Polymerized Unsaturated Compound Patents (Class 162/168.1)
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Patent number: 6379499Abstract: The strength properties of paper are improved by treating the paper with a hydroxy-containing polymer, a multifunctional aldehyde and a catalyst. The multifunctional aldehyde is present at a concentration of about 50% to about 800% weight percent of the polymer, the catalyst is present at a weight ratio of between about 1:0.1 to about 1:2 multifunctional aldehyde:catalyst and the total weight of the polymer, aldehyde and catalyst is between about 0.1% to about 10% based on the dry weight of the paper.Type: GrantFiled: September 28, 2000Date of Patent: April 30, 2002Assignee: University of Georgia Research Foundation, Inc.Inventors: Charles Q. Yang, Guozhong Xu
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Publication number: 20020045722Abstract: Synthetic polymers having hydrogen bonding capability and one or more polysiloxane moieties are capable of providing two distinct properties to paper products, such as tissues, which properties heretofore have been imparted through the use of at least two different molecules. The backbone of these synthetic polymers is based on modified vinyl polymers, such as polyvinyl alcohol, polyacrylamides and polyacrylic acids.Type: ApplicationFiled: February 7, 2001Publication date: April 18, 2002Inventors: Wen Zyo Schroeder, Daniel Arthur Clarahan, Mike Thomas Goulet, Thomas Gerard Shannon
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Patent number: 6372088Abstract: A process is disclosed for the production of paper and paper-like products from a suspension of papermaking materials to which poly(ethylene oxide) and a phenolic type cofactor which may be produced by a Williamson synthesis from a resin, are added to improve the retention of fibers, of fines, of dispersed extractives and of fillers during the processes of water removal for the manufacturing of paper.Type: GrantFiled: March 15, 2000Date of Patent: April 16, 2002Assignee: Pulp and Paper Reserch Institute of CanadaInventors: Gunar V. Laivins, Marco Polverari
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Patent number: 6372806Abstract: Disclosed are stable, aqueous colloidal silicas having surface area of greater than 700 m2/g and S-values of from 20-50. These colloidal silicas do not require treatment with surface treatment agents such as aluminum to achieve stability. These colloidal silica aquasols can be produced and stored at concentrations of greater than 7 percent by weight SiO2 solids, and even as high as 15 percent by weight solids or higher, and remain stable at room temperature for at least 30 days compared to art-known silica aquasols. These colloidal silica sols demonstrate advantageously improved performance over art-known colloidal silica sots in applications such as in drainage and retention in papermaking processes. Also disclosed are processes for making aqueous colloidal silicas of the invention and the use of such colloidal silicas in papermaking processes.Type: GrantFiled: February 14, 2000Date of Patent: April 16, 2002Assignee: Nalco Chemical CompanyInventors: Bruce A. Keiser, Maureen B. Nunn, Cheng-Sung Huang, Dennis L. MacDonald
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Patent number: 6365001Abstract: A method for making a nonwoven reinforcing may for vinyl floor coverings is described. A base mat is formed from a mixture of glass fibers and polymeric binder fibers and/or powder, follows by treatment with a second water-based polymeric binder composition. The mat has been found to be highly satisfactory as a substrate for compressible vinyl floor covering.Type: GrantFiled: May 25, 2001Date of Patent: April 2, 2002Assignee: Owens Corning Fiberglas Technology, Inc.Inventors: Gregory S. Helwig, Hendrik Jongetjes, Paul Geel
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Patent number: 6361653Abstract: The invention comprises a borosilicate retention aid composition and a method for improving the production of paper by addition of the borosilicate. The borosilicate may be utilized in conjunction with a high molecular weight synthetic flocculent and/or starch, with or without the addition of a cationic coagulant. The borosilicate material is preferably a colloidal borosilicate. Methods for the preparation of the borosilicate material are disclosed.Type: GrantFiled: April 22, 2001Date of Patent: March 26, 2002Assignee: Nalco Chemical CompanyInventors: Bruce A. Keiser, James E. Whitten
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Patent number: 6361652Abstract: The invention comprises a borosilicate retention aid composition and a method for improving the production of paper by addition of the borosilicate. The borosilicate may be utilized in conjunction with a high molecular weight synthetic flocculant and/or starch, with or without the addition of a cationic coagulant. The borosilicate material is preferably a colloidal borosilicate. Methods for the preparation of the borosilicate material are disclosed.Type: GrantFiled: April 22, 2001Date of Patent: March 26, 2002Assignee: Nalco Chemical CompanyInventors: Bruce A. Keiser, James E. Whitten
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Patent number: 6358364Abstract: The invention comprises a borosilicate retention aid composition and a method for improving the production of paper by addition of the borosilicate. The borosilicate may be utilized in conjunction with a high molecular weight synthetic flocculant and/or starch, with or without the addition of a cationic coagulant. The borosilicate material is preferably a colloidal borosilicate. Methods for the preparation of the borosilicate material are disclosed.Type: GrantFiled: April 22, 2001Date of Patent: March 19, 2002Assignee: Nalco Chemical CompanyInventors: Bruce A. Keiser, James E. Whitten
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Patent number: 6355141Abstract: A process for the production of paper in which cellulosic fibers are treated with microparticles comprising shell-formed carbon allotrope particles, paper obtainable from this process, and a drainage and/or retention agent comprising at least partially hydrophilic, anionic microparticles comprising shell-formed carbon allotrope particles.Type: GrantFiled: April 23, 1999Date of Patent: March 12, 2002Assignee: Akzo Nobel N.V.Inventors: Rein Sikkar, Michael Persson, Maria Norell
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Patent number: 6346169Abstract: This invention is to provide a paper bulking promoter with which a highly bulky sheet can be obtained without impairing paper strength. Namely, this invention provides a process for producing a bulky paper, comprising the step of making paper from pulp in the presence of a bulking promoter comprising at least one compound selected from the group consisting of a cationic compound, an amine compound, an acid salt of an amine compound, an amphoteric compound, an amide compound, a quaternary ammonium salt, and an imidazoline derivative.Type: GrantFiled: December 31, 1998Date of Patent: February 12, 2002Assignee: Kao CorporationInventors: Yasushi Ikeda, Yoichi Ishibashi, Takaaki Tadokoro, Hiromichi Takahashi
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Publication number: 20020014318Abstract: A paper having an improved print quality comprises a paper substrate having a surface with a surface roughness of less than 6 microns and a surface gloss of 5-80% which surface has been coated with a light-weight, low solids content, top coat. The top coat may comprise (i) a rheology modifier/binder component and at least one pigment or (ii) at least one binder coated pigment. The top coat provides a significant improvement to the delta gloss of the so-treated paper.Type: ApplicationFiled: April 4, 2001Publication date: February 7, 2002Inventors: Barrett Richard Bobsein, James Tinney Brown, Zhenwen Fu, Janet Drobits Windisch
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Publication number: 20020004571Abstract: Synthetic polymers having moieties capable of covalent or hydrogen bonding to cellulose and one or more amphiphilic moieties are disclosed. These polymers are capable of providing two distinct properties to paper products, such as tissues, which properties heretofore have been imparted through the use of at least two different molecules. The backbone of these synthetic polymers is based on modified vinyl polymers, such as polyvinyl alcohol, polyacrylamides and polyacrylic acids.Type: ApplicationFiled: May 14, 2001Publication date: January 10, 2002Inventors: Wen Zyo Schroeder, Daniel Arthur Clarahan, Mike Thomas Goulet, Thomas Gerard Shannon
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Patent number: 6322665Abstract: Methods for making high wet performance webs. A polymeric anionic reactive compound is applied heterogenously to a cellulosic fibrous web followed by curing of the compound to crosslink the cellulose fibers. The resulting tissue has high wet resiliency, high wet strength, and a high wet:dry tensile strength ratio.Type: GrantFiled: October 25, 1999Date of Patent: November 27, 2001Assignee: Kimberly-Clark CorporationInventors: Tong Sun, Jeffrey D. Lindsay
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Patent number: 6319361Abstract: Paper products having high initial wet strengths are disclosed. The paper products comprise cellulosic fibers having free aldehyde groups, which fibers are combined with a water-soluble polymer having functional groups that are reacted with the aldehyde groups to form bonds joining the fibers. In a preferred embodiment, the cellulosic fibers contain a polysaccharide in which the hydroxyl groups of at least a portion of the repeating units of the polysaccharide are cis-hydroxyl groups, preferred repeating units being mannose and/or galactose. Similarly, the water-soluble polymer is preferably a polysaccharide in which the hydroxyl groups of at least a portion of the repeating units of the polysaccharide are cis-hydroxyl groups. Preferred polysaccharides are derived from one or more sugars selected from mannose, galactose, allose, altrose, gulose, talose and lyxose.Type: GrantFiled: May 12, 2000Date of Patent: November 20, 2001Assignee: The Procter & Gamble CompanyInventors: David Jay Smith, Michael Martyn Headlam
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Patent number: 6315867Abstract: A method of dispersing a solid particulate material in an aqueous medium by addition to the aqueous medium of a dispersing agent wherein the solid particulate material is to be used as a filler or pigment in a sheet material which is required to come into contact with foodstuffs, wherein the dispersing agent is a composition comprising: (1) up to 0.25% by weight, based on the dry weight of the particulate solid material, of a water-soluble salt of a poly(acrylic acid) having a weight average molecular weight not greater than 20,000, and (2) from 0.02% to 1.5% by weight, based on the dry weight of the particulate solid material, of either (a) an anionic polyelectrolyte which comprises a water-soluble salt of a copolymer of acrylic acid with acrylamide; or (b) a water-soluble condensed phosphate salt.Type: GrantFiled: October 30, 1997Date of Patent: November 13, 2001Assignee: Imerys Minerals LimitedInventors: David Robert Skuse, Shih-Ruey Thomas Chen, William Leonard Garforth, Gary F Matz
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Publication number: 20010036597Abstract: An interleaf sheet is formed by adding a sizing agent into a slurry of bleached kraft pulp or by applying a sizing agent onto a surface of the interleaf sheet which surface contacts a planographic printing plate. The sizing agent is used for the interleaf sheet so as to easily adjust the release properties of the interleaf sheet with respect to the surface (i.e., a water-soluble polymer layer) of the planographic printing plate and to suppress changes in the release properties with the passage of time.Type: ApplicationFiled: April 2, 2001Publication date: November 1, 2001Inventor: Takayuki Usui
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Patent number: 6306256Abstract: A method and an agent for improving the retention when dewatering a cellulosic fiber suspension are disclosed In the method, there is added to the suspension a retention agent containing a phenol-formaldehyde resin and a polyethylene oxide, and the method is characterised in that a modified phenol-formaldehyde resin containing cationic groups is added to the suspension. The modified phenol-formaldehyde resin preferably has a cationicity of about 5-85% and the cationic groups preferably consist of amine groups. The polyethylene oxide in the retention agent preferably has a molecular weight of about 0.5-20×106. The modified phenol-formaldehyde resin and the polyethylene oxide are preferably added to the suspension in a weight ratio of modified phenol-formaldehyde resin:polyethylene oxide of from 1:5 to 50:1, and the amount of polyethylene oxide added preferably is about 10-1000 ppm, based on tie dry solids content of the suspension.Type: GrantFiled: January 4, 2000Date of Patent: October 23, 2001Assignee: Kemira Kemi ABInventors: Bo Rosengren, Ulla Gytel
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Patent number: 6303002Abstract: Paper, board and cardboard are produced from paper stocks which contain tacky impurities by the addition of surfactants and cationic polymers having a charge density of at least 1.5 meq/g (measured at pH 7) and a molar mass Mw of the cationic polymers of at least 15,000 and drainage of the paper stocks with fixation of the tacky impurities in the paper produced.Type: GrantFiled: October 15, 1999Date of Patent: October 16, 2001Assignee: BASF AktiengesellschaftInventors: Friedrich Linhart, Jaroslav Melzer, Hubert Meixner
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Patent number: 6303001Abstract: Process for homogenizing the property cross direction profile of a continuous web made of paper or cardboard and a paper machine that is suitable for carrying out the above-mentioned process. The process is characterized in that the shrinkage cross direction profile of the material web is homogenized during its manufacturing process by controlling the local composition of the stock suspension sectionally across the width by changing the proportions of components that have different shrinkage behaviors. The paper machine includes an approach flow system having at least two regions that produce different stock suspensions with fiber mixtures that have different shrinkage behaviors. The stock suspension supplies from the approach flow system to the headbox have at least two branches for the at least two different stock suspensions. Near the headbox, a plurality of sectional mixing points are provided, which combine the stock suspensions that have different shrinkage behaviors.Type: GrantFiled: September 23, 1999Date of Patent: October 16, 2001Assignee: Voith Sulzer Papiertechnik Patent GmbHInventors: Udo Grossmann, Guenter Halmschlager, Erich Brunnauer, Alexander Wassermann, Eduard Bachler
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Patent number: 6296737Abstract: The invention relates to cellulose fluff pulp products that are debondable into fluff with markedly lower energy input, to a process for making the products, and to absorbent products using the fluff Most of the pulp products show no reduction in liquid absorbency rate from that of untreated fiber and significantly higher rates than pulps treated with the usual debonding agents. The products are made by adhering fine non-cellulosic particles to the fiber surfaces using a retention aid. The fiber is preferably treated with the retention aid in an aqueous suspension for a sufficient time so that the retention aid is substantively bonded with little or none left free in the water. The fine particulate additive is then added and becomes attached and uniformly distributed over the fiber surfaces with very little particle agglomeration occurring. The fiber is most usually not refined or only very lightly refined before sheeting.Type: GrantFiled: June 12, 2000Date of Patent: October 2, 2001Assignee: Weyerhaeuser CompanyInventors: Jian Wu, Hugh West, Terry M. Grant
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Process for reducing sticky contaminants in stock systems containing waste paper and in coated broke
Publication number: 20010023751Abstract: The invention relates to a process for reducing sticky contaminants in stock systems containing waste paper and in coated broke, and their reuse in the manufacture of papers. In this process, both polyvinyl alcohols and bentonite are added.Type: ApplicationFiled: January 19, 2001Publication date: September 27, 2001Inventors: Achim Kohler, Peter Hentzschel, Bernd Reinhardt -
Patent number: 6290813Abstract: A smooth-textured non-woven, superabsorbent particle-impregnated fibrous structure is disclosed. The web exhibits an improved smooth surface texture. The structure contains from 50% to 80% of ion sensitive SAP having a particle size of less than 200 microns, wood pulp fibers and cellulose acetate fibers, each in preferred specified amounts indicated herein. The superabsorbent, ion sensitive polymer particle-impregnated fibrous structure is made from an aqueous, wet-lay process in which an aqueous furnish comprises solids of fibers and superabsorbent, ion sensitive polymer and dissolved salt, such as preferably, Na2SO4. The furnish is passed over a moving foraminous support, such as a Fourdrinier wire, and a wet web structure is formed, followed by drying.Type: GrantFiled: October 8, 1999Date of Patent: September 18, 2001Assignee: BASF CorporationInventor: G. Thomas Woodrum
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Patent number: 6290815Abstract: The invention relates to a paper sheet containing grit particles giving it, in use, a high abrasion resistance. It is characterized in that it contains grit particles coated in a non-abrasive material, in particular in a polymer. According to the invention, the particles are chosen from alumina, silica, boron nitride, silicon carbide, titanium carbide, tungsten carbide, zirconium oxide, cerium oxide, glass and ceramic particles, or mixtures thereof. The invention also relates to the laminates containing it, as well as to the processes for manufacturing the sheets and the laminates.Type: GrantFiled: September 3, 1997Date of Patent: September 18, 2001Assignee: Arjo Wiggins S.A.Inventors: Henri Magnin, Claude Perrin, Pierre Caulet
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Patent number: 6287418Abstract: Synthetic polymers having moieties capable of covalent or hydrogen bonding to cellulose and one or more amphiphilic moieties are disclosed. These polymers are capable of providing two distinct properties to paper products, such as tissues, which properties heretofore have been imparted through the use of at least two different molecules. The backbone of these synthetic polymers is based on modified vinyl polymers, such as polyvinyl alcohol, polyacrylamides and polyacrylic acids.Type: GrantFiled: November 24, 1999Date of Patent: September 11, 2001Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Wen Zyo Schroeder, Daniel Arthur Clarahan, Mike Thomas Goulet, Thomas Gerard Shannon
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Patent number: 6287423Abstract: Novel polymers are provided having phosphonated and sulphonated substituent groups such that the polymers is multifunctional in its use. Optional amide substituents are used to reduce electrostatic charge density or for hydrogen bonding. An advantage of the polymer is the flexibility of using it for multiple purposes. A particular application is for bonding paper fillers and paper fiber together.Type: GrantFiled: April 6, 1999Date of Patent: September 11, 2001Assignee: Minerals Technologies Inc.Inventors: Donald Kendall Drummond, Patrick Clinton Wernett
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Patent number: 6270627Abstract: The invention comprises a borosilicate retention aid composition and a method for improving the production of paper by addition of the borosilicate. The borosilicate may be utilized in conjunction with a high molecular weight synthetic flocculant and/or starch, with or without the addition of a cationic coagulant. The borosilicate material is preferably a colloidal borosilicate. Methods for the preparation of the borosilicate material are disclosed.Type: GrantFiled: November 22, 1999Date of Patent: August 7, 2001Assignee: Nalco Chemical CompanyInventors: Bruce A. Keiser, James E. Whitten
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Patent number: 6267843Abstract: A method for making a nonwoven reinforcing may for vinyl floor coverings is described. A base mat is formed from a mixture of glass fibers and polymeric binder fibers and/or powder, follows by treatment with a second water-based polymeric binder composition. The mat has been found to be highly satisfactory as a substrate for compressible vinyl floor covering.Type: GrantFiled: December 16, 1998Date of Patent: July 31, 2001Assignee: Owens Corning Fiberglas Technology, Inc.Inventors: Gregory S. Helwig, Hendrik Jongetjes, Paul Geel
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Patent number: 6264791Abstract: Methods for making high wet performance webs. A polymeric anionic reactive compound is applied to a cellulosic fibrous web followed by flash curing of the compound to crosslink the cellulose fibers. The resulting tissue has high wet resiliency, high wet strength, and a high wet:dry tensile strength ratio.Type: GrantFiled: October 25, 1999Date of Patent: July 24, 2001Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Tong Sun, Jeffrey D. Lindsay
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Patent number: 6245874Abstract: A process for making paper with increased wet and dry strength by incorporating into the pulp suspension an ionic thermosettable resin which is the reaction product of dialdehyde and epihalohydrin, or epihalohydrin equivalent, with a copolymer containing monomer units derived by polymerization of monomers comprising acrylamide or alkyl-substituted acrylamide and diallylamine or an acid salt thereof. The paper has wet and dry strength greater than that of paper not containing the resin and has a higher repulpability index than wet strength paper that is essentially the same but contains conventional polyazetidinium ion containing wet strength resin instead of the ionic thermosettable resin.Type: GrantFiled: March 1, 2000Date of Patent: June 12, 2001Assignee: Hercules IncorporatedInventors: Ronald Richard Staib, Joseph Raymond Fanning, William Walter Maslanka
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Patent number: 6241780Abstract: This invention relates to a method for strengthening a cellulosic substrate by treating the substrate with a formaldehyde-free curable aqueous composition and curing the composition. The cellulosic substrates include, for example, paper oil- and air-filter stock, rayon nonwoven wipes, cellulosic laminating stock, cotton woven fabrics, and wood flakes suitable to be consolidated into flakeboard.Type: GrantFiled: February 27, 1995Date of Patent: June 5, 2001Assignee: Rohm and Haas CompanyInventors: Charles Thomas Arkens, Scott Lind Egolf, Robert David Gleim, Oscar Hsien-Hsiang Hsu, Kenneth John Wiesinger
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Patent number: 6238520Abstract: Starch is added to the thinstock in a papermaking process in the form of a coagulated slurry containing undissolved starch particles, cationic polymeric flocculant and anionic microparticulate network agglomeration aid, such as bentonite. The flocculant and agglomeration aid interact to give network flocculation in which the starch particles are trapped. Improved retention of the starch in the resulting paper is achieved.Type: GrantFiled: May 10, 1999Date of Patent: May 29, 2001Assignee: Ciba Specialty Chemicals Water Treatments LimitedInventor: Graham Greenwood
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Patent number: 6238521Abstract: A papermaking process consisting essentially of: forming an aqueous cellulosic papermaking slurry; adding to the slurry certain additives, with said certain additives selected from the group including: coagulants; sizing agents; and mineral fillers; draining the slurry to form a sheet; and drying the sheet to form a paper sheet; the improvement comprising adding to the slurry, prior to it being drained; an effective amount of a cationic dispersion polymer; which cationic dispersion polymer is a copolymer comprising about 30 mole % diallyldimethylammonium chloride (DADMAC) and about 70 mole % acrylamide (AcAm); and adding to the slurry, either before or after said cationic dispersion polymer is added and the slurry is drained, a microparticle selected from the group consisting of a) copolymers of acrylic acid and acrylamide; b) bentonite; and c) dispersed silica; with the proviso that said coagulant cannot be a cationic dispersion copolymer comprising about 30 mole % diallyldimethylammonium chlorideType: GrantFiled: May 21, 1999Date of Patent: May 29, 2001Assignee: Nalco Chemical CompanyInventors: Jane B. Wong Shing, Chidambaram Maltesh, Ramasubramanyam Nagarajan
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Patent number: 6235835Abstract: Starch is modified with at least one cationic polymer P) and the modified starch is prepared by a process in which a) an anionically modified starch A) is reacted with a cationic polymer P) or b) a natural starch B) or a starch C) which has not been anionically modified is reacted with the cationic polymer P) in the presence of an anionic modifier M) and the polymer-modified starch is used.Type: GrantFiled: July 14, 1999Date of Patent: May 22, 2001Assignee: BASF AktiengesellschaftInventors: Manfred Niessner, Claudia Nilz, Primoz Lorencak, Martin Rübenacker, Roland Ettl
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Patent number: 6235155Abstract: Condensation polymers, such as polyamide epichlorohydrin (PAE) resins, can be combined with polysiloxanes in a single molecule to provide several potential benefits, depending upon the specific combination employed, including: (a) wet strength resins that soften; (b) softeners that do not reduce dry or wet tensile strength; (c) wet strength with improved wet/dry tensile ratio; (d) softeners/debonders with reduced linting and sloughing; (e) wet strength aids with controlled absorbency rate; and (f) Yankee dryer additives that provide surface protection and adhesion with controlled release properties.Type: GrantFiled: January 20, 2000Date of Patent: May 22, 2001Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Wen Zyo Schroeder, Daniel Arthur Clarahan, Mike Thomas Goulet, Thomas Gerard Shannon
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Patent number: 6231659Abstract: The sizing agents are mixtures of alkenyl succinic anhydrides in which the alkenyl groups have in the range of about 6 to about 40 carbon atoms, and in which at least 97 wt % of the alkenyl groups are bifurcated on the alpha carbon atom into two branches neither of which has less than two carbon atoms. Other characteristics of the mixture are that (1) 20-50% of the bifurcated alkenyl groups have only one methyl or methylene substituent and no other side chain, and the remainder of such bifurcated groups have two straight chain branches (no side chain) emanating from the alpha carbon atom, (2) at least 3 alkenyl succinic anhydrides that differ in the number of alkenyl carbon atoms are each present in at least 5 wt % in the mixture, (3) no more than about 50 wt % of the alkenyl succinic anhydrides is any given alkenyl succinic anhydride or mixture of isomers having the same number of carbon atoms in their alkenyl groups, (4) the average number of carbon atoms in the alkenyl groups is ca.Type: GrantFiled: June 24, 1999Date of Patent: May 15, 2001Assignee: Albemarle CorporationInventors: Patrick C. Hu, Valerie N. LeGloahec, Michelle R. Free, Dixie E. Goins
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Patent number: 6228218Abstract: A water-disintegratable cleaning sheet consisting of a fibrous sheet having incorporated thereinto, a binder of alkylcellulose; an electrolyte, and (a) a copolymer of a polymerizable acid anhydride and other compounds and/or (b) an amino acid. The water-disintegratable cleaning sheet has excellent water disintegratability and wet strength and further it is not degraded in the water disintegratability and wet strength after storage at high temperatures.Type: GrantFiled: December 24, 1998Date of Patent: May 8, 2001Assignee: Uni-Charm CorporationInventors: Naohito Takeuchi, Takayoshi Konishi, Ryuichiro Kurata, Nobuo Morohashi, Masayoshi Matsumoto
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Patent number: 6228223Abstract: The present invention generally relates to an aqueous softening and antistatic agent composition comprising a quaternary ammounium compound and a biodegradable nonionic surfactant, which composition comprises a quaternary ammounium compound having the formula wherein R1 is a C6-C22 hydrocarbyl group; and X is halogen or SO42−, in a concentration of at least about 15% by weight. The surfactant is a linear alkoxylated fatty acid or a linear alkoxylated unsaturated alcohol. Furthermore a method for providing cellulosic materials with a reduced tendency to retain an electrostatic charge as well as providing said material with improved softness, wherein the cellulosic material is treated with said composition, and fluff obtainable from fluff pulp treated with the composition.Type: GrantFiled: July 30, 1998Date of Patent: May 8, 2001Assignee: Akzo Nobel NVInventors: Ingemar Thebrin, Lisbeth Ankarbratt
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Patent number: 6228217Abstract: This invention is directed to a process for preparing an aqueous papermaking suspension containing a polyelectrolyte complex comprising providing an aqueous suspension of pulp fibers containing a water-soluble cationic polymer and a water-soluble anionic polymer that are reactable in the aqueous suspension to form the polyelectrolyte complex, and a multivalent cation having at least a +3 charge, and forming the polyelectrolyte complex. It also includes the process wherein the aqueous suspension of pulp fibers contains surface active carboxyl compounds and water-soluble anionic compounds. It further includes the process wherein the aqueous papermaking suspension is sheeted and dried to obtain paper of improved strength.Type: GrantFiled: January 13, 1995Date of Patent: May 8, 2001Assignee: Hercules IncorporatedInventors: Jay A. Dickerson, Harry J. Goldy, Douglas C. Smith, Ronald R. Staib
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Patent number: 6225437Abstract: Provided are alkenyl and/or alkyl succinimides formed from at least one alkenyl or alkyl succinic anhydride and at least one aliphatic amine having one or two primary amino groups in the molecule. These succinimides are characterized in that each alkenyl or alkyl group thereof contains in the range of 16 to 30 carbon atoms. Such group is bifurcated on its alpha carbon atom into two branches neither of which contains less than 2 carbon atoms, one such branch being free of any side chain, and the other such branch either being free of any side chain or containing at most one methyl or methylene side chain. In addition the succinimide has a viscosity at 80° C. of less than about 100 centistokes. These succinimides are especially useful as internal and external sizing agents for paper and paper products.Type: GrantFiled: June 24, 1999Date of Patent: May 1, 2001Assignee: Albemarle CorporationInventors: Patrick C. Hu, Valerie N. LeGloahec
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Patent number: 6222006Abstract: An aqueous formulation of a high solid content fully functional thermosettable wet strength resin designed for use in the manufacture of paper products is disclosed. The wet strength resin is the product of reaction of an epihalohydrin and an end-capped polyaminamide polymer. The thermosetting wet strength resins are useful in the manufacture of improved absorbent paper products such as bathroom tissues, facial tissues, napkins, towels, and paperboard products such as dairy cartons and bag paper.Type: GrantFiled: August 5, 1998Date of Patent: April 24, 2001Assignee: Fort James CorporationInventors: Bruce Jerome Kokko, Elroy Wayne Post
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Patent number: 6207719Abstract: A continuous output system makes paper coating by combining an emulsifier with ASA particles having sizes in the low to sub-micron region. A turbine, pump, blender or other device exposes the ASA to a number of repeated episodes of high shear until the resulting ASA is in the form of particles having a mean average diameter in approximately the 1&mgr; range. A manifold provides the system piping in order to minimize the internal areas where ASA may build up. This manifold has a plurality of holes bored in a solid metal block so that each of the bores forms a short pipe which is only an inch or two in length in order to reduce the interior surface area of an ASA transport and conveyance system.Type: GrantFiled: August 19, 1998Date of Patent: March 27, 2001Inventor: Dennis G. Pardikes
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Patent number: 6200420Abstract: Anionic nanocomposites for use as retention and drainage aids in papermaking are prepared by adding an anionic polyelectrolyte to a sodium silicate solution and then combining the sodium silicate and polyelectrolyte solution with silicic acid.Type: GrantFiled: April 10, 2000Date of Patent: March 13, 2001Assignee: Nalco Chemical CompanyInventors: Arthur James Begala, Bruce A. Keiser
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Patent number: 6190502Abstract: A fibrous sheet coated with a water-soluble binder of polyvinyl alcohol is impregnated with an aqueous solution dissolved with water-soluble carboxylate, so as to produce a water-disintegratable fibrous sheet. Salting out of the polyvinyl alcohol with the carboxylate maintains wet strength of the water-disintegratable fibrous sheet even in a wet state, which is easily disintegrated when immersed in a large amount of water after use. Furthermore, it does not suffer from deterioration in water-disintegratability and wet strength if it is left at high temperatures, and is good in water-disintegratability in cold water.Type: GrantFiled: July 21, 1998Date of Patent: February 20, 2001Assignee: Uni-Charm CorporationInventors: Naohito Takeuchi, Takayoshi Konishi
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Patent number: 6187141Abstract: A water-disintegratable fibrous sheet having a layered structure comprising: (a) at least one first fiber web comprising pulp of conifer and pulp of hardwood; (b) at least one second fiber web comprising pulp of conifer, having a content of pulp of hardwood less than that in said first fiber web or containing no pulp of hardwood, said first and second fiber webs forming said layered structure; and (c) a water-insoluble or water-swellable binder being added to at least one of said first and second fiber webs. The fibrous sheet excellent in water-disintegratability and strength can be obtained.Type: GrantFiled: September 16, 1998Date of Patent: February 13, 2001Assignee: Uni-Charm CorporationInventors: Naohito Takeuchi, Takayoshi Konishi, Daisuke Yamada
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Patent number: 6171444Abstract: Compositions and methods are provided for the sizing of paper, to enhance the quality of images printed thereon. The novel sizing compositions contain as a sizing agent a mixture of a polyacid and a polybase. When applied to a paper substrate, such as in an internal or external sizing process, the sizing compositions result in a sized paper substrate that provides high quality printed images when printed with an ink containing a reactive dye having ionizable and/or nucleophilic groups capable of reacting with the sizing agent. Images printed on a paper substrate coated with the sizing compositions of the invention are bleed-resistant, water-resistant (e.g., water-fast), and/or are characterized by an enhanced chroma and hue.Type: GrantFiled: March 31, 1999Date of Patent: January 9, 2001Assignee: SRI InternationalInventor: Asutosh Nigam