Abstract: A room temperature black coating for ferrous metal is formed in a solution based on selenium dioxide, an inorganic copper salt and an organic acid. The solution virtually eliminates the formation of a selenium iron precipitate which results from conventional blackening agents in which an inorganic acid such as phosphoric, sulfuric, nitric or hydrochloric acid is used. Further, the virtual elimination of the precipitate produces the additional benefit that the user needs handle and ultimately dispose of only an insignificant amount of toxic selenium iron or selenium phosphate compound materials.

Abstract: A composition and process is disclosed for improving the leach resistance of the copper oxide coating on the copper circuitry of printed circuit boards to solutions used in their preparation which comprises contacting the copper oxide of the circuit board with a solution containing an amphoteric element which forms an acidic oxide, such as selenium dioxide.

Abstract: Undesirable heavy metal peroxides formed during the continuous partial oxidation of cadmium electrodes made from a charged strip of material, by means of H.sub.2 O.sub.2, to introduce a charge reserve prior to incorporation in a sealed alkaline battery cell, are removed by an immersion treatment in an alkaline hydroxide solution, with simultaneous desorption of oxygen and removal of the heat of hydrogenation. A subsequent boric acid immersion bath is used to neutralize introduced alkaline residues and to improve the stability of the strip during storage. The phenomena which accompany peroxide decomposition (intense evolution of heat and sputtering of electrolyte) in the completely assembled cell during the introduction of the electrolyte, and which interfere with the metering of the electrolyte, are thus avoided.

Abstract: The use of modifiers such as disulfides and phosphines is particularly effective in modifying the properties of metals such as noble metals and silver. For example, disulfides are useful for modifying the properties of gold and silver while phosphines are useful for metals such as platinum and palladium. Through treatment with a suitable modifier it is possible to change properties such as the wetting and adhesion properties of the treated metal. Additionally, the use of modifiers to treat a desired substrate enhances formation of continuous metal films on this substrate.

Abstract: A process for producing chalcogenide semiconductor material is disclosed. The process includes forming a base metal layer and then contacting this layer with a solution having a low pH and containing ions from at least one chalcogen to chalcogenize the layer and form the chalcogenide semiconductor material.

Abstract: A composite cathode active material/current collector product useable as a component of a cathode for secondary batteries without the need for a separate current collector, which comprises a wire having a conductive interior portion of a transition metal and an exterior portion of an intercalatable layered transition metal chalcogenide, is made by a method which involves reacting a transition metal wire with a vapor of a chalcogen or a hydrogen chalcogenide.

Abstract: A method for the treatment of aluminum or aluminum alloy material comprising treating the material in a series of alkaline baths and a series of acid baths connected in series in regular order, said alkaline baths having an alkali concentration gradient continually decreasing from higher to lower values, the alkali concentration in the last stage bath being controlled to a defined level, and said acid baths having an acid concentration gradient continually decreasing from higher to lower values and the last stage bath being of pure water. The aluminum or aluminum alloy surface can be processed uniformly and economically by the instant process.

Abstract: A variety of coating resin latices may be deposited on metallic surfaces in the form of thin, pin hole-free polymer films from an alkaline latex comprising the coating latex, a cyanide salt and a water-soluble oxidizing agent. The coated substrates are resistant to fouling and to deposition of scale deposits when employed as heat transfer surfaces in cooling systems.

Abstract: In order to obtain a film having a low electric resistance and a good selective absorption property of solar radiation, good rust proofing and good weldability, a stainless steel is dipped in a chemical conversion bath, in which sodium bichromate or potassium bichromate is mixed with sulfuric acid at a predetermined proportion to one another, in accordance with the method of the present invention. The product film of the present invention comprises metal oxides or metal hydroxides with metal (Fe+Cr) finely dispersed therein.

Abstract: The present invention is directed to a method for improving the adhesion of epoxy resins to steel substrates which comprises first removing the oxide surface layer, preferably by chemical means, and then pretreating the substrate with a solution of at least one coupling agent selected from the group consisting of .beta.-diketones and mercaptoesters. The invention also provides a method for improving the adhesion of epoxy resins to steel substrates by pretreating with citric acid or a salt thereof.

Abstract: Nickel powders having an improved chemical stability are formed by reaction with an electroconductive coating such as a carbide, a silicide, or the like and, also, a reaction with sulfur.

Abstract: The invention concerns a fabrication process for a selective absorber of a solar collector to achieve a solar-radiation collection-surface with high absorptivity and low emissivity.The collector surface is made of an iron alloy containing chrome and is immersed in an acid bath containing oxygen atoms and at least one metalloid substance based on sulfur, selenium and/or tellurium; beforehand, the state of the collector surface is adjusted for activation.

Abstract: An object of the present invention is a method for the anti-wear treatment of the surface of steel parts having a carbon content of at least 0.15% and the coating obtained thereby. The method is characterized by the fact that an addition of sulfur, by depositing of a metal sulfide for example, and a vapor-phase chromizing are carried out in sucession on the surface to be treated.The coating obtained is characterized by the presence of a layer of chromium sulfide on the surface and by the partial recrystallization of the underlying M.sub.7 C.sub.3 chromium carbide layer.The invention can be applied to any moving mechanical system which is subject to abrasion. The invention has importance because it increases the resistance to wear and the life of the system treated while limiting the wear of the untreated opposing part as a result of friction.

Abstract: A low pH solution and a method for conversion coating aluminum and aluminum alloy surfaces, as well as the coated surfaces themselves, utilizing zirconium, fluoride and nickel and, optionally, fluorophosphate.

Abstract: A metal substrate is described herein, the metal substrate being one formed by contacting a metal surface, such as zinc, with a solution containing 0.1 to 2.5 weight percent salt selected from the group consisting of iron nitrate, nickel nitrate and copper nitrate, 0.01 to 3.5 weight percent of an oxidizing agent selected from the group consisting of perborates, peroxides, persulfates and perchlorates, 2 to 20 weight percent of a mineral acid selected from the group consisting of sulfuric acid and phosphoric acid and the remainder water, drying the contacted surface and thereafter applying an electrically conductive coating, such as graphite, thereon.

Abstract: Solutions and processes for accelerating the rate of application of a conversion coating to zinc surfaces utilizing an aqueous solution containing an oxidizing agent which is a bromate, nitrite, persulfate or hypochlorite; a cation of cobalt, nickel, iron or tin; a complexing agent to keep the cation in solution; and sufficient alkaline material to produce a pH of at least 10.5.

Abstract: A method of treating inorganic materials such as metals to ensure strong adhesion of a subsequently applied coating of another material, such as a paint, comprises the steps of applying to a surface of the material a composition containing a complexing agent comprising both a sulph-hydro and a carboxylic acid group and applying over the complexing agent a film-forming coating which also contains a complexing agent comprising both a sulph-hydro and a carboxylic acid group and/or an anti-oxidant.

Abstract: An aqueous acidic solution and process for treating receptive metal surfaces, particularly zinc and zinc alloy surfaces, to impart a passivate film thereon imparting improved corrosion resistance thereto. The aqueous solution contains effective amounts of hydrogen ions to provide a pH of about 1.2 to about 2.5, an oxidizing agent and a combination of iron and cobalt ions present in an amount effective to activate the bath and promote the formation of a passivate film on the metal substrate. The treating solution may optionally further contain cerium ions present in an amount to further activate the bath and to impart a light-yellow color to the passivate film, halide ions and a wetting agent.

Abstract: A steel stock such as hot-rolled pickled steel plate, cold-rolled steel plate, cast iron or the like is subjected to antirust treatment with an aqueous solution or an emulsion consisting mainly of a 1-hydroxybenzotriazole compound represented by the general formula: ##STR1## where X and Y represent hydrogen atoms and hydroxy, alkyl, carboxyl, nitro and sulfonic groups, and further containing one or more of aliphatic dicarboxylic acids added thereto, and having a pH within the range of 7-10.

Abstract: This invention relates to the process of inhibiting corrosion, and to compositions employed therein, which comprises coating copper with a barrier corrosion inhibitor, such as a water insoluble sulfonate, for example a petroleum or similar sulfonate as illustrated by a metal petroleum sulfonate, which contains an agent capable of complexing with copper, such as an organic sulfur, nitrogen, or sulfur-nitrogen compound for example an organic triazole, thiazole or the like. This process is particularly effective in inhibiting the corrosion of copper buried in the earth such as occurs when copper is exposed to electrochemical forces such as when copper is employed as neutral wires wrapped around the outside of an insulated power conducting cable and buried in the earth.

Abstract: Metal substrates in corrosive environments such as gas and oil pipelines, are normally prone to embrittlement caused by absorption of the hydrogen which is cathodically evolved during various corrosion processes. This is substantially prevented by providing an active substance in the vicinity of the metal substrate, and in electrical contact therewith, the active substance being one on which cathodic hydrogen evolution occurs in preference to the metal, thereby reducing the amount of hydrogen available for diffusion into the substrate. The active substrate is preferably a sulphide, for example FeS, or mixed sulphide, for example NiCo.sub.2 S.sub.4, and is advantageously applied as a coating on the surface of the substrate, a further coating of, for example, a thermosetting resin, preferably being employed for mechanical and environmental protection.

Abstract: The adhesion of brass plated steel cord to rubber is improved by treating the cord in a dilute acidic alcohol dip followed by treatment with H.sub.2 S gas or by treating the cord in a dilute aqueous ammonia dip, preferably followed by treatment with H.sub.2 S gas, before combining the cord with a vulcanizable rubber compound and vulcanizing the same.

Abstract: A method and composition are described for preparing metal surfaces, especially zinc, for receiving an electrically conductive coating, the preparatory composition being an aqueous solution containing about 2 to about 25 weight percent of the mixture of salts of heavy metals, an oxidizing agent, and a mineral acid. The preparatory coating has utility in battery manufacture.A preferred preparatory coating composition for zinc-base surfaces is a solution comprising about 0.1 to 2.5 weight percent salt of a heavy metal such as ferric nitrate, about 0.01 to about 3.5 weight percent of an oxidizing agent such as sodium or potassium persulfate, about 2 to about 20 weight percent of a mineral acid such as sulfuric acid (98%) or phosphoric acid (75%), and the remainder water. Another preferred preparatory coating composition for metal surfaces including zinc and zinc-base alloys is an aqueous solution consisting of about 0.1 to 2.5 weight percent salt of a heavy metal, about 0.01 to about 3.

Abstract: A process is provided for decreasing the rate of corrosion of titanium by a corrosive aqueous media containing dissolved acidic moieties in contact therewith at an elevated temperature in the substantial absence of molecular oxygen which comprises introducing into said corrosive aqueous medium at least one soluble tellurium or selenium compound or mixtures thereof as corrosion inhibitor, said corrosion inhibitor being introduced in an amount sufficient to provide at least about 1.times.10.sup.-6 gram-atoms of dissolved tellurium or selenium values per gram-mole of total acidic moieties in the corrosive aqueous medium.

Abstract: Substrates, especially those having plated metal surfaces, and subjected to passivation treatments in baths that incorporate one or more film-forming agents at least one of which does not require chromium and includes anions or cations of elements other than chromium. Typically, the anions or cations are introduced as bath-soluble salts which react with the plated surface of the substrate to form an adherent, coherent passivation surface film. Also present within these baths are a source of hydrogen ions and a bath-soluble carboxylic acid or derivative activator for enhancing the rate of the passivation reaction. Articles passivated in baths incorporating these film-forming agents have a hydrophobic surface that exhibits corrosion resistance and that typically has a bright finish.

Abstract: Cast iron is pretreated in an aqueous solution of nitric acid and then immersed in molten sulfur until a sulfurized layer is formed on its surface. The sulfurized layer is very thick and stable and has excellent molten aluminum resistance. Its uniformity is further improved by a subsequent diffusion treatment at elevated temperatures.

Abstract: Improved brightness and corrosion resistance are imparted to metal surfaces such as zinc plated surfaces, by treatment with a non-toxic solution comprised of sulfuric acid, hydrogen peroxide, a silicate, certain primary organophosphorus compound promoters and at least one secondary promoter selected from ascorbic acid, boric acid, gluconic acid, glycolic acid, tartaric acid and salts of said acids.

Abstract: Improved color, brightness and corrosion resistance are imparted to metal surfaces such as zinc plated surfaces, by treatment with a non-toxic solution comprised of sulfuric acid, hydrogen peroxide, a silicate and at least one cationic triarylmethane dye. Certain organophosphorus compound additives further enhance the corrosion resistance.

Abstract: Improved brightness and corrosion resistance are imparted to metal surfaces such as zinc plated surfaces, by treatment with a non-toxic solution comprised of sulfuric acid, hydrogen peroxide and a silicate. Certain organophosphorus and organonitrogen compound additives further enhance the corrosion resistance.

Abstract: A solar energy absorber consisting of a metallic copper or copper alloy substrate and a black to dark brown copper oxide coating on its surface. The copper oxide coating is formed by treating the surface of the substrate with an aqueous alkaline solution containing peroxodisulfuric acid or an inorganic peroxodisulfate. The solution may be activated by adding an oxidizing agent or applying ultraviolet or ultrasonic irradiation.

Abstract: An environmentally acceptable composition and process imparts improved corrosion resistance and paint adhesion to a conversion coated surface of zinc or zinc alloy. The coated surface is post-treated with an aqueous composition containing a thiourea compound and a vegetable tannin.

Abstract: Fuser members having surfaces of gold and the platinum groups metals and alloys thereof are described for fuser assemblies in office copier machines. Preferred fuser assemblies include cylindrical rolls having at least an outer surface of gold, a platinum group metal or alloys thereof. Electroscopic thermoplastic resin toner images are fused to a substrate by using a bare gold, a platinum group metal or alloys thereof fuser member coated with polymeric release agents having reactive functional groups for example, a mercapto-functional polysiloxane release fluid.

Abstract: A cathode electrode of copper-based material adapted for use in an electrical device is provided with a layer composed of at least one compound from the group of copper selenide, copper telluride and copper sulfide by the reaction between the copper-based cathode electrode and an appropriate reactive compound of selenium, tellurium or sulfur. When utilized in an electrolytic capacitor, the layer on the cathode electrode helps to depolarize the capacitor and helps to increase the capacitance of the cathode electrode.

Abstract: It has been found that esters and polyesters of thioglycolic acid, which form a protective, water insoluble complex with zinc atoms, are suitable for inhibiting wet storage staining and the formation of white rust in zinc and zinc coated materials. Many of these compounds are new products.

Abstract: A process for the electroless deposition of a metal layer on an article comprised of zirconium or a zirconium alloy is disclosed. The article is activated in an aged aqueous solution comprising from about 10 to about 20 grams per liter ammonium bifluoride and from about 0.75 to about 2 grams per liter of sulfuric acid. The solution is aged by immersion of pickled zirconium in the solution for at least about 10 minutes. The loosely adhering film formed on the article in the activating step is removed and the article is contacted with an electroless plating solution containing the metal to be deposited on the article upon sufficient contact with the article.

Abstract: A method of constructing a model tree structure and the article resulting therefrom constitute the present invention. First a full three-dimensional pattern is constructed from wire and tin-lead. The pattern is then partially flattened and placed in a rubber mold. The mold is filled in around the pattern with rubber and the entire mold with the pattern in place is heated to vulcanize the rubber and form a mold cavity conforming to the configuration of the pattern. A casting metal is provided which preferably is at least 98% lead. Up to 2% antimony may be added to increase flow characteristics. It is also permissible to include a quantity of tin. The part is cast in the mold using centrifugal casting techniques. After the part has solidified and been removed from the mold it is bent into full three-dimensional form corresponding generally to the initial shape of the pattern.

Abstract: The properties of black chromate coatings on zinc and cadmium metal substrates are improved by treating the coating with an aqueous solution of sodium thiosulphate, sodium thioglycolate or thio urea. Treatment of the black chromate coating ensures that light fastness and corrosion resistance are reliably obtained.

Abstract: A solar energy receiver comprising an aluminum panel and a coating which comprises a black metal sulfide film having a high solar absorptance but a low thermal emissivity and a method for the production of such a receiver by wet chemical deposition onto an aluminum panel of a metal sulfide film from an alkaline aqueous solution of a salt of a metal, a complexing agent for the metal ions, and a sulfur compound capable of reacting with the metal ions in the presence of aluminum to form a metal sulfide are disclosed.

Abstract: A method of providing improved corrosion resistance to coated metal substrates is disclosed. The process of the invention involves a passivating pretreatment with an onium salt before coating. The invention is particularly effective with ferrous metal substrates.

Abstract: A method of forming a low temperature seal on anodized aluminum and removing sealing smudge therefrom comprises treating anodized aluminum with an aqueous sealing solution at a temperature of at least 140.degree. F. and containing 2 to 6 g/l of hydrolyzable metallic salt, 5 to 20 ml/l of an ethanolamine and 50 to 2000 mg/l soluble sulfate (SO.sub.4 .sup.=), and thereafter removing sealing smudge formed by this treatment with mineral acid.

Abstract: A pretreatment of cold-rolled steel sheet for annealing so as to suppress graphite formation on the surface thereof and nitrogenization during the annealing for recrystallization, by causing an effective amount of sulfur, aluminum, tin, arsenic, lead, antimony, bismuth, selenium, and/or tellurium to exist on the steel sheet surface.

Abstract: Polyorgano siloxanes having functional mercapto groups are applied to a heated fuser member in an electrostatic reproducing apparatus to form thereon a thermally stable, renewable, self-cleaning layer having superior toner release properties for electroscopic thermoplastic resin toners. The polyorgano siloxane fluids having functional mercapto groups interact with the fuser member in such a manner as to form an interfacial barrier at the surface of the fuser member while leaving an unreacted, low surface energy release fluid as an outer layer or film. The interfacial barrier is strongly attached to the fuser member surface and prevents toner material from contacting the outer surface of the fuser member. The material on the surface of the fuser member is of minimal thickness and thereby represents a minimal thermal barrier.

Abstract: The method consists in preparing a mixture composed of 20-80 g of molybdenum disulphide and 1-5 g of sulphuric acid per liter of glycerine, heating said mixture from 180.degree. to 230.degree. C, holding the workpieces in said mixture for 3-7 hours in presence of brass, followed by washing the parts with a cooling liquid and drying them.

Abstract: Costume jewelry is manufactured through photofabrication processes from flat metal sheets to form items such as earrings and small pendants. A standard photo-fabrication operation includes covering a metal sheet with a layer of photosensitive, chemically resistive material commonly referred to as a photoresist. Portions of the covered sheet are exposed to light to outline the earrings and pendants on the sheet. The sheet is then developed and the exosed metal surface portions are chemically etched to remove excess metal and form the earrings and pendants. Thereafter, surface treatments involve supplementary photofabrication operations to provide different colors and finishes on the earrings and pendants by etching, plating and staining the exposed metal surfaces, all of which are supplemented by the retention of portons of photoresist layers of selected colors.

Abstract: A process for imparting a dark patina to the surface of an article formed from a low-melting alloy metal, the alloy metal being an alloy metal of two or more metals selected from the group consisting of Bi, Pb, Sn and Cd, comprising exposing the alloy metal surfaces of said article to an acid solution of a copper salt.