Abstract: An organo-metallic ballistic modifier produced as an evaporation residue by he reaction of normal lead beta resorcylate and monobasic cupric salicylate in an aqueous solution of water or alcohol at an elevated temperature (180.degree. F - 220.degree. F). The modifier allows the use of a solvent or solvent/solventless process in the production of double base propellants exhibiting a mesa burning rate.
Type:
Grant
Filed:
February 18, 1972
Date of Patent:
January 4, 1977
Assignee:
The United States of America as represented by the Secretary of the Army
Abstract: Ballistic modifiers of up to one micron in size are slurried and mixed with high impulse propellant slurry in order to produce a high impulse propellant having a plateau or mesa burning characteristic.
Type:
Grant
Filed:
May 28, 1974
Date of Patent:
December 28, 1976
Assignee:
The United States of America as represented by the Secretary of the Navy
Abstract: A novel ballistic modifier complex is produced by mixing and interacting an rganic isocyanate with lead beta resorcylate and cupric salicylate in an inert solvent. The complex product obtained after removal of the solvent, when incorporated into a nitrocellulose-nitroglycerine double base propellant, yields a propellant composition of excellent ballistic properties and improved stability against development of exudate which inhibits ignition.
Type:
Grant
Filed:
May 4, 1971
Date of Patent:
November 30, 1976
Assignee:
The United States of America as represented by the Secretary of the Army
Inventors:
Thomas E. Dunigan, George C. Sisco, Lawrence W. Pell
Abstract: A novel ballistic modifier complex is produced by mixing and interacting an rganic isocyanate with lead beta resorcylate and cupric salicylate in an inert solvent. The complex product obtained after removal of the solvent, when incorporated into a nitrocellulose-nitroglycerine double base propellant, yields a propellant composition of excellent ballistic properties and improved stability against development of exudate which inhibits ignition.
Type:
Grant
Filed:
January 3, 1973
Date of Patent:
November 30, 1976
Assignee:
The United States of America as represented by the Secretary of the Army
Inventors:
Thomas E. Dunigan, George C. Sisco, Lawrence W. Pell
Abstract: An organo-metallic ballistic modifier produced as an evaporation residue by the interaction of two or more organo-metallic salts in an aqueous solution of water or alcohol at an elevated temperature (180.degree. F - 220.degree. F). The modifier allows the use of a solvent or solvent/solventless process in the production of double base propellants exhibiting a mesa burning rate.
Type:
Grant
Filed:
October 7, 1970
Date of Patent:
November 2, 1976
Assignee:
The United States of America as represented by the Secretary of the Army
Abstract: In the preparation of double-base propellants where nitrocellulose-based granules are gelatinized by an explosive oil, the ballistic properties of the propellant are controlled by adjusting the content of nitrogen of the nitrocellulose of the granules, said content ranging from 12.6 to 14 % approximately.
Type:
Grant
Filed:
July 27, 1973
Date of Patent:
September 7, 1976
Assignee:
Societe Nationale des Poudres et Explosifs
Abstract: 1. A solid rocket propellant composition which consists essentially of from about:1. 30-60 weight per cent of a double base propellant2. 5-30 weight per cent of a finely divided metal fuel3. 5-30 weight per cent of an inorganic oxidizer4. 10-30 weight per cent of triaminoguanidinium azide.
Type:
Grant
Filed:
January 24, 1962
Date of Patent:
July 27, 1976
Assignee:
The Dow Chemical Company
Inventors:
William A. Rains, Robert D. Fox, James P. Flynn
Abstract: An energetic double base propellant composition consisting essentially of trocellulose and nitroglycerin as the major ingredients with about 48-52 weight percent of the propellant composition being nitrocellulose and about 40-44 weight percent of the propellant composition being nitroglycerin, and the minor ingredients comprised of about 2-4 weight percent di-n-propyladipate, about 2-2.5 weight percent 2-nitrodiphenylamine, about 0.1-0.2 weight percent candelilla wax, and about 1.0-1.3 weight percent aluminum is disclosed.
Type:
Grant
Filed:
November 8, 1974
Date of Patent:
June 15, 1976
Assignee:
The United States of America as represented by the Secretary of the Army
Abstract: 1. A process for the production of a cast propellent which consists in blending a colloided nitrocellulose smokeless powder composition containing a platonisation agent selected from the group consisting of lead stearate, lead citrate, lead salicylate, lead 2:4 dihydroxy-benzoate, lead sulphite, lead oxide, copper oxalate, copper salicylate, copper 2:4 dihydroxy-benzoate and cupric oxide, with colloided nitrocellulose smokeless powder composition containing a secondary flash suppressing potassium salt in the proportion by weight of at least three parts of the first mentioned nitrocellulose composition, adding to the blended nitrocellulose compositions a casting liquid consisting essentially of nitroglycerine in an amount sufficient to fill the interstices in the blended nitrocellulose compositions, and heating the resulting mixture.
Type:
Grant
Filed:
June 12, 1959
Date of Patent:
June 1, 1976
Assignee:
Imperial Chemical Industries Limited
Inventors:
Edward Whitworth, Stuart Gordon, Stephen Harry Hayes
Abstract: Propelling charge composition of a mixture of two powder components of different burning rates wherein the quicker burning powder component has a protective coating which retards its combustion.
Abstract: Double-base propellant compositions of the plateau and/or mesa type which e comprised of ballistic modifiers of lead and copper salts of acetamidobenzoic acids, acetamidosalicylic acids, and resorcylic acids.
Type:
Grant
Filed:
October 29, 1969
Date of Patent:
May 4, 1976
Assignee:
The United States of America as represented by the Secretary of the Navy
Abstract: Double-based propellant combustion catalysts such as lead stannate-tolylene iisocyanate(reduced) are extremely effective in lowering the temperature dependency of burning rate with pressure of smokeless propellants irrespective of their crossed or uncrossed linkages.
Type:
Grant
Filed:
December 14, 1973
Date of Patent:
May 4, 1976
Assignee:
The United States of America as represented by the Secretary of the Army
Abstract: 7. A process for preparing a solid propellant composition having a plateau-burning rate comprising the steps ofA. mixing at room temperature the following ingredients until a viscous binder results:Ingredients Percent by weight ______________________________________ High energy plasticizer selected from 15 to 85 the group consisting of pentaerythritol trinitrate, diethylene glycol dinitrate, trimethylolethane trinitrate and mixtures thereof Ingredients Percent by weight ______________________________________ Plastisol nitrocellulose 10 to 50 Ethyl centralite .4 to 5; ______________________________________B. blending into said binder, until a homogeneous pourable mixture result a cured propellant composition which has been milled to an average particle size of about 30 mesh, said composition consisting essentially of the following ingredientsIngredients Percent by weight ______________________________________ Nitrocellulose 13.5 to 27.5 Nitroglycerin 10.5 to 22.5 Additives .
Abstract: Double-based propellant combustion catalysts such as lead stannatetolylene iisocyanate(reduced) are extremely effective in lowering the temperature dependency of burning rate with pressure of smokeless propellants irrespective of their crossed or uncrossed linkages.
Type:
Grant
Filed:
July 1, 1970
Date of Patent:
April 20, 1976
Assignee:
The United States of America as represented by the Secretary of the Army
Abstract: A method for producing high density and high energy solid propellants conting of a solid inorganic oxidizing salt, a binder and a granular organic explosive comprising, the suspension of said ingredients in an organic solvent with agitation at ambient temperature to form a colloid, extruding the colloid, and raising the temperature to cure the grain, and the mixing of said propellant ingredients under vacuum, raising the temperature until a bulk viscosity of approximately 60,000 to 70,000 centipoises is reached, pouring said ingredients into a mold under vacuum, and curing the grains until the charge solidifies.
Type:
Grant
Filed:
January 11, 1968
Date of Patent:
March 9, 1976
Assignee:
The United States of America as represented by the Secretary of the Army