With Organic Agent Patents (Class 162/5)
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Patent number: 5658426Abstract: Deinking of printed paper is accomplished by repulping and defibering the printed paper in an alkaline aqueous medium containing a deinking composition to form an ink and pulp medium. The deinking composition is an alkoxylated lanolin derivative containing from about 55 to about 80% by weight of ethylene oxide and from about 15 to about 30% by weight of propylene oxide, based on the weight of the alkoxylated lanolin derivative.Type: GrantFiled: July 20, 1995Date of Patent: August 19, 1997Assignee: Geo Specialty Chemicals, Inc.Inventors: Gail M. Howell, Jose M. Rodriguez, Anthony B. Cook
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Patent number: 5651861Abstract: A process for removing oil-based inks and/or waterborne inks under slightly acidic, neutral or alkaline conditions by using either a flotation technique and/or a washing technique by using a novel deinking agent having a quarternized nitrogen group is provided.Type: GrantFiled: December 18, 1995Date of Patent: July 29, 1997Assignee: Rhone-Poulenc Inc.Inventors: Eric Heath Larson, Marie Odile Lafon
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Patent number: 5643409Abstract: A deinking method which comprises adding a specified nonionic surfactant having a specified solubility parameter as an essential component, during in the pulping step (the preceding step) and in any of the subsequent steps (the succeeding step). By use of the deinking surfactant composition and the deinking method of the present invention, an excellent deinking performance, including an elevated whiteness, a decrease in the number of unliberated large ink spots and an improved defoaming property of the flotation reject, can be achieved in deinking waste papers, in particular, waste OA papers and blends containing thereof.Type: GrantFiled: September 28, 1994Date of Patent: July 1, 1997Assignee: Kao CorporationInventors: Koji Hamaguchi, Yoichi Ishibashi, Hideaki Urushibata
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Patent number: 5639346Abstract: An improved process is disclosed for removing "stickies" from waste paper which contains hot-melt and pressure-sensitive adhesives and lattices to produce high quality (high brightness, little to no dirt content) pulp with little or no fiber loss. The process involves attachment of sticky particles in the waste paper pulp to a magnetic carrier material with the help of an agglomeration agent followed by removal of the attached sticky particles by magnetic separation. The magnetic treatment preferably is conducted at ambient or greater temperature, at neutral to alkaline pH, and at a low pulp consistency. Agglomeration and magnetite addition, followed by exposure of the repulped waste paper to a magnetic field provides near complete sticky removal over exposure to the magnetic field without such pre-treatment.Type: GrantFiled: May 22, 1995Date of Patent: June 17, 1997Assignee: Westvaco CorporationInventors: Nipun Marwah, Allen A. Gold
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Patent number: 5637191Abstract: A process of de-inking waste paper can be operated under conditions using a simple combination of chemicals to result in a waste liquor that is substantially environmentally friendly. The process comprises forming a pulp from the waste paper in a aqueous medium that has a pH of between 6 and 9 and that is substantially free of dissolved phosphate and that includes an ink-dispersing amount of polycarboxylic acid dispersing agent, and separating the ink from the pulp. The use of a cationic surfactant for promoting flotation is particularly desirable.Type: GrantFiled: October 17, 1994Date of Patent: June 10, 1997Assignee: Allied Colloids LimitedInventors: John G. Langley, Timothy G. Bingham, John O. Stockwell
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Patent number: 5635023Abstract: A flotation process for removing toner particles from photocopied paper which utilizes the following compound as a collector: ##STR1## wherein R is an alkyl, aryl, alkylaryl or allyl group having from 4-28 carbon atoms and, preferably from 6-10 carbon atoms, and M represents an alkali metal, or alkaline earth metal radical or a hydrogen atom.Type: GrantFiled: August 21, 1995Date of Patent: June 3, 1997Assignee: Nord Kaolin CompanyInventor: Jerry L. Curtis
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Patent number: 5632857Abstract: A process for removing water borne flexographic inks from paper stock comprising the steps of (a) forming a slurry by pulping paper containing water borne flexographic inks in an aqueous medium having a pH of greater than 8 which includes: (1) one or more basic agents; (2) one or more nonionic surfactants; (3) one or more anionic polyelectrolytes; and (4) an amount of paper different from that being processed which contains inorganic fillers, coatings or mixtures thereof; and (b) subjecting the slurry produced in step (a) to a flotation cell having an aqueous medium having a pH of greater than 8 which includes: (1) one or more basic agents; (2) one or more nonionic surfactants; and (3) one or more anionic polyelectrolytes is provided.Type: GrantFiled: April 4, 1995Date of Patent: May 27, 1997Assignee: Rhone-Poulenc Inc.Inventor: Eric H. Larson
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Patent number: 5624569Abstract: The invention is a method for clarifying ink-containing effluent water from recycled paper production which comprises the step of adding a water-soluble, surface active, silicon-containing polyelectrolyte polymer coagulant to the ink-containing effluent water from recycled paper production, wherein the polymer has from 0.01 to 10 mole percent of a vinyl alkoxysilane monomer. A preferred silicon-containing polyelectrolyte polymer is the product of a free radical synthesis from vinyltrimethoxysilane and diallyldimethylammoniumchloride monomers.Type: GrantFiled: January 23, 1996Date of Patent: April 29, 1997Assignee: NALCO Chemical CompanyInventors: Daniel K. Chung, Manian Ramesh, Karen R. Tubergen
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Patent number: 5622597Abstract: A process for deinking recycled paper using a pressurized deinking module to separate ink from paper pulp stock. The addition of salts of imidazolinium based compounds with alkyl, alkenyl and amidoethyl side chains to the pulp slurry at the beginning of the pressurized deinking module cycle removes ink more effectively and results in a brighter recycled paper and an increase in yield of final paper stock.Type: GrantFiled: January 24, 1995Date of Patent: April 22, 1997Assignee: Callaway CorporationInventors: John W. Callen, Alicia Anderson-Norris
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Patent number: 5609722Abstract: Wastepaper containing printing ink is refined in the presence of the reaction products of epoxidized derivatives of C.sub.10 -C.sub.22 carboxylic acids with alkoxylated carbohydrate-derived polyols and the detached printing ink particles are subsequently removed from the paper stock suspensions by flotation or washing.Type: GrantFiled: December 1, 1995Date of Patent: March 11, 1997Assignee: Henkel CorporationInventors: Jos e M. Rodriguez, Anthony B. Cook, Gail M. Howell
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Patent number: 5607544Abstract: The present invention provides a process for the oxidative bleaching of wood pulps and for deinking waste paper by means of hydrogen peroxide and a stabilizing agent, wherein, as stabilizing agent, there is used 2-oxo-2-(4-hydroxyphenyl)-acethydroximic acid chloride (N,4-dihydroxy-.alpha.Type: GrantFiled: March 27, 1995Date of Patent: March 4, 1997Assignee: BK Ladenburg GmbH fur Chemische ErzeugnisseInventors: Wolfram Salzburger, Silke Eifler, Margarete Scholl
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Patent number: 5601767Abstract: A process for the production of a cellulose moulded body, particularly cellulose fibres, characterized by the combination of the measures offeeding a cellulose-containing material into an aqueous solution of a tertiary amine-oxide in order to suspend said cellulose-containing material,removing water from the suspension while intensively mixing it and providing elevated temperature and reduced pressure, until a solution of cellulose is produced andmoulding said solution by means of a moulding device, particularly a spinneret, and introducing it into a precipitation bath in order to precipitate the dissolved cellulose,provided that as said cellulose-containing material, basically shredded waste paper, shredded cellulose-containing fibre assemblies and/or shredded, mechanically and/or chemically broken up annual plants are used.Type: GrantFiled: June 6, 1995Date of Patent: February 11, 1997Assignee: Lenzing AktiengesellschaftInventors: Heinrich Firgo, Dieter Eichinger, Markus Eibl
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Patent number: 5601689Abstract: A process for removing a xerographic image from a substrate which comprises contacting the image with an aqueous solution comprised of water, a surfactant, ionic salts and caustic reagent.Type: GrantFiled: February 27, 1995Date of Patent: February 11, 1997Assignee: Xerox CorporationInventors: Guerino G. Sacripante, David F. Rutland, Walter Mychajlowskij, J. Stephen Kittelberger
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Patent number: 5585339Abstract: A deinking composition which comprises a specified nonionic surfactant having a specified solubility parameter as an essential component.A deinking method which comprises adding the above-described deinking composition during in the pulping step (the preceding step) and in any of the subsequent steps (the succeeding step).By use of the deinking composition and the deinking method of the present invention, an excellent deinking performance, including an elevated whiteness, a decrease in the number of unliberated large ink spots and an improved defoaming property of the flotation reject, can be achieved in deinking waste papers, in particular, waste OA papers and blends containing thereof.Type: GrantFiled: September 28, 1994Date of Patent: December 17, 1996Assignee: Kao CorporationInventors: Koji Hamaguchi, Yoichi Ishibashi, Hideaki Urushibata
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Patent number: 5582681Abstract: A sanitary paper product made from newspapers containing coarse cellulosic fibers and printed with ink that contains oil and a method for making the same is provided. The method has the step of (a) pulping the newspapers in water with agitation to produce a pulp slurry at a consistency between 3% and 12% and a pH below about 8.0; (b) adding to the slurry an enzyme selected from the group consisting of cellulase, hemicellulase, and lipase and maintaining the pulp slurry at a temperature above about 100.degree. F. for at least 15 minutes; (c) maintaining at least about 2% of the of oil in contact with the newspaper fibers beginning with the making of the pulp slurry in step (a) through step (b); and using the enzyme treated pulp as a major source of fiber in the paper making process to produce a sanitary paper products.Type: GrantFiled: June 29, 1994Date of Patent: December 10, 1996Assignee: Kimberly-Clark CorporationInventors: Sangho Back, Nicholas W. Lazorisak, Norman L. Smeltzer, John F. Schmitt, Reginald Smith
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Patent number: 5575893Abstract: A method for conditioning the felts in a papermaking process utilizing deinked secondary fiber in the furnish by adding a felt conditioner consisting of from 5-33% of a nonionic surfactant, from 5-33% of a dispersant, or blends thereof, with the remainder water; wherein the nonionic surfactant is selected from the group consisting of ethoxylated nonylphenols having moles of ethoxylation of from 7.5 to 30 and an HLB of about 12 to 17.2 and di-alkyl phenol ethoxylates having moles of ethoxylation of from 15 to 24 and an HLB of about 13 to 15.1; and wherein the dispersant is selected from the group consisting of the sodium salt of naphthalene sulfonate formaldehyde-condensate having an average molecular weight of from about 700 to 3500, the potassium salt of polymerized alkyl naphthalene sulfonic acid having an average molecular weight of approximately 1000, or the sodium or ammonium salt of lignosulfonate. Additionally, from 1 to 5% of an alkylether hydroxypropyl sultaine enhances performance.Type: GrantFiled: March 15, 1995Date of Patent: November 19, 1996Assignee: BetzDearborn Inc.Inventors: Abdul Q. Khan, Kevin D. Curham, Jeffrey R. Cowart
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Patent number: 5573636Abstract: A recyclable support material and process of recycling the support material is disclosed in which the support material comprises a cellulose containing carrier and a radiation cured layer, and the radiation cured layer contains a solid which can be anchored to a limited extent. This support material can be reprocessed and recycled by aqueous reprocessing processes which are conventional within the paper industry.Type: GrantFiled: February 1, 1994Date of Patent: November 12, 1996Assignee: Felix Schoeller jr Papierfabriken GmbH & Co. KGInventors: Wieland Sack, Karl-Hermann Krauss, Reiner Mehnert, Peter Klenert
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Patent number: 5573640Abstract: A composition of paper comprising 99 to 10 weight percent cellulose fibers and 1 to 90 weight percent cored cellulose fibers that are uniformly dispersed within the paper. The cored cellulose fibers are composed of a cellulose sheath that is 4 to 15 weight percent of the weight of the fiber and a cellulose acetate core. The cored cellulose fibers contain no substantial crimp and have an average length of 1 to 7 mm, a density of 1.20 to about 1.35 gm/cc, a denier 1 to 30 grams per 9,000 meters and a uniform dispersion index of less than 0.15.Type: GrantFiled: July 28, 1995Date of Patent: November 12, 1996Assignee: Eastman Chemical CompanyInventors: Tim J. Frederick, Melvin G. Mitchell, Lee R. Partin
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Patent number: 5573675Abstract: The invention relates to the clarification of deinking process waters which result from the recycling of paper. More specifically, the present invention relates to the use of containing vinylamine as water clarifying agents in said processes.Type: GrantFiled: May 11, 1995Date of Patent: November 12, 1996Assignee: Nalco Chemical CompanyInventors: Anthony G. Sommese, Karen R. Tubergen, Daniel K. Chung
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Patent number: 5567272Abstract: The present invention relates to a process for recycling silicone-coated paper by disintegration and new formation of sheets, which comprises carrying out the disintegration in the presence of one or more salts of monophosphoric esters.Type: GrantFiled: August 28, 1995Date of Patent: October 22, 1996Assignee: Hoechst AktiengesellschaftInventors: Peter Hentzschel, Walter Kamutzki, Dieter Wolf
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Patent number: 5562803Abstract: Paper pulp, especially recycled paper pulp which has been deinked, is bleached in a synergistic two-stage process first with sodium bisulfite and then with sodium borohydride. The borohydride is preferably added in an aqueous mixture with sodium hydroxide. A weak acid such as acetic acid may be added to the pulp to advance further the brightness gain.Type: GrantFiled: November 18, 1994Date of Patent: October 8, 1996Assignee: Morton International, Inc.Inventors: David L. K. Wang, Patrick Meyers
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Patent number: 5560805Abstract: A method for bleaching pulp containing pulp from color dyed waste paper, wherein the method comprises bleaching the pulp with a bleaching chemical, especially sodium hydrosulfite, in the presence of a selected ethoxylated amine.Type: GrantFiled: July 27, 1993Date of Patent: October 1, 1996Assignee: Hoechst Celanese CorporationInventors: Glynn A. Hamilton, Paul W. Shepperd, III
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Patent number: 5560806Abstract: Describes a method for deinking wastepaper printed with electrostatic ink or mixtures thereof with wastepaper printed with impact ink in which a combination of nonionic surfactants are added to an alkaline slurry of the paper fibers. The surfactants are a first nonionic surfactant represented by the formula,R--Ph--(OC.sub.2 H.sub.4).sub.m --(OC.sub.3 H.sub.6).sub.n --(OC.sub.4 H.sub.8).sub.p --R.sup.1and a second nonionic surfactant represented by R.sup.2 --(OC.sub.2 H.sub.4).sub.r --OH, R.sup.3 --(OC.sub.2 H.sub.4).sub.s --R.sup.4 or mixtures of such second nonionic surfactants. R contains 8 to 10 carbon atoms, Ph is phenylene, R.sup.1 is chloro or phenoxy, R.sup.2 contains 10 to 16 carbon atoms, R.sup.3 contains 8 to 14 carbon atoms, R.sup.4 is chloro, the sum of m, n and p is a number of from 1 to 10, r is a number of from 1 to 5 and s is a number of from 0.5 to 15. The ratio of the first to second nonionic surfactants is from 1:100 to 1:1.Type: GrantFiled: April 22, 1994Date of Patent: October 1, 1996Assignee: PPG Industries, Inc.Inventors: Chin Li, Kevin Hipolit, Bhima R. Vijayendran
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Patent number: 5558745Abstract: A process for the treatment of absorbent sanitary paper products to separate such products into components thereof in a form suitable for recycling or re-use is disclosed; absorbent sanitary paper products include disposable diapers, incontinence products, feminine hygiene products, bedpads and other related absorbent and adsorbent products. The process comprises the step of treating said products in at least one bath of an aqueous solution to remove particulate and/or soluble matter from the products. The bath is operated under conditions that are conducive to non-destructive separation of said products into components thereof. In preferred embodiments, the treated product thus obtained is treated with at least one aqueous washing solution and with at least one aqueous solution of at least one of bleaching agent and antimicrobial agent, and separate streams of plastic and cellulosic materials are recovered. The process results in the recovery of usable products from absorbent sanitary paper products.Type: GrantFiled: June 29, 1993Date of Patent: September 24, 1996Assignee: Knowaste Technologies Inc.Inventors: Marlene E. Conway, Francois Jooste, Michael D. Smith
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Patent number: 5549787Abstract: This invention relates to a treatment process of wastepaper for making printing grade paper from newsprints and officewastes using surface active polymer composition including a novel surface active terpolymer. In particular, the invention is concerned with a process for removing ink from an aqueous pulp slurry by treating the pulp with a surface active polymer composing of two to three comonomers in which at least one is a hydrophobe and another is a hydrophil, having a glass transition temperature ranging from about 105.degree. C. to about 170.degree. C., alkali metal salts of the said surface active polymer and the combination of the said surface active polymer with a fatty oil alkoxy derivative or fatty acid soaps.Type: GrantFiled: February 3, 1995Date of Patent: August 27, 1996Inventors: Mohini M. Sain, Claude Daneault
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Patent number: 5540815Abstract: A method of recycling a copy sheet carrying a hydrophobic image thereon by impregnating the sheet with a water-containing separating liquid, causing the to image contact an image separating member, and heating the sheet for thereby transferring the image to the image separating member. The image separating member has a critical surface tension of 25 mN/m or above.Type: GrantFiled: December 9, 1994Date of Patent: July 30, 1996Assignee: Ricoh Company, Ltd.Inventors: Masato Igarashi, Toshiyuki Kawanishi, Eiichi Kawamura, Narihito Kojima
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Patent number: 5540814Abstract: Methods for reducing stickies and removing ink from wastepaper fiber wherein a cationic kaolin is added to a wastepaper fiber furnish under conditions such that the kaolin attaches to the stickies or the ink and the stickies or ink are removed from the furnish using a centrifugal cleaner.Type: GrantFiled: January 24, 1995Date of Patent: July 30, 1996Assignees: Nord Kaolin Company, Cascades, Inc.Inventors: Jerry Curtis, Henry Agbaje, Janet Woodward, Andres Vaska, Roger Gaudreault
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Patent number: 5536363Abstract: Compositions and methods for inhibiting the deposition of organic contaminants from pulp in pulp and papermaking systems are disclosed. The methods add to the pulp or to the deposition prone surface of the papermaking system a composition comprising a polyvinyl alcohol having 50 to 100% hydrolysis and a high molecular weight gelatin having a molecular weight of about 100,000 or higher.Type: GrantFiled: April 12, 1995Date of Patent: July 16, 1996Assignee: Betz PaperChem, Inc.Inventor: Duy T. Nguyen
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Patent number: 5531863Abstract: Recyclable containers such as corrugated or folding boxes are made from a coated paper or kraft grade sheet including a plastic coating thereon. Aqueous acrylic resin containing compositions can be applied in excess on the paper or kraft grade sheet and the unwanted coating metered and removed by directing a jet of air at the coating. After solidification of the coating, the coated paper or kraft sheets can be incorporated as components of corrugated or folding boxes. Recovery of the unwanted coating permits recycling of the coating component. Corrugated and folding boxes including the components can be recycled by conventional repulping processes. A process of manufacture of the coated sheets is also disclosed.Type: GrantFiled: February 9, 1995Date of Patent: July 2, 1996Assignee: Timbarco, Corp. c/o Belfint, Lyons & SchumanInventor: Charles Propst
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Patent number: 5527426Abstract: An improved process is disclosed for deinking waste paper which contains laser, electrostatic, and other non-impact printing toners/inks to produce high quality (high brightness, little to no dirt content) pulp with little or no fiber loss. The process involves attachment of ink particles in the waste paper pulp to a magnetic carrier material with the help of an agglomeration agent followed by removal of the attached ink particles by magnetic separation. The magnetic treatment preferably is conducted at ambient or greater temperature, at neutral to alkaline pH, and at a low pulp consistency. Agglomeration and magnetite addition, followed by exposure of the repulped waste paper to a magnetic field provides near complete ink removal over exposure to the magnetic field without such pretreatment.Type: GrantFiled: May 5, 1994Date of Patent: June 18, 1996Assignee: Westvaco CorporationInventors: Nipun Marwah, Allen A. Gold
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Patent number: 5525193Abstract: The invention is directed to a method for deinking and uncoating printed paper which comprises using a monocomponent cellulase during recycling.Type: GrantFiled: October 26, 1994Date of Patent: June 11, 1996Assignee: Novo Nordisk A/SInventors: Neal E. Franks, Steven E. Bazewicz, Hans C. Holm
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Patent number: 5518581Abstract: A floatation method for the regeneration of waste paper employs as a deinking agent a reaction product of an alkylene oxide with a mixture of products obtained by the reaction of a natural oil or fat with an alkanolamine in a mole ratio of the natural oil or fat to the alkanolamine of products is in the range from 1:0.1 to 1:3,, wherein the amount of the alkylene oxide is in the range from 100 parts by weight to 1000 parts by weight based on 100 parts by weight of the mixture of products, provides pulp having higher degree of whiteness and less residual ink and problems caused by pitch than pulp prepared by a corresponding floatation method which employs a conventional deinking agent.Type: GrantFiled: June 4, 1993Date of Patent: May 21, 1996Assignee: Nicca Chemical Co., Ltd.Inventors: Hiroaki Miyagoshi, Katsuhiko Takahara
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Patent number: 5518580Abstract: The present invention relates to a method of processing printed waste paper, in particular waste paper containing at least 80% newsprint or magazine paper by digestion, various cleaning steps, flotation or washing and disintegrating, the latter with a high consistency of at least 20%, and possibly bleaching. The invention is characterized by the fact that a final second disintegrating step, arranged possibly before a bleaching step, with treatment of the waste paper under strong kneading action of individual bar-shaped or block-shaped kneading elements of both the stator and the rotor of the disintegrating machine which are arranged in a kneading chamber thereof which is delimited by two concentric cylindrical surfaces, at temperatures between 20.degree. and 110.degree. C., and preferably 38.degree. to 65.degree. C., and with a specific power consumption of between 30 and 100, and preferably 80, kilowatt hours/ton oven-dried pulp.Type: GrantFiled: August 22, 1994Date of Patent: May 21, 1996Assignee: J.M. Voith GmbHInventors: Herbert Ortner, Hans-Dieter Dorflinger
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Patent number: 5512134Abstract: A process for removing printing inks from printed wastepaper in the presence of a deinking chemical is provided. In this process printed wastepaper is disintegrated to form a paper stock suspension and the detached printing ink particles are removed in known manner by flotation or washing in another stage. In this process, alkoxylates of blown oils are used as the deinking chemical. The deinking chemical is added during disintegration and/or before the flotation or washing step. Preferably, the printed wastepaper is disintegrated in the presence of 0.02 to 2% by weight and preferably 0.1 to 0.8% by weight, based on air-dry paper stock, of alkoxylates of blown oils. This deinking chemical also removed printing inks from paper circuit waters.Type: GrantFiled: July 29, 1994Date of Patent: April 30, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Peter Daute, Berthold Schreck, Klaus Hornfeck
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Patent number: 5505817Abstract: Wastepaper containing printing ink is refined in the presence of the reaction products of castor oil with an alkoxylated fatty acid, alcohol, amine, amide, phosphate ester, polyhydroxy alcohol, or sorbitan, and the detached printing ink particles are subsequently removed from the paper stock suspensions by flotation or washing.Type: GrantFiled: October 19, 1993Date of Patent: April 9, 1996Assignee: Henkel CorporationInventors: Jose M. Rodriguez, Anthony B. Cook, Gail M. Howell
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Patent number: 5503709Abstract: Waste lignocellulosic material, for example brown kraft grocery bag and corrugated paperboard, is treated in a multi-step process to produce a recycle brownstock pulp having a sufficiently low kappa number that it may be bleached according to conventional means such that its final optical and strength properties are comparable to that of virgin pulps bleached according to similar means; biological enzymes are used in conjunction with medium consistency pulping to separate fibers and loosen contaminants, such as wax and adhesives; low temperature soaking of waste lignocellulosic material in an alkaline peroxide liquid using long reaction times is used to minimize energy consumption, degrade contaminants, and to selectively remove lignin; loosened contaminants and poorly bonding lignocellulose debris are removed by screening and cleaning methods; high consistency peroxygen cooking is used to substantially delignify the pulp and to destroy contaminants in an energy efficient manner; liquid streams are treated anType: GrantFiled: July 27, 1994Date of Patent: April 2, 1996Inventor: Steven W. Burton
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Patent number: 5500082Abstract: Disclosed is a method of removing ink from xerographically printed paper. The method comprises pulping said printed paper in an aqueous slurry at a non-acidic pH to a consistency of about 8% or less. Next, added to the pulp slurry is a sufficient amount of long chain alcohol, the long chain alcohol having a melting point above room temperature, for a time sufficient with heating at a temperature sufficient, whereby an agglomeration of long chain alcohol and ink particles is formed. Next, the heating is stopped whereby the agglomeration solidifies into particles that settle to the bottom of the pulp slurry. Then, the agglomeration of solidified particles is removed from the pulp slurry thereby leaving a remaining slurry of deinked paper fiber and water. Optionally, the remaining slurry is subjected to flotation to remove substantially any remaining minute ink left particles behind after the agglomeration.Type: GrantFiled: April 26, 1993Date of Patent: March 19, 1996Assignee: North Carolina State UniversityInventors: Hou-Min Chang, Tien-Wang Wu, John A. Heitmann
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Patent number: 5466333Abstract: A process of recycling printed paper that contain a coating of a plastic olefin polymer by either (a) treating the deinked paper material with an oxidizing agent and reforming the deinked paper material into paper or (b) reforming the deinked paper material into paper and then treating the reformed paper with an oxidizing agent is described. The deinked paper material consists of fibers containing both cellulose and a plastic olefin polymer; fibers which are a mixture of cellulose fibers and fibers containing both cellulose and a plastic olefin polymer; fibers which are a mixture of cellulose fibers, fibers of a plastic olefin, and fibers containing both cellulose and a plastic olefin polymer; and fibers which are a mixture of fibers of a plastic olefin polymer and fibers containing both cellulose and a plastic olefin polymer.Type: GrantFiled: March 4, 1994Date of Patent: November 14, 1995Inventor: Alvin Guttag
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Patent number: 5460695Abstract: A method of deinking waste paper for reclamation thereof, which comprises disintegrating waste paper with an alkali in water in the presence of a polyoxyalkylene ether compound having the formulaR-O(PO)x(AO)y(PO)z-Hwherein R is an alkyl or alkenyl of 8-22 carbons, or an alkylphenyl wherein the alkyl has 4-12 carbons; PO is an oxypropylene group; and AO is an oxyethylene group, or a mixed oxyalkylene group composed of an oxyethylene group and at least one oxyalkylene group selected from the group consisting of an oxypropylene group and an oxybutylene group: and x is a numeral of 3-15, y is a numeral of 20-40, and z is a numeral of 5-20, in an amount effective as a deinking agent.Type: GrantFiled: June 10, 1994Date of Patent: October 24, 1995Assignee: Nissin Kagaku Kenkyusho Co., Ltd.Inventor: Yasuo Kato
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Patent number: 5454955Abstract: Hectorite is utilized in conjunction with a water soluble cationic coagulant to clarify waste water from the deinking of waste paper.Type: GrantFiled: March 25, 1994Date of Patent: October 3, 1995Assignee: Nalco Chemical CompanyInventors: William E. Albrecht, David W. Reed, James H. Smith
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Patent number: 5454909Abstract: A low-density hot melt adhesive is disclosed. Low-density filler, preferably hollow glass microspheres, is added to a hot melt adhesive to provide a hot melt adhesive having a specific gravity preferably between 0.7 and 0.93. The low-density hot melt adhesive is more effectively separated from cellulosic materials such as cardboard and kraft paper during recycling operations which separate contaminants such as adhesives from cellulosic fibers based upon the density of the adhesive.Type: GrantFiled: September 1, 1994Date of Patent: October 3, 1995Assignee: The Dexter CorporationInventor: Paul L. Morganelli
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Patent number: 5453159Abstract: A process for separating printing ink from recycled paper fiber includes the steps of repulping recycled paper furnish with water in a rotary mixer for about 5 minutes at a consistency of 6% to 18% with a mixing element having a top speed no greater than 2,000 ft/min. This first stage repulping and mixing is followed by a second mixing stage of 20 to 45 minutes with a mixing element tip speed of 2,500 to 4,000 ft/min. Agglomerated contamination particles in the resulting slurry are removed by centrifugal cleaning and slot screening.Type: GrantFiled: November 4, 1993Date of Patent: September 26, 1995Assignee: International Paper CompanyInventor: Larry D. Markham
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Patent number: 5441601Abstract: A method for deinking of repulped xerographic paper comprising adding an organic polymeric particulate and a substantially water insoluble organic ester to a repulped aqueous slurry containing xerographic toner particles in an amount sufficient to at least partially agglomerate the xerographic toner particles within the slurry to larger particle sizes; and removing the xerographic toner particles from the slurry by one or more liquid/solid separation techniques.Type: GrantFiled: August 8, 1994Date of Patent: August 15, 1995Assignee: Nalco Chemical CompanyInventors: David R. Cosper, Karen R. Tubergen
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Patent number: 5442082Abstract: The invention relates to alkoxylated compounds prepared by reaction of epoxidized C.sub.10-22 carboxylic acid derivatives with C.sub.2-4 alkylene oxides in the presence of alkoxylation catalysts and mono- and/or polyhydric alcohols.Type: GrantFiled: December 16, 1994Date of Patent: August 15, 1995Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Guenter Uphues, Uwe Ploog, Peter Daute, Gerhard Stoll, Berthold Schreck
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Patent number: 5435921Abstract: The invention comprises a process for removing true and apparent color from pulp and paper waste waters. It comprises treating these waste waters with a coagulant and vinylamine polymer. The coagulant is selected from the group consisting of epichlorohydrin-dimethylamine, guanidine-formaldehyde condensation polymers, cyanoguanidine-formaldehyde condensation polymers, urea-formaldehyde condensation polymers, polyethyleneimines, polydiallyldimethylammonium chloride, copolymers of polydiallyldimethylammonium chloride and acrylamide, and ethylenedichloride-ammonia. The vinylamine polymer includes from about 1 to about 100 mole percent vinylamine and from about 1 to about 99 mole percent of at least one monomer selected from the group consisting of amidine vinylformamide, vinyl alcohol, vinyl acetate, vinyl pyrrolidinone and the esters, amides, nitriles and salts of acrylic acid and methacrylic acid.Type: GrantFiled: May 9, 1994Date of Patent: July 25, 1995Assignee: Nalco Chemical CompanyInventors: John H. Collins, Dodd W. Fong, Anthony G. Sommese, Amy M. Tseng
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Patent number: 5433824Abstract: A method for controlling, inhibiting the deposition of and/or for removing stickies from the surfaces of pulping and papermaking machinery in secondary fiber operations by adding an effective amount of a melamine formaldehyde-type polymer to a pulp slurry or furnish containing secondary fiber that is in contact with said machinery. Improved paper end products resulting from this method are also disclosed.Type: GrantFiled: February 26, 1993Date of Patent: July 18, 1995Assignee: Calgon CorporationInventor: Paul F. Richardson
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Patent number: 5427650Abstract: Apparatus and method for separation, recovery, and recycling municipal solid waste and the like by introducing solid waste materials into a rotatable pressure vessel, rotating, pressurizing, adding pH controlling chemicals and heating the pressure vessel and thus the waste material while simultaneously applying a mixing action to the solid waste material. The addition of a predetermined amount of pH controlling chemicals and the application of a vacuum serve to control the moisture content of the final fine organic portion of the processed material. Organic contents of the vessel are pulped and sterilized when processed to facilitate ease of separation and prepare the resulting cellulose material for use.Type: GrantFiled: June 25, 1992Date of Patent: June 27, 1995Inventor: Clifford C. Holloway
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Patent number: 5417808Abstract: A deinking composition for regeneration of waste paper by floatation comprises 99.7 to 97% by weight of a mixture which comprises monoalkyl ethers of ethylene oxide/propylene oxide copolymers represented by the following general formulas (A) and (B) and the mixing ratio of the compound (A) to the compound (B) ranges from 10:90 to 90:10 (weight ratio); and about 0.3 to about 3.0% by weight of a polyoxyalkylene oxide selected from the group consisting of polyethylene oxides, polypropylene oxide and ethylene oxide/propylene oxide copolymers:R.sup.1 O-(PO).sub.n1 -[(EO).sub.m.(PO).sub.n2 ]-H (A)R.sup.2 O-(EO).sub.m1 -[(EO).sub.m2.(PO).sub.n ]-H (B)wherein m/(n1+n2) ranges from 0.5 to 1.5; (m1+m2)/n ranges from 1.1 to 2.0; EO and PO represent ethylene oxide and propylene oxide units respectively; and the EO and PO in the brackets may be in either a random or block configuration. The deinking composition exhibits excellent deinking properties.Type: GrantFiled: February 1, 1993Date of Patent: May 23, 1995Assignee: Lion CorporationInventors: Yataka Okamoto, Yoshie Hirakouchi, Masaaki Hagiwara
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Patent number: 5417807Abstract: The removal of hydrophilic flexographic inks from a pulp fiber slurry in a flotation or flotation/wash deinking system is accomplished by using a combination of (a) a fatty acid or salt thereof, (b) a rosin acid or salt thereof, and (c) a non-ionic or anionic surfactant along with water having a hardness of about 80 to 500 ppm Ca.sup.+2.Type: GrantFiled: May 27, 1993Date of Patent: May 23, 1995Assignees: KAO Corporation, High Point Chemical Corp.Inventors: Francisco F. Fossas, Pedro F. Ferre, Narciso R. Castano, Stephen P. Williams, Hideaki Urushibata
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Patent number: 5415733Abstract: The removal of inks, particularly hydrophilic flexographic inks, from a pulp fiber slurry is accomplished by use of a combination of (a) a non-ionic surfactant; (b) a fatty acid or salt thereof; and (c) a water-soluble cationic polymer having a molecular weight less than about 1,000,000 daltons, particularly a polymer derived from the reaction of epichlorohydrin and at least one diamine or the polymerization of aziridine.Type: GrantFiled: May 27, 1993Date of Patent: May 16, 1995Assignee: High Point Chemical Corp.Inventors: Peter M. Robinson, Stephen P. Williams, Thomas F. Skaar, Hideaki Urushibata