Phenol-aldehyde Patents (Class 162/165)
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Patent number: 8911593Abstract: A novel solvent-free method for the cationization of a legume starch, and uses of the cationic starches thus obtained, in aqueous compositions and the paper industry, including the folding carton or paper thus obtained.Type: GrantFiled: March 5, 2010Date of Patent: December 16, 2014Assignee: Roquette FreresInventors: Marika Ladret, Edmond Dobrogoszcz, Hervé Gombert, Philippe Sabre
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Publication number: 20140202647Abstract: Compositions that include hydrophobizing agents and stabilizers and methods for making and using same are provided. In at least one specific embodiment, a composition can include about 40 wt % to about 60 wt % lignosulfonic acid or a salt thereof, about 1 wt % to about 20 wt % of a hydrophobizing agent, and about 20 wt % to about 59 wt % of a liquid medium, where all weight percents are based on the combined weight of the lignosulfonic acid or salt thereof, the hydrophobizing agent, and the liquid medium.Type: ApplicationFiled: December 19, 2013Publication date: July 24, 2014Applicant: Georgia-Pacific Chemicals LLCInventors: Cornel Hagiopol, Adam K. Sniady, David F. Townsend, Bobby L. Williamson
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Patent number: 8660342Abstract: A method that includes classifying photographs into categories; generating computational models of image aesthetics, each computational model of image aesthetics associated to one different category of the categories; extracting a plurality of features from a photograph, the plurality of features including simplicity features, global features computed in the whole image and/or low-level features in contrasting regions of an image of the photograph, the contrasting regions being partitions of the image obtained by applying an image segmentation algorithm based on feature contrast to the photograph; and applying a computational model of image aesthetics to at least part of the plurality of features extracted from the photograph, the computational model applied according to the category of the photograph, in order to assess aesthetic quality of the photograph.Type: GrantFiled: January 24, 2012Date of Patent: February 25, 2014Assignee: Telefonica, S.A.Inventors: Pere Obrador, Michele Saad, Poonam Suryanarayan, Nuria Oliver
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Patent number: 8568563Abstract: Methods of making the burnthrough resistant non-woven mat include forming the mat from glass fibers and at least two binders, a first binder having a vinyl component and a second binder having a strengthening component. The vinyl component may be, for example, ethylene vinyl chloride, and the strengthening component may be, for example, melamine formaldehyde. In one method, the vinyl component is added to the glass fibers by a beater addition process and the strengthening component is sprayed onto the glass fibers. The burnthrough resistant non-woven mat may be used in conjunction with an insulation blanket, and may be especially suited to use in insulating aircraft.Type: GrantFiled: January 14, 2013Date of Patent: October 29, 2013Assignee: Jonhs ManvilleInventor: Glenda Beth Bennett
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Publication number: 20120216976Abstract: This disclosure relates to a resin-impregnated, opaque, cellulose pulp-based sheet comprising an inorganic particle, wherein the inorganic particle comprises at least about 0.002% of tungsten, based on the total weight of the inorganic particle, and has a photostability ratio (PSR) of at least about 2, as measured by the Ag+ photoreduction rate, and color as depicted by an L* of at least about 97.0, and b* of less than about 4. The disclosure also relates to paper laminates prepared from these resin-impregnated, opaque, cellulose pulp-based sheets.Type: ApplicationFiled: November 9, 2010Publication date: August 30, 2012Applicant: E.I. Dupont De Nemours and CompanyInventors: John Davis Bolt, Eugene Michael McCarron, III, Charles David Musick
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Patent number: 8118974Abstract: The invention relates to a structure for producing castings, which comprises an organic fiber, carbon fiber, inorganic particles, and at least one kind of thermosetting resin selected from the group consisting of phenol resin, epoxy resin and furan resin.Type: GrantFiled: June 10, 2004Date of Patent: February 21, 2012Assignee: Kao CorporationInventors: Shigeo Nakai, Tokuo Tsuura, Yoshimasa Takagi, Tadashi Kusube, Akira Yoshida, Yoshiaki Ban
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Patent number: 7928023Abstract: A composite sheet material, useful as a component of roofing shingles, and a process of making same, which includes a glass fiber web bound with a thermosetting resin which includes a fatty acid amide having the structural formula RCOONH2, where R is a C8-C25 alkyl.Type: GrantFiled: July 1, 2005Date of Patent: April 19, 2011Assignee: Building Materials Investment CorporationInventors: V. Robert Canfield, Robson F. Storey, Betty C. Roberts
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Publication number: 20110042021Abstract: The invention relates to a wood composition containing olefin and raw wood materials, the use of said olefins for rendering raw wood materials water repellent, and a method for producing wood materials therefrom. The raw wood materials contain or are made of lignocellulose and are provided in the form of fibers, strands, or chips.Type: ApplicationFiled: February 25, 2009Publication date: February 24, 2011Applicant: SASOL WAX GMBHInventors: Thomas Buchholz, Gernot Meyer, Marc Prüsmann
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Publication number: 20100300634Abstract: The present invention provides a method for producing an MDF board from pulp from a fibrous lignocellulose material using a treatment or pretreatment step which exposes the material to oxalic acid or oxalic acid derivatives (particularly dialkyl ester derivatives, particularly in the vapor phase). The treated wood is then subjected to a sugar extraction wash and refined using any one of the several pulping methods to produce a final pulp product. Once this is done the pulp is used to make MDF boards having improved water repellency properties.Type: ApplicationFiled: August 11, 2010Publication date: December 2, 2010Inventors: Masood Akhtar, William R. Kenealy, Eric G. Horn, Ross E. Swaney, Jerrold Winandy
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Patent number: 7591927Abstract: A method for manufacturing a wastepaper shock absorbing material using a vacuum forming principle is provided. The method includes disintegrating wastepaper selected from at least one of old corrugated containers, old newspapers and milk cartons, diluting the disintegrated wastepaper to form a pulp suspension, mixing the pulp suspension with a cationic starch to form a mixture, and vacuuming the mixture by applying a first vacuum in a first direction and a second vacuum in a second direction in a vacuum former to vacuum-dehydrate the mixture and provide a shock absorbing material. The first direction is substantially opposite to the second direction. The method further includes drying the shock absorbing material and performing a surface sizing process on a surface of the shock absorbing material. The wastepaper shock absorbing material has a low elastic modulus and density and can be manufactured without using the conventional press process performed by a press plate.Type: GrantFiled: December 1, 2006Date of Patent: September 22, 2009Assignee: Industry-Academic Cooperation Foundation Gyeongsang National UniversityInventors: Chul hwan Kim, Young min Lee, Dae bin Song
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Publication number: 20080115899Abstract: The invention relates to a method for the production of a lignocellulose product from a) at least one material containing lignocellulose, b) a resin-based binding agent and (c) an organic compound comprising at least one first and second functional group. The first functional group is an oxidizable functional group and the second functional group is a group which can react with the binding agent forming a substantially covalent bond. The reactand and reaction conditions of the method are selected in such a way that substantially covalent cross-polymerization occurs between the material containing lignocellulose and the binding agent. The lignocellulose products produced according to the inventive method contain less binding agent and have improved physical-chemical properties.Type: ApplicationFiled: September 13, 2004Publication date: May 22, 2008Inventors: Ewald Srebotnik, Thomas Kunginger, Martin Steinwender
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Patent number: 7323083Abstract: Resinous coatings can be applied to glass, exhibiting improved adhesion thereto, by including in the coating composition a sulfonic acid derived compound such as 2-acrylamido-2-methylpropanesulfonic acid or a salt thereof. Alternatively, the glass can be first coated with the sulfonic acid derived compound and thereafter the film-forming resin applied.Type: GrantFiled: October 28, 2003Date of Patent: January 29, 2008Assignee: The Lubrizol CorporationInventors: John S. Manka, Todd K. Yonker
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Patent number: 7282117Abstract: Cellulosic fiber composites and finished cellulosic fiber composite articles are provided. The cellulosic fiber composites comprise cellulosic material and a resin binder. The resin binder comprises vegetable protein hydrolysates and a synthetic resin. The synthetic resin can be phenolic resin, isocyanate resin, or combinations thereof. The composite contains an effective amount of resin binder so as to bind together the cellulosic material. The amount of resin binder is less than 40% of the dry weight of the cellulosic material. The protein hydrolysates provide a composite with a reduced amount of petrochemicals. The composite can also contain a silicone, silane, or combination thereof.Type: GrantFiled: October 31, 2003Date of Patent: October 16, 2007Assignee: Battelle Memorial InstituteInventors: Bhima Rao Vijayendran, Jan Moon
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Patent number: 7258764Abstract: Soft and strong cellulose-based fibrous web, comprises a) cellulosic fibres having a freeness value of more than 26° SR measured according to DIN-ISO 5267/1 (March 1999), b) a water-soluble cationic polymer, c) a water-soluble anionic polymer, and d) a cationic surfactant-based softener. The webs are prepared by refining cellulosic fibres to a degree of freeness of more than 26° SR measured according to DIN-ISO 5267/1, adding at least one water-soluble anionic polymer and water-soluble cationic polymer to the refined cellulosic fibres, adding a cationic surfactant-based softener to the cellulosic fibres obtained thereby, and wet-laying and dewatering the celulosic fibres obtained thereby.Type: GrantFiled: December 17, 2003Date of Patent: August 21, 2007Assignee: SCA Hygiene Products GmbHInventor: Dirk Mauler
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Patent number: 7074301Abstract: The present invention relates to cross-linked cellulosic fiber having improved absorbency characteristics when compared to conventional cross-linked fibers. The cross-linked cellulosic fiber is obtainable by reacting pulp in the sheet or fluff form with one or more reagents selected from organic molecule having acid and aldehyde functional groups “acid aldehydes.” The invention also relates to a method of producing the cross-linked fiber. The method includes heating the treated cellulosic fibers to promote intrafiber cross-linking. The cross-linked fibers are characterized by having an improved centrifuge retention capacity, fluid acquisition rate, resiliency, absorbent capacity, absorbency under load, and other absorbent properties. The inventive cross-linked fibers are useful in forming absorbent composites, and in particular absorbent cores for use in absorbent articles.Type: GrantFiled: June 11, 2002Date of Patent: July 11, 2006Assignee: Rayonier Products and Financial Services CompanyInventors: Othman A. Hamed, Harry J. Chmielewski, Dana B. McBee
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Patent number: 7008508Abstract: For use as a wet strength agent, a water-soluble blocked urethane prepolymer having a hydrophilic group and a blocked isocyanate group is combined with a cationic charge-adjusting agent. The adsorption and retention of the water-soluble blocked urethane prepolymer to cellulosic fiber are promoted by virtue of the cationic charge adjusting agent when the wet strength agent is added to a paper-making stock.Type: GrantFiled: July 18, 2002Date of Patent: March 7, 2006Assignee: Dai Ichi Kogyo Seiyaku Co.Inventors: Takeshi Doi, Takeshi Miyamura, Masahiro Kouchi
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Patent number: 6846384Abstract: A process for sizing paper comprising adding to an aqueous suspension containing cellulosic fibers, and optional fillers, an anionic or cationic sizing dispersion, and a sizing promoter comprising a cationic organic polymer having an aromatic group; and an anionic polymer having an aromatic group selected from step-growth polymers, polysaccharides and naturally occurring aromatic polymers, wherein the sizing dispersion and sizing promoter are added separately to the aqueous suspension.Type: GrantFiled: August 6, 2001Date of Patent: January 25, 2005Assignee: Akzo Nobel N.V.Inventors: Erik Lindgren, Sten Frölich, Michael Persson
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Publication number: 20040256068Abstract: A composite sheet material, useful as a component of roofing shingles, and a process of making same, which includes a glass fiber web bound with a thermosetting resin which includes a fatty acid amide having the structural formula RCOONH2, where R is a C8-C25 alkyl.Type: ApplicationFiled: June 17, 2003Publication date: December 23, 2004Applicant: BUILDING MATERIALS INVESTMENT CORPORATIONInventors: V. Robert Canfield, Robson F. Storey, Betty C. Roberts
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Patent number: 6811653Abstract: A multi-purpose paper, a manufacturing method thereof, and an application thereof are provided. The method of manufacturing the multi-purpose paper comprises steps of (a) providing a papermaking material and obtaining a clean paper pulp by treating the papermaking material, (b) adding at least one functional additive into the clean paper pulp to form the multi-purpose paper, and (c) processing the multi-purpose paper to form thereon an uneven surface structure. The cultivating paper has the combined functions of weed control, pest control, supplying the required nutrients to plants to help develop the root system, maintaining moisture and breath for the root system. The multi-purpose paper can be carriers of agricultural antagonistic microorganisms and serve as the basic functional substrate for weed control, pest control, sowing, growing seedlings, fertilization, fertilizer saving, manpower saving and organic cultivating.Type: GrantFiled: October 26, 2001Date of Patent: November 2, 2004Assignee: Yuen Foong Yu Paper MFG Co., Ltd.Inventor: Ching-Chung Huang
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Publication number: 20040144510Abstract: Soft and strong cellulose-based fibrous web, comprisesType: ApplicationFiled: December 17, 2003Publication date: July 29, 2004Inventor: Dirk Mauler
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Publication number: 20040099390Abstract: A paper product is described that includes a paper substrate having a first surface and a second surface; a coating layer provided on the first surface of the paper substrate, the coating layer comprising a binder component and a pigment component, wherein the weight ratio the binder component to the pigment component is between about 0.25:1 to about 1:1; and wherein the paper product exhibits a gloss of at least about 20 to 75 according to TAPPI T480 om-92, a Print-surf roughness of at least about 0.5 to 2.5 according to TAPPI T555 pm-94, and a density of at least about 12 to 18 according to TAPPI T410 om-93 and TAPPI T411 om-89. A method for manufacturing a paper product is provided.Type: ApplicationFiled: November 25, 2002Publication date: May 27, 2004Inventors: Thomas R. Trochlil, John A. Theisen, Bruce C. Unruh, John E. Katchko
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Patent number: 6719881Abstract: A microparticle system for use as a retention and drainage aid in the production of alkaline and acid paper products comprises a HMW flocculent polymer (6), an acid colloid (7), and a coagulant or a MMW flooculant (5). The acid colloid (7) comprises an aqueous solution of a water soluble polymer or copolymer of melamine aldehyde, preferably melamine formaldehyde, and is present in an amount ranging between 0.0005% to 0.5% by weight based on the dry weight of the solids in the furnish. The HMW flocculant polymer (6) may be added to stock or furnish after the fan pump; and prior to the pressure screen (2); the acid colloid (7) may be added to the stock after the pressure screen (2), and the coagulant/MMW flocculant (5) may be added prior to the fan pump (1). Alternatively, this sequence of chemical additions can be changed, i.e. the acid colloid (7) can be added prior to or after the fan pump (1) or prior to the pressure screen (2).Type: GrantFiled: July 5, 2001Date of Patent: April 13, 2004Inventors: Charles R. Hunter, Craig W. Vaughan
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Patent number: 6719882Abstract: Cellulosic fiber composites and methods for preparing cellulosic fiber composites are provided. The cellulosic fiber composites comprise cellulosic material and a resin binder. The resin binder comprises protein hydrolysates and a synthetic resin. The synthetic resin can be phenolic resin, isocyanate resin, or combinations thereof. The protein hydrolysates provide a composite with a reduced amount of petrochemicals. The composite contains an amount of resin binder sufficient to bind the cellulosic material. The composite can also contain a silicone, silane, or combination thereof. The method employs a low moisture-content mat that does not require drying prior to pressing. Additional methods can be employed to produce finished cellulosic fiber composite articles.Type: GrantFiled: February 8, 2001Date of Patent: April 13, 2004Assignee: Battelle Memorial InstituteInventors: Bhima Rao Vijayendran, Jan Moon
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Patent number: 6716314Abstract: A method for forming an abrasion resistant sheet which comprises forming a web of cellulosic fibers on a papermaking machine and applying a slurry including an encapsulated abrasion-resistant grit to the upper surface of the web on the papermaking machine.Type: GrantFiled: February 27, 2001Date of Patent: April 6, 2004Assignee: MeadWestvaco CorporationInventors: Mark A. Johnson, John Benson, Mahendra Mehta, Steve Canary, Eric Girardin
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Patent number: 6699360Abstract: A process for the manufacture of single-ply, absorbent paper product, printed on before or after embossing on the Yankee side, air side, or both sides, having a serpentine configuration; low sidedness; a basis weight of at least about 12.5 lbs. per 3000 square foot ream; a specific total tensile strength between 40 and 200 g/3 inches/lb per 3000 square foot ream; a cross direction specific wet tensile strength between 2.75 and 20.0 g/3 inches/lb per 3000 square foot ream; an MD tensile to CD tensile ratio between 1.25 and 2.75; a specific geometric mean tensile stiffness between 0.5 and 3.2 g/inch/% strain per pound per 3000 square foot ream; a friction deviation of less than 0.250; a sidedness parameter of less than 0.30; and a printed sidedness value of &Dgr;E of less than 2.Type: GrantFiled: October 3, 2002Date of Patent: March 2, 2004Assignee: Fort James CorporationInventors: Michael S. Heath, T. Philips Oriaran, Mark S. Siegel, Frank D. Harper, John H. Dwiggins
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Publication number: 20040011486Abstract: A process for forming an abrasion resistant, decorative sheet which comprises forming a web of cellulosic fibers on a papermaking machine and applying a coating suspension including an abrasion-resistant grit and decorative inclusion particles to the upper surface of the web on the papermaking machine.Type: ApplicationFiled: July 17, 2002Publication date: January 22, 2004Inventors: Eric Wagner, Dennis Hankey
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Publication number: 20030205346Abstract: A high performance purified natural zeolite pigment composition for use in papermaking and paper coating is disclosed. Use of the pigment facilitates manufacture of coated ink jet and digital printing papers with improved quality and economics. The novel zeolite pigment composition can also be used as a supplementary pigment to improve the properties of coated paper and paperboard for flexographic and water-based gravure printing. When used as filler, the novel zeolite pigment composition is readily retained and eliminates print-through in uncoated papers. The novel zeolite pigment is low in abrasion and provides improved coefficient of friction. The novel zeolite pigment is also useful as a microparticulate retention aid in papermaking and as an additive to improve the performance of deinking processes.Type: ApplicationFiled: June 4, 2003Publication date: November 6, 2003Inventors: Charles P. Klass, Margaret K. Joyce
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Publication number: 20030139517Abstract: The present invention refers to a process for the production of paper from a suspension containing cellulosic fibers, and optionally fillers, comprising adding to the suspension at least one cationic organic polymer and an aqueous silica-containing composition comprising an anionic naphthalene sulphonate formaldehyde condensate and anionic silica-based particles, the composition having a weight ratio of naphthalene sulphonate formaldehyde condensate to silica-based particles within the range of from 0.2:1 to 99:1, and containing naphthalene sulphonate formaldehyde condensate and silica-based particles in an amount of at least 0.01% by weight, based on the total weight of the aqueous silica-containing composition, and with the proviso that the composition contains substantially no cellulose-reactive sizing agent. The invention also encompasses an aqueous silica-containing composition and a method for preparation of an aqueous silica-containing compound.Type: ApplicationFiled: December 20, 2002Publication date: July 24, 2003Inventors: Johan Nyander, Hans Johansson-Vestin, Jan Nordin, Annika Viola Pal
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Publication number: 20030079846Abstract: A multi-purpose paper, a manufacturing method thereof, and an application thereof are provided. The method of manufacturing the multi-purpose paper comprises steps of (a) providing a papermaking material and obtaining a clean paper pulp by treating the papermaking material, (b) adding at least one functional additive into the clean paper pulp to form the multi-purpose paper, and (c) processing the multi-purpose paper to form thereon an uneven surface structure. The cultivating paper has the combined functions of weed control, pest control, supplying the required nutrients to plants to help develop the root system, maintaining moisture and breath for the root system. The multi-purpose paper can be carriers of agricultural antagonistic microorganisms and serve as the basic functional substrate for weed control, pest control, sowing, growing seedlings, fertilization, fertilizer saving, manpower saving and organic cultivating.Type: ApplicationFiled: October 26, 2001Publication date: May 1, 2003Applicant: Yuen Foong Yu Paper MFG Co., LTDInventor: Ching-Chung Huang
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Publication number: 20030075291Abstract: A method for the production of insulation plates from an aqueous pulp comprised of mineral fillers, cellulose-containing products and a binding agent based on a novolak wherein a pulp is used comprising an additive substance selected from the group consisting of fatty acid amides or substituted fatty acid amides, the plates obtained after curing are used, inter alia, as mold covering plates or as so-called tundish plates for application in continuous casting processes.Type: ApplicationFiled: August 29, 2002Publication date: April 24, 2003Inventor: Josef Suren
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Patent number: 6540874Abstract: The present invention herein relates to an asphalt-grade carbon fiber paper comprised primarily of asphalt-grade carbon fibers and paper base material, and its process, where the paper base material may be made of cellulose fibers or synthetic fibers and resin, while the asphalt-grade carbon fiber: paper base material=10˜50:50˜90% (by weight). The asphalt-grade carbon fibers, with their conductive, antistatic and shielding actions, are incorporated into the paper base material and give it conductive and statics elimination effect. Furthermore, the paper may be processed into products with electrical and thermal conductivity or for packaging. The aforesaid asphalt-grade carbon fiber paper features excellent conductivity, high thermal conversion ratio, long service life and low cost. Its process is also extremely simple and easy to operate.Type: GrantFiled: November 20, 2000Date of Patent: April 1, 2003Inventor: Ruey Ling-Chen
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Patent number: 6517674Abstract: Abrasion resistant papers such as overlays or decor sheets useful in decorative laminates, and in particular, to abrasion resistant papers incorporating spacer or separator particles to minimize the amount of damage to highly polished caul plates caused by contact of the caul plates with abrasion resistant materials during the lamination process and a process for manufacturing such abrasion resistant papers.Type: GrantFiled: May 12, 2000Date of Patent: February 11, 2003Assignee: The Mead CorporationInventor: Amit Das
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Patent number: 6503370Abstract: Method of producing paper having a three-dimensional pattern of alternating raised and recessed portions which is given the paper in connection with impulse drying, at which the wet paper web is passed through at least one press nip (12) comprising a rotatable roll (13) which is heated and that the paper web when passing through the press nip is given a three-dimensional pattern either by means of a pattern wire (11) and/or by the fact that the heated roll (13) is provided with a three-dimensional pattern, and where the wet paper web (10) before entering said press nip (12) is given a basis weight variation in a non-random pattern.Type: GrantFiled: April 2, 2001Date of Patent: January 7, 2003Assignee: SCA Hygiene Products ABInventors: Holger Hollmark, Lennart Reiner, Thomas Billgren, Kaveh Tondkar, Mats Söderberg, Bengt Järrehult
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Patent number: 6500303Abstract: Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a hindered amine compound which preferably is a nitroxide, a hydroxylamine or an ammonium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents, metal chelating agents, sulfur containing stabilizers, metal salts and diene compounds. Combinations of nitroxides, hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. Selected derivatives of 1-oxyl-2,2,6,6-tetramethyl-piperidin-4-ol and selected hydroxylamine salts are novel compounds and are surprisingly effective for this purpose.Type: GrantFiled: May 18, 2000Date of Patent: December 31, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Raymond R. Seltzer, Jean-Pierre Wolf, Cyril Heitner, John A. Schmidt, Peter F. McGarry, Glen T. Cunkle, Randall B. Nelson
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Patent number: 6488813Abstract: Paper with increased wet strength is produced by adding to the stock a water soluble blocked urethane prepolymer having a plurality of blocked isocyanate groups and hydrophilic groups. The blocking agent is a phenol compound having an electron-attracting group at the ortho- or para-position. The blocked urethane prepolymer is capable of unblocking under such conditions that encounter in the drying part of conventional paper making machines.Type: GrantFiled: July 31, 2001Date of Patent: December 3, 2002Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.Inventors: Takeshi Doi, Naofumi Saiuchi, Masahiro Kouchi
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Patent number: 6447644Abstract: Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a hindered amine compound which preferably is a nitroxide, a hydroxylamine or an ammonium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents, metal chelating agents, sulfur containing stabilizers, metal salts and diene compounds. Combinations of nitroxides, hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. Selected derivatives of 1-oxyl-2,2,6,6-tetramethylpiperidin-4-ol and selected hydroxylamine salts are novel compounds and are surprisingly effective for this purpose.Type: GrantFiled: October 10, 2001Date of Patent: September 10, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Raymond R. Seltzer, Jean-Pierre Wolf, Cyril Heitner, John A. Schmidt, Peter F. McGarry, Glen T. Cunkle, Randall B. Nelson
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Publication number: 20020117281Abstract: A method for forming an abrasion resistant sheet which comprises forming a web of cellulosic fibers on a papermaking machine and applying a slurry including an encapsulated abrasion-resistant grit to the upper surface of the web on the papermaking machine.Type: ApplicationFiled: February 27, 2001Publication date: August 29, 2002Inventors: Mark A. Johnson, John Benson, Mahendra Mehta, Steve Canary, Eric Girardin
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Patent number: 6432271Abstract: This invention is directed to a method of increasing retention and drainage in a papermaking furnish comprising adding to the furnish an effective flocculating amount of a high molecular weight water-soluble anionic or nonionic dispersion polymer.Type: GrantFiled: October 15, 2001Date of Patent: August 13, 2002Assignee: Nalco Chemical CompanyInventors: Jane B. Wong Shing, Chidambaram Maltesh, John R. Hurlock
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Publication number: 20020098317Abstract: The present invention relates to a cellulose-containing fibrous material, wherein hydroxy groups were oxidized at the C(6) of glucose units of the cellulose into aldehyde and/or carboxy groups, a paper or nonwoven (product) made therefrom, in particular tissue (products) a process for their manufacture. The paper or nonwoven (products) of the invention display excellent strength properties.Type: ApplicationFiled: August 16, 2001Publication date: July 25, 2002Inventors: Thomas Jaschinski, Susanna Gunnars, Arie Cornelis Besemer, Petter Bragd, Jan Matthijs Jetten, Ronald Van Den Dool, Willem Van Hartingsveldt
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Publication number: 20020088583Abstract: Paper with increased wet strength is produced by adding to the stock a water soluble blocked urethane prepolymer having a plurality of blocked isocyanate groups and hydrophilic groups. The blocking agent is a phenol compound having an electron-attracting group at the ortho- or para-position. The blocked urethane prepolymer is capable of unblocking under such conditions that encounter in the drying part of conventional paper making machines.Type: ApplicationFiled: July 31, 2001Publication date: July 11, 2002Applicant: Dai-ichi Kogyo Seiyaku Co., Ltd.Inventors: Takeshi Doi, Naofumi Saiuchi, Masahiro Kouchi
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Publication number: 20020060012Abstract: The disclosure is directed to a method of using melamine resin fibers, to an insulating material comprisingType: ApplicationFiled: December 4, 2001Publication date: May 23, 2002Inventors: Heinz Berbner, Karl Ott
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Patent number: 6372087Abstract: Single-ply absorbent tissue paper wherein of the fibers incorporated in the web: (a) at least 20% by weight have a coarseness exceeding 23 mg/100 m; (b) at least about 20% by weight have a coarseness of less than about 12 mg/100 m; and (c) the weight average fiber coarseness to length ratio is less than about 8.5 mg/100 m/mm. The single-ply tissue having: a serpentine configuration; low sidedness; a basis weight of at least about 12.5 lbs. per 3000 square foot ream; specific total tensile strength between 40 and 200 g/3 inches/lb per 3000 square foot ream; a cross direction specific wet tensile strength between 2.75 and 20.0 g/3 inches/lb per 3000 square foot ream; an MD tensile to CD tensile ratio between 1.25 and 2.75; a specific geometric mean tensile stiffness between 0.5 and 3.2 g/inch/% strain per pound per 3000 square foot ream; a friction deviation less than 0.250; and a sidedness parameter less than 0.30.Type: GrantFiled: June 18, 2001Date of Patent: April 16, 2002Assignee: Fort James CorporationInventors: Frank David Harper, Taiye Philips Oriaran, John Dennis Litvay
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Patent number: 6334931Abstract: The present invention relates to a soft, thick, single-ply tissue having a serpentine configuration and to a process for the manufacture of such tissue product having a basis weight of at least about 15 lbs. per 3000 square foot ream and having low sidedness, said tissue exhibiting: a specific total tensile strength of between 40 and 200 grams per 3 inches per pound per 3000 square foot ream, a cross direction specific wet tensile strength of between 2.75 and 20.0 grams per 3 inches per pound per 3000 square foot ream, the ratio of MD tensile to CD tensile of between 1.25 and 2.75, a specific geometric mean tensile stiffness of between 0.5 and 3.2 grams per inch per percent strain per pound per 3000 square foot ream, a friction deviation of less than 0.250, and a sidedness parameter of less than 0.30.Type: GrantFiled: December 11, 1997Date of Patent: January 1, 2002Assignee: Georgia-Pacific CorporationInventors: John H. Dwiggins, Ranga Ramesh, Frank D. Harper, Anthony O. Awofeso, T. Philips Oriaran, Galyn A. Schulz, Dinesh M. Bhat
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Patent number: 6331358Abstract: A wet friction material is mainly composed of a fiber base material, a filler, an friction adjusting agent and a thermosetting resin. The wet frictional material is prepared by impregnating with a liquid thermosetting resin a paper formed by mixing a paper-forming solid thermosetting resin with a fiber base material as at least a part of filler, and then applying heat to the paper so that it is hardened. The solid thermosetting resin is preferably a phenol resin. The liquid thermosetting resin is preferably made of a silicone resin represented by the following average composition formula and the amount of trifunctional unit monomers (RSiO3/2 in which R represents a substituted or unsubstituted monovalent hydrocarbon group) in monomers constituting said silicone resin is from 40 to 100 mol-%: (R1)a(OR2)bSiO(4−a−b)/2.Type: GrantFiled: March 3, 1999Date of Patent: December 18, 2001Assignee: NSK-Warner Kabushiki KaishaInventors: Shun Kitahara, Fumimasa Muramatsu, Shigeki Umezawa
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Patent number: 6306256Abstract: A method and an agent for improving the retention when dewatering a cellulosic fiber suspension are disclosed In the method, there is added to the suspension a retention agent containing a phenol-formaldehyde resin and a polyethylene oxide, and the method is characterised in that a modified phenol-formaldehyde resin containing cationic groups is added to the suspension. The modified phenol-formaldehyde resin preferably has a cationicity of about 5-85% and the cationic groups preferably consist of amine groups. The polyethylene oxide in the retention agent preferably has a molecular weight of about 0.5-20×106. The modified phenol-formaldehyde resin and the polyethylene oxide are preferably added to the suspension in a weight ratio of modified phenol-formaldehyde resin:polyethylene oxide of from 1:5 to 50:1, and the amount of polyethylene oxide added preferably is about 10-1000 ppm, based on tie dry solids content of the suspension.Type: GrantFiled: January 4, 2000Date of Patent: October 23, 2001Assignee: Kemira Kemi ABInventors: Bo Rosengren, Ulla Gytel
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Publication number: 20010030031Abstract: From about 50 to about 90% by weight of fibers, in particular wood fibers, and/or pellets made from cellulose or from wood, are mixed with from about 10 to about 50% by weight of a hot-curing resin, each of the percentages by weight being based on the total weight of the mixture. Instead of a single resin it is also possible to use a mixture made from two or more hot-curing resins. The mixture made from fibers and/or pellets and resin is kneaded and homogenized and then passed on to an extruder which has various heating zones in which the mixture is heated. Care has to be taken here that the maximum temperature, arising at the extruder exit, does not exceed about 120° C., since above this temperature the resin(s) begin(s) to cure.Type: ApplicationFiled: February 20, 2001Publication date: October 18, 2001Applicant: TRESPA INTERNATIONAL B.V.Inventor: Remco Cornelis Willemse
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Patent number: 6303002Abstract: Paper, board and cardboard are produced from paper stocks which contain tacky impurities by the addition of surfactants and cationic polymers having a charge density of at least 1.5 meq/g (measured at pH 7) and a molar mass Mw of the cationic polymers of at least 15,000 and drainage of the paper stocks with fixation of the tacky impurities in the paper produced.Type: GrantFiled: October 15, 1999Date of Patent: October 16, 2001Assignee: BASF AktiengesellschaftInventors: Friedrich Linhart, Jaroslav Melzer, Hubert Meixner
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Patent number: 6280570Abstract: The present invention relates to a process of making a soft, thick, single-ply, absorbent paper in the form of a bathroom tissue, facial tissue, or napkin wherein the cellulosic fibers incorporated in the furnish comprise: (a) at least 20 percent by weight of the fibers in the web have a coarseness exceeding 23 mg/100 m; (b) at least about 20 percent by weight of the fibers in the web have a coarseness of less than about 1.2 mg/100 m; and (c) the weight average coarseness to length ratio of the fibers in the web is less than about 8.5 mg/100 m/mm having a serpentine configuration and to a process for the manufacture of such absorbent paper having a basis weight of about 15 lbs. per 3000 square foot ream and having low sidedness, said tissue exhibiting: a specific total tensile strength of between 40 and 200 grams per 3 inches per pound per 3000 square foot ream, a cross direction specific wet tensile strength of between 2.75 and 20.Type: GrantFiled: September 29, 2000Date of Patent: August 28, 2001Assignee: Fort James CorporationInventors: Frank David Harper, Taiye Philips Oriaran, John Dennis Litvay
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Patent number: 6261414Abstract: The present invention relates to a method of producing a laminate base material useful for preparing a prepreg or a laminate for electronic equipment such as printed board. The method comprises the steps of: (1) preparing a slurry comprising para-aramid fibers and curable phenolic resin fibers; (2) preparing a sheet from said slurry; (3) adding a resin binder to said sheet so as to bond the fibers with each other, thereby to form a combined non-woven fabric and (4) compressing said non-woven fabric under heating. According to the present invention, a prepreg or laminate is obtained which has an improved high-frequency characteristics and much less warp.Type: GrantFiled: November 4, 1998Date of Patent: July 17, 2001Assignee: OJI Paper Co., Ltd.Inventors: Yoshihisa Kato, Takekazu Adachi, Mamoru Murata
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Patent number: 6254724Abstract: Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a hindered amine compound which preferably is a nitroxide, a hydroxylamine or an ammonium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents, metal chelating agents, sulfur containing stabilizers, metal salts and diene compounds. Combinations of nitroxides, hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. Selected derivatives of 1-oxyl-2,2,6,6-tetramethyl-piperidin-4-ol and selected hydroxylamine salts are novel compounds and are surprisingly effective for this purpose.Type: GrantFiled: July 20, 1998Date of Patent: July 3, 2001Assignee: Ciba Specialty Chemicals CorporationInventors: Raymond R. Seltzer, Jean-Pierre Wolf, Cyril Heitner, John A. Schmidt, Peter F. McGarry, Glen T. Cunkle, Randall B. Nelson