Phenol-aldehyde Patents (Class 162/165)
  • Patent number: 8911593
    Abstract: A novel solvent-free method for the cationization of a legume starch, and uses of the cationic starches thus obtained, in aqueous compositions and the paper industry, including the folding carton or paper thus obtained.
    Type: Grant
    Filed: March 5, 2010
    Date of Patent: December 16, 2014
    Assignee: Roquette Freres
    Inventors: Marika Ladret, Edmond Dobrogoszcz, Hervé Gombert, Philippe Sabre
  • Publication number: 20140202647
    Abstract: Compositions that include hydrophobizing agents and stabilizers and methods for making and using same are provided. In at least one specific embodiment, a composition can include about 40 wt % to about 60 wt % lignosulfonic acid or a salt thereof, about 1 wt % to about 20 wt % of a hydrophobizing agent, and about 20 wt % to about 59 wt % of a liquid medium, where all weight percents are based on the combined weight of the lignosulfonic acid or salt thereof, the hydrophobizing agent, and the liquid medium.
    Type: Application
    Filed: December 19, 2013
    Publication date: July 24, 2014
    Applicant: Georgia-Pacific Chemicals LLC
    Inventors: Cornel Hagiopol, Adam K. Sniady, David F. Townsend, Bobby L. Williamson
  • Patent number: 8660342
    Abstract: A method that includes classifying photographs into categories; generating computational models of image aesthetics, each computational model of image aesthetics associated to one different category of the categories; extracting a plurality of features from a photograph, the plurality of features including simplicity features, global features computed in the whole image and/or low-level features in contrasting regions of an image of the photograph, the contrasting regions being partitions of the image obtained by applying an image segmentation algorithm based on feature contrast to the photograph; and applying a computational model of image aesthetics to at least part of the plurality of features extracted from the photograph, the computational model applied according to the category of the photograph, in order to assess aesthetic quality of the photograph.
    Type: Grant
    Filed: January 24, 2012
    Date of Patent: February 25, 2014
    Assignee: Telefonica, S.A.
    Inventors: Pere Obrador, Michele Saad, Poonam Suryanarayan, Nuria Oliver
  • Patent number: 8568563
    Abstract: Methods of making the burnthrough resistant non-woven mat include forming the mat from glass fibers and at least two binders, a first binder having a vinyl component and a second binder having a strengthening component. The vinyl component may be, for example, ethylene vinyl chloride, and the strengthening component may be, for example, melamine formaldehyde. In one method, the vinyl component is added to the glass fibers by a beater addition process and the strengthening component is sprayed onto the glass fibers. The burnthrough resistant non-woven mat may be used in conjunction with an insulation blanket, and may be especially suited to use in insulating aircraft.
    Type: Grant
    Filed: January 14, 2013
    Date of Patent: October 29, 2013
    Assignee: Jonhs Manville
    Inventor: Glenda Beth Bennett
  • Publication number: 20120216976
    Abstract: This disclosure relates to a resin-impregnated, opaque, cellulose pulp-based sheet comprising an inorganic particle, wherein the inorganic particle comprises at least about 0.002% of tungsten, based on the total weight of the inorganic particle, and has a photostability ratio (PSR) of at least about 2, as measured by the Ag+ photoreduction rate, and color as depicted by an L* of at least about 97.0, and b* of less than about 4. The disclosure also relates to paper laminates prepared from these resin-impregnated, opaque, cellulose pulp-based sheets.
    Type: Application
    Filed: November 9, 2010
    Publication date: August 30, 2012
    Applicant: E.I. Dupont De Nemours and Company
    Inventors: John Davis Bolt, Eugene Michael McCarron, III, Charles David Musick
  • Patent number: 8118974
    Abstract: The invention relates to a structure for producing castings, which comprises an organic fiber, carbon fiber, inorganic particles, and at least one kind of thermosetting resin selected from the group consisting of phenol resin, epoxy resin and furan resin.
    Type: Grant
    Filed: June 10, 2004
    Date of Patent: February 21, 2012
    Assignee: Kao Corporation
    Inventors: Shigeo Nakai, Tokuo Tsuura, Yoshimasa Takagi, Tadashi Kusube, Akira Yoshida, Yoshiaki Ban
  • Patent number: 7928023
    Abstract: A composite sheet material, useful as a component of roofing shingles, and a process of making same, which includes a glass fiber web bound with a thermosetting resin which includes a fatty acid amide having the structural formula RCOONH2, where R is a C8-C25 alkyl.
    Type: Grant
    Filed: July 1, 2005
    Date of Patent: April 19, 2011
    Assignee: Building Materials Investment Corporation
    Inventors: V. Robert Canfield, Robson F. Storey, Betty C. Roberts
  • Publication number: 20110042021
    Abstract: The invention relates to a wood composition containing olefin and raw wood materials, the use of said olefins for rendering raw wood materials water repellent, and a method for producing wood materials therefrom. The raw wood materials contain or are made of lignocellulose and are provided in the form of fibers, strands, or chips.
    Type: Application
    Filed: February 25, 2009
    Publication date: February 24, 2011
    Applicant: SASOL WAX GMBH
    Inventors: Thomas Buchholz, Gernot Meyer, Marc Prüsmann
  • Publication number: 20100300634
    Abstract: The present invention provides a method for producing an MDF board from pulp from a fibrous lignocellulose material using a treatment or pretreatment step which exposes the material to oxalic acid or oxalic acid derivatives (particularly dialkyl ester derivatives, particularly in the vapor phase). The treated wood is then subjected to a sugar extraction wash and refined using any one of the several pulping methods to produce a final pulp product. Once this is done the pulp is used to make MDF boards having improved water repellency properties.
    Type: Application
    Filed: August 11, 2010
    Publication date: December 2, 2010
    Inventors: Masood Akhtar, William R. Kenealy, Eric G. Horn, Ross E. Swaney, Jerrold Winandy
  • Patent number: 7591927
    Abstract: A method for manufacturing a wastepaper shock absorbing material using a vacuum forming principle is provided. The method includes disintegrating wastepaper selected from at least one of old corrugated containers, old newspapers and milk cartons, diluting the disintegrated wastepaper to form a pulp suspension, mixing the pulp suspension with a cationic starch to form a mixture, and vacuuming the mixture by applying a first vacuum in a first direction and a second vacuum in a second direction in a vacuum former to vacuum-dehydrate the mixture and provide a shock absorbing material. The first direction is substantially opposite to the second direction. The method further includes drying the shock absorbing material and performing a surface sizing process on a surface of the shock absorbing material. The wastepaper shock absorbing material has a low elastic modulus and density and can be manufactured without using the conventional press process performed by a press plate.
    Type: Grant
    Filed: December 1, 2006
    Date of Patent: September 22, 2009
    Assignee: Industry-Academic Cooperation Foundation Gyeongsang National University
    Inventors: Chul hwan Kim, Young min Lee, Dae bin Song
  • Publication number: 20080115899
    Abstract: The invention relates to a method for the production of a lignocellulose product from a) at least one material containing lignocellulose, b) a resin-based binding agent and (c) an organic compound comprising at least one first and second functional group. The first functional group is an oxidizable functional group and the second functional group is a group which can react with the binding agent forming a substantially covalent bond. The reactand and reaction conditions of the method are selected in such a way that substantially covalent cross-polymerization occurs between the material containing lignocellulose and the binding agent. The lignocellulose products produced according to the inventive method contain less binding agent and have improved physical-chemical properties.
    Type: Application
    Filed: September 13, 2004
    Publication date: May 22, 2008
    Inventors: Ewald Srebotnik, Thomas Kunginger, Martin Steinwender
  • Patent number: 7323083
    Abstract: Resinous coatings can be applied to glass, exhibiting improved adhesion thereto, by including in the coating composition a sulfonic acid derived compound such as 2-acrylamido-2-methylpropanesulfonic acid or a salt thereof. Alternatively, the glass can be first coated with the sulfonic acid derived compound and thereafter the film-forming resin applied.
    Type: Grant
    Filed: October 28, 2003
    Date of Patent: January 29, 2008
    Assignee: The Lubrizol Corporation
    Inventors: John S. Manka, Todd K. Yonker
  • Patent number: 7282117
    Abstract: Cellulosic fiber composites and finished cellulosic fiber composite articles are provided. The cellulosic fiber composites comprise cellulosic material and a resin binder. The resin binder comprises vegetable protein hydrolysates and a synthetic resin. The synthetic resin can be phenolic resin, isocyanate resin, or combinations thereof. The composite contains an effective amount of resin binder so as to bind together the cellulosic material. The amount of resin binder is less than 40% of the dry weight of the cellulosic material. The protein hydrolysates provide a composite with a reduced amount of petrochemicals. The composite can also contain a silicone, silane, or combination thereof.
    Type: Grant
    Filed: October 31, 2003
    Date of Patent: October 16, 2007
    Assignee: Battelle Memorial Institute
    Inventors: Bhima Rao Vijayendran, Jan Moon
  • Patent number: 7258764
    Abstract: Soft and strong cellulose-based fibrous web, comprises a) cellulosic fibres having a freeness value of more than 26° SR measured according to DIN-ISO 5267/1 (March 1999), b) a water-soluble cationic polymer, c) a water-soluble anionic polymer, and d) a cationic surfactant-based softener. The webs are prepared by refining cellulosic fibres to a degree of freeness of more than 26° SR measured according to DIN-ISO 5267/1, adding at least one water-soluble anionic polymer and water-soluble cationic polymer to the refined cellulosic fibres, adding a cationic surfactant-based softener to the cellulosic fibres obtained thereby, and wet-laying and dewatering the celulosic fibres obtained thereby.
    Type: Grant
    Filed: December 17, 2003
    Date of Patent: August 21, 2007
    Assignee: SCA Hygiene Products GmbH
    Inventor: Dirk Mauler
  • Patent number: 7074301
    Abstract: The present invention relates to cross-linked cellulosic fiber having improved absorbency characteristics when compared to conventional cross-linked fibers. The cross-linked cellulosic fiber is obtainable by reacting pulp in the sheet or fluff form with one or more reagents selected from organic molecule having acid and aldehyde functional groups “acid aldehydes.” The invention also relates to a method of producing the cross-linked fiber. The method includes heating the treated cellulosic fibers to promote intrafiber cross-linking. The cross-linked fibers are characterized by having an improved centrifuge retention capacity, fluid acquisition rate, resiliency, absorbent capacity, absorbency under load, and other absorbent properties. The inventive cross-linked fibers are useful in forming absorbent composites, and in particular absorbent cores for use in absorbent articles.
    Type: Grant
    Filed: June 11, 2002
    Date of Patent: July 11, 2006
    Assignee: Rayonier Products and Financial Services Company
    Inventors: Othman A. Hamed, Harry J. Chmielewski, Dana B. McBee
  • Patent number: 7008508
    Abstract: For use as a wet strength agent, a water-soluble blocked urethane prepolymer having a hydrophilic group and a blocked isocyanate group is combined with a cationic charge-adjusting agent. The adsorption and retention of the water-soluble blocked urethane prepolymer to cellulosic fiber are promoted by virtue of the cationic charge adjusting agent when the wet strength agent is added to a paper-making stock.
    Type: Grant
    Filed: July 18, 2002
    Date of Patent: March 7, 2006
    Assignee: Dai Ichi Kogyo Seiyaku Co.
    Inventors: Takeshi Doi, Takeshi Miyamura, Masahiro Kouchi
  • Patent number: 6846384
    Abstract: A process for sizing paper comprising adding to an aqueous suspension containing cellulosic fibers, and optional fillers, an anionic or cationic sizing dispersion, and a sizing promoter comprising a cationic organic polymer having an aromatic group; and an anionic polymer having an aromatic group selected from step-growth polymers, polysaccharides and naturally occurring aromatic polymers, wherein the sizing dispersion and sizing promoter are added separately to the aqueous suspension.
    Type: Grant
    Filed: August 6, 2001
    Date of Patent: January 25, 2005
    Assignee: Akzo Nobel N.V.
    Inventors: Erik Lindgren, Sten Frölich, Michael Persson
  • Publication number: 20040256068
    Abstract: A composite sheet material, useful as a component of roofing shingles, and a process of making same, which includes a glass fiber web bound with a thermosetting resin which includes a fatty acid amide having the structural formula RCOONH2, where R is a C8-C25 alkyl.
    Type: Application
    Filed: June 17, 2003
    Publication date: December 23, 2004
    Applicant: BUILDING MATERIALS INVESTMENT CORPORATION
    Inventors: V. Robert Canfield, Robson F. Storey, Betty C. Roberts
  • Patent number: 6811653
    Abstract: A multi-purpose paper, a manufacturing method thereof, and an application thereof are provided. The method of manufacturing the multi-purpose paper comprises steps of (a) providing a papermaking material and obtaining a clean paper pulp by treating the papermaking material, (b) adding at least one functional additive into the clean paper pulp to form the multi-purpose paper, and (c) processing the multi-purpose paper to form thereon an uneven surface structure. The cultivating paper has the combined functions of weed control, pest control, supplying the required nutrients to plants to help develop the root system, maintaining moisture and breath for the root system. The multi-purpose paper can be carriers of agricultural antagonistic microorganisms and serve as the basic functional substrate for weed control, pest control, sowing, growing seedlings, fertilization, fertilizer saving, manpower saving and organic cultivating.
    Type: Grant
    Filed: October 26, 2001
    Date of Patent: November 2, 2004
    Assignee: Yuen Foong Yu Paper MFG Co., Ltd.
    Inventor: Ching-Chung Huang
  • Publication number: 20040144510
    Abstract: Soft and strong cellulose-based fibrous web, comprises
    Type: Application
    Filed: December 17, 2003
    Publication date: July 29, 2004
    Inventor: Dirk Mauler
  • Publication number: 20040099390
    Abstract: A paper product is described that includes a paper substrate having a first surface and a second surface; a coating layer provided on the first surface of the paper substrate, the coating layer comprising a binder component and a pigment component, wherein the weight ratio the binder component to the pigment component is between about 0.25:1 to about 1:1; and wherein the paper product exhibits a gloss of at least about 20 to 75 according to TAPPI T480 om-92, a Print-surf roughness of at least about 0.5 to 2.5 according to TAPPI T555 pm-94, and a density of at least about 12 to 18 according to TAPPI T410 om-93 and TAPPI T411 om-89. A method for manufacturing a paper product is provided.
    Type: Application
    Filed: November 25, 2002
    Publication date: May 27, 2004
    Inventors: Thomas R. Trochlil, John A. Theisen, Bruce C. Unruh, John E. Katchko
  • Patent number: 6719881
    Abstract: A microparticle system for use as a retention and drainage aid in the production of alkaline and acid paper products comprises a HMW flocculent polymer (6), an acid colloid (7), and a coagulant or a MMW flooculant (5). The acid colloid (7) comprises an aqueous solution of a water soluble polymer or copolymer of melamine aldehyde, preferably melamine formaldehyde, and is present in an amount ranging between 0.0005% to 0.5% by weight based on the dry weight of the solids in the furnish. The HMW flocculant polymer (6) may be added to stock or furnish after the fan pump; and prior to the pressure screen (2); the acid colloid (7) may be added to the stock after the pressure screen (2), and the coagulant/MMW flocculant (5) may be added prior to the fan pump (1). Alternatively, this sequence of chemical additions can be changed, i.e. the acid colloid (7) can be added prior to or after the fan pump (1) or prior to the pressure screen (2).
    Type: Grant
    Filed: July 5, 2001
    Date of Patent: April 13, 2004
    Inventors: Charles R. Hunter, Craig W. Vaughan
  • Patent number: 6719882
    Abstract: Cellulosic fiber composites and methods for preparing cellulosic fiber composites are provided. The cellulosic fiber composites comprise cellulosic material and a resin binder. The resin binder comprises protein hydrolysates and a synthetic resin. The synthetic resin can be phenolic resin, isocyanate resin, or combinations thereof. The protein hydrolysates provide a composite with a reduced amount of petrochemicals. The composite contains an amount of resin binder sufficient to bind the cellulosic material. The composite can also contain a silicone, silane, or combination thereof. The method employs a low moisture-content mat that does not require drying prior to pressing. Additional methods can be employed to produce finished cellulosic fiber composite articles.
    Type: Grant
    Filed: February 8, 2001
    Date of Patent: April 13, 2004
    Assignee: Battelle Memorial Institute
    Inventors: Bhima Rao Vijayendran, Jan Moon
  • Patent number: 6716314
    Abstract: A method for forming an abrasion resistant sheet which comprises forming a web of cellulosic fibers on a papermaking machine and applying a slurry including an encapsulated abrasion-resistant grit to the upper surface of the web on the papermaking machine.
    Type: Grant
    Filed: February 27, 2001
    Date of Patent: April 6, 2004
    Assignee: MeadWestvaco Corporation
    Inventors: Mark A. Johnson, John Benson, Mahendra Mehta, Steve Canary, Eric Girardin
  • Patent number: 6699360
    Abstract: A process for the manufacture of single-ply, absorbent paper product, printed on before or after embossing on the Yankee side, air side, or both sides, having a serpentine configuration; low sidedness; a basis weight of at least about 12.5 lbs. per 3000 square foot ream; a specific total tensile strength between 40 and 200 g/3 inches/lb per 3000 square foot ream; a cross direction specific wet tensile strength between 2.75 and 20.0 g/3 inches/lb per 3000 square foot ream; an MD tensile to CD tensile ratio between 1.25 and 2.75; a specific geometric mean tensile stiffness between 0.5 and 3.2 g/inch/% strain per pound per 3000 square foot ream; a friction deviation of less than 0.250; a sidedness parameter of less than 0.30; and a printed sidedness value of &Dgr;E of less than 2.
    Type: Grant
    Filed: October 3, 2002
    Date of Patent: March 2, 2004
    Assignee: Fort James Corporation
    Inventors: Michael S. Heath, T. Philips Oriaran, Mark S. Siegel, Frank D. Harper, John H. Dwiggins
  • Publication number: 20040011486
    Abstract: A process for forming an abrasion resistant, decorative sheet which comprises forming a web of cellulosic fibers on a papermaking machine and applying a coating suspension including an abrasion-resistant grit and decorative inclusion particles to the upper surface of the web on the papermaking machine.
    Type: Application
    Filed: July 17, 2002
    Publication date: January 22, 2004
    Inventors: Eric Wagner, Dennis Hankey
  • Publication number: 20030205346
    Abstract: A high performance purified natural zeolite pigment composition for use in papermaking and paper coating is disclosed. Use of the pigment facilitates manufacture of coated ink jet and digital printing papers with improved quality and economics. The novel zeolite pigment composition can also be used as a supplementary pigment to improve the properties of coated paper and paperboard for flexographic and water-based gravure printing. When used as filler, the novel zeolite pigment composition is readily retained and eliminates print-through in uncoated papers. The novel zeolite pigment is low in abrasion and provides improved coefficient of friction. The novel zeolite pigment is also useful as a microparticulate retention aid in papermaking and as an additive to improve the performance of deinking processes.
    Type: Application
    Filed: June 4, 2003
    Publication date: November 6, 2003
    Inventors: Charles P. Klass, Margaret K. Joyce
  • Publication number: 20030139517
    Abstract: The present invention refers to a process for the production of paper from a suspension containing cellulosic fibers, and optionally fillers, comprising adding to the suspension at least one cationic organic polymer and an aqueous silica-containing composition comprising an anionic naphthalene sulphonate formaldehyde condensate and anionic silica-based particles, the composition having a weight ratio of naphthalene sulphonate formaldehyde condensate to silica-based particles within the range of from 0.2:1 to 99:1, and containing naphthalene sulphonate formaldehyde condensate and silica-based particles in an amount of at least 0.01% by weight, based on the total weight of the aqueous silica-containing composition, and with the proviso that the composition contains substantially no cellulose-reactive sizing agent. The invention also encompasses an aqueous silica-containing composition and a method for preparation of an aqueous silica-containing compound.
    Type: Application
    Filed: December 20, 2002
    Publication date: July 24, 2003
    Inventors: Johan Nyander, Hans Johansson-Vestin, Jan Nordin, Annika Viola Pal
  • Publication number: 20030079846
    Abstract: A multi-purpose paper, a manufacturing method thereof, and an application thereof are provided. The method of manufacturing the multi-purpose paper comprises steps of (a) providing a papermaking material and obtaining a clean paper pulp by treating the papermaking material, (b) adding at least one functional additive into the clean paper pulp to form the multi-purpose paper, and (c) processing the multi-purpose paper to form thereon an uneven surface structure. The cultivating paper has the combined functions of weed control, pest control, supplying the required nutrients to plants to help develop the root system, maintaining moisture and breath for the root system. The multi-purpose paper can be carriers of agricultural antagonistic microorganisms and serve as the basic functional substrate for weed control, pest control, sowing, growing seedlings, fertilization, fertilizer saving, manpower saving and organic cultivating.
    Type: Application
    Filed: October 26, 2001
    Publication date: May 1, 2003
    Applicant: Yuen Foong Yu Paper MFG Co., LTD
    Inventor: Ching-Chung Huang
  • Publication number: 20030075291
    Abstract: A method for the production of insulation plates from an aqueous pulp comprised of mineral fillers, cellulose-containing products and a binding agent based on a novolak wherein a pulp is used comprising an additive substance selected from the group consisting of fatty acid amides or substituted fatty acid amides, the plates obtained after curing are used, inter alia, as mold covering plates or as so-called tundish plates for application in continuous casting processes.
    Type: Application
    Filed: August 29, 2002
    Publication date: April 24, 2003
    Inventor: Josef Suren
  • Patent number: 6540874
    Abstract: The present invention herein relates to an asphalt-grade carbon fiber paper comprised primarily of asphalt-grade carbon fibers and paper base material, and its process, where the paper base material may be made of cellulose fibers or synthetic fibers and resin, while the asphalt-grade carbon fiber: paper base material=10˜50:50˜90% (by weight). The asphalt-grade carbon fibers, with their conductive, antistatic and shielding actions, are incorporated into the paper base material and give it conductive and statics elimination effect. Furthermore, the paper may be processed into products with electrical and thermal conductivity or for packaging. The aforesaid asphalt-grade carbon fiber paper features excellent conductivity, high thermal conversion ratio, long service life and low cost. Its process is also extremely simple and easy to operate.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: April 1, 2003
    Inventor: Ruey Ling-Chen
  • Patent number: 6517674
    Abstract: Abrasion resistant papers such as overlays or decor sheets useful in decorative laminates, and in particular, to abrasion resistant papers incorporating spacer or separator particles to minimize the amount of damage to highly polished caul plates caused by contact of the caul plates with abrasion resistant materials during the lamination process and a process for manufacturing such abrasion resistant papers.
    Type: Grant
    Filed: May 12, 2000
    Date of Patent: February 11, 2003
    Assignee: The Mead Corporation
    Inventor: Amit Das
  • Patent number: 6503370
    Abstract: Method of producing paper having a three-dimensional pattern of alternating raised and recessed portions which is given the paper in connection with impulse drying, at which the wet paper web is passed through at least one press nip (12) comprising a rotatable roll (13) which is heated and that the paper web when passing through the press nip is given a three-dimensional pattern either by means of a pattern wire (11) and/or by the fact that the heated roll (13) is provided with a three-dimensional pattern, and where the wet paper web (10) before entering said press nip (12) is given a basis weight variation in a non-random pattern.
    Type: Grant
    Filed: April 2, 2001
    Date of Patent: January 7, 2003
    Assignee: SCA Hygiene Products AB
    Inventors: Holger Hollmark, Lennart Reiner, Thomas Billgren, Kaveh Tondkar, Mats Söderberg, Bengt Järrehult
  • Patent number: 6500303
    Abstract: Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a hindered amine compound which preferably is a nitroxide, a hydroxylamine or an ammonium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents, metal chelating agents, sulfur containing stabilizers, metal salts and diene compounds. Combinations of nitroxides, hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. Selected derivatives of 1-oxyl-2,2,6,6-tetramethyl-piperidin-4-ol and selected hydroxylamine salts are novel compounds and are surprisingly effective for this purpose.
    Type: Grant
    Filed: May 18, 2000
    Date of Patent: December 31, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Raymond R. Seltzer, Jean-Pierre Wolf, Cyril Heitner, John A. Schmidt, Peter F. McGarry, Glen T. Cunkle, Randall B. Nelson
  • Patent number: 6488813
    Abstract: Paper with increased wet strength is produced by adding to the stock a water soluble blocked urethane prepolymer having a plurality of blocked isocyanate groups and hydrophilic groups. The blocking agent is a phenol compound having an electron-attracting group at the ortho- or para-position. The blocked urethane prepolymer is capable of unblocking under such conditions that encounter in the drying part of conventional paper making machines.
    Type: Grant
    Filed: July 31, 2001
    Date of Patent: December 3, 2002
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Takeshi Doi, Naofumi Saiuchi, Masahiro Kouchi
  • Patent number: 6447644
    Abstract: Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a hindered amine compound which preferably is a nitroxide, a hydroxylamine or an ammonium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents, metal chelating agents, sulfur containing stabilizers, metal salts and diene compounds. Combinations of nitroxides, hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. Selected derivatives of 1-oxyl-2,2,6,6-tetramethylpiperidin-4-ol and selected hydroxylamine salts are novel compounds and are surprisingly effective for this purpose.
    Type: Grant
    Filed: October 10, 2001
    Date of Patent: September 10, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Raymond R. Seltzer, Jean-Pierre Wolf, Cyril Heitner, John A. Schmidt, Peter F. McGarry, Glen T. Cunkle, Randall B. Nelson
  • Publication number: 20020117281
    Abstract: A method for forming an abrasion resistant sheet which comprises forming a web of cellulosic fibers on a papermaking machine and applying a slurry including an encapsulated abrasion-resistant grit to the upper surface of the web on the papermaking machine.
    Type: Application
    Filed: February 27, 2001
    Publication date: August 29, 2002
    Inventors: Mark A. Johnson, John Benson, Mahendra Mehta, Steve Canary, Eric Girardin
  • Patent number: 6432271
    Abstract: This invention is directed to a method of increasing retention and drainage in a papermaking furnish comprising adding to the furnish an effective flocculating amount of a high molecular weight water-soluble anionic or nonionic dispersion polymer.
    Type: Grant
    Filed: October 15, 2001
    Date of Patent: August 13, 2002
    Assignee: Nalco Chemical Company
    Inventors: Jane B. Wong Shing, Chidambaram Maltesh, John R. Hurlock
  • Publication number: 20020098317
    Abstract: The present invention relates to a cellulose-containing fibrous material, wherein hydroxy groups were oxidized at the C(6) of glucose units of the cellulose into aldehyde and/or carboxy groups, a paper or nonwoven (product) made therefrom, in particular tissue (products) a process for their manufacture. The paper or nonwoven (products) of the invention display excellent strength properties.
    Type: Application
    Filed: August 16, 2001
    Publication date: July 25, 2002
    Inventors: Thomas Jaschinski, Susanna Gunnars, Arie Cornelis Besemer, Petter Bragd, Jan Matthijs Jetten, Ronald Van Den Dool, Willem Van Hartingsveldt
  • Publication number: 20020088583
    Abstract: Paper with increased wet strength is produced by adding to the stock a water soluble blocked urethane prepolymer having a plurality of blocked isocyanate groups and hydrophilic groups. The blocking agent is a phenol compound having an electron-attracting group at the ortho- or para-position. The blocked urethane prepolymer is capable of unblocking under such conditions that encounter in the drying part of conventional paper making machines.
    Type: Application
    Filed: July 31, 2001
    Publication date: July 11, 2002
    Applicant: Dai-ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Takeshi Doi, Naofumi Saiuchi, Masahiro Kouchi
  • Publication number: 20020060012
    Abstract: The disclosure is directed to a method of using melamine resin fibers, to an insulating material comprising
    Type: Application
    Filed: December 4, 2001
    Publication date: May 23, 2002
    Inventors: Heinz Berbner, Karl Ott
  • Patent number: 6372087
    Abstract: Single-ply absorbent tissue paper wherein of the fibers incorporated in the web: (a) at least 20% by weight have a coarseness exceeding 23 mg/100 m; (b) at least about 20% by weight have a coarseness of less than about 12 mg/100 m; and (c) the weight average fiber coarseness to length ratio is less than about 8.5 mg/100 m/mm. The single-ply tissue having: a serpentine configuration; low sidedness; a basis weight of at least about 12.5 lbs. per 3000 square foot ream; specific total tensile strength between 40 and 200 g/3 inches/lb per 3000 square foot ream; a cross direction specific wet tensile strength between 2.75 and 20.0 g/3 inches/lb per 3000 square foot ream; an MD tensile to CD tensile ratio between 1.25 and 2.75; a specific geometric mean tensile stiffness between 0.5 and 3.2 g/inch/% strain per pound per 3000 square foot ream; a friction deviation less than 0.250; and a sidedness parameter less than 0.30.
    Type: Grant
    Filed: June 18, 2001
    Date of Patent: April 16, 2002
    Assignee: Fort James Corporation
    Inventors: Frank David Harper, Taiye Philips Oriaran, John Dennis Litvay
  • Patent number: 6334931
    Abstract: The present invention relates to a soft, thick, single-ply tissue having a serpentine configuration and to a process for the manufacture of such tissue product having a basis weight of at least about 15 lbs. per 3000 square foot ream and having low sidedness, said tissue exhibiting: a specific total tensile strength of between 40 and 200 grams per 3 inches per pound per 3000 square foot ream, a cross direction specific wet tensile strength of between 2.75 and 20.0 grams per 3 inches per pound per 3000 square foot ream, the ratio of MD tensile to CD tensile of between 1.25 and 2.75, a specific geometric mean tensile stiffness of between 0.5 and 3.2 grams per inch per percent strain per pound per 3000 square foot ream, a friction deviation of less than 0.250, and a sidedness parameter of less than 0.30.
    Type: Grant
    Filed: December 11, 1997
    Date of Patent: January 1, 2002
    Assignee: Georgia-Pacific Corporation
    Inventors: John H. Dwiggins, Ranga Ramesh, Frank D. Harper, Anthony O. Awofeso, T. Philips Oriaran, Galyn A. Schulz, Dinesh M. Bhat
  • Patent number: 6331358
    Abstract: A wet friction material is mainly composed of a fiber base material, a filler, an friction adjusting agent and a thermosetting resin. The wet frictional material is prepared by impregnating with a liquid thermosetting resin a paper formed by mixing a paper-forming solid thermosetting resin with a fiber base material as at least a part of filler, and then applying heat to the paper so that it is hardened. The solid thermosetting resin is preferably a phenol resin. The liquid thermosetting resin is preferably made of a silicone resin represented by the following average composition formula and the amount of trifunctional unit monomers (RSiO3/2 in which R represents a substituted or unsubstituted monovalent hydrocarbon group) in monomers constituting said silicone resin is from 40 to 100 mol-%: (R1)a(OR2)bSiO(4−a−b)/2.
    Type: Grant
    Filed: March 3, 1999
    Date of Patent: December 18, 2001
    Assignee: NSK-Warner Kabushiki Kaisha
    Inventors: Shun Kitahara, Fumimasa Muramatsu, Shigeki Umezawa
  • Patent number: 6306256
    Abstract: A method and an agent for improving the retention when dewatering a cellulosic fiber suspension are disclosed In the method, there is added to the suspension a retention agent containing a phenol-formaldehyde resin and a polyethylene oxide, and the method is characterised in that a modified phenol-formaldehyde resin containing cationic groups is added to the suspension. The modified phenol-formaldehyde resin preferably has a cationicity of about 5-85% and the cationic groups preferably consist of amine groups. The polyethylene oxide in the retention agent preferably has a molecular weight of about 0.5-20×106. The modified phenol-formaldehyde resin and the polyethylene oxide are preferably added to the suspension in a weight ratio of modified phenol-formaldehyde resin:polyethylene oxide of from 1:5 to 50:1, and the amount of polyethylene oxide added preferably is about 10-1000 ppm, based on tie dry solids content of the suspension.
    Type: Grant
    Filed: January 4, 2000
    Date of Patent: October 23, 2001
    Assignee: Kemira Kemi AB
    Inventors: Bo Rosengren, Ulla Gytel
  • Publication number: 20010030031
    Abstract: From about 50 to about 90% by weight of fibers, in particular wood fibers, and/or pellets made from cellulose or from wood, are mixed with from about 10 to about 50% by weight of a hot-curing resin, each of the percentages by weight being based on the total weight of the mixture. Instead of a single resin it is also possible to use a mixture made from two or more hot-curing resins. The mixture made from fibers and/or pellets and resin is kneaded and homogenized and then passed on to an extruder which has various heating zones in which the mixture is heated. Care has to be taken here that the maximum temperature, arising at the extruder exit, does not exceed about 120° C., since above this temperature the resin(s) begin(s) to cure.
    Type: Application
    Filed: February 20, 2001
    Publication date: October 18, 2001
    Applicant: TRESPA INTERNATIONAL B.V.
    Inventor: Remco Cornelis Willemse
  • Patent number: 6303002
    Abstract: Paper, board and cardboard are produced from paper stocks which contain tacky impurities by the addition of surfactants and cationic polymers having a charge density of at least 1.5 meq/g (measured at pH 7) and a molar mass Mw of the cationic polymers of at least 15,000 and drainage of the paper stocks with fixation of the tacky impurities in the paper produced.
    Type: Grant
    Filed: October 15, 1999
    Date of Patent: October 16, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Friedrich Linhart, Jaroslav Melzer, Hubert Meixner
  • Patent number: 6280570
    Abstract: The present invention relates to a process of making a soft, thick, single-ply, absorbent paper in the form of a bathroom tissue, facial tissue, or napkin wherein the cellulosic fibers incorporated in the furnish comprise: (a) at least 20 percent by weight of the fibers in the web have a coarseness exceeding 23 mg/100 m; (b) at least about 20 percent by weight of the fibers in the web have a coarseness of less than about 1.2 mg/100 m; and (c) the weight average coarseness to length ratio of the fibers in the web is less than about 8.5 mg/100 m/mm having a serpentine configuration and to a process for the manufacture of such absorbent paper having a basis weight of about 15 lbs. per 3000 square foot ream and having low sidedness, said tissue exhibiting: a specific total tensile strength of between 40 and 200 grams per 3 inches per pound per 3000 square foot ream, a cross direction specific wet tensile strength of between 2.75 and 20.
    Type: Grant
    Filed: September 29, 2000
    Date of Patent: August 28, 2001
    Assignee: Fort James Corporation
    Inventors: Frank David Harper, Taiye Philips Oriaran, John Dennis Litvay
  • Patent number: 6261414
    Abstract: The present invention relates to a method of producing a laminate base material useful for preparing a prepreg or a laminate for electronic equipment such as printed board. The method comprises the steps of: (1) preparing a slurry comprising para-aramid fibers and curable phenolic resin fibers; (2) preparing a sheet from said slurry; (3) adding a resin binder to said sheet so as to bond the fibers with each other, thereby to form a combined non-woven fabric and (4) compressing said non-woven fabric under heating. According to the present invention, a prepreg or laminate is obtained which has an improved high-frequency characteristics and much less warp.
    Type: Grant
    Filed: November 4, 1998
    Date of Patent: July 17, 2001
    Assignee: OJI Paper Co., Ltd.
    Inventors: Yoshihisa Kato, Takekazu Adachi, Mamoru Murata
  • Patent number: 6254724
    Abstract: Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a hindered amine compound which preferably is a nitroxide, a hydroxylamine or an ammonium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents, metal chelating agents, sulfur containing stabilizers, metal salts and diene compounds. Combinations of nitroxides, hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. Selected derivatives of 1-oxyl-2,2,6,6-tetramethyl-piperidin-4-ol and selected hydroxylamine salts are novel compounds and are surprisingly effective for this purpose.
    Type: Grant
    Filed: July 20, 1998
    Date of Patent: July 3, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Raymond R. Seltzer, Jean-Pierre Wolf, Cyril Heitner, John A. Schmidt, Peter F. McGarry, Glen T. Cunkle, Randall B. Nelson