Nitrogen Containing Patents (Class 162/164.6)
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Patent number: 12018437Abstract: A papermaking agent exhibiting an excellent freeness and paper strength effect with little increase in viscosity after long-term storage. A papermaking agent including a (meth)acrylamide polymer containing two or more starches (a1) selected from the group consisting of unmodified starch, oxidized starch, esterified starch, etherified starch, amidated starch, cationic starch, amphoteric starch and crosslinked starch, a (meth)acrylamide (a2), a polymerizable monomer having an amino group (a3), a polymerizable monomer having a carboxy group (a4) and a polymerizable monomer having a sulfonate group (a5) as essential constituent components.Type: GrantFiled: September 16, 2022Date of Patent: June 25, 2024Assignee: ARAKAWA CHEMICAL INDUSTRIES, LTD.Inventors: Ryusuke Kambara, Hiroyuki Ioka, Shuichi Takaki
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Patent number: 11673982Abstract: A method of producing a surface sizing composition, the method comprising: providing a metal salt having at least 3 valence electrons, wherein the metal salt is selected from the group of aluminium sulfate, aluminium chloride, aluminium nitrate, polyaluminium sulfate (PAS), polyaluminium chloride (PAC), and polyaluminium chloride sulfate (PACS), polyaluminium formiate, polyaluminium nitrate, and any combination thereof; providing an aqueous polymer dispersion, wherein the aqueous polymer dispersion is an aqueous polymer dispersion (A) and an aqueous prepolymer composition (B), wherein the aqueous polymer dispersion (A) is obtainable by free radical emulsion copolymerizing a first ethylenically unsaturated monomer blend, and wherein the aqueous prepolymer composition (B) is obtainable by free radical emulsion copolymerizing in a polymerization solvent comprising C1-6-carboxylic acid and C1-6-carboxylic acid anhydride, a second ethylenically unsaturated monomer blend; and mixing the metal salt and the aqueous pType: GrantFiled: December 21, 2021Date of Patent: June 13, 2023Assignee: KEMIRA OYJInventors: Anneli Lepo, Tarja Turkki, Elsi Turunen
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Patent number: 11566378Abstract: A fiber assembly-forming method includes providing a water-soluble resin to a first feedstock containing fibers, forming disintegrated matter by disintegrating the first feedstock provided with the water-soluble resin, depositing the disintegrated matter, and providing water to the deposited disintegrated matter.Type: GrantFiled: November 25, 2020Date of Patent: January 31, 2023Assignee: Seiko Epson CorporationInventor: Tetsuya Aoyama
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Patent number: 11453979Abstract: Embodiments of the present invention relate to a method of making a paper comprising the steps of: a) providing a cationic wet strength resin comprising a polyamidoamine epihalohydrin, a condensation copolymer of epihalohydrin and amine, or combination thereof; b) providing an anionic polymer; c) co-mixing the cationic wet strength resin and the anionic polymer to provide a composition comprising polyelectrolyte complexes; d) providing an aqueous pulp slurry, draining the aqueous pulp slurry on a screen to form a wet fiber web, and drying the wet fiber web to obtain the paper, wherein said co-mixed composition is introduced to the aqueous pulp slurry or on the formed wet fiber web. Embodiments of the present invention further relates to a paper wet strength composition, its use in paper making and a paper obtainable therefrom.Type: GrantFiled: May 14, 2018Date of Patent: September 27, 2022Assignee: KEMIRA OYJInventors: Yuping Luo, Junhua Chen, Zheng Dang
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Patent number: 11441273Abstract: The invention relates to a use of a water-soluble polymer product comprising amphoteric polyacrylamide, which has neutral or cationic net charge at pH 7, a weight-average molecular weight of 2,500,000-18,000,000 g/mol and a total ionicity of 4-28 mol-%. The polymer product is used for controlling deposit formation caused by hydrophobic substances in manufacture of paper or board, where a fibre web is formed from an aqueous suspension of fibres. The invention relates also to a method for controlling deposit formation caused by hydrophobic substances in manufacture of paper or board, where a fibre web is formed from an aqueous suspension of fibres, as well as to produced paper or board.Type: GrantFiled: November 22, 2017Date of Patent: September 13, 2022Assignee: Kemira OyjInventors: Matti Hietaniemi, Asko Karppi, Maarit Latvanen, Elsa Olmos
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Patent number: 11346054Abstract: A fiber body forming method includes a step of preparing a web which contains fibers and which has a bulk density of 0.09 g/cm3 or more; and a step of applying a liquid containing a binder which binds the fibers together to the web.Type: GrantFiled: November 26, 2019Date of Patent: May 31, 2022Assignee: SEIKO EPSON CORPORATIONInventors: Tetsuya Aoyama, Shinichi Kato, Shigemi Wakabayashi, Kaneo Yoda
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Patent number: 11248344Abstract: The present invention relates to an enhanced process for the production of cellulose pulps with increased quality and applicability of said pulps, especially their physical resistance properties and degree of resistance to drainage, through an enzymatic treatment step comprised in the production process of said cellulose pulp, concomitantly with the polymer dosage based on carbohydrates.Type: GrantFiled: December 27, 2016Date of Patent: February 15, 2022Assignee: Suzano S.A.Inventors: Otávio Mambrim Filho, Leonardo Alves De Melo
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Patent number: 11242423Abstract: The present invention relates to a surface sizing composition comprising a metal salt, wherein the metal has at least 3 valence electrons, and an aqueous polymer dispersion, wherein the aqueous polymer dispersion is an aqueous polymer dispersion (A) obtainable by free radical emulsion copolymerizing a first ethylenically unsaturated monomer blend comprising (a) 0 to 75% by weight of at least one optionally substituted styrene, (b) 15 to 100% by weight of at least one C1-C4-alkyl (meth)acrylate, and (c) 0 to 10% by weight of other ethylenically unsaturated copolymerizable monomers, wherein the sum (a)+(b)+(c) is 100%, in the presence of a water-soluble redox system comprising a first free radical initiator for the free radical emulsion copolymerization and an aqueous prepolymer composition (B) obtainable by free radical emulsion copolymerizing in a polymerization solvent comprising C1-6-carboxylic acid and C1-6-carboxylic acid anhydride, a second ethylenically unsaturated monomer blend comprising (i) 5 to 50%Type: GrantFiled: March 29, 2018Date of Patent: February 8, 2022Assignee: Kemira OyjInventors: Anneli Lepo, Tarja Turkki, Elsi Turunen
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Patent number: 11203838Abstract: A method for the production of paper or cardboard is provide comprising the following steps: (A) Adding a water soluble polymer P to a first aqueous pulp suspension, wherein polymer P is obtainable by Polymerizing to a polymer V of (i) 33 to 83 mol % of a monomer of formula I in which R1?H or C1-C6 alkyl, (ii) 6 to 56 mol % of diallyl dimethyl ammonium chloride, diallyl diethyl ammonium chloride or a salt form of a monoethylenically unsaturated monomer, (iii) 11 to 61 mol % of a monoethylenically unsaturated carboxylic acid, sulfonic acid or phosphonic acid, or salt forms thereof, (iv) 0 to 50 mol % of one or more ethylenically unsaturated monomers, and hydrolyzing the N—C(?O)R1 groups to form primary amino or amidine groups, (B) dehydrating the second aqueous pulp suspension to a wet paper structure, (C) dehydrating the wet paper structure.Type: GrantFiled: October 1, 2018Date of Patent: December 21, 2021Inventors: Christoph Hamers, Hans-Joachim Haehnle, Kai Pahnke, Anton Esser
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Patent number: 10953568Abstract: The invention relates to a method for the production of MDF boards, fibre and particle boards, based on cellulose fibres, comprising the following steps: obtaining wood chips; transporting them to a vaporizer silo where they are heated; transporting the wood chips to a digester where they continue to be heated and are conveyed via a supply outlet screw towards a shredder/refiner; adding a paraffinic emulsion to the chips; transporting them towards the shredder/refiner; injecting resin; carrying to a dryer; transporting towards a fibre silo; carrying the fibres to a step of forming, pre-pressing, pressing, measuring, classification, cooling, standing, formatting and packaging of the boards produced, wherein nanofibrillated cellulose (NFC) is added, together with microfibrillated cellulose (MFC), be it in the supply screw, or after the shredder/refiner, or after the dryer.Type: GrantFiled: March 9, 2015Date of Patent: March 23, 2021Assignee: INVESTIGACIONES FORESTALES BIOFOREST S.A.Inventors: Olli Joutsimo, Bruno Gorrini
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Patent number: 10927200Abstract: In a method for preparing glyoxylated polyacrylamide, in which an aqueous solution of polyacrylamide is supplemented with ethanedial (glyoxal) under stirring by means of a circulation pump, the reaction is started by the addition of a base, at a basic pH value above 8, and is allowed to react under stirring and/or circulating, whereupon the reaction is stopped by the addition of an acid under stirring and/or circulating after completion of a predetermined reaction time, wherein the method is per as a discontinuous method in which the quantitative reaction of ethanedial with an excess amount of polyacrylamide in an aqueous basic medium is controlled and/or regulated by at least one, of the following factors: a) turbidity measurement b) adaptation as a function of the temperature c) pH adaptation as a function of the reaction time d) drop of pH the value, or e) current consumption of the circulation pump.Type: GrantFiled: February 27, 2017Date of Patent: February 23, 2021Assignee: APPLIED CHEMICALS HANDELS-GMBHInventor: Nuri Kerman
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Patent number: 10876254Abstract: A method of increasing chemical efficiency of chemical additives in a papermaking system includes the steps of providing thick stock pulp comprising soluble lignin, process water, and at least about 2% by weight of cellulosic fiber based on total weight of thick stock pulp, and adding at least one laccase enzyme and at least one organic polymer to the thick stock pulp to reduce the amount of soluble lignin therein. The organic polymer is chosen from cationic polymers, non-ionic polymers and combinations thereof.Type: GrantFiled: October 2, 2018Date of Patent: December 29, 2020Assignee: SOLENIS TECHNOLOGIES, L.P.Inventors: John C. Harrington, Mingxiang Luo, Davit E. Sharoyan, Sujan Singh
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Patent number: 10815622Abstract: Methods and apparatus for vacuum forming a beverage carrier yoke using a slurry. The slurry comprises: a moisture barrier comprising AKD in the range of about 4% by weight; and a fiber base comprising OCC and NP.Type: GrantFiled: August 16, 2018Date of Patent: October 27, 2020Assignee: Footprint International, LLCInventors: Yoke Dou Chung, Brandon Michael Moore, Yiyun Zhang, Michael Lembeck
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Patent number: 10711401Abstract: Compositions and methods related to new wet strength resins are provided. By using functionally-symmetrical cross-linkers and mono-functional modifiers, and separating the steps of reacting a prepolymer with the cross-linkers from the reaction of intermediate cross-linked prepolymer with epichlorohydrin, new wet strength resin products are provided having improved properties.Type: GrantFiled: October 2, 2017Date of Patent: July 14, 2020Assignee: ECOLAB USA INC.Inventors: Clay E. Ringold, Cornel Hagiopol, Dexter C. Johnson
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Patent number: 10704201Abstract: The present disclosure relates to a dry strength agent composition, use of an amine-containing cationic polymer for enhancing the dry strength of paper, and a method for enhancing the dry strength of paper. The dry strength agent composition includes at least two components. The first component is an amine-containing cationic polymer and the second component may be one or more anionic or amphoteric polymers.Type: GrantFiled: December 30, 2016Date of Patent: July 7, 2020Assignee: ECOLAB USA INC.Inventors: Yulin Zhao, Chunhao Wang, Na Xu, Jun Li, Meng Zhang
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Patent number: 10689809Abstract: The present invention relates to a process for manufacturing a sheet of paper and/or board from a fibrous suspension, according to which, before the formation of said sheet, added to the fibrous suspension, at one or more injection points, are at least two retention aids respectively: (a) at least one water-soluble organic cationic polymer P1 having a cationicity greater than 2 meq·g?1, and (b) at least one water-soluble amphoteric polymer P2 of at least one anionic monomer and of at least one cationic monomer. The polymer P2 is added to the fibrous suspension after dissolving, in aqueous solution, the polymer P2 previously obtained by one of the following polymerization techniques: gel polymerization, suspension polymerization, inverse emulsion polymerization, dispersion polymerization. The polymer P2 has a factor F>2, said factor F being defined by the formula: F=UL2×[(100?A)/(100?C)] with UL: Brookfield viscosity of the polymer P2 at 0.Type: GrantFiled: January 25, 2017Date of Patent: June 23, 2020Assignee: S.P.C.M. SAInventors: Gatien Faucher, Damien Fougerouse, René Hund
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Patent number: 10647802Abstract: An object of the present invention is to provide a polymer compound capable of improving adhesiveness between a hydrophobic member and a hydrophilic member. The polymer compound of the present invention is a polymer compound having a repeating unit represented by Formula (I) and a repeating unit represented by Formula (II).Type: GrantFiled: March 27, 2019Date of Patent: May 12, 2020Assignee: FUJIFILM CorporationInventors: Shunya Katoh, Masaru Yoshikawa, Masaaki Suzuki
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Patent number: 10626558Abstract: A method of producing paper and board by using at least one water-soluble amphoteric polymer is provided. The water-soluble amphoteric polymer is obtained by copolymerizing a monomer mixture containing a) at least one N-vinylcarboxamide, b) at least one monoethylenically unsaturated monomer having at least one free acid group or at least one acid group in salt form, c) optionally at least one monoethylenically unsaturated monomer other than components (a) and (b), and d) optionally at least one compound having two or more ethylenically unsaturated double bonds, and then partly or wholly hydrolyzing the —CO—R1 groups of the polymer. The cationic monomer units and the anionic monomer units differ in their respective molar fractions, each based on the total number of moles of all monomer units, by not more than 10 mol % in absolute terms.Type: GrantFiled: August 4, 2016Date of Patent: April 21, 2020Assignee: SOLENIS TECHNOLOGIES, L.P.Inventors: Anton Esser, Hans-Joachim Haehnle
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Patent number: 10450197Abstract: The present invention relates to a silica sol having a pH above about 10, molar ratio of SiO2:M2O, in which M is alkali metal, of from about 6:1 to about 16:1, concentration of soluble silica above about 3000 mg SiO2/l, and S-value of from about 18 to about 40%.Type: GrantFiled: August 28, 2017Date of Patent: October 22, 2019Assignee: Akzo Nobel Chemicals International B.V.Inventors: Erik Sanne, Freddie Hansson
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Patent number: 10378154Abstract: The present disclosure relates to a method and composition for increasing wet and/or dry strength of a paper product. The method comprises adding a composition comprising at least one polymer having a molecular weight more than 0.5 million Dalton and a degradation agent to a pulp suspension, and forming said paper product.Type: GrantFiled: April 19, 2016Date of Patent: August 13, 2019Assignee: Kemira OyjInventors: Yuping Luo, Jiang Li, Thomas J. Lynch, Jenna Sue Rabideau, Scott Rosencrance
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Patent number: 10351996Abstract: A cellulose based pressboard for insulation in an electrical power transformer, the pressboard includes polyvinylamine (PVAm), and polyacrylamide (PAM), in a combined amount of between 0.01% and 20% by weight of the pressboard.Type: GrantFiled: October 16, 2015Date of Patent: July 16, 2019Assignee: ABB Schweiz AGInventors: Claire Pitois, Elson Montibon, Fredrik Sahlen, Lars Schimdt, Orlando Girlanda, Torbjorn Brattberg, Lars Wagberg
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Patent number: 10329374Abstract: The present invention relates to a process for preparing a thermoplastic copolymer from polycaprolactam and thermoplastic polyurethane (TPU), to thermoplastic copolymers thus obtained and to shaped articles formed from copolymers of this type.Type: GrantFiled: January 30, 2015Date of Patent: June 25, 2019Assignee: BASF SEInventors: Philippe Desbois, Rajan Hollmann, Dirk Kempfert, Bernd Bruchmann, Frank Thielbeer, Rolf Muelhaupt
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Patent number: 10316224Abstract: A composition based on phenolic resin comprising at least one phenolic resin, a vegetable protein hydrolysate, preferentially a wheat gluten hydrolysate, and an agent for accelerating curing, and also to the process for the production thereof.Type: GrantFiled: October 7, 2014Date of Patent: June 11, 2019Assignees: TEREOS STARCH AND SWEETENERS BELGIUM, UNIVERSITE DE LORRAINEInventors: Antonio Pizzi, Marie-Christine Lagel, Andreas Redl
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Patent number: 10113270Abstract: Process for the Manufacture of Paper and Paperboard The present invention relates to a process of making paper or paperboard in which a cellulosic thin stock is provided and subjected to one or more shear stages and then drained and a moving screen to form a sheet which is dried, wherein the process employs a retention system which is applied to the thin stock, said retention system comprising as components i) a blend of different cationic polymers and ii) a microparticulate material, in which the blend of cationic polymers comprises, a) a cationic polymer having a charge density of from 0.Type: GrantFiled: January 9, 2014Date of Patent: October 30, 2018Assignee: BASF SEInventors: Christopher Alan Gray, Antonius Moormann-Schmitz, Hubert Meixner, Luis Miguel Sanchez Cerro, Thomas Muehlenbernd, Christian Jehn-Rendu
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Patent number: 10104866Abstract: Provided are a sheet for pets which contains carbon and has a superior appearance, and a method of manufacturing the sheet for pets. A sheet for pets is provided with a liquid-permeable front surface sheet, a liquid-impermeable back surface sheet, an absorbent layer that contains carbon and is positioned between the front surface sheet and the back surface sheet, and a front surface-side liquid-permeable sheet that is black and is positioned on the front surface sheet-side of the absorbent layer. The front surface-side liquid-permeable sheet is preferably formed from pulp fibers that have been dyed black.Type: GrantFiled: June 18, 2014Date of Patent: October 23, 2018Assignee: UNICHARM CORPORATIONInventors: Satoshi Hasegawa, Yasuhiro Sasano
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Patent number: 10080344Abstract: Provided are: a sheet for pets which contains carbon and has a superior appearance, and a method of manufacturing the sheet for pets. A sheet for pets is provided with a liquid-permeable front surface sheet, a liquid-impermeable back surface sheet, an absorbent layer that contains carbon and organic acid and is positioned between the front surface sheet and the back surface sheet, and a front surface-side liquid-permeable sheet that is black and is positioned on the front surface sheet-side of the absorbent layer. The front surface-side liquid-permeable sheet is preferably formed from pulp fibers that have been dyed black.Type: GrantFiled: August 18, 2014Date of Patent: September 25, 2018Assignee: UNICHARM CORPORATIONInventors: Satoshi Hasegawa, Yasuhiro Sasano
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Patent number: 10005982Abstract: The invention provides methods and compositions for recovering oil from stillage. The method comprises the addition of a surfactant and a microparticle comprising hydrophilic silica to a grain to ethanol stillage. The methods and compositions of the present invention release oil trapped in solid aggregates, increasing the total amount of oil extracted from the stillage.Type: GrantFiled: July 18, 2016Date of Patent: June 26, 2018Assignee: Ecolab USA Inc.Inventors: Lan Xiao, Xiaodong Huang, Xuejun Wang, Philip Eastin, Jason Van't Hul
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Patent number: 10006170Abstract: Disclosed are compositions and methods useful in applications relating to papermaking. The compositions and methods of the present invention comprise aldehyde-functionalized polymers designed to impart high paper strength and enhance water removal during the papermaking process. The aldehyde-functionalized polymers are of relatively low molecular weight, and comprise amino and/or amide groups mono-reacted and di-reacted at a ratio of at least about 1.5 to 1. The low molecular weight polymers of the present invention have the same strength and dewatering performance as corresponding high molecular weight polymers.Type: GrantFiled: August 5, 2016Date of Patent: June 26, 2018Assignee: Ecolab USA Inc.Inventors: Herman Mark Grimm, Mei Liu, Robert M. Lowe
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Patent number: 9982395Abstract: Strengthening resins and methods for making and using same. The strengthening resin can include a polyamine partially cross-linked with a bridging moiety and having azetidinium ions. The bridging moiety can be derived from a functionally symmetric cross-linker. The functionally symmetric cross-linker can include a diisocyanate, a 1,3-dialkyldiazetidine-2,4-dione, a dianhydride, a diacyl halide, a dienone, a dialkyl halide, or any mixture thereof.Type: GrantFiled: May 29, 2015Date of Patent: May 29, 2018Assignee: ECOLAB USA INC.Inventors: Clay E. Ringold, Cornel Hagiopol, Dexter C. Johnson, Brian L. Swift, David R. Snead
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Patent number: 9975781Abstract: The present invention relates to colloidal silicas having a low S-value and a high solids content, the preparation thereof, and the use thereof in the production of paper. When used in the production of paper, the colloidal silicas of the invention exhibit good retention and drainage performance so that they can be used in lower amounts compared to conventional colloidal silicas. The present invention also relates to an apparatus and a method for producing such activated colloidal silicas.Type: GrantFiled: December 17, 2014Date of Patent: May 22, 2018Assignee: Ecolab USA Inc.Inventors: Wen Bai, Jian Xu, Jia Wu, Zhi Chen, Jian Kun Shen, Raymond D. Miller, Jr., Jane B. Wong Shing
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Patent number: 9873986Abstract: A paper-making aid composition comprising dialdehyde-modified polyacrylamide-type strengthening agent, polyacrylamide-type strengthening agent and water and having a pH value of 6 or more is provided. A method of paper-making by using the paper-making aid composition is also provided.Type: GrantFiled: September 12, 2014Date of Patent: January 23, 2018Assignee: Ecolab USA Inc.Inventors: Bo Zhu, Na Xu, Meng Zhang, Yulin Zhao
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Patent number: 9725532Abstract: The present invention relates to a process for the preparation of an aqueous polymer solution containing at least one cationic or amphoteric (co)polymer, comprising the following steps: Hofmann degradation reaction on a (co)polymer based on at least one non-ionic monomer chosen from the group including acrylamide, methacrylamide, N,N-dimethylacrylamide, and acrylonitrile; post-processing of the resulting aqueous polymer solution of viscosity V1; characterized in that the post processing comprises the following successive steps: obtaining of an aqueous polymer solution containing at least one cationic or amphoteric (co)polymer derived from the Hofmann degradation reaction; post-processing of this aqueous polymer solution; characterized in that the post processing comprises the following successive steps: (a) adjustment of the pH of the aqueous polymer solution to a value greater than or equal to 5.5; (b) decrease of the pH of the aqueous polymer solution to a value between 2 and 5.Type: GrantFiled: January 15, 2015Date of Patent: August 8, 2017Assignee: S.P.C.M. SAInventors: René Hund, Christophe Auriant, Laurent Mialon
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Patent number: 9708771Abstract: A method of preparing an aqueous emulsion of a sizing agent for use in a papermaking process comprising, emulsifying the sizing agent into an aqueous liquid, in which an aqueous dispersion of a water-soluble polymer of N-vinylformamide and/or N-vinylacetamide units is added to either the sizing agent or the aqueous liquid before, during or after emulsification, wherein the dispersion contains, based on 100 parts by weight of water, (A) from 0.1 to 80 parts by weight of a water-soluble polymer containing N-vinylformamide units and/or N-vinylacetamide units, and (B) from 0.02 to 50 parts by weight of at least one polymeric dispersant.Type: GrantFiled: February 24, 2014Date of Patent: July 18, 2017Assignee: BASF SEInventors: Ingrid Haufe, Klaus Möller, Attila Kurucz
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Patent number: 9656914Abstract: Rheology modifying agents and methods of modifying the rheology of a slurry are disclosed, in addition to methods for the prevention of fouling. The slurry can be a lime slurry or a magnesium oxide slurry. The rheology modifying agent can be a low molecular weight anionic polymer, a high molecular weight polymer, a mixture of a low molecular weight anionic polymer and a high molecular weight polymer, a mixture of a high molecular weight polymer and a chelating agent, and a mixture of a chelating agent, a high molecular weight polymer, and a low molecular weight anionic polymer.Type: GrantFiled: May 1, 2013Date of Patent: May 23, 2017Assignee: ECOLAB USA INC.Inventors: Jasbir Gill, Tzu Y Chen, Reagan Faith, Adam Coulterman
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Patent number: 9644320Abstract: A cellulose reactive glyoxalated copolymer composition and methods of producing and using the glyoxalated copolymer composition to, for instance, strengthen paper or board are discussed. A glyoxalated copolymer composition includes an aqueous medium containing a glyoxalated copolymer, wherein the glyoxalated copolymer is obtained by reaction in an aqueous reaction medium of a dry weight ratio of glyoxalxationic copolymer. The cationic copolymer can have a weight average molecular weight of about 120,000 to about 1 million Daltons, the cationic copolymer can include diallyldimethylammonium halide monomer and acrylamide monomer, and a ratio a ratio of the weight average molecular weight of the cationic copolymer before glyoxalation to weight % of diallyldimethylammonium halide monomer making up the cationic copolymer before glyoxalation can be equal to or greater than 4,000 or range from 4,000 to 40,000 Daltons/weight %.Type: GrantFiled: September 8, 2014Date of Patent: May 9, 2017Assignee: BASF SEInventor: Matthew D. Wright
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Patent number: 9631319Abstract: The present invention concerns a process of making paper, board or paperboard in which a cellulosic thin stock is provided and subjected to one or more shear stages and then drained on a moving screen to form a sheet which is dried, wherein the process employs a treatment system which is applied to the thin stock, said treatment system comprising as components, a) a cationic organic polymer of charge density of at least 3.0 meq/g with a molar mass Mw of up to 3 million Daltons or poly aluminum chloride (PAC), b) a cationic polymer having an average molar mass Mw of at least 500,000 Daltons and a charge density not exceeding 4.0 meq/g; c) a microparticulate material; in which components (b) and (c) are added to the cellulosic thin stock after the last shear stage before the head box and component (a) is added to the cellulosic thin stock before the said last shear stage.Type: GrantFiled: February 25, 2013Date of Patent: April 25, 2017Assignee: BASF SEInventor: Christopher Alan Gray
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Patent number: 9598820Abstract: Mixtures of polyvinylamines and of liquid compositions of cationic amylaceous materials having very specific characteristics in terms of dry matter, viscosity, nitrogen content and pH. With such mixtures, it is possible to produce preparations that are particularly effective at increasing the dry strength of paper and cardboard. Also, the use of such mixtures for the production of paper and cardboard, the corresponding production method and the resulting paper and cardboard.Type: GrantFiled: July 5, 2013Date of Patent: March 21, 2017Assignee: ROQUETTE FRERESInventor: Regis Houze
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Patent number: 9506200Abstract: Process for manufacturing a sheet of paper and/or of paperboard and the like, according to which, the cellulosic material is brought into contact with at least one dry strength aid, characterized in that said dry strength aid is a cationic or amphoteric (co)polymer derived from the reaction between at least one aldehyde and at least one base (co)polymer comprising at least one nonionic monomer, said base copolymer being modified with at least one polyfunctional compound comprising at least three heteroatoms chosen from N, S, O and P, in which at least three of these heteroatoms each have at least one mobile hydrogen.Type: GrantFiled: February 26, 2013Date of Patent: November 29, 2016Assignee: S.P.C.M. SAInventors: René Hund, Cyril Barriere
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Publication number: 20150144282Abstract: The present invention provides a method for increasing paper strength in papermaking process comprising adding to a pulp a composition comprising an anionic polyacrylamide (APAM) and a high charge cationic glyoxylated polyacrylamide (GPAM). The present invention also provides paper obtained with said method.Type: ApplicationFiled: November 22, 2013Publication date: May 28, 2015Applicant: KEMIRA OYJInventors: Chen Lu, Scott Rosencrance, Danny Nguyen
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Patent number: 9028650Abstract: This technology relates to a method of sizing paper through the use of an aqueous solution of ketene dimer and vinylamine-containing polymers. It also relates to the stability of the ketene dimer/polyvinylamine solution.Type: GrantFiled: December 5, 2013Date of Patent: May 12, 2015Assignee: Solenis Technologies, L.P.Inventors: Susan M. Ehrhardt, Kyle Bottorff
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Publication number: 20150114582Abstract: This invention relates to a sheet comprising fibers and fibrids wherein either comprises a mixture of at least a first polymer and a second polymer; the first polymer derived from the reaction of one or more amine monomers and a plurality of acid monomers, wherein the one or more amine monomers includes at least 60 mole percent 5(6)-amino-2-(p-aminophenyl)benzimidazole, based on the total amount of amine monomers; and the plurality of acid monomers include those having a structure of Cl—CO—Ar1—CO—Cl & Cl—CO—Ar2—CO—Cl wherein Ar1 is an aromatic group having para-oriented linkages and Ar2 is an aromatic group having meta-oriented linkages, and wherein the plurality of acid monomers has at least 50 mole percent of the monomer containing aromatic group Ar2; and the second polymer derived from the reaction of metaphenylene diamine and isophthaloyl chloride.Type: ApplicationFiled: October 29, 2014Publication date: April 30, 2015Inventor: KIU-SEUNG LEE
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Patent number: 9005397Abstract: The invention relates to an aqueous polymer dispersion comprising an anionic water-soluble dispersion polymer comprising in polymerized form a monomer mixture comprising (i) one or more anionic monomers, (ii) a first non-ionic vinyl monomer which is acrylamide, and (iii) at least one second non-ionic vinyl monomer; a water-soluble salt and a stabilizer, wherein the water soluble salt is present in an amount of at least 2.0% by weight, based on the total weight of the dispersion. The invention further relates to a process for producing the aqueous polymer dispersion, use of the aqueous polymer dispersion as a flocculating agent in papermaking or for water purification, and a process for producing paper which comprises adding one or more drainage and retention aids comprising the aqueous polymer dispersion to an aqueous suspension containing cellulosic fibers and then dewatering the obtained suspension.Type: GrantFiled: August 19, 2009Date of Patent: April 14, 2015Assignees: Akzo Nobel N.V., Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung E.V.Inventors: Christian Przybyla, Oliver Struck, André Laschewsky, Bernd-Reiner Paulke
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Patent number: 8999112Abstract: A method for manufacturing a sheet of paper and/or board having improved retention and drainage properties is provided, according to which, before the formation of the sheet and/or board, at least two retention aids are added to the fibrous suspension. These two retention aids are a main retention aid corresponding to a (co)polymer having a cationic charge density above 2 meq/g, obtained by the Hofmann degradation reaction, and a secondary retention aid corresponding to a water-soluble or water-swellable polymer having an anionic charge density above 0.1 meq/g. The main retention aid is introduced into the fibrous suspension in a proportion of 100 to 800 g/t of dry pulp, and the secondary retention aid is introduced into the fibrous suspension in a proportion of 50 to 800 g/t of dry pulp and has an intrinsic viscosity IV above 3 dl/g.Type: GrantFiled: January 30, 2013Date of Patent: April 7, 2015Assignee: S.P.C.M. SAInventors: Gatien Faucher, Rene Hund
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Patent number: 8999110Abstract: Resin systems and methods for making and using same are provided. The method for making a paper product can include contacting a plurality of pulp fibers with a resin system. The resin system can include a first polyamidoamine-epihalohydrin resin and a second resin that can include a second polyamidoamine-epihalohydrin resin, a urea-formaldehyde resin, or a mixture thereof to produce a paper product. The first resin and the second resin can be sequentially or simultaneously contacted with the plurality of pulp fibers. The period for sequential addition between the first resin and the second resin is about 1 second to about 1 hour.Type: GrantFiled: December 17, 2013Date of Patent: April 7, 2015Assignee: Georgia-Pacific Chemicals LLCInventors: Cornel Hagiopol, David F. Townsend, Clay E. Ringold, James W. Johnston, Robert McDonald, Metric M. Simpson, Frederick S. Potter
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Patent number: 8992732Abstract: The invention relates to a process for making paper or paper board comprising forming a cellulosic suspension, flocculating the suspension, draining the suspension on a device to form a sheet and then drying the sheet, wherein the suspension is flocculated using a formation improving 3-component flocculation system comprising a) a linear cationic or ampoteric co-polymer of: i) acrylamide, and ii) a substance with formula (I) with a halide as counter-ion; b) at least one water soluble component chosen from the group of anionic polyacrylamide, non-ionic polyacrylamide and polyethyleneoxide; and c) inorganic microparticles, whereby the flocculation system does not contain a wafer-dispersible or branched anionic organic polymer. The invention also relates to use of the flocculation/retention system in the manufacture of paper or paper board, and to paper and paper board thus produced.Type: GrantFiled: December 17, 2012Date of Patent: March 31, 2015Assignee: Innventia ABInventors: Tom Lindström, Anna Svedberg, Mikael Ankerfors
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Publication number: 20150083355Abstract: A composition comprises (i) an elastomer, (ii) from 1 to 5 volume % of fibrous pulp, the pulp having a specific surface area of from 7 to 11 sq.m./g and the fiber having a fiber length of from 0.5 to 1.1 mm, a tensile modulus of from 2.5 to 130 GPa, and a tensile strength of from 1 to 3 GPa, and (iii) from 5 to 14 volume % of yield-strain promoter in the form of fibers, needles, powder or platelets, wherein the composition has a yield strain of at least 70%, an elongation at break of at least 200%, and a yield stress of at least 4 MPa.Type: ApplicationFiled: September 24, 2013Publication date: March 26, 2015Applicant: E I DU PONT DE NEMOURS AND COMPANYInventor: RAMESHCHANDRA M. GOHIL
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Publication number: 20150083026Abstract: The present invention concerns a process for preparing self-binding pigment particles from an aqueous suspension of a calcium carbonate containing material, wherein an anionic binder and at least one cationic polymer are mixed with the suspension.Type: ApplicationFiled: April 29, 2013Publication date: March 26, 2015Inventors: Daniel Gantenbein, Patrick A.C. Gane, Joachim Schoelkopf, Maximilian Laufmann, Lars Andersson
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Patent number: 8980056Abstract: A dry strength additive composition generally includes an anionic and/or amphoteric polyacrylamide having a molecular weight of less than 1,000,000 Daltons, wherein the amphoteric polyacrylamide has a net negative charge; a cationic and/or amphoteric starch; and a cationic non-starch polymer having a charge density greater than 1 milliequivalent per gram (meq/g) at a pH of 3. The components defining the composition can be added to a pulp suspension sequentially or as a pre-blended mixture.Type: GrantFiled: November 15, 2010Date of Patent: March 17, 2015Assignee: Kemira OyjInventors: Chen Lu, Vladimir Grigoriev, Scott Rosencrance
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Patent number: 8980011Abstract: A method of cleaning residue from a surface includes providing a disposable cellulosic wiper including a percentage by weight of pulp-derived papermaking fibers. The pulp-derived papermaking fibers have a characteristic scattering coefficient of less than 50 m2/kg. The wiper also includes a percentage by weight of fibrillated regenerated independent cellulosic microfibers having a number average diameter of less than about 2 microns, and a characteristic Canadian Standard Freeness (CSF) value of less than 175 ml. The microfibers are selected and present in amounts such that the wiper exhibits a scattering coefficient of greater than 50 m2/kg. The wiper is applied, with a predetermined amount of pressure, to a residue-bearing surface, and the surface is wiped, while applying the predetermined amount of pressure, to remove residue from the surface, such that the surface has less than 1 g/m2 of residue after being wiped under the predetermined amount of pressure.Type: GrantFiled: January 30, 2014Date of Patent: March 17, 2015Assignee: Georgia-Pacific Consumer Products LPInventors: Daniel W. Sumnicht, Joseph H. Miller
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Patent number: 8980055Abstract: A disposable cellulosic wiper includes (a) a percentage by weight of pulp-derived papermaking fibers, and (b) a percentage by weight of fibrillated regenerated independent cellulosic microfibers having a characteristic Canadian Standard Freeness (CSF) value of less than 175 ml and having a weight average diameter of less than 2 microns. The microfibers are further characterized in that 40% by weight thereof is finer than 14 mesh.Type: GrantFiled: January 30, 2014Date of Patent: March 17, 2015Assignee: Georgia-Pacific Consumer Products LPInventors: Daniel W. Sumnicht, Joseph H. Miller