Nitrogen Containing Compound Patents (Class 162/168.2)
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Patent number: 8449721Abstract: Aqueous slurries of finely divided fillers which are at least partly covered by anionic latices, the slurries being obtainable by treating aqueous slurries of finely divided fillers with at least one anionic latex which comprises, incorporated in the form of polymerized units, at least one monomer comprising phosphonic and/or phosphoric acid groups, preparation of the aqueous slurries and their use as an additive to the paper stock in the production of filler-containing paper, filler-containing cardboard or filler-containing board by draining the paper stock.Type: GrantFiled: June 30, 2009Date of Patent: May 28, 2013Assignee: BASF SEInventors: Juergen Schmidt-Thuemmes, Anton Esser, Joerg Nieberle
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Stable and aqueous compositions of polyvinylamines with cationic starch, and utility for papermaking
Patent number: 8444818Abstract: A stable aqueous composition comprising polyvinylamine and liquid cationic starch in a ratio of from 90 to 55 parts of polyvinylamine on active basis to 10 to 45 parts of liquid cationic starch on active basis is disclosed. The composition can be used in papermaking as a strength or as a drainage aid.Type: GrantFiled: April 7, 2011Date of Patent: May 21, 2013Assignee: Hercules IncorporatedInventors: Frank J. Sutman, Christopher P. Dilkus, Qu-Ming Gu -
Anionic functional promoter and charge control agent with improved wet to dry tensile strength ratio
Patent number: 8425724Abstract: The invention relates to a composition comprising (a) a functional promoter comprising a water-soluble anionic polymer having a molecular weight of at least about 50,000 daltons and a molecular weight charge index value of at least about 10,000; (b) a cationic surfactant component; such that when the composition treats a fibrous substrate, in conjunction with a cationic strength agent, the treated fibrous substrate exhibits (i) a ratio of wet tensile strength to dry tensile strength ranging from about 1:5 to about 1:2 and (ii) an increase in a ratio of wet tensile strength to dry tensile strength of at least about 10%, as compared to when the fibrous substrate is treated with the functional promoter and without a surfactant. The invention also relates to a paper product made with such a system, and method for imparting wet strength to a paper product with the functional promoter.Type: GrantFiled: October 18, 2011Date of Patent: April 23, 2013Assignee: Kemira OyjInventors: Michael Ryan, William Brevard -
Patent number: 8404084Abstract: A filler treatment process enhances the fixation of anionic latex on filler in a short time. Anionic polymer dispersions (latex) are added to papermaking filler slurries at ambient temperature and then mixed with water of temperature higher than the glass transition temperature (Tg) of the latex used. The anionic latexes applied by this process are totally and irreversibly fixed or bound onto the filler particles and the treated filler particle agglomerate to form an aggregated filler slurry which is stable over time. The latex-treated filler slurry can be added to papermaking furnishes at any point prior to the headbox of the paper machine or stored for later use. The latex-treated filler slurry improves filler retention, only slightly reduces sheet strength and improves sizing performance.Type: GrantFiled: August 30, 2011Date of Patent: March 26, 2013Assignee: FPInnovationsInventors: Makhlouf Laleg, Roderick Collins, Danielle Gagne, Steven Middleton
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Patent number: 8388809Abstract: The invention relates to thermally expandable thermoplastic microspheres comprising a polymer shell made from ethylenically unsaturated monomers encapsulating a propellant, said ethylenically unsaturated monomers comprising from 20 to 80 wt % of acrylonitrile, from 20 to 80 wt % of monomers selected from the group consisting of esters of acrylic acid, from 0 to 10 wt % of methacrylonitrile, from 0 to 40 wt % of monomers selected from the group consisting of esters of methacrylic acid, the total amount of acrylonitrile and esters of acrylic acid constituting from 50 to 100 wt % of said ethylenically unsaturated monomers, and said propellant comprising at least one of methane, ethane, propane, isobutane, n-butane and isopentane. The invention further relates to the production and use of the microspheres.Type: GrantFiled: February 9, 2007Date of Patent: March 5, 2013Assignee: Akzo Nobel N.V.Inventors: Ove Nordin, Heléne Ström, Christina Nyholm, Anna Kron
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Patent number: 8366879Abstract: A soil and/or moisture resistant secure document and a method for producing such a secure document, are provided. The inventive method preferably employs a size press or other similar device to force a soil and/or moisture resistant formulation into the pores of the substrate and to remove excess formulation from opposing surfaces thereof. Soil and/or moisture resistant formulations when applied this way instead of by way of standard coating techniques do not obscure optically variable effects generated by non-porous OVDs that may be employed on or within these secure documents. In addition, thin layers of fibers (e.g., papermaking fibers) overlying and thus embedding portions of security devices in windowed secure documents that have been rendered soil and/or moisture resistant in accordance with this invention demonstrate increased durability.Type: GrantFiled: September 24, 2007Date of Patent: February 5, 2013Assignee: Crane & Co., Inc.Inventors: Timothy T. Crane, Michael Darroch, Tod L. Niedeck, Marco Maraschi, Karin Morck-Hamilton
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Patent number: 8349134Abstract: The invention relates to a process for producing paper, board and cardboard of high dry strength by separately adding a polymer comprising vinylamine units and a polymeric anionic compound to a paper pulp, dewatering the pulp and drying the paper products, which comprises using as polymeric anionic compound at least one copolymer obtainable by copolymerizing (a) at least one N-vinylcarboxamide of the formula in which R1 and R2 are H or C1- to C6 alkyl, (b) at least one monoethylenically unsaturated monomer comprising acid groups, and/or the alkali metal, alkaline earth metal or ammonium salts thereof, and if appropriate (c) other monoethylenically unsaturated monomers, and if appropriate (d) compounds having at least two ethylenically unsaturated double bonds in their molecule.Type: GrantFiled: November 21, 2005Date of Patent: January 8, 2013Assignee: BASF SEInventors: Anton Esser, Hans-Joachim Haehnle, Martin Ruebenacker, Norbert Schall, Jacques Dupuis, Josef Neutzner, Manfred Niessner, Berthold Sturm
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Patent number: 8337665Abstract: A process for the production of paper, board and cardboard by draining a paper stock containing interfering substances in the presence of polymers which contain vinylamine units and which have an average molar mass Mw of at least 1 million, a high-consistency stock first being prepared, at least one polymer containing vinylamine units and having an average molar mass Mw of at least 1 million and a degree of hydrolysis of from 1 to 20 mol % being metered into the high-consistency stock, the high-consistency stock being diluted to a low-consistency stock by adding water, and the low-consistency stock being drained, and the use of hydrolyzed homo- or copolymers of N-vinylcarboxamides having a degree of hydrolysis of from 1 to 20 mol % and an average molar mass Mw of at least 1 million in the production of paper, board or cardboard as an additive to a high-consistency stock containing interfering substances, for reducing deposits in the wire part, press section and drying section of paper machines.Type: GrantFiled: March 14, 2005Date of Patent: December 25, 2012Assignee: BASF SEInventors: Anton Esser, Rainer Blum, Joachim Kuhn, Marc Leduc, Ralf Hemel
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Patent number: 8293073Abstract: This invention is method of creping a paper web comprising a) applying to a rotating creping cylinder an adhesive composition having a pH of about 6.5 to about 8 and comprising one or more vinylamine/N-vinyl formamide polymers composed of about 10 to about 99 mole percent vinylamine monomer and about 90 to about 1 mole percent N-vinylformamide monomer; b) pressing the paper web against the creping cylinder to effect adhesion of the paper web to the creping cylinder; and c) dislodging the paper web from the creping cylinder with a doctor blade.Type: GrantFiled: June 30, 2005Date of Patent: October 23, 2012Assignee: Nalco CompanyInventors: Vladimir A. Grigoriev, Gary S. Furman, Mingli Wei, Winston Su, Christopher D. Kaley
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Patent number: 8262859Abstract: The present invention is directed to compositions comprising a cellulose reactive functionalized polyvinylamine first adduct, compositions comprising combinations of the cellulose reactive functionalized polyvinylamine first adduct and cellulose reactive functionalized polyvinylamide second adduct, methods for preparing first adduct and second adduct blends and finally methods of increasing the wet or dry strength of paper by incorporation into the paper furnish or coating a paper or board with said adducts.Type: GrantFiled: October 31, 2008Date of Patent: September 11, 2012Assignee: BASF SEInventor: Matthew D. Wright
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Patent number: 8241462Abstract: To provide a papermaking internal sizing agent capable of efficiently imparting sizing performance even in neutral papermaking which uses calcium carbonate as filler, and uses no aluminum sulfate or uses a small amount of aluminum sulfate, and also provide a paper or a paperboard obtained by using the papermaking internal sizing agent. The papermaking internal sizing agent comprises as an effective ingredient an amphoteric copolymer having hydrophobic groups and cationic groups, at least a part of the cationic groups being quaternized. Preferably, the amphoteric copolymer is obtained by polymerizing monomer ingredients that it essentially contain a hydrophobic monomer (A), a cationic monomer (B), and an anionic monomer (C) and that an anion equivalent of the monomer (C) is 0.1 to 90% of a cation equivalent of the monomer (B), in which a rate of quaternizing of the cationic groups is not less than 40% by mole. The paper or the paperboard contains the above papermaking internal sizing agent.Type: GrantFiled: March 6, 2008Date of Patent: August 14, 2012Assignees: Harima Chemicals, Inc., Nippon Paper Industries Co., Ltd.Inventors: Kazunari Sakai, Takahiro Fujiwara, Kazushige Inaoka, Takashi Yamaguchi, Masaki Ito, Yasunobu Ooka
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Patent number: 8163134Abstract: Methods for making a heterogeneous polymer blend comprising one or more anionic polymers, one or more cationic polymers, and one or more non-ionic polymers, which method comprises (a) adding to a non-neutral solution a first amount of polymerization initiator and one or more anionic or cationic monomers, wherein each monomer has the same charge; (b) adding a second amount of the polymerization initiator and one or more non-ionic monomers; (c) adding a third amount of the polymerization initiator and one or more ionic monomers that are oppositely charged from the monomers of (a); adding stepwise, a fourth amount of the polymerization initiator to react any residual monomer, and (e) neutralizing the resulting polymer blend. Also claimed are heterogeneous polymer blends containing polymers formed from one or more anionic, cationic, and non-ionic monomers, either polymerized in situ or separately and then combined.Type: GrantFiled: September 18, 2009Date of Patent: April 24, 2012Assignees: Hercules Incorporated, Specialty Minerals (Michigan) Inc.Inventors: Frank J. Sutman, Joseph M. Mahoney, Robert Anthony Gill, Daniel Bruce Evans
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Patent number: 8123906Abstract: Compositions and methods of producing paper-based materials are disclosed. In general, the techniques utilize an amine-containing polymer, such as chitosan, to functionalize one or more components of a mixture used to form materials such as paper-based materials. Such components can include the fibers of a pulp and/or filler particles. In one instance, either the pulp or the filler particles are functionalized, but not both. Such functionalization can improve the qualifies of a paper-based material relative to when such functionalization is not utilized. Techniques and compositions are also described to further improve the qualities of a paper material by utilizing a complementary polymer which can couple with the amine-containing polymer.Type: GrantFiled: August 1, 2008Date of Patent: February 28, 2012Assignee: NanoPaper, LLCInventors: David S. Soane, Michael C. Berg, William A. Mowers
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Patent number: 8088252Abstract: A solution with a salt-sensitive polymer binder for use in fibrous webs, where the binder contains a copolymer comprising repeat units derived from butyl acrylate, methyl methacrylate and amino functionalized alkyl acrylate or methacrylate or amino functionalized alkyl acrylamide or methacrylamide optionally including monomers such as vinyl acetate and/or vinyl acetate/ethylene. The binder solution is prepared by emulsion-polymerizing a copolymer and then neutralizing the copolymer with acid to make it water soluble. The binders are particularly suitable for strengthening nonwoven fibrous webs in disposable articles such as wet-wipes, personal care products, diapers, and the like and retain their salt-sensitivity with or without divalent metal scavengers.Type: GrantFiled: March 2, 2009Date of Patent: January 3, 2012Inventors: Rajeev Farwaha, Philip Confalone
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Anionic functional promoter and charge control agent with improved wet to dry tensile strength ratio
Patent number: 8070914Abstract: The invention relates to a composition comprising (a) a functional promoter comprising a water-soluble anionic polymer having a molecular weight of at least about 50,000 daltons and a molecular weight charge index value of at least about 10,000; (b) a cationic surfactant component; such that when the composition treats a fibrous substrate, in conjunction with a cationic strength agent, the treated fibrous substrate exhibits (i) a ratio of wet tensile strength to dry tensile strength ranging from about 1:5 o to about 1:2 and (ii) an increase in a ratio of wet tensile strength to dry tensile strength of at least about 10%, as compared to when the fibrous substrate is treated with the functional promoter and without a surfactant. The invention also relates to a paper product made with such a system, and method for imparting wet strength to a paper product with the functional promoter.Type: GrantFiled: April 9, 2010Date of Patent: December 6, 2011Assignee: Kemira OyjInventors: Michael Ryan, William Brevard -
Patent number: 8038846Abstract: According to the present invention, a process is provided for making paper or board comprising forming a cellulosic suspension that may or may not comprise a filler, flocculating the cellulosic suspension, draining the cellulosic suspension on a screen to form a sheet, wherein the cellulosic suspension is flocculated using a flocculation system comprising the sequential or simultaneous addition of a siliceous material and an organic, cationic or anionic, water-in-water or dispersion micropolymer in a salt solution.Type: GrantFiled: September 14, 2007Date of Patent: October 18, 2011Assignee: Kemira OyjInventors: Marco Savio Polverari, Christopher Michael Lewis, Matthew Gerard Fabian
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Patent number: 8029647Abstract: Process for the production of paper, board and cardboard by draining a paper stock on a wire with sheet formation and drying of the sheets, the sheet formation being carried out in the absence of finely divided inorganic flocculants and (a) polymers comprising vinylamine units and/or polyvinylformamide having a molar mass Mw of, in each case, at least 1 million and (b) at least one cationic or nonionic polyacrylamide and/or one cationic or nonionic polymethacrylamide having a molar mass Mw of, in each case, at least 2.5 million being used as retention aids.Type: GrantFiled: September 8, 2005Date of Patent: October 4, 2011Assignee: BASF AktiengesellschaftInventors: Marc Leduc, Rainer Blum, Peter Leifert
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Patent number: 8025768Abstract: A continuous fiIter treatment process in which anionic polymer dispersions (latex) are added to common papermaking filler slurries ai ambient temperature and then mixed with water of temperature higher than the glass transition temperature (Tg) of the latex used. To efficiently fix the latex the temperature of the filler/latex mixture must be 30-60° C. higher than ihe Tg of the latex used. The chemical composition of the resin and the type of surfactant used during the emulsion polymerization process of the polymer latex dispersions are important factors for efficiently fixing the latex onto the filler by adding hot water and improving the properties of paper made with the treated filler. Enhanced fixation of anionic latex onto filler using hot water is done in mixing vessels that can control shear and mixing time. The anionic latexes are totally and irreversibly fixed or bound onto the filler particles and the aggregated filler slurry is stable over time.Type: GrantFiled: June 5, 2008Date of Patent: September 27, 2011Assignee: FpinnovationsInventors: Makhlouf Laleg, Roderick Collins, Danielle Gagne, Steven Middleton
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Patent number: 8025767Abstract: They are mixtures of (a) from 1 to 99.9% by weight of a water-soluble epihalohydrin-crosslinked polyamidoamine and (b) from 0.1 to 20% by weight of at least one other cationic polymer.Type: GrantFiled: July 7, 2008Date of Patent: September 27, 2011Assignee: BASF AktiengesellschaftInventors: Ellen Krueger, Martin Wendker, Stefan Frenzel, Claus Boettcher
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Patent number: 7998311Abstract: Size press compositions and methods for producing sized paper products, including liner board, are disclosed. The size press compositions contain at least one non-reactive cationic surface sizing agent, at least one reactive sizing agent, at least one promoter resin, at least one binder, and water. The at least one non-reactive cationic surface sizing agent may be a polymer in the form of a dispersion, an emulsion or a latex with a positive zeta potential below about pH 6. The at least one reactive sizing agent may be a dispersion, an emulsion or a latex including an alkyl ketene dimer or an alkyl succinic anhydride. The at least one promoter resin may be a polyaminoamide-epichlorohydrin resin or poly (dimethyldiallylammonium chloride).Type: GrantFiled: July 24, 2008Date of Patent: August 16, 2011Assignee: Hercules IncorporatedInventor: Daniel F. Varnell
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Patent number: 7988826Abstract: The invention improves a sizing effect even on paper containing no internal sizing agent and improves productivity by making solution polymerization in a small amount of an organic solvent. The invention provides a cationic surface sizing agent composed of a copolymer obtained by solution polymerization of (a) 15 to 35% by weight of a tertiary amino group-containing monomer, (b) 30 to 85% by weight of C1 to C4 alkyl(meth)acrylate, and (c) 1 to 50% by weight of styrenes in an organic solvent in the presence of a chain transfer agent. The copolymer may be subjected to cationization treatment with a quaternization agent. As a constituent monomer of the copolymer, 0 to 20% by weight of another copolymerizable vinyl monomer (d) may be contained. The cationic surface sizing agent is applied to paper.Type: GrantFiled: March 30, 2006Date of Patent: August 2, 2011Assignee: Harima Chemicals, Inc.Inventors: Kazushige Inaoka, Tomohiko Nakata, Yoshiharu Hashiguchi
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Patent number: 7981250Abstract: According to the present invention, a process is provided for making paper or board comprising forming a cellulosic suspension that may or may not comprise a filler, flocculating the cellulosic suspension, draining the cellulosic suspension on a screen to form a sheet, wherein the cellulosic suspension is flocculated using a flocculation system comprising the sequential or simultaneous addition of a siliceous material and an organic, cationic or anionic, dispersion micropolymer in a salt solution.Type: GrantFiled: September 14, 2006Date of Patent: July 19, 2011Assignee: Kemira OyjInventors: Marco Savio Polverari, Christopher Michael Lewis, Matthew Gerard Fabian, Sr.
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Patent number: 7972478Abstract: In a method of producing a sheet of paper and/or cardboard and similar products, prior to the formation of the sheet from a fibrous suspension, at least two dry strength agents are added to the suspension either separately in any order or mixed together and at one or more injection points, namely: a first agent corresponding to a product for Hofmann degradation in solution on a base (co)polymer comprising at least one non-ionic monomer which is selected from the group containing acrylamide and/or methacrylamide, N,N dimethylacrlamide and/or acrylonitrile; and a second agent corresponding to a (co)polymer having an anionic charge density greater than 0.1 meq/g. The Hofmann degradation product comprises an organic polymer produced at a concentration greater than 3.5% by weight, and preferably greater than 4.5% and the first and second agents are each introduced into the pulp suspension at a concentration of between 0.Type: GrantFiled: January 11, 2006Date of Patent: July 5, 2011Assignee: S.P.C.M. SAInventors: René Hund, Christian Jehn-Rendu, Fabrice Moretton
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Patent number: 7956096Abstract: The invention relates to thermally expandable thermoplastic microspheres comprising a polymer shell made from ethylenically unsaturated monomers encapsulating a propellant, said ethylenically unsaturated monomers comprising from 40 to 70 wt % of acrylonitrile, from 5 to 40 wt % of methacrylonitrile, from 10 to 50 wt % of monomers selected from the group consisting of esters of acrylic acid, esters of methacrylic acid and mixtures thereof, and said propellant comprising at least one of methane, ethane, propane, isobutane, n-butane and neo-pentane. The invention further relates to the production and use of the microspheres.Type: GrantFiled: February 9, 2007Date of Patent: June 7, 2011Assignee: Akzo Nobel N.V.Inventors: Ove Nordin, Heléne Ström, Christina Nyholm, Claes Hammer
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Patent number: 7922867Abstract: Process for the production of paper, board and cardboard having high dry strength by separate addition of a polymer comprising vinylamine units and of ligninsulfonic acid and/or a ligninsulfonate to a paper stock, draining of the paper stock and drying of the paper products.Type: GrantFiled: March 9, 2007Date of Patent: April 12, 2011Assignee: BASF SEInventors: Norbert Schall, Ellen Krueger, Martin Ruebenacker
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Patent number: 7918965Abstract: Process for the production of paper, board and cardboard by draining a paper stock with sheet formation in the presence of a retention aid system comprising (i) at least one polymer comprising vinylamine units, in the form of the free bases, of the salts and/or in quaternized form, as the sole cationic polymer, (ii) at least one linear, anionic polymer having a molar mass Mw of at least 1 million and/or at least one branched, anionic, water-soluble polymer and/or bentonite and/or silica gel and (iii) at least one particulate, anionic, crosslinked, organic polymer having a mean particle diameter of at least 1 ?m and an intrinsic viscosity of less than 3 dl/g, and use of the retention aid system comprising the components (i), (ii) and (iii) as an additive in the production of paper, board and cardboard.Type: GrantFiled: September 5, 2006Date of Patent: April 5, 2011Assignee: BASF AktiengesellschaftInventors: Marc Leduc, Oliver Koch, Simon Champ, Rainer Blum, Andreas Merkel, Knut Menke
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Publication number: 20110073265Abstract: The invention relates to a process for producing paper or board from an aqueous fibre suspension, which process includes the step of adding a process chemical to the aqueous fibre suspension, said process chemical being a polymer obtained by controlled radical polymerization technique from an ethylenically unsaturated monomer, a chain transfer agent, and an initiator in a liquid medium or by controlled photopolymerization technique from an ethylenically unsaturated monomer and a photoiniferter in a liquid medium. The process chemical improves the runnability and productivity of the paper or board machine.Type: ApplicationFiled: May 21, 2008Publication date: March 31, 2011Inventors: Rosa Carceller, Ari Juppo
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Patent number: 7883603Abstract: A method for making a sheet of paper and/or cardboard and the like, comprises, prior to forming said sheet, adding to the fibrous suspension, separately or mixed, in any sequence of introduction, into one or more injection points, at least three dry strength agents respectively: first agent corresponding to a (co)polymer having a cationic filler density higher than 1 meq/g and exhibiting primary amine functions; a second agent corresponding to a synthetic organic (co)polymer having cationic filler density higher than 0.1 meq/g; and a third agent corresponding to a (co)polymer having an anionic filler density higher than 0.1 meq/g.Type: GrantFiled: January 31, 2006Date of Patent: February 8, 2011Assignee: S.P.C.M. SAInventors: Rene Hund, Christian Jehn-Rendu, Fabrice Moretton
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Publication number: 20100236736Abstract: Finely divided, starch-containing polymer dispersions which are obtainable by free radical emulsion copolymerization of (a) from 25 to 50% by weight of at least one optionally substituted styrene, methyl methacrylate, acrylonitrile and/or methacrylonitrile, (b) from 1 to 49% by weight of at least one C1-C4-alkyl acrylate and/or one C2-C4-alkyl methacrylate, (c) from 1 to 49% by weight of at least one C5-C22-alkyl acrylate and/or one C5-C22-alkyl methacrylate and (d) from 0 to 10% by weight of at least one other ethylenically unsaturated copolymerizable monomer and (e) from 15 to 40% by weight of a degradable starch which has a molar mass Mw of from 1000 to 65 000 the sum (a)+(b)+(c)+(d)+(e) being 100% and being based on the total solids content, in the presence of redox initiators and at least 0.Type: ApplicationFiled: June 23, 2006Publication date: September 23, 2010Applicant: BASF AktiengesellschaftInventors: Andreas Brockmeyer, Hildegard Stein, Roland Ettl
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Patent number: 7794565Abstract: The present invention is a soft tissue sheet having reduced lint and slough. The tissue sheet comprises papermaking fibers and a synthetic co-copolymer. The synthetic co-polymer has the general structure: wherein R1, R2, R3 are independently selected from a group consisting of: H; C1-4 alkyl radicals; and, mixtures thereof; R4 is selected from a group consisting of C1-C8 alkyl radicals and mixtures thereof; Z1 is a bridging radical attaching the R4 functionality to the polymer backbone; and, Q1 is a functional group containing at least a cationic quaternary ammonium radical. w, x, y?1 and the mole ratio of x to (x+y) is about 0.5 or greater.Type: GrantFiled: April 4, 2008Date of Patent: September 14, 2010Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Thomas Gerard Shannon, Kelly Dean Branham, William Clayton Bunyard, Lisa Ann Flugge-Berendes
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Patent number: 7776181Abstract: A novel retention aid is provided, which can realizes not only high retention but also excellent paper formation and is easy to use, in various papermaking processes. A composition for improving retention is provided, which comprises (A) a cationic water-soluble polymer and (B) an amphoteric water-soluble polymer. The component (A) preferably is a copolymer having a cation equivalent of 0.05 to 4.00 meq/g or one having a 0.5% salted viscosity of 30 to 200 mPa·s. The component (B) preferably is either a copolymer comprising a cationic radical-polymerizable monomer unit, an anionic radical-polymerizable monomer unit, and a nonionic radical-polymerizable monomer unit, or an amphoteric water-soluble polymer obtained by polymerizing a cationic radical-polymerizable monomer with an anionic radical-polymerizable monomer in the presence of a polysaccharide.Type: GrantFiled: December 28, 2005Date of Patent: August 17, 2010Assignee: Toagosei Co., Ltd.Inventors: Yoshio Mori, Koichi Adachi, Ken Takeda, Tetsuya Tsuzuki
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Anionic functional promoter and charge control agent with improved wet to dry tensile strength ratio
Patent number: 7736465Abstract: The invention relates to a composition comprising (a) a functional promoter comprising a water-soluble anionic polymer having a molecular weight of at least about 50,000 daltons and a molecular weight charge index value of at least about 10,000; (b) a cationic surfactant component; such that when the composition treats a fibrous substrate, in conjunction with a cationic strength agent, the treated fibrous substrate exhibits (i) a ratio of wet tensile strength to dry tensile strength ranging from about 1:5 to about 1:2 and (ii) an increase in a ratio of wet tensile strength to dry tensile strength of at least about 10%, as compared to when the fibrous substrate is treated with the functional promoter and without a surfactant. The invention also relates to a paper product made with such a system, and method for imparting wet strength to a paper product with the functional promoter.Type: GrantFiled: February 6, 2004Date of Patent: June 15, 2010Assignee: Kemira OyjInventors: Michael Ryan, William Brevard -
Patent number: 7727359Abstract: A thermosetting resin comprising a reacted A) first partially crosslinked glyoxalated polymer comprising a reacted (i) first polyacrylamide backbone and (ii) a first glyoxal component; and B) a second crosslinked glyoxalated polymer comprising a reacted (i) second polyacrylamide backbone and (ii) a second glyoxyal component; such that the first polyacrylamide backbone has a molecular weight that is less than the molecular weight of the second polyacrylamide backbone; and the first polyacrylamide backbone and the second polyacrylamide backbone have a weight ratio ranging from 75:25 to 95:5. Methods for making and using the resin. Fibrous substrates made with the resin.Type: GrantFiled: July 27, 2009Date of Patent: June 1, 2010Assignee: Kemira OyjInventors: Robert Joseph Proverb, Lucyna M. Pawlowska
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Patent number: 7691231Abstract: Newsprint for offset printing having sufficient water absorption resistance to provide a clear printing image with less color registration problems upon offset printing is manufactured by coating base paper, to which aluminum sulfate (a 50% by weight Al2O3.14H2O product) is added at a ratio of less than 3.0% by weight upon paper making, with a surface treating agent mainly comprised of (A) a water-soluble macromolecular substance selected from starches, PVAs, polyacrylamides, and cellulose derivatives, (B) a copolymer obtained by the copolymerization of a styrene monomer and a cationic monomer, a water-soluble copolymer obtained by the copolymerization of a styrene monomer, a cat ionic monomer and a hydrophobic monomer, or a water-soluble copolymer obtained by treating one of these copolymers in which a tertiary amine-containing vinyl monomer is used as a cationic monomer, with a quaternizing agent.Type: GrantFiled: June 24, 2004Date of Patent: April 6, 2010Assignee: Nippon Paper Industries Co., Ltd.Inventors: Hiroshi Ono, Satoshi Ishioka, Fuminari Nonomura, Yasunori Nanri
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Patent number: 7682438Abstract: The present invention relates to a sizing composition that, when applied to paper substrate, creates a substrate, preferably suitable for inkjet printing, having increased print density, print sharpness, low HST, and/or image dry time, the substrate preferably having high brightness and reduced color-to-color bleed as well. In addition, the present invention relates to a method of reducing the HST of a paper substrate by applying the sizing composition to at least one surface thereof. Further, the application relates to methods of making and using the sizing composition, as well as methods of making and using the paper containing the sizing composition.Type: GrantFiled: November 1, 2006Date of Patent: March 23, 2010Assignee: International Paper CompanyInventors: Jay C Song, Sen Yang, Yan C Huang, Kapil M Singh, Michael Koenig, David B Shelmidine
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Patent number: 7678232Abstract: Synthetic co-polymers having moieties capable of forming hydrogen bonds, ionic bonds, or covalent bonds with cellulose fibers and paper modifying moieties capable of modifying a paper sheet are disclosed. These synthetic co-polymers are derived from the reaction of an aldehyde functional polymer and an aldehyde reactive paper modifying agent containing a non-hydroxyl aldehyde reactive functional group.Type: GrantFiled: June 14, 2007Date of Patent: March 16, 2010Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Thomas Gerard Shannon, Mike Thomas Goulet, Dana Stephanie Kass
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Patent number: 7678228Abstract: Topically-applied binder materials for imparting wet strength to soft, absorbent paper sheets, such as are useful as household paper towels and the like, include an azetidinium-reactive polymer, such as a carboxyl-functional polymer, an azetidinium-functional polymer and, optionally, a component useful for reducing sheet-to-sheet adhesion (blocking) in the product. These binder materials can be cured at ambient temperature over a period of days and do not impart objectionable odor to final product when wetted.Type: GrantFiled: September 17, 2007Date of Patent: March 16, 2010Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Mike Thomas Goulet, Tracy Ho Mathews, Stacey Lynn Pomeroy, Maurizio Tirimacco
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Patent number: 7670459Abstract: Fibrous products containing a durable softening agent are disclosed. The softening agent generally comprises a polysiloxane containing a plurality of first functional groups. In order to improve the wet retention of the softening agent on cellulosic fibers, the softening agent is reacted with a retention agent. The retention agent generally comprises a cationic polymer having a second functional group. In one embodiment, for instance, the softening agent contains epoxy groups or anhydride groups, while the retention agent contains amine groups. Products that may be made according to the present invention include tissue products, wipes and other absorbent articles.Type: GrantFiled: December 29, 2004Date of Patent: March 2, 2010Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Gil Bernard Didier Garnier, Michael Ralph Lostocco, Troy Michael Runge, Thomas Hampshire Schulz
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Patent number: 7641765Abstract: Paper coated with a coating slip containing at least one optical brightener is produced by a process in which base paper or precoated paper is treated, before application of the coating slip containing optical brightener, with at least one substance which enhances the efficiency of optical brighteners.Type: GrantFiled: August 7, 2002Date of Patent: January 5, 2010Assignee: BASF AktiengesellschaftInventors: Thierry Blum, Friedrich Linhart, Stephan Frenzel
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Publication number: 20090308553Abstract: The invention firstly discloses a new method for treating mineral materials, by means of an amphoteric polymer, to make said mineral materials effective as an agent for reducing the quantity of natural and organic colloids in the process of manufacturing a sheet of paper. A second object of the invention resides in the mineral materials thereby treated and obtained using the inventive method. The third, fourth, and fifth objects of the invention are the dry powders, aqueous suspensions, and granulated treated mineral materials obtained using the inventive method. A final object of the invention is the usage of said mineral materials treated using the inventive method as an agent for reducing the quantity of natural and organic colloids in the process for manufacturing sheets of paper.Type: ApplicationFiled: April 18, 2007Publication date: December 17, 2009Applicant: COATEX S.A.S.Inventors: Renaud Souzy, Christian Jacquemet, Jacques Mongoin
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Patent number: 7628888Abstract: A composition includes at least one hydrophilic polymer containing primary (—NH2) and/or secondary (—NHR) amine groups and at least one saccharide containing a reducible function. A method of increasing the strength of paper includes the step of contacting the paper with a composition comprising (i) at least one hydrophilic polymer containing at least two groups which are independently the same or different a primary amine group or a secondary amine group and at least one saccharide containing a reducible function. A hydrogel composition is formed from a mixture of at least one hydrophilic polymer containing at least two groups which are independently the same or different a primary amine group or a secondary amine group and at least one saccharide containing a reducible function.Type: GrantFiled: June 12, 2006Date of Patent: December 8, 2009Assignee: University of Pittsburgh—Of the Commonwealth System of Higher EducationInventors: Eric J. Beckman, W. Eamon Carroll, Toby Chapman, Kristen E. Minnich, Dennis Sagl, Richard J. Goddard
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Patent number: 7604713Abstract: The process for the production of crepe paper by adhesive bonding of a paper web with the aid of an adhesive comprising (i) polyethyleneimine having a molar mass Mw of from 50 000 to 2 million, (ii) reaction products of polyethyleneimine having a molar mass Mw of from 500 to 1 million with at least one C14- to C22-alkyldiketene, a monocarboxylic acid, an ester of a monocarboxylic acid or an acid chloride of a monocarboxylic acid and/or (iii) reaction products of polyalkylenepolyamines having a molar mass of from 300 to 1 million with at least one bischlorohydrogen ether or bisglycidyl ether of a polyalkylene glycol having a molecular weight MN of from 300 to 3000 to a creping cylinder, compression and removal of the crepe paper, as well as the use of the adhesives (i) to (iii) as creping assistants.Type: GrantFiled: May 19, 2005Date of Patent: October 20, 2009Assignee: BASF AktiengesellschaftInventors: Friedrich Linhart, Anton Esser, Detlef Kannengiesser
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Publication number: 20090065162Abstract: A method of preparing a stable dispersion of flocculated filler particles for use in papermaking processes comprises sequential addition of high and low molecular weight flocculating agents to an aqueous dispersion of filler particles followed by shearing of the resultant filler flocs to the desired particle size resulting in shear resistant filler flocs with a defined and controllable size distribution.Type: ApplicationFiled: September 12, 2007Publication date: March 12, 2009Inventors: Weiguo Cheng, Ross T. Gray
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Patent number: 7488402Abstract: The invention related to process for the production of paper from an aqueous suspension containing cellulosic fibers, and optional fillers, which comprises adding to the suspension (i) a cationic vinyl addition polymer prepared by polymerizing one or more ethylenically unsaturated monomers comprising a cationic monomer; (ii) an anionic polymer having one or more aromatic groups selected from the group consisting of polymers obtained by condensation of formaldehyde with benzene-based and naphthalene-based compounds, polyurethanes, polysaccharides, and lignin-based polymers; wherein (i) and (ii) are separately added to the suspension; and (iii) a low molecular weight cationic organic polymer having a molecular weight in the range of from 2,000 to about 700,000; or an anionic microparticulate material; and forming and draining the obtained suspension on a wire.Type: GrantFiled: June 10, 2005Date of Patent: February 10, 2009Assignee: Akzo Nobel N.V.Inventors: Sten Frölich, Fredrik Solhage, Erik Lindgren, Hans E. Johansson-Vestin
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Publication number: 20080302498Abstract: Synthetic co-polymers having moieties capable of forming hydrogen bonds, ionic bonds, or covalent bonds with cellulose fibers and paper modifying moieties capable of modifying a paper sheet are disclosed. These synthetic co-polymers are derived from the reaction of an aldehyde functional polymer and an aldehyde reactive paper modifying agent containing a non-hydroxyl aldehyde reactive functional group.Type: ApplicationFiled: June 14, 2007Publication date: December 11, 2008Inventors: Thomas Gerard Shannon, Mike Thomas Goulet, Dana Stephanie Kass
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Patent number: 7442280Abstract: A process for the production of paper from a suspension containing cellulosic fibers, and optional fillers, which comprises adding to the suspension a drainage and retention aid comprising a cationic organic polymer, forming and dewatering the suspension on a wire, wherein the cationic organic polymer has an aromatic group and the suspension which is dewatered on the wire has a conductivity of at least 2.0 mS/cm.Type: GrantFiled: October 18, 2000Date of Patent: October 28, 2008Assignee: Akzo Nobel NVInventors: Bore Klemets, Hans Hallstrom, Anna Asplund, Rein Sikkar
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Patent number: 7432309Abstract: Disclosed is a composition suitable for atomizing without excessive aerosolization in the form of an oil-in-water emulsion comprising: a) a continuous aqueous phase, and b) a discontinuous oil phase wherein the rheology of the aqueous phase is modified by the addition of a water-in-oil emulsion comprising: i) a high molecular weight polymer in a discontinuous aqueous phase, and ii) a continuous organic solvent phase. Preferred embodiments of the present invention relate to compositions for softening an absorbent paper tissue comprising a) a quaternary ammonium softening active ingredient; b) an electrolyte; c) a high molecular weight polymer emulsion comprising: i) from about 20% to about 40% by weight of the premix of a high molecular weight polymer; ii) from about 40% to about 60% of water; and iii) from about 20% to about 40% of an organic solvent; and d) a vehicle in which said softening active ingredient is dispersed.Type: GrantFiled: October 17, 2003Date of Patent: October 7, 2008Assignee: The Procter & Gamble CompanyInventor: Kenneth Douglas Vinson
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Publication number: 20080190574Abstract: A method of manufacturing a cellulosic sheet having at least one of hydrophobic and oleophobic properties comprises the steps of depositing a stock of cellulosic fibres onto at least one forming fabric at an impingement zone and forming a web therefrom in a formation process; combining a water-based composition comprising an adhesion promoter, an organic nanoparticulate polymer and a fluorocarbon with the web at a preselected combination stage prior to a heating stage at which the web is subjected to a temperature exceeding 60° C.; and heat-curing the composition with the web during a drying process. A water-based composition for imparting at least one of hydrophobic and oleophobic properties to a cellulosic sheet during manufacture comprises an adhesion promoter, an organic nanoparticulate polymer and a fluorocarbon. A cellulosic sheet or layer thereof has at least one of hydrophobic and oleophobic properties. Improved resistance of cellulosic sheets to oil or water is obtained.Type: ApplicationFiled: July 4, 2006Publication date: August 14, 2008Applicant: ASTENJOHNSON, INC.Inventors: Samuel Baker, Graham Jackson, Dietmar Wirtz
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Publication number: 20080185114Abstract: The present invention is a soft tissue sheet having reduced lint and slough. The tissue sheet comprises papermaking fibers and a synthetic co-copolymer. The synthetic co-polymer has the general structure: wherein R1, R2, R3 are independently selected from a group consisting of: H; C1-4 alkyl radicals; and, mixtures thereof; R4 is selected from a group consisting of C1-C8 alkyl radicals and mixtures thereof; Z1 is a bridging radical attaching the R4 functionality to the polymer backbone; and, Q1 is a functional group containing at least a cationic quaternary ammonium radical. w, x, y?1 and the mole ratio of x to (x+y) is about 0.5 or greater.Type: ApplicationFiled: April 4, 2008Publication date: August 7, 2008Applicant: Kimberly-Clark Worldwide, Inc.Inventors: Thomas Gerard Shannon, Kelly Dean Branham, William Clayton Bunyard, Lisa Ann Flugge
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Patent number: RE42110Abstract: A method and composition are disclosed for providing a two-part polymer binder additive for a fibrous sheet for improving both its strength and durability. The two-part polymer binder may be added to augment organic binders to increase board strength and durability or to reduce the amount of organic binder required. The polymers may also be added in place of conventional organic binders or added in addition to organic binders to improve sag resistance and fibrous sheet performance.Type: GrantFiled: June 29, 2006Date of Patent: February 8, 2011Assignee: AWI Licensing CompanyInventors: Kenneth P. Kehrer, Sheldon M. Atlas, Helen Atlas, Victor A. Kabanov, Alexander Kabanov, Alexander Zezin, Valentine Rogachova