Abstract: Chlorous acid is generated from a chlorite salt precursor, a chlorate salt precursor, or a combination of both by ion exchange. The ion exchange material facilitates the generation of chlorous acid by simultaneously removing unwanted cations from solution and adding hydrogen ion to solution. Chlorine dioxide is generated in a controlled manner from chlorous acid by catalysis. Chlorine dioxide can be generated either subsequent to the generation of chlorous acid or simultaneously with the generation of chlorous acid. For catalysis of chlorous acid to chlorine dioxide, the chlorous acid may be generated by ion exchange or in a conventional manner. Ion exchange materials are also used to purify the chlorous acid and chlorine dioxide solutions, without causing degradation of said solutions, to exchange undesirable ions in the chlorous acid and chlorine dioxide solutions with desirable ions, such as stabilizing ions, and to adjust the pH of chlorous acid and chlorine dioxide solutions.

Abstract: An apparatus for carboxylating wood pulp which utilizes the wood pulp bleach plant and the method of carboxylating the pulp which takes place in the bleach plant.

Abstract: The present invention relates to a process for the removal of lignin from lignocellulose containing material comprising treating the lignocellulose containing material prior to a high-yield pulping process with a delignifying gas comprising gaseous compounds comprising at least one oxygen atom such as chlorine dioxide containing gas.

Abstract: In a method for the production of fiber pulp for subsequent use in the production of a fiber web, especially a paper or cardboard web, the fiber pulp that was produced in a pulp production process is first loaded with an additive by way of a chemical precipitation reaction. The loaded pulp is then dried and available for subsequent utilization or formulated into a suitable form for shipment.

Abstract: The present invention relates to a process for the removal of lignin from lignocellulose containing material comprising treating the lignocellulose containing material prior to a chemical pulping process with a delignifying gas, wherein the gas comprises chlorine dioxide.

Abstract: Provided is a process for bleaching pulp with ozone. The process involves preparing a slurry of cellulosic pulp having a consistency in fibers of from 1-5 weight %. Such a low consistency slurry is then mixed with ozone under high shear conditions. The ozone is then maintained in contact with the cellulosic fibers to effect bleaching of the fibers. The present process offers the advantages of bleaching using a low consistency slurry, with the added advantages of employing ozone.

Abstract: The present invention is directed to a process for making a lyocell fiber by contacting an alkaline pulp having cellulose and at least about 7% hemicellulose under alkaline conditions with an amount of an oxidant sufficient to reduce the average degree of polymerization of the cellulose to the range of from about 200 to about 1100 without substantially reducing the hemicellulose content of the pulp or increasing the copper number and then forming fibers from the pulp.

Abstract: Perfluoroalkyl-substituted amino acid oligomers or polymers obtainable from (A) an aliphatic diamino acid having 3 to 10 carbon atoms such as lysine, (B) a chain extender such as epichlorohydrin, a dihalide or an aliphatic diepoxide, (C) an amino-reactive allyl compound and (D) a perfluoroalkyl iodide, and, optionally, other reactants, are useful as grease-proofing agents for paper and are excellent foam stabilizers for Aqueous Fire-Fighting Foam (AFFF) formulations used on polar solvent fires.

Abstract: In the treatment of cellulose pulp in connection with bleaching, the pulp is first cooked and, if necessary, oxygen delignified in order to reduce the Kappa number below 24, preferably below 14, and after that the pulp is treated in an acid stage at a pH of 2-5 and at a temperature range of 75-130° C. in order to reduce the Kappa number by 2-9 units. To prevent essential weakening of the strength properties of the pulp in the acid stage treatment tower, the retention time, t min, is 30 to 300 minutes and the treatment temperature, T° C.

Abstract: Process and device for mixing fluid into a pulp suspension of cellulose-containing fiber material, in which the pulp suspension is pumped in through a pump inlet (17), brought into rotation and, at the desired reaction pressure, mixed with the said fluid while passing through a reaction sector comprising a stator shell (1), a rotor (7) which is coaxial therewith, and at least one fluid inlet (23), after which the pulp mixture leaves the reaction sector through a pulp outlet (20), in which the fluid, via the said fluid inlet (23), is supplied in the vicinity of the center of rotation of the rotating pulp suspension, where the local pressure in the pulp suspension is lower, due to the centrifugal force increasing radially outwards, than the reaction pressure prevailing at the periphery of the pulp suspension.

Abstract: A cellulose pulp continuous digester (e.g. for producing kraft pulp) is operated so that it has the advantages of a hydraulic digester yet has a gas-filled zone over the liquid level. A slurry of chips and cooking liquor is introduced into the top of the digester vessel through an inverted top separator. A liquid level is established below the inverted top separator, and a chips level is established below the inverted top separator (above or below the liquid level). A gas-filled zone above the liquid level includes compressed gas, and is at a temperature of less than 160 (preferably less than 120).degree.C. and at a pressure of between 50-200 (preferably 80-150) psig. The chips are heated by recirculating and heating liquid using a recirculation loop below the chips level, and a countercurrent flow zone is preferably provided.

Abstract: In the bleaching of kraft cellulosic pulps employing a stage in which the pulp is contacted simultaneously with gaseous chlorine and ozone, the improvement in which the pulp at a low to high consistency is initially chlorinated with hypochlorous acid and thereafter is contacted substantially simultaneously with gaseous chlorine and ozone. The pulp so processed exhibits enhanced brightness and good viscosity, and the process produces low quantities of environmentally undesirable chlorinated organics. The bleaching sequence of M(C+Z).sub.g ED is disclosed.

Abstract: A process for gas phase delignifying wood pulp comprising: contacting wood pulp in the first stage of pulp bleaching with chlorine dioxide-containing gas to delignify said wood pulp; wherein(a) said wood pulp has a consistency of at least about 15 percent;(b) said chlorine dioxide-containing gas contains less than about 3% by weight chlorine gas, based on the weight of chlorine dioxide in said gas; and(c) said contacting is conducted at a subatmospheric pressure from about 15 to about 750 mm Hg. This process reduces the formation of chloroform and significantly reduces the amounts of toxic by-products such as dioxin and other organic chlorides. These undesirable by-products, collectively identified as absorbable organic halides (AOX), require effluents from pulp bleaching processes to undergo expensive treatment methods to eliminate AOX's prior to discharges to sewers. The effluent discharge from this process generally has less than 2.0 kg adsorbed organic halides (AOX) per ton of wood pulp.

Abstract: Secondary pulp is deinked and bleached by contacting the pulp simultaneously with oxygen, alkali, and a surfactant in a reaction zone followed by washing to recover a secondary fiber product. Simultaneous contacting with oxygen and surfactant yields higher pulp brightness than sequential contacting in oxygen bleaching and washing stages, and enhances bleachability in further bleaching stages.

Abstract: An improved process for bleaching cellulosic pulp in a first chlorination stage of a multi-stage bleaching process is provided, which involves an improved process for bleaching cellulosic pulp in a first chlorination stage of a multi-stage bleaching process, comprising: (a) admixing cellulosic pulp with a first chlorine dioxide charge and reacting the cellulosic pulp and said chlorine dioxide for a period of time ranging from about 1 second to about 10 minutes; (b) admixing the cellulosic pulp effluent obtained after step (a) wtih chlorine and chlorine dioxide and reacting the thus-obtained cellulosic pulp for a period of time ranging from 1 second to about 10 minutes; and then (c) admixing the cellulosic pulp effluent obtained after step (b) with a second chlorine dioxide charge and reacting the thus-obtained cellulosic pulp effluent for a period of time ranging from about 1 second to about 10 minutes, wherein the pH of the reaction mixture is maintained throughout the bleaching process at from about 5.

Abstract: Ozone and chlorine are used to bleach cellulosic fibrous material pulp in the production of kraft pulp for paper and paper products, being applied together in a mixture. When the ozone and chlorine are applied simultaneously it is possible to achieve delignification to a greater extent than is possible utilizing chlorine at any level. The total chlorinated ring compounds in the bleach plant effluent are remarkably reduced utilizing the ozone-chlorine mixture, compared to all chlorine, with resulting decrease in the fish toxicity of the bleach plant effluent. Utilizing an O.sub.3 /Cl.sub.2 E.sub.o D bleaching sequence (only three stages) it is possible to obtain pulp with 90 TAPPI Absolute, or greater, brightness.

Abstract: Chlorine gas is directly introduced, without the necessity of adding water with the gas, into a paper pulp slurry (i.e. comminuted cellulosic fibrous material) having a consistency of between about 6-15 percent. The gas is added to the inlet of a fluidizing mixer at the point where the slurry enters the fluidizing mixer, and is intimately mixed with the pulp by the mixer. The flow of the chlorine gas is in a flow controlled pathway, which is split into at least two flows so as to increase the total gas volume added to the pulp stock and obtain enhanced mixing. Each of the split flows is introduced to the inlet of a fluidizing mixer. The split flow addition of chlorine gas into two or more mixer inlets also may be practiced for low consistency pulp (e.g. pulp having a consistency of between about 1-5 percent).

Abstract: A gas injector element for use in a mixing apparatus having a plurality of mixing elements, where the injector element is airfoil-shaped and is installed adjacent to the first of the plurality of mixing elements. The airfoil-shaped injector is fabricated from a metal or other suitable material having a porosity within a range of 0.5 to 100 or more microns, such that fluid injected into the mixing conduit through the injector will be released from the injector and will immediately contact material flowing through the conduit without the undesirable result of bubbles of the fluid or gas flowing from the injector coalescing with larger bubbles resulting in ineffective mixing of the gas with the material in the mixer.

Abstract: Gaseous chlorine is blended with a paper pulp slurry flow stream for pulp bleaching by mixing the chlorine with a larger quantity of steam prior to blending the chlorine/steam gas mixture with bleach washer filtrate which serves as carrier water for a multiplied number of gas bubbles entrained in the filtrate. As the cooler filtrate water extracts heat from the mixed gas bubble, the steam constituent condenses to collapse each bubble to a fraction of the original volume thereby providing a larger number of smaller chlorine bubbles than otherwise available from conventional phase mixing injectors.The mixed phase flow stream of chlorine and filtrate is thereafter blended with the pulp slurry flow stream by shear induced turbulence resulting from a greater injection velocity of the mixed phase stream into the center of the slower moving slurry stream.

Abstract: Modified cellulose products for use as carrier vehicles in forming cosmetics, pharmaceutical preparations, insecticides, etc. are prepared by treating a minimum weight ratio of about 10:1 of fibrous cellulosic material with an alkali metal or alkaline earth metal hypohalite (e.g. sodium hypochlorite) at a temperature of from about 15.degree. to 60.degree. C. for a period of time sufficient to render the material non-fibrous (i.e. pH drop to about 6 or less), filtering and washing obtain the desired product.

Abstract: An apparatus and method for mixing a fluid, such as chlorine or oxygen gas, into a suspension, such as comminuted cellulosic material. A circular cross-section conduit defines a flow path for a suspension, and a circular smooth-faced disc is mounted in the conduit for rotation, covering substantially the entire interior of the conduit. A relatively small opening extends through the disc, and that disc is rotated in the conduit with small portions of suspension flowing in the conduit progressively passing through the opening and being fluidized when passing through the opening. The fluid is introduced into the suspension as the suspension flows through the opening, and in this way an even distribution of fluid in the suspension, with minimum power consumption, is provided.

Abstract: A process is provided for the processing of certain organic agricultural foodstuff by-products normally having little commercial value to produce a cellulosic product suitable for human consumption or use in various products. The process of the present invention is characterized by subjecting a variety of certain agricultural by-products having little commercial value, such as, for example, soy bean hulls, to a series of separate steps utilizing certain chemical treating to effect a solubilizing and removal of the non-cellulosic components of the by-product agricultural material to produce residue solids which consist essentially of cellulose. The cellulose residue solids are subjected to specified purification procedures and thereafter dried to produce a short, fine fibered cellulose which may be processed to a fine powdered state suitable for use as a component part in a wide variety of edible or otherwise useable products by humans, an example of such a product being a low calorie bread.

Abstract: A wood pulp slurry is treated with oxygen in a mill with little change to the process or structure of the mill. No special pressure tanks are required. The consistency of the pulp need not be altered for the treatment step. It may be treated at the usual process consistency of the pulp; e.g., it may be treated at the usual consistency of the pulp leaving a washer or subsequent steam mixer without additional dewatering or additional dilution.The oxygen is added into a closed section of the system so that it cannot immediately vent to the atmosphere. Alkali should also be present when the oxygen is mixed with the slurry. The mixing should occur near to the point of oxygen addition.The mixing occurs in a relatively small mixer that intensively mixes the slurry and gas. The mixer has a mixing zone with a swept area of 10,000 to 1,000,000 square meters per metric ton of oven-dry pulp.

Abstract: The invention relates to a process for bleaching preoxidized paper pulp enabling a pulp having a very high degree of whiteness to be obtained with a limited number of treatment steps and enabling pollution to be reduced without degrading the qualities of the pulp; such a process essentially comprises the combination of the three successive treatment steps, namely:(a) a first step of hot chlorination with gaseous chlorine at a temperature of between about 30.degree. and 80.degree. C., and preferably between 35.degree. and 50.degree. C., in the presence of urea used at a rate of 0.5 to 5% by weight of the chlorine used, and preferably from 1 to 3%, with a concentration of pulp of between 3 and 30%, and a duration of retention of the chlorine of 30 seconds to 45 minutes;(b) a second step of alkaline extraction in the presence of an oxidizing agent of the hypochlorite or peroxide type, at a temperature of between about 30.degree. and 70.degree. C., and at a pH of between about 8 and 12, and preferably between 10.

Abstract: A pulp containing lignocellulosic fibers is treated with chlorine in two steps. In the first step, chlorine in the amount of 0.6-0.9 grams per gram of lignin in the fibers, is mixed in the gaseous state into the pulp and in a second step the reaction products, which contain chlorinated lignin, are removed by displacing the liquid in the pulp with a chlorine solution, the amount of active chlorine in the solution in the second step being between 0.1 and 0.3 grams per gram of the lignin initially present in the pulp. In this manner 92% delignification is achieved without any intermediate washing between the two steps and with a total amount of chlorine between 0.7 and 1.2 grams per gram of lignin. The consistency of the pulp in both steps is the same and is between 6 and 12%.

Abstract: Method and apparatus for the continuous distribution and mixing of high concentration pulp with at least one treatment fluid such as chlorine or chlorine dioxide. An enclosed housing has a cylindrical portion, a closed conical wall portion extending inwardly from one end of the cylindrical portion, and a generally converging open conical portion extending outwardly from the other end of the cylindrical portion. High concentration pulp is introduced into the cylindrical portion of the housing, and a rapid circular movement is imparted thereto by rapidly rotating rotor transport blades, so that the pulp is essentially fluidized. Treatment fluid is added to the pulp through the cylindrical housing portion to generally form a layer over pulp rotating in the cylindrical housing portion.

Abstract: A pulping process which includes the steps of oxidizing vegetable materials with an oxidizing chemical selected from the group comprising Cl.sub.2, Cl.sub.2 O,ClO.sub. 2, Mg(ClO).sub.2, Mg(ClO.sub.2).sub.2 Mg.(ClO.sub. 3).sub.2 and mixtures thereof, extracting the oxidized materials with Mg(OH).sub.2 thereby to delignify and bleach the materials and treating the waste liquor from the oxidation, extraction and washing steps by combustion or thermal decomposition thereby to regenerate the chemicals necessary for the oxidation and extraction steps. The process of the invention produces semi-bleached or completely bleached pulp of high strength with high yield while eliminating the problem relating to environmental pollution.

Abstract: A cellulose containing vegetable material is bleached by the steps of chlorinating said material, followed by ammonia treatment and post bleaching with washing stages between said steps. Waste waters resulting from the washing stages are purified by subjecting said waste waters to electrodialysis and recovering ammonium chloride from the purified waste waters. The recovered ammonium chloride is used to pre-treat the cellulose material prior to chlorination thereof and the purified waste waters are reused in the washing stages.

Abstract: There is provided a process for the bleaching of woodpulp comprising reacting the pulp with chlorine dioxide until the chlorine dioxide is .[.at least partially.]. .Iadd.more than 50% .Iaddend.depleted and, thereafter, .Iadd.without an intermediate wash, .Iaddend.reacting the woodpulp with chlorine. .[.The process provides bleached pulps with excellent strength brightness, and color reversion properties..].

Abstract: There is provided a process for the sequential bleaching of kraft pulp comprising reacting kraft pulp with chlorine dioxide until the chlorine dioxide is .[.at least partially.]. .Iadd.more than 50% .Iaddend.depleted, reacting the kraft pulp with chlorine .Iadd.without an intermediate wash.Iaddend., and treating the kraft pulp with caustic..[.Via this process bleached kraft pulps with exceptionally good brightness and strength characteristics are obtained..].