Alkali Metal, Ammonium, Alkaline Earth Metal Or Magnesium Hydroxide Or Carbonate Patents (Class 162/90)
  • Patent number: 10413490
    Abstract: This invention provides an effective, dermatologically safe composition based on partially carbonated magnesium hydroxide for use in cosmetic formulations.
    Type: Grant
    Filed: November 10, 2016
    Date of Patent: September 17, 2019
    Assignee: Dead Sea Bromine Company Ltd.
    Inventors: Mohammed Abuelhaiga, Nikolay Fux, Ariel Peleg, Meyrav Abecassis Wolfovich, Ganit Levi-Ruso, Smadar Swissa
  • Patent number: 9115215
    Abstract: The invention discloses a method for completely dissolving and rapidly hydrolyzing cellulose, and uses thereof. Cellulose is placed in an acidic aqueous solution with a [H+] concentration of 10?7˜1 M or an alkaline aqueous solution with a [OH?] concentration of 10?7˜1 M as sample A, wherein the volume ratio of solid to liquid is (0.003˜1.05):1. The acidic aqueous solution with a [H+] concentration of 10?7˜1 M or the alkaline aqueous solution with a [OH?] concentration of 10?7˜1 M is heated up to 261˜352 as sample B. Sample A and sample B obtained from step 1 and step 2 are mixed in a reactor to a concentration of cellulose of 0.1%˜35%, the concentration of the mixed solution is adjusted to an acidity of 10?7˜1 M [H+] or an alkalinity of 10?7˜1 M [OH?], and a water density of 587˜997 kg/m3, pressure is set at 6˜584 MPa. The mixture is rapidly heated up to 261˜352 at heating rate of 7.8˜14.8 /s, and then cellulose is dissolved completely in 0.8˜2 sec and hydrolyzed in 5 sec.
    Type: Grant
    Filed: August 18, 2010
    Date of Patent: August 25, 2015
    Assignee: XISHUANGBANNA TROPICAL BOTANICAL GARDEN, CHINESE ACADEMY OF SCIENCES
    Inventor: Zhen Fang
  • Publication number: 20150064331
    Abstract: A method and a system for preparing xylan and calcium carbonate, xylan, a cellulose fibre, and precipitated calcium carbonate. The method includes extracting xylan from cellulose fibres with sodium hydroxide to form a mixture containing cellulose fibres and an extract solution containing xylan; removing the cellulose fibres from the mixture to isolate the extract solution; adding carbon dioxide to the isolated extract solution to form a mixture containing a liquid brightener and precipitated xylan; separating the brightener from the mixture to isolate the precipitated xylan; adding calcium hydroxide to the separated brightener to form a mixture of precipitated calcium carbonate and liquid sodium hydroxide; and removing the sodium hydroxide from the mixture to isolate the calcium carbonate.
    Type: Application
    Filed: March 26, 2013
    Publication date: March 5, 2015
    Inventors: Björn Krogerus, Agneta Fuhrmann, Christiane Laine
  • Patent number: 8956502
    Abstract: The objective of this invention is a method for separating cellulosic fibres, hemicellulose and lignin from parts of plants containing these, such as stems, leaves and seed coats or hulls of cereal, oilseed, fibre or grassy plants. After appropriate pre-treatments the material is heated in an alkaline solution at lower temperatures than used in the traditional cellulose manufacturing. After this heat treatment, the fibrous and other undissolved materials are separated from the solution and subsequently ground in wet condition, using preferably chafing treatments. For improving the separation, surface active substances can be included in the alkaline heat treatment solution.
    Type: Grant
    Filed: April 18, 2006
    Date of Patent: February 17, 2015
    Assignee: Cerefi Oy
    Inventor: Yrjö Mälkki
  • Publication number: 20150013925
    Abstract: A method for pulp processing used in connection with a pre-hydrolysis kraft process (PHKP) includes adding wood chips or similar material to a reaction vessel, performing pre-hydrolysis, and neutralizing the mixture with a first quantity of white liquor followed by a different solution such as a cold caustic extraction alkaline filtrate optionally enriched with white liquor. The neutralization fluids are replaced with a cooking fluid comprising a hot black liquor and alkaline filtrate, optionally enriched with white liquor. The cooking fluid may have a relatively high effective alkali concentration. The cooked pulp may exhibit very low residual hemicelluloses and a kappa number within an optimal range.
    Type: Application
    Filed: April 16, 2014
    Publication date: January 15, 2015
    Inventor: Marcelo Moreira Leite
  • Patent number: 8864943
    Abstract: Provided is a method for preparing nonionic water-soluble cellulose ether having low insoluble content and providing a transparent solution. More specifically, provided is a method for preparing nonionic water-soluble cellulose ether comprising at least the steps of: drying a pulp sheet or pulp chips into which the pulp sheet has been converted, bringing the dried pulp sheet or pulp chips into contact with an alkali metal hydroxide solution to obtain alkali cellulose, draining the alkali cellulose, and reacting the drained alkali cellulose with an etherifying agent.
    Type: Grant
    Filed: August 28, 2012
    Date of Patent: October 21, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Mitsuo Narita
  • Patent number: 8734612
    Abstract: A method for pulp processing used in connection with a pre-hydrolysis kraft process (PHKP) includes adding wood chips or similar material to a reaction vessel, performing pre-hydrolysis, and neutralizing the mixture with a first quantity of white liquor followed by a different solution such as a cold caustic extraction alkaline filtrate optionally enriched with white liquor. The neutralization fluids are replaced with a cooking fluid comprising a hot black liquor and alkaline filtrate, optionally enriched with white liquor. The cooking fluid may have a relatively high effective alkali concentration. The cooked pulp may exhibit very low residual hemicelluloses and a kappa number within an optimal range.
    Type: Grant
    Filed: May 27, 2010
    Date of Patent: May 27, 2014
    Assignee: Bahia Specialty Cellulose
    Inventor: Marcelo Moreira Leite
  • Publication number: 20140120596
    Abstract: A process for pretreating a lignocellulosic material is provided. The process comprises mixing the lignocellulosic material and an alkaline aqueous solution, in a solid to liquid weight ratio of equal to or more than 25:75 to equal to or less than 60:40, in a mixer to produce an aqueous slurry and heat-treating the aqueous slurry at a temperature in the range from equal to or more than 50° C. to equal to or less than 200° C. to produce a heat-treated aqueous slurry comprising a pretreated lignocellulosic material. The lignocellulosic material has a lignin content in the range from equal to or more than 10 wt % to equal to or less than 50 wt %, based on the total weight of the lignocellulosic material. The alkaline aqueous solution has a pH of equal to or more than 9.0.
    Type: Application
    Filed: October 30, 2013
    Publication date: May 1, 2014
    Applicant: Shell Oil Company
    Inventors: Haisong WANG, Chao Liu, Xindong Mu, Evert Van Der Heide, Bin Li, Guang Yu
  • Publication number: 20140048223
    Abstract: A method for treating a cellulosic material comprising extracting the cellulosic material with an extractant to selectively extract hemicellulose therein and separating the extracted hemicellulose to form a cellulosic product comprising less hemicellulose than the cellulosic material. The extractant comprises an amine oxide and a non-solvent. The cellulosic product retains the cellulosic fiber morphology.
    Type: Application
    Filed: March 14, 2013
    Publication date: February 20, 2014
    Applicant: CELANESE INTERNATIONAL CORPORATION
    Inventors: Rongfu Li, Jay Mehta, Xiaoyan Tu, Prabuddha Bansal, Michael Combs, Denis Fallon, Lawton E Kizer
  • Patent number: 8609379
    Abstract: Alcohols useful as fuel compositions are produced from biomass by pretreating the biomass prior to hydrolysis and fermentation. In the pretreatment, the biomass is contacted with an aqueous solution containing a dilute acid with concentration of up to 10 wt % producing a predigested stream containing an aqueous liquor that contains at least a portion of hemicelluloses and a residual biomass that contains celluloses and lignin; separating at least a portion of the aqueous liquor from the residual biomass providing an aqueous liquor stream and a pre-digested biomass stream; then contacting the pre-digested biomass stream with a cooking liquor containing at least one alkali selected from the group consisting of sodium hydroxide, sodium carbonate, sodium sulfide, potassium hydroxide, potassium carbonate, ammonium hydroxide, and mixtures thereof and water. A process that allows for higher recovery of carbohydrates and thereby increased yields is provided.
    Type: Grant
    Filed: December 20, 2011
    Date of Patent: December 17, 2013
    Assignee: Shell Oil Company
    Inventors: Juben Nemchand Chheda, Evert Van Der Heide
  • Patent number: 8591702
    Abstract: Impregnating or spraying softwood chips in a solution containing an appropriate concentration of alkaline earth metal ions selected from the group consisting of calcium ions, barium ions and strontium, preferably calcium ions, at room temperature before a reductive alkaline pulping process, for example kraft pulping, significantly increases pulp yield. Using an agent that complexes with the metal ions, such as hydroxyethylidene diphosphonic acid (HEDP) allows this benefit of metal ions to be achieved during the pulping process rather than in a separate impregnation step.
    Type: Grant
    Filed: December 3, 2009
    Date of Patent: November 26, 2013
    Assignee: FPInnovations
    Inventors: Yujun Sun, Richard McKinnon Berry, Theodore Radiotis
  • Publication number: 20130280762
    Abstract: A process is provided comprising subjecting a quantity of plant biomass fibers to a pretreatment to cause at least a portion of lignin contained within each fiber to move to an outer surface of said fiber, wherein a quantity of pretreated tacky plant biomass fibers is produced; and densifying the quantity of pretreated tacky plant biomass fibers to produce one or more densified biomass particulates, wherein said biomass fibers are densified without using added binder.
    Type: Application
    Filed: March 15, 2013
    Publication date: October 24, 2013
    Applicant: BOARD OF TRUSTEES OF MICHIGAN STATE UNIVERSITY
    Inventor: Board Of Trustees Of Michigan State University
  • Patent number: 8524474
    Abstract: Methods for obtaining concentrated sugar solution from polysaccharide enriched biomass by contacting biomass with water and at least one nucleophilic base to produce a polysaccharide enriched biomass comprising a solid fraction and a liquid fraction and then contacting the solid fraction with saccharification enzyme consortium to produce a saccharification product comprising at least about 7 percent by weight sugars in 24 hours. The methods include optionally adding at least one additive selected from the group consisting of polyethylene glycols, fatty acid esters, fatty acid ethoxylates, nonionic surfactants derived from polyethoxylated sorbitan and a fatty acid, sodium lauriminodipropionate, sodium cocoamphoacetate, sodium tridecyl ether sulfate and a combination of these, such that enzyme loading of the saccharification enzyme consortium can be reduced.
    Type: Grant
    Filed: November 19, 2009
    Date of Patent: September 3, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventors: Subramaniam Sabesan, Christina Jacy Spado
  • Publication number: 20130219547
    Abstract: The invention relates to nucleic acids encoding a feruloyl-CoA:monolignol transferase and the feruloyl-CoA:monolignol transferase enzyme that enables incorporation of monolignol ferulates, for example, including p-coumaryl ferulate, coniferyl ferulate, and sinapyl ferulate, into the lignin of plants.
    Type: Application
    Filed: July 22, 2011
    Publication date: August 22, 2013
    Applicant: BOARD OF TRUSTEES OF MICHIGAN STATE UNIVERSITY
    Inventors: Curtis Wilkerson, John Ralph, Saunia Withers
  • Patent number: 8496782
    Abstract: Provided is a method for preparing cellulose ether which is transparent as dissolved in water and has low water-insoluble content. More specifically, provided are a method for preparing alkali cellulose comprising a contact step of bringing a pulp sheet having a pore volume of 1.0 ml/g or greater, or chips into which the pulp sheet has been converted, into contact with an alkali metal hydroxide solution to obtain an alkali cellulose reaction mixture, and a drain step of draining the alkali cellulose reaction mixture; and a method for preparing water-soluble cellulose ether comprising a step of reacting the alkali cellulose with an etherifying agent.
    Type: Grant
    Filed: December 9, 2008
    Date of Patent: July 30, 2013
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Mitsuo Narita
  • Patent number: 8497410
    Abstract: A method of making personal hygiene articles of high absorbency from cellulosic fiber pulp without chemical cross-linking of the cellulosic fibers is disclosed. The method comprises interposing a sublayer of mechanically fluffed alkali extracted cellulosic fiber pulp between a fluid permeable layer and a fluid impermeable layer.
    Type: Grant
    Filed: February 18, 2011
    Date of Patent: July 30, 2013
    Assignee: Rayonier TRS Holdings Inc.
    Inventors: Phyllis Leithem, Charles A. Kremers, W. Paul Harrell, Stephen Lewis, Karl D. Sears, Quan He, Peter R. Abitz
  • Publication number: 20130102984
    Abstract: A method of producing a modified pulp for use in paper or paper web products, the method comprising treating wood chips in an extraction process to remove hemicellose to form treated wood chips; and subjecting said treated wood chips to chemical or semichemical pulping to form a modified Kraft pulp wherein the amount of hemicellulose contained in the modified Kraft pulp is from about 5 to about 10% by dry weight of the modified pulp.
    Type: Application
    Filed: December 11, 2012
    Publication date: April 25, 2013
    Applicant: INTERNATIONAL PAPER COMPANY
    Inventor: International Paper Company
  • Publication number: 20130062027
    Abstract: Provided is a method for preparing nonionic water-soluble cellulose ether having low insoluble content and providing a transparent solution. More specifically, provided is a method for preparing nonionic water-soluble cellulose ether comprising at least the steps of: drying a pulp sheet or pulp chips into which the pulp sheet has been converted, bringing the dried pulp sheet or pulp chips into contact with an alkali metal hydroxide solution to obtain alkali cellulose, draining the alkali cellulose, and reacting the drained alkali cellulose with an etherifying agent.
    Type: Application
    Filed: August 28, 2012
    Publication date: March 14, 2013
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventor: Mitsuo Narita
  • Publication number: 20130052695
    Abstract: To provide a fine fibrous cellulosic material capable of producing a saccharide in a high yield by hydrolysis; to provide a process for producing the fine fibrous cellulosic material from a cellulosic material; and to provide a process for producing the saccharide using the fine fibrous cellulosic material. The present invention is the fine fibrous cellulosic material containing cellulose, hemicellulose and lignin, which the fine fibrous cellulosic material has a width of 1 ?m or less and a length of 5,000 ?m or less and is used for glycation reaction by hydrolysis.
    Type: Application
    Filed: September 10, 2012
    Publication date: February 28, 2013
    Inventors: Takashi ENDO, Seung-Hwan LEE, Yoshikuni TERAMOTO, Noriko TANAKA, Manami SAKAI, Naomi KADOTANI
  • Patent number: 8268126
    Abstract: The invention herein discloses a method and its equipment for fast and complete dissolution and hydrolysis of lignocellulosic biomass. Lignocellulosic biomass is placed in a dilute alkaline solution and then rapidly heated to a temperature between 329˜367° C. to achieve complete dissolution of the lignocellulosic biomass as biomass solution in 0.7˜2 s. The biomass solution is further hydrolyzed rapidly to hydrolysates at homogeneous conditions. The solubilized biomass solution is easy to rapidly hydrolyze into sugars to produce bio-fuels and other value-added products, and to rapidly quench to produce micron particles in the continuous flow equipment at high pressures and high temperatures. The invention herein provides a simple and low-cost method to quickly dissolve and hydrolyze biomass with great potential for a novel biorefinery.
    Type: Grant
    Filed: March 28, 2008
    Date of Patent: September 18, 2012
    Inventors: Zhen Fang, Chun Fang
  • Patent number: 8262853
    Abstract: According to one embodiment of the invention, a system for processing biomass includes a water-impermeable bottom liner, a gravel layer supported by the bottom liner, a drain pipe disposed within the gravel layer, a biomass input device operable to deliver biomass over the gravel layer to form a biomass pile, a lime input device operable to deliver lime to the biomass for pretreating the biomass, a distribution pipe elevated above the gravel layer, and a pump operable to circulate water through the biomass pile by delivering water to the distribution pipe and receiving water from the drain pipe after it has traveled through the biomass pile. According to another embodiment, a method for biomass pretreatment with alkali, conducted at ambient pressure for approximately 4-16 weeks at temperatures ranging from approximately 25° C. to 95° C. Biomass may be lignocellulosic biomass and may be rendered suitable for enzymatic digestion or pulp production.
    Type: Grant
    Filed: September 5, 2007
    Date of Patent: September 11, 2012
    Assignee: The Texas A&M University System
    Inventors: Mark Thomas Holtzapple, Richard Read Davison, Lee Leon Lowery, Jr., Cesar Benigno Granda
  • Publication number: 20120168102
    Abstract: A method for producing pulp by extracting hemicellulosic materials from lignocellulosic materials using water in an extraction stage, wherein the extraction stage is either a single extraction or a double extraction process; treating the lignocellulosic materials with an oxidizing agent in a treatment stage, wherein the treatment stage is selected from the group consisting of a second extraction process, an agent impregnation process, and a first pretreatment process; treating the lignocellulosic materials with a reducing agent in the treatment stage, wherein the treatment stage is selected from the group consisting of the second extraction process, the agent impregnation process, and a second pretreatment process; and then subjecting the lignocellulosic materials to a modified Kraft pulping process to produce pulp.
    Type: Application
    Filed: April 2, 2010
    Publication date: July 5, 2012
    Inventors: Sung-Hoon Yoon, Harry T. Cullinan, Gopal A. Krishnagopalan
  • Publication number: 20120006321
    Abstract: The present invention relates generally to a process for recovering hemicellulose from Arundo donax comprising extracting a hemicellulose containing fraction from an Arundo donax biomass, purifying the hemicellulose containing fraction to remove lignin and other extractives, concentrating the purified hemicellulose containing fraction, and hydrolyzing the concentrated and purified hemicellulose containing fraction to yield 5 and 6 carbon sugars.
    Type: Application
    Filed: March 8, 2011
    Publication date: January 12, 2012
    Applicant: TreeFree Biomass Solutions, Inc.
    Inventor: W. T. McKean
  • Publication number: 20110284175
    Abstract: Impregnating or spraying softwood chips in a solution containing an appropriate concentration of alkaline earth metal ions selected from the group consisting of calcium ions, barium ions and strontium, preferably calcium ions, at room temperature before a reductive alkaline pulping process, for example kraft pulping, significantly increases pulp yield. Using an agent that complexes with the metal ions, such as hydroxyethylidene diphosphonic acid (HEDP) allows this benefit of metal ions to be achieved during the pulping process rather than in a separate impregnation step.
    Type: Application
    Filed: December 3, 2009
    Publication date: November 24, 2011
    Inventors: Yujun Sun, Richard Mckinnon Berry, Theodore Radiotis
  • Publication number: 20110272110
    Abstract: A method for pulp processing used in connection with a pre-hydrolysis kraft process (PHKP) includes adding wood chips or similar material to a reaction vessel, performing pre-hydrolysis, and neutralizing the mixture with a first quantity of white liquor followed by a different solution such as a cold caustic extraction alkaline filtrate optionally enriched with white liquor. The neutralization fluids are replaced with a cooking fluid comprising a hot black liquor and alkaline filtrate, optionally enriched with white liquor. The cooking fluid may have a relatively high effective alkali concentration. The cooked pulp may exhibit very low residual hemicelluloses and a kappa number within an optimal range.
    Type: Application
    Filed: May 27, 2010
    Publication date: November 10, 2011
    Inventor: Marcelo Moreira Leite
  • Publication number: 20110253326
    Abstract: A method is described for separating lignin from liquid solutions resulting from the pretreatment of lignocellulosic materials such as switchgrass with ammonium hydroxide. The method involves a sequence of steps including acidification, evaporation, and precipitation or centrifugation that are performed under defined conditions, and results in a relatively pure, solid lignin product. The method is tested on ammonium hydroxide solutions containing lignin extracted from switchgrass. Experimental results show that the method is capable of recovering between 66-95% of dissolved lignin as a precipitated solid.
    Type: Application
    Filed: April 18, 2011
    Publication date: October 20, 2011
    Applicant: Savannah River Nuclear Solutions, LLC
    Inventors: Steven Randall Sherman, Maximilian Boris Gorensek
  • Publication number: 20110214826
    Abstract: A process of treating a lignocellulosic material includes a pre-extraction step in which hemicellulose is extracted from the lignocellulosic material. In one embodiment, the pre-extraction step involves contacting the lignocellulosic material with an aqueous solution under conditions that release acidic material from the lignocellulosic material into the aqueous solution, and the aqueous solution includes a basic material that at least partly neutralizes the acidic material so that the aqueous solution at the end of the pre-extraction step has a pH within a range of from 4.5 to 11. The process also includes a pulping step, after the pre-extraction step, in which the lignocellulosic material is separated into pulp. The process further includes an adsorption step, after the pulping step, in which hemicellulose is adsorbed on the pulp.
    Type: Application
    Filed: May 16, 2011
    Publication date: September 8, 2011
    Applicants: UNIVERSITY OF MAINE SYSTEM BOARD OF TRUSTEES, INTERNATIONAL PAPER COMPANY
    Inventors: Adriaan Reinhard Pieter van Heiningen, Sung-Hoon Yoon, Haixuan Zou, Jianer Jiang, Gopal C. Goyal
  • Publication number: 20110209839
    Abstract: A method of making personal hygiene articles of high absorbency from cellulosic fiber pulp without chemical cross-linking of the cellulosic fibers is disclosed. The method comprises interposing a sublayer of mechanically fluffed alkali extracted cellulosic fiber pulp between a fluid permeable layer and a fluid impermeable layer.
    Type: Application
    Filed: February 18, 2011
    Publication date: September 1, 2011
    Inventors: Phyllis Leithem, Clarles A. Kremers, W. Paul Harrell, Stephen Lewis, Karl D. Sears, Quan He, Peter R. Abitz
  • Patent number: 7972479
    Abstract: The present invention relates to a process for the control of pitch in an aqueous medium by adding surface-reacted natural calcium carbonate or an aqueous suspension comprising surface-reacted calcium carbonate and having a pH greater than 6.0 measured at 20° C., to the medium, wherein the surface-reacted calcium carbonate is a reaction product of natural calcium carbonate with carbon dioxide and one or more acids, the use of the surface-reacted natural calcium carbonate for pitch control, as well as to a combination of a surface-reacted natural calcium carbonate and talc for pitch control, and the resulting composites.
    Type: Grant
    Filed: March 19, 2008
    Date of Patent: July 5, 2011
    Assignee: Omya Development AG
    Inventors: Patrick A. C. Gane, Joachim Schölkopf, Daniel Gantenbein
  • Patent number: 7922991
    Abstract: Basic magnesium carbonate comprising a tubular aggregated particle of flaky fine crystals.
    Type: Grant
    Filed: February 12, 2003
    Date of Patent: April 12, 2011
    Assignee: Nittetsu Mining Co., Ltd.
    Inventors: Kohei Mitsuhashi, Katsuyuki Tanabe, Naoki Tagami
  • Patent number: 7919667
    Abstract: An improved absorbency material for absorbency applications comprised of a cellulosic fibrous material wherein said cellulosic fibrous material such as pulp is a cold alkali solution treated material at a treatment temperature of less than about 50° C.; a process for improving absorbency and other characteristics of said pulp.
    Type: Grant
    Filed: June 15, 1999
    Date of Patent: April 5, 2011
    Assignee: Rayonier TRS Holdings Inc.
    Inventors: Phyllis Leithem, Charles A. Kremers, W. Paul Harrell, Stephen Lewis, Karl D. Sears, Quan He, Peter R. Abitz
  • Publication number: 20110073264
    Abstract: The method of the present invention is directed towards a method to increase the pulp yield of a lignocellulosic material, or increasing pulp bulk and/or pulp viscosity. This method comprises the following steps; preparing a lignocellulosic material, contacting the lignocellulosic material in a vessel with hot water or steam for a predetermined time, producing acetic acid from the reaction of the hot water or steam and the lignocellulosic material, lowering the pH to less than about 4, removing lignocellulosic material extracts including a large percentage of hemicellulose, acetic acid and metal ions, exposing contacted lignocellulosic material to pulping chemicals in a pulping reactor, forming a contacted lignocellulosic material pulp with a kappa number below about 19 after about 90 minutes of contact with the pulping chemicals, exposing the contacted lignocellulosic material pulp to whitening agents, and producing a whitened hot water contacted lignocellulosic material pulp.
    Type: Application
    Filed: August 12, 2010
    Publication date: March 31, 2011
    Applicant: The Research Foundation of State University of New York
    Inventors: Shijie Liu, Gangesh Mishra, Thomas E. Amidon, Kathryn E. Gratien, Jennifer A. Putnam
  • Patent number: 7892397
    Abstract: A process for producing dissolving pulp includes a degumming step using a degumming liquor which includes hydrogen peroxide and ammonia.
    Type: Grant
    Filed: May 23, 2008
    Date of Patent: February 22, 2011
    Assignee: Alberta Innovates - Technology Futures
    Inventors: Keith Luo, Wade Chute
  • Patent number: 7887672
    Abstract: A method for extracting such natural cellulosic fiber bundles from natural cellulose sources selected from the group consisting of cornhusk, cornstalk, switchgrass leaves, switchgrass stems, rice straw, sorghum leaves, sorghum stems, soybean straw, wheat straw, cotton stems, barley straw, and combinations thereof, the method comprising performing an alkali treatment to partially delignify the cellulose source material and an enzyme treatment to depolymerize hemicellulose, break covalent links between lignin and carbohydrates, and decompose cellulose chains in the natural cellulosic source material, or a combination thereof thereby yielding extracted natural cellulosic fiber bundles having a length that is greater than that of individual cells and a fineness of at least about 1 denier and no greater than about 300 denier.
    Type: Grant
    Filed: February 16, 2007
    Date of Patent: February 15, 2011
    Assignee: University of Nebraska-Lincoln
    Inventors: Yiqi Yang, Narenda Reddy
  • Publication number: 20100285550
    Abstract: The invention relates to processes of delignifying lignocellulose-containing material, wherein the lignocellulose-containing material is treated with a delignification catalyst and a lignin solubilizing agent.
    Type: Application
    Filed: January 9, 2009
    Publication date: November 11, 2010
    Applicant: Novozymes A/S
    Inventor: Yongming Zhu
  • Publication number: 20100224333
    Abstract: The invention provides a composition of matter and a method, which enhance the process of mechanically pulping paper precursors. The composition of matter includes a small quantity of a reducing agent and a source of alkali. When added to the pulped material, e.g., wood chips, before or during mechanical pulping, the composition reduces the energy cost of the operation. In addition, not only does the composition also does not reduce the brightness of pulp, the composition can also enhance the effectiveness of subsequent bleaching processes.
    Type: Application
    Filed: March 9, 2009
    Publication date: September 9, 2010
    Inventors: Prasad Duggirala, Sergey Shevchenko
  • Publication number: 20100206499
    Abstract: A method for mitigating the costs of establishing a biomass-based pellet manufacturing plant includes identifying an existing pulp processing plant, obtaining permission to access and convert the pulp processing plant, and converting the pulp processing plant for manufacture of biomass-based pellets. Converting the pulp processing plant may include installing a pellet mill in the pulp processing plant, re-routing output from a pulp digester, such that the output enters the pellet mill, and bypassing unnecessary equipment. Biomass-based pellets may be manufactured in the converted pulp processing plant by liberating lignin from biomass-based feedstock via pulp digester and pelletizing the biomass-based feedstock and the liberated lignin to form the biomass-based pellets.
    Type: Application
    Filed: August 21, 2009
    Publication date: August 19, 2010
    Inventors: Wallace R. Lasonde, Larry J. Weick
  • Publication number: 20100186912
    Abstract: A process for the production of a paper pulp, comprising preparing the pulp from a raw material derived from a plant of the Araceae family.
    Type: Application
    Filed: June 12, 2007
    Publication date: July 29, 2010
    Applicant: ECOPULPA LIMITADA
    Inventors: Jerome Paul Pascal Mauborgne, Alex Rossano Imbimbo, Jerome Finbarr O'Donovan, Jairo Torres
  • Publication number: 20100051216
    Abstract: The present invention relates to a process for the control of pitch in an aqueous medium by adding surface-reacted natural calcium carbonate or an aqueous suspension comprising surface-reacted calcium carbonate and having a pH greater than 6.0 measured at 20° C., to the medium, wherein the surface-reacted calcium carbonate is a reaction product of natural calcium carbonate with carbon dioxide and one or more acids, the use of the surface-reacted natural calcium carbonate for pitch control, as well as to a combination of a surface-reacted natural calcium carbonate and talc for pitch control, and the resulting composites.
    Type: Application
    Filed: March 19, 2008
    Publication date: March 4, 2010
    Applicant: OMYA DEVELOPMENT AG
    Inventors: Patrick A.C. Gane, Joachim Schölkopf, Daniel Gantenbein
  • Publication number: 20100024997
    Abstract: The invention relates to a process for the deresination of pulp as well as to the use of carbon dioxide or a (bi)carbonate compound for the deresination of pulp. The process concerns the removal of wood extractives or resin from an aqueous pulp suspension in an alkaline process stage of the pulping process, such as an oxygen delignification stage, at a pH above 10. Carbonate ions are provided in the pulp at the high pH for solubilizing a significant part of the wood extractives in the pulp. The alkaline pulp is dewatered to remove solubilized extractives and for providing a deresinated pulp.
    Type: Application
    Filed: September 7, 2007
    Publication date: February 4, 2010
    Applicant: LINDE AKTIENGESELLSCHAFT
    Inventor: Anna Tigerstrom
  • Publication number: 20100006246
    Abstract: The invention relates to a process for increasing bulk of a fiber product, in which process a fiber pulp, and further a fiber product, is formed. In accordance with the invention, in a first step a carbonate compound is added to the fiber pulp as a basic component, and in a second step acid is added as an acidic component, in order to form salt, to provide the formation of small-bubbled gas, and to increase the bulk, and the fiber pulp is dehydrated. The invention also relates to a corresponding fiber product and to the use thereof.
    Type: Application
    Filed: July 10, 2007
    Publication date: January 14, 2010
    Applicant: Fibertus OY
    Inventor: Mikko Juhani Kaira
  • Publication number: 20090314443
    Abstract: A method for producing fibrous material from softwood, hardwood, or annual plants, including preparing a solution of chemicals having one of: more than 5% of chemicals for softwood, more than 3.5% of chemicals for hardwood, or more than 2.5% of chemicals for annual plants. The method includes: mixing the solution of chemicals with the lignocellulosic material in a predetermined liquor ratio; heating the solution of chemicals and the lignocellulosic material to a temperature above room temperature; and, after the heating, performing one of: removing a free-flowing portion of the solution of chemicals and digesting the lignocellulosic material in a vapor phase, or digesting the lignocellulosic material in a liquid phase and separating the free-flowing portion of the solution of chemicals and the lignocellulosic material. The produced fibrous material has a lignin content of at least 15% for softwood, at least 12% for hardwood, and at least 10% for annual plants.
    Type: Application
    Filed: April 7, 2007
    Publication date: December 24, 2009
    Inventors: Esa-Matti Aalto, Hans-Ludwig Schubert
  • Publication number: 20090266500
    Abstract: The invention relates to a process for producing a tissue web, which is produced from a stock suspension including fibers. In this case, the volume and the tearing length are to be improved with the lowest possible freeness by the stock suspension containing lignocellolosic fibrous material made of wood or annual plants which has a tearing length of more than 6.5 km at 12°SR or a tearing length of more than 8.0 km at 15°SR and a lignin content of at least 15%, based on the oven-dry fibrous material, for coniferous wood in the unbleached state, or a tearing length of more than 4.5 km at 20°SR and a lignin content of at least 12%, based on the oven-dry fibrous material, for deciduous wood in the unbleached state, or a tearing length of more than 3.5 km at 20°SR and a lignin content of at least 10%, based on the oven-dry fibrous material, for annual plants in the unbleached state.
    Type: Application
    Filed: April 30, 2009
    Publication date: October 29, 2009
    Inventors: Hans-Ludwig Schubert, Frank Peter Meltzer, Esa-Matti Aalto
  • Publication number: 20090264036
    Abstract: Provided is a nanofiber sheet that sufficiently refined by fibrillation and has high crystallinity of cellulose fiber and can realize a fiber-reinforced composite material exhibiting high transparency, a high elastic modulus, a low coefficient of linear thermal expansion, and high heat resistance and being high in flatness and smoothness. This nanofiber sheet includes crystalline cellulose as the main component and a lignin in an amount of from 10 ppm to 10 wt %. When a fiber/resin composite material obtained by impregnating the nanofiber sheet with tricyclodecane dimethacrylate, subjecting the impregnated product to UV-curing at 20 J/cm2, and heating the cured product in vacuum at 160° C. for two hours includes 60 wt % of the cured tricyclodecane dimethacrylate and 40 wt % of nanofiber, the following physical characteristics (i) to (iii) are satisfied: (i) the parallel light transmittance of light of a wavelength of 600 nm at a sheet thickness of 100 ?m is 70% or more; (ii) the Young's modulus is 5.
    Type: Application
    Filed: July 13, 2007
    Publication date: October 22, 2009
    Applicants: Nippon Telegraph and Telephone Corporation, Pioneer Corporation, Hitachi, Ltd., Mitsubishi Chemical Corporation, Rohm Co., Ltd.
    Inventors: Hiroyuki Yano, Masaya Nogi, Shinsuke Ifuku, Kentarou Abe, Keishin Handa
  • Publication number: 20090229772
    Abstract: This invention relates to bleached mechanical paper pulps, based on fibrillated fibres of cellulose, hemicelluloses and lignin, containing calcium carbonate, in which calcium carbonate is crystallised and at least partly covers the fibrillated fibres of cellulose, hemicelluloses and lignin to which the calcium carbonate is mechanically bonded, papers made from these pulps and their preparation process.
    Type: Application
    Filed: March 10, 2009
    Publication date: September 17, 2009
    Applicant: INTERNATIONAL PAPER COMPANY
    Inventor: CLAUDE RAYMOND RIOU
  • Publication number: 20090165971
    Abstract: Provided is a method for preparing cellulose ether which is transparent as dissolved in water and has low water-insoluble content. More specifically, provided are a method for preparing alkali cellulose comprising a contact step of bringing a pulp sheet having a pore volume of 1.0 ml/g or greater, or chips into which the pulp sheet has been converted, into contact with an alkali metal hydroxide solution to obtain an alkali cellulose reaction mixture, and a drain step of draining the alkali cellulose reaction mixture; and a method for preparing water-soluble cellulose ether comprising a step of reacting the alkali cellulose with an etherifying agent.
    Type: Application
    Filed: December 9, 2008
    Publication date: July 2, 2009
    Inventor: Mitsuo Narita
  • Publication number: 20090165972
    Abstract: Provided is a method for preparing cellulose ether which is transparent as dissolved in water and has low water-insoluble content. More specifically, provided is a method for preparing alkali cellulose, comprising a contact step of bringing a pulp sheet having a sheet density of 0.60 g/ml or less or being formed from pine, or chips into which the pulp sheet has been converted, into contact with an alkali metal hydroxide solution at 5 to 70° C. for 10 to 600 seconds to obtain an alkali cellulose reaction mixture, and a drain step of draining the reaction mixture, wherein an amount of the alkali metal hydroxide solution to be used for the contact step is selected so that the alkali cellulose obtained by the drain step has a ratio of a weight of alkali metal hydroxide component determined by neutralization titration of the alkali cellulose to a weight of solid component in the pulp {(alkali metal hydroxide component)/(solid component in the pulp)} of 0.3 to 1.5.
    Type: Application
    Filed: December 9, 2008
    Publication date: July 2, 2009
    Inventor: Mitsuo Narita
  • Publication number: 20090014138
    Abstract: The invention relates to an improved process to break down lignin macromolecules and liberating cellulose fibers in lignocellulosic material using delignifying reactants with a gaseous organic agent as a heating and reaction-accelerating media. Lignocellulosic material is first impregnated with reactant chemicals, e.g. commonly used agents such as sodium hydroxide and sodium sulfide. Subsequently, the energy required for the delignification reactions is provided through heating with a gaseous organic agent such as methanol or ethanol, condensing and releasing energy to the solid lignocellulosic material. The temperature during the heating step with a gaseous organic agent is higher than the temperature during the impregnation step.
    Type: Application
    Filed: February 10, 2006
    Publication date: January 15, 2009
    Applicant: Metso Paper, Inc.
    Inventors: Eric Enqvist, Panu Tikka, Leopold Heinrich, Matti Luhtanen
  • Patent number: 7396434
    Abstract: A continuous and batch system to produce cellulose, native lignin and unicellular protein from any form of vegetation in a closed process. The biomass is mixed in the impregnate solution of nitric acid and/or ammonium hydroxide and water. After a period of time at room temperature and atmospheric pressure the chemical solution is recycled. The biomass is moved to the reactor and heated. Evaporated impregnate is recovered via absorption tower and recycled back to chemical solution. The biomass is moved to an alkaline solution, then cooled to separate pulp from black liquor. The black liquor is pumped to a separation tank and is treated to precipitate lignin. The solution is filtered to separate sweet liquor and lignin. The lignin is dried and the sweet liquor is fermented to produce unicellular protein.
    Type: Grant
    Filed: June 3, 2004
    Date of Patent: July 8, 2008
    Inventors: Jose Antonio Rodriguez Rivera, Kelly Anthony O'Flynn
  • Patent number: 7390378
    Abstract: A method of providing papermaking fibers with durable curl comprising: a) introducing papermaking fiber into a rotatable drum adapted for operation at elevated pressure; b) rotating the drum containing the papermaking fiber while maintaining: i) the fiber in aqueous dispersion having a consistency of from about 5 to about 45 percent; ii) a temperature of above about 100° C.; the drum being configured such that the aqueous fiber dispersion contacts the rotating wall of the drum during rotation thereof and the mechanical action of the drum on the dispersion provides a durable curl to the papermaking fiber; removing the curled fiber from the rotatable drum wherein the temperature, time, consistency and energy input to the fiber are controlled such that fibers treated exhibit a curl elevation of at least 50 percent at 1 hour storage time.
    Type: Grant
    Filed: July 16, 2004
    Date of Patent: June 24, 2008
    Assignee: Georgia-Pacific Consumer Products LP
    Inventors: Jeffrey R. Carels, Robert L. de Jong, Daniel W. Sumnicht, Jeffrey A. Lee