Acrylamide Containing Patents (Class 162/168.3)
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Patent number: 6712934Abstract: The invention relates to a method for the production of paper or board, wherein retention aids are added to the stream of stock. Improved retention and more effective dewatering are achieved by adding to the stream of stock a cationic polymer solution and a suspension-form microparticle mixture composed of a swellable clay of the smectite group and a colloidal synthetic metal silicate in which the prevalent cation is magnesium.Type: GrantFiled: May 31, 2002Date of Patent: March 30, 2004Assignee: Kemira Chemicals OyInventors: Jonni Ahlgren, Kimmo Strengell
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Patent number: 6709551Abstract: This invention is directed to high molecular weight water-soluble polymers comprised of zwitterionic, nonionic and cationic or anionic monomer units, and to the use of these polymers in papermaking processes.Type: GrantFiled: December 17, 2001Date of Patent: March 23, 2004Assignee: Ondeo Nalco CompanyInventors: Martin J. Coffey, Steven T. Govoni, Arthur J. Begala, Ross T. Gray, Patrick G. Murray
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Publication number: 20040050514Abstract: Synthetic co-polymers having moieties capable of forming hydrogen bonds, ionic bonds, or covalent bonds with cellulose fibers and paper modifying moieties capable of modifying a paper sheet are disclosed. These synthetic co-polymers are derived from the reaction of an aldehyde functional polymer and an aldehyde reactive paper modifying agent containing a non-hydroxyl aldehyde reactive functional group.Type: ApplicationFiled: June 2, 2003Publication date: March 18, 2004Inventors: Thomas Gerard Shannon, Mike Thomas Goulet, Dana Stephanie Kass
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Publication number: 20040045688Abstract: A method for increasing filler retention of cellulosic fiber sheets is disclosed. In the method, cellulosic fibers with increased anionic sites are treated with either positively charged filler particles and/or amphoteric filler particles or a cationic retention aid and negatively charged filler particles and/or amphoteric filler particles. Cellulosic fiber sheets with retained filler particles are also disclosed.Type: ApplicationFiled: September 4, 2003Publication date: March 11, 2004Applicant: Weyerhaeuser CompanyInventors: Richard A. Jewell, Amar N. Neogi, Steven J. White
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Patent number: 6702923Abstract: A method for preparing a wet strength agent comprising a first step of reacting a nitrogen-containing polymer with a hydrophobic compound to form hydrophobic side-chain substituents on the polymer, a second step of reacting the hydrophobised nitrogen-containing polymer obtained with a crosslinker to form a cationic nitrogen-containing resin, and a third step comprising forming of particles by emulsion polymerisation of one or more ethylenically unsaturated monomers in the presence of the wet strength resin formed. The invention further relates to a wet strength agent and resin. It further relates to the use of said agent and resin in cellulosic suspensions, the production of paper, preferably tissue paper, and paper, preferably tissue paper comprising a wet strength resin or agent.Type: GrantFiled: November 15, 2000Date of Patent: March 9, 2004Assignee: Akzo Nobel NVInventors: Marek Gorzynski, Christian Biermann, Heribert J. Macherey, Arne Andersson
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Publication number: 20040040683Abstract: The invention relates to an improved paper production process, according to which a branched polymer prepared in reverse phase emulsion is used as the main retention aid, and then bentonite is used as the secondary retention aid (a dual type system). The two additions are separated by a stage for shearing the fibrous suspension (or mass).Type: ApplicationFiled: September 3, 2003Publication date: March 4, 2004Applicant: SNF SAInventors: Rene Hund, Christian Jehn-Rendu
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Patent number: 6699363Abstract: A process that can be used for producing a starch product is provided. The process comprises heating a composition, which comprises or consists essentially of a starch, a polyacrylamide, and a multivalent cation. The weight ratio of starch to polyacrylamide is greater than about 2 to 1. The process can also comprise heating a composition, which comprises or consists essentially of a starch and a polyacrylamide to produce a heated composition followed by contacting the heated composition with a multivalent cation. The heating can be carried out at a pH above 7.0 if the polyacrylamide is a cationic polyacrylamide or nonionic polyacrylamide and, if the starch is a cationic starch and the polyacrylamide is an amphoteric polyacrylamide or anionic polyacrylamide, the heating neutralizes less than 75% of the cationic starch.Type: GrantFiled: November 13, 2001Date of Patent: March 2, 2004Assignee: E. I. du Pont de Nemours and CompanyInventor: Robert Harvey Moffett
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Patent number: 6673208Abstract: The present invention relates to polysilicate microgels, their preparation and use in paper making and water purification, the polysilicate microgels being obtainable by a process which comprises bringing into contact (i) particles of a salt AB with an aqueous silicate or polysilicate solution, (ii) an ion A with an ion B in the presence of an aqueous silicate or polysilicate solution, whereby the salt AB is precipitating in the aqueous phase, or (iii) an ion A with an ion B in the presence of an aqueous silicate or polysilicate solution, whereby the ions A and B represent ions of a precipitable salt AB having a pKS value of at least 4, measured at 20° C. in water. The invention further relates to aqueous silicate or polysilicate solutions, their preparation and use as precursors for polysilicate microgels.Type: GrantFiled: July 1, 2002Date of Patent: January 6, 2004Assignee: Akzo Nobel N.V.Inventors: Michael Persson, Marek Tadeusz Tokarz, Rein Sikkar
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Patent number: 6669816Abstract: The process contemplates the use of a sizing dispersion that comprises an aqueous dispersion of rosin material, a synthetic sizing agent and a aluminum compound selected from the group formed by aluminum sulfate and aluminum polymers of formulas [Al(OH)x(A)(3−x)]n (1) or [Al(OH)x(H3PO4)y(A)(3−x)]n (2) where A=Cl−, NO3−, HCOO−, CH3COO−; or [Al(OH)x(H3PO4)y(SO4)(3−x/2)]n (3) where “x” ranges from 0.03 to 2.7, and “y” ranges from 0.01 to 0.8 and n≧2; and by mixtures thereof.Type: GrantFiled: December 14, 2000Date of Patent: December 30, 2003Assignees: Erplip S.A., Kemira Iberica S.A.Inventors: Juan José Costas Poch, Josep Lluis Bisbal Tudela
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Publication number: 20030234089Abstract: The invention relates to a functional promoter comprising a water-soluble anionic polymer having a molecular weight of at least about 50,000 daltons and a molecular weight charge index value of at least about 10,000, and a cationic strength component. The invention also relates to a paper product made with such a system, and method for imparting wet strength to a paper product with the functional promoter.Type: ApplicationFiled: June 19, 2002Publication date: December 25, 2003Inventors: Michael Ryan, William Brevard, David Dauplaise, Michael Lostocco, Robert Proverb, David Wesley Lipp
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Publication number: 20030217825Abstract: Copolymers of dimethylaminopropyl methacrylamide and hydroxyethyl methacrylate having residual monomer levels of <2000 ppm and <500 ppm, respectively, are made by copolymerizing the monomers in a predetermined weight ratio in an aqueous-alcoholic solvent of defined composition. Substrates coated with these copolymers are capable of absorbing the solvents, e.g. water or organic solvents, of digital printing inks rapidly with dry times of <1 min.Type: ApplicationFiled: May 22, 2002Publication date: November 27, 2003Applicant: ISP INVESTMENTS INC.Inventors: Stephen L. Kopolow, Drupesh Patel, Michael Tallon
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Publication number: 20030205344Abstract: This invention discloses a talc additive for use as a filler in making paper products which is useful in preventing dusting or linting of paper. Also disclosed is a method of making the additive and using it in making paper.Type: ApplicationFiled: March 31, 2003Publication date: November 6, 2003Applicant: Luzenac America, Inc.Inventors: Vicente Lasmarias, Shripal Sharma, Alexis Layne
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Publication number: 20030188840Abstract: Addition of a premixed aqueous mixture of anionic dry strength resin and cationic or amphoteric starch to a paper making pulp slurry yields paper with higher dry strength than paper that is the same except that the starch and dry strength resin are added separately.Type: ApplicationFiled: April 8, 2002Publication date: October 9, 2003Inventors: Joseph Donald Van Handel, Constance K. Klaisner, John C. Gast
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Patent number: 6616806Abstract: A process for making paper comprising forming a cellulosic suspension, flocculating the suspension, draining the suspension on a screen to form a sheet and then drying the sheet, wherein the cellulosic suspension is flocculated by addition of a water soluble polymer which is selected from a) a polysaccharide or b) a synthetic polymer of intrinsic viscosity at least 4 dl/g and then reflocculated by a subsequent addition of a reflocculating system, wherein the reflocculating system comprises i) a siliceous material and ii) a water soluble polymer. In one aspect the siliceous material is added prior to or simultaneous with the water soluble polymer. In an alternative for the water soluble polymer is anionic and added prior to the siliceous material.Type: GrantFiled: August 2, 2002Date of Patent: September 9, 2003Assignee: Ciba Specialty Chemicals Water Treatments LimitedInventor: Gordon Cheng I Chen
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Patent number: 6616807Abstract: Paper, board and cardboard having high dry strength are produced by the addition of cationic, anionic and/or amphoteric starch as dry strength agents to the paper stock and drainage of the paper stock with sheet formation in the presence of cationic polymers as retention aids for starch, and cationic polymeric retention aids are used for increasing the retention of dry strength agents comprising cationic, anionic and/or amphoteric starch in the production of paper, board and cardboard.Type: GrantFiled: October 1, 1999Date of Patent: September 9, 2003Assignee: BASF AktiengesellschaftInventors: Rainer Dyllick-Brenzinger, Primoz Lorencak, Hubert Meixner, Peter Baumann, Ellen Krüger, Andreas Stange, Martin Rübenacker
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Patent number: 6616805Abstract: A surface-treating agent mainly includes three constituents: a water-soluble polymer; a surface sizing agent which is a copolymer of a styrene type monomer and an anionic monomer and which mainly includes a water-soluble copolymer containing 20 to 80 weight % of the styrene type monomer; and a surface sizing agent which is a copolymer of an olefin type monomer and an anionic monomer and which mainly includes a water-soluble copolymer containing 20 to 80 weight % of the olefin type monomer. The surface-treating agent is coated and dried on a base paper for offset printing.Type: GrantFiled: September 19, 2001Date of Patent: September 9, 2003Assignee: Nippon Paper Industries, Co., Ltd.Inventors: Toshiyuki Takano, Hiroshi Ono, Hideki Fujiwara
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Publication number: 20030150575Abstract: The invention relates to an improved paper production process, according to which a branched polymer prepared in reverse phase emulsion is used as the main retention aid, and then bentonite is used as the secondary retention aid (a dual type system). The two additions are separated by a stage for shearing the fibrous suspension (or mass).Type: ApplicationFiled: August 27, 2002Publication date: August 14, 2003Applicant: SNF SAInventors: Rene Hund, Christian Jehn-Rendu
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Publication number: 20030145966Abstract: The invention relates to a process for making paper wherein an anionic starch, which is based on a starch comprising at least 95 wt. %, based on dry substance of the starch, of amylopectin, or a derivative of said starch, is used in combination with a fixative as a strengthening agent.Type: ApplicationFiled: November 27, 2002Publication date: August 7, 2003Applicant: COOPERATIEVE VERKOOP-EN PRODUCTIEVERENIGING VAN AARDAPPELMEEL EN DERIVATEN AVEBE B.A.Inventors: Jacob Terpstra, Jan Hendriks
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Patent number: 6602389Abstract: Disclosed is a process for preparing a paper web. The paper web is prepared from a low-grade furnish, which contains low-grade pulps, such as recycled pulp and/or groundwood pulp, and which, in one preferred embodiment, is a newsprint furnish. In accordance with the disclosed process, a pre-flocculated filler is added to the furnish prior to forming the paper web from the furnish. Filler will be retained in the web, and retention of undesired components of the furnish in the web will be reduced as compared with newsprint in which a filler is incorporated via conventional processes. Another embodiment contemplates the incorporation of a pre-flocculated coated broke slurry into a paper furnish prior to paper formation. The paper web formed via the process of the invention will have improved properties as a result of the incorporation of the pre-flocculated filler or treated broke into the web.Type: GrantFiled: January 4, 2002Date of Patent: August 5, 2003Assignee: Grain Processing CorporationInventors: Richard D. Harvey, Stuart W. Mabee, James M. Crandall
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Publication number: 20030139517Abstract: The present invention refers to a process for the production of paper from a suspension containing cellulosic fibers, and optionally fillers, comprising adding to the suspension at least one cationic organic polymer and an aqueous silica-containing composition comprising an anionic naphthalene sulphonate formaldehyde condensate and anionic silica-based particles, the composition having a weight ratio of naphthalene sulphonate formaldehyde condensate to silica-based particles within the range of from 0.2:1 to 99:1, and containing naphthalene sulphonate formaldehyde condensate and silica-based particles in an amount of at least 0.01% by weight, based on the total weight of the aqueous silica-containing composition, and with the proviso that the composition contains substantially no cellulose-reactive sizing agent. The invention also encompasses an aqueous silica-containing composition and a method for preparation of an aqueous silica-containing compound.Type: ApplicationFiled: December 20, 2002Publication date: July 24, 2003Inventors: Johan Nyander, Hans Johansson-Vestin, Jan Nordin, Annika Viola Pal
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Publication number: 20030136534Abstract: The present invention relates to an aqueous silica-containing composition comprising an anionic organic polymer having at least one aromatic group and anionic aggregated or microgel formed silica-based particles. The aqueous silica-containing composition contains the anionic organic polymer having at least one aromatic group and the anionic silica-based particles in an amount of at least 0.01% by weight of the total weight of the aqueous silica-containing composition. The aqueous silica-containing composition contains substantially no cellulose-reactive sizing agent and the anionic organic polymer having at least one aromatic group is not an anionic naphthalene sulphonate formaldehyde condensate.Type: ApplicationFiled: December 20, 2002Publication date: July 24, 2003Inventors: Hans Johansson-Vestin, Johan Nyander, Jan Nordin
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Publication number: 20030136532Abstract: A method for increasing filler retention of cellulosic fiber sheets is disclosed. In the method, cellulosic fibers with increased anionic sites are treated with either positively charged filler particles and/or amphoteric filler particles or a cationic retention aid and negatively charged filler particles and/or amphoteric filler particles. Cellulosic fiber sheets with retained filler particles are also disclosed.Type: ApplicationFiled: December 20, 2002Publication date: July 24, 2003Applicant: Weyerhaeuser CompanyInventors: Richard A. Jewell, Amar N. Neogi, Steven J. White
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Publication number: 20030127206Abstract: Disclosed is a composition for softening an absorbent tissue and tissue structures softened using the composition. The composition includes an effective amount of a softening active ingredient; a vehicle in which the softening active ingredient is dispersed; an electrolyte dissolved in the vehicle; a bilayer disrupter and a high polymer. The electrolyte and the bilayer disrupter cooperate to cause the viscosity of the composition to be less than the viscosity of a dispersion of the softening active ingredient in the vehicle alone. The high polymer adds “stringiness” to the composition opening the air pressure operating window for spray application of the softening composition.Type: ApplicationFiled: January 7, 2003Publication date: July 10, 2003Applicant: The Procter & Gamble CompanyInventors: Steven Lee Barnholtz, Kenneth Douglas Vinson, Paul Joseph Coffaro, Larry Neil Mackey, Amy Jo Hamilton, Errol Hoffman Wahl, Gayle Marie Frankenbach, Yenchun Wu
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Publication number: 20030121627Abstract: A method for forming a tissue product that is soft and produces relatively low levels of lint and slough is provided. The method includes providing a liquid furnish of cellulosic fibers and forming a multi-layered wet web therefrom. At least one latex having a glass transition temperature less than about 30° C. is applied to the furnish, wet web, or combinations thereof in an amount less than about 60 pounds per ton of the dry weight of the cellulosic fibers. The web is then dried such that at least one outer layer of the dried web contains the latex-treated cellulosic fibers.Type: ApplicationFiled: December 3, 2001Publication date: July 3, 2003Inventors: Sheng-Hsin Hu, Shan Chen, K.B. Makoui
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Patent number: 6582557Abstract: Carboxylated cellulosic fibers are disclosed. The fibers include a polycarboxylic acid covalently coupled to the fibers. Methods for producing the fibers and for producing fibrous products that incorporate the fibers are also disclosed.Type: GrantFiled: September 27, 2002Date of Patent: June 24, 2003Assignee: Weyerhaeuser CompanyInventor: Richard A. Jewell
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Patent number: 6579417Abstract: According to the present invention, a cross-linked polymer or copolymer formed by reverse phase emulsion polymerization from suitable water-soluble monomers or from mixtures of such monomers is used as a retention agent. The process according to the invention is characterized in that the cross-linked polymer is sheared before its introduction or injection into the suspension to be flocculated. This results in a distinct improvement in the retention, formation, drainage and other properties of the paper or paperboard sheet thus obtained, as a function of the shearing.Type: GrantFiled: March 9, 2001Date of Patent: June 17, 2003Assignee: SNF S.A.Inventors: Rene Hund, Christian Jehn-Rendu
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Publication number: 20030102097Abstract: A process that can be used for producing a starch product is provided. The process comprises heating a composition, which comprises or consists essentially of a starch, a polyacrylamide, and a multivalent cation. The weight ratio of starch to polyacrylamide is greater than about 2 to 1. The process can also comprise heating a composition, which comprises or consists essentially of a starch and a polyacrylamide to produce a heated composition followed by contacting the heated composition with a multivalent cation. The heating can be carried out at a pH above 7.0 if the polyacrylamide is a cationic polyacrylamide or nonionic polyacrylamide and, if the starch is a cationic starch and the polyacrylamide is an amphoteric polyacrylamide or anionic polyacrylamide, the heating neutralizes less than 75% of the cationic starch.Type: ApplicationFiled: November 13, 2001Publication date: June 5, 2003Inventor: Robert Harvey Moffett
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Publication number: 20030079846Abstract: A multi-purpose paper, a manufacturing method thereof, and an application thereof are provided. The method of manufacturing the multi-purpose paper comprises steps of (a) providing a papermaking material and obtaining a clean paper pulp by treating the papermaking material, (b) adding at least one functional additive into the clean paper pulp to form the multi-purpose paper, and (c) processing the multi-purpose paper to form thereon an uneven surface structure. The cultivating paper has the combined functions of weed control, pest control, supplying the required nutrients to plants to help develop the root system, maintaining moisture and breath for the root system. The multi-purpose paper can be carriers of agricultural antagonistic microorganisms and serve as the basic functional substrate for weed control, pest control, sowing, growing seedlings, fertilization, fertilizer saving, manpower saving and organic cultivating.Type: ApplicationFiled: October 26, 2001Publication date: May 1, 2003Applicant: Yuen Foong Yu Paper MFG Co., LTDInventor: Ching-Chung Huang
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Publication number: 20030079848Abstract: The invention relates to a method for the production of paper or board, wherein retention aids are added to the stream of stock. Improved retention and more effective dewatering are achieved by adding to the stream of stock a cationic polymer solution and a suspension-form microparticle mixture composed of a swellable clay of the smectite group and a colloidal synthetic metal silicate in which the prevalent cation is magnesium.Type: ApplicationFiled: May 31, 2002Publication date: May 1, 2003Inventors: Jonni Ahlgren, Kimmo Strengell
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Publication number: 20030079847Abstract: A method and composition are disclosed for providing a two-part polymer binder additive for a fibrous sheet by improving both its strength and durability. The polymer binder comprises both the addition of a resin system and an anionic polymer which impart both increased strength and resistance to moisture and sagging. The resin system includes a polyamidoamine-epihalohydrin resin, a latex and an anionic polymer.Type: ApplicationFiled: September 10, 2002Publication date: May 1, 2003Applicant: Armstrong World Industries, Inc.Inventors: Matthew Howle, Karl B. Himmelberger
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Patent number: 6551457Abstract: A process for the production of paper from an aqueous suspension containing cellulosic fibers, and optional fillers, which comprises draining the suspension to obtain a paper web and subjecting the obtained paper web to impulse pressing by passage through at least one press nip having at least one heated roll which is in contact with the web and heated to a temperature above 100° C., wherein a chemical system comprising a polymer component and micro- or nanoparticles are added to the suspension or the paper web before the paper web passes the press nip of the impulse unit.Type: GrantFiled: September 20, 2001Date of Patent: April 22, 2003Assignee: Akzo Nobel N.V.Inventors: Caroline Westman, Tom Lindstrom, Janne Laine, Maria Norell
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Publication number: 20030070782Abstract: A method of reducing the level of malodorous amines emitted by paper when exposed to an alkaline environment is provided, which comprises making the paper so that it does not contain ammonium groups that are bonded to any polymer contained in the paper by only one chemical bond. Laminates which emit reduced levels of amines and which are comprised of this paper are also provided. In a preferred embodiment, the paper is sized with a sizing emulsion comprised of alkenyl succinic anhydride and a cationic water-soluble polymer having ammonium groups that are attached to the polymer by at least two chemical bonds.Type: ApplicationFiled: November 5, 2002Publication date: April 17, 2003Inventors: Robert J. Proverb, Michael J. Scanlon
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Patent number: 6548427Abstract: The present invention is generally directed to a tissue product with improved flushability. Specifically, the incorporation of both a temporary wet strength agent and an alkaline reagent into the tissue product results in the tissue product having high initial wet tensile strength and a high rate of wet tensile loss. The high rate of wet tensile loss is caused by the high pH of the alkaline reagent that is incorporated during the dry end of a tissue manufacturing process. The temporary wet strength agent is added in the wet end of a tissue manufacturing process. In certain embodiments of the present invention, glyoxylated polyacrylamide may be used as the temporary wet strength agent, while the alkaline reagent may be in dry form or may be encapsulated.Type: GrantFiled: November 22, 2000Date of Patent: April 15, 2003Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Thomas G. Shannon, Michael J. Smith, Patrick P. Chen, Graciela Jimenez
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Patent number: 6547928Abstract: Disclosed is a composition for softening an absorbent tissue and tissue structures softened using the composition. The composition includes an effective amount of a softening active ingredient; a vehicle in which the softening active ingredient is dispersed; an electrolyte dissolved in the vehicle; a bilayer disrupter and a high polymer. The electrolyte and the bilayer disrupter cooperate to cause the viscosity of the composition to be less than the viscosity of a dispersion of the softening active ingredient in the vehicle alone. The high polymer adds “stringiness” to the composition opening the air pressure operating window for spray application of the softening composition.Type: GrantFiled: November 30, 2001Date of Patent: April 15, 2003Assignee: The Procter & Gamble CompanyInventors: Steven Lee Barnholtz, Kenneth Douglas Vinson, Paul Joseph Coffaro, Larry Neil Mackey, Amy Jo Hamilton, Errol Hoffman Wahl, Gayle Marie Frankenbach, Yenchun Wu
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Publication number: 20030066617Abstract: The invention relates to an aqueous silica-based sol comprising a nitrogen-containing organic compound and silica-based particles with a specific surface area of at least 300 square meters per gram of silica. The invention further relates to a process for the production of an aqueous silica-based sol comprising a nitrogen-containing organic compound which comprises incorporating a nitrogen-containing organic compound into a silica-based sol containing silica-based particles with a specific surface area of at least 300 square meters per gram of silica. The invention also relates to the use of an aqueous silica-based sol comprising a nitrogen-containing organic compound and silica-based particles with a specific surface area of at least 300 square meters per gram of silica as a flocculating agent in the production of pulp and paper and in water purification.Type: ApplicationFiled: September 23, 2002Publication date: April 10, 2003Inventors: Peter Greenwood, Magnus Olof Linsten, Hans E Johansson-Vestin
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Patent number: 6540876Abstract: This invention pertains to the use of compounds containing amide or imide type functional groups to increase the rate of nitroxide mediated oxidation of alcohols, particularly primary and secondary alcohols. While suitable for oxidation of alcohol groups on a variety of substrates, it is particularly useful to oxidize cellulose, cellulose pulp or cellulose fiber such that it is commercially compatible with the traditional paper making process. Such co-catalysts may be used to increase the absolute amount of aldehyde groups on cellulose, cellulose pulp or cellulose fiber, thereby further increasing the inherent wet strength, temporary wet strength, and dry strength of paper made with such cellulose, cellulose pulp or cellulose fiber.Type: GrantFiled: May 19, 2000Date of Patent: April 1, 2003Assignee: National Starch and Chemical Ivnestment Holding CorporationInventors: A. Levent Cimecioglu, John S. Thomaides, Kraig A. Luczak, Danielle E. Harkins
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Publication number: 20030051840Abstract: Printing paper superior in a texture, a feel and ease in turning the page is provided by adjusting the product of the paper density, the breaking length of a paper-making direction and the Young's modulus of the paper-making direction of the paper made by a paper machine within the limits of no less than 2×1018 and no more than 10×1018 g·N/m4 by using the following means independently or in appropriate combination: a means of lowering paper density by increasing the compounding ratios of low-density pulp and low-density filler, using bulking chemicals or reducing press pressure during paper-making process, a means of lowering the paper breaking length of a paper-making direction by improving the compounding ratios of filler, and a means of lowering the Young's modulus of the paper by using a softening agent.Type: ApplicationFiled: September 13, 2002Publication date: March 20, 2003Inventors: Takashi Ochi, Masaya Tosaka, Takehide Kasahara, Hideki Fujiwara
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Patent number: 6524439Abstract: According to the present invention a process is provided for making paper or paper board comprising forming a cellulosic suspension, flocculating the suspension, draining the suspension on a screen to form a sheet and then drying the sheet, characterised in that the suspension is flocculated using a flocculation system comprising a siliceous material and organic microparticies which have an unswollen particle diameter of less than 750 nanometers.Type: GrantFiled: October 10, 2001Date of Patent: February 25, 2003Assignee: Ciba Specialty Chemicals Water Treatments Ltd.Inventors: Gordon Cheng I. Chen, Gary Peter Richardson
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Patent number: 6517677Abstract: This invention is directed to a method of improving retention and drainage performance in a papermaking process comprising adding to the furnish an effective amount of a low molecular weight water-soluble cationic dispersion polymer prepared by polymerizing one or more cationic monomers and one or more nonionic monomers and one or more chain transfer agents under free radical forming conditions in an aqueous solution of an anionic salt in the presence of a stabilizer polymer, wherein the cationic dispersion has a cationic charge of from about 10 mole percent to about 80 mole percent and an RSV of from about 0.2 dl/g to about 6 dl/g.Type: GrantFiled: January 4, 2002Date of Patent: February 11, 2003Assignee: Ondeo Nalco CompanyInventors: Richard P. Cardile, John W. Sparapany, Cathy C. Johnson, Angela P. Zagala
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Publication number: 20030024671Abstract: An aqueous sol containing silica-based particles which has an S-value within the range of from 10 to 45%, a viscosity within the range of from 5 to 40 cP, and a molar ratio of SiO2 to M2O, where M is alkali metal or ammonium, within the range of from 10:1 to 40:1, or a silica content of at least 10% by weight. The invention further relates to a process for the production of silica-based particles comprising the steps of: (a) acidifying an aqueous silicate solution to a pH of from 1 to 4 to form an acid sol; (b) alkalising the acid sol at an SiO2 content within the range of from 4.5 to 8% by weight to; (c) allowing particle growth of the alkalised sol for at least 10 minutes, or heat-treating the alkalised sol at a temperature of a least 30° C.; and then (d) alkalising the obtained sol to a pH of at least 10.0.Type: ApplicationFiled: November 5, 2001Publication date: February 6, 2003Inventors: Michael Persson, Marek Tokarz, Maj-Lis Dahlgren
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Publication number: 20030024669Abstract: The present invention uses hydrophobically modified polyaminamide with standard wet strength agent to produce a softer and more absorbent paper material. The hydrophobically modified polyaminamide is substantive to cellulosic fibers, thus is able to carry polyethylene glycol esters or ethers, a non-substantive material to cellulosic fiber as stable complexes, into the paper product.Type: ApplicationFiled: May 10, 2001Publication date: February 6, 2003Inventor: Bruce Jerome Kokko
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Patent number: 6503370Abstract: Method of producing paper having a three-dimensional pattern of alternating raised and recessed portions which is given the paper in connection with impulse drying, at which the wet paper web is passed through at least one press nip (12) comprising a rotatable roll (13) which is heated and that the paper web when passing through the press nip is given a three-dimensional pattern either by means of a pattern wire (11) and/or by the fact that the heated roll (13) is provided with a three-dimensional pattern, and where the wet paper web (10) before entering said press nip (12) is given a basis weight variation in a non-random pattern.Type: GrantFiled: April 2, 2001Date of Patent: January 7, 2003Assignee: SCA Hygiene Products ABInventors: Holger Hollmark, Lennart Reiner, Thomas Billgren, Kaveh Tondkar, Mats Söderberg, Bengt Järrehult
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Publication number: 20020195216Abstract: The invention relates to a method of forming a multicomponent mat, the multicomponent mat which is formed from glass fibers and natural fibers and methods of making a multicomponent mat. Initially in the method of forming a multicomponent mat, a natural fiber slurry is formed. The next step involves using a surfactant to disperse glass fibers in white water. The natural fiber slurry and the slurry of glass fibers are generally compatible and are combined to form a multicomponent slurry which is used to form a multicomponent mat.Type: ApplicationFiled: April 30, 2001Publication date: December 26, 2002Inventor: Daojie Dong
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Publication number: 20020195218Abstract: A process for making paper comprising forming a cellulosic suspension, flocculating the suspension, draining the suspension on a screen to form a sheet and then drying the sheet, wherein the cellulosic suspension is flocculated by addition of a water soluble polymer which is selected fromType: ApplicationFiled: August 2, 2002Publication date: December 26, 2002Inventor: Gordon Cheng I Chen
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Patent number: 6494989Abstract: Absorbent wetlaid paper containing at least 1% by weight, calculated on the dry weight of the paper, of an absorbent polymeric material having a thermo-reversible liquid uptake capacity, which has a cloud point, Cp, in water within the temperature interval 30-60° C., preferably 35-55° C., at which the polymer has a substantially higher liquid uptake capacity at temperatures below said cloud point as compared to at temperatures above the cloud point. The thermo-reversible polymer will then be inactive during the papermaking process and be activated to its swelling and absorbent form when it is brought into contact with a liquid, the temperature of which is below the cloud point, Cp, of the polymer.Type: GrantFiled: August 16, 2001Date of Patent: December 17, 2002Assignee: SCA Hygiene Products ABInventors: Jeanette Annergren, Holger Hollmark, Ulrika Strandlund
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Patent number: 6494990Abstract: A paper or board is coated with a composition comprising from 30-95 parts by weight of a synthetic, carboxylated surface size containing at least about 40 mole percent of hydrophobic groups and at least about 25 mole percent of carboxylated groups such as styrene/acrylic acid copolymer, and from 5-70 parts by weight of a substantially hydrophilic polyacrylamide such as a cationic or anionic polyacrylamide.Type: GrantFiled: April 29, 1999Date of Patent: December 17, 2002Assignee: Bayer CorporationInventors: Rajiv Bazaj, Gerald Guerro, David Dauplaise
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Patent number: 6491790Abstract: A method of reducing the level of malodorous amines emitted by paper when exposed to an alkaline environment is provided, which comprises making the paper so that it does not contain ammonium groups that are bonded to any polymer contained in the paper by only one chemical bond. Laminates which emit reduced levels of amines and which are comprised of this paper are also provided. In a preferred embodiment, the paper is sized with a sizing emulsion comprised of alkenyl succinic anhydride and a cationic water-soluble polymer having ammonium groups that are attached to the polymer by at least two chemical bonds.Type: GrantFiled: May 27, 1999Date of Patent: December 10, 2002Assignee: Bayer CorporationInventors: Robert J. Proverb, Michael J. Scanlon
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Publication number: 20020179267Abstract: The present invention relates to polysilicate microgels, their preparation and use in paper making and water purification, the polysilicate microgels being obtainable by a process which comprises bringing into contact (i) particles of a salt AB with an aqueous silicate or polysilicate solution, (ii) an ion A with an ion B in the presence of an aqueous silicate or polysilicate solution, whereby the salt AB is precipitating in the aqueous phase, or (iii) an ion A with an ion B in the presence of an aqueous silicate or polysilicate solution, whereby the ions A and B represent ions of a precipitable salt AB having a pKS value of at least 4, measured at 20° C. in water. The invention further relates to aqueous silicate or polysilicate solutions, their preparation and use as precursors for polysilicate microgels.Type: ApplicationFiled: July 1, 2002Publication date: December 5, 2002Inventors: Michael Persson, Marek Tadeusz Tokarz, Rein Sikkar
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Publication number: 20020179268Abstract: Process and apparatus for manufacturing a fibrous material web. The apparatus includes an automatic formation regulator, and the process includes on-line measuring of formation of the fibrous material web, utilizing the on-line measured formation as a controlled variable, and maintaining the formation at a preselectable target level via the automatic formation regulator.Type: ApplicationFiled: April 10, 2002Publication date: December 5, 2002Applicant: VOITH PAPER PATENT GMBHInventor: Michael Schwarz
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Patent number: 6488812Abstract: A synthetic polymer having hydrogen bonding capability and containing a hydrophobic aliphatic hydrocarbon moiety can reduce lint and slough in soft tissue products while maintaining softness and strength.Type: GrantFiled: December 14, 2000Date of Patent: December 3, 2002Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Thomas Gerard Shannon, Mike Thomas Goulet, Fu Chen