Cellulose Derivative (e.g., Cellulose Ester) Patents (Class 162/177)
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Publication number: 20100132902Abstract: The invention relates to a paper that is formed of a fibre-based source material and is applicable as printing paper. According to the invention, the surface of the paper is surface-treated by arranging on the surface sufficient density in such manner that the density of at least one surface layer of the paper is sufficiently high to yield a Gurley-Hill value of over 7000 s/100 ml as measured from the entire paper. Furthermore, the invention relates to a method for making paper.Type: ApplicationFiled: April 25, 2008Publication date: June 3, 2010Applicant: UPM-Kymmene OyjInventors: Tarja Sinkko, Mikko Oksanen, Janne Varvemaa, Kyösti Haapoja, Teuvo Lappänen
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Publication number: 20100089541Abstract: A process of making filled paper comprising the steps of providing a thick stock cellulosic suspension that contains mechanical pulp and filler, diluting the thick stock suspension to form a thin stock suspension, in which the filler is present in the thin stock suspension in an amount of at least 10% by weight based on dry weight of thin stock suspension, flocculating the thick stock suspension and/or the thin stock using a polymeric retention/drainage system, draining the thin stock suspension on a screen to form a sheet and then drying the sheet, in which the polymeric retention/drainage system comprises, i) a water-soluble branched anionic polymer and ii) a water-soluble cationic or amphoteric polymer. The process is particularly suitable for making filled mechanical grade paper, such as SC grade paper. The process enables the separation of retention and drainage parameters, especially useful for fast draining paper machines, such as Gapformers.Type: ApplicationFiled: January 21, 2008Publication date: April 15, 2010Inventor: Holger Reinicke
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Publication number: 20100084103Abstract: A process of making paper or paperboard with improved ash retention relative to total retention comprising the steps of providing a thick stock cellulosic suspension that contains filler, diluting the thick stock suspension to form a thin stock suspension, in which the filler is present in the thin stock suspension in an amount of at least 10% by weight based on dry weight of thin stock suspension, flocculating the thick stock suspension and/or the thin stock using a polymeric retention/drainage system, draining the thin stock suspension on a screen to form a sheet and then drying the sheet, in which the polymeric retention/drainage system comprises, i) a water-soluble branched anionic polymer and ii) a water-soluble cationic or amphoteric polymer, wherein the anionic polymer is present in the thick stock or thin stock suspension prior to the addition of the cationic or amphoteric polymer. The process brings about improved ash retention relative to total retention.Type: ApplicationFiled: January 22, 2008Publication date: April 8, 2010Applicant: BASF SE, 67056Inventor: Holger Reinicke
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Publication number: 20100065236Abstract: The present invention relates to a method of producing a cellulose based paper, the paper itself and the use thereof where the paper exhibits enhanced mechanical properties. The method involves providing a suspension of well dispersed modified cellulose at a low concentration. The properties and the chemical structure of the paper make it suitable for in vivo applications such as implant material.Type: ApplicationFiled: May 18, 2009Publication date: March 18, 2010Inventors: Marielle Henriksson, Lars Berglund, Qi Zhou, Vincent Bulone
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Publication number: 20100059191Abstract: A heat, grease, and cracking resistance release paper, said release paper is composed by 55% to 68% by weight of cellulose fiber, 3% to 6% by weight of one or more sizing agents, 27% to 37% by weight of one or more fillers, and 1% to 3% by weight of one or more binding agents.Type: ApplicationFiled: September 10, 2009Publication date: March 11, 2010Applicant: Copamex, S.A. De C.V.Inventors: ESTEBAN GARCIA MELGAREJO, FABIOLA RODRIGUEZ MATA
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Patent number: 7641765Abstract: Paper coated with a coating slip containing at least one optical brightener is produced by a process in which base paper or precoated paper is treated, before application of the coating slip containing optical brightener, with at least one substance which enhances the efficiency of optical brighteners.Type: GrantFiled: August 7, 2002Date of Patent: January 5, 2010Assignee: BASF AktiengesellschaftInventors: Thierry Blum, Friedrich Linhart, Stephan Frenzel
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Patent number: 7585388Abstract: Fabric-creped absorbent sheet has an MD bending length of about 3.5 cm or more as well as an absorbency of about 3 g/g or more. The sheet is preferably produced without through drying or dry creping and is a low-dust product especially suitable for automatic towel dispensers.Type: GrantFiled: June 12, 2006Date of Patent: September 8, 2009Assignee: Georgia-Pacific Consumer Products LPInventors: Kang C. Yeh, Stephen J. McCullough, Hung Liang Chou, Mark S. Hunter, Thomas E. Lyse, Ronald R. Reeb
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Publication number: 20090188639Abstract: A water-soluble interjacent complex that includes a first water-soluble polymer and one or more water-soluble monomers polymerized to form a second water-soluble polymer in the presence of the first water-soluble polymer. The water-soluble interjacent complex forms a solution in water that is free of insoluble polymer particles. The interjacent complexes may be used to treat a waste sludge by adding an effective amount thereof to the waste sludge. The interjacent complexes may also be used in making paper by adding an effective amount thereof to a pulp or a forming sheet at a suitable location on a paper making machine. The interjacent complexes may further be used as a rheology modifier in aqueous systems by adding an effective amount thereof to an aqueous medium to effect a desired viscosity, rheology, or flow curve property.Type: ApplicationFiled: April 6, 2009Publication date: July 30, 2009Applicant: WSP CHEMICALS & TECHNOLOGY, LLCInventors: Shih-Ruey T. Chen, Valentino L. DeVito, Kevin W. Frederick
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Publication number: 20090165975Abstract: Compositions and methods of producing paper-based materials are disclosed. In general, the techniques utilize an amine-containing polymer, such as chitosan, to functionalize one or more components of a mixture used to form materials such as paper-based materials. Such components can include the fibers of a pulp and/or filler particles. In one instance, either the pulp or the filler particles are functionalized, but not both. Such functionalization can improve the qualifies of a paper-based material relative to when such functionalization is not utilized. Techniques and compositions are also described to further improve the qualities of a paper material by utilizing a complementary polymer which can couple with the amine-containing polymer.Type: ApplicationFiled: August 1, 2008Publication date: July 2, 2009Applicant: NanoPaper, LLCInventors: David S. Soane, Michael C. Berg, William A. Mowers
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Patent number: 7473333Abstract: The present invention refers to a method of producing a coated paper or paperboard, but excluding photographic papers, comprising the steps of: (a) forming a free flowing curtain comprising at least one layer, whereby the composition forming at least one layer of the free flowing curtain has a high shear viscosity of at least about 50 mPa·s, and (b) contacting the curtain with a continuous web substrate of basepaper and paperboard.Type: GrantFiled: October 16, 2003Date of Patent: January 6, 2009Assignee: Dow Global Technologies Inc.Inventors: Robert Urscheler, Pekka J. Salminen, Jamel F. Attai, John A. Roper, III
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Publication number: 20080283207Abstract: Methods to control organic contaminants in fibers are described. One method involves contacting the fibers with a composition containing water-soluble cellulose derivative and ester hydrolyzing enzyme, for a sufficient time and in a sufficient amount to control the organic contaminants present in the fibers. This method is effective to reduce stickies in paper mill furnish formed with recycled fibers. A method for pitch control in paper mill furnish formed with virgin fibers is also provided by the additional inclusion of lipoxygenase in the composition. Resulting paper products formed from the processed fibers are also described as well as methods to make them.Type: ApplicationFiled: May 13, 2008Publication date: November 20, 2008Applicant: BUCKMAN LABORATORIES INTERNATIONAL, INC.Inventor: George S. Thomas
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Publication number: 20080223536Abstract: The invention relates to paper comprising a filler and a cellulose ether wherein the cellulose ether comprises a quaternary ammonium group, with the proviso that the cellulose ether is not a hydroxyethyl cellulose.Type: ApplicationFiled: December 21, 2004Publication date: September 18, 2008Applicant: ANZO NOBEL N.V.Inventor: Peter Marten Van Der Horst
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Patent number: 7294189Abstract: An emulsion comprising water as the continuous phase, a wax as the discontinuous phase, an emulsifier and a preservative having the general structure: wherein R1 can be a heterocycle containing nitrogen and sulfur, such as thiazolyl, isothiazolyl, or thiadiazolyl, which can optionally be substituted with C1–C6 alkyl; R2 can be hydrogen or C1–C6 alkyl, specifically hydrogen; n is 0, 1, 2, or 3; each instance of R3 can independently be hydrogen, C1–C6 alkyl, phenoxy, C1–C6 alkoxy, halo, amino, C1–C6 alkylamino, di C1–C6 alkyl amino, imidazolyl, thiazolyl, isothiazolyl, thiadiazolyl, thienyl, furyl, pyrryl, naphthyl, phenyl, halophenyl, C1–C6 alkyl phenyl, or C1–C6 alkoxyphenyl. The preservative may be added to the emulsion after the emulsion is formed. The emulsion can be incorporated into a gypsum product such as gypsum board or gypsum wood fiber board. The gypsum product may be made by forming a slurry containing gypsum, water, and the emulsion into a solid product.Type: GrantFiled: September 2, 2005Date of Patent: November 13, 2007Assignee: Hexion Specialty Chemicals, Inc.Inventor: Steven Wantling
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Patent number: 7285182Abstract: A composition for surface treatment of paper which includes a nanoparticle fraction, and a carrier fraction for detaining the nanoparticles in the surface layer. The carrier fraction includes plate-like pigment particles, and at least one binder. The invention also relates to the method of manufacturing the composition and to its use.Type: GrantFiled: March 19, 2003Date of Patent: October 23, 2007Assignee: Ciba Specialty Chemicals CorporationInventors: Geoff Mason, Tomi Kimpimäki, Kenneth Sundberg
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Patent number: 7138035Abstract: The present invention relates to an environmentally friendly process for the selective oxidation of carbohydrates. The process comprises the addition of a hydroperoxide, including hydrogen peroxide, to a carbohydrate having primary alcohol groups, particularly including polysaccharides, wherein said carbohydrate is contact with a nitroxyl radical mediator and the process is catalyzed by a peroxidase enzyme in the presence of halide ions.Type: GrantFiled: May 8, 2001Date of Patent: November 21, 2006Assignee: National Starch and Chemical Investment Holding CorporationInventors: Xiaoyuan Cui, A. Levent Cimecioglu, Yong-Cheng Shi
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Patent number: 6998016Abstract: The present invention is a through-air-drying process for producing a fibrous web that possesses not only softness and absorbency but also strength. The method of the present invention monitors and controls the overall charge in the headbox.Type: GrantFiled: December 20, 2001Date of Patent: February 14, 2006Assignee: Fort James CorporationInventors: Kang Chang Yeh, Gary L. Worry, Thomas N. Kershaw, Henry S. Ostrowski
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Patent number: 6958108Abstract: The present invention relates to a modified fiber product and a method of producing same. According to the method, the cellulosic raw material is formed into a fiber suspension, into which components modifying the properties of the fibers are added, subsequent to which the fibrous material is dried in connection with, for example, web forming. According to the invention, alkyl derivative of cellulose is mixed into the fiber suspension in alkaline conditions, the derivative being at least partly dissolved in water, and the derivative is allowed to be sorbed into the fibrous material prior to drying such that the sorbed cellulose derivative can not be washed off with water. The strength properties or the water retention of paper and paperboard products can be improved by using the invention.Type: GrantFiled: April 30, 1999Date of Patent: October 25, 2005Assignee: M-real OyjInventor: Tapani Vuorinen
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Patent number: 6951962Abstract: A water-dispersible oil/grease-sizing and water-sizing agent that provides oil/grease and water-sizing for paper and other cellulosic materials. The agent works effectively for both oil/grease and water sizing at high temperatures. The polymeric agent's key features include a polyamine component which is a repeating monomer unit with cellulose-reactive and fluorinated groups substituted on the polyamine.Type: GrantFiled: April 12, 2002Date of Patent: October 4, 2005Assignee: Hercules IncorporatedInventor: Kyle J. Bottorff
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Patent number: 6896725Abstract: The invention concerns the use of a water-soluble or water-dispersible polymer having a molecular weight of at least 800, containing at least 5 aldehyde groups per molecule and at least 1 carboxyl group per molecule, the ratio of aldehyde groups to carboxyl groups being higher than 0.75:1, as a wet strength additive. The invention also discloses novel cationic derivatives thereof.Type: GrantFiled: April 25, 2003Date of Patent: May 24, 2005Assignee: SCA Hygiene Products Zeist B.V.Inventors: Jeffrey Wilson Thornton, Dorine Lisa Van Brussel-Verraest, Arie Besemer, Sussan Sandberg
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Patent number: 6716314Abstract: A method for forming an abrasion resistant sheet which comprises forming a web of cellulosic fibers on a papermaking machine and applying a slurry including an encapsulated abrasion-resistant grit to the upper surface of the web on the papermaking machine.Type: GrantFiled: February 27, 2001Date of Patent: April 6, 2004Assignee: MeadWestvaco CorporationInventors: Mark A. Johnson, John Benson, Mahendra Mehta, Steve Canary, Eric Girardin
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Patent number: 6620295Abstract: Modified polysaccharides (such as starches, gums, chitosans, celluloses, alginates, sugars, etc.), which are commonly used in the paper industry as strengthening agents, surface sizes, coating binders, emulsifiers and adhesives, can be combined into a single molecule with amphiphilic hydrocarbons (e.g. surface active agents) which are commonly utilized in the paper industry to control absorbency, improve softness, enhance surface feel and function as dispersants. The resulting molecule is a modified polysaccharide having surface active moieties which can provide several potential benefits, depending on the specific combination employed, including: (a) strength aids that do not impart stiffness; (b) softeners that do not reduce strength; (c) wet strength with improved wet/dry strength ratio; (d) debonders with reduced linting and sloughing; (e) strength aids with controlled absorbency; and (f) surface sizing agents with improved tactile properties.Type: GrantFiled: September 5, 2002Date of Patent: September 16, 2003Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Thomas Gerard Shannon, Daniel Arthur Clarahan, Mike Thomas Goulet, Wen Zyo Schroeder
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Patent number: 6596126Abstract: Modified polysaccharides (such as starches, gums, chitosans, celluloses, alginates, sugars, etc.), which are commonly used in the paper industry as strengthening agents, surface sizes, coating binders, emulsifiers and adhesives, can be combined into a single molecule with modified aliphatic hydrocarbons, which are commonly utilized, in conjunction with cationic moieties, as softeners, debonders, lubricants and sizing agents. The resulting molecule is a modified polysaccharide having an aliphatic moiety which can provide several potential benefits, depending on the specific combination employed, including: (a) strength aids that do not impart stiffness; (b) softeners that do not reduce strength; (c) wet strength with improved wet/dry strength ratio; (d) debonders with reduced linting and sloughing; (e) strength aids with controlled absorbency; and (f) surface sizing agents with improved tactile properties.Type: GrantFiled: January 20, 2000Date of Patent: July 22, 2003Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Thomas Gerard Shannon, Daniel Arthur Clarahan, Mike Thomas Goulet, Wen Zyo Schroeder
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Patent number: 6582559Abstract: The invention concerns the use of a water-soluble or water-dispersible polymer having a molecular weight of at least 800, containing at least 5 aldehyde groups per molecule and at least 1 carboxyl group per molecule, the ratio of aldehyde groups to carboxyl groups being higher than 0.75:1, as a wet strength additive. The invention also discloses novel cationic derivatives thereof.Type: GrantFiled: May 4, 2001Date of Patent: June 24, 2003Assignee: SCA Hygiene Products Zeist B.V.Inventors: Jeffrey Wilson Thornton, Dorine Lisa Van Brussel-Verraest, Arie Besemer, Sussan Sandberg
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Patent number: 6547927Abstract: There is disclosed a water-decomposable fibrous sheet including water-dispersible fibers and water-insoluble carboxymethyl cellulose. The water-insoluble carboxymethyl cellulose has a degree of substitution for etherification (DE) falling between 0.3 and 0.6. In the water-insoluble carboxymethyl cellulose, the hydrogen of the carboxyl group in at least 95% of the carboxymethyl groups is substituted with a metal.Type: GrantFiled: September 18, 2000Date of Patent: April 15, 2003Assignee: Uni-Charm CorporationInventors: Naohito Takeuchi, Takayoshi Konishi, Jyoji Shimizu
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Patent number: 6540876Abstract: This invention pertains to the use of compounds containing amide or imide type functional groups to increase the rate of nitroxide mediated oxidation of alcohols, particularly primary and secondary alcohols. While suitable for oxidation of alcohol groups on a variety of substrates, it is particularly useful to oxidize cellulose, cellulose pulp or cellulose fiber such that it is commercially compatible with the traditional paper making process. Such co-catalysts may be used to increase the absolute amount of aldehyde groups on cellulose, cellulose pulp or cellulose fiber, thereby further increasing the inherent wet strength, temporary wet strength, and dry strength of paper made with such cellulose, cellulose pulp or cellulose fiber.Type: GrantFiled: May 19, 2000Date of Patent: April 1, 2003Assignee: National Starch and Chemical Ivnestment Holding CorporationInventors: A. Levent Cimecioglu, John S. Thomaides, Kraig A. Luczak, Danielle E. Harkins
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Publication number: 20030045707Abstract: The present invention provides a polymer derived from a cellulosic, lignocellulosic, or polysaccharide material having superabsorbent properties. Methods for making the polymer and personal care absorbent products that incorporated the polymer are also provided.Type: ApplicationFiled: August 5, 2002Publication date: March 6, 2003Applicant: Weyerhaeuser CompanyInventors: Hugh West, John A. Westland
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Patent number: 6521088Abstract: This invention is directed to degraded, hydrated particulate starches that are hydrophobically modified and a method of providing paper with reduced porosity, resistance to liquid penetration and increased surface strength comprising applying to the surface of a paper substrate an effective amount of a surface sizing composition which comprises such starch. In particular, the starches are those in which the starch base is degraded to a water fluidity (WF) of from about 10 to 80 or the modified and/or particulate starch is degraded using a substantially equivalent amount of degradation agent and substantially the same reaction conditions, the starch is modified with a hydrophobic hydrocarbon group of 5 to 23 carbon atoms at about 1 to 20% substitution level by weight of bound hydrophobe based on the weight of starch, and the hydrated starch has a volume average hydrated particle size of at least about 20 microns and a volume fraction of hydrated particles at 1% solids of at least about 5%.Type: GrantFiled: October 27, 2000Date of Patent: February 18, 2003Assignee: National Starch and Chemical Investment Holding CorporationInventors: Paul H. Richardson, Ralph M. Trksak, John J. Tsai, Eric M. Weisser
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Patent number: 6517678Abstract: Modified polysaccharides (such as starches, gums, chitosans, celluloses, alginates, sugars, etc.), which are commonly used in the paper industry as strengthening agents, surface sizes, coating binders, emulsifiers and adhesives, can be combined into a single molecule with amphiphilic hydrocarbons (e.g. surface active agents) which are commonly utilized in the paper industry to control absorbency, improve softness, enhance surface feel and function as dispersants. The resulting molecule is a modified polysaccharide having surface active moieties which can provide several potential benefits, depending on the specific combination employed, including: (a) strength aids that do not impart stiffness; (b) softeners that do not reduce strength; (c) wet strength with improved wet/dry strength ratio; (d) debonders with reduced linting and sloughing; (e) strength aids with controlled absorbency; and (f) surface sizing agents with improved tactile properties.Type: GrantFiled: January 20, 2000Date of Patent: February 11, 2003Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Thomas Gerard Shannon, Daniel Arthur Clarahan, Mike Thomas Goulet, Wen Zyo Schroeder
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Patent number: 6503370Abstract: Method of producing paper having a three-dimensional pattern of alternating raised and recessed portions which is given the paper in connection with impulse drying, at which the wet paper web is passed through at least one press nip (12) comprising a rotatable roll (13) which is heated and that the paper web when passing through the press nip is given a three-dimensional pattern either by means of a pattern wire (11) and/or by the fact that the heated roll (13) is provided with a three-dimensional pattern, and where the wet paper web (10) before entering said press nip (12) is given a basis weight variation in a non-random pattern.Type: GrantFiled: April 2, 2001Date of Patent: January 7, 2003Assignee: SCA Hygiene Products ABInventors: Holger Hollmark, Lennart Reiner, Thomas Billgren, Kaveh Tondkar, Mats Söderberg, Bengt Järrehult
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Patent number: 6461476Abstract: The ratio of the wet tensile strength to the dry tensile strength of uncreped throughdried tissues and towels can be increased by treating the papermaking pulp with a debonder, a wet strength agent and a dry strength agent. The properties of the resulting product can be manipulated to either provide a product with normal degree of softness (as measured by the machine direction sheet stiffness) and a high wet strength, or a normal degree of wet strength and a higher degree of softness.Type: GrantFiled: May 23, 2001Date of Patent: October 8, 2002Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Mike Thomas Goulet, Heath David Van Wychen
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Patent number: 6455661Abstract: A graft polymer comprises a carbohydrate polymer having pendant 3-amino-2-hydroxy propyl groups grafted thereon and may be employed as a retention aid and strengthening additive in paper manufacture. When the carbohydrate polymer is a component of wood pulp the resulting chemically modified wood pulp may be employed in conjunction with unmodified wood pulp to incorporate therein the retention and strengthening characteristics.Type: GrantFiled: July 2, 2001Date of Patent: September 24, 2002Assignee: Pulp and Paper Research Institute of CanadaInventors: Miroslav Antal, Makhlouf Laleg, Ivan Ignac Pikulik
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Publication number: 20020117277Abstract: A process for forming an abrasion resistant, printable sheet which comprises forming a web of cellulosic fibers on a papermaking machine and applying a slurry including an abrasion-resistant grit to the upper surface of the web on the papermaking machine and then applying a secondary web of cellulosic fibers over said grit to form a three layer overlay product.Type: ApplicationFiled: November 8, 2001Publication date: August 29, 2002Inventors: Mark A. Johnson, John Benson, Mahendra Mehta, Steve Canary, Eric Girardin
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Patent number: 6419789Abstract: The present invention is a through-air-drying process for producing a fibrous web that possesses not only softness and absorbency but also strength. The method of the present invention monitors and controls the overall charge in the headbox.Type: GrantFiled: October 11, 1996Date of Patent: July 16, 2002Assignee: Fort James CorporationInventors: Kang Chang Yeh, Gary L. Worry, Thomas N. Kershaw, Henry S. Ostrowski
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Patent number: 6398860Abstract: A sizing agent composition for printing paper comprising (A) a water-soluble diorganopolysiloxane described by formula where each R is independently selected from the group consisting of a hydrogen atom, methyl group, and ethyl group, each R1 is an independently selected monovalent hydrocarbon group comprising 1 to 20 carbon atoms, Q is an organic group comprising an amino group or quaternary ammonium salt, m is an integer equal to or greater than 2, n is 0 or an integer equal to or greater than 1, and (m+n) is in the range of 2 to 100; (B) a sizing agent; and (C) water.Type: GrantFiled: August 4, 2000Date of Patent: June 4, 2002Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Isao Ona, Hiroki Ishikawa, Tadashi Takimoto, Tsutomu Naganawa
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Patent number: 6398911Abstract: Modified polysaccharides (such as starches, gums, chitosans, celluloses, alginates, sugars, etc.), which are commonly used in the paper industry as strengthening agents, surface sizes, coating binders, emulsifiers and adhesives, can be combined into a single molecule with modified aliphatic hydrocarbons, which are commonly utilized, in conjunction with cationic moieties, as softeners, debonders, lubricants and sizing agents. The resulting molecule is a modified polysaccharide having an aliphatic moiety which can provide several potential benefits, depending on the specific combination employed, including: (a) strength aids that do not impart stiffness; (b) softeners that do not reduce strength; (c) wet strength with improved wet/dry strength ratio; (d) debonders with reduced linting and sloughing; (e) strength aids with controlled absorbency; and (f) surface sizing agents with improved tactile properties.Type: GrantFiled: January 21, 2000Date of Patent: June 4, 2002Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Wen Zyo Schroeder, Daniel Arthur Clarahan, Mike Thomas Goulet, Thomas Gerard Shannon
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Patent number: 6346170Abstract: Compositions suitable for use as dry strength additives comprising water soluble polyamidoamine/epchlorohydrin resin bearing polyol sidechains wherein the weight fraction of the polyol in the resin is less than 50 percent by weight and the polyol sidechain is attached to the polyamidoamine/epichlorohydrin resin by carbon-nitrogen bond, such as amide bond or secondary or tertiary amine bonds.Type: GrantFiled: September 20, 2000Date of Patent: February 12, 2002Assignee: Hercules IncorporatedInventor: Barton K. Bower
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Patent number: 6306255Abstract: The invention relates to an aqueous disperion containing a cellulose-reactive sizing agent and an anionic hydrophobicailly modified cellulose-derivative, its preparation and use in the production of paper. The invention also relates to a substantially water-free composition containing a cellulose-reactive sizing agent and an anionic hydrophobicailly modified cellulose-derivative, its preparation and use in the preparation of an aqueous dispersion of cellulose-reactive sizing agent. The invention further relates to a process for sizing cellulosic fibers by addition of an aqueous sizing dispersion containing a cellulose-reactive sizing agent and a hydroically modified dispersing agent to a stock containing cellulosic fibers, and optional fillers, and dewatering the stock on a wire to obtain a web containing cellulosic fibers.Type: GrantFiled: May 15, 2000Date of Patent: October 23, 2001Assignee: Akzo Nobel NVInventors: Sten Frölich, Erik Lindgren, Rein Sikkar
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Patent number: 6296696Abstract: A one-pass, non-tolerance dependent method for preparing paper size emulsions comprising an aqueous emulsion of a substituted cyclic dicarboxylic anhydride, a colloidal stabilizer, and a surfactant wherein the emulsion after one-pass through a dispersion system has an average particle size of less than 2 microns.Type: GrantFiled: December 15, 1998Date of Patent: October 2, 2001Assignee: National Starch & Chemical Investment Holding CorporationInventors: Michel D. Létourneau, Walter Maliczyszyn
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Patent number: 6290813Abstract: A smooth-textured non-woven, superabsorbent particle-impregnated fibrous structure is disclosed. The web exhibits an improved smooth surface texture. The structure contains from 50% to 80% of ion sensitive SAP having a particle size of less than 200 microns, wood pulp fibers and cellulose acetate fibers, each in preferred specified amounts indicated herein. The superabsorbent, ion sensitive polymer particle-impregnated fibrous structure is made from an aqueous, wet-lay process in which an aqueous furnish comprises solids of fibers and superabsorbent, ion sensitive polymer and dissolved salt, such as preferably, Na2SO4. The furnish is passed over a moving foraminous support, such as a Fourdrinier wire, and a wet web structure is formed, followed by drying.Type: GrantFiled: October 8, 1999Date of Patent: September 18, 2001Assignee: BASF CorporationInventor: G. Thomas Woodrum
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Patent number: 6290815Abstract: The invention relates to a paper sheet containing grit particles giving it, in use, a high abrasion resistance. It is characterized in that it contains grit particles coated in a non-abrasive material, in particular in a polymer. According to the invention, the particles are chosen from alumina, silica, boron nitride, silicon carbide, titanium carbide, tungsten carbide, zirconium oxide, cerium oxide, glass and ceramic particles, or mixtures thereof. The invention also relates to the laminates containing it, as well as to the processes for manufacturing the sheets and the laminates.Type: GrantFiled: September 3, 1997Date of Patent: September 18, 2001Assignee: Arjo Wiggins S.A.Inventors: Henri Magnin, Claude Perrin, Pierre Caulet
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Patent number: 6267844Abstract: A paper production process, characterized by the process step of providing to the paper at some point in the production process a compound of formula (I) which reduces the tendency of the obtained paper products, particularly those made from high-yield pulps, to yellow on exposure to light.Type: GrantFiled: April 30, 1999Date of Patent: July 31, 2001Assignee: Clariant Finance (BVI) LimitedInventor: Andrew Clive Jackson
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Patent number: 6241853Abstract: A soft, flexible yet strong paper product is provided from the unique configuration of particular pulp types, cationic wet strength resins, and anionic processing aids.Type: GrantFiled: December 10, 1998Date of Patent: June 5, 2001Assignee: Kimberly Clark Worldwide, Inc.Inventors: Michael John Smith, Gary L. Bushman
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Patent number: 6228895Abstract: This invention relates to compositions, paper, thermoplastic sheets, and medical paper containing cellulose ester alkylpolyglycoside (APG) or a mixture of APG and polyether glycol, and, optionally, cellulose. The process of incorporating APG or a mixture of APG and polyether glycol in paper composed of cellulose ester fibers and cellulose fibers and to calendaring of such paper is also disclosed.Type: GrantFiled: November 30, 1998Date of Patent: May 8, 2001Assignee: Eastman Chemical CompanyInventors: Charles Michael Buchanan, Eric Eugene Ellery, Matthew Davie Wood
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Patent number: 6228218Abstract: A water-disintegratable cleaning sheet consisting of a fibrous sheet having incorporated thereinto, a binder of alkylcellulose; an electrolyte, and (a) a copolymer of a polymerizable acid anhydride and other compounds and/or (b) an amino acid. The water-disintegratable cleaning sheet has excellent water disintegratability and wet strength and further it is not degraded in the water disintegratability and wet strength after storage at high temperatures.Type: GrantFiled: December 24, 1998Date of Patent: May 8, 2001Assignee: Uni-Charm CorporationInventors: Naohito Takeuchi, Takayoshi Konishi, Ryuichiro Kurata, Nobuo Morohashi, Masayoshi Matsumoto
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Patent number: 6193843Abstract: Cationic polysaccharide derivatives are prepared by reacting a polysaccharide with a polycationic reagent having one polysaccharide reactive group and at least two cationic groups. Suitable reagents include polycationic alkyl, aryl, alkaryl, cycloaliphatic, or heterocyclic amines, some of which are novel compositions. The polycationic polysaccharide derivatives prepared from these reagents are useful in the manufacture of paper.Type: GrantFiled: June 1, 1994Date of Patent: February 27, 2001Assignee: National Starch and Chemical Investment Holding CorporationInventors: John (Ji-Hsiung) Tsai, Peter T. Trzasko, Michael T. Philbin, Robert L. Billmers, Martin M. Tessler, Joseph A. Van Gompel, Morton W. Rutenberg
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Patent number: 6165259Abstract: The invention relates to an aqueous dispersion containing a dispersant and a disperse phase containing a hydrophobic material, the dispersant comprising an anionic compound having a molecular weight less than 50,000 and being selected from the group consisting of carbon-containing compounds and silicon-containing compounds, and a cationic organic compound having a molecular weight less than 50,000. The invention further relates to the preparation and use of the dispersion in the production of paper. The invention also relates to a substantially water-free composition containing a hydrophobic material, an anionic compound having a molecular weight less than 50,000 and being selected from carbon-containing compounds and silicon-containing compounds, and a cationic organic compound having a molecular weight less than 50,000, as well as it use in the preparation of an aqueous dispersion.Type: GrantFiled: February 3, 1998Date of Patent: December 26, 2000Assignee: Akzo Nobel N.V.Inventors: Hans Hallstrom, Sten Frolich, Erik Lindgren, Rein Sikkar
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Patent number: 6132557Abstract: A water-disintegratable fibrous sheet comprising a web of fibers comprising pulp of hardwood and pulp of conifer, pulp of conifer having a fiber length longer than that of the pulp of hardwood, and a water-insoluble or water-swellable binder being contained in the web to bind the fibers, is disclosed. The fibrous sheet is excellent in water-disintegratability and has sufficient strength for withstanding practical use. Furthermore, since excellent water-disintegratability and strength can be obtained without using a water-soluble binder, a production process of the fibrous sheet can be made simple.Type: GrantFiled: September 4, 1998Date of Patent: October 17, 2000Assignee: Uni-Charm CorporationInventors: Naohito Takeuchi, Takayoshi Konishi
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Patent number: 6123811Abstract: An aqueous slurry for manufacturing water soluble or dispersible paper for use in medical device packaging. The slurry has a solid component consisting of methylcellulose and paper pulp. The slurry also has a liquid component consisting of water and an alkylalcohol. The methylcellulose remains in a substantially undissolved state in the aqueous slurry.Type: GrantFiled: December 14, 1998Date of Patent: September 26, 2000Assignee: Ethicon, Inc.Inventors: Peter Komarnycky, Robert J. Cerwin
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Patent number: 6114417Abstract: Sizing agents comprised of dispersed synthetic polymers in an aqueous solution are provided, as well as methods for making these sizing agents and methods for using these sizing agents to size paper. Improved sizing is obtained by including recurring units of methyl acrylate, ethyl acrylate and/or propyl acrylate in the synthetic polymers.Type: GrantFiled: October 16, 1998Date of Patent: September 5, 2000Assignee: Cytec Technology Corp.Inventors: Michael Philip O'Toole, Otto S. dePierne
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Patent number: 6054022Abstract: A method is provided for forming a wet-laid nonwoven glass fiber mat comprised of a plurality of bundles of fibers. The method includes the steps of adding chopped fibers to a water slurry containing a sufficient amount of a suitable hydrophobic agent to cause the fibers to form a plurality of bundles. The fibers are then formed into a mat which may be used in a number of reinforcement applications. A method is also provided for modifying the components in the water slurry to produce mats comprising either bundles of fibers or dispersed fibers.Type: GrantFiled: March 6, 1998Date of Patent: April 25, 2000Assignees: Owens-Corning Veil U.K. Ltd., Owens Corning Fiberglas Technology, Inc.Inventors: Gregory S. Helwig, Vallipuram Pathmanathan, Robert W. Heseltine