Injecting While Producing By In Situ Combustion From Same Well Patents (Class 166/257)
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Patent number: 10669828Abstract: Thermal energy delivery and oil production arrangements and methods thereof are disclosed which heat a subterranean formation (132), and which comprises positioning concentric tubing strings (220) in a wellbore (130); heating a heat transfer fluid (250) using a surface thermal fluid heater (186); flowing a liquid or feedwater (142) downward through an extremely hot innermost tubing string (248) that is inside and concentric to an outermost tubing string (252) and a casing/annulus (260), which extends below a thermal packer (156) positioned in the wellbore, and continually circulating the heat transfer fluid through the outermost tubing string and the casing/annulus above the thermal packer such that the liquid or feedwater flowing through the innermost tubing string is heated thereby and injected into the wellbore below the thermal packer and out of perforations to heat the subterranean formation to temperatures that allow for hydrocarbon production from the subterranean formation.Type: GrantFiled: April 1, 2015Date of Patent: June 2, 2020Assignee: Future Energy, LLCInventor: Kent B. Hytken
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Patent number: 10060237Abstract: A method of extracting hydrocarbons from a subterranean formation comprises forming a suspension comprising reactive particles and a carrier fluid. The suspension is introduced into a subterranean formation containing a hydrocarbon material. At least a portion of the reactive particles are exothermically reacted with at least one other material within the subterranean formation to form a treated hydrocarbon material from the hydrocarbon material. The treated hydrocarbon material is extracted from the subterranean formation. An additional method of extracting hydrocarbons from a subterranean formation, and a method of treating a hydrocarbon material within a subterranean formation are also described.Type: GrantFiled: November 22, 2013Date of Patent: August 28, 2018Assignee: Baker Hughes, a GE company, LLCInventors: Oleg A. Mazyar, Oleksandr V. Kuznetsov, Gaurav Agrawal, Michael H. Johnson, Valery N. Khabashesku
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Patent number: 9534482Abstract: A method is provided for applying a thermal process to a lower zone underlying an overlying hydrocarbon zone with thermal energy from the thermal process mobilizing oil in the overlying zone. The lower zone itself could be a hydrocarbon zone undergoing thermal EOR. Further, one can economically apply a thermal EOR process to an oil formation of low mobility and having an underlying zone such as a basal water zone. Introduction gas and steam, the gas having a higher density than the steam, into the underlying zone displaces the basal water and creates an insulating layer of gas between the steam and the basal water maximizing heat transfer upwardly and mobilizing viscous oil greatly reducing the heat loss to the basal water, economically enhancing production from thin oil bearing zones with underlying basal water which are not otherwise economic by other known EOR processes.Type: GrantFiled: December 11, 2013Date of Patent: January 3, 2017Assignee: R.I.I. NORTH AMERICA INC.Inventors: Fred Schneider, Greg Kuran, Lynn Tessier
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Patent number: 9050545Abstract: In embodiments, an aqueous solution containing lixiviants and/or other chemicals and/or reagents may be delivered into the well through one or more conduits or pipes. The chemicals in the aqueous solution may further be mixed together and/or with other ingredients. The solution may thereafter be screened and delivered by being pumped to pressures required for delivery of the solution from a perforated well, deep into a heap leach pad to leach, re-leach, and/or rinse extracted components of interest, such as metals for recovery. The delivery method may open or stimulate new fluid pathways or channels by lifting and mobilizing materials in the heap, thereby creating new channels, and allowing fluid to travel substantially horizontally through the heap to interface with inventory metal for recovery. The system may include a mobile platform assembled near or at the vicinity of the injection well.Type: GrantFiled: April 30, 2012Date of Patent: June 9, 2015Assignee: DIFFERENTIAL ENGINEERING INC.Inventor: Thomas Joseph Seal
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Publication number: 20150144337Abstract: A method of producing heated water from a reservoir having a hot bitumen-depleted zone adjacent to an aqueous mobile zone. The method includes generating fluid communication between the aqueous mobile zone and the hot bitumen-depleted zone. The method further includes driving water from the aqueous mobile zone through a portion of the hot bitumen-depleted zone to heat the water to produce heated water from a heated water production well.Type: ApplicationFiled: November 20, 2014Publication date: May 28, 2015Inventors: Mark BILOZIR, Christian CANAS, Carlos Emilio PEREZ DAMAS, Arun SOOD
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Publication number: 20140251598Abstract: Radio frequency radiation is introduced downhole to heat one or more components of an in-situ hydrocarbon mixture. The mixture is heated to a temperature conducive to auto-ignition. Upon heating, an oxidant is introduced at conditions supportive of auto-ignition. The combined oxidant/hydrocarbon mixture is then allowed to auto-ignite and combust to form a partially upgraded mixture. Certain embodiments include introducing an ignition agent to facilitate auto-ignition. The radio frequency radiation may be supplemented, continued, or varied as desired to maintain, facilitate, or manage the resulting combustion process. In some cases, an activator is introduced to the formation to interact with the generated radio frequency radiation to enhance hydrocarbon heating. Advantages of certain embodiments include lower cost, reduced heating/ignition equipment, higher efficiencies, increased hydrocarbon recovery, and fewer auto-ignition failures.Type: ApplicationFiled: March 7, 2014Publication date: September 11, 2014Applicant: CONOCOPHILLIPS COMPANYInventor: Sergei Aleksandrovich FILATYEV
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Patent number: 8613316Abstract: A downhole steam generation system may include a burner head assembly, a liner assembly, a vaporization sleeve, and a support sleeve. The burner head assembly may include a sudden expansion region with one or more injectors. The liner assembly may include a water-cooled body having one or more water injection arrangements. The system may be optimized to assist in the recovery of hydrocarbons from different types of reservoirs. A method of recovering hydrocarbons may include supplying one or more fluids to the system, combusting a fuel and an oxidant to generate a combustion product, injecting a fluid into the combustion product to generate an exhaust gas, injecting the exhaust gas into a reservoir, and recovering hydrocarbons from the reservoir.Type: GrantFiled: March 7, 2011Date of Patent: December 24, 2013Assignee: World Energy Systems IncorporatedInventors: Anthony Gus Castrogiovanni, Randall Todd Voland, Charles H. Ware, Blair A. Folsom, M. Cullen Johnson
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Publication number: 20130104596Abstract: A pumping system is disclosed comprising a supply pipe, a delivery pipe, a pump capable of pumping a liquid, a first tank with a top port and a bottom port, a second tank with top port and a bottom port, a first pipe switcher operable to switch connections the supply/delivery pipes and the top ports, and a second pipe switcher operable to switch connections between the bottom ports and the pump inlet/outlet. The pipe switchers serve to switch input and output connections such that the tanks are swapped from a position between the supply pipe and the pump inlet and a position between the pump outlet and the delivery pipe. Uses for cooling systems, air compressors, deep wells, and oil extraction are also disclosed.Type: ApplicationFiled: June 28, 2012Publication date: May 2, 2013Inventor: Jasim Saleh Al-Azzawi
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Patent number: 8428924Abstract: A method is disclosed having application notably towards ranking earth models responsive to dynamic heterogeneity. A plurality of earth models representing a subsurface reservoir are provided. Streamline analysis for each of the plurality of earth models is conducted. Flow Capacity (F) vs. Storage Capacity (?) curves are constructed for each of the plurality of earth models based on the streamline analysis. Dynamic heterogeneity for each of the plurality of earth models is computed from the Flow Capacity (F) vs. Storage Capacity (?) curves constructed for each of the plurality of earth models. The plurality of earth models are ranked responsive to dynamic heterogeneity.Type: GrantFiled: December 15, 2009Date of Patent: April 23, 2013Assignee: Chevron U.S.A. Inc.Inventors: George Michael Shook, Kameron Monroe Mitchell
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Patent number: 8276661Abstract: A method of heating a portion of a subsurface formation includes drawing fuel on a fuel carrier through an opening formed in the formation. Oxidant is supplied to the fuel at one or more locations in the opening. The fuel is combusted with the oxidant to provide heat to the formation.Type: GrantFiled: October 13, 2008Date of Patent: October 2, 2012Assignee: Shell Oil CompanyInventors: Michael Costello, Harold J. Vinegar
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Patent number: 8215387Abstract: The invention provides methods for natural gas and oil recovery, which include the use of air injection and in situ combustion in natural gas reservoirs to facilitate production of natural gas and heavy oil in gas over bitumen formations.Type: GrantFiled: March 22, 2012Date of Patent: July 10, 2012Assignee: Encana CorporationInventors: Larry Weiers, Ben Nzekwu
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Patent number: 8167040Abstract: The invention provides methods for natural gas and oil recovery, which include the use of air injection and in situ combustion in natural gas reservoirs to facilitate production of natural gas and heavy oil in gas over bitumen formations.Type: GrantFiled: March 7, 2011Date of Patent: May 1, 2012Assignee: Encana CorporationInventors: Larry Weiers, Ben Nzekwu
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Patent number: 8167036Abstract: A novel method is provided for in situ combustion and recovery of oil from underground reservoirs including injecting oxygen into the reservoir at a region near the reservoir floor, establishing a combustion front wherein hot combustion gases rise at the combustion front, withdrawing hot combustion gases from a region near the reservoir ceiling, and extracting oil from a horizontal production well near the reservoir floor.Type: GrantFiled: July 29, 2009Date of Patent: May 1, 2012Assignee: Precision Combustion, Inc.Inventor: William C. Pfefferle
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Patent number: 8002033Abstract: This method deals in recovering energy in-situ from an underground resource and upgrading such resource above ground. It consists of injecting a hot gas to pyrolyze it to produce gases and liquids with high hydrogen content and a residual hot char. The gases and liquids together with the injected hot gas form a mixture of gases and liquids that is brought above ground and treated into a clean mixture of gases and liquids rich in hydrogen and then used as a chemical feedstock and/or transportation fuel. Following the pyrolyzation of the resource, carbon dioxide and air are injected into the residual hot char to convert the CO2 into 2CO+N2, which is brought above ground and treated into a clean lean gas. This lean gas is used to generate efficient electric power, heat the injected gas for pyrolysis, and convert the 2CO+N2 as a feedstock into fertilizer.Type: GrantFiled: March 3, 2009Date of Patent: August 23, 2011Inventors: Albert Calderon, Terry James Laubis
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Patent number: 7934555Abstract: Multiple producing zones separated by a non-producing zone are gravel packed together. The non-producing zone has locations to take returns so as to get a consistent pack in the non-producing zone. The production string features external seals and/or an internal plug so that no matter which producing zone is aligned to produce, the screens in the non-producing zone are selectively isolated so that the producing zone that is not intended to be produced has only the path through the gravel pack to get to the actual zone being produced. Since the annulus can be long and full of gravel this path will make flow from the zone that is not of interest minimal into the flow from the zone of interest without using a packer between pairs of spaced apart producing zones.Type: GrantFiled: June 1, 2009Date of Patent: May 3, 2011Assignee: Baker Hughes IncorporatedInventor: Robert D. Morton
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Patent number: 7900701Abstract: The invention provides methods for natural gas and oil recovery, which include the use of air injection and in situ combustion in natural gas reservoirs to facilitate production of natural gas and heavy oil in gas over bitumen formations.Type: GrantFiled: January 13, 2006Date of Patent: March 8, 2011Assignee: Encana CorporationInventors: Larry Weiers, Ben Nzekwu
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Patent number: 7841404Abstract: A modified method for in situ recovery of hydrocarbon from an underground hydrocarbon-containing formation. An “L” shaped production well, having a vertical section, and a lower horizontal leg positioned low in the formation, is provided. The horizontal leg connects to the vertical section at a heel portion, and has a toe portion at an opposite end thereof. Oxidizing gas is injected into the formation in or proximate the vertical section. A combustion front sweeps outwardly from the vertical section and laterally within the formation above the horizontal leg, from the heel to the toe, causing hydrocarbons in the formation above the horizontal leg to drain downwardly into the horizontal leg, which are then delivered to surface via production tubing. A non-oxidizing gas is injected into at least the heel portion and preferably additional portions of the horizontal leg via injection tubing contained within the vertical section of the production well.Type: GrantFiled: February 13, 2008Date of Patent: November 30, 2010Assignee: Archon Technologies Ltd.Inventors: Conrad Ayasse, Xinjie Wu, Chris Bloomer
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Patent number: 7814975Abstract: Diluted wet combustion forms a hot process fluid or VASTgas including carbon dioxide (CO2) and fluid water which is delivered to geologic formations and/or to surface mined materials to reduce the viscosity and/or increase hydrocarbon extraction. High water and/or CO2 content is achieved by reducing non-aqueous diluent and/or adding or recycling CO2. Power recovered from expanding the VASTgas may be used to pressurize the VASTgas for delivery by partial expansion through a Direct VAST cycle, and/or by diverting compressed oxidant through a parallel thermogenerator in a Diverted VAST cycle. Pressurized VASTgas may be injected into a well within the hydrocarbon formation or with mined material into a heavy hydrocarbon separator vessel to heat, mobilize, solubilize and/or extract heavy hydrocarbons. Light hydrocarbons may be mixed in with the hot process fluid to enhance hydrocarbon mobilization and recovery. Microwaves may further heat the VASTgas and/or hydrocarbon.Type: GrantFiled: September 18, 2008Date of Patent: October 19, 2010Assignee: Vast Power Portfolio, LLCInventors: David L. Hagen, Ian Wylie, L. Allan McGuire, Gary Ginter
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Publication number: 20100218942Abstract: A method for producing bitumen or heavy oil from a subsurface oil sands reservoir, the subsurface oil sands reservoir and an overlying gas zone in fluid communication, the method includes providing an in situ combustion process in the overlying gas zone, to create or expand a combustion front within the overlying gas zone, providing a thermal recovery process in the oil sands reservoir, to create or expand a rising hot zone within the oil sands reservoir, and selectively operating the thermal recovery process or the in situ combustion process or both such that the rising hot zone does not intersect the overlying gas zone until the combustion front has moved beyond that portion of the overlying gas zone at the intersection.Type: ApplicationFiled: February 5, 2010Publication date: September 2, 2010Inventors: Javier Enrique SANMIGUEL, Matthew Abram Toews, Larry Wayne Freeman
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Patent number: 7686086Abstract: A subsea well assembly has a string of casing with perforations leading to a producing zone and perforations leading to an injection zone. A string of production tubing extends into the casing in communication with the producing formation. A barrier separates the interior of the tubing from the injection zone formation. A subsea Christmas tree is located at the upper end of the well. A subsea separator is connected to a production outlet of the tree for separating waste fluid from the well fluid. A subsea injection pump pumps waste fluid from the separator back to the tree and into the injection formation.Type: GrantFiled: December 8, 2005Date of Patent: March 30, 2010Assignee: Vetco Gray Inc.Inventor: Norman Brammer
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Patent number: 7654320Abstract: A system and method is disclosed for treating a mixture of hydrocarbon and carbon dioxide gas produced from a hydrocarbon reservoir. The system includes a gas power turbine adapted to burn the produced gas mixture of hydrocarbon and carbon dioxide gas with oxygen as an oxidizing agent and a capture system to collect the exhaust gas from the power turbine. An inlet compressor receives exhaust gas from the capture system and compresses the exhaust gas for injection of the exhaust gas into a hydrocarbon reservoir and for recycle to the power turbine. The system may further include a membrane system that preferentially removes carbon dioxide and hydrogen sulfide from the produced gas stream before said stream is used as fuel gas in the power turbine. The carbon dioxide and hydrogen sulfide removed by the membrane system is combined with the exhaust gas, and the combined gas is injected into a hydrocarbon reservoir.Type: GrantFiled: March 22, 2007Date of Patent: February 2, 2010Assignee: Occidental Energy Ventures Corp.Inventor: Thomas J. Payton
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Patent number: 7654330Abstract: Apparatus, methods, and systems for extracting oil or natural gas from a well using a portable coal reformer. In one example, the method may include reforming coal by reaction with water to generate driver gas (comprising carbon dioxide and hydrogen gas), and injecting the driver gas into the well. The driver gas reduces the viscosity and pressurizes the oil to help extract the oil from the oil well. The coal reforming operation may include combusting coal or other combustible material with ambient oxygen to release energy, and heating coal and water with the energy released to a temperature above that required for the coal reforming reaction to proceed, thereby reforming coal and water into driver gas. The driver gas may be purified by filtering out particles and sulfur before injecting into the well. A portion of the hydrogen gas may be separated from the driver gas and used to generate electrical power.Type: GrantFiled: May 19, 2007Date of Patent: February 2, 2010Assignee: Pioneer Energy, Inc.Inventors: Robert M. Zubrin, Mark H. Berggren
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Patent number: 7581587Abstract: A novel method is provided for in situ combustion and recovery of oil from underground reservoirs including injecting air into the reservoir at a region near the reservoir floor, withdrawing combustion products from a region near the reservoir ceiling, and collecting oil from a horizontal production well near the reservoir floor.Type: GrantFiled: December 27, 2006Date of Patent: September 1, 2009Assignee: Precision Combustion, Inc.Inventor: William C. Pfefferle
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Patent number: 7571644Abstract: A system for analyzing reservoir fluids in connection with a drilling operation includes an injection system for providing geochemical analysis of injected drilling fluids; a production system for providing geochemical analysis of produced drilling fluids; a cuttings system for providing geochemical analysis fluid recovered from reservoir cuttings; and a fluid characterization system for characterizing reservoir fluids of a reservoir intersected by the drilling operation based on geochemical analysis from the injection system, the production system, and the cutting system. The fluid characterization system is coupled to the injection system, the production system, and the cutting system.Type: GrantFiled: December 19, 2007Date of Patent: August 11, 2009Assignee: Halliburton Energy Services, Inc.Inventors: Emad B. Ibrahim, Louis W. Elrod, Christopher M. Jones, Sara Shayegi, Timothy O. Wiemers
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Publication number: 20090050319Abstract: A method for in situ heating of a selected portion of a targeted organic-rich rock formation such as an oil shale formation is provided. The method includes the steps of providing casing in a wellbore extending to a depth within or below the selected portion of the organic-rich rock formation, and also providing a tubing within the casing. An annular region is formed between the tubing and the surrounding casing. Air or other oxidant and a combustible fuel are injected into the wellbore. Either the air or the combustible fuel is in stoichiometric combustion excess. The method also includes providing hardware in the wellbore so as to cause the air and the combustible fuel to mix and to combust at substantially the depth of the organic-rich rock formation. The hardware may include more than one burner. Insulation may be placed along the tubing adjacent the first burner in order to reduce the heat transfer coefficient within the tubing and to provide a more uniform temperature within the annulus.Type: ApplicationFiled: April 18, 2008Publication date: February 26, 2009Inventors: Robert D. Kaminsky, Chad C. Rasmussen
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Publication number: 20080289820Abstract: A method of producing hydrogen and extracting heavy oil from underground reserves is provided. This method includes providing a carbon monoxide source stream and a water vapor stream to a first reactor, wherein the first reactor comprises a water shift reactor and a membrane-type separation device. This method also includes separating the products of the water shift reactor, thereby producing at least a hydrogen-rich stream, and a high pressure off-gas stream. This method also includes providing the high pressure off-gas stream and an oxidant stream to a combustion chamber. This method also includes combusting the oxidant stream and the high pressure off-gas stream as at least part of a combustion cycle thereby producing a hot injection gas stream. This method also includes combining the hot injection gas stream with a liquid water stream, wherein the combined stream may be used to heat the underground reserve sufficiently to release petroleum hydrocarbons therefrom.Type: ApplicationFiled: November 8, 2007Publication date: November 27, 2008Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exloitation Des Procedes Georges ClaudeInventor: Errico De Francesco
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Publication number: 20080236820Abstract: Methods and apparatus for producing methane gas from a hydrate formation. A column of modified material substantially filling a wellbore extending into the hydrate formation. The column of modified material is permeable to gases. A heat source extends into the column of modified material and is operable to provide heat to the hydrate formation so as to release methane gas from the hydrate formation. Methane gas flow through the column of modified material to a gas collector, which regulates the flow of gas to a production system.Type: ApplicationFiled: May 5, 2008Publication date: October 2, 2008Inventor: Charles R. Yemington
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Publication number: 20080121393Abstract: A method of dissociating methane hydrate deposits in-situ is provided in which a supply of oxygen, carbon dioxide, and fuel are provided, the oxygen and the carbon dioxide are mixed to form an oxidizer fluid, and the fuel is combusted downhole by reacting it with the oxidizer fluid to provide hot combustion products. The combustion products are placed in contact with a diluent fluid to produce a cooled product fluid at a temperature higher than the prevailing methane hydrate decomposition temperature. The cooled product fluid is injected into the methane hydrate deposit decomposing the hydrate and releasing natural gas.Type: ApplicationFiled: January 23, 2008Publication date: May 29, 2008Inventor: William C. Pfefferle
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Publication number: 20070187093Abstract: The present invention provides a method of recovering stranded oil wherein heated fluid is injected into a reservoir containing stranded oil in a region near the reservoir ceiling. The heated oil drains toward the reservoir floor and is recovered via a production well.Type: ApplicationFiled: January 26, 2007Publication date: August 16, 2007Inventor: William C. Pfefferle
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Patent number: 7114566Abstract: An in situ process for treating a hydrocarbon containing formation is provided. The process may include providing heat from one or more heat sources to at least a portion of the formation. Heat sources may include a natural distributed combustor. The natural distributed combustor may include an oxidizing fluid source to provide oxidizing fluids to a reaction zone in the formation to generate heat within the reaction zone. The heat may be allowed, in some embodiments, to transfer from the reaction zone to a selected section of the formation such that heat from one or more heat sources pyrolyzes at least some hydrocarbons within the selected section. Hydrocarbons may be produced from the formation.Type: GrantFiled: October 24, 2002Date of Patent: October 3, 2006Assignee: Shell Oil CompanyInventors: Harold J. Vinegar, Eric Pierre de Rouffignac, Scott Lee Wellington, Robert Martijn Van Hardeveld
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Patent number: 7096942Abstract: A method for treating a relatively permeable formation containing heavy hydrocarbons in situ may include providing heat from one or more heat sources to a portion of the formation. The heat may be allowed to transfer from the heat sources to a selected section of the formation. The transferred heat may pyrolyze at least some hydrocarbons within the selected section. A mixture of hydrocarbons may be produced from the selected section. In some embodiments, pressure may be controlled to produce a desired property in the produced mixture.Type: GrantFiled: April 24, 2002Date of Patent: August 29, 2006Assignee: Shell Oil CompanyInventors: Eric Pierre de Rouffignac, Ilya Emil Berchenko, Thomas David Fowler, Robert Charles Ryan, Gordon Thomas Shahin, Jr., George Leo Stegemeier, Harold J. Vinegar, Scott Lee Wellington, Etuan Zhang
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Patent number: 7066254Abstract: An in situ process for treating a tar sands formation is provided. The process may include providing heat from one or more heaters to at least a portion of the formation. The heat may be allowed to transfer from the one or more heaters to a part of the formation such that heat from the one or more heat sources pyrolyzes at least some hydrocarbons within the part. Hydrocarbons may be produced from the formation.Type: GrantFiled: October 24, 2002Date of Patent: June 27, 2006Assignee: Shell Oil CompanyInventors: Harold J. Vinegar, Eric Pierre de Rouffignac, John Michael Karanikas, Kevin Albert Maher, Meliha Deniz Sumnu-Dindoruk, Scott Lee Wellington, Steven Dexter Crane, Margaret Ann Messier, Bruce Edmunds Roberts
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Patent number: 7040399Abstract: An oil shale formation may be treated using an in situ thermal process. A mixture of hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a desired temperature. A heating rate for a selected volume of the formation may be controlled by altering an amount of heating energy per day that is provided to the selected volume.Type: GrantFiled: April 24, 2002Date of Patent: May 9, 2006Assignee: Shell Oil CompanyInventors: Scott Lee Wellington, Ilya Emil Berchenko, Eric Pierre de Rouffignac, Thomas David Fowler, Robert Charles Ryan, Gordon Thomas Shahin, Jr., George Leo Stegemeier, Harold J. Vinegar, Etuan Zhang
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Patent number: 7040400Abstract: A method for treating a relatively low permeability formation containing heavy hydrocarbons in situ may include providing heat from one or more heat sources to a portion of the formation. The heat may be allowed to transfer from the heat sources to a selected section of the formation. The transferred heat may pyrolyze at least some hydrocarbons within the selected section. A mixture of hydrocarbons may be produced from the selected section. In certain embodiments, one or more heat sources may be placed in an uncased wellbore.Type: GrantFiled: April 24, 2002Date of Patent: May 9, 2006Assignee: Shell Oil CompanyInventors: Eric Pierre de Rouffignac, Ilya Emil Berchenko, Thomas David Fowler, Bruce Gerard Hunsucker, John Michael Karanikas, Charles Robert Keedy, Robert Charles Ryan, Harold J. Vinegar, Scott Lee Wellington, Etuan Zhang
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Patent number: 7040398Abstract: A method for treating a relatively permeable formation containing heavy hydrocarbons in situ may include providing heat from one or more heat sources to a portion of the formation. The heat may be allowed to transfer from the heat sources to a selected section of the formation. The transferred heat may pyrolyze at least some hydrocarbons within the selected section. A mixture of hydrocarbons may be produced from the selected section. In some embodiments, a reducing environment may be maintained in a portion of the formation.Type: GrantFiled: April 24, 2002Date of Patent: May 9, 2006Assignee: Shell Oil CompanyInventors: Scott Lee Wellington, Ilya Emil Berchenko, Eric Pierre de Rouffignac, Thomas David Fowler, Robert Charles Ryan, Gordon Thomas Shahin, Jr., George Leo Stegemeier, Harold J. Vinegar, Etuan Zhang
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Patent number: 7013972Abstract: An oil shale formation may be treated using an in situ thermal process. A mixture of hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a pyrolysis temperature. Heat may be supplied to the formation by reacting an oxidant with hydrocarbons adjacent to wellbores to generate heat. Generated heat may be transferred to the portion substantially by conduction to pyrolyze at least a portion of hydrocarbon material within the portion.Type: GrantFiled: April 24, 2002Date of Patent: March 21, 2006Assignee: Shell Oil CompanyInventors: Harold J. Vinegar, John Matthew Coles, Eric Pierre de Rouffignac, John Michael Karanikas, James Louis Menotti, Robert Martijn Van Hardeveld, Scott Lee Wellington
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Patent number: 7011154Abstract: In an embodiment, a method of treating a kerogen and liquid hydrocarbon containing formation in situ may include providing heat from one or more heat sources to at least a portion of the formation. Heat may be allowed to transfer from the one or more heat sources to a part of the formation. In some embodiments, at least a portion of liquid hydrocarbons in the part may be mobilized. At least a portion of kerogen in the part may be pyrolyzed. In certain embodiments, a pressure within at least a part of the formation may be controlled. The pressure may be controlled to be at least about 2.0 bars absolute. A mixture may be produced from the formation.Type: GrantFiled: October 24, 2002Date of Patent: March 14, 2006Assignee: Shell Oil CompanyInventors: Kevin Albert Maher, Ilya Emil Berchenko, Eric Pierre de Rouffignac, John Michael Karanikas, Harold J. Vinegar, Scott Lee Wellington, Etuan Zhang
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Patent number: 6997255Abstract: A hydrocarbon containing formation may be treated using an in situ thermal process. A mixture of hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a pyrolysis temperature. A reducing environment may be maintained within a portion of the formation.Type: GrantFiled: April 24, 2001Date of Patent: February 14, 2006Assignee: Shell Oil CompanyInventors: Scott Lee Wellington, Harold J. Vinegar, Eric Pierre de Rouffignac, IIya Emil Berchenko, George Leo Stegemeier, Etuan Zhang, Gordon Thomas Shahin, Jr., Thomas David Fowler, Robert Charles Ryan
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Patent number: 6991033Abstract: An oil shale formation may be treated using an in situ thermal process. Heat may be provided to the treatment area. Heat may be allowed to transfer from at least one heat source to a section of the formation. Pressure within a portion of the formation may be controlled. Hydrocarbons, H2, and/or other formation fluids may be produced from the formation. In some embodiments, the pressure may be controlled to obtain a desired property in the produced fluids.Type: GrantFiled: April 24, 2002Date of Patent: January 31, 2006Assignee: Shell Oil CompanyInventors: Scott Lee Wellington, Ilya Emil Berchenko, Eric Pierre de Rouffignac, Thomas David Fowler, Robert Charles Ryan, Gordon Thomas Shahin, Jr., George Leo Stegemeier, Harold J. Vinegar, Etuan Zhang
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Patent number: 6991032Abstract: A oil shale formation may be treated using an in situ thermal process. A mixture of hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a pyrolysis temperature. Heat sources may be used to heat the formation. The heat sources may be positioned within the formation in a selected pattern.Type: GrantFiled: April 24, 2002Date of Patent: January 31, 2006Assignee: Shell Oil CompanyInventors: Ilya Emil Berchenko, Eric Pierre de Rouffignac, Thomas David Fowler, John Michael Karanikas, Robert Charles Ryan, Gordon Thomas Shahin, Jr., George Leo Stegemeier, Harold J. Vinegar, Scott Lee Wellington, Etuan Zhang
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Patent number: 6981548Abstract: A method for treating a relatively permeable formation containing heavy hydrocarbons in situ may include providing heat from a first set of heat sources to a first section of the formation. The heat provided to the first section may pyrolyze at least some hydrocarbons in the first section. Heat may also be provided from a second set of heat sources to a second section of the formation. The heat provided to the second section may mobilize at least some hydrocarbons in the second section. A portion of the hydrocarbons from the second section may be induced to flow into the first section. A mixture of hydrocarbons may be produced from the formation. The produced mixture may include at least some pyrolyzed hydrocarbons.Type: GrantFiled: April 24, 2002Date of Patent: January 3, 2006Assignee: Shell Oil CompanyInventors: Scott Lee Wellington, Steven Dexter Crane, Eric Pierre de Rouffignac, John Michael Karanikas, Kevin Albert Maher, Margaret Ann Messier, Bruce Edmunds Roberts, Meliha Deniz Sumnu-Dindoruk, Harold J. Vinegar
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Patent number: 6973967Abstract: A coal formation may be treated using an in situ thermal process. A mixture of hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a pyrolysis temperature. Pressure within the formation may be controlled as a function of temperature or temperature within the formation may be controlled as a function of pressure to yield a desired mixture.Type: GrantFiled: April 24, 2001Date of Patent: December 13, 2005Assignee: Shell Oil CompanyInventors: George Leo Stegemeier, Harold J. Vinegar, Scott Lee Wellington, Eric Pierre de Rouffignac, Ilya Emil Berchenko, Etuan Zhang, Thomas David Fowler, Robert Charles Ryan
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Patent number: 6923258Abstract: A hydrocarbon containing formation may be treated using an in situ thermal process. A mixture of hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a pyrolysis temperature. The mixture produced from the formation may have a relatively high hydrogen partial pressure, and a large portion of the pressure within the formation may be attributable to hydrogen partial pressure.Type: GrantFiled: June 12, 2003Date of Patent: August 2, 2005Assignee: Shell Oil CompanyInventors: Scott Lee Wellington, Harold J. Vinegar, Eric Pierre de Rouffignac, Ilya Emil Berchenko, George Leo Stegemeier, Etuan Zhang, Gordon Thomas Shahin, Jr., Thomas David Fowler, Robert Charles Ryan
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Patent number: 6923257Abstract: An oil shale formation may be treated using an in situ thermal process. Hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a pyrolysis temperature. Heat input into the formation may be controlled to maintain a temperature below about a maximum selected temperature.Type: GrantFiled: April 24, 2002Date of Patent: August 2, 2005Assignee: Shell Oil CompanyInventors: Scott Lee Wellington, Ilya Emil Berchenko, Eric Pierre de Rouffignac, Thomas David Fowler, John Michael Karanikas, Robert Charles Ryan, Gordon Thomas Shahin, Jr., George Leo Stegemeier, Harold J. Vinegar, Etuan Zhang
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Patent number: 6918443Abstract: An oil shale formation may be treated using an in situ thermal process. A mixture of hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a desired temperature. An average temperature and/or pressure within the formation may be controlled to inhibit production of hydrocarbons that have carbon numbers greater than a selected carbon number. In some embodiments, the selected carbon number may be 25. A small amount of hydrocarbons having carbon numbers greater than the selected carbon number may be entrained in vapor produced from the formation.Type: GrantFiled: April 24, 2002Date of Patent: July 19, 2005Assignee: Shell Oil CompanyInventors: Scott Lee Wellington, Ilya Emil Berchenko, Eric Pierre de Rouffignac, Thomas David Fowler, Robert Charles Ryan, Gordon Thomas Shahin, Jr., George Leo Stegemeier, Harold J. Vinegar, Etuan Zhang
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Patent number: 6918442Abstract: An oil shale formation may be treated using an in situ thermal process. A mixture of hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a pyrolysis temperature. A reducing environment may be maintained within a portion of the formation.Type: GrantFiled: April 24, 2002Date of Patent: July 19, 2005Assignee: Shell Oil CompanyInventors: Scott Lee Wellington, Ilya Emil Berchenko, Eric Pierre de Rouffignac, Thomas David Fowler, Robert Charles Ryan, Gordon Thomas Shahin, Jr., George Leo Stegemeier, Harold J. Vinegar, Etuan Zhang
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Patent number: 6910536Abstract: A hydrocarbon containing formation may be treated using an in situ thermal process. A mixture of hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a pyrolysis temperature. Heat may be supplied to the formation by reacting an oxidant with hydrocarbons adjacent to heater wellbores to generate heat. Generated heat may be transferred to the portion substantially by conduction to pyrolyze at least a portion of hydrocarbon material within the portion.Type: GrantFiled: April 24, 2001Date of Patent: June 28, 2005Assignee: Shell Oil CompanyInventors: Scott Lee Wellington, Harold J. Vinegar, Eric Pierre de Rouffignac, John Michael Karanikas, Ilya Emil Berchenko, Kevin Albert Maher, Gordon Thomas Shahin, Jr., James Louis Menotti, John Matthew Coles
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Patent number: 6896053Abstract: A hydrocarbon containing formation may be treated using an in situ thermal process. A mixture of hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a pyrolysis temperature. Heat sources may be used to heat the formation. The heat sources may be positioned within the formation in a pattern. The pattern may be a repeating pattern of triangles.Type: GrantFiled: April 24, 2001Date of Patent: May 24, 2005Assignee: Shell Oil CompanyInventors: Ilya Emil Berchenko, Harold J. Vinegar, Scott Lee Wellington, Eric Pierre de Rouffignac, John Michael Karanikas, George Leo Stegemeier, Thomas David Fowler, Robert Charles Ryan
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Patent number: 6880633Abstract: An oil shale formation may be treated using an in situ thermal process. Heat may be provided from one or more heat sources. Heat may be allowed to transfer from the heat sources to a section of the formation. Hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Conditions in a section of the formation may be controlled to produced a desired product.Type: GrantFiled: April 24, 2002Date of Patent: April 19, 2005Assignee: Shell Oil CompanyInventors: Scott Lee Wellington, Ilya Emil Berchenko, Eric Pierre de Rouffignac, Thomas David Fowler, Robert Charles Ryan, Gordon Thomas Shahin, Jr., George Leo Stegemeier, Harold J. Vinegar, Etuan Zhang
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Patent number: 6877554Abstract: A hydrocarbon containing formation may be treated using an in situ thermal process. A mixture of hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a pyrolysis temperature. Pressure within the formation may be controlled as a function of temperature or temperature within the formation may be controlled as a function of pressure to yield a desired mixture.Type: GrantFiled: April 24, 2001Date of Patent: April 12, 2005Assignee: Shell Oil CompanyInventors: George Leo Stegemeier, Harold J. Vinegar, Scott Lee Wellington, Eric Pierre de Rouffignac, Gordon Thomas Shahin, Jr., John Michael Karanikas, Ilya Emil Berchenko, Etuan Zhang, Thomas David Fowler, Robert Charles Ryan