Tread Composition Patents (Class 152/905)
  • Patent number: 6476115
    Abstract: This invention relates to a conjugated diene-based rubber composition reinforced with silica-based reinforcement together with a non-silane coupling agent as N-3-(1,2-dihydroxypropyl)-N-oleylammonium bromide and/or N-3-(1,2-dihydroxypropyl)-N-methyl-2-mercaptoimidazolium bromide for endeavoring to both couple synthetic aggregates of precipitated silica to elastomers and enhancing electrical conductivity of such rubber compositions which contain less than 25 parts by weight carbon black per 100 parts by weight elastomer. Said coupling agent materials may be provided for mixing with said diene-based rubber(s), for example, as individual materials, as at least one of said materials being supported on a carbon black carrier or as being pre-reacted, or otherwise pre-treated, with synthetic silica aggregates. The invention includes an article of manufacture, including a tire, having at least one component comprised of such rubber composition.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: November 5, 2002
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Lawson Gibson Wideman, David John Zanzig
  • Patent number: 6448325
    Abstract: There is disclosed a rubber composition particularly suited for use in tires. The rubber composition is composed of 100 parts by weight of at least one rubber containing olefinic unsaturation; and from 1 to 150 parts per 100 parts by weight of rubber, of a silica having predispersed on the surface of the silica a liquid epoxidized butadiene polymer having a number average molecular weight of from 500 to 10,000.
    Type: Grant
    Filed: February 27, 2001
    Date of Patent: September 10, 2002
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Friedrich Visel, Thierry Florent Edme Materne, Giorgio Agostini
  • Publication number: 20020088521
    Abstract: There is provided a rubber composition for breaker cushion excellent in elongation at break strength at break after aging with maintaining control stability, and a truck and bus tire using the rubber composition. A rubber composition for breaker cushion comprises 1,3-bis(citraconimidomethyl)benzene and 25 to 35 parts by weight of carbon black having a nitrogen adsorption specific surface area of 70 to 120 cm2/g based on 100 parts by weight of a rubber component.
    Type: Application
    Filed: November 13, 2001
    Publication date: July 11, 2002
    Inventor: Yoichi Mizuno
  • Patent number: 6390163
    Abstract: The subject invention is based upon the unexpected discovery that tires having outstanding dry and wet traction characteristics, including wet skid resistance, can be made by incorporating certain blends of styrene-butadiene rubber (SBR) and isoprene-butadiene rubber (IBR) into the treads thereof without greatly sacrificing rolling resistance and tread wear characteristics.
    Type: Grant
    Filed: September 3, 1999
    Date of Patent: May 21, 2002
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: James Edward Duddey
  • Publication number: 20020042479
    Abstract: A process for producing tires for vehicle wheels includes making a raw tire including at least one crosslinkable elastomeric material, molding the raw tire in a molding cavity defined in a vulcanization mold, and crosslinking the elastomeric material by heating the tire to a predetermined temperature for a predetermined time, wherein the raw tire includes at least one crosslinkable elastomeric material having an elastomeric polymer containing epoxide groups and an active filler containing hydroxyl groups dispersed in the elastomeric polymer, and wherein the crosslinking step is carried out essentially without additional crosslinking agents. A related composition, process for producing the composition, manufactured product, and tire are also disclosed.
    Type: Application
    Filed: June 12, 2001
    Publication date: April 11, 2002
    Inventors: Marco Nahmias Nanni, Antonio Serra
  • Patent number: 6357499
    Abstract: The present application relates to polymeric resinous material comprising (1) from 5 to 70 weight percent units derived from limonene; (2) from 5 to 70 weight percent units derived from dicyclopentadiene; (3) from 5 to 45 weight percent units derived from indene; and (4) from 5 to 45 weight percent units derived from tertiary-butyl styrene; wherein the sum of the weight percent units derived from limonene and dicyclopentadiene range from 40 to 75 weight percent units of the resin and the sum of the weight percent units derived from indene and tertiary-butyl styrene range from 25 to 60 weight percent units of the resin.
    Type: Grant
    Filed: August 27, 1999
    Date of Patent: March 19, 2002
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Mark Leslie Kralevich, Jr., Edward John Blok, Paul Harry Sandstrom, Lawson Gibson Wideman, Joseph Miles Ruscak
  • Patent number: 6355710
    Abstract: A rubber composition comprising (A) at least one natural or synthetic diene rubber, (B) an inorganic filler comprising at least one of silica and silicates as the main component and (C) an addition salt of an amine represented by general formula (I): wherein R1 represents a C8 to C24 alkyl group, an aryl group or an aralkyl group, R2 and R3 represent a hydrogen atom, a C1 to C12 alkyl group, an aryl group, an aralkyl group or a hydroxyalkyl group and R4 represents a C6 to C24 alkyl or alkenyl group, an aryl group or an aralkyl group; and a pneumatic tire produced by using the rubber composition.
    Type: Grant
    Filed: August 28, 2000
    Date of Patent: March 12, 2002
    Assignees: Bridgestone Corporation, Kao Corporation
    Inventors: Kazuhiro Yanagisawa, Masaaki Tsuchihashi, Isao Nishi, Tetsuo Takano
  • Patent number: 6306949
    Abstract: The invention relates to the preparation of a rubber composition containing silica-based filler reinforcement through the utilization of a organosilane disulfide compound mixed with a rubber composition in at least one preparatory, non-productive, mixing stage followed by utilization of an organosilane polysulfide compound mixed with the rubber composition in a subsequent, productive, mixing stage. The invention further relates to the resulting rubber composition and use thereof in tires.
    Type: Grant
    Filed: October 22, 1998
    Date of Patent: October 23, 2001
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Thierry Florent Edmé Materne, Giorgio Agostini, Ghislain Adolphe Léon Thise
  • Patent number: 6277902
    Abstract: The present invention relates to rubber compounds comprising one or more soluble rubbers, hydrophobized filler, and one or more sulfane-silane compounds on an inorganic or organic support and to a process for making them. The novel rubber compounds are suitable for moldings of every kind, especially tires or tire treads having low rolling resistance and high resistance to abrasion.
    Type: Grant
    Filed: April 16, 1999
    Date of Patent: August 21, 2001
    Assignee: Bayer Aktiengesellschaft
    Inventor: Thomas Scholl
  • Patent number: 6258886
    Abstract: The invention provides solid supported anionic catalysts, suitable for gas phase anionic polymerization of conjugated diene monomers, that are useful for anionically producing very high molecular weight branched diene polymers, such as styrene butadiene rubber, polybutadiene rubber, polyisoprene rubber, and the like. The catalysts comprise a metalatable particle, such as a bound rubber, a thermoplastic polymer or a cured elastomer, that is multiply metalated with Group IA alkali metal atoms. The multi-branched diene polymers obtained by gas phase anionic polymerization employing the catalysts exhibit desirable properties, such as an extremely high molecular weight, a controlled molecular weight distribution, Tg and vinyl content, and the ability to readily absorb hydrocarbon solvents and oils. The polymers are easily compounded to form vulcanizable elastomeric compounds and articles, such as tires, that have excellent resistance to wear and tear and exhibit reduced hysteresis properties.
    Type: Grant
    Filed: November 23, 1999
    Date of Patent: July 10, 2001
    Assignee: Bridgestone Corporation
    Inventors: William M. Cole, William L. Hergenrother, Theodore J. Knutson, Georg G. A. Böhm
  • Patent number: 6242523
    Abstract: This invention relates to a rubber composition composed of high Tg diene-based elastomers and which contains a high Tg liquid polymer of high vinyl polybutadiene and to such a composition being sulfur cured. The invention also relates to a tire having a tread of such rubber composition.
    Type: Grant
    Filed: March 8, 1999
    Date of Patent: June 5, 2001
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Edward John Blok, Mark Leslie Kralevich, Jr., Paul Harry Sandstrom, Shingo Futamura
  • Patent number: 6242522
    Abstract: There is disclosed a rubber composition for a tire tread Which comprises 100 parts by weight of (A) a rubber component comprising a diene-based synthetic rubber or a mixture of a diene-based synthetic rubber and natural rubber and containing at least 20% by weight of a styrene-butadiene rubber; 5 to 50 parts by weight of (B) aluminum hydroxide powders; and at least 5 parts by weight of (C) silica powders, wherein the total amount of the components (B) and (C) is in the range of 40 to 80 parts by weight; and optionally chemical agents such as vulcanizing agents, vulcanization accelerators and antioxidants, and also is disclosed a pneumatic tire in which the above rubber composition is used as the tread rubber. The above rubber composition, when made into a tire tread, can maintain favorable low fuel consumption properties and low wear resistance, and besides can impart the tire with greatly improved gripping properties on wet road surfaces particularly at a low temperature.
    Type: Grant
    Filed: March 22, 1999
    Date of Patent: June 5, 2001
    Assignee: Bridgestone Corporation
    Inventors: Naofumi Ezawa, Kazuo Yagawa, Naohiro Sasaka
  • Patent number: 6228928
    Abstract: New carbon blacks that when incorporated into rubber compositions impart increased abrasion resistance and lower hysteresis. Also disclosed are rubber composition incorporating the novel carbon blacks, which have nitrogen surface area of at least 100, a CDBP of at least 105, a tint of 90-140 and a delta D50/Dmode ratio of 0.6-0.76.
    Type: Grant
    Filed: March 21, 1994
    Date of Patent: May 8, 2001
    Assignee: Cabot Corporation
    Inventors: Mizuo Soeda, Yoichi Yuza, Takeo Ito, Kazue Watanabe, Ted W. Bush, Martin Green, John M. Branan, Jr.
  • Patent number: 6220323
    Abstract: The invention relates to a rubber composition containing relatively low levels of carbon black and/or silica reinforcement together with a particulate calcium carbonate and selected modifiers. The invention particularly relates to a tire having a component, particularly a tread, of such composition.
    Type: Grant
    Filed: January 29, 1998
    Date of Patent: April 24, 2001
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Paul Harry Sandstrom, Mark Samuel Sinsky
  • Patent number: 6214911
    Abstract: The present invention relates to rubber compositions containing borate compounds of the formula wherein R1 and R2 are independently selected from the group consisting of alkoxy radicals having from 1 to 8 carbon atoms; R3 is selected from the group consisting of alkylene groups having from 1 to 15 carbon atoms and arylene and alkyl substituted arylene groups having from 6 to 10 carbon atoms; X is selected from the group consisting of and Y is selected from the group consisting of Sx and Sex where x is an integer of from 1 to 8.
    Type: Grant
    Filed: March 2, 2000
    Date of Patent: April 10, 2001
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Thierry Florent Edme Materne, Rene Jean Zimmer, Friedrich Visel, Uwe Ernst Frank
  • Patent number: 6211281
    Abstract: There is disclosed a pneumatic tire for heavy duty use having a tread which is composed of a rubber composition comprising 100 parts by weight of an (A) isoprene-based rubber and 30 to 70 parts by weight of (B) carbon black which has a nitrogen-adsorption specific surface area (BET) of 120 to 160 m2/g; a dibutyl phthalate absorption amount (DBP) of 80 to 130 ml/100 g; a most frequent value of aggregate diameter distribution (Dst) of 60 to 70 nm; and a half peak width (&Dgr;D50) of 65 to 80 nm, and as the case may be, 3 to 20 parts by weight of (C) silica which has a nitrogen-adsorption specific surface area (BET) of 210 to 260 m2/g; and an oil absorption amount of 200 to 260 ml/100 g. The above pneumatic tire is capable of enhancing the low heat-buildup property without detriment to the abrasion resistance of a tread rubber, and favorably reconciling both the low heat-buildup property and the abrasion resistance of itself.
    Type: Grant
    Filed: January 14, 1999
    Date of Patent: April 3, 2001
    Assignee: Bridgestone Corporation
    Inventor: Tomohiro Kusano
  • Patent number: 6158488
    Abstract: The invention relates to a rubber composition containing a modified silanol-containing carbon black reinforcement which has a grafted hydrocarbon on its surface. The invention also relates to an article such as, for example, a tire having at least one component of such rubber composition.
    Type: Grant
    Filed: October 8, 1998
    Date of Patent: December 12, 2000
    Assignee: The GoodYear Tire & Rubber Company
    Inventors: Thierry Florent Edme Materne, Giorgio Agostini, Marc Junio
  • Patent number: 6130283
    Abstract: Aluminum hydroxide is disclosed, wherein a mean particle size of a secondary particle is from 0.1 to 8 .mu.m, a BET specific surface area is not less than about 30 m.sup.2 /g and a pore size distribution has a maximum value within the range from 5 to 100 nm, a method for producing the same, and a method of using the same, comprising containing the same in a rubber, a method for using the same as a filler of a rubber composition for tire tread, and a rubber composition for tire tread using the same.
    Type: Grant
    Filed: May 16, 1997
    Date of Patent: October 10, 2000
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Satoru Nippa, Toshiyuki Mizoe
  • Patent number: 6107384
    Abstract: A silica-blended rubber composition comprising 100 parts by weight of sulfur-vulcanizable rubber blended with 10 to 100 parts by weight of silica, 3 to 20% by weight of a silane coupling agent based on the silica and 1 to 20% by weight of sodium borate based on the silica. An alkoxy group-containing silane coupling agent is preferred as the silane coupling agent, and sodium tetraborate is preferred as the sodium borate.
    Type: Grant
    Filed: March 17, 1999
    Date of Patent: August 22, 2000
    Assignee: Bridgestone Corporation
    Inventors: Kazuya Hatakeyama, Kazuaki Someno
  • Patent number: 6095216
    Abstract: A tire is described which has a tread pattern provided with a large central channel (2) interposed between two continuous circumferential ribs (8), and a pair of large circumferential grooves (4) located at symmetrically opposite positions relative to the central channel (2). Also provided are transverse grooves (3) having a symmetrically converging inclined extension, the axial inclination of which increasingly grows larger towards the central channel (2). The longitudinal grooves (4) each consist of a sequence of oblique portions (4a) giving the grooves a broken-line course, so that each land portion or block (5, 6) delimited by the grooves (3, 4) has a corner (5a, 6a) projecting inwardly of the corresponding circumferential groove (4) with respect to the opposite corner (5b, 6b) of the circumferentially adjacent block.
    Type: Grant
    Filed: July 12, 1996
    Date of Patent: August 1, 2000
    Assignee: Pirelli Coordinamento Pneumatici SpA
    Inventors: Roberto Cenni, Gianfranco Colombo
  • Patent number: 6095217
    Abstract: A pneumatic tire comprising a tread which contacts a road surface and comprises a rubber composition which contains a rubber component composed of 70% by weight or more of a copolymer of a conjugated diene and a vinyl aromatic hydrocarbon and a remaining amount of another synthetic rubber and/or natural rubber, at least one reinforcing filler selected from a group consisting of carbon black and silica, and at least one type of vulcanization accelerator, such as bis(4-methylbenzothiazolyl-2)-disulfide, bis(5-methylbenzothiazolyl-2)-dis ulfide, mercapto-4-methylbenzothiazole, and mercapto-5-methylbenzothiazole, an amount of the reinforcing filler being 45 to 120 parts by weight and an amount of the vulcanization accelerator being 0.5 to 5.0 parts by weight per 100 parts by weight of the rubber component. Decrease in chipping resistance during tire use is suppressed, and both abrasion resistance and controllability on wet roads after use of the tire are improved.
    Type: Grant
    Filed: July 11, 1997
    Date of Patent: August 1, 2000
    Assignee: Bridgestone Corporation
    Inventors: Eiji Nakamura, Naohiro Sasaka, Masayuki Ohashi
  • Patent number: 6053226
    Abstract: This invention relates to a rubber composition and to a tire with tread of rubber composition prepared with filler reinforcement, a majority of which is silica reinforcement, together with a silica coupling agent, and a minority is carbon black and conventional rubber compounding ingredients wherein at least one of said compounding ingredients and/or coupling agent is liquid and is provided as being deposited on a specified carbon black carrier. In particular, the carbon black carrier is characterized by having a DBP value in a range of about 280 to about 600 cm.sup.3 /100 g and a BET value in a range of about 550 to about 1200 m.sup.2 /g. The selection of the said carbon black carrier is intended to reduce the electrical volume resistivity of the tread composition.
    Type: Grant
    Filed: March 13, 1998
    Date of Patent: April 25, 2000
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Giorgio Agostini
  • Patent number: 6022922
    Abstract: The invention relates to a tire with a tread which is reinforced with a quantitative amount of silica, including a silica coupler, where the tread rubbers are of a blend comprised of styrene/isoprene/butadiene terpolymer rubber and cis 1,4-polybutadiene rubber or styrene/isoprene/butadiene terpolymer rubber, cis 1,4-polybutadiene rubber and isoprene/butadiene copolymer rubber. Optionally, the rubber blend can contain a minor amount of cis 1,4-polyisoprene natural rubber.
    Type: Grant
    Filed: July 7, 1997
    Date of Patent: February 8, 2000
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Jean Bergh, Marc Junio, Jean-Claude Joseph Marie Kihn, Tom Dominique Linster, Jean-Paul Lambotte