Acrylamide Containing Patents (Class 162/168.3)
  • Patent number: 8152962
    Abstract: A process for producing paper of high basis weight by draining a paper pulp on a wire in the presence of a combination of at least two polymers as a retention and drainage aid system, forming sheets, and drying the sheets, which comprises forming the sheets in the absence of finely divided inorganic flocculants and using as retention and drainage aids (a) at least one amino-containing polymer and (b) at least one branched cationic polyacrylamide.
    Type: Grant
    Filed: December 1, 2005
    Date of Patent: April 10, 2012
    Assignee: BASF Aktiengesellschaft
    Inventors: Oliver Koch, Rainer Blum, Ron Van Dijk
  • Patent number: 8123906
    Abstract: Compositions and methods of producing paper-based materials are disclosed. In general, the techniques utilize an amine-containing polymer, such as chitosan, to functionalize one or more components of a mixture used to form materials such as paper-based materials. Such components can include the fibers of a pulp and/or filler particles. In one instance, either the pulp or the filler particles are functionalized, but not both. Such functionalization can improve the qualifies of a paper-based material relative to when such functionalization is not utilized. Techniques and compositions are also described to further improve the qualities of a paper material by utilizing a complementary polymer which can couple with the amine-containing polymer.
    Type: Grant
    Filed: August 1, 2008
    Date of Patent: February 28, 2012
    Assignee: NanoPaper, LLC
    Inventors: David S. Soane, Michael C. Berg, William A. Mowers
  • Patent number: 8088252
    Abstract: A solution with a salt-sensitive polymer binder for use in fibrous webs, where the binder contains a copolymer comprising repeat units derived from butyl acrylate, methyl methacrylate and amino functionalized alkyl acrylate or methacrylate or amino functionalized alkyl acrylamide or methacrylamide optionally including monomers such as vinyl acetate and/or vinyl acetate/ethylene. The binder solution is prepared by emulsion-polymerizing a copolymer and then neutralizing the copolymer with acid to make it water soluble. The binders are particularly suitable for strengthening nonwoven fibrous webs in disposable articles such as wet-wipes, personal care products, diapers, and the like and retain their salt-sensitivity with or without divalent metal scavengers.
    Type: Grant
    Filed: March 2, 2009
    Date of Patent: January 3, 2012
    Inventors: Rajeev Farwaha, Philip Confalone
  • Patent number: 8070914
    Abstract: The invention relates to a composition comprising (a) a functional promoter comprising a water-soluble anionic polymer having a molecular weight of at least about 50,000 daltons and a molecular weight charge index value of at least about 10,000; (b) a cationic surfactant component; such that when the composition treats a fibrous substrate, in conjunction with a cationic strength agent, the treated fibrous substrate exhibits (i) a ratio of wet tensile strength to dry tensile strength ranging from about 1:5 o to about 1:2 and (ii) an increase in a ratio of wet tensile strength to dry tensile strength of at least about 10%, as compared to when the fibrous substrate is treated with the functional promoter and without a surfactant. The invention also relates to a paper product made with such a system, and method for imparting wet strength to a paper product with the functional promoter.
    Type: Grant
    Filed: April 9, 2010
    Date of Patent: December 6, 2011
    Assignee: Kemira Oyj
    Inventors: Michael Ryan, William Brevard
  • Patent number: 8066847
    Abstract: A composition comprising one or more polyaminoaminde epihalohydrin resins and one or more polyamides in a ratio of about 1:99 to about 99:1 based on polymer actives and use of the composition for creping paper webs.
    Type: Grant
    Filed: December 29, 2005
    Date of Patent: November 29, 2011
    Assignee: Nalco Corporation
    Inventors: Vladimir A. Grigoriev, Gary S. Furman, Sammy Lee Archer, Winston Su, Christopher D. Kaley, Mingli Wei
  • Patent number: 8048267
    Abstract: The present invention relates to a sizing or coating composition that, when applied to paper substrate, creates a substrate having improved waterfastness, surface strength, and surface strength as measured by resistance to abrasion. In addition, the present invention relates to paper substrates containing the composition, as well as methods of using and making the paper substrate and composition.
    Type: Grant
    Filed: May 21, 2008
    Date of Patent: November 1, 2011
    Assignee: International Paper Company
    Inventors: Michael F Koenig, Kapil M Singh
  • Patent number: 8038846
    Abstract: According to the present invention, a process is provided for making paper or board comprising forming a cellulosic suspension that may or may not comprise a filler, flocculating the cellulosic suspension, draining the cellulosic suspension on a screen to form a sheet, wherein the cellulosic suspension is flocculated using a flocculation system comprising the sequential or simultaneous addition of a siliceous material and an organic, cationic or anionic, water-in-water or dispersion micropolymer in a salt solution.
    Type: Grant
    Filed: September 14, 2007
    Date of Patent: October 18, 2011
    Assignee: Kemira Oyj
    Inventors: Marco Savio Polverari, Christopher Michael Lewis, Matthew Gerard Fabian
  • Patent number: 8029647
    Abstract: Process for the production of paper, board and cardboard by draining a paper stock on a wire with sheet formation and drying of the sheets, the sheet formation being carried out in the absence of finely divided inorganic flocculants and (a) polymers comprising vinylamine units and/or polyvinylformamide having a molar mass Mw of, in each case, at least 1 million and (b) at least one cationic or nonionic polyacrylamide and/or one cationic or nonionic polymethacrylamide having a molar mass Mw of, in each case, at least 2.5 million being used as retention aids.
    Type: Grant
    Filed: September 8, 2005
    Date of Patent: October 4, 2011
    Assignee: BASF Aktiengesellschaft
    Inventors: Marc Leduc, Rainer Blum, Peter Leifert
  • Publication number: 20110226432
    Abstract: A method of mixing at least two chemicals or additives into a process liquid flow flowing in a process liquid flow duct including: feeding a liquid jet to the process liquid flow in the process liquid flow duct, wherein the liquid jet is formed in a feeding device and the liquid jet flows in a transverse direction to a flow direction of the process liquid flow through the process liquid flow duct; mixing the at least two chemicals or additives together to form a mixture; feeding the mixture of the at least two chemicals or additives into the process liquid flow duct with the feeding liquid jet, and mixing the at least two chemicals or additives with the feeding liquid jet in the process liquid flow duct.
    Type: Application
    Filed: May 16, 2011
    Publication date: September 22, 2011
    Applicant: WETEND TECHNOLOGIES OY
    Inventor: Jouni MATULA
  • Patent number: 7981250
    Abstract: According to the present invention, a process is provided for making paper or board comprising forming a cellulosic suspension that may or may not comprise a filler, flocculating the cellulosic suspension, draining the cellulosic suspension on a screen to form a sheet, wherein the cellulosic suspension is flocculated using a flocculation system comprising the sequential or simultaneous addition of a siliceous material and an organic, cationic or anionic, dispersion micropolymer in a salt solution.
    Type: Grant
    Filed: September 14, 2006
    Date of Patent: July 19, 2011
    Assignee: Kemira Oyj
    Inventors: Marco Savio Polverari, Christopher Michael Lewis, Matthew Gerard Fabian, Sr.
  • Patent number: 7972478
    Abstract: In a method of producing a sheet of paper and/or cardboard and similar products, prior to the formation of the sheet from a fibrous suspension, at least two dry strength agents are added to the suspension either separately in any order or mixed together and at one or more injection points, namely: a first agent corresponding to a product for Hofmann degradation in solution on a base (co)polymer comprising at least one non-ionic monomer which is selected from the group containing acrylamide and/or methacrylamide, N,N dimethylacrlamide and/or acrylonitrile; and a second agent corresponding to a (co)polymer having an anionic charge density greater than 0.1 meq/g. The Hofmann degradation product comprises an organic polymer produced at a concentration greater than 3.5% by weight, and preferably greater than 4.5% and the first and second agents are each introduced into the pulp suspension at a concentration of between 0.
    Type: Grant
    Filed: January 11, 2006
    Date of Patent: July 5, 2011
    Assignee: S.P.C.M. SA
    Inventors: René Hund, Christian Jehn-Rendu, Fabrice Moretton
  • Patent number: 7967953
    Abstract: This invention relates to a paper substrate containing high surface sizing and low internal sizing and having high dimensional stability, as well as methods of making and using the composition.
    Type: Grant
    Filed: May 5, 2010
    Date of Patent: June 28, 2011
    Assignee: International Paper Company
    Inventors: Kapil M. Singh, Dennis W. Anderson, Peter M. Froass, Yaoliang Hong, Krishna Kosaraju Mohan, Thomas R. Arnson, Yan C. Huang
  • Patent number: 7955473
    Abstract: The present invention relates to a process for producing paper which comprises: (vii) providing an aqueous suspension comprising cellulosic fibres, (viii) adding to the suspension after all points of high shear: a first polymer being a cationic polymer having a charge density above 2.5 meq/g; a second polymer; and a third polymer being an organic or inorganic anionic polymer; and (ix) dewatering the obtained suspension to form paper.
    Type: Grant
    Filed: December 14, 2005
    Date of Patent: June 7, 2011
    Assignee: Akzo Nobel N.V.
    Inventors: Fredrik Solhage, Joakim Carlén, Birgitta Johansson
  • Patent number: 7918965
    Abstract: Process for the production of paper, board and cardboard by draining a paper stock with sheet formation in the presence of a retention aid system comprising (i) at least one polymer comprising vinylamine units, in the form of the free bases, of the salts and/or in quaternized form, as the sole cationic polymer, (ii) at least one linear, anionic polymer having a molar mass Mw of at least 1 million and/or at least one branched, anionic, water-soluble polymer and/or bentonite and/or silica gel and (iii) at least one particulate, anionic, crosslinked, organic polymer having a mean particle diameter of at least 1 ?m and an intrinsic viscosity of less than 3 dl/g, and use of the retention aid system comprising the components (i), (ii) and (iii) as an additive in the production of paper, board and cardboard.
    Type: Grant
    Filed: September 5, 2006
    Date of Patent: April 5, 2011
    Assignee: BASF Aktiengesellschaft
    Inventors: Marc Leduc, Oliver Koch, Simon Champ, Rainer Blum, Andreas Merkel, Knut Menke
  • Publication number: 20110073265
    Abstract: The invention relates to a process for producing paper or board from an aqueous fibre suspension, which process includes the step of adding a process chemical to the aqueous fibre suspension, said process chemical being a polymer obtained by controlled radical polymerization technique from an ethylenically unsaturated monomer, a chain transfer agent, and an initiator in a liquid medium or by controlled photopolymerization technique from an ethylenically unsaturated monomer and a photoiniferter in a liquid medium. The process chemical improves the runnability and productivity of the paper or board machine.
    Type: Application
    Filed: May 21, 2008
    Publication date: March 31, 2011
    Inventors: Rosa Carceller, Ari Juppo
  • Patent number: 7901543
    Abstract: A composition for enhancing the dewatering of a paper sheet on a paper machine and a method for using the composition is disclosed. The composition comprising one or more aldehyde-functionalized polymers comprising amino or amido groups wherein at least about 15 mole percent of the amino or amido groups are functionalized by reacting with one or more aldehydes and wherein the aldehyde functionalized polymers have a molecular weight of at least about 100,000. The method comprising adding the composition to the paper machine at a dosage of about 0.05 lb/ton to about 15 lb/ton, based on dry fiber.
    Type: Grant
    Filed: December 14, 2009
    Date of Patent: March 8, 2011
    Assignee: Nalco Company
    Inventors: Michael R. St. John, Angela P. Zagala
  • Patent number: 7897013
    Abstract: Compositions comprising a blend of two or more paper strengthening agents have improved stability compared with previously known paper strengthening agents. One component is a polymeric paper strengthening agent, preferably a wet strengthening agent. The other component is a stabilized polyacrylamide prepared by (1) reacting a first portion of glyoxal with a polyacrylamide having pendant amide groups to form a first reaction mixture comprising polyacrylamide; (2) adding an acid to the first reaction mixture to form a second reaction mixture having a reduced pH and comprising the polyacrylamide; and (3) adding a second portion of glyoxal to the second reaction mixture to form the stabilized polyacrylamide. If desired, an aldehyde scavenger can be included in one or more of step (1), step (2), step (3), or the stabilized polyacrylamide. Such compositions can be used to enhance the strength of paper, particularly the wet strength of paper.
    Type: Grant
    Filed: November 21, 2008
    Date of Patent: March 1, 2011
    Assignee: Georgia-Pacific Chemicals LLC
    Inventors: Cornel Hagiopol, Yuping Luo, David F. Townsend, James W. Johnston, Clay E. Ringold, Karla D. Favors
  • Patent number: 7883603
    Abstract: A method for making a sheet of paper and/or cardboard and the like, comprises, prior to forming said sheet, adding to the fibrous suspension, separately or mixed, in any sequence of introduction, into one or more injection points, at least three dry strength agents respectively: first agent corresponding to a (co)polymer having a cationic filler density higher than 1 meq/g and exhibiting primary amine functions; a second agent corresponding to a synthetic organic (co)polymer having cationic filler density higher than 0.1 meq/g; and a third agent corresponding to a (co)polymer having an anionic filler density higher than 0.1 meq/g.
    Type: Grant
    Filed: January 31, 2006
    Date of Patent: February 8, 2011
    Assignee: S.P.C.M. SA
    Inventors: Rene Hund, Christian Jehn-Rendu, Fabrice Moretton
  • Patent number: 7842162
    Abstract: A method is provided for manufacturing paper by means of layer-by-layer nanocoating techniques. The method comprises the sequential processing of an aqueous pulp of lignocellulose fibers which is first subjected to nanocoating by alternatively adsorbing onto the fibers multiple consecutively-applied layers of oppositely-charged nanoparticles, polymers and/or proteins thereby making a modified aqueous pulp of multi-layer nanocoated lignocellulose fibers, then draining the water out of the modified pulp to form sheets of multi-layer nanocoated fibers, and drying the formed sheets of multi-layer nanocoated fibers. The resulting dried sheets are then processed to make a finished paper that has superior physical strength and improved surface properties.
    Type: Grant
    Filed: March 11, 2006
    Date of Patent: November 30, 2010
    Assignee: Louisiana Tech University Foundation, Inc.
    Inventors: Yuri M. Lvov, George Grozdits
  • Publication number: 20100288457
    Abstract: The present invention provides a process for preparing a paper or paper board of improved strength which comprises the steps of i) providing a cellulosic thick stock, ii) diluting the thick stock of step i) to form a thin stock, iii) draining the thin stock of step ii) on a wire to form a web, and iv) drying the web of step iii) to form paper or paper board, wherein the cellulosic thick stock of step (i) comprises organic polymeric microparticles, as well as paper obtainable by above process.
    Type: Application
    Filed: October 15, 2007
    Publication date: November 18, 2010
    Inventors: Suleman Buwono, Gary Reddihough, Jozef Maria Leonardus Dogge
  • Patent number: 7828934
    Abstract: This invention relates to resins useful for imparting strength to paper, the process of incorporating these resins into paper and the paper produced containing the resins. In particular the invention relates to resins useful for imparting dry-strength and wet-strength to paper under conditions of high sulfite ion concentrations.
    Type: Grant
    Filed: December 15, 2005
    Date of Patent: November 9, 2010
    Assignee: Hercules Incorporated
    Inventors: Shane Cyr, Henk Bakker, Willem Marinus Stevels, Ronald Richard Staib
  • Patent number: 7815771
    Abstract: A process for the manufacture of paper, board or similar products, comprises first of all, adding, to the paper pulp fibrous suspension, at least one main retention aid composed of a cationic (co)polymer. Then optionally the flocs obtained are sheared. Subsequently there is added to the suspension, separately or as a mixture, in any order: at least one secondary retention aid chosen from the group consisting of silica derivatives and anionic or amphoteric organic polymers, and at least one tertiary retention aid composed of a crosslinked anionic organic polymer with a size of greater than or equal to 1 micrometer and exhibiting an intrinsic viscosity of less than 3 dl/g.
    Type: Grant
    Filed: November 8, 2004
    Date of Patent: October 19, 2010
    Assignee: SNF S.A.S.
    Inventors: Gatien Faucher, Rene Hund, Christian Jehn-Rendu
  • Patent number: 7776181
    Abstract: A novel retention aid is provided, which can realizes not only high retention but also excellent paper formation and is easy to use, in various papermaking processes. A composition for improving retention is provided, which comprises (A) a cationic water-soluble polymer and (B) an amphoteric water-soluble polymer. The component (A) preferably is a copolymer having a cation equivalent of 0.05 to 4.00 meq/g or one having a 0.5% salted viscosity of 30 to 200 mPa·s. The component (B) preferably is either a copolymer comprising a cationic radical-polymerizable monomer unit, an anionic radical-polymerizable monomer unit, and a nonionic radical-polymerizable monomer unit, or an amphoteric water-soluble polymer obtained by polymerizing a cationic radical-polymerizable monomer with an anionic radical-polymerizable monomer in the presence of a polysaccharide.
    Type: Grant
    Filed: December 28, 2005
    Date of Patent: August 17, 2010
    Assignee: Toagosei Co., Ltd.
    Inventors: Yoshio Mori, Koichi Adachi, Ken Takeda, Tetsuya Tsuzuki
  • Patent number: 7767059
    Abstract: The invention relates to a flushable paper product comprising a fibrous substrate having (i) at least one strength region comprising a reacted cationic or a reacted nonionic strength agent and (ii) at least one dispersibility region, wherein the paper product has (a) a dispersibility of at least one tenth of a second, (b) a dry strength, and (c) a wet strength of at least about five percent of the dry strength.
    Type: Grant
    Filed: June 18, 2003
    Date of Patent: August 3, 2010
    Assignee: Kemira Oyj
    Inventors: Michael Ryan, David L. Dauplaise
  • Publication number: 20100175842
    Abstract: A preparation of high strength paper by incorporating a polymeric film into the paper web during the paper making process is provided. The polymeric film is either a cold water soluble film or hot water soluble film or water insoluble hydrophilic film or non soluble non hydrophilic film or a combination of cold+hot+cold water soluble film or cold+hot water soluble film or cold+non soluble hydrophilic film or cold+non soluble hydrophilic film+cold water soluble film or cold+non soluble non hydrophilic film or cold+non soluble non hydrophilic film+cold water soluble film or slit strips of one or many of these combinations woven or intertwined offline and incorporated into the paper during the paper making process. Zone coating or discreet printing or zone extrusion striping or formation of hot water soluble film on preformed cold water soluble film which is then inserted into paper during the paper making process, thus using cold water soluble film as a carrier is also provided.
    Type: Application
    Filed: March 22, 2006
    Publication date: July 15, 2010
    Applicant: Arrow Coated Products Ltd.
    Inventors: Shilpan Pravinchandra Patel, Nikita Kamlesh Thanawala
  • Patent number: 7736466
    Abstract: This invention relates to a paper substrate containing high surface sizing and low internal sizing and having high dimensional stability, as well as methods of making and using the composition.
    Type: Grant
    Filed: January 17, 2007
    Date of Patent: June 15, 2010
    Assignee: International Paper Company
    Inventors: Kapil Mohan Singh, Dennis W. Anderson, Peter M Froass, Yaoliang Hong, Krishna K Mohan, Thomas R Arnson, Yan C Huang
  • Patent number: 7736465
    Abstract: The invention relates to a composition comprising (a) a functional promoter comprising a water-soluble anionic polymer having a molecular weight of at least about 50,000 daltons and a molecular weight charge index value of at least about 10,000; (b) a cationic surfactant component; such that when the composition treats a fibrous substrate, in conjunction with a cationic strength agent, the treated fibrous substrate exhibits (i) a ratio of wet tensile strength to dry tensile strength ranging from about 1:5 to about 1:2 and (ii) an increase in a ratio of wet tensile strength to dry tensile strength of at least about 10%, as compared to when the fibrous substrate is treated with the functional promoter and without a surfactant. The invention also relates to a paper product made with such a system, and method for imparting wet strength to a paper product with the functional promoter.
    Type: Grant
    Filed: February 6, 2004
    Date of Patent: June 15, 2010
    Assignee: Kemira Oyj
    Inventors: Michael Ryan, William Brevard
  • Patent number: 7731820
    Abstract: The invention relates to a composition comprising a) at least one water-soluble fluorescent whitening agent, b) a polymer formed from an ethylenically unsaturated monomer or monomer blend, characterized in that at least one monomer is acrylamide and the water-soluble polymer has an average (weight average) molecular weight of between 500 and 49,000, optionally, c) polyethylene glycol with a weight average molecular weight of between 500 and 6000 and d) water and the use of the composition for the fluorescent whitening of paper in coating and size press or film press applications.
    Type: Grant
    Filed: October 17, 2005
    Date of Patent: June 8, 2010
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Robert Cockcroft, Ted Deisenroth, Peter Rohringer, Winfried Steffen
  • Patent number: 7727359
    Abstract: A thermosetting resin comprising a reacted A) first partially crosslinked glyoxalated polymer comprising a reacted (i) first polyacrylamide backbone and (ii) a first glyoxal component; and B) a second crosslinked glyoxalated polymer comprising a reacted (i) second polyacrylamide backbone and (ii) a second glyoxyal component; such that the first polyacrylamide backbone has a molecular weight that is less than the molecular weight of the second polyacrylamide backbone; and the first polyacrylamide backbone and the second polyacrylamide backbone have a weight ratio ranging from 75:25 to 95:5. Methods for making and using the resin. Fibrous substrates made with the resin.
    Type: Grant
    Filed: July 27, 2009
    Date of Patent: June 1, 2010
    Assignee: Kemira Oyj
    Inventors: Robert Joseph Proverb, Lucyna M. Pawlowska
  • Patent number: 7682488
    Abstract: A method of forming a cellulosic web is discussed, the product of which may, for example, possess at least one of increased softness, strength, and absorbency. The method measures the total anionic charge and controls the net charge of an aqueous stream.
    Type: Grant
    Filed: June 27, 2007
    Date of Patent: March 23, 2010
    Assignee: Georgia-Pacific Consumer Products LP
    Inventors: Kang Chang Yeh, Gary L. Worry, Thomas N. Kershaw, Henry S. Ostrowski
  • Patent number: 7678232
    Abstract: Synthetic co-polymers having moieties capable of forming hydrogen bonds, ionic bonds, or covalent bonds with cellulose fibers and paper modifying moieties capable of modifying a paper sheet are disclosed. These synthetic co-polymers are derived from the reaction of an aldehyde functional polymer and an aldehyde reactive paper modifying agent containing a non-hydroxyl aldehyde reactive functional group.
    Type: Grant
    Filed: June 14, 2007
    Date of Patent: March 16, 2010
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Thomas Gerard Shannon, Mike Thomas Goulet, Dana Stephanie Kass
  • Publication number: 20100059191
    Abstract: A heat, grease, and cracking resistance release paper, said release paper is composed by 55% to 68% by weight of cellulose fiber, 3% to 6% by weight of one or more sizing agents, 27% to 37% by weight of one or more fillers, and 1% to 3% by weight of one or more binding agents.
    Type: Application
    Filed: September 10, 2009
    Publication date: March 11, 2010
    Applicant: Copamex, S.A. De C.V.
    Inventors: ESTEBAN GARCIA MELGAREJO, FABIOLA RODRIGUEZ MATA
  • Patent number: 7670460
    Abstract: A process for the production of paper which includes the steps of providing an aqueous suspension containing cellulosic fibers, and optional fillers; adding to the suspension: (a) at least one charged organic polymer; and (b) an aqueous sol containing silica-based particles; wherein the sol has: (i) an S-value within the range of from 10 to 45%; (ii) a viscosity within the range of from 5 to 40 cP; and (iii) a molar ratio of SiO2 to M2O, where M is alkali metal or ammonium, within the range of from 10:1 to 40:1; and (III) forming and draining the suspension on a wire.
    Type: Grant
    Filed: December 20, 2006
    Date of Patent: March 2, 2010
    Assignee: Akzo Nobel N.V.
    Inventors: Michael Persson, Marek Tokarz, Maj-Lis Dahlgren
  • Patent number: 7670459
    Abstract: Fibrous products containing a durable softening agent are disclosed. The softening agent generally comprises a polysiloxane containing a plurality of first functional groups. In order to improve the wet retention of the softening agent on cellulosic fibers, the softening agent is reacted with a retention agent. The retention agent generally comprises a cationic polymer having a second functional group. In one embodiment, for instance, the softening agent contains epoxy groups or anhydride groups, while the retention agent contains amine groups. Products that may be made according to the present invention include tissue products, wipes and other absorbent articles.
    Type: Grant
    Filed: December 29, 2004
    Date of Patent: March 2, 2010
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Gil Bernard Didier Garnier, Michael Ralph Lostocco, Troy Michael Runge, Thomas Hampshire Schulz
  • Patent number: 7641766
    Abstract: A method of enhancing the dewatering of a paper sheet on a paper machine comprising adding to the paper sheet about 0.05 lb/ton to about 15 lb/ton, based on dry fiber, of one or more aldehyde functionalized polymers comprising amino or amido groups wherein at least about 15 mole percent of the amino or amido groups are functionalized by reacting with one or more aldehydes and wherein the aldehyde functionalized polymers have a molecular weight of at least about 100,000.
    Type: Grant
    Filed: January 26, 2004
    Date of Patent: January 5, 2010
    Assignee: Nalco Company
    Inventors: Michael R. St. John, Angel P. Zagala
  • Publication number: 20090308553
    Abstract: The invention firstly discloses a new method for treating mineral materials, by means of an amphoteric polymer, to make said mineral materials effective as an agent for reducing the quantity of natural and organic colloids in the process of manufacturing a sheet of paper. A second object of the invention resides in the mineral materials thereby treated and obtained using the inventive method. The third, fourth, and fifth objects of the invention are the dry powders, aqueous suspensions, and granulated treated mineral materials obtained using the inventive method. A final object of the invention is the usage of said mineral materials treated using the inventive method as an agent for reducing the quantity of natural and organic colloids in the process for manufacturing sheets of paper.
    Type: Application
    Filed: April 18, 2007
    Publication date: December 17, 2009
    Applicant: COATEX S.A.S.
    Inventors: Renaud Souzy, Christian Jacquemet, Jacques Mongoin
  • Patent number: 7625462
    Abstract: Polymeric bonding agents having a “triggerable” bonding functionality and which are in the form of particles or fibers, are blended with papermaking fibers prior to formation of a tissue web. After the web is dewatered, and advantageously during or after drying, the triggerable bonding functionality is activated to strengthen the resulting sheet structure. Tissue sheets prepared in this manner can exhibit an improved combination of softness, bulk and strength.
    Type: Grant
    Filed: April 20, 2006
    Date of Patent: December 1, 2009
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventor: Kou-Chang Liu
  • Patent number: 7589153
    Abstract: A method for making storage-stable glyoxalated inter-copolymers with higher and adjustable charge density suitable for use as a strengthening agent for paper. The glyoxalated inter-copolymers can be used to enhance the strength of paper, particularly recycled paper and mechanical printing paper.
    Type: Grant
    Filed: May 25, 2005
    Date of Patent: September 15, 2009
    Assignee: Georgia-Pacific Chemicals LLC
    Inventors: Cornel Hagiopol, Yuping Luo, David F. Townsend, Clay E. Ringold, Karla D. Favors
  • Patent number: 7585389
    Abstract: Fabric-creped absorbent sheet has an MD bending length of about 3.5 cm or more as well as an absorbency of about 3 g/g or more. The sheet is preferably produced without through drying or dry creping and is a low-dust product especially suitable for automatic towel dispensers.
    Type: Grant
    Filed: June 12, 2006
    Date of Patent: September 8, 2009
    Assignee: Georgia-Pacific Consumer Products LP
    Inventors: Kang C. Yeh, Stephen J. McCullough, Hung Liang Chou, Mark S. Hunter, Thomas E. Lyse, Ronald R. Reeb
  • Patent number: 7585388
    Abstract: Fabric-creped absorbent sheet has an MD bending length of about 3.5 cm or more as well as an absorbency of about 3 g/g or more. The sheet is preferably produced without through drying or dry creping and is a low-dust product especially suitable for automatic towel dispensers.
    Type: Grant
    Filed: June 12, 2006
    Date of Patent: September 8, 2009
    Assignee: Georgia-Pacific Consumer Products LP
    Inventors: Kang C. Yeh, Stephen J. McCullough, Hung Liang Chou, Mark S. Hunter, Thomas E. Lyse, Ronald R. Reeb
  • Publication number: 20090165978
    Abstract: Compositions comprising a blend of two or more paper strengthening agents have improved stability compared with previously known paper strengthening agents. One component is a polymeric paper strengthening agent, preferably a wet strengthening agent. The other component is a stabilized polyacrylamide prepared by (1) reacting a first portion of glyoxal with a polyacrylamide having pendant amide groups to form a first reaction mixture comprising polyacrylamide; (2) adding an acid to the first reaction mixture to form a second reaction mixture having a reduced pH and comprising the polyacrylamide; and (3) adding a second portion of glyoxal to the second reaction mixture to form the stabilized polyacrylamide. If desired, an aldehyde scavenger can be included in one or more of step (1), step (2), step (3), or the stabilized polyacrylamide. Such compositions can be used to enhance the strength of paper, particularly the wet strength of paper.
    Type: Application
    Filed: November 21, 2008
    Publication date: July 2, 2009
    Applicant: Georgia-Pacific Chemicals LLC
    Inventors: Cornel Hagiopol, Yuping Luo, David F. Townsend, James W. Johnston, Clay E. Ringold, Karla D. Favors
  • Patent number: 7547376
    Abstract: The invention provides a paper quality improver for papermaking that allows improvement in the bulky value and the optical properties such as brightness and opacity as well as in the paper strength of a sheet obtained by papermaking a pulp material. The paper quality improver for papermaking is a paper quality improver for papermaking containing a copolymer (A) having a constituent unit derived from at least one nonionic monomer having a solubility parameter of 20.5 (MPa)1/2 or less and a constituent unit derived from at least one anionic or cationic monomer and a surfactant (B) at a certain ratio, the quality improver providing at least one paper quality improving effect of: (i) standard improved bulky value: 0.02 g/cm or more; (ii) standard improved opacity: 1.0 point or more; and (iii) standard improved brightness: 0.5 point or more.
    Type: Grant
    Filed: July 17, 2003
    Date of Patent: June 16, 2009
    Assignee: Kao Corporation
    Inventor: Haruyuki Satoh
  • Publication number: 20090065162
    Abstract: A method of preparing a stable dispersion of flocculated filler particles for use in papermaking processes comprises sequential addition of high and low molecular weight flocculating agents to an aqueous dispersion of filler particles followed by shearing of the resultant filler flocs to the desired particle size resulting in shear resistant filler flocs with a defined and controllable size distribution.
    Type: Application
    Filed: September 12, 2007
    Publication date: March 12, 2009
    Inventors: Weiguo Cheng, Ross T. Gray
  • Patent number: 7488403
    Abstract: Compositions comprising a blend of two or more paper strengthening agents have improved stability compared with previously known paper strengthening agents. One component is a polymeric paper strengthening agent, preferably a wet strengthening agent. The other component is a stabilized glyoxalated polyacrylamide prepared by (1) reacting a first portion of glyoxal with a polyacrylamide having pendant amide groups to form a first reaction mixture comprising glyoxalated polyacrylamide; (2) adding an acid to the first reaction mixture to form a second reaction mixture having a reduced pH and comprising the glyoxalated polyacrylamide; and (3) adding a second portion of glyoxal to the second reaction mixture to form the stabilized glyoxalated polyacrylamide. If desired, an aldehyde scavenger can be included in one or more of step (1), step (2), step (3), or the stabilized glyoxalated polyacrylamide. Such compositions can be used to enhance the strength of paper, particularly the wet strength of paper.
    Type: Grant
    Filed: August 17, 2004
    Date of Patent: February 10, 2009
    Inventors: Cornel Hagiopol, Yuping Luo, David F. Townsend, James W. Johnston, Clay E. Ringold, Karla D. Favors
  • Patent number: 7473334
    Abstract: A method of preparing a modified diallyl-N,N-disubstituted ammonium halide polymer and use of the polymer in combination with one or more high molecular weight, water soluble cationic, anionic, nonionic, zwitterionic or amphoteric polymers for increasing retention and drainage in a papermaking furnish.
    Type: Grant
    Filed: October 15, 2004
    Date of Patent: January 6, 2009
    Assignee: Nalco Company
    Inventors: Jane B. Wong Shing, Alessandra Gerli, Xavier S. Cardoso, Angela P. Zagala, Przem Pruszynski, Cathy C. Doucette
  • Publication number: 20080308242
    Abstract: Storage-stable glyoxalated polyacrylamide polymers and high solids aqueous compositions formulated with them are described. These glyoxalated polyacrylamide compositions can be used as additives for papermaking, providing paper with good dry and temporary wet strength, and increasing papermaking de-watering rates.
    Type: Application
    Filed: June 13, 2008
    Publication date: December 18, 2008
    Applicant: BUCKMAN LABORATORIES INTERNATIONAL, INC.
    Inventors: Chen Lu, James Drew Ward
  • Publication number: 20080302498
    Abstract: Synthetic co-polymers having moieties capable of forming hydrogen bonds, ionic bonds, or covalent bonds with cellulose fibers and paper modifying moieties capable of modifying a paper sheet are disclosed. These synthetic co-polymers are derived from the reaction of an aldehyde functional polymer and an aldehyde reactive paper modifying agent containing a non-hydroxyl aldehyde reactive functional group.
    Type: Application
    Filed: June 14, 2007
    Publication date: December 11, 2008
    Inventors: Thomas Gerard Shannon, Mike Thomas Goulet, Dana Stephanie Kass
  • Patent number: 7459059
    Abstract: The invention discloses a paper or paperboard produced from a slurry comprising cellulose fibers and an effective amount of SMS. In addition, a method for increasing retention and dewatering during the papermaking process is also disclosed. The method involves the addition of an effective amount of SMS to said papermaking process.
    Type: Grant
    Filed: September 21, 2005
    Date of Patent: December 2, 2008
    Assignee: Nalco Company
    Inventors: Bruce A. Keiser, Laura M. Sherman
  • Patent number: 7442280
    Abstract: A process for the production of paper from a suspension containing cellulosic fibers, and optional fillers, which comprises adding to the suspension a drainage and retention aid comprising a cationic organic polymer, forming and dewatering the suspension on a wire, wherein the cationic organic polymer has an aromatic group and the suspension which is dewatered on the wire has a conductivity of at least 2.0 mS/cm.
    Type: Grant
    Filed: October 18, 2000
    Date of Patent: October 28, 2008
    Assignee: Akzo Nobel NV
    Inventors: Bore Klemets, Hans Hallstrom, Anna Asplund, Rein Sikkar
  • Patent number: RE42110
    Abstract: A method and composition are disclosed for providing a two-part polymer binder additive for a fibrous sheet for improving both its strength and durability. The two-part polymer binder may be added to augment organic binders to increase board strength and durability or to reduce the amount of organic binder required. The polymers may also be added in place of conventional organic binders or added in addition to organic binders to improve sag resistance and fibrous sheet performance.
    Type: Grant
    Filed: June 29, 2006
    Date of Patent: February 8, 2011
    Assignee: AWI Licensing Company
    Inventors: Kenneth P. Kehrer, Sheldon M. Atlas, Helen Atlas, Victor A. Kabanov, Alexander Kabanov, Alexander Zezin, Valentine Rogachova