Abstract: An infrared decoy flare composition for generating infrared radiation, including a fuel, an oxidizing agent and a binder, wherein the decoy flare composition contains no metals or metal-containing compounds and no halogens or halogen-containing compounds. Such an infrared decoy flare composition can be particularly advantageously used in aerial infrared decoy flares for civil aircraft.

Abstract: Explosive or propellant compositions containing at least one nitrocellulose contain an additive including at least one substituted tetrazine in amounts effective to increase the burning rate of the composition. A preferred additive is 3,6-dihydrazino-s-tetrazine.

Abstract: This invention relates to liquid propellant compositions containing an enetic material of organic nitrate esters. The organic nitrate esters of the present invention are complexed with a nitrate ester plasticizer, bismuth subsalicylate, and stabilizer to form liquid compositions with an appropriate energy, stability, and sensitivity that is useful as a propellant.

Abstract: Castable propellant formulations are provided including reduced toxicity ballistic modifiers that do not adversely increase the sensitivity of the propellant to shock detonation. Failure to adequately control the propellant burn rate often results in unacceptable performance of the propellant. Carbon can act as an effective ballistic, but not to the extent of metal compounds. It has been found that pasting a ballistic modifier, including ballistic modifiers containing lead, in an inert polymer modifies the burn rate of propellants while allowing the use of a reduced amount of modifier to achieve the same desired burn rate modification as the prior art, and therefore creating reduced shortcomings associated with the ballistic modifiers.

Abstract: A high energy propellant, comprising at least one oxidizer; a nitrocellul binder; an ethyl centralite stabilizer; a plasticizer; and an oxetane thermoplastic elastomer energetic binder. The oxetane thermoplastic elastomer energetic binder comprises from about zero percent to about fifteen percent by weight of the propellant. The preferred oxidizer is selected from the group consisting of CL-20, TNAZ, RDX, HMX and mixtures thereof. The oxidizer comprises from about five percent to about forth percent by weight of the propellant. The nitrocellulose binder comprises from about fifteen percent to about fifty percent by weight of the propellant and the ethyl centralite stabilizer comprises from about 0.7 percent to about 1.5 percent by weight of the propellant. The plasticizer is selected from the group consisting of TNAZ, BTTN, TMETN, TEGDN, BDNPA/F, methyl NENA, ethyl NENA and mixtures thereof. The plasticizer comprises from about five percent to about thirty-five percent by weight of the propellant.

Abstract: Double base propellants having a mixture of bismuth and copper salts of hydroxy-substituted benzoic acids added as burning rate (ballistic) modifiers.

Abstract: The present invention lies in the field of compositions which modify the ballistic properties of solid propellants and in that of the double-base solid propellants containing these compositions. Various lead compounds are known to be effective in this function, but these compounds are toxic; the problem which is solved by the present invention is to replace these lead compounds with nontoxic compounds which furthermore do not impair other properties and the performance values of the propellants. The modifying compounds are chosen from the group consisting of .beta.-resorcylates and .gamma.-resorcylates. The invention also relates to processes for the synthesis of some of these products. Finally, it relates to double-base solid propellants containing these compounds.

Abstract: The present invention relates to the unexpected discovery that the use of single base or triple base propellant of small grain size in combination with a detonator and a booster, produces a blasting agent which has considerable commercial value. The resulting blasting agent exhibits favorable cost for performance characteristics.

Abstract: A non-toxic primer composition for center-fire cartridges which provides improved ballistic data and is void of metallic oxidizing compounds. It is comprised of a mixture of about 10-30% by weight of nitrocellulose and/or a double based propellant such as Hercules Fines, approximately 30-75% by weight of two percussion-sensitive compounds such as DDNP and tetracene, and approximately 10-30% by weight of calcium silicide. The mixture provides improved propellant ignition and non-toxic ignition products, and minimizes misfires in that it contains no hygroscopic compounds.

Abstract: Nitrocellulose propellant compositions are provided comprising as ballistic modifier a copper II complex of a C.sub.6 -C.sub.12 chain aliphatic carboxylic acid, advantageously in conjunction with one or more conventional ballistic modifiers for example, lead or copper compounds such as lead stearate, lead acetophthalate, lead .beta.-resorcylate and basic copper salicylate. The preferred complex is copper II caproate. The propellant compositions exhibit good quality plateau or mesa burning over a useful pressure range for a wide range of energy and burning rates. The copper II complexes are especially advantageous in cast double base propellants particularly because their solubility in the organic solvents used facilitates their incorporation into these compositions.

Abstract: A unitary propellant charge module for use in separate ammunition comprises a combustible container having a generally hollow cylindrical shape, a generally cylindrical charge body of interconnected compacted spheroidal propellant grains disposed within the container, each of the grains having an uncompacted propellant grain diameter of at least 100 mils, and at least one generally tubular center core igniter body of interconnected compacted spheroidal propellant grains having an unrolled grain size between about 20 to less than 100 mils in diameter. The igniter body is disposed within a central bore extending along the longitudinal axis of the charge body.

Abstract: Nitrocellulose propellant compositions are provided comprising zinc oxide as ballistic modifier, advantageously in conjunction with one or more conventional ballistic modifiers for example, lead or copper compounds such as lead stearate, lead acetophthalate, lead B-resorcylate and basic copper salicylate. The propellant compositions exhibit good quality plateau burning over a useful pressure range for a wide range of burning rates.

Abstract: The present invention relates to water-in-oil emulsion explosive compositions comprising a discontinuous aqueous phase, a continuous water-immiscible organic phase, and an emulsifier content being at least 45% by weight of the emulsified fuel phase which decreases precompression or dead pressing.

Abstract: Triplebasic propellant powders consist of nitrocellulose, nitroglycerin or an equivalently acting explosive oil and crystalline nitroguanidino, which are processed by mixing with one another and plasticizing the NC by means of a solvent, e.g. acetone, as well as by kneading the mixture and subsequent shaping to solid propellant powder bodies. In order to improve the thermal stability, particularly the cold embrittlement behaviour, at least one organic titanate from the group of monoalkoxy, chelate, quaternary, neoalkoxy, cycloheteroatom or coordinated titanates and/or at least one organic zirconate from the group of neoalkoxy zirconates is added to the propellant powder in a proportion of .ltoreq.2%, preferably .ltoreq.0.5%. This addition improves the chemical stability of the propellant powder.

Abstract: The invention relates to a process for the manufacture of a double-base propellent composition with low flame-glare emission, and a propellent composition thus obtained.The process of the invention consists in casting a nitrocellulose-based moulding powder with a nitroglycerine-based casting solvent. According to the invention, the moulding powder consists of a mixture of two powders, one of which contains the antiglare agents, and the weight ratio of the powder containing the antiglare agents to the other powder is between 15/85 and 50/50. The invention permits an antiglare agent to be added to a propellent composition without affecting the ballistic properties of the composition, while strengthening the antiglare effect of this agent.The invention is applicable particularly in the field of solid-fuel propulsion.

Abstract: Use of mixtures of certain solid oxidizers in minimum smoke crosslinked propellants dramatically enhances burn rates.

Abstract: A process for producing double base propellant powders deterred with Vinsol by diluting the Vinsol with isopropyl alcohol or similar solvent and then adding the solvent Vinsol solution to the propellant powder in a sweetie barrel in an intermittent manner proceeded by addition of graphite.

Abstract: A primer charge containing an oxidizing agent and an initiating explosive. The charge contains as the oxidant zinc peroxide and as the initiating explosive diazodinitrophenol and/or a strontium salt of mono- and/or dinitrodihydroxydiazobenzene. In correspondence with the content of the strontium salt employed, the charge can also be utilized with low tamping; alternatively, such tamping can be selected at will. The charge is furthermore distinguished by lead-free and barium-free combustion products so that the charge does not exhibit the properties which make the heretofore known primer charges deleterious to the health of humans.

Abstract: A high density emulsion blasting agent and method is provided for increasing volume energy and optimizing booster sensitivity of water-in-oil emulsion blasting agents without loss of desirable handling characteristics of invert emulsions by utilizing an effective amount of a special sensitizing formulation in total or partial substitution for gas entraining density control agents.

Abstract: A combustion inhibitor for a double base propellant is described which comprises a polyurethane elastomer having in chemically combined form a compound which is an aliphatic polyester polyol or an aliphatic polyether polyol, or a mixture thereof, which compound contains 2-6 hydroxyl groups per molecule, and an aliphatic polyisocyanate. The inhibitor also contains 0.1-10 parts by weight of mineral fibers or thermostable organic fibers of length between 0.1 mm and 15 mm per 100 parts inhibitor. The inhibitor may contain an organic gasifiable charge and an aliphatic plasticizer.

Abstract: An embedment system with controlled shrinkage for use with a composite-modified double-base propellant composition which is comprised of an embedment granule portion in percent by weight of nitrocellulose of about 23.0, nitroglycerine of about 8.8-13.8, triacetin of about 1.2, bisspiro orthocarbonate from about 2.5-5.0, resorcinol of about 1.5, 2-nitrodiphenylamine of about 1.0, ammonium perchlorate (10 micrometers) of about 48.5 and aluminum powder (20 micrometers) of about 10.0 and an embedment resin portion in percent by weight of bisphenol A-epichlorohydrin of about 50.0, epoxidized dimer acid of about 50.0, and a curative which is comprised of equal parts mixture of methylenedianiline, m-phenylenediamine, and i-propyl-m-phenylenediamine with an added accelerator of 2,4-dinitrophenol. This embedment system employs a specific bisspiro orthocarbonate, 3,9-bis(5'-norbornene-2'-yl)-1,5,7,11-tetraoxaspiro[5.

Abstract: A double base propellant composition having well-platonized ballistics at low burning rates consists of nitroglycerine (NG), nitrocellulose (NC) at least one lead compound and at least one copper (II) salt of an aliphatic dicarboxylic acid. The copper salt preferably comprises copper succinate, and the lead compound may include any of those known as ballistic modifiers in the propellants art. A preferred composition, having a platonized burning rate of 2.3 mm s.sup.-1 at a chamber pressure of 2-3 MPa, comprises by weight 35.1% NC (12.6% nitrogen), 41.6% NG, 8.3% triacetin, 10.7% sucrose octa-acetate, 0.3% 2-nitrodiphenylamine, 1.2% p-nitromethylaniline, 1.0% copper (II) succinate and 1.8% lead acetophthalate.

Abstract: Certain urethane compounds containing m-phenylene substituents are useful as stabilizers for composite modified double base (CMDB) propellants. Examples of these novel urethanes are 1,3-bis(N-methoxyphenylurethane)benzene, 1,3-bis(N-m-tolylurethane)benzene, 1,3-bis(N-m-chlorophenylurethane)benzen e, 1,3-bis(N-m-phenylurethane)benzene, 1,3-bis(N-ethylurethane)benzene and bis(m-methoxyphenyl)urethane.

Abstract: Manufacturing gel free nitrocellulose lacquers in shorter time by less hazardous methods is disclosed. A low boiling solvent, miscible with polyol polymer and nitrate ester, is used during the manufacture to provide a lacquer premix comprising the polyol polymer and nitrocellulose. The premix may be a clear solution or an emulsion. Explosive nitrate esters are added to the lacquer premix and the resulting admixture sparged to reduce the water (if present) and low boiling solvent each to below about 0.02% by weight and form the gel free nitrocellulose lacquer.

Abstract: An improved embedment system is disclosed which is comprised of an embedm granule portion in percent by weight of nitrocellulose of about 23.0, nitroglycerine of about 15.0, resorcinol of about 1.5, 2-nitrodiphenylamine of about 1.0, ammonium perchlorate (10 micrometers) of about 45.5, and aluminum powder (20 micrometers) of about 14.0 and an embedment resin portion in percent by weight of bisphenol A-epichlorohydrin of about 44, epoxidized dimer acid of about 20, and a curative which is the condensation product of 2 moles of 1,2-bis(maleimido)ethane and one mole of triaminotriazine of about 36.0. This embedment system has superior characteristics of a high peel strength and greater resistance to penetration by or absorption of carboranylmethyl propionate or casting solvent absorption.

Abstract: The inclusion in a double base propellant of a ballistic modifier selected rom the class consisting of copper, lead, tin, and bismuth chelates of a dihydroxybenzophenone or alkoxyhydroxyphenzophenone.

Abstract: The present invention relates to double-base solid propellant mixtures whose burning characteristic is regulated by the addition of certain moderators such that the burn rates obtained are achieved independently of the temperature and pressure during the burn. This regulation is accomplished by the addition of a mixture of carbon black and cellulose acetate. The weight ratio of carbon black to cellulose acetate in this mixture is between 1:0.5 and 1:10. Depending on the composition of the solid propellant, the combustion of the rocket fuel can be regulated by regulating this mixture within the stated limits such that it takes place independently of temperature and pressure. The amount of the carbon black and cellulose acetate mixture present in the fuel can vary between 0.2 and 6% by weight; the carbon black is contained in the propellants of the invention in amounts between 0.05 and 1.0% by weight.

Abstract: A gas generating propellant charge which is made by piling explosive powder sheets having a plurality of projections on at least one surface thereof so as to make contact them with each other is excellent in firing characteristics, and the explosive powders in the gas generating propellant charge can be burnt in a short time, thereby generating a large amount of gas.

Abstract: Water-soluble protein is coated onto particles of nitramines by making a rry of nitramine powder in a water solution of the protein and removing the water by evaporation or by filtration after previously precipitating the protein by addition of ethanol. The protein coating acts as a bonding agent to enhance the bond strength between propellant binders and the nitramine particles, resulting in substantial enhancement of desirable propellant properties.

Abstract: The present invention relates to propellant powders based on nitrocellulose, nitrated oil and polyvinyl nitrate and also to the process for their manufacture.The powders according to the invention contain between 50 and 75 parts by weight of nitrocellulose, between 5 and 25 parts by weight of nitrated oil and between 5 and 25 parts by weight of polyvinyl nitrate.The manufacturing process consists in malaxating the energy-producing bases in the presence of an acetone/alcohol mixture until a homogeneous paste is obtained, which is extruded, drained, chopped, soaked and dried, and the process is characterized in that(i) the proportion of acetone in the paste during malaxation is between 30 and 36% by weight, relative to the dry nitrocellulose and the dry polyvinyl nitrate, and in that the weight ratio acetone/alcohol is between 1.10 and 1.

Abstract: An explosive slurry containing red water, a nitrocellulose containing prolant, oxidizer, passivated aluminum and a thickening agent.

Abstract: A method for strengthening a propellant charge by incorporating a support ructure in the propellant charge comprises slowly traversing a flexible perforated material through a propellant lacquer until the desired loading is obtained. Reinforcement by this technique makes possible the use of a double base propellant in high-thrust, short-burning applications.

Abstract: A process is provided for deterrent coating of propellant compositions useful as gun propellant in which the propellant contains nitrocellulose, nitroglycerin and nitroguanidine. In the process strands of propellant containing processing solvents are coated with burning rate deterrent on the exterior surface of the strand only. The strands are cut and dried. The process reduces exposure of the propellant to heat by elimination of the preliminary drying step to remove processing solvents prior to deterrent coating. Ethyl alcohol is the preferred processing solvent.

Abstract: Smokeless crosslinked double-base propellant compositions having good mechanical properties over a wide temperature range are provided. The propellant compositions contain nitrocellulose, energetic plasticizer, a crosslinking agent which is a prepolymer of a hydroxy terminated polyester and a diisocyanate, lead salt and carbon black.

Abstract: A double-base granular propellant consisting mainly of nitroglycerine and nitrocellulose, said nitrocellulose being formed into a three-dimensional structure by the crosslinking reaction of a polyfunctional isocyanate, is disclosed. The propellant is superior to conventional double-base granular propellant in the shooting performance, and can be obtained by a simple solvent-granulation process.

Abstract: A double base propellant charge is primed with a dimethyl siloxane resin before application of a silicone elastomer inhibitor to the primed surface. There may be a barrier coating, preferably of a polyvinyl acetal resin, between the double base material and the primer.

Abstract: A method for manufacturing crosslinked double base propellants which incls compounding the propellant with no more than 0.1 weight percent of a crosslinking catalyst, partially curing the propellant by a mild heat prior to extrusion until the energetic binder is plasticized but not crosslinked, and extruding the propellant in a ram extruder at a temperature from 120.degree. F. to 150.degree. F. before the crosslinking mechanism has become too advanced for extrusion.

Abstract: A new class of ballistic modifiers and the synthesis thereof is disclosed rein and are used in propellants either individually or as admixtures in percentages of approximately 0.5 to 6 weight percent to impart mesa or plateau burning rate characteristics over a wide pressure range and reduce the temperature sensitivity of the propellants in relation to burning rates. The modifiers are chelate type compounds comprised of lead and/or copper, and various predetermined molar ratios of compounds such as salicylic acid and beta-resorcylic acid.

Abstract: 1. Lead chelate complex compounds selected from the group consisting of lead 3-nitrosalicylaldehyde, lead 5-nitrosalicylaldehyde, lead 5-chlorosalicylaldehyde, lead 2, 4-dihydroxybenzophenone, lead ortho-hydroxyacetophenone, lead 1, 4-dihydroxyanthraquinone, lead 2,5-dihydroxybenzoquinone, lead bis-ortho-hydroxyphenacylphenone, lead phenylsalicylate, lead ethylsalicylate, lead disalicylamide, lead disalicylethylene diamide, lead salicylamide, lead bis-salicylaldehyde-o-phenylene diimine, lead salicylidene acetamide, lead bis-salicylaldehyde-ethylene diimine, and lead (o-carboxyphenyl) salicylaldimine.

Abstract: A double-base granular propellant consisting mainly of nitroglycerine and nitrocellulose, said nitrocellulose being formed into a three-dimensional structure by the crosslinking reaction of a polyfunctional isocyanate, is disclosed. The propellant is superior to conventional double-base granular propellant in the shooting performance, and can be obtained by a simple solvent-granulation process.

Abstract: A new class of ballistic modifiers and the synthesis thereof is disclosed rein and are used in propellants either individually or as admixtures in percentages of approximately 0.5 to 6 weight percent to impart mesa or plateau burning rate characteristics over a wide pressure range and reduce the temperature sensitivity of the propellants in relation to burning rates. The modifiers are chelate type compounds comprised of lead and/or copper, and various predetermined molar ratios of compounds such as salicylic acid and beta-resorcylic acid.

Abstract: Process for removal of residual "processing" solvent from propellant casting powder particles, following their manufacture, which comprises "liquid drying" the particles by contacting them with an organic liquid miscible with the processing solvent but exhibiting substantially no solvent action for the powder particle ingredients with substantially no penetration of the particles. Normally liquid hydrocarbons are exemplary liquid drying solvents of which n-heptane and n-hexane are now preferred.In preferred practice the liquid drying solvent is maintained in substantially complete wetting relationship with the particle surfaces until emplacement of the particles for casting. This eliminates safety hazards involved in conventional heat drying of the green powder and subsequent handling of the resulting dry material.

Abstract: A propellant charge composition comprising individual powder particles of a nitrocellulose propellant coated with a coating of an acrylic resin and a process for its preparation. Also disclosed is a propellant charge composition of the type described containing a second propellant.

Abstract: A casting powder granule containing a magnetic material is provided. The granule can be oriented in a desired direction by an applied magnetic field. Cast propellant charges having augmented burning rates can be prepared from magnetically susceptible casting powder granules containing metallic staple which are oriented by a magnetic field prior to addition of casting solvent.

Abstract: A process is provided for preparing double base propellant by slurry casting in which flake casting powder is employed as the source of nitrocellulose. High burning rate propellants can be prepared by this process employing flake casting powder containing ballistic modifiers.

Abstract: Explosive or propellant powder which include a cation exchange polymer having alkali metal ions bound thereto, and method of preparation.

Abstract: A process for producing propellant charge powders from solvent-containing mixtures such as nitroguanidine powders containing nitrocellulose and/ or nitrocellulose and diglycol dinitrate or nitroglycerin and nitroguanidine and additives wherein an alcohol-containing mixture or optionally a water-containing mixture of said propellant charge powders is premixed with additional components of the propellant powder, the mixture is first dried, if necessary, and the solvent is incorporated therein and the solvent-containing premix is homogenized and preplasticized in a kneading device or the water-containing premix is homogenized and preplasticized in the kneading device and then the resultant mixture is dewatered by drying and then combined with a solvent; then the solvent-containing mixture is plasticized in an extruder and converted thereby into granular form and the resulting granular material is extruded into a final product form in a screw-type extruder. Subsequently, the solvent is evaporated therefrom.

Abstract: The addition of azobisformamide to a double base propellant in order to (1) hift the plateau pressure-burning rate relationship of a double base propellant modified by any of the commonly used copper and lead organo salts and (2) increase the volume and nitrogen content of the exhaust gas of the propellant.

Abstract: 1. A propellant formulation comprising the following ingredients:NitrocellulosePrepolymer of polyglycoladipate and 2,4-tolylene diisocyanateNitroglycerinCyclotetramethylenetetranitramineAluminum2-Nitrodiphenylamine.6. A propellant composition consisting essentially of:The prepolymer of polyglycoladipate and 2,4-tolylene diisocyanate;Nitrocellulose, andNitroglycerin.

Abstract: Low (thermal) Vulnerability Ammunition or LOVA is more responsive to the rmal stimulation of the igniter compositions disclosed herein. The igniter compositions of this invention generate oxygen rich flames upon decomposition. Such igniter compositions comprise nitrocellulose, nitroglycerine, potassium perchlorate and ethyl centralite. An agent comprising one or more titanate salts and/or carbon black may optionally be included in such compositions to the extent of about 0.35% w/w. Such compositions can be extruded and utilized in strand form.