Abstract: A feed system for a cellulose pulp treating vessel (such as a continuous digester) is not limited by the required L/W ratio of the pump feeding a wood chip slurry to a high pressure transfer device, the feed system may be kept at a low temperature to minimize flashing of liquid into steam, and a return conduit from the treatment vessel to the transfer device high pressure inlet may be eliminated. Some of the liquid is removed from the slurry just before the low pressure inlet to the transfer device, and/or just after the high pressure outlet, to reduce the L/W ratio of the slurry by at least 0.25, e.g. from 3.0:1 to 2.25:1 just before the low pressure inlet, and from, 7.0:1 to 5.0:1 substantially immediately after the high pressure outlet.

Abstract: A process for final bleaching cellulose-containing pulp which has been subjected to previous bleaching with a peroxide compound. The process involves the sequential steps of exposing the pulp to an amount of a reducing agent in order to eliminate residual peroxide compound from the pulp and then final bleaching the pulp by exposing the pulp to an amount of formamidine sulfinic acid.

Abstract: An aqueous dispersion of a sizing agent comprising starch having aromatic groups and a condensed sulfonate, wherein the starch contains less than 95 weight % of amylopectin.

Abstract: A chemical wood pulping process having reduced volatile organic compound emissions includes extracting wood particulates with solvent at a pressure less than 50 psi to reduce naturally-occurring particulate pitch and volatile organic compound content without significant dissolution of lignin and wood cellulosic components. The solvent used is methanol, ethanol, or acetone. This is followed by comingling the extracted wood particulates with a liquor having chemical reactants, not including the solvent used to extract the wood particulates, for solubilizing lignin. Then, allowing the chemical reactants of the liquor to react with lignin contained in the extracted wood particulates under controlled conditions of temperature and pressure for a sufficient time to solubilize and remove lignin. This is followed by producing a wood pulp having individual cellulosic fibers while releasing a reduced amount of VOCs in the wood pulping process.

Abstract: A method is disclosed for reducing or inhibiting alkaline darkening of mechanical pulp caused by the presence of calcium carbonate filler during production; the method comprises adding a sulfite, or sulfur-containing reducing agent, especially a sulfite to the mechanical pulp and the filler; the method is usefully applied in the production of mechanical pulp and paper in which calcium carbonate is used as a filler and also in the production of paper at neutral or mildly alkaline conditions.

Abstract: Chemical pulp is produced from a slurry of comminuted cellulosic fibrous material using a beneficial additive such as AQ, or polysulfide. In the first treatment zone the effective alkali concentration and temperature conditions are such so that substantially no alkali degradation of the cellulose occurs, but so that the material is effectively impregnated with the additive. Then the material is treated with an alkaline cooking liquor, at cooking temperature, to produce a chemical cellulose pulp with higher yield or strength than if the low temperature, low alkali, additive pretreatment was not practiced. Typical alkali and temperature conditions in the first zone are less than 10 g/l expressed as NaOH; and between about 80-130° C., e.g. about 80-110° C. The first zone is preferably a feed system (which may include a separate impregnation vessel) for a continuous digester, while cooking is in a continuous digester.

Abstract: A process for production of chemical fibrous pulp for making paper, paperboard and other fibrous products from herbaceous plants, such as kenaf. Pulp from the herbaceous plant is made by a process which involves densification of pieces of all or part of the plants; i.e., both the core and the stalk or just the core portion, into cubes or pellets having a density ranging from about 15 to about 70 lbs/ft3, preferably from about 25 to about 50 lbs/ft3, which are then chemically digested to produce a fibrous pulp. The densified cubes or pellets may be digested alone or together with conventional wood chips. A principal advantage of the invention is that the densified cubes or pellets exhibit significantly better yield and strength after treatment by conventional chemical pulping methods as compared with the undensified material, enabling more efficient and economical use of this material to supplement limited supplies of conventional hardwood and softwood pulp sources.

Abstract: A single stage method delignification process for pulps, preferably sulphite pulps. The improvement to conventional oxygen delignification process comprises in situ addition of a reducing agent substantially non-reactive with oxygen. The end result is a pulp having enhanced strength properties and higher viscosity. Sodium borohydride is the preferred reducing agent, and MgO is the preferred alkali source. Similar results can be obtained with a two-stage oxygen delignification wherein the pulp is treated with the reducing agent in the first stage, and then washed and pressed conventionnally before proceeding with the oxygen delignification in a second stage.

Abstract: A low energy process for the manufacture of high yield pulp that involves the processing of chemically-treated chips or wood fiber at high stresses or intensity.

Abstract: A low energy thermomechanical pulping process which employs an enzyme treatment stage between two low energy thermomechanical stages.

Abstract: A process for modifying, breaking down or bleaching lignin, material containing lignin or like substances uses oxidation catalysts and suitable oxidizing agents wherein these catalysts are used in combination with aliphatic, cycloaliphatic, hetercyclic or aromatic compounds containing NO, NOH or (A).

Abstract: A process for the delignification and bleaching lignocellulosic-containing pulp, in which the pulp is delignified with an organic peracid or salts thereof, treated with a complexing agent, washed and subsequently bleached with a chlorine-free peroxide containing bleaching.

Abstract: An absorbent, chemithermomechanical pulp produced from lignocellulosic material with a wood yield above 88%, a low resin content <0.15%, a long fiber content above 70%, a short fiber content below 10% and a shive content below 3%. The method for producing the pulp comprises the steps of impregnating, preheating, defibering, and washing the material. The impregnation and preheating of the chips are effected in one and the same vessel over a combined time period of at most 2 minutes, particularly at most 1 minute, preferably at most 0.5 minutes; using a warm impregnating liquid having a temperature of at least 100.degree. C., suitably at least 130.degree. C. and preferably having essentially the same temperature as in the preheating process; and preheating the chips at a temperature of 150.degree.-175.degree. C., preferably 160.degree.-170.degree. C.

Abstract: A method for eliminating the formation of sulfur dioxide in a refiner bleaching process is disclosed wherein a selected amount of a carbonate is added to the refiner contents at approximately the same time that sodium dithionite is added.

Abstract: A method and apparatus for treating wood pulp that includes incompletely washed brownstock, in which the brownstock is treated at a pH range of approximately 7.0 to 9.0 with a hemicellulase enzyme preparation that has a pH optimum below 6.0. Also, a method and apparatus for treating wood pulp containing incompletely washed brownstock in which the brownstock is treated at a pH range of approximately 6.0 to 9.0 with a hemicellulase enzyme preparation that has a pH optimum below 6.0 and that has a low cellulase content such that not more than about 10,000 FPU are added per ton of pulp.

Abstract: Paper pulp, especially recycled paper pulp which has been deinked, is bleached in a synergistic two-stage process first with sodium bisulfite and then with sodium borohydride. The borohydride is preferably added in an aqueous mixture with sodium hydroxide. A weak acid such as acetic acid may be added to the pulp to advance further the brightness gain.

Abstract: A method for bleaching pulp containing pulp from color dyed waste paper, wherein the method comprises bleaching the pulp with a bleaching chemical, especially sodium hydrosulfite, in the presence of a selected ethoxylated amine.

Abstract: A method of making a wood pulp is disclosed. Wood is first chipped into wood chips. The wood chips are treated with an amount of sulfite salt sufficient to inhibit indigenous microorganism growth. The treated wood chips are introduced into a bioreactor and inoculated with a culture of white-rot fungus. The wood chips are incubated under conditions favoring the propagation of white-rot fungus and then mechanically pulped.

Abstract: A process for preparing chemithermomechanical pulp comprising subjecting a lignocellulosic substance from which said pulp is to be formed to the simultaneous action of a sulfite and a reducing agent that is more electronegative than the sulfite ion during a nondestructive cooking operation at a temperature of about 100.degree. C. or above under saturated steam pressure; said simultaneous action taking place at an initial pH of between 7 and 12.5.

Abstract: Resin can be hydrolyzed enzymatically during the reductive bleaching (e.g. with sodium dithionite) commonly used in pulp manufacture. The enzyme treatment necessitates little or no change of commonly used bleaching conditions.

Abstract: Bleached chemithermomechanical wood pulp having a high degree of whiteness is economically prepared by mechanically disintegrating and chemically digesting lignocellulosic material with sulfite at a temperature of at least 100.degree.C. under saturated water vapor pressure and thereafter bleaching the pulp thus treated with hydrogen peroxide in an alkaline medium, and wherein no solids or liquids are removed from the pulp from the outset of treatment through completion of the bleaching step.

Abstract: A sodium borohydride/sodium hydroxide solution for dithionite generation contains sufficient levels of diethylene triamine pentaacetic acid to chelate metals in the dithionate generation process and also in a pulp bleaching process.

Abstract: A process for the manufacture of high-yield pulps bleached with the aid of hydrogen peroxide in alkaline medium, which consists in subjecting the pulp to be bleached successively to:(a) a pretreatment with the aid of a sequestering agent for metal ions, followed by a washing operation,(b) a treatment with sulphite and a reducing agent which is more electronegative than the sulphite ion, which act together and in a medium of initial pH between 7 and 12.5, followed by a washing operation to remove the sulphite ions and the reducing agent, and(c) to a bleaching treatment with the aid of hydrogen peroxide in alkaline medium in the presence of a quantity of silicate of between 0% and 1%.

Abstract: A process for the production of a hemicellulose hydrolysate and special pulp through two steps, the first step comprising the prehydrolysis of the material and the second step the dissolving of the lignin contained in the prehydrolyzed material. According to the process the lignin dissolving is carried out by neutral sulphite cooking with anthraquinone or a derivative thereof as a catalyst, the pH of the cooking liquor being initially at least 10.

Abstract: A paper pulp refining and bleaching process wherein the pulp is treated in one or more refiners with a sodium hydrosulfite bleach liquor in the presence of a strong alkali such as NaOH, whereby the bleaching solution has an alkaline pH, preferably 10 to 12, and the pulp is discharged from the refiner at a pH of from about 5 to 6. The bleaching produces a brightness gain of at least 8 to 13 ISO points in the refiners. The process is preferably carried out by passing the pulp successively through a primary refiner at elevated pressure, a secondary refiner at atmospheric pressure and a bleaching tower, an alkaline hydrosulfite solution being fed to each.

Abstract: An aqueous solution containing sulphur dioxide and sodium in high percentages is obtained by bringing sulphur dioxide into contact with a recirculating aqueous solution of sodium hydroxide and previously absorbed sulphur dioxide to obtain a ratio between SO.sub.2 and the sum of SO.sub.2 and Na.sub.2 O of 0.61-0.66, preferably 0.63-0.65, and a concentration of SO.sub.2 and Na.sub.2 O amounting to 85-98%, preferably about 95% of the solubility maximum of the solution at the ratio and storage temperature in question.The invention also relates to a solution having the aforesaid ratio of SO.sub.2 /(SO.sub.2 +Na.sub.2 O) and concentation and its use for sulphite cooking purposes or for bleaching purposes.

Abstract: An improved wood pulping process for the delignification of wood in a solvent wherein the solvent is a supercritical fluid under supercritical conditons and contains a delignification agent such as sodium hydroxide, sodium sulfide and/or sodium bisulfate.

Abstract: Resin is removed from mechanical pulps, such as TMP, CTMP, and the like, in a quick and simple manner. Mechanical pulp at a consistency of about 7-20 percent (preferably 8-15 percent) is subjected to high turbulence. The high turbulence may be effected by fluidizing the pulp, as in a centrifugal fluidizing pump, or otherwise by subjecting it to high turbulence as in a mixer, screen, or disc mill refiner. By subjecting the pulp to high turbulence treatment for a time period of about 0.2-10 seconds, resin removal is greatly enhanced, and in subsequent dewatering of the pulp a pressate is formed which has a higher concentration of resin in the pressate than in pressates produced by conventional processes. After dewatering the pulp is preferably diluted (again to about 7-20 percent consistency), and the turbulence and dewatering steps are repeated. Chemicals to improve deresination can be added to the pulp while it is subjected to high turbulence.

Abstract: Process for bleaching of materials, at which an aqueous solution of borohydride containing borohydride corresponding to from 15 to 35 percent by weight of sodium borohydride and hydroxylic ions corresponding to not more than 10 percent by weight of NaOH is brought to react with a bisulfite solution, after which the dithionite solution thus obtained is added to the material to be treated. This process gives a simple and economic preparation of dithionite bleaching solution in situ, in connection with the bleaching.

Abstract: A method for producing low fines content pulp having successive treatment stages in each of which compressive and shearing forces are applied to the cellulosic fiber while simultaneously one or more chemicals are added. Gradual breakdown of the fibers is achieved with resulting low fines production whereby the pulp may be used for tissue, fluff and towel products.

Abstract: A method of rapid determination of the concentrations of the total sulphur dioxide and the lignosulphonate present in sulphite pulping process liquors. The lignosulphonates are separated from compounds which form the total sulphur dioxide by means of an ion exclusion column, whereby the filling material of the column consists of a cation exchange resin. The concentration measurements of the sulphur dioxide and the lignosulphonate are carried out from the liquor flow coming out from the separation column by means of UV-method at the wave length of 280 nm. The invention also relates to a method of controlling the sulphite pulping process by determining the total sulphite dioxide concentration in the pulping liquor.

Abstract: A method is described for increasing the brightness of reductively bleached high yield pulps, comprising bleaching the pulps with a reductive bleaching solution under anaerobic conditions and maintaining the bleached pulps under anaerobic conditions during all handling steps subsequent to bleaching, including paper formation, wet pressing, and drying of the paper formed therefrom. The bleached paper has higher brightness than the same paper produced under aerobic conditions, and the bleaching and handling-derived portion of this higher brightness is retained after storage of the finished paper.

Abstract: Bamboo can be formed into a suitable pulp if prior to digestion it undergoes a process of shredding, washing and wet depithing. The fibers are then chemically digested preferably by a process which uses rapid pressure drops to open the fibers using the energy contained in the wet superheated fibers.

Abstract: A method of controlling sulphite pulping or hydrolytic processes by means of a rapid furfural analyzer. Furfural and 5-hydroxymethylfurfural are separated from the other UV-absorbing compounds of a process liquor sample. The concentration measurements are carried out by menas of an UV-method. The obtained measuring results are utilized for on-line controlling of the process in question.

Abstract: A multistage process for bleaching high-yield and ultra high-yield pulps is described whereby the pulp is treated sequentially with a peroxygen compound, a reducing compound and a final peroxygen compound to achieve higher brightness levels.

Abstract: A process of manufacturing cellulose pulp from wood by digesting the wood with sulphite cooking liquor containing additions of sulphide and in the presence of a quinone or hydroquinone compound. According to the invention, the mole ratio between sulphide and sulphite shall amount to 0.01-0.2, preferably 0.05.0.15, suitably 0.08-0.12.

Abstract: A method for the production of fiber pulp from lignocellulosic material containing at least 70% spruce or spruce-like material. The method comprises the steps of lignin softening and defibration/refining, the step of lignin softening being performed prior to the step of defibration/refining and comprising impregnating the starting material with a dilute aqueous solution of a lignin softening agent, namely a solution of sulfurous acid, metal bisulfite salts and/or metal sulfite salts in an amount sufficient to provide a defibrated/refined pulp containing an absorbed and bonded amount of sulfonate groups within the range of from 0.06 to 0.75 wt.-%, calculated as Na.sub.2 SO.sub.3 and based on the dry pulp weight. The absorbed and bonded amount of sulfonate groups is balanced to the composition of the starting material and the temperature-pressure conditions in the defibration step to provide a pulp of maximum tensile strength such as to represent a point within the polygon ABGH in FIG. 1.

Abstract: A sulphite cooking process is described for the production of pulp from materials containing lignocelluloses, with recovery of the cooking chemicals, in which the cooking, the blowing, the washing and the bleaching are performed sucessively. The waste liquor is subjected to several thermal treatments for the recovery of the cooking chemicals. For the cooking of the lignocellulosic materials, alkaline sulphite solutions are used, to which one or, in mixture, several low-boiling solvents are added, as well as at least one compound suitable as a redox catalyst.

Abstract: Lignocellulosic material is pulped by a process comprising the steps of: introducing a molecular oxygen-containing gas, such as air, into an alkaline sulfide solution containing NaOH, Na.sub.2 S and at least one cyclic organic compound selected from quinone, hydroquinone, 9,10-diketohydroanthracene and 9,10-dihydroxyhydroanthracene compounds, to oxidize at least a portion of Na.sub.2 S; delignifying the lignocellulosic material with an alkaline sulfide cooking liquor containing the oxidized alkaline sulfide solution at an elevated temperature and; then, recovering the resultant pulp from the delignification mixture.

Abstract: Air is removed from wood chips, and they are impregnated by treatment liquid, in a process that is an alternative to presteaming and is particularly applicable to environments where presteaming is undesirable, such as in the sulphite treatment of chips during the production of mechanical pulp. The chips are passed in a continuous manner in a generally serpentine, vertically oriented path so that the chips are subjected to a pressure build-up pulsation as they move downwardly, and a pressure release pulsation as they move upwardly. The diameters or cross-sectional areas of the conduit portions defining the upward and downward portions of the path are controlled so that there is about twice the residence time during pressure build-up than there is during pressure release. A high pressure feeder and pump with a fly wheel are operatively connected to one end of the serpentine path, while an in-line drainer and other apparatus are connected to the other end.

Abstract: Described herein is a process for producing potassium salts from potassium-based liquors for pulping of lignocellulosic material. The process comprises the steps of(a) digesting lignocellulosic material with a potassium-base aqueous cooling liquor to obtain an aqueous slurry of partially delignified pulp of the lignocellulosic material;(b) separating the pulp from the spent potassium-base aqueous cooling liquor;(c) concentrating the spent pulping liquor; and(d) recovering potassium salts including potassium carbonate, potassium sulphate and potassium lignosulphonate from the concentrated spent pulping liquor. The recovered potassium salts find numerous uses, an example being use in fertilizers.

Abstract: Aqueous sodium dithionite slurries or suspensions, which are nonsettling during shipment thereof and are thereafter pumpable after storage at 32.degree.-40.degree. F. for at least fourteen days, comprise, on a weight basis, about 34% of sodium dithionite, about 0.17% of a xanthan gum, 5.5-6.5% of 50% sodium hydroxide, about 0.26% of a chelate, and about 1.96% of sodium tripolyphosphate which is added after adding the sodium dithionite. Preferably, the sodium tripolyphosphate is added last in making the slurry which is used as a woodpulp bleaching composition.

Abstract: A method for rapid determination of the contents of lignin, monosaccharides and organic acids in the process solutions of sulfite pulping. Accordingly, any non-ionized compounds that disturbs the measurement of these concentrations are separated from the lignin material by an ion-exclusion technique. The measurements of concentrations are carried out by means of the UV-method, refractive-index method, and/or by means of the polarimetric method. The method of the present invention is usable for the controlling of sulfite cooking or other pulping or by-product production processes as well as for the characterization of the spent liquor.

Abstract: A two stage sulfonation system includes a mixing tank, a retention tank, a thickening press, a pressurized vessel, and a liquor recovery press in series relation.The system is designed to receive mechanical pulp, in a slurry form, first introduced into the mixing tank simultaneously with a metered charge of sodium sulfite solution from the holding tank, the sodium sulfite content of which is at a level from about 40 to about 200 g/l. The solution is mixed into the slurry to provide a relatively uniform and intimate contact thereof with its fiber content. This slurry is transferred to the retention tank and there held subject to a sub-boiling temperature between 140 to 210 degrees F., producing a first stage sulfonation of the fiber content. The slurry is then passed to the pressurized vessel, in the course of which it is subjected to a pressing action, extracting liquor which inherently contains a majority of the original sodium sulfite charge directed to the mixing tank.

Abstract: The brightness of a thermomechanical pulp can be improved if a serial multiple blowdown technique is used and a bleachant is present at an effective concentration throughout the thermomechanical pulping process.

Abstract: A process is provided for preparing cellulose pulp by delignification of lignocellulosic material, which comprises subjecting particulate lignocellulosic material in a pulping zone to the pulping action of a pulping liquor at a temperature at which pulping reactions leading to formation of cellulose pulp proceed, and substances having a molecular weight above about 3500, preferably above about 2000, and preferably above about 1500, are physically separated and removed from the lignocellulosic material and become dispersed in the pulping liquor; in the course of the pulping, withdrawing pulping liquor containing such dispersed substances, and removing such dispersed substances therefrom; and then returning the pulping liquor to the pulping zone.

Abstract: Wood pulps, particularly sulphonate pulps, such as jack pine ultra-high-yield pulps produced by sulphonation, are readily discolored by metal ions commonly found in paper mills. Additions of 0.001 to 2% on pulp dry basis of tin ions, especially derived from stannous compounds, to wood pulps effectively brighten the pulps at ambient temperature.Metal ions such as ferrous, ferric, cupric, aluminum, nickel and manganese are common discoloring ions and pulps containing these ions can be brightened by the addition of tin ions particularly derived from stannous chloride, stannous sulphate, stannous tartrate, stannous oxolate, stannic chloride and stannic sulphate, the tin ions as Sn.sup.+2 being added in an amount to provide a ratio of stannous ions to discoloring metal ions up to about 2:1, preferably about 1.5:1.

Abstract: The method relates to a process in the preparation of the cooking liquor for sodium sulphite pulp for carrying out a reaction between sodium bisulphite and sodium bicarbonate and/or sodium carbonate by bringing solutions containing said compounds into contact with each other. The contact between the solution and gas phase takes place in a layer of tower packings. The carbon dioxide produced as a reaction product is allowed to pressurize the reaction vessel a pressure of 1 to 5 bar by restricting the flow escaping from the reaction vessel and by recovering at the same time the carbon dioxide escaping from the reaction vessel at the said pressure in order to use it for carbonation of a solution of green liquor and/or sodium carbonate.

Abstract: A process for the delignification of .Iadd.softwood .Iaddend.lignocellulosic material is described wherein the lignocellulosic material is cooked with .[.an alkaline or.]. .Iadd.a .Iaddend.neutral sulphite pulping liquor, and there is added to the pulping liquor at least 0.001% by weight of an additive compound or mixture of additive compounds selected from quinones and hydroquinones.

Abstract: An improved process for the production of pulp from lignocellulosic material characterized by the employment of a cooking aid is disclosed. The cooking of the lignocellulosic material is carried out in the presence of a small amount of a compound selected from the group consisting of hydroxyanthracenes and derivatives thereof.