Polymerized Unsaturated Compound Patents (Class 162/168.1)
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Publication number: 20130068409Abstract: A core paper comprising fiber material for producing a carrier material that can be laminated and that has at least one proportion of a reconstituted fiber material mixture and a wet sealer as a first additive, characterized in that the core paper comprises at least one active substance active on the boundary surface as a second additive for increasing capillarity at a weight proportion of 0.05% to 2% relative to the material.Type: ApplicationFiled: May 5, 2011Publication date: March 21, 2013Applicant: PAPIERFABRIK JULIUS SCHULTE SOHNE GMBH & CO. KG.Inventor: Georg Pingen
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Patent number: 8382950Abstract: The invention provides a method of recovering and recycling waste coating color from papermaking coating process for use as wet end filler. The inventive method overcomes many technical challenges inherent in using waste coating colors as wet end filler such as the coatings having fine pigments that hurts sheet strength more than regular filler, having strong anionic charge and tendency to disturb wet end chemistry, causing excessive foaming, and containing a large amount of hydrophobic binder particles that tend to agglomerate in the white water and deposit on papermaking equipment. The method involves mixing the coatings with fresh filler particles, adding de-foaming agent, adding cationic coagulant, then preflocculating the mixture. This process causes fresh filler particles, pigments and binders in waste coating color to agglomerate together and form stable flocs with defined particle size distribution.Type: GrantFiled: December 22, 2010Date of Patent: February 26, 2013Assignee: Nalco CompanyInventor: Weiguo Cheng
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Patent number: 8382949Abstract: A paper substrate, particularly useful in wallboard tape applications containing PVOH on and/or in at least one surface of the paper, as well as methods of making and using the same. The use of the tape of the invention is used in conjunction with a joint compound that may contain no or reduced amounts of bonding agent.Type: GrantFiled: August 11, 2010Date of Patent: February 26, 2013Assignee: International Paper CompanyInventor: Martha Patricia Wild
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Patent number: 8381536Abstract: Conductive nonwoven webs are disclosed. The nonwoven webs contain pulp fibers combined with conductive fibers. In one embodiment, the webs are made in a wetlaid tissue making process.Type: GrantFiled: November 15, 2011Date of Patent: February 26, 2013Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Davis-Dang H. Nhan, Duane Joseph Shukoski, Michael J. Rekoske
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Patent number: 8361278Abstract: A base sheet for food wrap products. The base sheet can include a pulp-derived papermaking fiber and a fibrillated regenerated cellulose microfiber having a CSF value of less than about 175 mL.Type: GrantFiled: September 16, 2009Date of Patent: January 29, 2013Assignee: Dixie Consumer Products LLCInventors: Gregory M. Fike, Joseph R. Pounder, Daniel W. Sumnicht
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Patent number: 8349134Abstract: The invention relates to a process for producing paper, board and cardboard of high dry strength by separately adding a polymer comprising vinylamine units and a polymeric anionic compound to a paper pulp, dewatering the pulp and drying the paper products, which comprises using as polymeric anionic compound at least one copolymer obtainable by copolymerizing (a) at least one N-vinylcarboxamide of the formula in which R1 and R2 are H or C1- to C6 alkyl, (b) at least one monoethylenically unsaturated monomer comprising acid groups, and/or the alkali metal, alkaline earth metal or ammonium salts thereof, and if appropriate (c) other monoethylenically unsaturated monomers, and if appropriate (d) compounds having at least two ethylenically unsaturated double bonds in their molecule.Type: GrantFiled: November 21, 2005Date of Patent: January 8, 2013Assignee: BASF SEInventors: Anton Esser, Hans-Joachim Haehnle, Martin Ruebenacker, Norbert Schall, Jacques Dupuis, Josef Neutzner, Manfred Niessner, Berthold Sturm
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Patent number: 8343312Abstract: Process for the production of filler-containing papers and filler-containing paper products by addition of an aqueous suspension of at least one finely divided polymer-pigment hybrid to a paper stock and drainage of the paper stock with sheet formation, the polymer-pigment hybrid being obtainable by milling an aqueous suspension of at least one inorganic pigment in the presence of at least one binder and, if appropriate, by drying the aqueous suspension thus obtainable and redispersing the dried polymer-pigment hybrid in water, and the use of the polymer-pigment hybrids thus obtainable as a filler for the production of filler-containing paper or filler-containing paper products.Type: GrantFiled: May 24, 2006Date of Patent: January 1, 2013Assignee: BASF AktiengesellschaftInventors: Norbert Mahr, Dieter Meck, Rainer Blum, Ralf Hemel, Norbert Gispert, Juergen Schmidt-Thuemmes, Christoph Hamers
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Patent number: 8337665Abstract: A process for the production of paper, board and cardboard by draining a paper stock containing interfering substances in the presence of polymers which contain vinylamine units and which have an average molar mass Mw of at least 1 million, a high-consistency stock first being prepared, at least one polymer containing vinylamine units and having an average molar mass Mw of at least 1 million and a degree of hydrolysis of from 1 to 20 mol % being metered into the high-consistency stock, the high-consistency stock being diluted to a low-consistency stock by adding water, and the low-consistency stock being drained, and the use of hydrolyzed homo- or copolymers of N-vinylcarboxamides having a degree of hydrolysis of from 1 to 20 mol % and an average molar mass Mw of at least 1 million in the production of paper, board or cardboard as an additive to a high-consistency stock containing interfering substances, for reducing deposits in the wire part, press section and drying section of paper machines.Type: GrantFiled: March 14, 2005Date of Patent: December 25, 2012Assignee: BASF SEInventors: Anton Esser, Rainer Blum, Joachim Kuhn, Marc Leduc, Ralf Hemel
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Patent number: 8317976Abstract: The specification discloses a method for making a paper material having a reduced tendency to cut human skin. The method includes providing a papermaking furnish containing cellulosic fibers and from about 0.5 to about 5.0 wt % by weight dry basis expandable microspheres, forming a paperboard web from the papermaking furnish, drying the web, and calendaring the web to a caliper of from about 11.0 to about 18.0 mils and a density ranging from about 7.0 to about 12.0 lb/3000 ft2/mil. Papers formed according to the method and articles formed therefrom are also disclosed.Type: GrantFiled: August 19, 2010Date of Patent: November 27, 2012Assignee: International Paper CompanyInventors: Richard C. Williams, Peter M. Froass, David A. Boone, Richard D. Faber
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Patent number: 8308902Abstract: A method of improving retention and drainage in a papermaking process is disclosed. The addition of an associative polymer, a poly(vinylamine) and optionally a siliceous material to the papermaking slurry to improve retention and drainage is disclosed. Additionally a method to improve retention and drainage comprising addition of an organic microparticle, a poly(vinylamine) and optionally a siliceous material to the papermaking slurry is disclosed. A composition comprising an associative polymer, and a poly(vinylamine) and optionally further comprising cellulose fiber is disclosed.Type: GrantFiled: May 8, 2009Date of Patent: November 13, 2012Assignee: Hercules IncorporatedInventors: Frank Sutman, John Harrington, Robert Gelman
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Publication number: 20120270458Abstract: The present invention relates to a medical nonwoven fabric comprising gelable cellulose derivative short-cut fibers as prepared by the paper making process, a preparation method thereof, and an adhesion prevention barrier using the same. The present invention provides a single phase of medical nonwoven fabric comprising gelable cellulose derivative short-cut fibers, to induce capillary action of micropores formed between the fibers and thereby control the gelation time, and provides a composite nonwoven fabric formed by laminating a nonwoven fabric layer comprising a different kind of biodegradable polymer material not susceptible to gelation on the single-phase of medical nonwoven fabric comprising gelable cellulose derivative short-cut fibers, thereby improving dimensional stability and convenience of surgical procedure. The present invention further provides a dyed medical nonwoven fabric to improve visibility, allowing easiness of recognizing the placement or location of the medical nonwoven fabric.Type: ApplicationFiled: April 1, 2010Publication date: October 25, 2012Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGYInventors: Jung Nam Im, Dae Young Lim, Guk-Hwan An, Yoon Jin Kim
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Patent number: 8262857Abstract: Tissue products are disclosed containing an additive composition. The additive composition, for instance, comprises an aqueous dispersion containing an alpha-olefin polymer, an ethylene-carboxylic acid copolymer, or mixtures thereof. The alpha-olefin polymer may comprise an interpolymer of ethylene and octene, while the ethylene-carboxylic acid copolymer may comprise ethylene-acrylic acid copolymer. The additive composition may also contain a dispersing agent, such as a fatty acid. The additive composition may be incorporated into the tissue web as the web is being formed. Alternatively, the additive composition may be topically applied to the web in a post processing operation. For instance, in one embodiment, the additive composition may be applied to the web as a creping adhesive during a creping operation.Type: GrantFiled: July 1, 2010Date of Patent: September 11, 2012Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Michael Alan Hermans, Michael J. Rekoske, Thomas Joseph Dyer
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Publication number: 20120211189Abstract: A method is provided for manufacturing recyclable mineral paper, which has a composition comprising 60-85 wt % natural inorganic mineral powders, 5-40 wt % polypropylene (PP), and 1-5 wt % assisting agents, through the following steps: feeding and mixing of the constituents of the composition; stirring and mixing the composition; pressing to cause bi-directional extension of the composition so as to form a sheet; subjecting the sheet to operation of a high density squeezing machine for further mixing and pressing the sheet; reversely turning and shaping the sheet for further extension of the sheet; and continuous compression and extension of the sheet to induce further bi-directional extension of the sheet in both lateral and longitudinal direction and to control thickness of the sheet.Type: ApplicationFiled: February 18, 2011Publication date: August 23, 2012Inventors: CHUN-TENG HUANG, Chun-Ming Huang
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Patent number: 8241462Abstract: To provide a papermaking internal sizing agent capable of efficiently imparting sizing performance even in neutral papermaking which uses calcium carbonate as filler, and uses no aluminum sulfate or uses a small amount of aluminum sulfate, and also provide a paper or a paperboard obtained by using the papermaking internal sizing agent. The papermaking internal sizing agent comprises as an effective ingredient an amphoteric copolymer having hydrophobic groups and cationic groups, at least a part of the cationic groups being quaternized. Preferably, the amphoteric copolymer is obtained by polymerizing monomer ingredients that it essentially contain a hydrophobic monomer (A), a cationic monomer (B), and an anionic monomer (C) and that an anion equivalent of the monomer (C) is 0.1 to 90% of a cation equivalent of the monomer (B), in which a rate of quaternizing of the cationic groups is not less than 40% by mole. The paper or the paperboard contains the above papermaking internal sizing agent.Type: GrantFiled: March 6, 2008Date of Patent: August 14, 2012Assignees: Harima Chemicals, Inc., Nippon Paper Industries Co., Ltd.Inventors: Kazunari Sakai, Takahiro Fujiwara, Kazushige Inaoka, Takashi Yamaguchi, Masaki Ito, Yasunobu Ooka
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Patent number: 8236136Abstract: Additives for paper making are disclosed herein. Specifically, the additives are wax-free alternatives to conventional coatings, including ASA, AKD and optionally an acrylic containing composition. Other additives may be included in the coating, such as cationic particles or compositions. The coatings may be used at a variety of points during the paper making process, including on the calender stack and in the wet end.Type: GrantFiled: February 25, 2010Date of Patent: August 7, 2012Assignee: Spectra-Kote CorporationInventors: Charles W. Propst, Jr., James C. Jones
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Patent number: 8206553Abstract: A method of improving retention and drainage in a papermaking process is disclosed. The method provides for the addition of an associative polymer, prepared by an inverse emulsion polymerization process that utilizes multiple, discrete additions of initiator. Additionally, a process for preparation of an associative polymer, prepared by an inverse emulsion polymerization process that utilizes multiple discrete additions of initiator is disclosed.Type: GrantFiled: December 21, 2005Date of Patent: June 26, 2012Assignee: Hercules IncorporatedInventors: Robert A. Gelman, Erin A. S. Doherty
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Patent number: 8187419Abstract: The present disclosure provides a paper product having at least two plies. Only one outer surface of the tissue paper product has a lotion and a polyhydroxy compound having a molecular weight ranging from about 150 to about 4,000 and selected from the group consisting of glycerols, polyglycerols, polyethylene glycols (PEGs), polyoxyethylenes, polyoxypropylenes, and combinations thereof applied thereto by slot extrusion. The polyhydroxy compound provides the tissue paper product with a Wet Burst greater than about 90 g, a Dynamic Coefficient of Friction less than about 0.9, and a Bending Flexibility less than about 0.042 gf cm2/cm.Type: GrantFiled: June 14, 2011Date of Patent: May 29, 2012Assignee: The Procter & Gamble CompanyInventors: Eric Chan, Brooke Marie Woods, LaTisha Evette Salaam
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Publication number: 20120118520Abstract: The present invention provides a method for easily and efficiently manufacturing microfibrous cellulose composite sheets. The present invention is a method for manufacturing microfibrous cellulose composite sheets, including a preparation process in which a polymer emulsion is mixed with an aqueous suspension including microfibrous cellulose, thereby preparing a mixed fluid, a papermaking process in which the mixed fluid is dehydrated on a porous base material through filtration, and a sheet including moisture is formed, and a drying process in which the sheet including moisture is heated and dried. In addition, the present invention is a method for manufacturing a microfibrous cellulose composite sheet laminate, in which the microfibrous cellulose sheets are thermally compressed and thus laminated as they are or after being provided with a polymer layer on at least one surface thereof.Type: ApplicationFiled: July 22, 2010Publication date: May 17, 2012Applicant: OJI PAPER CO., LTD.Inventors: Yasutomo Noishiki, Takashi Kawamukai, Mitsuru Tsunoda, Yoshiyuki Asayama
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Patent number: 8177939Abstract: In one embodiment, the present invention provides a method of forming a cellulose article having a specific volume of less than 3 cc/gm. The method includes the step of incorporating cellulose fibers with a compound, wherein the compound includes an aqueous dispersion. The aqueous dispersion may have at least one polymer selected from the group consisting of an ethylene-based thermoplastic polymer, a propylene-based thermoplastic polymer, and mixtures thereof; at least one polymeric stabilizing agent; and water. In certain embodiments, a combined amount of the at least one polymer and the at least one stabilizing agent comprises about 25 to about 74 volume percent of the aqueous dispersion.Type: GrantFiled: August 26, 2011Date of Patent: May 15, 2012Assignee: Dow Global Technologies LLCInventors: Brad M. Moncla, Ronald Wevers, Wenbin Liang, Henk Felix, Michael R. Lostocco, Troy M. Runge, Thomas J. Dyer, Deborah J. Nickel, Johan Vanrijsbergen
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Publication number: 20120103548Abstract: The invention provides a method of improving dewatering efficiency, increasing sheet wet web strength, increasing sheet wet strength and enhancing filler retention in a papermaking process The method improves the efficiency of drainage aids or wet web strength aids or wet strength aid by coating at least some of the filler particles with a material that prevents the filler materials form adhering to a those additives. The drainage additive or wet web strength additive or wet strength aid holds the cellulose fibers together tightly and is not wasted on the filler particles.Type: ApplicationFiled: October 13, 2011Publication date: May 3, 2012Inventors: Yulin ZHAO, Jun LI, Qing Long RAO, Weiguo CHENG
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Patent number: 8163133Abstract: The invention relates to an aqueous dispersion useful for internal sizing or surface sizing in the production of paper, comprising at least one cellulose reactive sizing agent selected from the group consisting of ketene dimers and multimers, at least one cellulose non-reactive sizing agent and at least one emulsifier selected from the group consisting of oxyalkylene phosphate and sulfate esters and salts thereof. The invention further concerns a process for its preparation, use thereof, and processes for the production of paper.Type: GrantFiled: March 26, 2004Date of Patent: April 24, 2012Assignee: Akzo Nobel N.V.Inventor: Ralf Krückel
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Patent number: 8163134Abstract: Methods for making a heterogeneous polymer blend comprising one or more anionic polymers, one or more cationic polymers, and one or more non-ionic polymers, which method comprises (a) adding to a non-neutral solution a first amount of polymerization initiator and one or more anionic or cationic monomers, wherein each monomer has the same charge; (b) adding a second amount of the polymerization initiator and one or more non-ionic monomers; (c) adding a third amount of the polymerization initiator and one or more ionic monomers that are oppositely charged from the monomers of (a); adding stepwise, a fourth amount of the polymerization initiator to react any residual monomer, and (e) neutralizing the resulting polymer blend. Also claimed are heterogeneous polymer blends containing polymers formed from one or more anionic, cationic, and non-ionic monomers, either polymerized in situ or separately and then combined.Type: GrantFiled: September 18, 2009Date of Patent: April 24, 2012Assignees: Hercules Incorporated, Specialty Minerals (Michigan) Inc.Inventors: Frank J. Sutman, Joseph M. Mahoney, Robert Anthony Gill, Daniel Bruce Evans
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Patent number: 8157959Abstract: The invention relates to a method of manufacturing board (2), a board provided by the method, and a container formed from the same, such as a disposable drinking cup. According to the invention, fiber-based stock is doped with a polymer (6), ending in a pulp web that is formed of this pulp on a board machine wire, and in a board layer (3) that is obtained from the same by pressing and drying. When the board layer is heated, the polymer melts and water vapor bubbles penetrate it, rendering the layer porous. The polymer used for the doping can comprise, for example, a low density polyethylene (LDPE) that has a melt viscosity of about 15. Pore-generating heating can be carried out for the board or only for the container manufactured from it. The porous layer prevents the hot drink enjoyed from the cup from burning the fingers of the user.Type: GrantFiled: March 17, 2008Date of Patent: April 17, 2012Assignee: Stora Enso OyjInventors: Jari Räsänen, Tapani Penttinen, Niilo Pöyhönen
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Patent number: 8157961Abstract: The present invention relates to a sizing composition that, when applied to paper substrate, creates a substrate, preferably suitable for inkjet printing, having increased print density, print sharpness, low HST, and/or image dry time, the substrate preferably having high brightness and reduced color-to-color bleed as well. In addition, the present invention relates to a method of reducing the HST of a paper substrate by applying the sizing composition to at least one surface thereof. Further, the application relates to methods of making and using the sizing composition, as well as methods of making and using the paper containing the sizing composition.Type: GrantFiled: March 22, 2010Date of Patent: April 17, 2012Assignee: International Paper CompanyInventors: Jay C. Song, Sen Yang, Yan C. Huang, Kapil M. Singh, Michael F. Koenig, David B. Shelmidine
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Patent number: 8114252Abstract: A composition for treating paper products comprising protein particulate, colloidal pigment, synthetic latex polymer, and preservative is described, as well as methods and an apparatus using the composition for such treatments, and products obtained thereby. The treated paper products preferably have improved strength, water holdout, and/or ink holdout, amongst other advantages and benefits.Type: GrantFiled: July 10, 2008Date of Patent: February 14, 2012Assignee: Buckman Laboratories International, Inc.Inventor: Gerald M. Dykstra
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Patent number: 8088252Abstract: A solution with a salt-sensitive polymer binder for use in fibrous webs, where the binder contains a copolymer comprising repeat units derived from butyl acrylate, methyl methacrylate and amino functionalized alkyl acrylate or methacrylate or amino functionalized alkyl acrylamide or methacrylamide optionally including monomers such as vinyl acetate and/or vinyl acetate/ethylene. The binder solution is prepared by emulsion-polymerizing a copolymer and then neutralizing the copolymer with acid to make it water soluble. The binders are particularly suitable for strengthening nonwoven fibrous webs in disposable articles such as wet-wipes, personal care products, diapers, and the like and retain their salt-sensitivity with or without divalent metal scavengers.Type: GrantFiled: March 2, 2009Date of Patent: January 3, 2012Inventors: Rajeev Farwaha, Philip Confalone
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Patent number: 8070913Abstract: A tissue paper product having at least one ply, wherein only one outer surface of said tissue paper product has a polyhydroxy compound selected from the group consisting of glycerols, polyglycerols, polyethylene glycols (PEGS), polyoxyethylenes, polyoxypropylenes, and combinations thereof applied thereto by slot extrusion, said polyhydroxy compound providing said tissue paper product with a Wet Burst greater than about 90 g, a Dynamic Coefficient of Friction less than about 0.9, and a Bending Flexibility less than about 0.1 gf cm2/cm.Type: GrantFiled: November 30, 2010Date of Patent: December 6, 2011Assignee: The Procter & Gamble CompanyInventors: LaTisha Evette Salaam, Michael Scott Prodoehl
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Absorbent sheet prepared with papermaking fiber and synthetic fiber exhibiting improved wet strength
Patent number: 8066849Abstract: A wet-laid absorbent sheet includes a mixture of pulp-derived papermaking fibers and synthetic polymer fibers, a strength agent selected from carboxymethylcellulose and anionic starch as well as an epihalohydrin/amine functional wet strength resin. Also included is an anionic olefin copolymer resin effective to increase the wet/dry tensile ratio of the sheet.Type: GrantFiled: June 11, 2009Date of Patent: November 29, 2011Assignee: Georgia-Pacific Consumer Products LPInventors: Bruce J. Kokko, Daniel W. Sumnicht -
Patent number: 8062476Abstract: A preparation of high strength paper by incorporating a polymeric film into the paper web during the paper making process is provided. The polymeric film is either a cold water soluble film or hot water soluble film or water insoluble hydrophilic film or non soluble non hydrophilic film or a combination of cold+hot+cold water soluble film or cold+hot water soluble film or cold+non soluble hydrophilic film or cold+non soluble hydrophilic film+cold water soluble film or cold+non soluble non hydrophilic film or cold+non soluble non hydrophilic film+cold water soluble film or slit strips of one or many of these combinations woven or intertwined offline and incorporated into the paper during the paper making process. Zone coating or discreet printing or zone extrusion striping or formation of hot water soluble film on preformed cold water soluble film which is then inserted into paper during the paper making process, thus using cold water soluble film as a carrier is also provided.Type: GrantFiled: March 22, 2006Date of Patent: November 22, 2011Assignee: Arrow Coated Products Ltd.Inventors: Shilpan Pravinchandra Patel, Nikita Kamlesh Thanawala
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Patent number: 8048267Abstract: The present invention relates to a sizing or coating composition that, when applied to paper substrate, creates a substrate having improved waterfastness, surface strength, and surface strength as measured by resistance to abrasion. In addition, the present invention relates to paper substrates containing the composition, as well as methods of using and making the paper substrate and composition.Type: GrantFiled: May 21, 2008Date of Patent: November 1, 2011Assignee: International Paper CompanyInventors: Michael F Koenig, Kapil M Singh
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Patent number: 8043476Abstract: A paper or paper board coated with an aqueous paper coating composition containing pigment having a phosphorous-containing emulsion polymer and a phosphorous-containing dispersant.Type: GrantFiled: October 29, 2007Date of Patent: October 25, 2011Assignee: Rohm and Haas CompanyInventors: John Robert Haigh, Ravi Mukkamala
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Patent number: 8038846Abstract: According to the present invention, a process is provided for making paper or board comprising forming a cellulosic suspension that may or may not comprise a filler, flocculating the cellulosic suspension, draining the cellulosic suspension on a screen to form a sheet, wherein the cellulosic suspension is flocculated using a flocculation system comprising the sequential or simultaneous addition of a siliceous material and an organic, cationic or anionic, water-in-water or dispersion micropolymer in a salt solution.Type: GrantFiled: September 14, 2007Date of Patent: October 18, 2011Assignee: Kemira OyjInventors: Marco Savio Polverari, Christopher Michael Lewis, Matthew Gerard Fabian
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Patent number: 8034463Abstract: Fibrous structures that exhibit a Wet Burst of greater than 30 g as measured according to the Wet Burst Test Method and that may also exhibit a Geometric Mean (“GM”) Modulus and/or CD Modulus of less than 1320 at 15 g/cm and/or less than 875 at 15 g/cm as measured according to the Modulus Test Method are provided.Type: GrantFiled: July 30, 2009Date of Patent: October 11, 2011Assignee: The Procter & Gamble CompanyInventors: Angela Marie Leimbach, Michael Scott Prodoehl, John Allen Manifold
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Publication number: 20110240241Abstract: A method for inhibiting deposition of multivalent saturated fatty acids on paper sizing equipment and/or devices which use a paper surface sizing composition containing one or more surface sizing starches and a source of multivalent cations, such as a multivalent metal drying salt, by including a C16 or higher saturated fatty acid solubilizing and dispersing surfactant in the paper surface sizing composition. Also, a paper surface sizing system for carrying out this method.Type: ApplicationFiled: April 2, 2010Publication date: October 6, 2011Applicant: INTERNATIONAL PAPER COMPANYInventors: Michael F. Koenig, Ascencion L. Koenig, Ewa Gertruda Bucher
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Patent number: 8029647Abstract: Process for the production of paper, board and cardboard by draining a paper stock on a wire with sheet formation and drying of the sheets, the sheet formation being carried out in the absence of finely divided inorganic flocculants and (a) polymers comprising vinylamine units and/or polyvinylformamide having a molar mass Mw of, in each case, at least 1 million and (b) at least one cationic or nonionic polyacrylamide and/or one cationic or nonionic polymethacrylamide having a molar mass Mw of, in each case, at least 2.5 million being used as retention aids.Type: GrantFiled: September 8, 2005Date of Patent: October 4, 2011Assignee: BASF AktiengesellschaftInventors: Marc Leduc, Rainer Blum, Peter Leifert
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Patent number: 8025767Abstract: They are mixtures of (a) from 1 to 99.9% by weight of a water-soluble epihalohydrin-crosslinked polyamidoamine and (b) from 0.1 to 20% by weight of at least one other cationic polymer.Type: GrantFiled: July 7, 2008Date of Patent: September 27, 2011Assignee: BASF AktiengesellschaftInventors: Ellen Krueger, Martin Wendker, Stefan Frenzel, Claus Boettcher
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Patent number: 8025764Abstract: A paper product with absorbency and moisture strike through resistance is disclosed. More particularly, a multi-ply paper product with improved strike through resistance is disclosed, wherein at least one ply is a wetting resistant ply comprising at least one wetting resistant compound and at least one ply is an absorbent ply possessing greater absorbency than the wetting resistant ply. In addition, a two-ply paper napkin with improved moisture strike through resistance is disclosed, wherein the wetting resistant ply comprises alkyl ketene dimer and the two plies are separately microembossed, glue laminated together in a point to point configuration, and macroembossed with coin edging. Furthermore, a multi-ply paper product with improved strike through resistance is disclosed, wherein a first ply comprises at least one wetting resistant compound and a second ply possesses greater absorbency than the first ply.Type: GrantFiled: August 31, 2010Date of Patent: September 27, 2011Assignee: Georgia-Pacific Consumer Products LPInventors: Dinesh M. Bhat, Daniel W. Sumnicht
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Patent number: 8025768Abstract: A continuous fiIter treatment process in which anionic polymer dispersions (latex) are added to common papermaking filler slurries ai ambient temperature and then mixed with water of temperature higher than the glass transition temperature (Tg) of the latex used. To efficiently fix the latex the temperature of the filler/latex mixture must be 30-60° C. higher than ihe Tg of the latex used. The chemical composition of the resin and the type of surfactant used during the emulsion polymerization process of the polymer latex dispersions are important factors for efficiently fixing the latex onto the filler by adding hot water and improving the properties of paper made with the treated filler. Enhanced fixation of anionic latex onto filler using hot water is done in mixing vessels that can control shear and mixing time. The anionic latexes are totally and irreversibly fixed or bound onto the filler particles and the aggregated filler slurry is stable over time.Type: GrantFiled: June 5, 2008Date of Patent: September 27, 2011Assignee: FpinnovationsInventors: Makhlouf Laleg, Roderick Collins, Danielle Gagne, Steven Middleton
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Patent number: 8021516Abstract: A water-soluble interjacent complex that includes a first water-soluble polymer and one or more water-soluble monomers polymerized to form a second water-soluble polymer in the presence of the first water-soluble polymer. The water-soluble interjacent complex forms a solution in water that is free of insoluble polymer particles. The interjacent complexes may be used to treat a waste sludge by adding an effective amount thereof to the waste sludge. The interjacent complexes may also be used in making paper by adding an effective amount thereof to a pulp or a forming sheet at a suitable location on a paper making machine. The interjacent complexes may further be used as a rheology modifier in aqueous systems by adding an effective amount thereof to an aqueous medium to effect a desired viscosity, rheology, or flow curve property.Type: GrantFiled: April 6, 2009Date of Patent: September 20, 2011Assignee: WSP Chemicals & Technology, LLCInventors: Shih-Ruey T Chen, Valentino L. DeVito, Kevin W. Frederick
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Patent number: 8021518Abstract: The invention provides a method of increasing the absorbency of an absorbent article. The method includes introducing a super-absorbent polymer composition to a paper web in a papermaking process to increase the absorbent capacity of an absorbent article made in the process. The polymer composition includes a super-absorbent polymer and a cross-linking agent applied to the paper web. The paper web is then subjected to heat in a heated drum or a through-air drier to cure or cross-link the super-absorbent polymer.Type: GrantFiled: November 30, 2006Date of Patent: September 20, 2011Assignee: Nalco CompanyInventors: Gary S. Furman, Laurence S. Bonday, Shiby John
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Patent number: 8007638Abstract: A method of manufacturing a cellulosic sheet having at least one of hydrophobic and oleophobic properties comprises the steps of depositing a stock of cellulosic fibers onto at least one forming fabric at an impingement zone and forming a web therefrom in a formation process; combining a water-based composition comprising an adhesion promoter, an organic nanoparticulate polymer and a fluorocarbon with the web at a preselected combination stage prior to a heating stage at which the web is subjected to a temperature exceeding 60° C.; and heat-curing the composition with the web during a drying process. A water-based composition for imparting at least one of hydrophobic and oleophobic properties to a cellulosic sheet during manufacture comprises an adhesion promoter, an organic nanoparticulate polymer and a fluorocarbon. A cellulosic sheet or layer thereof has at least one of hydrophobic and oleophobic properties. Improved resistance of cellulosic sheets to oil or water is obtained.Type: GrantFiled: July 4, 2006Date of Patent: August 30, 2011Assignee: AstenJohnson, Inc.Inventors: Samuel Baker, Jackson Graham, Dietmar Wirtz
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Patent number: 8002119Abstract: A method for controlling the thickening of aqueous systems comprising silicates, which comprises adding to the aqueous system at least one copolymer of a mean molecular weight Mw of at least 3000 g/mol to at most 60 000 g/mol and the copolymer being made up essentially randomly from monoethylenically unsaturated monocarboxylic acids, monoethylenically unsaturated dicarboxylic acids and other ethylenically unsaturated comonomers, the polymerization for producing the copolymer being performed in the presence of from 0.01 to 100 mol % of at least one base, based on the total amount of all COOH groups of the monocarboxylic and dicarboxylic acids, the quantitative figures in % by weight being respectively based on the total amount of all monomers used.Type: GrantFiled: January 30, 2007Date of Patent: August 23, 2011Assignee: BASF SEInventors: Karl-Heinz Buechner, Stephan Nied, Alexander Goethlich, Frank Klippel, Gunnar Schornick
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Patent number: 7998312Abstract: Moisture absorptive and desorptive paper having both high moisture absorptive and desorptive properties and high dimensional stability is provided. Moisture absorptive and desorptive paper comprising organic fine particles having cross-linking structure and 1 to 10 mmol/g of acidic group where not less than 1 mmol/g of metal ion of at least one kind of metal selected from the group consisting of Li, Na, K, Mg and Ca is bonded to said acidic group, inorganic fiber and pulp-shaped fiber. By the basic constitution as above, on one hand the moisture absorptive and desorptive properties inherent to the organic fine particles are efficiently utilized by suppressing the use of binder as much as possible, and on the other hand deformation or thermal shrinking of the paper due to swelling in water at the time of absorption etc. is able to be suppressed.Type: GrantFiled: November 29, 2004Date of Patent: August 16, 2011Assignee: Japan Exlan Company LimitedInventors: Ryosuke Nishida, Hideo Naka
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Patent number: 7998311Abstract: Size press compositions and methods for producing sized paper products, including liner board, are disclosed. The size press compositions contain at least one non-reactive cationic surface sizing agent, at least one reactive sizing agent, at least one promoter resin, at least one binder, and water. The at least one non-reactive cationic surface sizing agent may be a polymer in the form of a dispersion, an emulsion or a latex with a positive zeta potential below about pH 6. The at least one reactive sizing agent may be a dispersion, an emulsion or a latex including an alkyl ketene dimer or an alkyl succinic anhydride. The at least one promoter resin may be a polyaminoamide-epichlorohydrin resin or poly (dimethyldiallylammonium chloride).Type: GrantFiled: July 24, 2008Date of Patent: August 16, 2011Assignee: Hercules IncorporatedInventor: Daniel F. Varnell
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Patent number: 7988826Abstract: The invention improves a sizing effect even on paper containing no internal sizing agent and improves productivity by making solution polymerization in a small amount of an organic solvent. The invention provides a cationic surface sizing agent composed of a copolymer obtained by solution polymerization of (a) 15 to 35% by weight of a tertiary amino group-containing monomer, (b) 30 to 85% by weight of C1 to C4 alkyl(meth)acrylate, and (c) 1 to 50% by weight of styrenes in an organic solvent in the presence of a chain transfer agent. The copolymer may be subjected to cationization treatment with a quaternization agent. As a constituent monomer of the copolymer, 0 to 20% by weight of another copolymerizable vinyl monomer (d) may be contained. The cationic surface sizing agent is applied to paper.Type: GrantFiled: March 30, 2006Date of Patent: August 2, 2011Assignee: Harima Chemicals, Inc.Inventors: Kazushige Inaoka, Tomohiko Nakata, Yoshiharu Hashiguchi
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Patent number: 7981250Abstract: According to the present invention, a process is provided for making paper or board comprising forming a cellulosic suspension that may or may not comprise a filler, flocculating the cellulosic suspension, draining the cellulosic suspension on a screen to form a sheet, wherein the cellulosic suspension is flocculated using a flocculation system comprising the sequential or simultaneous addition of a siliceous material and an organic, cationic or anionic, dispersion micropolymer in a salt solution.Type: GrantFiled: September 14, 2006Date of Patent: July 19, 2011Assignee: Kemira OyjInventors: Marco Savio Polverari, Christopher Michael Lewis, Matthew Gerard Fabian, Sr.
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Patent number: 7972478Abstract: In a method of producing a sheet of paper and/or cardboard and similar products, prior to the formation of the sheet from a fibrous suspension, at least two dry strength agents are added to the suspension either separately in any order or mixed together and at one or more injection points, namely: a first agent corresponding to a product for Hofmann degradation in solution on a base (co)polymer comprising at least one non-ionic monomer which is selected from the group containing acrylamide and/or methacrylamide, N,N dimethylacrlamide and/or acrylonitrile; and a second agent corresponding to a (co)polymer having an anionic charge density greater than 0.1 meq/g. The Hofmann degradation product comprises an organic polymer produced at a concentration greater than 3.5% by weight, and preferably greater than 4.5% and the first and second agents are each introduced into the pulp suspension at a concentration of between 0.Type: GrantFiled: January 11, 2006Date of Patent: July 5, 2011Assignee: S.P.C.M. SAInventors: René Hund, Christian Jehn-Rendu, Fabrice Moretton
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Patent number: 7972475Abstract: The present invention provides a paper product having at least one ply, wherein only one outer surface of said tissue paper has a polyhydroxy compound and a lotion applied thereto.Type: GrantFiled: January 9, 2009Date of Patent: July 5, 2011Assignee: The Procter & Gamble CompanyInventors: Eric Chan, Brooke Marie Woods, LaTisha Evette Salaam
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Publication number: 20110146927Abstract: A solution with a salt-sensitive polymer binder for use in fibrous webs, where the binder contains a copolymer of carboxylic acid monomer units and ethylenically unsaturated monomer units. The binder solution is prepared by emulsion-polymerizing a copolymer and then neutralizing the copolymer with base to make it water soluble. The binders provide a higher wet strength in concentrated salt solutions than in deionized water, and are particularly suitable for strengthening nonwoven fibrous webs in disposable articles such as wet-wipes, personal care products, diapers, and the like.Type: ApplicationFiled: February 23, 2011Publication date: June 23, 2011Inventors: Rajeev Farwaha, Steven P. Pauls, SR., Pavneet S. Mumick, James L. Walker
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Publication number: 20110146928Abstract: The specification discloses papers suitable for liquid electrophotographic printing (“LEP”) and a method for making such papers. According to the method, a papermaking furnish containing cellulosic fibers is formed into a fibrous web on a papermaking machine and at least partially dried. The web is then treated with a sizing composition comprising starch, an acrylic acid polymer, an organic material having an HLB value of from about 2 to about 14 such as a polyglycerol ester, and water. The treated web is dried and calendered to a final desired caliper. Since the sizing composition is an aqueous mixture, it may be applied to the web on-line during production of the paper on the papermaking machine, thereby avoiding the expense and inconvenience of conventional off-line methods used to make existing LEP papers. The resulting paper exhibits at least 80% and preferably above 90% toner adhesion as measured by the tape pull tests used for the assessment of papers printed by LEP.Type: ApplicationFiled: November 9, 2010Publication date: June 23, 2011Applicant: INTERNATIONAL PAPER COMPANYInventors: YAN C. HUANG, David B. Shelmidine, Jeff R. Becker, Ernie L. Morgan