Amorphous Semiconductor Patents (Class 148/DIG1)
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Patent number: 6124186Abstract: A method or producing hydrogenated amorphous silicon on a substrate, comprising the steps of: positioning the substrate in a deposition chamber at a distance of about 0.5 to 3.0 cm from a heatable filament in the deposition chamber; maintaining a pressure in said deposition chamber in the range of about 10 to 100 millitorr and pressure times substrate-filament spacing in the range of about 10 to 100 millitorr-cm, heating the filament to a temperature in the range of about 1,500 to 2,000.degree. C., and heating the substrate to a surface temperature in the range of about 280 to 475.degree. C.Type: GrantFiled: April 24, 1998Date of Patent: September 26, 2000Assignee: Midwest Research InstituteInventors: Edith C. Molenbroek, Archie Harvin Mahan, Alan C. Gallagher
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Patent number: 5981326Abstract: This invention is a processing method for electrically isolating CMOS transistors. The method involves implanting a channel stop dopant into field regions between transistor active regions, self aligning relatively thick silicon dioxide over these field regions and providing thin oxide in the active regions that are self aligned to the field regions. The method does not require any shallow trench isolation (STI), and does not require Local Oxidation of Silicon (LOCOS), thereby resulting in little damage to the silicon.Type: GrantFiled: March 23, 1998Date of Patent: November 9, 1999Inventor: Frank M. Wanlass
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Patent number: 5946601Abstract: The present invention is a liner and/or barrier layer that will encapsulate the low k materials and act as a diffusion barrier between the low k material and the surrounding metal layers. As the temperatures of the processing sequence increase the liner and/or barrier layer will decrease the diffusion of fluorine from the low k material into the surrounding metal layers. Thus, the present invention will reduce potential corrosion problems of the metal layers.Type: GrantFiled: December 31, 1997Date of Patent: August 31, 1999Assignee: Intel CorporationInventors: Lawrence D. Wong, Indrajit Banerjee, Steven Towie
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Patent number: 5902650Abstract: A method of depositing an amorphous silicon based film that has controlled resistivity in between that of an intrinsic amorphous silicon and an n.sup.+ doped amorphous silicon on a substrate for an electronic device by a chemical vapor deposition process or a plasma-enhanced chemical vapor deposition process.Type: GrantFiled: July 11, 1995Date of Patent: May 11, 1999Assignee: Applied Komatsu Technology, Inc.Inventors: Jeff Feng, Robert Robertson, Kam Law
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Patent number: 5894037Abstract: A silicon semiconductor substrate including a silicon semiconductor layer at one of upper and lower surfaces thereof, the silicon semiconductor layer being composed of polysilicon or noncrystal silicon and containing oxygen in the range of 2 atomic % to 20 atomic % both inclusive, nitrogen in the range of 4 atomic % to 20 atomic % both inclusive, or both nitrogen at 2 atomic % or greater and oxygen at 1 atomic % or greater. The polysilicon or noncrystal silicon semiconductor layer acts as a core for extrinsic gettering. In the silicon semiconductor substrate, the gettering performance is not deteriorated, even if the silicon semiconductor substrate experiences thermal treatment. Thus, it is possible to get rid of contamination caused by heavy metals in the silicon semiconductor substrate.Type: GrantFiled: November 15, 1996Date of Patent: April 13, 1999Assignee: NEC CorporationInventors: Hiroaki Kikuchi, Seiichi Shishiguchi
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Patent number: 5874129Abstract: A method of producing amorphous silicon layers on a substrate by chemical vapor deposition at elevated pressures of at least about 25 Torr whereby deposition occurs at practicable rates. A substrate is loaded in a vacuum chamber, the temperature adjusted to obtain an amorphous silicon deposit of predetermined microcrystalline density, and the silicon precursor gases fed to the chamber to a preselected high pressure. Doped amorphous silicon films also can be deposited at high deposition rates.The above amorphous silicon films have a low density of nucleation sites; thus when the films are annealed, polycrystalline films having large crystal grains are produced.Type: GrantFiled: December 10, 1996Date of Patent: February 23, 1999Assignee: Applied Materials, Inc.Inventors: Israel Beinglass, Mali Venkatesan
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Patent number: 5863598Abstract: A method of forming a doped silicon film on a substrate. According to the present invention, a substrate is placed in a reaction chamber and heated. Next, a silicon containing gas is fed into the reaction chamber to produce a silicon containing gas partial pressure of between 4 and 20 torr.Type: GrantFiled: April 12, 1996Date of Patent: January 26, 1999Assignee: Applied Materials, Inc.Inventors: Mahalingam Venkatesan, Shulin Wang, Vedapuram S. Achutharaman
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Patent number: 5811323Abstract: There is Disclosed a semiconductor device comprising a silicon film formed on a substrate having at least a surface formed of an insulative material, the silicon film being heat-treated at a temperature below 600.degree. C. and being partially coated with a silicon oxide film formed by electronic cyclotron resonance plasma CVD.Type: GrantFiled: September 27, 1996Date of Patent: September 22, 1998Assignee: Seiko Epson CorporationInventors: Mitsutoshi Miyasaka, Thomas W. Little
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Patent number: 5789030Abstract: A method for forming an in-situ doped amorphous or polycrystalline silicon thin film on a substrate is provided. The method includes placing the substrate in a reaction chamber of a CVD reactor and introducing a silicon gas species into the reaction chamber. The flow of the silicon gas species is continued for a time period sufficient to dehydrate the substrate and form a thin layer of silicon. Following formation of the thin layer of silicon, a dopant gas species is introduced into the reaction chamber and continued with the flow of the silicon gas species to form the doped silicon thin film. In an illustrative embodiment a phosphorus doped amorphous silicon thin film for a cell plate of a semiconductor capacitor is formed in a LPCVD reactor.Type: GrantFiled: March 18, 1996Date of Patent: August 4, 1998Assignee: Micron Technology, Inc.Inventor: J. Brett Rolfson
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Patent number: 5776819Abstract: A method of producing hydrogenated amorphous silicon on a substrate by flowing a stream of safe (diluted to less than 1%) silane gas past a heated filament.Type: GrantFiled: May 25, 1994Date of Patent: July 7, 1998Assignee: Midwest Research InstituteInventors: Archie Harvin Mahan, Edith C. Molenbroek, Brent P. Nelson
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Patent number: 5700520Abstract: A method of producing doped and undoped silicon layers on a substrate by chemical vapor deposition at elevated pressures of from about 10 to about 350 Torr whereby deposition occurs at practicable rates. A substrate is loaded in a vacuum chamber, the temperature adjusted to obtain a silicon deposit of predetermined crystallinity, and the silicon precursor gases fed to the chamber to a preselected high pressure. Both undoped and doped silicon can be deposited at high rates up to about 3000 angstroms per minute.Type: GrantFiled: June 19, 1996Date of Patent: December 23, 1997Assignee: Applied Materials, Inc.Inventors: Israel Beinglass, David K. Carlson
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Patent number: 5686320Abstract: The present invention relates to a method for manufacturing a thin film transistor which can improve the yield, characteristics and reliability of the thin film transistor by selectively forming a semiconductor layer on a desired portion of a substrate using a temperature difference on the surface of the substrate achieved by heating the substrate with a lamp. The method comprises the steps of forming a black matrix layer of metal on a portion of the whole surface of an insulating glass substrate, forming an insulating layer for protecting the substrate on the whole substrate including the black matrix layer, forming source/drain electrodes on the insulating layer over the black matrix, selectively forming a semiconductor layer on the insulating layer including the source/drain electrodes, forming a gate insulating layer and forming a gate electrode.Type: GrantFiled: January 20, 1995Date of Patent: November 11, 1997Assignee: Goldstar Co., Ltd.Inventor: Jeong Hyun Kim
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Patent number: 5674777Abstract: The present invention is related to a method for fabricating a silicon electronic device having a boron diffusion source layer, includes steps of: a) providing a silicon substrate; b) depositing a silicon layer on said silicon substrate; and c) growing a silicon-boron binary compound layer on said silicon layer as said boron diffusion source. When the Si-B layer is formed by a UHV/CVD process according to the present invention, the boron concentration in the Si-B binary compound layer will be extraordinary high (up to 1.times.10.sup.21 to 5.times.10.sup.22 atoms/cm.sup.3).Type: GrantFiled: December 14, 1995Date of Patent: October 7, 1997Assignee: National Science CouncilInventors: Tung-Po Chen, Tan-Fu Lei, Chun-Yen Chang
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Patent number: 5648287Abstract: A process for forming a MOS transistor having a salicide structure with a second gate spacers 36 and a source/drain/gate contact pads 32 33. A gate electrode 18 having first sidewall spacers 24 is formed on a substrate. Source and drain regions 28 are formed in the substrate. An amorphous silicon layer is formed over the substrate and patterned leaving the amorphous silicon layer over first sidewall spacers 24 and forming source/drain contact pads 33 over the source/drain regions and gate contact pads 32 over the gate electrode. Nitrogen ions are implanted vertically into the amorphous silicon layer 32 forming a nitrogen rich layer 34. The nitrogen rich layer 34 acts as an oxidation barrier source/drain an gate contact pads. The amorphous silicon layer 28 over the first sidewall spacer is oxidized using the nitrogen rich layer 34 as an oxidation barrier forming second gate spacers 36. A Ti layer is formed over the resultant surface.Type: GrantFiled: October 11, 1996Date of Patent: July 15, 1997Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.Inventors: Chao-Chieh Tsai, Shie-Sen Peng
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Patent number: 5648293Abstract: The invention provides a novel method of depositing an amorphous silicon film wherein a high frequency discontinuous discharge is carried out to decompose a silane system gas for a chemical vapor deposition for depositing an amorphous silicon film under conditions of a cyclic frequency of 500 Hz or more and a duty ratio of 30% or less.Type: GrantFiled: July 22, 1994Date of Patent: July 15, 1997Assignee: NEC CorporationInventors: Hiroshi Hayama, Hiroyuki Uchida, Kazushige Takechi
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Patent number: 5614257Abstract: A method of producing amorphous silicon layers on a substrate by chemical vapor deposition at elevated pressures of at least about 25 Torr whereby deposition occurs at practicable rates. A substrate is loaded in a vacuum chamber, the temperature adjusted to obtain an amorphous silicon deposit of predetermined microcrystalline density, and the silicon precursor gases fed to the chamber to a preselected high pressure. Doped amorphous silicon films also can be deposited at high deposition rates. The above amorphous silicon films have a low density of nucleation sites; thus when the films are annealed, polycrystalline films having large crystal grains are produced.Type: GrantFiled: May 18, 1995Date of Patent: March 25, 1997Assignee: Applied Materials, IncInventors: Israel Beinglass, Mali Venkatesan
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Patent number: 5597741Abstract: A process for preparing a semiconductor device, in which a polycrystalline silicon film is formed on a monocrystalline semiconductor substrate and arsenic or phosphorus is injected as an impurity into the polycrystalline silicon film by an ion-injection method to make the polycrystalline silicon film an amorphous layer. The amorphous layer is heat-treated at a temperature of 600.degree. C. to 650.degree. C. to recrystallize the amorphous layer, thus forming a recrystallized layer having a grain size greater than that of the polycrystalline silicon film by solid phase growth. The recrystallized layer is heat-treated at a temperature of 800.degree. C. to 900.degree. C. to diffuse the impurity into the monocrystalline semiconductor substrate.Type: GrantFiled: February 17, 1995Date of Patent: January 28, 1997Assignee: Canon Kabushiki KaishaInventors: Masaru Sakamoto, Masakazu Morishita, Shigeru Nishimura
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Patent number: 5585295Abstract: A method for forming an inverse-T gate lightly-doped drain (ITLDD) structure for deep sub-micron metal oxide semiconductor (MOS) transistors is disclosed. The present invention includes forming a gate oxide layer on a substrate, and forming stacked-amorphous-silicon layers on the gate oxide layer, where the stacked-amorphous-silicon layers comprise at least two layers. Next, a first dielectric layer is patterned on top of the stacked-amorphous-silicon layer by a photoresist mask, and then a lightly-doped source/drain regions is formed. Thereafter, all of the stacked-amorphous-silicon layers are removed except for the bottom amorphous polysilicon layer. A second dielectric spacer is formed on the sidewalls of the stacked-amorphous-silicon layers and heavily-doped source/drain regions are formed. The bottom layer of the stacked-amorphous-silicon layers is and the gate oxide layer is removed using the spacer as an etch mask.Type: GrantFiled: March 29, 1996Date of Patent: December 17, 1996Assignee: Vanguard International Semiconductor CorporationInventor: Shye-Lin Wu
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Patent number: 5576060Abstract: A CVD process of forming a hydrogenated amorphous silicon film comprising not more than 40 atomic percent of hydrogen atoms is disclosed, which comprises introducing a silicon-containing gas and a gas containing impurity for controlling conductivity of said film into a film-forming space, wherein the concentration of the gas containing the impurity is controlled during film formation to vary the content of the impurity in the thickness direction of the amorphous silicon film.Type: GrantFiled: June 7, 1995Date of Patent: November 19, 1996Assignee: Canon Kabushiki KaishaInventors: Yutaka Hirai, Toshiyuki Komatsu, Katsumi Nakagawa
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Patent number: 5552027Abstract: A working electrode or an electrochemical-enzymatic sensor system has a metallic base body which is provided with a thin layer of amorphous hydrogenated carbon (a-C:H).Type: GrantFiled: July 18, 1995Date of Patent: September 3, 1996Assignee: Siemens AktiengesellschaftInventors: Siegfried Birkle, Johann Kammermaier, deceased, Rolf Schulte
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Patent number: 5531182Abstract: Polycrystalline silicon thin-films having a large grain size are formed by preparing a substrate of amorphous surface comprising first regions containing tin atoms at a higher content and second regions containing tin atoms at a lower content or not substantially containing them, and then heat-treating the substrate to grow crystal grains from crystal nuclei formed only in the first regions.Type: GrantFiled: May 12, 1994Date of Patent: July 2, 1996Assignee: Canon Kabushiki KaishaInventor: Takao Yonehara
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Patent number: 5529937Abstract: After a pattern is transferred on silicon film crystallized by annealing, the silicon film is annealed by radiation of intense rays for a short time. Especially, in the crystallizing process by annealing, an element which promotes crystallization such as nickel is doped therein. The area not crystallized by annealing is also crystallized by radiation of intense rays and a condensed silicon film is formed. After a metal element which promotes crystallization is doped, annealing by light for a short time is performed by radiating intense rays onto the silicon film crystallized by annealing in an atmosphere containing halide. After the surface of the silicon film is oxidized by heating or by radiating intense rays in a halogenated atmosphere and an oxide film is formed on the silicon film, the oxide film is then etched. As a result, nickel in the silicon film is removed.Type: GrantFiled: July 20, 1994Date of Patent: June 25, 1996Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Hongyong Zhang, Hideto Ohnuma, Yasuhiko Takemura
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Patent number: 5518937Abstract: A bipolar transistor includes a base region made of silicon crystal doped with a first impurity to a first level so as to establish a first carrier concentration in the base region and an emitter region made of silicon crystal doped with a second impurity to a second level substantially larger than the first level by a predetermined factor so as to establish a second carrier concentration in the emitter region, in which the second impurity exceeds the solubility limit of the second impurity in silicon crystal. The first and second levels are chosen in such a range that a difference in the carrier concentrations between the emitter region and the base region decreases substantially with increasing impurity level in the base region.Type: GrantFiled: March 20, 1995Date of Patent: May 21, 1996Assignee: Fujitsu LimitedInventors: Yuji Furumura, Fumitake Mieno, Tsutomu Nakazawa, Takashi Eshita, Mamoru Maeda, Tsunenori Yamauchi
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Patent number: 5514618Abstract: A direct laser ablation process is disclosed for forming thin film transistors on liquid crystal matrix for enabling typically color presentation from a flat panel display. The thin film transistor is of the type having an active matrix addressing scheme wherein a capacitor when charged turns on and maintains in the "on" state a field effect transistor to permit passage of light through a liquid crystal display. All patterning of the display is done either by utilizing deposition, direct ablation of an etch block followed by etching, or more preferably deposition followed by direct laser ablation. In the preferred embodiment, aluminum channels are made by deposition followed by a direct laser ablation. Anodizing follows with deposition of a silicon-nitrogen layer. With respect to the capacitor, indium tin oxide is deposited to complete a matrix capable of selectively strobing and charging the capacitor for each matrix element.Type: GrantFiled: February 23, 1995Date of Patent: May 7, 1996Assignee: Litel InstrumentsInventors: Robert O. Hunter, Jr., Chester A. Farris
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Patent number: 5491107Abstract: A semiconductor processing method of providing a polysilicon layer atop a semiconductor wafer comprises the following sequential steps: a) depositing a first layer of arsenic atop a semiconductor wafer; b) depositing a second layer of silicon over the arsenic layer, the second layer having an outer surface; c) first annealing the wafer at a temperature of at least about 600.degree. C. for a time period sufficient to impart growth of polycrystalline silicon grains in the second layer and providing a predominately polysilicon second layer, the first annealing step imparting diffusion of arsenic within the second layer to promote growth of large polysilicon grains; and d) with the second layer outer surface being outwardly exposed, second annealing the wafer at a temperature effectively higher than the first annealing temperature for a time period sufficient to outgas arsenic from the polysilicon layer.Type: GrantFiled: April 21, 1995Date of Patent: February 13, 1996Assignee: Micron Technology, Inc.Inventors: Charles L. Turner, Monte Manning
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Patent number: 5488000Abstract: Method of fabricating TFTs starts with forming a nickel film selectively on a bottom layer which is formed on a substrate. An amorphous silicon film is formed on the nickel film and heated to crystallize it. The crystallized film is irradiated with infrared light to anneal it. Thus, a crystalline silicon film having excellent crystailinity is obtained. TFTs are built, using this crystalline silicon film.Type: GrantFiled: June 14, 1994Date of Patent: January 30, 1996Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Hongyong Zhang, Satoshi Teramoto
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Patent number: 5441914Abstract: In one embodiment, delamination of a patterned silicon nitride anti-reflective layer (26) from an underlying patterned tungsten silicide layer (32), is prevented by forming a thin silicon layer (30) between the patterned tungsten silicide layer (32) and the overlying patterned silicon nitride anti-reflective layer (26).Type: GrantFiled: May 2, 1994Date of Patent: August 15, 1995Assignee: Motorola Inc.Inventors: Robert C. Taft, Craig D. Gunderson, Arkalgud R. Sitaram
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Patent number: 5424230Abstract: An amorphous silicon hydride thin film is deposited on an insulating body by a plasma CVD method, and is then heated for dehydrogenating the amorphous silicon thin film so that a dehydrogenated amorphous silicon thin film containing hydrogen of 3 atomic % or less is formed. The insulating body may be an insulating substrate (such as a glass substrate) alone, or a combination of an insulating substrate with an intermediate insulating base layer thereon. Impurity ions are injected into the dehydrogenated amorphous silicon hydride thin film to form source and drain regions. Excimer laser beams are applied to the dehydrogenated amorphous silicon thin film, thereby polycrystallizing the amorphous silicon thin film into a polysilicon thin film and activating the injected impurity ions.Type: GrantFiled: July 29, 1994Date of Patent: June 13, 1995Assignee: Casio Computer Co., Ltd.Inventor: Haruo Wakai
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Patent number: 5391518Abstract: To fabricate a programmable read only memory cell an implant region is formed within a substrate. A first conductive layer is formed over the substrate. For example, the first conductive layer is polysilicon. The first conductive layer is etched to form a first electrode on the substrate in physical and electrical contact with the implant region and to form a gate region for a transistor. Atoms of a first conductivity type are implanted into the substrate into a first source/drain region on a first side of the gate region and into a second source/drain region on a second side of the gate region. The second source/drain region is electrically coupled to the implant region. An insulating layer is formed over the first electrode. The insulating layer has a link contact which extends to the first electrode region. The insulating layer also has a contact hole extending to the first source drain region. An amorphous silicon layer is formed within the link contact and in contact with the first electrode.Type: GrantFiled: September 24, 1993Date of Patent: February 21, 1995Assignee: VLSI Technology, Inc.Inventor: Bharat Bhushan
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Patent number: 5366921Abstract: An electronic circuit apparatus which is constructed by laminating a plurality of thin films onto an insulative substrate. On the substrate, an electronic circuit element having two conductive layer which are laminated through an insulative layer is formed. The insulative layer is formed so as to cover the whole surface of the insulative substrate.Type: GrantFiled: December 22, 1993Date of Patent: November 22, 1994Assignee: Canon Kabushiki KaishaInventor: Kazuaki Tashiro
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Patent number: 5366928Abstract: A method of manufacturing a semiconductor device is set forth comprising a semiconductor body (1) having a surface (2) adjoined by a semiconductor region (3) and a field oxide region (4) surrounding this region, on which surface (2) is provided a metal layer (13), in which a conductor track (17, 18) is formed, after which an isolating layer of silicon oxide (19) is deposited over the conductor track (17, 18) on the surface (2). According to the invention, before the layer of silicon oxide (19) is provided over the conductor track (17, 18), this track is provided with a top layer (16) of an oxidation-preventing material. By providing this top layer (16), it is avoided that the conductor track (17, 18) covered by silicon oxide (19) has a high electrical resistance or even an electrical interruption.Type: GrantFiled: June 4, 1993Date of Patent: November 22, 1994Assignee: U.S. Philips CorporationInventors: Robertus A. M. Wolters, Alexander G. M. Jonkers
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Patent number: 5346833Abstract: An inverted staggered (bottom gate) thin film transistor (TFT) for active matrix liquid crystal display is processed with three masks. The first mask is used to pattern a metal film on a glass substrate as the gate of the TFT, the scan line of the TFT array, and a portion of the data line of the TFT array. The second mask is used to form a TFT mesa with a gate dielectric layer, an a-Si layer as channel, and a heavily-doped n+s-Si layer for contacting the source and the drain of the TFT. A third mask is used to pattern the transparent conductive indium-tin oxide film as the pixel electrode, the source/drain electrodes of the TFT, and the interconnections of the data line.Type: GrantFiled: April 5, 1993Date of Patent: September 13, 1994Assignee: Industrial Technology Research InstituteInventor: Biing-Seng Wu
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Patent number: 5326712Abstract: A method for manufacturing a semiconductor device which utilizes anodic oxidation. A first semiconductor layer of a first conductive type is formed on an insulating substrate, a highly doped second semiconductor layer of the first conductive type is formed on the first semiconductor layer, and then an anti-oxidizing pattern is formed on the second semiconductor layer to expose a predetermined portion of the second semiconductor layer. After forming the anti-oxidizing pattern, anodic oxidation is performed to oxidize the exposed portion of the second semiconductor layer. Instead of employing a conventional plasma etching process for removing the portion of the ohmic contact layer which is not in contact with the source and drain electrodes, the portion of the ohmic contact layer to be removed is subjected to anodic oxidation, to thereby form an anodic oxidation layer, thus facilitating removal of the unnecessary portions of the ohmic contact layer without the use of a plasma etching step.Type: GrantFiled: December 3, 1992Date of Patent: July 5, 1994Assignee: Samsung Electronics Co., Ltd.Inventor: Byung-seong Bae
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Patent number: 5318920Abstract: A silicon layer having semispherical protrusions of about 100 nm is formed as a lower electrode of a capacitor by low pressure vapor deposition method. A silicon oxide film is formed by oxidizing the surface of this silicon layer. The intervals between the rough portions of the silicon layer are increased by removing this silicon oxide film. Thereafter, a dielectric layer and an upper electrode are formed. In other methods, after the formation of the silicon layer having the roughness, thermal treatment is continuously carried out in oxygen-free atmosphere to increase radius of curvature of the roughness of the silicon layer. Thereafter, the dielectric layer and the upper electrode are formed.Type: GrantFiled: October 5, 1992Date of Patent: June 7, 1994Assignee: Mitsubishi Denki Kabushiki KaishaInventor: Yoshio Hayashide
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Patent number: 5310698Abstract: In a multistage process for producing a smooth polycrystalline silicon layer, in particular a layer with low arsenic doping, for very large scale integrated circuits, by thermal decomposition of gaseous compounds containing the elements, a doped layer and an undoped silicon layer above the doped layer are deposited directly one after the other in a two-stage process. Initially, a surface-covering arsenic layer being at most a few atoms thick, is deposited as a preliminary lining. Then an undoped amorphous silicon layer is deposited on the arsenic layer at a temperature of less than 580.degree. C. Subsequently, the silicon layer is uniformly doped with the arsenic layer serving as a diffusion source, by temperature treatment. Simultaneously, the amorphous silicon is made into a polycrystalline silicon layer.Type: GrantFiled: December 23, 1991Date of Patent: May 10, 1994Assignee: Siemens AktiengesellschaftInventor: Barbara Wild
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Patent number: 5302549Abstract: A metal semiconductor ohmic contact farming process consists of enrichment of the surface of the semiconductor on which contact is to be formed, by ion implantation of a dopant, followed by deposition of a metal film on the implanted surface and then by thermal annealing at a temperature lower than 500.degree. C. and for a period shorter than 60 minutes.Type: GrantFiled: October 13, 1992Date of Patent: April 12, 1994Assignee: SGS-Thompson Microelectronics S.r.L.Inventors: Antonello Santangelo, Carmelo Magro, Guiseppe Ferla, Paolo Lanza
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Patent number: 5296405Abstract: An improved semiconductor processing is disclosed. In the manufacturing process, a semiconductor layer is formed and then undergoes photo annealing. A neutralizer is then introduced to the photoannealed semiconductor. The semiconductor thus formed demonstrates the SEL effect instead of the Staebler-Wronski effect.Type: GrantFiled: August 24, 1992Date of Patent: March 22, 1994Assignee: Semiconductor Energy Laboratory Co.., Ltd.Inventors: Shunpei Yamazaki, Kunio Suzuki, Susumu Nagayama, Takashi Inujima, Masayoshi Abe, Takeshi Fukada, Mikio Kinka, Ippei Kobayashi, Katsuhiko Shibata, Masato Susukida, Kaoru Koyanagi
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Patent number: 5290734Abstract: An anti-fuse structure characterized by a substrate, an oxide layer formed over the substrate having an opening formed therein, an amorphous silicon material disposed within the opening and contacting the substrate, a conductive protective material, such as titanium tungsten, disposed over the amorphous silicon material, and oxide spacers lining the walls of a recess formed within the protective material. The protective material and the spacers provide tighter programming voltage distributions for the anti-fuse structure and help prevent anti-fuse failure.Type: GrantFiled: July 26, 1991Date of Patent: March 1, 1994Assignee: VLSI Technology, Inc.Inventors: William J. Boardman, David P. Chan, Kuang-Yeh Chang, Calvin T. Gabriel, Vivek Jain, Subhash R. Nariani
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Patent number: 5290729Abstract: A lower electrode of a stacked capacitor in accordance with the present invention is formed of a silicon layer formed by low pressure CVD method. The silicon layer is formed by thermal decomposition of monosilane gas at a prescribed temperature. By setting partial pressure of the monosilane gas and formation temperature at prescribed values, the silicon layer is formed to be in a transitional state between poly crystal and amorphous. Such silicon layer has large concaves and convexes on the surface thereof. Consequently, opposing areas of the electrodes of the capacitor can be increased, and therefore electrostatic capacitance of the capacitor is also increased.Type: GrantFiled: April 30, 1992Date of Patent: March 1, 1994Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Yoshio Hayashide, Wataru Wakamiya
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Patent number: 5283207Abstract: A photoconductive material comprises a photocarrier generating zone using a wide-band gap material and a photocarrier moving zone using an amorphous silicon material. A photocarrier generating zone including a silicon atom as a principal atom comprises an amorphous silicon which contains at least one kind of atom selected from a group including oxygen, nitrogen and carbon and also contains an atom which terminates a dangling bond of a silicon. This photoconductive material can be used for various devices because of its wide-band gap and high photosensitivity.Type: GrantFiled: June 10, 1992Date of Patent: February 1, 1994Assignees: Ricoh Company, Ltd., Ricoh Research Institute of General Electronics Co., Ltd.Inventors: Koichi Haga, Masafumi Kumano
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Patent number: 5281546Abstract: A method of fabricating a thin film transistor (TFT) including the steps of forming a gate conductor on a substrate; depositing a gate dielectric layer over the gate conductor; depositing a layer of amorphous silicon over the gate dielectric layer; treating the exposed surface of the amorphous silicon with a hydrogen plasma; depositing a layer of n+ doped silicon over the treated amorphous silicon surface such that an interface is formed between the amorphous silicon and the n+ doped layer that has relatively low contact resistance; depositing a layer of source/drain metallization over the n+ doped layer; and patterning the source/drain metallization and portions of the underlying n+ doped layer to form source and drain electrodes. The TFT material layers are preferably deposited by plasma enhanced chemical vapor deposition.Type: GrantFiled: September 2, 1992Date of Patent: January 25, 1994Assignee: General Electric CompanyInventors: George E. Possin, Robert F. Kwasnick, Brian W. Giambattista
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Patent number: 5278096Abstract: A method of forming p.sup.+ transistor gates is disclosed. A polysilicon layer is covered with an amorphous silicide layer which prevents penetration of p-type dopants through the gate oxide. The silicide may be covered by a dielectric which is formed at a temperature low enough to prevent crystallization of the silicide, a p-type dopant species is directed at the silicide layer. Subsequently an anneal is performed at a temperature high enough to cause a substantial amount of the p-type dopant to move to the polysilicon layer.Type: GrantFiled: December 23, 1991Date of Patent: January 11, 1994Assignee: AT&T Bell LaboratoriesInventors: Kuo-Hua Lee, Chen-Hua D. Yu
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Patent number: 5278087Abstract: A single transistor electrically programmable and erasable memory cell has a substrate of a semiconductor material of a first-conductivity type. Within the substrate are defined source, drain, regions with a channel region therebetween. A first insulating layer is disposed over the substrate and over the source, channel and drain regions. An electrically conductive, re-crystallized floating gate is disposed over the first-insulating layer and extends over a portion of the channel region and over a portion of the drain region to maximize capacitive coupling therewith. A second insulating layer has a top wall portion over the floating gate and a side wall portion immediately adjacent to the floating gate and has a thickness which permits the Fowler-Nordheim tunneling of charges therethrough. An electrically conductive control gate has two electrically connected sections: A first section is over the first insulating layer and is immediately adjacent to the side-wall portion of the second insulating layer.Type: GrantFiled: October 15, 1992Date of Patent: January 11, 1994Assignee: Silicon Storage Technology, Inc.Inventor: Ching-Shi Jenq
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Patent number: 5278093Abstract: A method for forming a semiconductor thin film comprises crystallizing an amorphous silicon thin film by a first thermal treatment at 700.degree. C. or lower for ten hours or longer and carrying out a second thermal treatment at 1200.degree. C. or higher in which a lamp light is radiated to the crystallized thin film.Type: GrantFiled: July 29, 1992Date of Patent: January 11, 1994Assignee: Canon Kabushiki KaishaInventor: Takao Yonehara
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Patent number: 5273920Abstract: A method of fabricating a thin film transistor (TFT) includes the steps of forming a gate conductor on a substrate; depositing a gate dielectric layer of silicon nitride over the gate conductor; treating the exposed silicon nitride on the surface of the gate dielectric layer with a hydrogen plasma at a power level of at least 44 mW/cm.sup.2 for at least 5 minutes; depositing a layer of amorphous silicon semiconductor material over the gate dielectric layer; depositing a layer of n+ doped silicon over the treated amorphous silicon surface; depositing a layer of source/drain metallization over the n+ doped layer; and patterning the source/drain metallization and portions of the underlying n+ doped layer to form source and drain electrodes. The deposition of the TFT material layers and the hydrogen plasma treatment is preferably by plasma enhanced chemical vapor deposition.Type: GrantFiled: September 2, 1992Date of Patent: December 28, 1993Assignee: General Electric CompanyInventors: Robert F. Kwasnick, George E. Possin
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Patent number: 5273919Abstract: A method of producing a thin film field effect transistor. An insulating thin film layer is formed on a gate electrode subsequent to the gate electrode being formed on a substrate. A multilayer structure is formed on the insulating thin film layer subsequent to the insulating thin film layer being formed on the gate electrode by alternately laminating a number of non-monocrystalline semiconductor material layers and a number of non-monocrystalline material layers.Type: GrantFiled: April 16, 1992Date of Patent: December 28, 1993Assignee: Canon Kabushiki KaishaInventors: Masafumi Sano, Katsuji Takasu, Hisanori Tsuda, Yutaka Hirai
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Patent number: 5270227Abstract: An improved method for fabrication of a super-high density semiconductor device wherein ion implantation is used to eliminate defects or inhibit the occurrence of growth of defects in the semiconductor device. Ions of high concentration are implanted into a monocrystal semiconductor region in which principal elements such as bipolar element and MOS element are formed, by using a mask pattern covering the semiconductor region and at a largely inclined implantation angle equal to or of more than 20 degrees. This provides for formation of amorphous regions 170A, 170B extending sufficiently into areas beneath the ends of the mask. The amorphous regions are recrystallized by heat treatment, thereby inhibiting the growth of a corner defect known as "voids 21" which has often occurred at edges of amorphous regions 170A, 170B in the conventional method. Thus, a device which is less liable to electrical leaks is provided.Type: GrantFiled: March 26, 1992Date of Patent: December 14, 1993Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Shuichi Kameyama, Genshu Fuse
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Patent number: 5266504Abstract: A method of manufacturing a bipolar transistor by use of low temperature emitter process is disclosed. After completion of the usual base and collector formation in a vertical bipolar transistor, an emitter opening is etched in the insulator layer over the base layer at selected locations. A thin layer (less than 500 .ANG.) of in-situ doped amorphous silicon is deposited over the substrate and heated to densify for 30 to 60 minutes at about 650.degree. C. Subsequently an in-situ doped polysilicon layer of 100 to 200 nm is deposited over the amorphous Si film preferably at about 600.degree. C. Subsequently the layers are heated below 600.degree. C. for several hours to convert partially the amorphous Si into a monocrystalline emitter layer over the base regions.Type: GrantFiled: March 26, 1992Date of Patent: November 30, 1993Assignee: International Business Machines CorporationInventors: Jeffrey L. Blouse, Jack O. Chu, Brian Cunningham, Jeffrey P. Gambino, Louis L. Hsu, David E. Kotecki, Seshadri Subbanna, Zu-Jean Tien
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Patent number: 5262350Abstract: A semiconductor device which has a non-single crystal semiconductor layer formed on a substrate and in which the non-single crystal semiconductor layer is composed of a first semiconductor region formed primarily of non-single crystal semiconductor and a second semi-conductor region formed primarily of semi-amorphous semiconductor. The second semiconductor region has a higher degree of conductivity than the first semiconductor region so that a semi-conductor element may be formed.Type: GrantFiled: July 1, 1992Date of Patent: November 16, 1993Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Shunpei Yamazaki, Yujiro Nagata
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Patent number: 5250451Abstract: Process for the local passivation of a substrate by a hydrogenated amorphous carbon layer and process for producing thin film transistors on said passivated substrate. The local passivation process consists of producing photosensitive resin patterns (3) on the substrate (1), subjecting the structure obtained to a radio-frequency plasma essentially constituted by a hydrocarbon for thus depositing a hydrogenated amorphous carbon layer (6) on the structure and dissolving the resin patterns (3) in order to eliminate the amorphous carbon deposited on the resin, the amorphous carbon deposited on the substrate constituting the said passivation.Type: GrantFiled: April 10, 1992Date of Patent: October 5, 1993Assignee: France Telecom Etablissement Autonome de Droit PublicInventor: Yannick Chouan