Abstract: A pyrotechnic composition includes a fuel, an oxidizer, flow and rate control agents and oleoresin capsicum as an irritant. The composition is useful in crowd control products. The composition contains rate control ingredients to maintain combustion at a temperature below the point of degradation of the oleoresin capsicum, balanced with a booster material to maintain combustion.

Abstract: A method for decoying an infrared seeker comprising the steps of providing a plurality of small pyrotechnic pellets, igniting the pellets and dispersing the pellets.

Abstract: A pyrotechnic active material for producing IR-radiation is proposed. An active material according to the invention contains fuel (preferably magnesium) which combines with fluorine in a strongly exergonic reaction (for example Li, Be, Mg, Ca, Sr, Ba, Ti, Zr, Hf, B, Al and alloys thereof) and poly-(carbon monofluoride) ((—CFx—)n) (x=0.6-1.2) as an oxidation agent. Compositions according to the invention further contain VITON® as a polymeric binding agent and graphite for reduction of the electrostatic sensitivity. A process for producing those compositions is also provided.

Abstract: An infrared illuminating composition comprising approximately 70 weight % of an oxidant evidencing strong emission in the NIR region selected from the group consisting of potassium nitrate, cesium nitrate and mixtures thereof; 9 weight % of a metallic fuel evidencing low visible light emission, 4 weight % of an epoxy resin binder, 16 weight % of a NIR light enhancer and 1% by weight of an additive selected from the group consisting of a double base propellant material, a triple base propellant material and mixtures thereof.

Abstract: Compositions are provided which, when burned, produce significant levels of infrared radiation, but only limited levels of visible radiation. The basic components of the compositions include a binder, an oxidizer, and a fuel, where the binder also acts the fuel. Preferred oxidizers include those compounds which produce large quantities of infrared radiation when the flare composition is burned. Such oxidizers include potassium nitrate, cesium nitrate, rubidium nitrate, and combinations of these compounds. Selection of the binder is important in order to provide the composition with the desirable characteristics identified above. The binder of the present invention does not produce significant soot. At the same time, the binder serves to form a composition which is processible, avoids chunking, and is compatible with the oxidizers used. It has been found that polymer binders which include relatively short carbon chains (1-6 continuous carbon atoms) are preferred.

Abstract: Compositions are provided which, when burned, produce significant levels of infrared radiation, but only limited levels of visible radiation. The basic components of the compositions include a binder, an oxidizer, and a fuel, where the binder also acts the fuel. Preferred oxidizers include those compounds which produce large quantities of infrared radiation when the flare composition is burned. Such oxidizers include potassium nitrate, cesium nitrate, rubidium nitrate, and combinations of these compounds. Selection of the binder is important in order to provide the composition with the desirable characteristics identified above. The binder of the present invention does not produce significant soot. At the same time, the binder serves to form a composition which is processible, avoids chunking, and is compatible with the oxidizers used. It has been found that polymer binders which include relatively short carbon chains (1-6 continuous carbon atoms) are preferred.

Abstract: A fire starting flare suitable for hand-held launchers has a fuse and ignitor assembly within a flare core material such that as the flare is launched the fire ignites and as the flare lands the fuse reaches the ignitor assembly to set off the flare.

Abstract: Compositions are provided which, when burned, produce significant levels of infrared radiation, but only limited levels of visible radiation. The basic components of the compositions include a binder, an oxidizer, and an organic fuel. Preferred oxidizers include those compounds which produce large quantities of infrared radiation when the flare composition is burned. Such oxidizers include potassium nitrate, cesium nitrate, rubidium nitrate, and combinations of these compounds. The composition preferably includes significant quantities of cesium nitrate as an oxidizer. Selection of the binder is important in order to provide the composition with the desirable characteristics identified above. The binder of the present invention does not produce significant soot when burned. At the same time, the binder serves to form a composition which is processible, avoids chunking, and is compatible with the oxidizers used.

Abstract: A pyrotechnic composition that emits essentially only infrared radiation upon combustion contains at least one peroxide component, an oxidizer that is more energetic than the peroxide component, a coolant, a binder and silicon. In one embodiment, the peroxide component is a mixture of strontium peroxide and barium peroxide, the oxidizer more energetic than the peroxide component is barium nitrate, the coolant is magnesium carbonate, the binder is calcium resonate and the silicon has a minimum purity of 99.9%. The pyrotechnic composition is useful as the combustible component of an infrared tracer.

Abstract: This invention relates to flares; more particularly it relates to flares ch are good emitters of infra-red radiation and which are adapted to be attached to rockets for tracking purposes.

Abstract: Convert infrared tracer compositions are provided. The compositions are formed using peroxide such as strontium peroxide and barium peroxide. Added to these materials is a burn rate catalyst such as boron, iron oxide, cupric oxide, manganese dioxide, carbon, silicon, graphite fibrils, amorphous silica, copper oxide, potassium dodecaborate, the dipotassium salt of bitetrazole amine, and the potassium salt of dilituric acid. The composition also includes alkali metal compounds in order to enhance the infrared emissions. The compositions are bound together using a binder such that the composition results in a granular material having a mean particle size in the range of from about 500.mu. to about 800.mu..

Abstract: A flare mass for dummy target production has an incendiary composition component and an inert component, the weight ratio of the incendiary mass component and the inert component being adjusted such that the maximum of the spectral radiant flux of the flare mass in adaptation to the spectral radiant flux distribution of the target signature to be simulated is displaced toward longer wavelengths compared with the spectral radiant flux distribution of the incendiary mass component alone.

Abstract: Energetic compositions and the process for obtaining same for use as the itable composition in infrared-emitting decoy flares, for high-temperature ignition compositions, and the like, are disclosed. These compositions are attained by combining a fluorinated hydrocarbon, either in a liquid state or as a water emulsion, with a powdered metal fuel such as aluminum, magnesium, titanium or zirconium to yield volatile solvent free energetic compositions.

Abstract: Energetic compositions and the process for obtaining same for use as the itable composition in infrared-emitting decoy flares, for high-temperature ignition compositions, and the like, are disclosed. These compositions are attained by combining a fluorinated hydrocarbon, either in a liquid state or as a water emulsion, with a powdered metal fuel such as aluminum, magnesium, titanium or zirconium to yield volatile solvent free energetic compositions.

Abstract: Infrared illuminant compositions are disclosed which produce significant quantities of infrared radiation when burned but which produce very little visible light. The infrared illuminant compositions provide specific illumination in the spectral range visible with night vision devices. The disclosed infrared illuminant compositions include ammonium nitrate as the main oxidizer, an infrared generator such as cesium nitrate, rubidium nitrate, or mixtures thereof, and a fuel. By eliminating potassium and its direct and indirect visible light contributions, from the illuminant compositions, improved concealment indexes are obtained. Other additives, including conventional binders and burn rate modifiers may be used as to tailor the performance and physical characteristics of the infrared illuminant composition.

Abstract: An aircraft-launched pyrotechnic decoy flare for luring an incoming missile away from the aircraft's exhaust which comprises a compactly clustered substantially void free array of discrete pieces of a gassy high intensity infra-red emitting pyrotechnic composition contained in a rupturable air-tight container. On ignition of the flare, combustion spreads rapidly along the interfaces between the discrete pieces to produce gaseous combustion products. When the pressure within the air-tight container reaches a predetermined level the container ruptures and the discrete pieces burst apart. The plurality of pieces have a large combined surface area over which combustion occurs and so produce a high intensity emission of infra-red radiation. In a preferred embodiment the discrete pieces comprise a mixtured fibrous activated carbon cloth impregnated with a metallic salt and coated with a mixture of an oxidizing halogenated polymer, an oxidizable metallic material and an organic binder. FIG. 1.

Abstract: An aircraft launched pyrotechnic decoy flare (1) which comprises a pellet (2) configured with a cavity (4) which extends along a fore-and-aft axis (8) of the pellet (2) and is vented at its rearward end (12). Part of the external surface of the pellet (2) is covered with a casing (16) to prevent combustion of said part of the surface. The pellet (2) is made of a gassy pyrotechnic composition including an organic binder, and an oxidizing halogenated polymer and an oxidizable metallic material which react with each other on ignition and emit infrared radiation. When the flare (1) is ignited the surface of the cavity (4) combusts and produces hot gaseous products which escape from the cavity (4) through the vent (22) thus propelling the flare (1) in a forwards direction. In this way the flare (1) can be propelled in the same direction as the aircraft to reduce the rate at which the flare (1) separates from the aircraft exhaust.

Abstract: An infrared illuminant composition and flares produced therefrom having increased burn rate and increased infrared intensity while maintaining low visible light intensity. The composition comprises potassium nitrate, cesium nitrate, hexamine, boron, silicon, ferric oxide and a binder. A process to produce infrared illuminant flares prevents or substantially eliminates chunking out of burning pieces of the illuminant at pressing increments in the flares.

Abstract: A signal flare with luminous oscillations resulting from a combustible cosition of octafluorohexanediol, magnesium or aluminum, chlorinated benzene, an inorganic oxidizer, and polyisocyanate.

Abstract: High intensity yellow smoke and flame flare compositions are manufactured a procedure which closely parallels that of solid rocket propellants. These compositions use similar ingredients to those used in solid rocket propellants. These compositions are castable whereas conventional flares consist of pressed flare charges. Both colored flame and smoke are produced from the same composition. A liquid curable binder composition is selected from triethylene glycol succinate or carboxyl-terminated polybutadiene crosslinked with O,NN-tris(2,3-epoxypropyl)-4-aminophenol, and hydroxyl-terminated polybutadiene crosslinked with isophorone diisocyanate. The color producing ingredient is a first inorganic salt of lead iodide which can be further enhanced by an additive of a reactive source of iodine selected from iodine pentoxide and iodoform. A second inorganic salt is selected from inorganic oxidizing salts consisting of potassium perchlorate and amononium perchlorate.

Abstract: The subject of the invention is a castable pyrotechnic composition of the type producing smoke with a colored or colorless flame comprising in particular an oxidation-reduction pair and a chlorinated binder. The binder is a high chlorine content resin. It is constituted by the association of a polymerizable chlorinated monomer with a copolymerized or non-copolymerized chlorinated polymer, the resulting mixture being subjected to polymerization at a moderate temperature, said binder then containing 30 to 70% by weight of chlorine.

Abstract: A low cost infrared flare composition which uses a high molecular weight fluorinated resin, a low molecular weight fluorinated resin, a polymerizing solvent, and an initiator to form a binder which is combined with a reducing agent to yield a composition readily processable into various grain shapes and varying degrees of hardness thereby providing more consistent burning rates.

Abstract: An improved pyrotechnic fuel composition comprising a metal fuel and a contional pyrotechnic oxidizer for producing light, heat, smoke and sound through an exothermic reaction wherein the improvement comprises the use of a metal hydride as the fuel ingredient to produce a pyrotechnic composition which readily ignites and which has a lower burning rate for increased luminous intensity. The metal hydride fuel is preferably selected from the group consisting of magnesium hydride, titanium hydride, sodium borohydride and a lithium aluminum hydride.

Abstract: Improved green flare compositions which retain acceptable dominant waveleh and purity and produce efficiencies up to about 11,000 cd-s/g. The flare compositions contain magnesium, barium nitrate, boron and a binder.

Abstract: A pyrotechnic composition which, when burned, produces yellow smoke and yellow flame. The composition is comprised of between 5 and 30 percent of a fuel which is either magnesium or silicon, between 65 and 85 percent of bismuth subnitrate and between 5 and 13 percent of an epoxy binder.

Abstract: An illuminating pyrotechnic composition comprising a stable inorganic combustion-supporting agent, a nitrated carbohydrate as a high energy binder, at least one non-volatile organic combustible compound whose combustion is exothermic overall and, optionally, a metallic constituent. Such a composition is readily ignitable and combustible and is particularly useful in block form in a signal flare or firework.

Abstract: The compositions burn to produce flickering signals of flame and smoke, and which in addition emit infrared and radar signals. The compositions comprise a fuel of either magnesium, aluminum or both, a reactive chlorinated aromatic compound such as hexachlorobenzene, one or more oxidizers selected from nitrates and perchlorates of ammonium, barium, cesium, lithium, potassium, sodium, and strontium, and a binder of a fluorinated polymer.

Abstract: A pyrotechnic signal providing smoke and flame and which is launchable from nderwater. Launching of the signal from underwater arms the signal, however, the signal is not initiated until the ambient sea pressure reaches a predetermined pressure valve. When this predetermined pressure valve is reached, sea water enters a cavity and energizes a battery which detonates an electric squib. The squib, in turn, ignites a smoke composition in the signal housing.

Abstract: A flare composition is passivated to prevent gas generation during curing at elevated temperatures by incorporating therein as a passivating agent a small amount of a polyalkylene oxide phosphate ester. The additive also serves to increase the pot life of the composition.

Abstract: An encapsulated signal illuminant flare composition is comprised of powde magnesium from about 45 to about 60 weight percent, of powdered sodium nitrate from about 32 to about 49 weight percent, and of capsular adhesives containing about 91 weight liquid materials contained within capsules having cell walls of equal parts Arabic gum and gelatin of about 9 weight percent to yield a binder from about 6 to about 12 weight percent. The composition ingredients are blended in a dry mixer to achieve a homogeneously, blended signal illuminant flare composition. The blended signal illuminant flare composition is incrementally fed into a flare press for compacting into cartridges in two increments at about 14,000 psi pressure which ruptures the capsular adhesives by hydraulic forces to achieve polymer mixing and the surrounding of the powder ingredients with the binder ingredients to form a very homogenous signal illuminant flare composition mass.

Abstract: A reactive material for use as a reactive liner in penetrating (shape-charge) warheads and for use in reactive fragments in fragmenting warheads is disclosed. The reactive material comprises an oxidizing agent and a metal filler or metal/metal oxide filler. The oxidizing agent comprises a fluoropolymer having high fluorine content, a low melt temperature, and a high mechanical strength. Preferably, the fluoropolymer is a thermoplastic fluoropolymer, such as a polymer of tetrafluoroethylene, hexafluoropropylene, and vinylidene fluoride. The metal filler comprises a high density, reactive metal. Preferably, the metal filler is hafnium or tantalum. The reactive material is safely processed at temperatures significantly below the thermal autoignition point of the reactive material.