Titanium(ti) Or Titanium Base Alloy Patents (Class 148/669)
  • Patent number: 11650543
    Abstract: A spiral timepiece spring with a two-phase structure, made of a niobium and titanium alloy, and method for manufacturing this spring, including: producing a binary alloy containing niobium and titanium, with: niobium: the remainder to 100%; titanium: strictly greater than 60% and less than or equal to 85% by mass of the total, traces of components from among O, H, C, Fe, Ta, N, Ni, Si, Cu, Al; applying deformations alternated with heat treatments until a two-phase microstructure is obtained comprising a solid solution of niobium with ?-phase titanium and a solid solution of niobium with ?-phase titanium, the ?-phase titanium content being greater than 10% by volume, wire drawing to obtain wire able to be calendered; calendering or insertion into a ring to form a mainspring, in a double clef shape before it is wound for the first time, or winding to form a balance spring.
    Type: Grant
    Filed: November 25, 2019
    Date of Patent: May 16, 2023
    Assignee: Nivarox-FAR S.A.
    Inventor: Christian Charbon
  • Patent number: 11578399
    Abstract: The present disclosure relates to a titanium or titanium alloy member and to a surface hardening method for the titanium or titanium alloy member. The titanium or titanium alloy member includes a base material of titanium or titanium alloy, and at a surface of the base material, a hardened layer formed by diffusion of oxygen into the surface. The method includes: a heating step of heating the titanium or titanium alloy base material of the member to a predetermined temperature under an inert gas atmosphere; a hardening step of introducing (i) a mixed gas including an inert gas, and (ii) oxygen gas as a hardening treatment gas, to perform hardening treatment of the surface of the base material; and a cooling step of cooling the base material down to room temperature under the inert gas atmosphere.
    Type: Grant
    Filed: June 29, 2019
    Date of Patent: February 14, 2023
    Assignee: CASIO COMPUTER CO., LTD.
    Inventors: Junichi Sato, Kazuma Kobayashi, Shouta Nagasawa, Kenichi Inoue, Chinfu Liu, Wuchien Liu, Tienchai Lin, Weipin Kao
  • Patent number: 11542574
    Abstract: A TiAl alloy member for hot forging includes a substrate made of TiAl alloy, and an Al layer formed on a surface of the substrate, the Al layer containing Al as a main constituent and containing Ti.
    Type: Grant
    Filed: June 17, 2020
    Date of Patent: January 3, 2023
    Assignee: IHI Corporation
    Inventors: Keiji Kubushiro, Masanobu Baba, Yohei Sakakibara, Yutaro Ota
  • Patent number: 11186904
    Abstract: A method for manufacturing an ?+? Ti-6Al-4V alloy includes providing a near-net shape part made of an ?+? Ti-6Al-4V alloy, The part is heat treated in the ?+? field between 875 and 920° C. The heat treated part is water quenched to transform the ? phase into ?? martensite. There is no further heat treatment after the quenching step.
    Type: Grant
    Filed: May 4, 2017
    Date of Patent: November 30, 2021
    Assignee: UNIVERSITÉ LIBRE DE BRUXELLES
    Inventors: Stéphane Godet, Charlotte De Formanoir De La Cazerie
  • Patent number: 10822670
    Abstract: A controlled thermal coefficient product manufacturing system and method is disclosed. The disclosed product relates to the manufacture of metallic material product (MMP) having a thermal expansion coefficient (TEC) in a predetermined range. The disclosed system and method provides for a first material deformation (FMD) of the MMP that comprises at least some of a first material phase (FMP) wherein the FMP comprises martensite randomly oriented and a first thermal expansion coefficient (FTC). In response to the FMD at least some of the FMP is oriented in at least one predetermined orientation. Subsequent to deformation, the MMP comprises a second thermal expansion coefficient (STC) that is within a predetermined range and wherein the thermal expansion of the MMP is in at least one predetermined direction. The MMP may be comprised of a second material phase (SMP) that may or may not transform to the FMP in response to the FMD.
    Type: Grant
    Filed: July 22, 2016
    Date of Patent: November 3, 2020
    Inventors: James Alan Monroe, Ibrahim Karaman, Raymundo Arroyave
  • Patent number: 10107112
    Abstract: The invention relates to a method for producing a component from a TiAl alloy, wherein the component is shaped by forging, in particular isothermal forging, and is subsequently subjected to at least one heat treatment, wherein in the first heat treatment the temperature is between 1100 and 1200° C. and is maintained for 6 to 10 hours and then the component is cooled.
    Type: Grant
    Filed: January 19, 2013
    Date of Patent: October 23, 2018
    Assignee: MTU AERO ENGINES AG
    Inventor: Wilfried Smarsly
  • Patent number: 9982330
    Abstract: Disclosed herein is a shape memory alloy comprising 48 to 50 atomic percent nickel, 15 to 30 atomic percent hathium, 1 to 5 atomic percent aluminum; with the remainder being titanium. Disclosed herein too is a method of manufacturing a shape memory alloy comprising mixing together to form an alloy nickel, hafnium, aluminum and titanium in amounts of 48 to 50 atomic percent nickel, 15 to 30 atomic percent hafnium, 1 to 5 atomic percent aluminum; with the remainder being titanium; solution treating the alloy at a temperature of 700 to 1300° C. for 50 to 200 hours; and aging the alloy at a temperature of 400 to 800° C. for a time period of 50 to 200 hours to form a shape memory alloy.
    Type: Grant
    Filed: November 25, 2014
    Date of Patent: May 29, 2018
    Assignee: University of Florida Research Foundation, Inc.
    Inventors: Michele Viola Manuel, Derek Hsen Dai Hsu
  • Patent number: 9963977
    Abstract: Components include a low pressure turbine having a plurality of rotor assemblies including a first gamma TiAl intermetallic blade having a maximum operating temperature over 1180° F. (638° C.). At least two of the rotor assemblies include gamma TiAl intermetallic alloy blades. In an embodiment, a method of making a turbine having a plurality of rotor assemblies includes attaching a first gamma TiAl intermetallic alloy blade to an upstream stage of the plurality of rotor assemblies.
    Type: Grant
    Filed: September 29, 2015
    Date of Patent: May 8, 2018
    Assignee: UNITED TECHNOLOGIES CORPORATION
    Inventors: Gabriel L. Suciu, James D. Hill, Gopal Das
  • Patent number: 9822431
    Abstract: The present invention provides a ?-type titanium alloy that includes, by mass %, when Al: 2 to 5%, 1) Fe: 2 to 4%, Cr: 6.2 to 11%, and V: 4 to 10%, 2) Fe: 2 to 4%, Cr: 5 to 11%, and Mo: 4 to 10%, or 3) Fe: 2 to 4%, Cr: 5.5 to 11%, and Mo+V (total of Mo and V): 4 to 10% in range, and a balance of substantially Ti. These include Zr added in amounts of 1 to 4 mass %. Furthermore, by making the oxygen equivalent Q 0.15 to 0.30 or leaving the alloy in the work hardened state or by applying both, the tensile strength before aging heat treatment can be further increased.
    Type: Grant
    Filed: January 25, 2012
    Date of Patent: November 21, 2017
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Kazuhiro Takahashi, Hideki Fujii, Kenichi Mori
  • Patent number: 9382607
    Abstract: A method and a product made through it by utilizing Zirconium alloys containing Titanium in the manufacture of metal articles of sports, night stealth compatible articles for law enforcement and military equipment, night-stealth personal and body adornments for members of such forces, garden and household implements, fashion accessories, body art articles, and medical and dental implants, and other articles. The articles benefit from any combination of properties from being hypo-allergenic, possessing high tensile strength, abrasion resistance, and hardness, having low ductility and elasticity and of having the outer appearance within the scale of dark grey to blackness. In this method an alloy of components in their respective ratios from within the method's stipulated preferred range is shaped into a workpiece by conventional metal forming devices and methods, and then subjected to an oxidation process and optional quenching steps.
    Type: Grant
    Filed: August 2, 2012
    Date of Patent: July 5, 2016
    Assignee: MARIA DA COSTA DEsign Inc
    Inventor: Gad Zak
  • Patent number: 9205171
    Abstract: Systems and methods for hydrogen out gas of a porous metal scaffold are disclosed. A method can comprise heating a porous metal scaffold for a period of time sufficient to remove at least a portion of a hydrogen concentration from the scaffold, subjecting the porous metal scaffold to a vacuum while heating it, flowing an inert gas through or around the porous metal scaffold while heating it, and enhancing a mechanical property of the porous metal scaffold. Heating of the porous metal scaffold can include maintaining a temperature of the scaffold between 1035° C. and 1065° C., inclusive. A system can comprise a reaction chamber, a heater, a gas feed, and a vacuum apparatus. The heater can be configured to heat the reaction chamber and the porous metal scaffold, while the gas feed and the vacuum apparatus respectively flow inert gas and subject the porous metal scaffold to a vacuum.
    Type: Grant
    Filed: June 25, 2013
    Date of Patent: December 8, 2015
    Assignee: Zimmer, Inc.
    Inventors: Edward M. Willis, Mae Abiog, Joseph R. Vargas
  • Patent number: 9120151
    Abstract: Substantially defect-free titanium aluminide components and methods are provided for manufacturing the same from articles formed by consolidation processes. The method includes providing an intermediate article comprised of a titanium aluminide alloy and formed by a consolidation process. The intermediate article is encapsulated with an aluminum-containing encapsulation layer. The intermediate article is compacted after the encapsulation step. A substantially defect-free titanium aluminide component comprises a compacted three-dimensional article comprised of titanium aluminide and formed by a consolidation process and an aluminum-containing encapsulation layer on at least one surface of the compacted three-dimensional article. The aluminum-containing encapsulation layer comprises an aluminide material, MCrAlY wherein M is cobalt, nickel, or a combination of cobalt and nickel, or TiAlCr.
    Type: Grant
    Filed: August 1, 2012
    Date of Patent: September 1, 2015
    Assignee: HONEYWELL INTERNATIONAL INC.
    Inventors: Donald G. Godfrey, Mark C. Morris, George Reimer, William F. Hehmann, Daira Legzdina, Richard Fox, Yiping Hu, Harry Lester Kington
  • Patent number: 9039963
    Abstract: A titanium based, ceramic reinforced alloy ingot for use in producing medical implants. An ingot is formed from an alloy having comprising from about 5 to about 35 wt. % niobium, from about 0.5 to about 3.5 wt. % silicon, and from about 61.5 to about 94.5 wt. % of titanium. The alloy has a hexagonal crystal lattice ? phase of from about 20 vol % to about 70 vol %, and a cubic body centered ? crystal lattice phase of from about 30 vol. % to about 80 vol. %. The ingot has an ultimate tensile strength of about 940 MPa or more, and a Young's modulus of about 150 GPa or less. A molten substantially uniform admixture of a niobium, silicon, and titanium alloy is formed, cast into a shape, and cooled into an ingot. The ingot may then be formed into a medical implant and optionally annealed.
    Type: Grant
    Filed: October 12, 2012
    Date of Patent: May 26, 2015
    Assignee: Pulse Technologies, Inc.
    Inventors: Andrew E. Fisk, Anatolii Demchyshyn, Mykola Kuzmenko, Sergei Firstov, Leonid Kulak
  • Publication number: 20140295988
    Abstract: A golf club head with an improved striking face is disclosed herein. More specifically, the present invention utilizes an innovative die quenching method that can alter the Young's modulus of the material of the striking face. The striking face portion of the present invention generally created from an ?+? titanium alloy such as SP 700 that contains a ? rich alloy composition to create more phase change in the alloying elements. In a preferred embodiment, the die quenching process could create a localized change in the material's Young's modulus throughout different regions of the striking face, resulting in a change in the Young's modulus of the material within the same striking face.
    Type: Application
    Filed: April 1, 2013
    Publication date: October 2, 2014
    Inventors: Ryuichi Sugimae, Uday V. Deshmukh, Heng-Jui Henry Yeh
  • Patent number: 8813360
    Abstract: In a method for beam welding on components with a laser beam or electron beam generated by a beam source, the heat treatment of the welded component required to remove stresses is integrated into the welding process. In a work cycle combined with the welding process, a regulated heat supply to a selected region takes place, according to its residual heat resulting from the welding process and the predicted stresses in that region, using the residual heat remaining from the welding process following the welding process from the same or other beam source(s). The welding region is cooled in a controlled manner, so that welded components which are likely to be subject to high stress in use, provided for example for a aircraft engine, can be made available without inherent stresses and with the desired microstructure in a single—combined—work step.
    Type: Grant
    Filed: October 6, 2011
    Date of Patent: August 26, 2014
    Assignees: Rolls-Royce PLC, Rolls-Royce Deutschland Ltd & Co KG
    Inventors: Daniel Clark, Claudia Berkenhoff, Claus T Haubold
  • Patent number: 8771439
    Abstract: The invention is directed to a method for producing a titanium aluminide intermetallic alloy composition having an improved wear resistance, the method comprising heating a titanium aluminide intermetallic alloy material in an oxygen-containing environment at a temperature and for a time sufficient to produce a top oxide layer and underlying oxygen-diffused layer, followed by removal of the top oxide layer such that the oxygen-diffused layer is exposed. The invention is also directed to the resulting oxygen-diffused titanium aluminide intermetallic alloy, as well as mechanical components or devices containing the improved alloy composition.
    Type: Grant
    Filed: April 1, 2009
    Date of Patent: July 8, 2014
    Assignee: UT-Battelle, LLC
    Inventors: Jun Qu, Hua-Tay Lin, Peter J. Blau, Vinod K. Sikka
  • Publication number: 20140185977
    Abstract: A titanium alloy that is created to be formed into a bearing component, wherein the titanium alloy comprises from 5 to 7 wt % Al, from 3.5 to 4.5 wt % V, from 0.5 to 1.5 wt % Mo, from 2.5 to 4.5 wt % Fe, from 2.5 to 4.5 wt % Fe, from 0.05 to 2 wt % Cr. The alloy can optionally include one or more of the following elements: up to 2.5 wt % Zr, up to 2.5 wt % Sn, and up to 0.5 wt % C. The balance of the composition comprises Ti together with unavoidable impurities.
    Type: Application
    Filed: April 26, 2012
    Publication date: July 3, 2014
    Applicant: AKTIEBOLAGET SKF
    Inventors: Alejandro Sanz, Alejandro De Vries
  • Publication number: 20140127068
    Abstract: Disclosed is a method of producing an object, the object being made of metal or an alloy, having a desired shape and being non-porous, the method comprising: providing some metal or alloy having a first average solute level; using the provided metal or alloy, performing a net-shape or near-net shape manufacturing process to produce an intermediate object, the intermediate object having the desired shape, being non-porous, and having a second average solute level, the second average solute level being greater than or equal to the first average solute level; and performing a solute level changing process on the intermediate object to change the solute level of at least the bulk of the intermediate object such as to provide the intermediate object with a third average solute level, thereby providing the object, the third average solute level being different to the second.
    Type: Application
    Filed: June 6, 2012
    Publication date: May 8, 2014
    Inventor: Charles Malcolm Ward-Close
  • Publication number: 20140116581
    Abstract: A method for preparing titanium alloy that is created to be formed into a bearing component, wherein the titanium alloy comprises from 5 to 7 wt % Al, from 3.5 to 4.5 wt % V, from 0.5 to 1.5 wt % Mo, from 2.5 to 4.5 wt % Fe, from 2.5 to 4.5 wt % Fe, and from 0.05 to 2 wt % Cr. The alloy can optionally include one or more of the following elements: up to 2.5 wt % Zr, up to 2.5 wt % Sn, and up to 0.5 wt % C. The balance of the composition comprises Ti together with unavoidable impurities. The alloy is heated to a temperature T below the (?+?/?)-transition temperature T? and then quenched. The alloy is then aged a temperature of from 400 to 600° C.
    Type: Application
    Filed: April 26, 2012
    Publication date: May 1, 2014
    Applicant: AKTIEBOLAGET SKF
    Inventors: Alejandro Sanz, Alexander Vries De
  • Patent number: 8702877
    Abstract: A cathodic member for electrochemical cells used in hypochlorite production comprises a zirconium plate coated with a zirconium oxide layer, which is particularly suitable for minimising the decomposition of the hypochlorite product while ensuring a prolonged lifetime. The coated zirconium plate can be used as the cathodic plate in a monopolar cell, or can be welded to a titanium plate for use in a bipolar configuration.
    Type: Grant
    Filed: March 28, 2011
    Date of Patent: April 22, 2014
    Assignee: Industrie de Nora S.p.A.
    Inventors: Carl W. Brown, Jr., Richard C. Carlson, Kenneth L. Hardee
  • Patent number: 8597443
    Abstract: A method of forming an article from an ?-? titanium including, in weight percentages, from about 2.9 to about 5.0 aluminum, from about 2.0 to about 3.0 vanadium, from about 0.4 to about 2.0 iron, from about 0.2 to about 0.3 oxygen, from about 0.005 to about 0.3 carbon, from about 0.001 to about 0.02 nitrogen, and less than about 0.5 of other elements. The method comprises cold working the ?-? titanium alloy.
    Type: Grant
    Filed: September 12, 2011
    Date of Patent: December 3, 2013
    Assignee: ATI Properties, Inc.
    Inventors: John J. Hebda, Randall W. Hickman, Ronald A. Graham
  • Patent number: 8597442
    Abstract: A method of forming an article from an ??? titanium including, in weight percentages, from about 2.9 to about 5.0 aluminum, from about 2.0 to about 3.0 vanadium, from about 0.4 to about 2.0 iron, from about 0.2 to about 0.3 oxygen, from about 0.005 to about 0.3 carbon, from about 0.001 to about 0.02 nitrogen, and less than about 0.5 of other elements. The method comprises cold working the ??? titanium alloy.
    Type: Grant
    Filed: September 12, 2011
    Date of Patent: December 3, 2013
    Assignee: ATI Properties, Inc.
    Inventors: John J. Hebda, Randall W. Hickman, Ronald A. Graham
  • Patent number: 8545644
    Abstract: The present invention is aimed at providing a method for producing a vacuum-insulated double container that exhibits a remarkable and heretofore unobtainable operating effect. The invention provides a method for producing a vacuum-insulated double container by placing a titanium internal cylinder (2) into a titanium external cylinder (1) via a space section (S), and using the space section (S) between the external cylinder (1) and the internal cylinder (2) as a vacuum-insulating space section, the method comprising the steps of degassing the space section (S) of a workpiece (3) that includes the external cylinder (1) and the internal cylinder (2), and vacuum sealing a degassing hole while the workpiece (3) is heated in a vacuum heating furnace (6); and then providing concavoconvex portions (4, 5) to a surface of the recrystallized external cylinder (1) and the internal cylinder (2) by placing the workpiece (3) in an atmospheric-pressure environment.
    Type: Grant
    Filed: March 16, 2011
    Date of Patent: October 1, 2013
    Assignee: Seven—seven Co., Ltd.
    Inventor: Shuichi Shibuki
  • Publication number: 20130233456
    Abstract: The invention relates to a monolithic titanium alloy (M) comprising, in a temperature range (?T) and at atmospheric pressure: an outer peripheral zone consisting of a micro-structure (m1) having a modulus of elasticity (E1) and possessing superelastic properties in said range (?T), and a core consisting of a microstructure (m2) having a modulus of elasticity (E2), and possessing elastic properties in said range (?T); said microstructures (m1) and (m2) being different from one another, and said modulus of elasticity (E1) being lower than said modulus of elasticity (E2).
    Type: Application
    Filed: November 4, 2011
    Publication date: September 12, 2013
    Applicant: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
    Inventors: Frédéric Prima, Sophie Nowak
  • Patent number: 8492002
    Abstract: An alloy having from about 5 to about 15 wt % Ta, from 0 to about 5 wt % Nb, from about 0.5 to about 15 wt % Zr, and the balance Ti is disclosed. The alloy is particularly intended for medical devices, such as implants for the body.
    Type: Grant
    Filed: September 23, 2009
    Date of Patent: July 23, 2013
    Assignee: Sandvik Intellectual Property AB
    Inventor: Susanne Norgren
  • Publication number: 20130139933
    Abstract: A titanium-molybdenum alloy having ?? phase as a major phase is subjected to an aging treatment, so that yield strength of the aged alloy is increased by 10% to 120% with elongation to failure thereof being not less than about 5.0%.
    Type: Application
    Filed: December 6, 2012
    Publication date: June 6, 2013
    Applicant: NATIONAL CHENG KUNG UNIVERSITY
    Inventor: National Cheng Kung University
  • Patent number: 8454768
    Abstract: A high strength near-beta titanium alloy including, in weight %, 5.3 to 5.7% aluminum, 4.8 to 5.2% vanadium, 0.7 to 0.9% iron, 4.6 to 5.3% molybdenum, 2.0 to 2.5% chromium, and 0.12 to 0.16% oxygen with balance titanium and incidental impurities is provided. An aviation system component comprising the high strength near-beta titanium alloy, and a method for the manufacture of a titanium alloy for use in high strength, deep hardenability, and excellent ductility applications are also provided.
    Type: Grant
    Filed: March 29, 2012
    Date of Patent: June 4, 2013
    Assignee: Titanium Metals Corporation
    Inventor: John Fanning
  • Patent number: 8444775
    Abstract: Shape Memory Alloy tube is protected from damage during drawing, caused by galling-type interaction between the tube and high-carbon dies, by forming an oxide surface layer. This invention protects the tube internal diameter from oxidation while allowing the tube outside diameter to be oxidized, by using an oxygen getter located within the tube during the oxidation step. The method yields a higher quality internal diameter and improves productivity.
    Type: Grant
    Filed: September 26, 2008
    Date of Patent: May 21, 2013
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Edwin Alfred Crombie, III, William Andrew Hochella
  • Patent number: 8388776
    Abstract: A description is given of a method for the heat treatment of a workpiece produced from a titanium alloy for obtaining a fine-grained microstructure by annealing the same above its ?-transus temperature T?. According to the invention, the workpiece is heated in a furnace to a temperature level TH above its ?-transus temperature T?. Reaching the temperature level TH determines the beginning of a predefined holding time, for which the workpiece is kept at this temperature level TH. The workpiece subsequently undergoes a cooling process. To carry out the heat treatment, the furnace temperature TF is set such that, for heating up the workpiece to the temperature level intended for carrying out the holding, it lies above the temperature level TH of the workpiece determining the beginning of the holding time.
    Type: Grant
    Filed: January 29, 2010
    Date of Patent: March 5, 2013
    Assignee: Otto Fuchs KG
    Inventors: Markus Buscher, Thomas Witulski
  • Publication number: 20130037183
    Abstract: The invention relates to a process for the preparation of a part made of titanium alloy, comprising a thermal treatment for relaxing the internal stresses of the part, the thermal treatment comprising maintaining at a temperature “T1” greater than the beta transus (beta transition) temperature, referred to as “Tbt”, and the part being free to deform by creeping. The invention also relates to a tool for carrying out this process.
    Type: Application
    Filed: October 20, 2010
    Publication date: February 14, 2013
    Applicant: AUBERT & DUVAL
    Inventors: Christophe Daffos, Michel Miquel, Laurent Foucher, Vincent Albert
  • Patent number: 8349248
    Abstract: A metallic material is made from at least one refractory metal or an alloy based on at least one refractory metal. The metallic material has an oxygen content of about 1,000 to about 30,000 ?g/g and the oxygen is interstitial.
    Type: Grant
    Filed: April 13, 2006
    Date of Patent: January 8, 2013
    Assignee: Heraeus Precious Metals GmbH & Co. KG
    Inventors: Jens Trotzschel, Bernd Spaniol
  • Publication number: 20120255657
    Abstract: A method of improving the properties of a component of a medical device entails constraining the component, which comprises about 45-55 at. % Ni, about 45-55 at. % Ti, and about 0.3 at. % Cr, into a predetermined configuration. The component also includes at least about 35% cold work. The component is heated during the constraining at a temperature of between about 425° C. and about 500° C. for a time duration of between about 5 minutes and about 30 minutes, thereby improving the superelastic and mechanical properties of the component. A medical device includes a superelastic component for use in a body vessel that comprises about 45-55 at. % Ni, about 45-55 at. % Ti, and about 0.3 at. % Cr, where the component has an upper plateau strength of at least about 75 ksi, a residual elongation of about 0.1% or less, and an austenite finish temperature (Af) of about 30° C. or less.
    Type: Application
    Filed: November 17, 2010
    Publication date: October 11, 2012
    Inventor: James M. Carlson
  • Patent number: 8262819
    Abstract: The present disclosure describes methods of heat treating Ti-based alloys and various improvements that can be realized using such heat treatments. In one exemplary implementation, the invention provides a method of forming a metal member that involves forming an alloy into a utile shape and cooling the alloy from a first temperature above a beta transus temperature of the alloy to a second temperature below the beta transus temperature at a cooling rate of no more than about 30° F./minute. If so desired, the alloy my be treated for a period of about 1-12 hours at about 700-1100° F. Titanium alloys treated according to aspects of the invention may have higher tensile strengths and higher fracture toughness than conventional wrought, mill-annealed Ti 64 alloy.
    Type: Grant
    Filed: July 6, 2010
    Date of Patent: September 11, 2012
    Assignee: The Boeing Company
    Inventor: Robert D. Briggs
  • Patent number: 8262814
    Abstract: Method, and articles therefrom, for providing a hard, abrasion-resistant, attractive, oxide surface layer of selectable thickness and having an outer appearance within the scale from gray to blackness, to a zirconium titanium alloy article by heating the article in an oxygen containing atmosphere.
    Type: Grant
    Filed: November 17, 2008
    Date of Patent: September 11, 2012
    Inventor: Gad Zak
  • Patent number: 8252130
    Abstract: Surface processing of titanium alloy members for aerospace equipment imparts high wear resistance, lubricity and high fatigue strength. The method includes an oxygen diffusion step for causing oxygen to diffuse and penetrate in solid solution form into a surface of a titanium alloy member under an oxygen-containing gas atmosphere and a particle bombardment step for bombarding the surface of the titanium alloy member with an airflow containing particles. The aerospace equipment can include a flap rail member and slat rail member for aircraft.
    Type: Grant
    Filed: February 16, 2005
    Date of Patent: August 28, 2012
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Kazuyuki Oguri, Takashi Kimura, Takahiro Sekigawa, Takayuki Takahashi
  • Patent number: 8225478
    Abstract: The disclosure provides bearing sleeves or bushings made of memory shape material, and processes for installing such bearing sleeves or bushings. In one process, inner and outer surfaces of a bearing sleeve, made of a memory shape material, may be compressed at least one first temperature. A bearing may be inserted in a cavity of the bearing sleeve, and the bearing sleeve may be disposed adjacent to a surface of a structure, while the bearing sleeve is at the at least one first temperature. The inner and outer surfaces of the bearing sleeve may be expanded, at least one second temperature, to abut against the bearing and the surface of the structure.
    Type: Grant
    Filed: January 30, 2008
    Date of Patent: July 24, 2012
    Assignee: The Boeing Company
    Inventor: Daniel J. Kane
  • Publication number: 20120181385
    Abstract: A high strength near-beta titanium alloy including, in weight %, 5.3 to 5.7% aluminum, 4.8 to 5.2% vanadium, 0.7 to 0.9% iron, 4.6 to 5.3% molybdenum, 2.0 to 2.5% chromium, and 0.12 to 0.16% oxygen with balance titanium and incidental impurities is provided. An aviation system component comprising the high strength near-beta titanium alloy, and a method for the manufacture of a titanium alloy for use in high strength, deep hardenability, and excellent ductility applications are also provided.
    Type: Application
    Filed: March 29, 2012
    Publication date: July 19, 2012
    Applicant: TITANIUM METALS CORPORATION
    Inventor: John Fanning
  • Publication number: 20120180913
    Abstract: A method for refining the microstructure of titanium alloys in a single thermomechanical processing step, wherein the titanium alloy comprises boron. In some embodiments, the method comprises the steps of first adding boron to the titanium alloy then subjecting the boron-containing titanium alloy to a thermomechanical processing step. Also provided is a method for achieving superplasticity in titanium alloys comprising the steps of selecting a boron-containing titanium alloy, determining the temperature and strain rate necessary to achieve beta superplasticity, and applying sufficient temperature and strain rate to the boron-containing titanium alloy to deform the alloy to the desired shape. Also provided methods of forming titanium alloy parts and the parts prepared by these methods.
    Type: Application
    Filed: January 6, 2012
    Publication date: July 19, 2012
    Inventors: Daniel B. Miracle, Seshacharyulu Tamirisakandala, Radhakrishna B. Bhat, Jaimie S. Tiley
  • Publication number: 20120118444
    Abstract: A titanium alloy having at least 4% by weight aluminum and at least 0.1% by weight oxygen, the alloy also including at least one element selected from vanadium, molybdenum, chromium, and iron. The titanium alloy also includes hafnium in a proportion by weight of at least 0.1%.
    Type: Application
    Filed: June 8, 2010
    Publication date: May 17, 2012
    Applicant: MESSIER-DOWTY SA
    Inventors: Francis Soniak, Jean-Michel De Monicault
  • Publication number: 20120107132
    Abstract: A titanium alloy having high strength, fine grain size, and low cost and a method of manufacturing the same is disclosed. In particular, the inventive alloy offers a strength increase of about 100 MPa over Ti 6-4, with a comparable density and near equivalent ductility. The inventive alloy is particularly useful for a multitude of applications including components of aircraft engines. The Ti alloy comprises, in weight percent, about 6.0 to about 6.7% aluminum, about 1.4 to about 2.0% vanadium, about 1.4 to about 2.0% molybdenum, about 0.20 to about 0.42% silicon, about 0.17 to about 0.23% oxygen, maximum about 0.24% iron, maximum about 0.08% carbon and balance titanium with incidental impurities.
    Type: Application
    Filed: January 12, 2012
    Publication date: May 3, 2012
    Applicant: TITANIUM METALS CORPORATION
    Inventors: Roger Thomas, Paul Garratt, John Fanning
  • Publication number: 20120000581
    Abstract: A description is given of a method for the heat treatment of a workpiece produced from a titanium alloy for obtaining a fine-grained microstructure by annealing the same above its ?-transus temperature T?. According to the invention, the workpiece is heated in a furnace to a temperature level TH above its ?-transus temperature T?. Reaching the temperature level TH determines the beginning of a predefined holding time, for which the workpiece is kept at this temperature level TH. The workpiece subsequently undergoes a cooling process. To carry out the heat treatment, the furnace temperature TF is set such that, for heating up the workpiece to the temperature level intended for carrying out the holding, it lies above the temperature level TH of the workpiece determining the beginning of the holding time.
    Type: Application
    Filed: January 29, 2010
    Publication date: January 5, 2012
    Applicant: OTTO FUCHS KG
    Inventors: Markus Buscher, Thomas Witulski
  • Patent number: 8083873
    Abstract: Endodontic instruments for use in performing root canal therapy on a tooth are disclosed. In one form, the instruments include an elongate shank having a cutting edge extending from a distal end of the shank along an axial length of the shank. The shank comprises a titanium alloy, and the shank is prepared by heat-treating the shank at a temperature above 25° C. in an atmosphere consisting essentially of a gas unreactive with the shank. In another form, the endodontic instruments have an elongate shank having a cutting edge extending from a distal end of the shank along an axial length of the shank. The shank consists essentially of a titanium alloy selected from alpha-titanium alloys, beta-titanium alloys, and alpha-beta-titanium alloys. The instruments solve the problems encountered when cleaning and enlarging a curved root canal.
    Type: Grant
    Filed: December 23, 2010
    Date of Patent: December 27, 2011
    Assignee: Gold Standard Instruments, LLC
    Inventor: Neill Hamilton Luebke
  • Patent number: 8075713
    Abstract: A production of precision castings by centrifugal casting, includes the following steps: a) providing in a crucible (8) a melt of the following composition: Ti45-52 at. %Al45-50 at. %Xl1-3 at. %X22-4 at. %X30-1 at. %/ where Xl =Cr, Mn, V, X2=Nb, Ta, W, Mo, X3=Si, B, C; b) forcing the melt by means of centrifugal forces from the crucible (8) into a mold (4); c) solidifying the melt within the mold thereby creating a casting consisting of a titanium alloy having a lamellar microstructure; and d) reheating the casting for a duration of 60 to 150 hours at a temperature higher than the eutectic temperature and lower than the alpha-transus temperature of the composition.
    Type: Grant
    Filed: April 11, 2007
    Date of Patent: December 13, 2011
    Inventor: Manfred Renkel
  • Patent number: 8062440
    Abstract: A hafnium alloy target containing either or both of Zr and Ti in a gross amount of 100 wtppm-10 wt % in Hf, wherein the average crystal grain size is 1-100 ?m, the impurities of Fe, Cr and Ni are respectively 1 wtppm or less, and the habit plane ratio of the plane {002} and three planes {103}, {014} and {015} lying within 35° from {002} is 55% or greater, and the variation in the total sum of the intensity ratios of these four planes depending on locations is 20% or less. As a result, obtained is a hafnium alloy target having favorable deposition property and deposition speed, which generates few particles, and which is suitable for forming a high dielectric gate insulation film such as HfO or HfON film, and the manufacturing method thereof.
    Type: Grant
    Filed: September 4, 2008
    Date of Patent: November 22, 2011
    Assignee: JX Nippon Mining & Metals Corporation
    Inventors: Takeo Okabe, Shuichi Irumata, Yasuhiro Yamakoshi, Hirohito Miyashita, Ryo Suzuki
  • Patent number: 8048240
    Abstract: A method of forming an article from an ??? titanium including, in weight percentages, from about 2.9 to about 5.0 aluminum, from about 2.0 to about 3.0 vanadium, from about 0.4 to about 2.0 iron, from about 0.2 to about 0.3 oxygen, from about 0.005 to about 0.3 carbon, from about 0.001 to about 0.02 nitrogen, and less than about 0.5 of other elements. The method comprises cold working the ??? titanium alloy.
    Type: Grant
    Filed: May 7, 2007
    Date of Patent: November 1, 2011
    Assignee: ATI Properties, Inc.
    Inventors: John J. Hebda, Randall W. Hickman, Ronald A. Graham
  • Patent number: 7985307
    Abstract: Article (e.g., turbine engine fan or compressor blade) comprising a titanium alloy has a first portion with alpha+beta microstructure and a second portion with martensitic or a bimodal microstructure. The modified microstructure of the second portion is provided by selectively heating, and immediately quenching, the second portion without substantially heating the first portion. An exemplary method includes providing a near net-shaped article having a first portion (e.g., an airfoil region) and a second portion (e.g., an unfinished dovetail region). Initially, the article comprises an alpha+beta microstructure throughout. Thereafter, the second portion is selectively heated, followed by immediate quenching, without substantially heating the first portion, to modify the microstructure of the second portion to a martensitic or bimodal microstructure without substantially modifying the microstructure of the first portion. Thereafter, the second portion may be processed to a final body dimension.
    Type: Grant
    Filed: May 30, 2008
    Date of Patent: July 26, 2011
    Assignee: General Electric Company
    Inventors: Kazim Ozbaysal, William Houchens, William Miller, Jesse Moses
  • Publication number: 20110120601
    Abstract: Endodontic instruments for use in performing root canal therapy on a tooth are disclosed. In one form, the instruments include an elongate shank having a cutting edge extending from a distal end of the shank along an axial length of the shank. The shank comprises a titanium alloy, and the shank is prepared by heat-treating the shank at a temperature above 25° C. in an atmosphere consisting essentially of a gas unreactive with the shank. In another form, the endodontic instruments have an elongate shank having a cutting edge extending from a distal end of the shank along an axial length of the shank. The shank consists essentially of a titanium alloy selected from alpha-titanium alloys, beta-titanium alloys, and alpha-beta-titanium alloys. The instruments solve the problems encountered when cleaning and enlarging a curved root canal.
    Type: Application
    Filed: December 23, 2010
    Publication date: May 26, 2011
    Inventor: Neill Hamilton Luebke
  • Patent number: 7892369
    Abstract: A titanium alloy subjected to thermal treatment followed by quenching. The thermal treatment raises the temperature of the alloy to a temperature above the alloy's recrystallization temperature and below the alloy's beta-transus temperature to cause a phase shift within the alloy. After the thermal treatment has been applied for a predetermined time, the alloy is rapidly quenched, preserving the phase shift induced by the thermal treatment. By the present method, the microstructure of the titanium alloy is changed from a fine grained alpha-beta phase to a microstructure substantially comprised of an equiaxed alpha phase and an acicular or plate-like alpha phase. The resulting prostheses may have a microstructure including between 25% and 75% percent acicular alpha phase, for example.
    Type: Grant
    Filed: April 19, 2007
    Date of Patent: February 22, 2011
    Assignee: Zimmer, Inc.
    Inventor: Shushil K. Bhambri
  • Publication number: 20100320317
    Abstract: A high strength near-beta titanium alloy including, in weight %, 5.3 to 5.7% aluminum, 4.8 to 5.2% vanadium, 0.7 to 0.9% iron, 4.6 to 5.3% molybdenum, 2.0 to 2.5% chromium, and 0.12 to 0.16% oxygen with balance titanium and incidental impurities is provided. An aviation system component comprising the high strength near-beta titanium alloy, and a method for the manufacture of a titanium alloy for use in high strength, deep hardenability, and excellent ductility applications are also provided.
    Type: Application
    Filed: May 28, 2010
    Publication date: December 23, 2010
    Applicant: TITANIUM METALS CORPORATION
    Inventor: John Fanning
  • Publication number: 20100276040
    Abstract: To provide a method of producing a strengthened alloy capable of shortening the time necessary for aging treatment and obtaining a strengthened alloy with enhanced tensile strength. The method of producing a strengthened alloy comprises a solution treatment step S1 of immersing an alloy material into molten lithium held at a solution treatment temperature higher than solution temperature of solute metal of the alloy material, a solution stop step S2 of immersing the alloy material into molten lithium held at a cooling temperature lower than the solution treatment temperature after the solution treatment step S1, an aging treatment step S3 of immersing the alloy material into molten lithium held at an aging treatment temperature lower than the solution temperature after the solution stop step S2, and an aging stop step S4 of immersing the alloy material into molten lithium held at an aging stop temperature lower than the aging treatment temperature after the aging treatment step S3.
    Type: Application
    Filed: April 22, 2010
    Publication date: November 4, 2010
    Applicant: JAPAN THERMOTECH CO., LTD.
    Inventor: Susumu Ninomiya