a process for producing the steel tube. The alloy comprises up to 0.05% of C, 1.0 to 2.6% of Si, 0.02 to 1.0% of Mn, 20.0 to 28.0% of Cr, 18.0 to 30.0% of Ni, up to 4.0% of Mo, up to 0.05% of Al, 0.05 to 0.30% of N and the balance Fe and unavoidable impurities. Furthermore, the present invention also provides a multilayer steel tube having the alloy as a liner material and a standardized boiler tube as a base layer material, and a process for producing the multilayer steel tube.

Abstract: This process makes it possible to manufacture articles of any shape by stamping, in which articles the matrix of the alloy has to have a coarse-grained structure. According to the invention, a partial hot-forming operation is carried out by stamping a blank made of an oxide-dispersion-strengthened alloy, especially a nickel-based alloy, having an initial ultrafine-grained structure, in order to form a shaped component, this shaped component is subjected to a secondary recrystallization heat treatment so as to develop an abnormal grain growth, and then a new hot-forming operation is carried out by stamping in order to give the recrystallized shaped component the final shape of the article.

Abstract: An extra high tensile steel having an excellent stress corrosion cracking resistance in sea water and a yield strength of 1080 MPa or more is provided. A slab comprising, in terms of % by weight, 0.04 to 0.09% of C, 0.01 to 0.10% of Si, 0.05 to 0.65% of Mn, 8.0 to 11.0% of Ni, 0.5 to 1.5% of Mo, 0.2 to 1.5% of Cr, 0.02 to 0.20% of V and 0.01 to 0.08% of Al with the balance consisting of iron and unavoidable impurities is heated to a temperature between 1000.degree. C. and 1250.degree. C., hot rolled at a temperature of Ar' point or above, air-cooled, reheated at a rate of 120.degree. C./min or less to a temperature region of from (A.sub.C3 point--40.degree. C.) to (A.sub.C3 point+40.degree. C.), quenched and subsequently tempered at a temperature of the A.sub.C1 point or below.

Abstract: A method for manufacturing an alloy sheet for a shadow mask is provided which includes: (i) annealing a hot-rolled sheet containing Fe and Ni at a temperature of 910.degree. to 990.degree. C.; (ii) cold-rolling the annealed hot-rolled sheet from step (i) to produce a cold-rolled sheet; (iii) crystallization annealing of the cold-rolled sheet from step (ii); (iv) cold-rolling the annealed cold rolled sheet from step (iii); (v) finish recrystallization annealing step of the cold-rolled sheet of step (iv); (vi) finish cold-rolling of the sheet from step (v) at a cold-rolling reduction ratio R (%) satisfying the following equations: 16.ltoreq.R.ltoreq.75 and 6.38 D-133.9.ltoreq.R.ltoreq.6.38 D-51.0 wherein D is the average austenite grain size in .mu.m; (vii) softening annealing the sheet from step (vi) at a temperature of 720.degree. to 790.degree. C. for 2 to 40 minutes before press-forming and at conditions of temperature T in .degree.C. and time t in minutes which satisfy the following equation :T.gtoreq.-53.

Abstract: A method for manufacturing an alloy sheet comprising the steps of: (a) hot-rolling a slab containing Fe, Ni and Cr into a hot-rolled strip; (b) annealing the hot-rolled strip at a temperature of 810.degree. to 890.degree. C.; (c) cold-rolling the annealed hot-rolled strip at a reduction ratio of 81 to 94% into a cold-rolled sheet; (d) recrystallization annealing of the cold-rolled sheet; (e) finish cold-rolling the cold-rolled sheet subjected to the recrystallization annealing at a reduction ratio of 14 to 29%; (f) stress relief annealing of the cold-rolled sheet subjected to the finish cold-rolling; and (g) annealing, before press-forming. The cold-rolled sheet subjected to the stress relief annealing at a temperature of 740.degree. to 900.degree. C. for 2 to 40 minutes and satisfying the following equation: T.ltoreq.-123 logt+937, where T is a temperature (.degree.C.) and t is a time (minutes) for the annealing.

Abstract: A thin Fe--Ni alloy sheet for shadow mask consists essentially of Ni of 34 to 38 wt. %, Si of 0.05 wt. % or less, B of 0.0005 wt. % or less, O of 0.002 wt. % or less and N of 0.0015% or less, the balance being Fe and inevitable impurities; said alloy sheet after annealing before press-forming having 0.2% proof stress of 28.5 kgf/mm.sup.2 or less; and a degree of {211} plane on a surface of said alloy sheet being 16% or less. And further modified similar alloy sheets are also provided.Further, a method for producing a thin Fe--Ni alloy sheet for shadow mask comprises the steps of: (a) hot-rolling of a slab into a hot-rolled alloy strip; (b) hot-rolled sheet annealing of the hot-rolled strip at 910.degree. to 990.degree. C.; (c) cold-rolling of the annealed hot-rolled strip into a cold-rolled strip; (d) recrystallization annealing of the cold-rolled strip; (e) finish cold-rolling of the recrystallization annealed strip at a finish cold reduction ratio in response to austenite grain size D(D.mu.

Abstract: A thin Fe--Ni alloy sheet for shadow mask consists essentially of Ni of 34 to 38 wt. %, Si of 0.05 wt. % or less, B of 0.0005 wt. % or less, O of 0.002 wt. % or less and N of 0.0015% or less, the balance being Fe and inevitable impurities; said alloy sheet after annealing before press-forming having 0.2% proof stress of 28.5 kgf/mm or less; and a degree of {211 } plane on a surface of said alloy sheet being 16% or less. And further modified similar alloy sheets are also provided.Further, a method for producing a thin Fe--Ni alloy sheet for shadow mask comprises the steps of: (a) hot-rolling of a slab into a hot-rolled alloy strip; (b) hot-rolled sheet annealing of the hot-rolled strip at 910.degree. to 990.degree. C.; (c) cold-rolling of the annealed hot-rolled strip into a cold-rolled strip; (d) recrystallization annealing of the cold-rolled strip; (e) finish cold-rolling of the recrystallization annealed strip at a finish cold reduction ratio in response to austenite grain size D(D .mu.

Abstract: A thin Fe--Ni alloy sheet for shadow mask consists essentially of Ni of 34 to 38 wt. %, Si of 0.05 wt. % or less, B of 0.0005 wt. % or less, O of 0.002 wt. % or less and N of 0.0015% or less, the balance being Fe and inevitable impurities; said alloy sheet after annealing before press-forming having 0.2% proof stress of 28.5 kgf/mm.sup.2 or less; and a degree of {211} plane on a surface of said alloy sheet being 16% or less. And further modified similar alloy sheets are also provided.Further, a method for producing a thin Fe--Ni alloy sheet for shadow mask comprises the steps of: (a) hot-rolling of a slab into a hot-rolled alloy strip; (b) hot-rolled sheet annealing of the hot-rolled strip at 910.degree. to 990.degree. C.; (c) cold-rolling of the annealed hot-rolled strip into a cold-rolled strip; (d) recrystallization annealing of the cold-rolled strip; (e) finish cold-rolling of the recrystallization annealed strip at a finish cold reduction ratio in response to austenite grain size D(D .mu.

Abstract: Disclosed is a large alloy forging, the forging having an alloy composition selected from one of a nickel base alloy, a cobalt-chromium-nickel base alloy, a nickel-cobalt base alloy and an iron-nickel-chromium-molybdenum alloy, the forging having a grain size of ASTM grain size 3 or finer, as measured by ASTM method E112 and having a tensile strength in the range of 135 to 175 KSI.

Abstract: Disclosed is a large alloy forging and method for making it. The forging having an alloy composition selected from one of a nickel base alloy, a cobalt-chromium-nickel base alloy, a nickel-cobalt base alloy and an iron-nickel-chromium-molybdenum alloy and having a grain size of ASTM grain size 4 or finer, as measured by ASTM method E112 and having a tensile strength in the range of 135 to 175 KSI. The process includes: (1) four upset forgings, (2) a rapid cooling after the final upset cooling, (3) a first and second upset forging with a reduction greater than 50%, (4) a third upset forging with a reduction greater than 25.%, and (5) a forging process with a fourth upset forging with a reduction greater than 50%.

Abstract: An Fe-Ni alloy sheet for a shadow mask, which consists essentially of:nickel: from 34 to 38 wt. %,silicon: from 0.01 to 0.15 wt. %,manganese: from 0.01 to 1.00 wt. %, andthe balance being iron and incidental impurities.The surface portion of the alloy sheet has a silicon (Si) segregation rate, as expressed by the following formula, of up to 10%: ##EQU1## and a center-line mean roughness (Ra) of the alloy sheet satisfies the following formula:0.3 .mu.m<.ltoreq.Ra .ltoreq.0.7 .mu.m.The above-mentioned Fe-Ni alloy sheet is manufactured by preparing an Fe-Ni alloy sheet having the chemical composition and the silicon segregation rate as described above, and imparting a center-line mean roughness (Ra) which satisfies the above-mentioned formula onto the both surfaces of the alloy sheet by means of a pair of dull rolls during the final rolling of the alloy sheet for said preparation.

Abstract: A high-strength lead frame material consists, by weight, of 0.5 to 22% Co, 22 to 32.5% Ni, not more than 1.0% Mn, not more than 0.5% Si, at least one kind of 0.1 to 3.0% in total selected from the group consisting of Nb, Ti, Zr, Mo, V, W and Be, and the balance Fe and incidental impurities; the total content of Ni and Co being selected so that the content of Ni is in the range of 27 to 32.5% when the content of Co is less than 12% and so that 66%.ltoreq.2Ni+Co.ltoreq.74% is met when the content of Co is not less than 12%; the lead frame material having a duplex-phase structure composed of a reverse-transformed austenite phase (which can involve a residual austenite phase) and a martensite phase; and the austenite phase being not less than 50%.

Abstract: An Fe-Ni alloy sheet for a shadow mask excellent in etching pierceability, preventing sticking during annealing, and inhibiting production of gases, which consists essentially of:______________________________________ nickel (Ni) from 34 to 38 wt. %, silicon (Si) from 0.01 to 0.09 wt. %, aluminum (Al) from 0.002 to 0.020 wt. %, calcium (Ca) from 0.0002 to 0.0020 wt. %, magnesium (Mg) from 0.0003 to 0.0020 wt. %, where, Ca + 1/2 Mg from 0.0005 to 0.0025 wt. %, ______________________________________andthe balance being iron and incidental impurities,where, the contents of carbon (C), nitrogen (N), sulfur (S), oxygen (O) and phosphorus (P) as the incidental impurities being respectively:up to 0.0050 wt.% for carbon,up to 0.0020 wt.% for nitrogen,up to 0.0020 wt.% for sulfur,up to 0.0040 wt.% for oxygen, andup to 0.0040 wt.% for phosphorus,where, 1/10 C+1/10 N+S+1/5 O+1/2P:up to 0.0045 wt.%, andCa+1/2 Mg.gtoreq.

Abstract: An Fe-Ni alloy sheet excellent in hot workability, adhesivity to a plating layer and solderability, which consists essentially of:______________________________________ nickel (Ni): from over 38 to 52 wt. %, silicon (Si): from 0.01 to 0.15 wt. %, calcium (Ca): from 0.0002 to 0.0020 wt. %, magnesium (Mg): from 0.0003 to 0.0020 wt. %, where, Ca + 1/2Mg: from 0.0005 to 0.0025 wt. %, ______________________________________and the balance being iron and incidental impurities,where, the contents of carbon (C), nitrogen (N), sulfur (S), oxygen (O), phosphorus (P) and aluminum (Al) as the incidental impurities being respectively:up to 0.0050 wt. % for carbon,up to 0.0020 wt. % for nitrogen,up to 0.0020 wt. % for sulfur,up to 0.0040 wt. % for oxygen,up to 0.0040 wt. % for phosphorus, andunder 0.010 wt.% for aluminum,where, 1/10 C+1/10 N+S+1/5 O +1/2 P.ltoreq.0.0045 wt.

Abstract: A high-fineness shadow mask material comprising 33-40% by weight of Ni, 0.0001-0.0015% by weight of one or more of boron, magnesium and titanium, and the remainder consisting essentially of Fe, wherein the contents of sulfur and aluminum are confined to not more than 0.0020% and not more than 0.020% by weight, respectively, and a process for producing the material. The shadow mask material according to this invention is excellent in hot working property and in etching properties.

Abstract: For the annealing of steel in continuously operating units, the formation of so-called white dust is almost completely eliminated by subjecting the steel to a deoxidizing pretreatment before the annealing sequence so as to at least largely remove the oxygen adsorbed on the surface of the steel, as well as any oxygen compounds also present on the surface.

Abstract: In composition of a Fe-Ni alloy used for television shadow masks and containing in, Co, Mn, Si and Cr as the major components, additional inclusion of Be assures high deformation resistance and easy pore formation via etching without impairing its inherent low thermal expansion. Introduction of annealing at 800.degree. to 1200.degree. C. temperature into production process sufficiently lowers proof stress of the product without causing any noticeable crystal coarseness. Increased mechanical strength enables production of a thin shadow mask material well suited for pore formation via etching, thereby assuring high grade screen display.

Abstract: A method of improving the low temperature ductility of an iron-aluminide is taught. The aluminide for which the method is applicable is one having between 30 and 50 atom percent of aluminum. The aluminide may also have substituents for part of the iron and for the aluminum. The alloy may contain up to 10 atom percent of substituents for the iron selected from the group of metals comprising nickel cobalt chromium and manganese. The alloy may also contain substituents for the aluminum of up to 5 atom percent of a metal selected from the group comprising titanium, niobium, tantalum, hafnium, zirconium, vanadium, and silicon. The alloy has a B2 crystal structure. The first step of the process is to select the metal to be processed. The next step is to directionally solidify the selected metal. The next step is to determine the Ductile Brittle Transition Temperature (DBTT). The metal is then heated to above the DBTT and is deformed while above the DBTT temperature.

Abstract: An Fe-Ni alloy sheet for a shadow mask, which consists essentially of:nickel: from 34 to 38 wt. %,silicon: from 0.01 to 0.15 wt. %,manganese: from 0.01 to 1.00 wt. %, andthe balance being iron and incidental impurities;the surface portion of the alloy sheet having a silicon (si) segregation rate, as expressed by the following formula, of up to 10%: ##EQU1## and the alloy sheet having a surface roughness which satisfies all the following formulae (1) to (3):0.3 .mu.m.ltoreq.Ra.ltoreq.0.8 .mu.m (1)where, Ra: center-line mean roughness;3.ltoreq.Rkr.ltoreq.

Abstract: The invention relates to a high-hardness steel for armouring having the following chemical composition by weight: 0.4 to 0.7% of carbon, 0.3 to 1.5% of manganese, 0.1 to 2% of chromium, 0.5 to 1.5% of silicon, 1 to 5% of nickel, 0.2 to 1% of molybdenum, less than 0.015% of phosphorus and less than 0.005% of sulphur, the remainder being iron and residual impurities resulting from the smelting of the materials necessary for the production.The invention also relates to a process for the production of such a steel.

Abstract: A method of passivating a zinc-cobalt alloy, which alloy has a cobalt content of 0.1-2%, by contacting the alloy with an aqueous composition which has a pH of 0.5-2.5 and contains hexavalent chromium, hydrogen ions to provide the pH, chloride ions and sulfate ions and which may also contain nickel and/or cobalt ions.

Abstract: A continuous process for coloring a stainless steel strip by continuously causing the strip to pass through a coloring solution wherein a potential difference between the steel of the strip and a reference electrode in the coloring solution is monitored regarding at least two positions where the strip is caused to pass, at least a part of the length of immersion of the strip in the coloring solution being present between the two positions; and processing conditions are controlled so that a variation in the difference between the monitored potential differences may be suppressed.

Abstract: The present invention includes an aqueous acidic chromate solution, suitable for forming colored chromate coatings on zinc-nickel alloy electrodeposits containing up to about 15% by weight nickel, which solutions have a pH within the range of about 1.3 to about 2.7, a hexavalent chromium concentration of at least 0.5 grams per liter, and preferably about 0.5 to about 100 grams per liter, and which contain sulfate in a weight ratio of SO.sub.4 :Cr.sup.+6 of about 0.025-1.5:1.The zinc-nickel alloy electrodeposits are preferably immersed in the chromating solution for a period sufficient to form the desired colored chromate coating. In some instances, a flash electrodeposit of zinc may be applied to the zinc-nickel alloy electrodeposit before it is immersed in the chromating solution.

Abstract: In order to obtain a film having a low electric resistance and a good selective absorption property of solar radiation, good rust proofing and good weldability, a stainless steel is dipped in a chemical conversion bath, in which sodium bichromate or potassium bichromate is mixed with sulfuric acid at a predetermined proportion to one another, in accordance with the method of the present invention. The product film of the present invention comprises metal oxides or metal hydroxides with metal (Fe+Cr) finely dispersed therein.

Abstract: The invention is an improved method for depositing a chromite coating onto a magnesium-containing material comprising:contacting the magnesium-containing material with a solution at least containing chromite ions and silicate ions for a time sufficient to deposit a corrosion resistant coating onto said magnesium-containing material;wherein the concentration of chromite ions in the solution is from about 0.2 to about 1.2 moles per liter; the concentration of silicate ions is from about 0.1 to about 0.3 moles per liter; the pH of the solution is from about 1 to about 5; and the temperature of the solution is from about 25.degree. C. to about 80.degree. C.

Abstract: In order to obtain a film having a low electric resistance and a good selective absorption property of solar radiation, good rust proofing and good weldability, a stainless steel is dipped in a chemical conversion bath, in which sodium bichromate or potassium bichromate is mixed with sulfuric acid at a predetermined proportion to one another, in accordance with the method of the present invention. The product film of the present invention comprises metal oxides or metal hydroxides with metal (Fe+Cr) finely dispersed therein.

Abstract: A material and process for preparing corrosion resistant reflective material. The process in the preferred embodiment comprises abrading a metal substrate, anodizing the metal substrate, depositing a thin film of substantially pure metal on the anodized substrate, and covering the reflective metal with a protective organic coating. The material produced is a metallic substrate having an anodized layer with a relatively thin film of reflective metal covered by a protective organic coating.

Abstract: An aqueous acidic solution and process for treating metal surfaces, particularly zinc and zinc alloy surfaces, for depositing a passivate film of improved clarity and hardness and to impart improved corrosion resistance thereto. The solution contains effective amounts of chromium ions substantially all of which are in the trivalent state, hydrogen ions to provide a pH of about 1.2 to about 2.5, an oxidizing agent, a bath soluble and compatible silicate compound present in an amount to provide improved corrosion protection to the substrate and increased hardness to the passivate film and at least one additional metal ion selected from the group consisting of iron, cobalt, nickel, molybdenum, manganese, aluminum, lanthanum, cerium, lanthanide mixtures as well as mixtures thereof. The treating solution may optionally further contain halide ions, a carboxylic acid or salt and a wetting agent.

Abstract: In continuously forming color display layer on the surface of the stainless steel strip, potential difference between the strip immersed in the oxidizing solution and a reference electrode is utilized for controlling the thickness, or color tone, of the color display layer, namely, the relationship between the thickness of the color display layer and the potential difference mentioned above is measured first, followed by continuously immersing a strip of the same kind in the oxidizing solution for forming a color display layer on the surface of the strip. The difference in thickness between the actually formed color display layer and a desired color display layer is converted into the difference in potential difference based on the above-noted relationship and the immersion time of the strip in the oxidizing solution is controlled on the basis of said difference in potential difference.

Abstract: A process for treating metal surfaces, particularly zinc and zinc alloy surfaces, for depositing a passivate film of improved corrosion resistance and hardness which comprises the steps of providing an aqueous acidic solution containing effective amounts of chromium ions substantially all of which are in the trivalent state, hydrogen ions to provide a pH of about 1.2 to about 2.

Abstract: An aqueous acidic solution and process for treating metal surfaces, particularly zinc and zinc alloy surfaces, to impart improved corrosion resistance thereto. The solution contains effective amounts of chromium ions substantially all of which are in the trivalent state, hydrogen ions to provide a pH of about 1.5 to about 2.2, an oxidizing agent, iron ions in combination with at least one additional metal ion selected from the group consisting of cobalt, nickel, molybdenum, manganese, lanthanum and mixtures thereof. The treating solution may optionally further contain halide ions and a wetting agent.

Abstract: An aqueous acidic solution and process for treating receptive metal surfaces, particularly zinc and zinc alloy surfaces, to impart a light-yellow iridescent passivate film thereon imparting improved corrosion resistance thereto. The aqueous solution contains effective amounts of chromium ions substantially all of which are in the trivalent state, hydrogen ions to provide a pH of about 1.2 to about 2.5, an oxidizing agent and cerium ions present in an amount effective to activate the bath and promote the formation of a light-yellow passivate film on the metal substrate. The treating solution may optionally further contain halide ions, a wetting agent and additional metal ions selected from the group consisting of iron, cobalt, nickel, molybdenum, manganese, lanthanum, lanthanide mixtures of rare earth oxides as well as mixtures thereof.

Abstract: An aqueous acidic solution and process for treating metal surfaces, particularly zinc and zinc alloy surfaces, for depositing a passivate film of improved clarity and hardness and to impart improved corrosion resistance thereto. The solution contains effective amounts of chromium ions substantially all of which are in the trivalent state, hydrogen ions to provide a pH of about 1.2 to about 2.5, an oxidizing agent, a bath soluble and compatible organic carboxylic acid or metal salts thereof present in an amount to impart increased initial hardness and improved clarity to the passivate film and at least one additional metal ion selected from the group consisting of iron, cobalt, nickel, molybdenum, manganese, lanthanum, cerium, lanthanide mixtures as well as mixtures thereof. The treating solution may optionally further contain halide ions and a wetting agent.

Abstract: A surface treatment method for tin-free steel, which comprises applying a water solution, containing a polymer obtained from one or two or more kinds of monomers of unsaturated carboxylic acids, on to the surface of a steel sheet having a metallic chromium layer formed thereon and having a film, mainly consisting of hydrated chromic oxide, formed on the above layer, and then conducting heating and drying. The coating of tin-free steel obtained by this method is excellent in adhesiveness and is most suitable for bonded cans requiring high-temperature treatment.

Abstract: This invention relates to a method for coloring stainless steel by controlling the potential difference between the surface of the stainless steel being colored and a reference electrode in a coloring liquor, characterized by differentiating a potential-time curve showing the variation with time of the potential difference between the surface of the stainless steel and the reference electrode by time to prepare the differentiation curve thereof and removing the stainless steel from the coloring liquor when the potential difference has changed from the coloring starting point that is the inflexion point on this differentiation curve, at which the variation amount of the potential per unit time changes from a falling tendency to a rising tendency, by a predetermined amount associated with the desired color.

Abstract: No-rinse compositions and a process are provided for inhibiting corrosion of ferrous or non-ferrous metal surfaces and for producing a surface to which synthetic resin coating compositions will adhere so that the resultant coatings have satisfactory impact and bending resistance, together with resistance to creeping corrosion between the metal and the dried resin coating.

Abstract: Aqueous acidic chromate coating solutions are described for treating zinc, zinc alloy, or cadmium surfaces comprising trivalent chromium as substantially the only chromium ion present, fluoride ion and an acid, the trivalent chromium ions comprising a mixture of green and blue trivalent chromium. One method of preparing the green trivalent chromium is by reducing an aqueous solution of hexavalent chromium with sufficient reducing agent to reduce all of the hexavalent chromium to trivalent chromium. The blue trivalent chromium can be prepared by reducing hexavalent chromium with reducing agent and adding an acid and fluoride ion (pH<1). Chromate coatings on zinc, zinc alloy and cadmium surfaces are produced by contacting said surfaces with an aqueous acidic solution of the invention.

Abstract: Aqueous acidic coating solutions are described for treating zinc or zinc alloy surfaces comprising trivalent chromium as substantially the only chromium ion present, fluoride ion, an acid other than nitric acid, and an oxidizing agent. The coating solutions containing trivalent chromium as substantially the only chromium ion present preferably are prepared by reducing an aqueous solution of hexavalent chromium with sufficient reducing agent to reduce all of the hexavalent chromium to trivalent chromium. Chromate coatings on zinc and zinc alloy surfaces are produced by contacting said surfaces with an aqueous acidic solution of the invention.

Abstract: A method of producing chromium conversion coatings is described. The coatings are novel in that they are chromite i.e. Cr.sub.2 O.sub.3 coatings rather than the conventional chromate i.e. CrO.sub.3 coatings. The invention includes a novel electrolyte for depositing chromite layers. The electrolyte is an aqueous solution containing Cr.sup.III ions, a weak complexing agent for Cr.sup.III ions and a poison for the electrodeposition of chromium metal. The electrolyte preferably also contains conductivity salts and may include other additives such as fluoride ion and boric acid. Examples of poisons are Cr.sup.VI ions, peroxide, nitrate, polyamines, phosphates and formaldehyde. The chromite conversion coatings can be improved by aging and can be subsequently painted or lacquered. The electrolytes of the present invention are much less corrosive than Cr.sup.VI electrolytes and thus the substrates which can be coated include materials which cannot readily be chromate coated because they are reactive towards Cr.sup.

Abstract: Compositions for forming chromate coatings on zinc metal or zinc alloys typically contain water as a solvent with hexavalent chromium compounds therein as active ingredients. Such hexavalent chromium compounds are environmentally undesirable. An aqueous composition for forming a chromate coating on zinc metal or zinc alloys is provided which does not contain hexavalent chromium compounds. The composition contains a trivalent chromium compound, an alum and a vanadate.

Abstract: The present invention relates to a selective absorption surface of a solar collector in which a coating layer consisting of the predetermined composition of metal oxide is tightly adhered to a substrate having the mirror-like surface in the predetermined thickness.The composition of metal oxide consists of those comprising 0.001 - 0.15 wt % of C, 0.005 - 3.00 wt % of Si, 0.005-10.00 wt % of Mn, 11.00 - 30.00 wt % of Cr, 0.005 - 22.00 wt % of Ni, optionally, 0.75 - 5.00 wt % of Mo and the balance being Fe or those comprising instead of Cr, 0.001 - 5.0 wt % of at least one of metals selected from the group of N, Cu, Al, V, Y, Ti, Nb, Ta, U, Th, W, Zr, and Hf, the atom ratio of Metal/Carbon + additional element being more than 5.0. An acidic oxidation method and an alkaline oxidation method are applied to manufacture oxide of the metal compositions.It has been observed that the superior selective absorption surface showing high energy absorption factor at a wave length of 0.3 - 2.5 .mu.

Abstract: A bright finish on a copper or copper alloy metal piece is sealed by dipping the piece in an aqueous solution of sodium bichromate, chromic acid and sulfuric acid followed by rinsing in cold and then hot water. The sealed piece is quite resistant to corrosion.

Abstract: The properties of black chromate coatings on zinc and cadmium metal substrates are improved by treating the coating with an aqueous solution of sodium thiosulphate, sodium thioglycolate or thio urea. Treatment of the black chromate coating ensures that light fastness and corrosion resistance are reliably obtained.

Abstract: A method for coloring a stainless steel using a potential-time curve which comprises seeking for an individual coloring potential difference to be colored by compensating a standard coloring potential difference by difference between a standard inflexion point potential and an individual inflexion point potential, and stopping the coloring when the individual coloring potential changes in an amount corresponding to the individual coloring potential difference from the individual inflexion point potential.

Abstract: Methods of coating metal articles to protect them from corrosion, and the products of such methods. Metal articles which have been electroplated with zinc, cadmium, nickel or chromium, or which have been phosphated, are chromated, and coated with a hydrophobic thermosetting polymer, and heated to convert the polymer to a hard, adherent film. Multiple polymer coatings may be applied prior to heat curing, and the corrosion resistance of the coating is thereby vastly improved.